Diffuse interstellar bands — an observational review (Review)

Es wird eine Übersicht über Beobachtungsergebnisse hinsichtlich der unidentifizierten diffusen interstellaren Banden (DIB) gegeben. Mit hohem S/A-Verhältnis aufgenommene Spektren erlaubten die Einteilung der DIB in mindestens drei Familien. Ferner konnten Profile der in einer einzelnen interstellaren Wolke entstehenden Linien abgeleitet werden. Die bei weit entfernten Sternen auftretenden DIB lassen eindeutige Doppler-Strukturen erkennen. Die DIB könnten in Wolken geringer Opazität entstehen, wobei der (die) Absorber in dem Fall widerstandsfähig gegen UV-Strahlung sein müßte(n). Der (die) Absorber scheint (scheinen) nicht mit dem die visuelle Extinktion verursachenden Staub identisch zu sein. Beziehungen zwischen den DIB und anderen Größen, die die interstellare Extinktion charakterisieren, werden zusammengestellt.     

Diffuse interstellar bands in low E (B – V) objects

We analyse spectra of slightly reddened, early-type stars in which the major diffuse interstellar bands at 5870 and 5797 Å are either strong or weak in relation to E(B – V) . It is demonstrated that among the low E(B – V) objects one can find stars obscured by 'sigma' as well as 'zeta' type clouds. The profiles of the diffuse bands seem not to be dependent on the total opacities of the interstellar clouds. We also discuss the physical conditions leading to the formation of the diffuse band carriers in low-opacity interstellar clouds; the carriers are apparently formed in media in which one can observe complex velocity fields.     

The alkali metal atmospheres on the Moon and Mercury: Explaining the stable exospheres by heavy Rydberg Matter clusters

Despite recent progress in the modeling of alkali atmospheres like those around the Moon and Mercury, many problems still exist. It is proposed that Rydberg Matter (RM) clusters containing Na and K atoms are the main part of the alkali atmospheres of the Moon and Mercury, forming large clouds. RM clusters are studied in the laboratory with laser fragmentation and laser spectroscopy methods. Due to the very large collision cross sections of Rydberg atoms and RM clusters, the atmospheres are not collision free, as normally assumed based on the low densities of free alkali atoms. The non-escaping radial density variation for the Na atoms, observed, e.g., on the Moon, and the Maxwellian velocity distributions observed on Mercury are caused by a true atmosphere with collisional equilibration; this process is not possible in an exosphere. Fast alkali atoms are released from the RM clusters already at large heights by solar photons and charged particle impact. The kinetic temperatures derived for the atmospheres agree with the quantized energy release. The cluster model predicts that the rate of loss from the surface is much smaller than for a purely atomic model, since the transient storage is in the RM cluster form in the atmosphere and not at the surface. The conductance of the atmosphere is of the order of 100 S due to the facile collisional ionization of the RM clusters. The apparent depletion of K in the atmosphere of Mercury is explained.     

Rydberg Matter as the dust atmosphere in comets: Spectroscopic and polarization signatures

The long-lived excited state of matter called Rydberg Matter (RM) may explain several spectroscopic features in space, like the diffuse interstellar bands (DIBs) and the unidentified infrared bands (UIR, UIB). RM is here used to interpret some previously unexplained or inconsistent features in comets: (1) line absorption in the emission from the nucleus, (2) IR band emission from the coma, (3) selective and variable molecular line emission from the coma, (4) extended sources of molecules in the coma, (5) degree of linear polarization of light scattered from the coma. (1) The unexplained IR absorptions observed in the flyby of the nucleus of the Comet Borrelly agree well with RM emission bands observed by stimulated emission in the laboratory. It is proposed that RM is the so-called ultrared matter or at least formed from it. (2) The IR bands previously attributed to silicate particles are shown to be better described by RM theory. Transitions in atoms in RM are shown to dominate. (3) The inverted RM medium will optically amplify light from molecular transitions in the comet comae, in agreement with observations that many of the molecular IR emission lines lie within the emission bands from RM, or much too close to Rydberg transitions to be accidental. (4) The unexplained extended sources observed, e.g., for CO are proposed to be due to release of molecules previously incorporated in the RM clusters at low temperature. Such clusters may be the very small particles observed by space probes. (5) Finally, the largely unexplained measurements of the degree of linear polarization of scattered sunlight from comets are explained as due to scattering by the planar RM clusters. Quantitative agreement is demonstrated.     

The chemistry of interstellar CH: The contribution of Bates and Spitzer (1951)

We review the present understanding of interstellar CH⁺. We show that the essential chemistry was correctly identified by Bates and Spitzer in 1951. More recent work has been concerned with defining appropriate venues within which this chemistry can function efficiently. This process had led to a much fuller understanding of the nature of the interstellar medium.     

