X射线能谱分析中谱线重叠问题

扫描电子显微镜上配接Si(Li)探测器X射线能谱仪,进行地质样品分析时,由于它的峰,背比值较低和谱线分辨率不如X射线波谱仪,尽管探测效率很高,仍然存在谱线的干扰或重叠现象。谱线的干扰或重叠现象主要划分为三个类型:相邻或相近元素同一线系(K、L、M)的谱线之间重叠;原子序数较低的K线系谱线与原子序数较高的L线系谱线之间的重叠;原子序数较低的K线系谱线与原子序数高的L线系谱线以及原子序数高的M线系谱线之间的重叠。为了保证X射线能谱分析中定性分析的准确性,本文介绍了辨认和处理干扰或重叠谱线的技巧。     

光谱半定量全分析方法

光谱丰定量分析是在映谱仪下目视比较谱线的黑度,来确定元素质量分数范围的方法。其优点是成本低、快速、简单、信息量十分丰富,一次摄谱可同时测定45个元素。是实验室对于地质找矿不可缺少的分析手段之一。     

计算机译谱鉴定会及计算机在岩矿分析中的应用

该译谱仪是将微型计算机的数据采集、信息处理、自动控引、数据计算等功能用于发射光谱照相谱图大量信息的检验和解释。其特点有一、仪器能自动识别起始标志线,能准确地自动寻找被测的谱线。二、谱板的扫描速度、实测数据为:正反扫描长度193毫米,正扫描范围内测量13条谱线。三、     

CE3玉兔号月球车APXS特征X射线能谱信息分析

通过对CE3玉兔号月球车粒子激发X射线谱仪（APXS）获取的数据进行处理,获得测点的累积特征X荧光计数率谱线,经小波滤波,消除放射性涨落对X荧光谱线的影响。由能量刻度获得了月球车着陆点月壤元素X射线特征能量峰,由此分析了着陆点月壤元素的成分,得知测量点月壤元素成分包括Si、Ca、Al、Mg、K、P、S、Fe、Ti、Ni、Cr、Mo、Sr、Y、Zr、Nb。研究结果为月陆地质演化提供了有利的参数制约。     

γ射线低能谱测量在地质调查中的初步应用

在分析介绍野外地面γ射线谱仪器设备的基础上，针对低能γ射线谱的特点，结合地质调查项目，在金矿勘查工作中进行了实际应用。并以特例的形式，给出一个测点的实测γ射线谱曲线图、一条测线的综合剖面图和一个工作区的平面结果图，结果表明，低能γ射线谱能够在覆土覆盖的泥质片岩中较好地区分出含矿有利层位一炭质片岩的分布范围。     

地面雨滴谱观测技术及特征研究进展

雨滴谱是反映降水微观物理过程和宏观动力结构的主要指标之一.通过分析雨色斑滴谱,可以深入了解降水的发展和演变过程,揭示降水机制.传统雨滴谱测量包括动力学法、滤纸色斑法、面粉团法、快速摄影法和浸润法等,但是普遍存在精度低、工作量大、实时性差、成本高及无法自动完成测量分类等缺点.以雨滴谱仪为代表的新型雨滴谱测量技术包括冲击雨滴谱仪、光学雨滴谱仪和声学雨滴谱仪以及雷达技术等克服了这些缺点,在降水粒子观测和降水物理研究中发挥了重要的作用.综合概述了描述雨滴谱的主要分布模型及其适用条件.归纳分析了不同降水云系(对流云、层状云和层积云降水)、不同降水类型(大陆云和海洋云降水)及不同高度处观测的降水的雨滴谱特征.从学科发展趋势和社会需求的角度,概述了有关雨滴谱研究中存在的主要问题和发展趋势.     

发射光谱深孔大电极法测定硼、锡、银

以Al2O3、NaF和K2S2O7作为缓冲剂,以Ge为内标,与样品研磨混匀,装入石墨深孔大电极中作为样品电极,石墨电极平头柱形空腔为上电极,样品电极为下电极进行摄谱,由光电译谱仪测定谱线的黑度值。用发射光谱法深孔大电极一次性摄谱,对农业地质样品中硼、锡、银的测定,经过反复实验取得了较好的效果。本法测定了国家一级标准物质,结果与标准值相符。本法灵敏度高,背景浅,能满足多目标地质样品分析的要求。     

野外多道伽马能谱测量在核环境地质评价中的应用

介绍了最新研制的CD-10野外便携式伽马全谱仪工作原理和主要技术指标。该仪器对伽马射线能量分析范围是30～3000keV,分析道数为1024道,对¹³⁷Cs的能量分辨率小于12%,取消了放射性稳谱参考源,采用数字稳谱技术,实现了无干扰天然伽马射线全谱(30～3000keV)测量,并以在核环境地质评价中的应用实例,说明了伽马全谱仪的主要特点和应用前景。     

计算机译谱鉴定会及计算机在岩矿分析中的应用(资料摘要选登)

ZYP—1型计算机自动译谱系统 新疆地质矿产局中心实验室 该译谱仪是将微型计算机的数据采集、信息处理、自动控引、数据计算等功能用于发射光谱照相谱图大量信息的检验和解释。其特点有一、仪器能自动识别起始标志线,能准确地自动寻找被测的谱线。二、谱板的扫描速度、实测数据为:正反扫描     

山东大磨曲家矿区成矿元素多重分形特征

通过矩方法,以无序数据集中不同品位级次内的频率为测度,研究了胶东大磨曲家金矿矿体及玲珑花岗岩、胶东群等近矿围岩的Au、Ag、As等主要成矿元素分布的广义谱曲线(D_q-q)和多重谱曲线(f(α)-α)特征。在权重-0.2≤q≤1. 6时,结果显示矿体与近矿围岩中成矿元素品位分布的广义谱和多重谱特征存在明显的区别。矿体中三种成矿元素的广义谱曲线近似直线,而多重谱曲线的宽度较小,显示成矿元素品位级次密集,较为均匀,接近简单分形;近矿围岩中广义谱曲线弯曲明显,多重谱曲线的宽度较大,显示近矿围岩中元素品位级次范围较宽,相对不均匀。同时,矿体中多重谱曲线f(α)的极值所对应的α比近矿围岩中的小,代表最或然子集的品位增加,指示成矿元素在矿体中富集。多重分形分析显示矿体中的成矿元素较近矿围岩中变得更为富集而均匀。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861