Seasonal variations in the sediment biogenic properties of a tropical mangrove environment,southwest coast of India

Temporal and spatial changes in the sediment properties of a mangrove ecosystem (Cochin, southwest coast India) are presented. The region was freshwater dominated during monsoon (June–September) and seawater dominated during other two seasons. The system remained eutrophic due to the high inputs of organic matter (OM) during most part of the year. The organic-rich sediments accumulated high amount of carbohydrates (22% of OM) and proteins (11% of OM) during non-monsoon months as compared to coastal environments. Principal component analysis showed that the biochemical properties are uniformly influenced by seasonal and spatial variations. Higher concentrations of sediment protein over carbohydrate indicate an efficient mineralization leading to the non-availability of aged OM in the system. The dominance of these labile components is generally indicative of the eutrophic condition of the system.     

Seasonal variations of Zn, Cu, As and Mo in arsenic-rich stream at the Mokrsko gold deposit, Czech Republic

Monthly sampling of slightly alkaline arsenic-rich stream in the Mokrsko gold deposit revealed seasonal variations in dissolved Zn, Cu, As and Mo. Concentrations of trace metal cations (Zn, Cu) increased as much as 330 and 178%, respectively, from minimum mean values at autumn to maximum mean values at spring. In contrast, concentrations of trace element oxyanions (As, Mo) revealed opposite seasonal pattern with increase to 189% (As) and 123% (Mo) during summer–autumn, indicating that in-stream biogeochemical process(es) played the main role in controlling the seasonal variations of these trace elements. The trace elements were mainly scavenged by low crystalline Mn oxyhydroxide and Fe oxyhydroxide (ferrihydrite). Results are consistent with sorption and coprecipitation processes controlling seasonal variations of dissolved Zn and Cu, while As and Mo dynamics appear linked to Mn redox reactions. The sorption processes and Mn redox processes are attributed to the changes of pH and oxic/anoxic conditions on the surface of oxyhydroxides, respectively, which are themselves controlled by the balance between photosynthesis and respiration. Under the geochemical conditions of the stream, inferred Mn redox reactions can only be explained by microbial activity.     

Groundwater components in the alluvial aquifer of the alpine Rhone River valley, Bois de Finges area, Wallis Canton, Switzerland

Source, type, and quantity of various components of groundwater, as well as their spatial and temporal variations were determined by different hydrochemical methods in the alluvial aquifer of the upper Rhone River valley, Bois de Finges, Wallis Canton, Switzerland. The methods used are hydrochemical modeling, stable-isotope analysis, and chemical analysis of surface water and groundwater. Sampling during high- and low-water periods determined the spatial distribution of the water chemistry, whereas monthly sampling over three years provided a basis for understanding seasonal variability. The physico-chemical parameters of the groundwater have spatial and seasonal variations. The groundwater chemical composition of the Rhone alluvial aquifer indicates a mixing of weakly mineralized Rhone River water and SO₄-rich water entering from the south side of the valley. Temporal changes in groundwater chemistry and in groundwater levels reflect the seasonal variations of the different contributors to groundwater recharge. The Rhone River recharges the alluvial aquifer only during the summer high-water period. Electronic Publication     

Seasonal cycle and mass balance of cadmium in an estuary with an agricultural catchment: The Morlaix River estuary (Brittany,France)

Cadmium (Cd) variations were investigated over an annual cycle (12 surveys between February 1998–January 1999) in the Morlaix estuary (Brittany, France) in both the water column and the benthic compartment in relation to hydrological conditions. The drainage basin of the Morlaix River estuary is predominantly agricultural in character. Dissolved Cd concentrations in the water column varied from 0.04 to 0.48 nM. Particulate Cd concentrations ranged from 1 to 64 nmol g⁻¹. These concentrations reach levels commonly observed in estuaries affected by heavy industrial activities. Extensive agricultural activities in the drainage basin may be responsible for Cd levels above pristine conditions. Metal concentrations varied significantly over the seasonal cycle and the dissolved fraction exhibited high values in summer months. Particulate concentrations were always lowest during this season. In the benthic compartment, Cd concentrations in surface sediment varied from 0.4 to 5.0 nmol g⁻¹ and from 0.2 to 5.0 nM in porewaters. Concentrations in sediment were slightly affected by Cd contamination and temporal changes were important over the seasonal cycle. The variations seem to be controlled by the succession of sedimentation and erosion processes, which are tightly linked to seasonal changes in river discharge. A box model was constructed based on known Cd sources and sinks in the estuary. Cd is chiefly brought into the estuary by the Morlaix River and accumulates within the estuary. The accumulation within the estuary represents from 6.3 to 7.2 kg yr⁻¹.     