Σ(D)-dependence of SNR in a cloudy interstellar medium and regularZ-effect

Critical analysis of the earlier obtained Σ(D)-dependences in the light of new observational data on the interaction of SNR expanding envelopes with inhomogeneities of interstellar medium is carried out. It is shown that more correct consideration of the factors which are the basis ofZ-effect introduction testifies to the dominating role of interstellar medium cloudiness, which completely suppresses the influence of the regular component of the medium. On the basis of most reliable calibrators and on the last observations, theoretical notions of evolution, new Σ(D)-dependence for shell type SNR in a cloudy interstellar medium is obtained. On the basis of this dependence diametersD, distances from the Sund and height over the galactic planeZ for ～100 shell type SNR at two frequencies, 408 MHz and 1 GHz are calculated.     

Formation of cyanoallene （buta-2, 3-dienenitrile） in theinterstellar medium： a quantum chemical and spectroscopicstudy

The interstellar medium, filling the vast space between stars, is a rich reser-voir of molecular material ranging from simple diatomic molecules to more com-plex, astrobiologically important molecules such as vinylcyanide, methylcyanodiac-cetylene, cyanoaUene, etc. Interstellar molecular cyanoallene is one of the most stableisomers of methylcynoacetylene. An attempt has been made to explore the possibilityof forming cyanoallene in interstellar space by radical-radical and radical-moleculeinteraction schemes in the gaseous phase. The formation of cyanoallene starting fromsome simple, neutral interstellar molecules and radicals has been studied using densityfunctional theory. The reaction energies and structures of the reactants and productsshow that the formation of cyanoallene is possible in the gaseous phase. Both of theconsidered reaction paths are totally exothermic and barrierless, thus giving rise to ahigh probability of occurrence. Rate constants for each step in the formation processof cyanoallene in both the reaction paths are estimated. A full vibrational analysishas been attempted for cyanoallene in the harmonic and anharmonic approximations.Anharmonic spectroscopic parameters such as rotational constants, rotation-vibrationcoupling constants and centrifugal distortion constants have been calculated.     

Cross sections from 5 to 35 MeV for the reactions natMg(3He,x)26Al, 27Al(3He,x)26Al,natCa(3He,x)41Ca,and natCa(3He,x)36Cl: Implications for early irradiation in the solar system

Abstract– Cross sections were measured for the nuclear reactions ^natMg(³He,x)²⁶Al, ²⁷Al(³He,x)²⁶Al, ^natCa(³He,x)⁴¹Ca, and ^natCa(³He,x)³⁶Cl in the energy region from approximately 5–35 MeV. The rates of these reactions are important for studies of early solar system irradiation scenarios. The ²⁶Al, ³⁶Cl, and ⁴¹Ca were separated chemically, and the numbers of atoms produced in each reaction channel were measured using accelerator mass spectrometry (AMS). From these results, 26 cross sections were determined and compared with predictions of the TALYS code. Agreement is within 40% for most cross sections. Our measurements were used to model the production of ⁷Be, ¹⁰Be, ²⁶Al, and ⁴¹Ca in the early solar system. For projectiles ¹H, ³He, and ⁴He, we assumed energy spectra of the general form E^?α. For a wide range of parameterizations, the modeled ratios of ⁷Be/Be and ¹⁰Be/Be on the one hand and of ²⁶Al/²⁷Al and ⁴¹Ca/Ca on the other are coupled because the excitation functions for the relevant nuclear reactions have similar shapes. Modeling of a closed system with the constraint that ¹⁰Be/⁹Be = 0.001 fails to reproduce simultaneously the range of ⁷Be/⁹Be, ²⁶Al/²⁷Al, and ⁴¹Ca/Ca ratios inferred for the early solar system from studies of meteorites.     

Intensity variations and ratios of (9-4) and (7-3) hydroxyl bands in nightglow at Poona

The observed types of nocturnal intensity variations for the OH (9-4) and OH (7-3) bands during IQSY at this Station are further analysed using the theoretical band intensity distribution of Evans and Llewellyn (1972). A considerable agreement is noticed between observed and theoretical intensity ratios, $\text{I(9-4)}\text{I(7-3)}$, for a major portion of the data (～70%), which has a “continuous decrease” type of noctural intensity variation. This data is thereby satisfactorily explained on the basis of available information.For the remaining portion of the data (～30%), which has “an increase followed by decrease” type of intensity variation and higher intensities, the observed ratios are also systematically higher than the above. A satisfactory explanation is offered, by postulating a second layer of emission, by examining closely several aspects of the other observational results.     

