Relation of lava compositions to volcano size and structure in El Salvador

Most of the lavas at the nine volcanic centers along the volcanic front of El Salvador are basalts, basaltic andesites and andesites. The compositional variation within and among these centers can be explained by fractionation processes within the crust. Cognate gabbroic inclusions found in the lavas have appropriate mineralogy (plagioclase, olivine, magnetite and augite) to be cumulates formed by fractional crystallization. Two main variation trends occur, depending on the proportion of plagioclase removal. The more common, or normal, trend has a high (> 55%) proportion of plagioclase being removed. A less common, Al-rich, trend has a low (40%) proportion of plagioclase being removed. The Al-rich trend is found only at volcanoes that lack large negative Bouguer gravity anomalies. These volcanoes are unlikely to have large shallow magma chambers and fractionation probably occurs deeper in the crust where plagioclase removal is inhibited.The incompatible element (Na₂O, K₂O, Rb, Ba) contents of lavas vary systematically with the volume of the volcanic centers. At the same level of SiO₂, large volcanic centers have higher incompatible element contents than small volcanic centers. This suggests that open system fractionation in a periodically refilled chamber is the controlling factor. The large difference in Ba contents of lavas between eastern (low) and western (high) El Salvador suggests a difference in the mantle source region.     

Petrogenetic modeling of rock variety in the Khalkhab–Neshveh pluton,NW of Saveh,Iran

The Khalkhab–Neshveh (KN) pluton is a part of Urumieh–Dokhtar Magmatic Arc and was intruded into a covering of basalt and andesite of Eocene to early Miocene age. It is a medium to high‐K, metaluminous and I‐type pluton ranging in composition from quartz monzogabbro, through quartz monzodiorite, granodiorite, and granite. The KN rocks show subtle differentiation trends strongly controlled by clinopyroxene, plagioclase, hornblende, apatite, and titanite, where most major elements (except K₂O) are negatively correlated with SiO₂; and Al₂O₃, Na₂O, Sr, Eu, and Y define curvilinear trends. Considering three processes of magmatic differentiation including mixing and/or mingling between basaltic and dacitic magmas, gravitational fractional crystallization and in situ crystallization revealed that the latter is the most likely process for the evolution of KN magma. This is supported by the occurrence of all rock types at the same level, the lack of mafic enclaves in the granitoid rocks, the curvilinear trends of Na₂O, Sr, and Eu, and the constant ratios of (⁸⁷Sr/⁸⁶Sr)_i from quartz monzodiorite to granite (0.70475 and 0.70471, respectively). In situ crystallization took place via accumulation of plagioclase and clinopyroxene phenocrysts and concentration of these phases in the quartz monzogabbro and quartz monzodiorite at the margins of the intrusion at T ≥ 1050°C, and by filter pressing and fractionation of hornblende, plagioclase, and later biotite in the granitoids at T = ～880°C.     

Neodymium-strontium isotopic evidence for extreme contamination in a layered basic intrusion

Neodymium and strontium isotopic analyses from the Kalka layered basic intrusion, central Australia, are arrayed parallel to the Sr-axis of a Nd-Sr isotopic correlation diagram and are removed from the normal basaltic field. Initial¹⁴³Nd/¹⁴⁴Nd ratios are almost constant and typical of continental basalts, whereas initial⁸⁷Sr/⁸⁶Sr ratios vary greatly and range to high values (0.7049–0.7088). Acidic granulites from the country rock lie upon the continuation of the Kalka trend at higher⁸⁷Sr/⁸⁶Sr ratios outlining a mixing system between granulite and normal basaltic magma. If average granulite acted as a contaminant, isotope dilution calculations show that amounts assimilated reached as high as 25%. Bulk contamination is confirmed petrologically by the abundance of orthopyroxene, particularly as basal orthopyroxenites and the restriction of olivine to less-contaminated levels. Analogies between Kalka and several other major layered intrusions, such as the Bushveld Complex, suggest that large-scale contamination was a significant aspect of their genesis.     