Assessment of the factors controlling groundwater quality in a coastal aquifer adjacent to the Bay of Bengal,India

A study has been conducted in the heavily populated coastal areas of the Puri district (Odisha, India) with the aim to: (1) identify the factors that influence the major ion composition and concentrations of trace elements in groundwater; (2) determine the spatial distribution of the water-quality parameters and how they vary on a seasonal basis. To do this, groundwater samples were collected from 60 shallow tube wells located along the Puri coast during the pre-monsoon and post-monsoon seasons. Based on their TDS content, 52% of the collected groundwater samples were identified as being brackish-to-saline and unsuitable for drinking purposes in both the pre- and post-monsoon seasons. Significant concentrations of trace elements including Ba, Br, F, Fe, Mn, and Sr were detected in most of the samples. Iron concentrations were found to be higher than the WHO drinking water guideline value (0.3 mg/l) in 92% of the samples irrespective of seasons. Elevated Mn concentrations were observed in 37% and 40% of samples during the pre-monsoon and post-monsoon seasons, respectively. In addition, fluoride concentrations in excess of the WHO limit (1.5 mg/l) were found in 15% of samples during the pre-monsoon and 23% of samples during the post-monsoon season. The concentrations of major and trace elements show wide spatial and minor temporal variations. Large spatial and limited temporal variations in Cl and Na concentrations along with considerable Br and Sr concentrations in groundwater suggest that saltwater intrusion is the dominant process controlling groundwater quality in the study area, although other processes including ion exchange, the precipitation and dissolution of minerals, microbial activity, and the weathering of aquifer material also play roles to some extent in determining the spatial and seasonal distribution of the major and trace elements in coastal groundwater. Grouping of various water-quality parameters related to these processes by principal component analysis and their linking to one cluster in the hierarchical cluster analysis further supports the view that these processes control the groundwater chemistry in the coastal aquifer.     

Temporal variations in arsenic concentration in the groundwater of Murshidabad District,West Bengal,India

Systematic investigations on seasonal variations in arsenic (As) concentrations in groundwater in both space and time are scarce for most parts of West Bengal (India). Hence, this study has been undertaken to investigate the extent of As pollution and its temporal variability in parts of Murshidabad district (West Bengal, India). Water samples from 35 wells were collected during pre-monsoon, monsoon and post-monsoon seasons and analyzed for various elements. Based on the Indian permissible limit for As (50 μg/L) in the drinking water, water samples were classified into contaminated and uncontaminated category. 18 wells were reported as uncontaminated (on average 12 μg/L As) and 12 wells were found contaminated (129 μg/L As) throughout the year, while 5 wells could be classified as either contaminated or uncontaminated depending on when they were sampled. Although the number of wells that alternate between the contaminated and uncontaminated classification is relatively small (14%), distinct seasonal variation in As concentrations occur in all wells. This suggests that investigations conducted within the study area for the purpose of assessing the health risk posed by As in groundwater should not rely on a single round of water samples. In comparison to other areas, As is mainly released to the groundwater due to reductive dissolution of Fe-oxyhydroxides, a process, which is probably enhanced by anthropogenic input of organic carbon. The seasonal variation in As concentrations appear to be caused mainly by dilution effects during monsoon and post-monsoon. The relatively high concentrations of Mn (mean 0.9 mg/L), well above the WHO limit (0.4 mg/L), also cause great concern and necessitate further investigations.     

