Subsurface gas hydrates in the northern Gulf of Mexico

The northern Gulf of Mexico (GoM) has long been a focus area for the study of gas hydrates. Throughout the 1980s and 1990s, work focused on massive gas hydrates deposits that were found to form at and near the seafloor in association with hydrocarbon seeps. However, as global scientific and industrial interest in assessment of the drilling hazards and resource implications of gas hydrate accelerated, focus shifted to understanding the nature and abundance of “buried” gas hydrates. Through 2005, despite the drilling of more than 1200 oil and gas industry wells through the gas hydrate stability zone, published evidence of significant sub-seafloor gas hydrate in the GoM was lacking. A 2005 drilling program by the GoM Gas Hydrate Joint Industry Project (the JIP) provided an initial confirmation of the occurrence of gas hydrates below the GoM seafloor. In 2006, release of data from a 2003 industry well in Alaminos Canyon 818 provided initial documentation of gas hydrate occurrence at high concentrations in sand reservoirs in the GoM. From 2006 to 2008, the JIP facilitated the integration of geophysical and geological data to identify sites prospective for gas hydrate-bearing sands, culminating in the recommendation of numerous drilling targets within four sites spanning a range of typical deepwater settings. Concurrent with, but independent of, the JIP prospecting effort, the Bureau of Ocean Energy Management (BOEM) conducted a preliminary assessment of the GoM gas hydrate petroleum system, resulting in an estimate of 607 trillion cubic meters (21,444 trillion cubic feet) gas-in-place of which roughly one-third occurs at expected high concentrations in sand reservoirs. In 2009, the JIP drilled seven wells at three sites, discovering gas hydrate at high saturation in sand reservoirs in four wells and suspected gas hydrate at low to moderate saturations in two other wells. These results provide an initial confirmation of the complex nature and occurrence of gas hydrate-bearing sands in the GoM, the efficacy of the integrated geological/geophysical prospecting approach used to identify the JIP drilling sites, and the relevance of the 2008 BOEM assessment.     

Cetacean habitat in the northern oceanic Gulf of Mexico

Cetaceans (whales and dolphins) are diverse and abundant upper trophic level predators in the Gulf of Mexico, a semi-enclosed, intercontinental sea with a total area of about 1.5 million km². The objectives of this study were to better define the habitat of cetaceans in the northern oceanic Gulf of Mexico. An integrated methodology was used that included visual surveys and hydrographic collections from ships. Near real-time sea surface altimetry from the TOPEX/POSEIDON and ERS satellites was used during ship surveys to determine the location of hydrographic features (e.g., cyclones, anticyclones and confluence zones). Archival satellite sea surface altimetry data were also used to retrospectively determine the location of hydrographic features for analysis with earlier cetacean sightings. We estimated zooplankton and micronekton biomass using both net and acoustic sampling to indicate the amount of potential food available for higher trophic level foraging by cetaceans. Nineteen cetacean species were identified during ship surveys. Cetaceans were concentrated along the continental slope in or near cyclones and the confluence of cyclone–anticyclone eddy pairs, mesoscale features with locally concentrated zooplankton and micronekton stocks that appear to develop in response to increased nutrient-rich water and primary production in the mixed layer. A significant relationship existed between integrated zooplankton biomass and integrated cephalopod paralarvae numbers, indicating that higher zooplankton and micronekton biomass may correlate with higher concentrations of cetacean prey. In the north-central Gulf, an additional factor affecting cetacean distribution may be the narrow continental shelf south of the Mississippi River delta. Low salinity, nutrient-rich water may occur over the continental slope near the mouth of the Mississippi (MOM) River or be entrained within the confluence of a cyclone–anticyclone eddy pair and transported beyond the continental slope. This creates a deep-water environment with locally enhanced primary and secondary productivity and may explain the presence of a resident, breeding population of sperm whales within 100 km of the Mississippi River delta. Overall, the results suggest that the amount of potential prey for cetaceans may be consistently greater in the cyclone, confluence areas, and south of the MOM, making them preferential areas for foraging. However, this may not be true for bottlenose dolphins, Atlantic spotted dolphins and possibly Bryde's whales, which typically occur on the continental shelf or along the shelf break outside of major influences of eddies.     