Three magmatic components in the 1973 eruption of Eldfell volcano,Iceland: Evidence from plagioclase crystal size distribution (CSD) and geochemistry

The 1973 eruption of Eldfell volcano, Iceland, appears to have been a short, simple event, but textural and geochemical evidence suggest that it may have had three different magmatic components. The first-erupted fissure magmas were chemically evolved, rich in plagioclase (∼ 18%) and had shallow, straight crystal size distribution (CSD) curves. The early lavas were less evolved chemically, had lower plagioclase contents (∼ 13%) and steeper, slightly concave up CSDs. The late lavas were chemically similar to the early lavas, but even richer in plagioclase than the initial magmas (∼ 24%) and had the steepest CSDs. There was no chemical evidence for plagioclase fractionation, but compositional diversity could be produced by clinopyroxene fractionation which must have occurred at depth. We propose that the eruption started with old, coarsened (Ostwald ripened) magma left over from a previous eruption, possibly that which produced Surtsey Island ten years earlier. The early flows may be mixtures of small amounts of this old magma with a new, low crystallinity, uncoarsened magma or a completely new magma. The late flows are another new magma from depth, chemically similar to the early flows, but which has grown plagioclase under increasing saturation (undercooling) perhaps during its ascent. All three magmatic components may have originated from the same parent, but had varying degrees of clinopyroxene fractionation, plagioclase nucleation and growth, and coarsening.     

Origin of differentiated lavas at Kilauea Volcano,Hawaii: Implications from the 1955 eruption

Kilauea's 1955 eruption was the first major eruption (longer than 2 days) on its east rift zone in 115 years. It lasted 88 days during which 108 × 10⁶ m³ of lava was erupted along a discontinuous, 15-km-long system of fissures. A wide compositional range of lavas was erupted including the most differentiated lavas (5.0 wt% MgO) from a historic Kilauea eruption. Lavas from the first half of the eruption are strongly differentiated (5.0–5.7 wt% MgO); later lavas are weakly to moderately differentiated (6.2–6.7 wt% MgO). Previous studies using only major-element compositions invoked either crystal fractionation (Macdonald and Eaton 1964) or magma mixing (Wright and Fiske 1971) as models to explain the wide compositional variation in the lavas. To further evaluate these models detailed petrographic, mineralogical, and whole-rock, major, and trace element XRF analyses were made of the 1955 lavas. Plagioclase and clinopyroxene in the early and late lavas show no petrographic evidence for magma mixing. Olivines from both the early and late lavas show minor resorption, which is typical of tholeiitic lavas with low MgO contents. Core-to-rim microprobe analyses across olivine, augite, and plagioclase mineral grains give no evidence of disequilibrium features related to mixing. Instead, plots of An/Ab vs distance from the core (D) and %Fo vs (D)^4.5 generated essentially linear trends indicative of simple crystal fractionation. Least-squares, mass-balance calculations for major- and trace-element data using observed mineral compositions yield excellent results for crystal fractionation (sum of residuals squared <0.01 for major elements, and <5% for trace elements); magma mixing produced less satisfactory results especially for Cr. Furthermore, trace-element plots of Zr vs Sr, Cr, and A1₂O₃ generate curved trends indicative of crystal fractionation processes. There is no evidence that mixing occurred in the 1955 lavas. Instead, the data are best explained by crystal fractionation involving a reservoir that extends at least 15 km along Kilauea's east rift zone. A dike was intruded into the rift zone from the summit reservoir eight days after the eruption started. Instead of causing magma mixing, the dike probably acted as a hydraulic plunger forcing more of the stored magma to be erupted.     

Contrasted abyssal basalt liquidus trends: evidence for mantle major element heterogeneity

Natural submarine basalt glasses define liquidus trends which may be summarized as curvilinear regression lines in the normative plagioclase-pyroxene-olivine ternary. Individual basalt suites separated in time or space may differ in major element composition; these differences translate into systematic differences in normative plagioclase, leading to efficient discrimination of individual trends in this ternary. Comparison of two contrasted sets of trends to available experimental and petrographic data confirms the similarity of the natural basalt trends to those predicted by 1-atm experiments, in general agreement with earlier studies based on whole-rock data. These contasted liquidus trends are believed to reflect major element heterogeneity and varying degrees of melting of the mantle source. This major element heterogeneity is not simply correlated with heterogeneity in incompatible trace elements, and like incompatible trace element heterogeneity, there is growing evidence that it may vary abruptly in space and time. The existence of these compositionally contrasted basalt suites must be considered in petrogenetic modelling; specifically, they will introduce scatter in most generalized variation diagrams, and will increase the likelihood of “misfits” in fractionation calculations utilizing parent and residual compositions drawn from different suites.     