Changes in the molecular hydrogen concentration in an underground mine (Lovozero rare-metal deposit,Kola Peninsula)

Long-term monitoring yielded significant variations in the hydrogen volume concentration in an underground mine at the developed Lovozero rare-metal deposit of the nepheline–syenite massif in the Kola Peninsula. The deposit is characterized by emission of natural combustible gases. Basic structural elements of the time series obtained include relatively stable and long ranges of low background concentrations, low- and medium-amplitude rises of various duration, and short-term, commonly high-amplitude peaks. The range structure is characterized by a general decreasing trend, a low intensity random noise component, and seasonal and off-seasonal periodic and other cyclical components. Periodic circadian and semidiurnal harmonics are the most pronounced.     

The hydrogeochemistry of the Lake Waco drainage basin,Texas

The origin of surface water chemistry in highly impacted drainage basins must be investigated on a drainage-basin scale if the causes of the pollution are to be elucidated. This study characterizes and deciphers the surface water chemistry of a nutrient polluted river system in central Texas. Four tributaries of the Lake Waco reservoir were chemically characterized temporally and spatially in order to gain a complete understanding of the nature and origin of dissolved solids being transported into the lake. Temporal chemical variations measured at the base of each of the drainage basins are repetitive and seasonal. The most periodic and well-defined variation is exhibited by nitrate concentrations although many of the other solutes show seasonal changes as well. These temporal chemical changes are controlled by seasonal precipitation. During rainy seasons, the shallow aquifer is recharged resulting in stream discharge that is high in nitrate, calcium, and bicarbonate. When the shallow flow system is depleted in the summer, stream waters are dominated by deeper groundwater and become rich in sodium. Spatial variations in the chemistry of South Bosque surface waters were characterized using the snapshot technique. The spatial distribution of nitrate in surface waters is controlled by fertilizer application to row crops and the location of a munitions factory. The concentrations of naturally derived solutes such as Ca⁺, Na⁺, Cl^–, and SO₄^–2are controlled by underlying lithologies.     

Seasonal deposition of Holocene banded sediments in the Severn Estuary Levels (southwest Britain): palynological and sedimentological evidence

Banded sediments outcrop widely in the intertidal zone of the Severn Estuary and have been suggested, on the basis of textural analysis, to have formed in response to seasonal variations in sea temperature and windiness (Holocene, 14 (2004) 536). Here palynological and sedimentological analyses of banded sediments of mid-Holocene date from Gold Cliff, on the Welsh side of the Severn Estuary, are combined to test and further develop the hypothesis of seasonal deposition. Pollen percentage and concentration data are presented from a short sequence of bands to establish whether textural variations in the bands coincide with variations in pollen content reflecting seasonal flowering patterns. It is shown that fine-grained band parts contain higher total pollen concentrations, and a higher proportion of pollen from late spring- to summer-flowering plants, than coarse-grained band parts. Pollen in the coarser deposits appears primarily to reflect deposition from the buffering ‘reservoir’ of suspended pollen in the estuarine water-body and from rivers, when there is little pollen in the air in winter, while the finer sediments contain pollen deposited from the atmosphere during the flowering season, superimposed on these ‘background’ sources. The potential of such deposits for refining chronologies and identifying seasonality of coastal processes is noted, and the results of charcoal particle analysis of the bands presented as an example of how they have the potential to shed light on seasonal and annual patterns of human activity.     

Measuring and modeling atmospheric particles and particle bound mercury Hg(p) at five characteristic-sampling sites

The main purpose of this study was to monitor ambient air particles and particulate-bound mercury Hg(p) in total suspended particulates (TSP) concentration, dry deposition at five characteristic-sampling sites. In addition, the calculated/measured dry deposition flux ratios of ambient air particles and particulate-bound mercury Hg(p) using three dry deposition models during the years of 2009–2010 were also studied. The results showed that the order of seasonal variations for mean particulate-bound mercury Hg(p) concentrations in TSP at Bei-shi (suburban/coastal), Chang-hua (downtown) and He-mei (residential) were all shown as spring > fall, winter > summer, respectively. However, the order of seasonal variations mean particulate-bound mercury Hg(p) concentrations in TSP that occurred at Gao-mei (wetland) were shown as spring > fall > winter > summer, respectively. Finally, the results of this study also indicated that using the Noll and Fang model exhibited batten prediction results for ambient air particles and particulate-bound mercury Hg(p) dry deposition when compared with the other depositions models at any of the characteristic-sampling sites for this study.     