墨西哥湾天然气水合物矿产资源预测模型及其应用

墨西哥湾是世界上研究天然气水合物较深入的海区,调查资料丰富,已在50多处采集到天然气水合物样品,具备建立天然气水合物矿产资源预测模型的条件。选择34处已知天然气水合物矿点和34处已知无矿点作为训练区,建立矿点存在与否的预测模型。模型的相关系数值表明墨西哥湾天然气水合物与盐底辟关系密切。将该模型应用于整个墨西哥湾北部,初步获得了天然气水合物存在可能性概率分布图;概率大于0.7的预测单元包含已知矿点中的30个,利用该阈值圈定了墨西哥湾天然气水合物潜在资源分布区。     

Trace metal concentrations in menhaden larvae Brevoortia patronus from the northern Gulf of Mexico

Whole body concentrations of Cu, Zn, Mn and Fe were measured in individual gulf menhaden larvae, Brevoortia patronus (11–18 mm standard length) from coastal waters of the northern Gulf of Mexico as part of a continuing project investigating the mechanisms of biological interaction and effect of trace metals in marine food webs. Larvae were collected at three different times between February 1981 and 1982 at two locations, offshore of Southwest Pass of the Mississippi River and offshore of Galveston, Texas.Fish at the Mississippi location had significantly (P≤0·05) greater concentrations of all metals compared with those from the Galveston location. No significant (P>0·05) differences in concentration were detected among the three sampling periods. Menhaden larvae had metal conentrations comparabe to other species of larval fish and zooplankton from the Gulf of Mexico and other coastal waters. Differences in metal concentrations in larvae from the two locations appear to be a subtle response of the fish to differences in the trace metal chemistries of the two coastal areas. Processes influencing metal concentrations are discussed.     

Physiographic features on the northern Gulf of Mexico continental slope

The continental slope of the northern Gulf of Mexico is diapirically controlled and is comprised of coalescing salt sheets, salt withdrawal basins, salt ridges, salt tongues and sills, and submarine canyons. Bathymetric information from single-beam data has resulted in several published maps. Many of the map areas have been remapped, using multibeam surveys, by the US National Ocean Service, and names have been given to the major physiographic features. The multibeam program was discontinued before complete coverage of the slope was accomplished. We provide charts of the remaining areas with names of features that have been accepted by the US Board of Geographic Names.     

Depositional history of the Lagniappe Delta,northern Gulf of Mexico

The northern Gulf of Mexico continental shelf is characterized by superimposing deltas. One such delta, informally named Lagniappe, extends east of the Mississippi Delta from mid-shelf to the continental slope. This late Wisconsinan delta is adjacent to, but not associated with the Mississippi Delta complex: the fluvial source was probably the ancient Pearl and/or Mobile Rivers. The fluvially dominated Lagniappe Delta is characterized by complex sigmoid-oblique seismic-reflection patterns, indicating delta switching of high-energy sand-prone facies to low-energy facies. The areal distribution and sediment thickness of the delta were partially controlled by two diapirs.     

Mineral assemblages occurring around hydrocarbon vents in the northern Gulf of Mexico

Magnesian calcites are the most abundant authigenic minerals associated with hydrocarbon vents at 25 sites, in water depths ranging from 100 to 600 m in the Green Canyon area and about 2200 m in the Alaminos Canyon area on the Continental Slope of the northern Gulf of Mexico. The most frequently encountered magnesian calcites have 10–15 mol% MgCO₃ and the apparent structural disorder revealed by XRD peak widths increases with Mg substitution. There are no systematic variations in Mg content with respect to water depth or geographic location. The calcite saturation state of the precipitating fluid is primarily determined by the nature of the fluids escaping from the vents, not the ambient seawater.     