On the origin of eucrites and diogenites

Eleven eucrites have been analysed for major, minor and some trace (K, Sr, Zr, Y, Ba and Ni) constituents. These data are interpreted in terms of an igneous fractionation model according to which the observed enrichment trends of various elements in eucrite liquids are considered to be indicative of the simultaneous fractionation of plagioclase and pyroxene. Serra de Magéand Moore County are representatives of the cumulates thus formed. The achondrite Binda, a monomict breccia of howarditic composition, is interpreted as a possible precursor to the eucrite liquids. The derivation of a parent eucrite liquid from material of this composition could have occurred by fractionation of orthopyroxene. Diogenites are considered to represent the orthopyroxenites thus formed. The original liquid from which Binda and the eucrites were derived must, in terms of this model, have been more mafic than Binda.     

On the interpretation of vertical gravity gradients produced by magmatic intrusions

A method for the computation and interpretation of gravity and height changes and vertical gravity gradients produced by magmatic intrusions in a layered elastic–gravitational medium is presented. The methodology assumes a planar medium geometry, which consists of welded layers overlying a half-space. The medium is elastic and gravitating. The intrusion is treated as a point source and can be located at any depth inside the medium. The theoretical elastic–gravitational model allows the computation of the so-called geometric and orthometric vertical displacements as well as gravity changes of different types. The corresponding vertical gravity gradients can also be computed. We present several examples of theoretical computations and study different types of these geometric and orthometric gravity gradients and the information we can get from the application of the methodology described. The results presented show that the use of these gradients is a useful tool to obtain information on the dynamics of the injection processes, including the detection of new magma recharge. We show that using the elastic–gravitational deformation model we can explain non-linear gravity–height relationships that appear in volcanic areas. We also present the application of the methodology to Mayon volcano, Philippines, delineating the intrusion of new magma, consistent with the produced eruptions after the observation period.     

Crustal compositions exposed by impact craters in the Tyrrhena Terra region of Mars: Considerations for Noachian environments

Crater ejecta blankets distinguished by differences in thermophysical properties from the target material were investigated in Tyrrhena Terra, Mars. Approximately one third of craters exhibit spectral differences from target material in Mars Global Surveyor Thermal Emission Spectrometer (TES) data. Craters that exhibit these spectral differences from the target material do not strongly correlate with phyllosilicate exposures detected in near infrared data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Shock processes cannot fully explain the observed spectral trends. Rather, the subtle spectral differences observed in TES data are likely due to differences in plagioclase and/or high-silica phase abundance relative to pyroxene abundance, with the crater ejecta exhibiting lower pyroxene abundance than target materials. These mineralogic trends are consistent with several scenarios, none of which can be ruled out from existing observations: 1) vertical variations in primary lithology (considered least likely), 2) subsurface alteration exposed by impact, 3) syn- or post-impact alteration associated with the impact process, such as devitrification of melt glass materials or alteration of highly shocked materials, and 4) light surface alteration that preferentially altered/removed plagioclase and/or high-silica glass relative to pyroxene and subsequent exposure of less-altered materials from the subsurface by impact. Scenario 2 is consistent with phyllosilicate detections; Scenarios 1, 3 and 4 are consistent with CRISM phyllosilicate detections in some impact craters if phyllosilicate mineral abundance is volumetrically small. Results from this work suggest that some signatures of alteration may be escaping detection by near infrared measurements; alteration environments would be best interpreted through a combination of near infrared and thermal infrared data sets, rather than near infrared detections alone.     