The influence of extraction rate on the reduced sulphur content of Aix-les-Bains’ thermal spring waters: Consequences for resource-quality monitoring

Sulphurous thermal springs account for a few percent of all thermal springs. As each degree of oxidation of elemental S corresponds to a different S species, sulphurous spring waters may contain a variety of S species. Total S content is one of the parameters measured when analysis is carried out for issuing a spa’s operating licence. Under French law these parameters must be stable over time. The two spas in Aix-les-Bains are fed by a number of natural springs and boreholes, whose waters have total reduced S concentrations of between 30 and 800 mg L⁻¹. To ensure compliance with the requirements of the spas’ operating licences, particularly in terms of total reduced S content, official analysis of the waters is carried out every month at random dates and times. Monthly analyses have revealed seasonal variations in the S content of some of Aix-les-Bains’ springs; therefore, more frequent monitoring was carried out in order to investigate the extent and causes of these fluctuations. As well as seasonal variations, this monitoring has revealed daily and hourly fluctuations that appear to be related to extraction rates. For some of the springs and boreholes, S concentrations were correlated with extraction rates; for others, an increase in extraction rate led to a reduction in total S content. Concentrations of sulphide ions (one of the species included in the total sulphur analyses) were monitored at the same time as the total S content. Variations in sulphide ion concentrations and in sulphide concentration/total S ratios did not appear to be linked to variations in flow rate. These tests show that random monthly testing is not suitable for monitoring the stability of S contents, as this parameter can only be considered stable in terms of its yearly mean value.     

Transport of dissolved organic nitrogen in Mississippi River plume and Texas-Louisiana continental shelf near-surface waters

Dissolved organic nitrogen (DON) in near-surface (<20 m depth) waters of the Texas-Louisiana continental shelf is the predominant form of total dissolved nitrogen that is advected by the Mississippi-Atchafalaya River plume. Relatively high DON concentrations associated with low-salinity (<33 psu) waters throughout the year can be traced within the plume along the Texas-Louisiana inner shelf. DON concentrations throughout the shelf were significantly higher near the Mississippi-Atchafalaya outflow region relative to downstream inner Gulf shelf locations. Significant intercruise variations were also evident, with the highest concentrations during May 1992 and lower values in October 1992. At a fixed location off the Mississippi River outflow region DON concentration covaried inversely with salinity on time scales of hours to months, confirming that source water is a determining factor for variations of bulk DON concentrations in the region. Similar variations in upper water DON concentrations at different locations and seasons occurred in both plume and nonplume waters, which resembled the seasonal concentration changes of riverine nitrogen, and show that this pool is useful in tracing the influence of riverine-derived nitrogen on the overall nitrogen balance of the NW Gulf of Mexico’s continental shelf. Plume and nonplume DON concentrations deviated from mixing lines between riverine and oceanic endmembers, suggesting that plume waters may be a sink and nonplume waters may be a source of a labile fraction of DON in the region.     