Recombination dynamics of primordial hydrogen and helium (He I) in the universe

We calculated the ionization fraction for hydrogen and helium (He I) as a function of the redshift z by including the two-photon decays of high hydrogen and parahelium levels and the radiative transfer in the helium 2³P₁ ? 1¹S₀ intercombination line. We show that this yields corrections of no more than a few percent to the ionization fraction for hydrogen and speeds up significantly the recombination for helium compared to the recent works by Seager et al. (1999, 2000), in which these effects were disregarded.     

Dust radiation fields and pumping of excited state OH masers in W3(OH)

I show that it is quite possible to obtain saturating amplification in the 13.44-GHz maser which is so far unique to W3(OH), using a combined radiative and collisional pumping scheme. The dominant radiative part of the pump involves far-infrared line overlap, and the far-infrared continuum is provided by dust, modelled as either a two-component mixture or composite grains. Transport of the far-infrared radiation is carried out via the accelerated lambda iteration method. The observational link between 13.44-GHz and 6035-MHz masers is reproduced by the model. Inadequate amplification in Sobolev models probably results from the optical depth limitations imposed by this approximation. I review the dust models used in far-infrared pumping models of OH masers, and conclude that the main consequence of moving from skewed blackbody functions to more sophisticated models is a selective pumping enhancement when ice mantles are included.     

Structure and kinematics of the interstellar medium in the star-forming region in the BCD galaxy VII Zw 403 (UGC 6456)

The structure and kinematics of ionized supershells in the star-forming region in the BCD galaxy VII Zw 403 (UGC 6456) are analyzed using observations with the SCORPIO focal reducer on the 6-m Special Astrophysical Observatory telescope in three modes: direct imaging (in the Hα, [O III], and [S II] lines), long-slit spectroscopy, and spectroscopy with a scanning Fabry-Perot interferometer. In addition to the previously known bright H II regions and the faint giant ring that surrounds the entire starforming region, many new faint diffuse and arc structures have been detected. A fine structure of the giant ring has been revealed. We do not confirm the previously detected expansion of the bright shells around young stellar associations with a velocity of 50–70 km s^?1. We have estimated their expansion velocities to be no higher than 15–20 km s^?1; the corresponding kinematic age, no younger than 3–4 Myr, agrees well with the age of the compact OB associations associated with them. We correlate the faint extended filamentary and diffuse regions of ionized gas identified almost in the entire central region of the galaxy and the giant H II ring with the older (10 Myr) stellar population of the most recent starburst. Weak high-velocity [O III] and Hα line wings (up to 300 km s^?1 from the line center) have been detected in the brightest H II region. Such velocities have been observed in the galaxy for the first time. The previously published Hα luminosity measurements for the galaxy are refined.     

Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.     

Scattering properties of a moonlet (satellite) embedded in a particle ring: Application to the rings of Saturn

The gravitational influence of moonlets or satellites on the radial structure of the rings of Saturn has been calculated numerically. A drastic change in the surface mass density is obtained even after a single scattering process of the ring particles on a moonlet (satellite). The final surface density shows a significant radial structure, which has been used to estimate the radius and the mass of moonlets or satellites embedded in rings of low optical depth (E ring, Cassini division, C ring).     

Diffuse reflection and transmission in accordance with the phase function 3/4(1+cos2Θ)

We have considered the transport equation for the problem of diffuse reflection and transmission on Rayleigh's phase function and obtained the exact solution of this equation for angular distributions of the intensities diffusely reflected from the surfacet=0 and diffusely transmitted below the surfacet=t ₀ of a finite atmosphere of optical deptht=t ₀ using the Laplace transform and the theory of singular operators. This is an exact method.     

Grain alignment in dense interstellar environments: spectropolarimetry of the 4.67-μm CO-ice feature in the field star Elias 16 (Taurus dark cloud)

We present spectropolarimetry of the solid CO feature at 4.67 μm along the line of sight to Elias 16, a field star background to the Taurus dark cloud. A clear increase in polarization is observed across the feature with the peak of polarization shifted in wavelength relative to the peak of absorption. This shows that dust grains in dense, cold environments (temperatures ∼20 K or less) can align and produce polarization by dichroic absorption. For a grain model, consisting of a core with a single mantle, the polarization feature is best modelled by a thick CO mantle, possibly including 10 per cent water-ice, with the volume ratio of mantle to bare grain of ∼5. Radiative torques could be responsible for the grain alignment provided the grain radius is at least 0.5 μm. This would require the grain cores to have a radius of at least 0.3 μm, much larger than grain sizes in the diffuse interstellar medium. Sizes of this order seem reasonable on the basis of independent evidence for grain growth by coagulation, as well as mantle formation, inside dense clouds.