Melting relations of a magnesian abyssal tholeiite and the origin of MORBs

Melting relations of a glassy magnesian olivine tholeiite from the FAMOUS area have been studied within the pressure range 1 atm to 15 kbar. From 1 atm to 10 kbar, olivine is the liquidus phase, followed by plagioclase and Ca-rich clinopyroxene. Above 10 kbar, Ca-rich clinopyroxene appears on the liquidus, followed by orthopyroxene and spinel. Near 10 kbar, olivine, orthopyroxene, clinopyroxene, spinel and plagioclase crystallize within 10°C of the liquidus. This indicates that a liquid of this magnesian olivine tholeiite composition could coexist with mantle peridotite at about 10 kbar. This result is in agreement with the geochemistry of Ni; the Ni concentration of the studied sample corresponds to the theoretical concentration in a primary magma [14,15].These data suggest that at least some magnesian mid-oceanic ridge basalts (MORBs) could be primary melts segregated from the mantle at depths near the transition zone between plagioclase lherzolite and spinel lherzolite (about 10 kbar). Based on this model, the residual mantle after extraction of MORBs should be lherzolite, not harzburgite.High-pressure (7–10 kbar) fractionation models involving olivine, plagioclase and clinopyroxene, which have been proposed by several workers (e.g. [36]) to explain the varieties of MORBs, were re-emphasized based on this melting study. The rare occurrence of clinopyroxene as a phenocryst phase in MORBs is explained by precipitation in a magma chamber at high pressure, or by dissolution of clinopyroxene formed earlier at high pressure.     

Thermodynamics of the oxygen isotope fractionation involving plagioclase

The thermodynamic relationship between the oxygen isotope fractionation properties of plagioclase and its composition has been derived by treating plagioclase as a “reciprocal solution” consisting of independent cationic and anionic substitutions, namely (NaAl)⁵⁺?(CaSi)⁵⁺and¹⁸O?¹⁶O. The results show that the logarithm of the oxygen isotope fractionation factor, α, between plagioclase and a coexisting phase varies linearly with the anorthite content of plagioclase. The proportionality constant is given by the oxygen isotope fractionation factor between albite and anorthite, and has been derived from the experimental data of two groups of workers, O'Neil and Taylor [2] and Matsuhisa et al. [3], on the isotopic fractionation between each plagioclase end-member and aqueous solutions. It is found that O'Neil and Taylor's data on isotopic exchange of plagioclase end-members with only 2–3 M chloride solution, rather than with both pure water and the chloride solution, lead essentially to zero intercept of the ln α(Ab-An) vs. 1/T² relation, in accord with Bottinga and Javoy's [10] conclusion about the oxygen isotope fractionation between two anhydrous silicates at T<500°C.     

Geochemistry of the andesite flank lavas of three composite cones within the Atitlán Cauldron,Guatemala

Three composite cones have grown on the southern edge of the previously existing Atitlán Cauldron, along the active volcanic axis of Guatemala. Lavas exposed on the flanks of these cones are generally calc-alkaline andesites, but their chemical compositions vary widely. Atitlán, the largest and most southerly of the three cones, has recently erupted mainly pyroclastic basaltic andesites, while the flanks of San Pedro and Tolimán are mantled by more silicic lava flows. On Tolimán, 74 different lava units have been mapped, forming the basis for sequential sampling. Rocks of all three cones are consistently higher in K₂O, Rb, Ba and REE than other Guatemalan andesites. Atitlán’s rocks and late lavas from Tolimán have high Al₂O₃ content, compared to similar andesites from other nearby cones. All major and trace element data on the rocks are shown to be consistent with crystal fractionation involving phases observed in the rocks. If such models are correct, significant differences in the relative proportions of fractionation phases are necessary to explain the varied compositions, in particular higher Al₂O₃ rocks have fractionated less plagioclase. We speculate that inhibition of plagioclase fractionation could occur in chambers where PH₂O is greater and when repose intervals are shorter. The distribution of volcanic vents throughout Guatemala which show this postulated «inhibition of plagioclase fractionation» is systematic with such vents lying just to the south of the main axis. The andesites of the three cones cannot be simply related to the late-Pleistocene rhyolites which are apparently associated with cauldron formation, because unlike the andesites, the rhyolites have markedly depleted heavy REE abundances. Recent dacitic lavas from vents south of San Pedro volcano and silicic pyroclastic rocks which mantle the slopes the San Pedro may reflect residual post-cauldron rhyolitic volcanism.     