黑河流域不同下垫面水热通量特征分析

"黑河流域遥感—地面观测同步试验"在黑河上中游地区不同下垫面上建立了多个自动气象站和涡动相关仪及大孔径闪烁仪通量观测站。选取草地、森林及农田3种下垫面的观测资料,分析了水、热和CO2通量特征。结果表明:黑河流域内不同下垫面能量收支各分量(净辐射、感热、潜热和土壤热通量等)有明显的日变化特征;各通量观测站观测结果如季节变化趋势等差异明显,反映了不同下垫面地气交换特征的不同。黑河上游阿柔冻融观测站和中游临泽草地站两套大孔径闪烁仪(LAS)的观测与涡动相关仪有关结果有较好的对应关系。结合浅层土壤热储存量的计算等分析了地表能量平衡的闭合情况。LAS观测的感热通量一般大于涡动相关仪的测量值;两者的差异主要由下垫面的非均一性、通量贡献源区大小不同以及影响大气湍流通量观测的涡旋尺度不同等原因引起。     

Temporal analysis of air pollution and its relationship with meteorological parameters in Bahrain, 2006–2012

The objective of this paper is to analyze temporal and seasonal trends of air pollution in Bahrain between 2006 and 2012 by utilizing datasets from five air quality monitoring stations. The non-parametric and robust Theil-Sen approach is employed to study quantitatively temporal variations of particulate matter (PM₁₀ and PM_2.5), nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and ozone (O₃). The calculated annual concentrations for PM₁₀ and PM_2.5 in Bahrain were substantially higher than recommended World Health Organization (WHO) guideline standards. Results showed increasing trends for PM₁₀, PM_2.5, and SO₂ whereas O₃ and its precursor NO₂ showed decreasing behavior. The general increase in air pollution trends is in agreement with prediction of air pollution models for Middle East region due to economic growth, industrialization, and urbanization. The significances of long-term trends were examined. Additional to actual (unadjusted) trends, meteorological adjusted (deseasonalized) trends and seasonal trends were quantified. The box-plot analysis visually illustrated monthly variations of key air pollutants. It showed that only PM₁₀ and PM_2.5 exhibited seasonal pattern, and their concentrations increased during summer and decreased during winter. The effects of ambient air temperature, relative humidity, wind speed, and rainfall on particulate matter (PM) concentrations were further investigated. The Spearman correlation coefficient results demonstrated significant negative correlation between relative humidity and PM concentrations (??0.595 for PM₁₀ and ??0.526 for PM_2.5) while significant positive correlation was observed between temperature and PM concentrations (0.420 for PM₁₀ and 0.482 for PM_2.5).     

Hydrological and biogeochemical dynamics of the minor and trace elements in the St. Lawrence River

Surface water samples from the St. Lawrence River were collected in order to study the processes controlling minor and trace elements concentrations (Al, Fe, Mn, Cd, Co, Cu, Ni and Zn), and to construct mass balances allowing estimates of the relative importance of their natural and anthropogenic sources. The two major water inputs, the upper St. Lawrence River, which drains waters originating from the Lake Ontario, and the Ottawa River were collected fortnightly over 18 months. In addition, other tributaries were sampled during the spring floods. The output was monitored near Quebec City at the river mouth weekly between 1995 and 1999. Dissolved metal concentrations in the upper St. Lawrence River carbonated waters were lower than in the acidic waters of the tributaries draining the crystalline rocks of the Canadian shield and the forest cover. Biogeochemical and hydrodynamic processes occurring in Lake Ontario drive the seasonal variations observed in the upper St. Lawrence River. Biogeochemical processes relate to biological uptake, regeneration of organic matter (for Cd and Zn) and oxyhydroxide formation (for Mn and Fe), while hydrodynamic processes mainly concern the seasonal change in vertical stratification (for Cd, Mn, and Zn). In the Ottawa River, the main tributary, oxyhydroxide formation in summer governs seasonal patterns of Al, Fe, Mn, Cd, Co and Zn. The downstream section of the St. Lawrence River is a transit zone in which seasonal variations are mainly driven by the mixing of the different water masses and the large input of suspended particulate matter from erosion. The budget of all dissolved elements, except Fe and Zn, was balanced, as the budget of particulate elements (except Cd and Zn). The main sources of metals to the St. Lawrence River are erosion and inputs from tributaries and Lake Ontario. Direct anthropogenic discharges into the river accounted for less than 5% of the load, except for Cd (10%) and Zn (21%). The fluxes in transfer of dissolved Cd, Co, Cu and Zn species from the river to the lower St. Lawrence estuary were equal to corresponding fluxes calculated for Quebec City since the distributions of dissolved concentrations of these metals versus salinity were conservative. For Fe, the curvature of the dilution line obtained suggests that dissolved species were removed during early mixing.     