High-resolution seismic-reflection investigation of the northern Gulf of Mexico gas-hydrate-stability zone

We recorded high-resolution seismic-reflection data in the northern Gulf of Mexico to study gas and gas-hydrate distribution and their relation to seafloor slides. Gas hydrate is widely reported near the seafloor, but is described at only one deep drill site. Our data show high-reflectivity zones (HRZs) near faults, diapirs, and gas vents and interbedded within sedimentary sections at shallow depth (<1 km). The HRZs lie below the gas-hydrate-stability zone (GHSZ) as well as within the zone (less common), and they coincide with zones of shallow water-flows. Bottom simulating reflections are rare in the Gulf, and not documented in our data.We infer HRZs result largely from free gas in sandy beds, with gas hydrate within the GHSZ. Our estimates for the base BHSZ correlate reasonably with the top of HRZs in some thick well-layered basin sections, but poorly where shallow sediments are thin and strongly deformed. The equivocal correlation results from large natural variability of parameters that are used to calculate the base of the GHSZ. The HRZs may, however, be potential indicators of nearby gas hydrate. The HRZs also lie at the base of at least two large seafloor slides (e.g. up to 250 km²) that may be actively moving along decollement faults that sole within the GHSZ or close to the estimated base of the GHSZ. We suspect that water/gas flow along these and other faults such as ‘chimney’ features provide gas to permit crystallization of gas hydrate in the GHSZ. Such flows weaken sediment that slide down salt-oversteepened slopes when triggered by earthquakes.     

Metazoan meiofauna abundance in relation to environmental variables in the northern Gulf of Mexico deep sea

In order to more fully understand the distribution of meiofauna and how they respond to topographic, geochemical and physical forcing in the northern Gulf of Mexico, meiofauna abundance and environmental variables were analyzed in a hypothesis-based univariate and multivariate design. Meiofauna abundance was significantly related to water depth, but also exhibited significant longitudinal differences resulting from proximity to Mississippi River outflow. Canyon features in proximity of Mississippi River outflow were found to greatly enhance meiofauna abundance. The Florida Escarpment interacts with Mississippi River outflow and the Loop Current to enhance meiofauna abundance at stations lying directly above and below the escarpment. Multivariate comparisons of meiofauna abundance with environmental variables revealed a strong Mississippi River influence. River outflow alters local sediment characteristics, and interacts with loop current eddies and dynamic slope topography to increase particulate organic matter flux in the northeastern region, thus creating areas of higher than normal meiofauna abundance.     

The generation and preservation of multiple hurricane beds in the northern Gulf of Mexico

Cores collected from Mississippi Sound and the inner shelf of the northeast Gulf of Mexico have been examined using ²¹⁰Pb and ¹³⁷Cs geochronology, X-radiography, granulometry, and a multi-sensor core logger. The results indicate that widespread event layers were probably produced by an unnamed hurricane in 1947 and by Hurricane Camille in 1969. Physical and biological post-depositional processes have reworked the event layers, producing regional discontinuities and localized truncation, and resulting in an imperfect and biased record of sedimentary processes during the storms. The oceanographic and sedimentological processes that produced these event beds have been simulated using a suite of numerical models: (1) a parametric cyclone wind model; (2) the SWAN third-generation wave model; (3) the ADCIRC 2D finite-element hydrodynamic model; (4) the Princeton Ocean Model; (5) a coupled wave–current bottom boundary layer-sedimentation model; and (6) a model for bed preservation potential as a function of burial rate and bioturbation rate. Simulated cores from the Mississippi Sound region are consistent with the observed stratigraphy and geochronology on both the landward and seaward sides of the barrier islands.     

Controls of listric normal fault styles in the northern Gulf of Mexico: Insights from experimental models

Passive margins such as the Gulf of Mexico are characterized by two distinct styles of faulting. Homogenous sand/shale packages in offshore Texas mostly display basinward-dipping listric normal faults with associated rollover structures cut by synthetic and antithetic faults. The fault traces are generally long and show a linear trend. Stratigraphic packages with a ductile substratum (salt) in offshore Louisiana are characterized by basinward and landward-dipping, short arcuate faults detaching within the salt. The structures consist of a series of half-grabens, with the movement of salt from the front to the back of each fault block. Clay experimental models are used to study the controls of fault geometries in the two structural styles and their interaction to form complex transfer zones. The surface of the clay cake is laser-scanned to enable 3D visualization and accurate measurements of structures. The results suggest that within homogeneous sand-shale packages, the dips of the faults and their locations are primarily dependent on the direction of the drop down of the basal detachment along pre-existing discontinuities, with the slope of the basal discontinuity and the direction of extension providing secondary controls. On the other hand, the dips of fault systems in packages underlain by a ductile substratum are primarily controlled by the slope of the basal detachment. Therefore, the more common regional Roho systems typically form above salt sheets with initial basinward slopes, whereas counter-regional fault systems form above salt sheets with initial landward slopes. The direction of extension and the presence of small pre-existing discontinuities impart only secondary controls when ductile basal units are involved. The faults initiate at the head of ductile layer and propagate downslope. Complex transfer zones develop at the boundary of the ductile substratum due to interference between the two fault styles.     