Role of the alkali feldspars fractionation in the evolution of the pantelleria peralkaline silicic rocks

The bearing of fractional crystallization processes, involving mainly the separation of alkali feldspars, on the genesis and evolution of the Pantelleria peralkaline rocks suite has been studied. The separation of phenocrysts from representative vitrophyric rock samples allowed a comparison of the rock bulk compositions with those of their own glasses and alkali feldspars. The peralkaline character of the glassy matrix of a metaluminous trachyte showed the link between alkaline and peralkaline rock suites at Pantelleria, and pointed to a feldspars fractionation as the genetic main acting process (« plagioclase effect » of Bowen) of peralkaline trends. The results of the present study are consistent on the whole with the model proposed byNoble (1968) for the genesis and evolution of peralkaline liquids.     

Conditions and mechanisms of origination of gravitational instability in layered bulk-elastic geomasses

Various geophysical processes which can lead to the origination of gravitational instability of the Rayleigh-Taylor type in layered bulk-elastic geomasses are analyzed. The analysis is based on obtained by the authors general results of theoretical study of two-layer systems of heavy bulk-elastic materials which are arbitrarily stratified over depth and occupy domains of arbitrary shape. Additionally some presented in a number of recent publications erroneous assertions related to considered issues of stability, are criticized.     

Petrology of arc volcanic rocks and their origin by mantle diapirs

Calc-alkalic chemical trends characteristic of arc volcanic rocks mainly result from three mechanisms which act additively: (1) fractional crystallization involving separation of titanomagnetite; (2) selective concentration of plagioclase phenocrysts and selective depletion of titanomagnetite phenocryst compared with the actually fractionated proportion; and (3) mixing of magmas on continuous fractionation trends. The association of calc-alkalic and tholeiitic trends in a single composite volcano may not represent different fractional crystallization processes or different chemistries of primary magmas, but the calc-alkalic chemical trend can be considered as a mixing trend resulting from mixing of various magmas on associated tholeiitic chemical trends. Chemical variations of most arc volcanic rocks, including calc-alkalic ones, can accordingly be essentially accounted for by the low-pressure fractional crystallization of phenocrystic phases from primary basaltic magmas.Crystallization sequences of arc magmas which are strongly dependent on water content in magmas are deduced from the phenocryst assemblages. The crystallization sequence changes laterally across-arc, suggesting increasing water contents in magmas toward the back-arc side, as is also seen for other incompatible elements such as K and Rb. Systematic differences in the characteristic crystallization sequence are also observed among arcs, roughly correlating with the crustal thickness. Water content in magma, like other incompatible elements, tends to increase with increasing crustal thickness. The variation of incompatible elements including water roughly represents that of the degree of partial melting of the upper mantle, which is broadly controlled by the crustal thickness.The variation of water content indicates that arc magmas are not saturated with water during differentiation to late differentiates such as dacite or rhyolite. This strongly constrains the maximum water contents in primary basaltic magma, at most 2.5 wt.%. This value suggests that magma generation beneath arcs is dependent on dry solidus of peridotite. Diapiric uprise of the hot deeper mantle and associated adiabatic decompression would be necessary for mantle peridotite to attain the temperature as high as dry solidus. Diapirs that begin to rise from the subduction zone may stop at or near the crust-mantle boundary because of the surrounding density change, and their degree of partial melting is roughly controlled by their stopped depth assuming their similar temperature. Across-arc variation is also explained by the stopped depth of diapirs, but is not controlled by crustal thickness.     

Evaluation of magmatic processes for the products of the Nevado del Ruiz Volcano, Colombia from geochemical and petrological data

Trace-element concentrations of the eruptive products from the Nevado del Ruiz volcano indicate that at least for the last 1 Ma, the major controlling factor in the evolution of the magma has been a simple fractional crystallization.The Zr/Hf ratios suggest that the source material is mantle-like in origin and whilst subduction-related contamination of the source material has taken place, there is no evidence that assimilation of continental crust has affected the series.No convincing geochemical evidence for magma mixing was found, and data on banded pumices of Pleistocene, Historic and the 1985 eruptions strongly support a crystal fractionation model to explain the compositional variation of their glasses. Therefore, if mixing has taken place it can only be a mixing of layers within a stratified or partially stratified magma chamber.Modeling of fractional crystallization using a stepwise program has been undertaken and least-squares approximations with small residuals are commensurate with analyzed samples. Crystal fractionation models with plagioclase dominating two-pyroxenes and iron oxides give good fits for all calculations. We conclude that simple crystal fractionation is the process most consistent with major- and trace-element variations in the Ruiz series. This closed-system model requires at least 77% crystal fractionation of a basaltic parent to generate the observed compositions of dacites.     