Seasonal dripwater Mg/Ca and Sr/Ca variations driven by cave ventilation: Implications for and modeling of speleothem paleoclimate records

A 4-year study in a central Texas cave quantifies multiple mechanisms that control dripwater composition and how these mechanisms vary at different drip sites. We monitored cave-air compositions, in situ calcite growth, dripwater composition and drip rate every 4-6 weeks. Three groups of drip sites are delineated (Groups 1-3) based on geochemical variations in dripwater composition. Quantitative modeling of mineral-solution reactions within the host carbonate rock and cave environments is used to identify mechanisms that can account for variations in dripwater compositions. The covariation of Mg/Ca (and Sr/Ca) and Sr isotopes is key in delineating whether Mg/Ca and Sr/Ca variations are dictated by water-rock interaction (i.e., calcite or dolomite recrystallization) or prior calcite precipitation (PCP). Group 1 dripwater compositions reflects a narrow range of the extent of water-rock interaction followed by varying amounts of prior calcite precipitation (PCP). Group 2 dripwater compositions are controlled by varying amounts of water-rock interaction with little to no PCP influence. Group 3 dripwater compositions are dictated by variable extents of both water-rock interaction and PCP. Group 1 drip sites show seasonal variations in dripwater Mg/Ca and Sr/Ca, whereas the other drip sites do not. In contrast to the findings of most previous dripwater Mg/Ca-Sr/Ca studies, these seasonal variations (at Group 1 drip sites) are independent of changes in water flux (i.e., rainfall and/or drip rate), and instead significantly correlate with changes in cave-air CO₂ concentrations. These results are consistent with lower cave-air CO₂, related to cool season ventilation of the cave atmosphere, enhancing calcite precipitation and leading to dripwater geochemical evolution via PCP. Group 1 dripwater Mg/Ca and Sr/Ca seasonality and evidence for PCP as a mechanism that can account for that seasonality, have two implications for many other regions where seasonal ventilation of caves is likely: (1) speleothem trace-element records may provide seasonal signals, and (2) such records may be biased toward recording climate conditions during the season when calcite is depositing. Additionally, we use our results to construct a forward model that illustrates the types of speleothem Mg/Ca and Sr/Ca variations that would result from varying controls on dripwater compositions. The model provides a basis for interpreting paleo-dripwater controls from high frequency Mg/Ca and Sr/Ca variations for speleothems from caves at which long term monitoring studies are not feasible.     

Spatial and temporal variations of suspended solid concentrations from 2000 to 2013 in Poyang Lake,China

Concentrations of suspended solids in lakes can affect the latter’s primary productivity and reflect changes in sediment deposition. Determining the temporal and spatial distribution of suspended solid concentrations has important significance in lake water environmental management; this is particularly urgent for Poyang Lake, the largest freshwater lake in China. In this study, suspended solid concentration inversion models for Poyang Lake were created using a semi-empirical method with regression analysis between continuously measured suspended solid concentration data and multi-band moderate-resolution imaging spectroradiometer images for spring, summer, autumn, and winter from 2009 to 2012. The coefficient of determination (R²) is from 0.6 to 0.9 and the average relative error for the accuracy verification was between 10 and 30%. The seasonal distributions of suspended solid concentrations in Poyang Lake from 2000 to 2013 were then obtained using optimal reversal models. The results showed that the seasonal variation in suspended solid concentrations had a “W” shape in which high spring and autumn and low summer and winter values. The suspended solid concentrations increased annually from 2000 to 2013 and were mainly distributed in the northern and central portions of the lake, with lower values along the shorelines. Further analysis indicated that the large difference in water level between the wet and dry seasons is an important factor in explaining these seasonal variations. Moreover, the suspended solid concentrations were poorly correlated with water temperature and chlorophyll-a concentration but more highly correlated with the deferred chlorophyll-a concentration.     