Crystal fractionation of granitic magma during its non-transport processes: A physics-based perspective

Granitic continental crust distinguishes the Earth from other planets in the Solar System. Consequently, for understanding terrestrial continent development, it is of great significance to investigate the formation and evolution of granite.Crystal fractionation is one of principal magma evolution mechanisms. Nevertheless, it is controversial whether crystal fractionation can effectively proceed in felsic magma systems because of the high viscosity and non-Newtonian behavior associated with granitic magmas. In this paper, we focus on the physical processes and evaluate the role of crystal fractionation in the evolution of granitic magmas during non-transport processes, i.e., in magma chambers and after emplacement. Based on physical calculations and analyses, we suggest that general mineral particles can settle only at tiny speed(~10~(-9)–10~(-7) m s~(-1))in a granitic magma body due to high viscosity of the magma; however, the cumulating can be interrupted with convection in magma chambers, and the components of magma chambers will tend to be homogeneous. Magma convection ceases once the magma chamber develops into a mush(crystallinity, F~40–50%). The interstitial melts can be extracted by hindered settling and compaction, accumulating gradually and forming a highly silicic melt layer. The high silica melts can further evolve into high-silica granite or high-silica rhyolite. At various crystallinities, multiple rejuvenation of the mush and the following magma intrusion may generate a granite complex with various components. While one special type of granites, represented by the South China lithium-and fluoride-rich granite, has lower viscosity and solidus relative to general granitic magmas, and may form vertical zonation in mineral-assemblage and composition through crystal fractionation. Similar fabrics in general intrusions that show various components on small lengthscales are not the result of gravitational settling. Rather, the flowage differentiation may play a key role. In general, granitic magma can undergo effective crystal fractionation; high-silica granite and volcanics with highly fractionated characteristics may be the products of crystal fractionation of felsic magmas, and many granitoids may be cumulates.     

Plagioclase lamellae in hypersthene,Tikkoatokhakh Bay,Labrador

Abundant lamellae of plagioclase are present in the (100) planes of hypersthene megacrysts in andesine anorthosite along Tikkoatokhakh Bay, northwest of Nain, Labrador. Spongy intergrowths of plagioclase in hypersthene also occur. Plagioclase lamellae have mean compositions ranging from An₄₃ to An₉₂, with extreme compositions from An₃₉ to An₉₇; the calcic compositions are the more abundant. Such lamellae are always accompanied in the hypersthene by grains or lamellar segments of magnetite, and rarely by lamellae of olivine, augite, magnetite, or ilmenite. Some calcic plagioclase lamellae contain antiperthitic spindles of orthoclase. The host rocks of the hypersthene megacrysts are layered leuconorites and anorthosites with mean plagioclase compositions ranging from An₄₁ to An₅₅. The plagioclase lamellae in hypersthene are characteristically much more calcic than the host-rock plagioclase. There is little doubt that the lamellae exsolved from a pyroxene host, dominantly by a coupled redox reaction which generated magnetite, thereby releasing silica to combine with the Ca-Tschermak and jadeite components of the precursor pyroxene. Rapid growth of megacrysts may account for their aluminous nature.     

Phase equilibria modeling in igneous petrology: use of COMAGMAT model for simulating fractionation of ferro-basaltic magmas and the genesis of high-alumina basalt

A new version of COMAGMAT-3.5 model designed for computer simulations of equilibrium and fractional crystallization of basaltic magmas at low to high pressures is presented. The most important modifications of COMAGMAT include an ability to calculate more accurately the crystallization of magnetite and ilmenite, allowing the user to study numerically the effect of oxygen fugacity on basalt magma fractionation trends. Methodological principles of the use of COMAGMAT were discussed based on its thermodynamical and empirical basis, including specific details of the model calibration. Using COMAGMAT-3.5 a set of phase equilibria calculations (called Geochemical Thermometry) has been conducted for six cumulative rocks from the Marginal Border Series of the Skaergaard intrusion. As a result, initial magma temperature (1165±10°C) and trapped melt composition proposed to be parental magma to the Skaergaard intrusion were determined. Computer simulations of perfect fractionation of this composition as well as another proposed parent produced petrochemical trends opposite to those followed from natural observations. This is interpreted as evidence for an initial Skaergaard magma containing a large amount of olivine and plagioclase crystals (about 40–45%), so that the proposed and calculated parents are related through the melt trapped in the crystal–liquid mixture. This promotes the conclusion that the Skaergaard magma fractionation process was intermediate between equilibrium and fractional crystallization. In this case the classic Wager's trend should be considered an exception rather than a rule for the differentiation of ferro-basaltic magmas. A polybaric version of COMAGMAT has been applied for the genetic interpretation of a volcanic suite from the Klyuchevskoi volcano, Kamchatka, Russia. To identify petrological processes responsible for the observed suite ranging from high-magnesia to high-alumina basalts, we used the model to simulate the Klyuchevskoi suite assuming isobaric crystallization of a parental HMB magma at a variety of pressures and a separate set of simulations assuming fractionation during continuous magma ascent from a depth of 60 km. These results indicate that the Klyuchevskoi trend can be produced by 40% fractionation of Ol–Aug–Sp±Opx assemblages during ascent of the parental HMB magma over the pressure range 19–7 kbar with the rate of decompression being 0.33 kbar/% crystallized (at 1350–1110°C), with 2 wt.% of H₂O in the initial melt and 3 wt.% of H₂O in the resultant high-Al basalt.     

Mineralogy and petrology of sample 67075 and the origin of lunar anorthosites

Plagioclase in cataclastic anorthosite 67075 occurs as angular matrix grains and as recrystallized clasts of micro-anorthosite. Olivines are Fe-rich and fall into two compositional groupings. Large grains of pyroxene show exceptionally well-developed exsolution lamellae analogous to those observed in pyroxenes from layered complexes. The low-Ca component in both pigeonites and augites shows varying degrees of inversion to orthopyroxene. The lattices of host and lamellae may deviate slightly (up to 2°) from the ideal orientation. Very slow cooling from magmatic temperatures is required to produce the coarse exsolution textures and inversion features. Augite macrocrystals are distinctly subcalcic indicating crystallization at temperatures around1100 ± 50°C while host-lamellae pairs and small grains in lithic clasts and matrix indicate reequilibration on a micron scale to temperatures less than 800°C. Pyroxene compositions tend to cluster into two groups both of which are among the most Fe-rich reported for highland pyroxenes. Ti and Al contents of pyroxenes are very low and Ti, Cr, and Mn follow well-established magmatic differentiation trends. The high Cr content may reflect low?O₂ conditions and/or early crystallization of olivine and plagioclase.The⁸⁷Sr/⁸⁶Sr ratios in lunar anorthosites are the lowest reported for any lunar rock. It is likely that anorthosites formed as cumulates during the major differentiation episode which occurred prior to～4.3AE. Recrystallization features are common and³⁹Ar/⁴⁰Ar ages cluster around 4.0 AE. This may be the result of the intense bombardment prior to 4.0 AE which caused repeated cycles of in-situ fracturing and granulation followed by recrystallization. The low siderophile element content and the inferred slow cooling indicate a plutonic source region (10km) not frequently plumbed by impact events. The Fe-rich silicates indicate crystallization from a melt at an advanced stage of fractionation. However, the low REE abundances are not consistent with late-stage crystallization. Plagioclase apparently crystallized relatively early and was concentrated by flotation and/or convection currents while the mafic minerals crystallized from a fractionated trapped liquid. The chemical, isotopic, and mineralogical data place stringent constraints on the nature of genetically related rocks and the relationship of anorthosites to other members of the ANT suite does not appear to be one ofsimple fractionation. The data presented in this paper are consistent with the Taylor-Jake?model of lunar evolution.