天山乌鲁木齐河源冰川积雪化学特征及其季节变化

高海拔雪冰可以记录源自于地球表面的各种化学物质信号.从2002年9月到2005年10月3年的时段内,在天山乌鲁木齐河源1号冰川积累区采集积雪样品,运用比较法、相关分析法等方法,对其中主要离子、不溶粉尘、痕量金属和δ18O等特征及其季节变化进行了分析研究.分析结果表明,积雪离子浓度大小顺序依次为:Ca2+＞SO₄2-＞NO₃-＞Cl-＞NH₄+＞Mg2+＞Na+＞K+,其中Ca2+是主要的阳离子,SO₄2-是主要的阴离子.离子相关性分析表明,除NO₃-之外,其他离子浓度之间均存在较好的正相关.积雪中δ18O值随时间变化表现出与大气温度变化相反的规律.积雪中不溶粉尘和主要化学离子浓度具有明显的季节变化特征,春季期间浓度明显高于其他季节,表明沙尘活动对冰川区化学物质输入有较大贡献;此外,痕量金属(Cd、Pb、Zn、Al、Fe)季节变化特征表明,人类活动的污染物对于研究区雪冰中的化学特征亦有重要影响.      

Dissolved silica in the Garonne River waters: changes in the weathering dynamics

 The major ion chemistry of the Garonne River is indicative of seasonal variations in the weathering dynamics of the drainage basin. Using the geochemical model MEGA for calculation of the contribution of atmospheric CO₂ to the total bicarbonate fluxes exported by the Garonne River allows estimations of the concentrations of the major dissolved elements that originate from silicate- and carbonate-rock weathering. The molecular ratio SiO₂/Al₂O₃ was calculated for the 1989–1992 period to identify the main type of weathering in the Garonne River, and montmorillonite was shown to be the major mineral occurring in the weathering products. The seasonal variations of the SiO₂/Al₂O₃ ratio also showed that removal of silica was accelerated during humid periods. Revision received: 14 May 1999 · Accepted: 12 January 2000     

Temporal variability of trace metals in new jersey pinelands streams: relationships to discharge and pH

Dissolved and particulate trace metal (Al, Cd, Cu, Pb, and Zn) concentrations were determined over a 21 month time period at four streamwater sites in the Pinelands (New Jersey, USA), a coastal plain region characterized by low-pH waters and highly weathered soils. Al and Zn were also determined at two sites over a 5 day period following a major precipitation event. In the Batsto River (pH 4.4–6.3), a representative Pinelands stream draining a largely forested watershed moderately impacted by agriculture, discharge-weighted mean concentrations of dissolved metals were (in nM): Al = 4610; Cd = 0.39; Cu = 4.6; Pb = 1.0; and Zn = 149. Dissolved Cd, Cu, and Zn in the undeveloped Bass River (pH 4.1–4.8) are in a similar range, but Pb concentration is 2–3 times greater. Dissolved metals show highly significant positive correlations to discharge, and weaker inverse relationships to pH over both the long- and short-term time series. Overall, seasonal and short-term variability in dissolved metal concentrations is most consistent with control by hydrologic flow path changes during high discharge, when shallow groundwaters mobilize anthropogenic metals stored in near-surface soil horizons and bypass potential metal removal processes in bordering wetlands. The data also suggest that in-stream metal removal driven by summertime biological productivity may further reduce low-discharge metal concentrations, as a secondary effect. For these metals, the particulate fraction is generally minor, and variations in solution/particle partitioning are unimportant to spatial/temporal variations dissolved concentrations, except for Pb. Estimates of atmospheric input can account for riverine fluxes of these metals, and suggest that Zn retention is minimal in this system, while Pb, Cu and Cd are more strongly retained. The positive relationship between discharge and metals concentration, and the unusually high concentrations in Pinelands streams compared to other world rivers, suggest that riverine effects on metals distributions in the estuary and nearby coastal ocean will be measurable and strongly seasonal.