Predictors of species richness in the deep-benthic fauna of the northern Gulf of Mexico

Species richness in macrofauna and megafauna collected with box cores and trawls from 35 standard stations over a depth range of 175–3720 m in the northern Gulf of Mexico was examined in terms of two primary questions: (1) are observed patterns random? and (2) if not, what environmental factors might account for the patterns? A null model tested whether richness vs. depth distributions were random. Groups with species that had broad vertical depth ranges fit the null model better than groups with small ranges, but for almost all phyla a non-random pattern was indicated. With randomness as a proximal explanation ruled out, further examination of the relationship between richness and environmental factors was justified. A generalized linear model (GLM) showed that a suite of 18 factors categorized as food-related, habitat-related, pollution-related and location-related were significantly related to richness patterns, but that different mixes of factors applied to different phyla. No one factor accounted for any observed patterns. Thus, each taxonomic group needs to be examined individually, and no generally applicable explanation for the causes of richness patterns may exist. Nonetheless, mapping richness itself indicates valuable areas in the Mississippi Trough that must receive special consideration and possible protection.     

Epizooic metazoan meiobenthos associated with tubeworm and mussel aggregations from cold seeps of the northern Gulf of Mexico

The abundance and higher taxonomic composition of epizooic metazoan meiobenthic communities associated with mussel and tubeworm aggregations of hydrocarbon seeps at Green Canyon, Atwater Valley, and Alaminos Canyon in depths between 1400 and 2800?m were studied and compared to the infaunal community of non-seep sediments nearby. Epizooic meiofaunal abundances of associated meiobenthos living in tubeworm bushes and mussel beds at seeps were extremely low (usually <100?ind. 10?cm(-2)), similar to epizooic meiofauna at deep-sea hydrothermal vents, and the communities were composed primarily of nematodes, copepods, ostracods, and halacarids. In contrast, epizooic meiobenthic abundance is lower than previous studies have reported for infauna from seep sediments. Interestingly, non-seep sediments contained higher abundances and higher taxonomic diversity than epizooic seep communities, although in situ primary production is restricted to seeps.     

Hydrodynamic and sedimentary responses to two contrasting winter storms on the inner shelf of the northern Gulf of Mexico

Results are presented from the deployment of three bottom-mounted instrumentation systems in water depths of 6–9 m on the sandy inner shelf of Louisiana, USA. The 61-day deployment included nine cold front passages that were associated with large increases in wind speed. Two of the most energetic cold front passages were characterized by distinct meteorological, hydrodynamic, bottom boundary layer, and sedimentary responses and may potentially be treated as end-member types on a continuum of regional cold front passages. Arctic surges (AC storms) have a very weak pre-frontal phase followed by a fairly powerful post-frontal phase, when northeasterly winds dominate. Migrating cyclones (MC storms) are dominated by a strong low-pressure cell and have fairly strong southerly winds prior to the frontal passage, followed by strong northwesterly winds.

On the basis of measurements taken during this study, AC storms are expected to have a lower average significant wave height than MC storms and are dominated by short-period southerly waves subsequent to the frontal passage. Currents are weak and northerly during the pre-frontal phase, but become very strong and southwesterly following the passage. Sediment transport rate during AS storms was not as high as during MC storms, and the mean and overall direction tended to be southwesterly to westerly, with low-frequency flows producing easterly transport, and wind-wave flows producing southeasterly transport.

MC storms had the most energetic waves of any storm type, with peaks in significant wave height occurring during both the pre- and post-frontal phases. The wave field during MC storms tended to be more complex than during AS storms, with an energetic, northerly swell band gradually giving way to a southerly sea band as the post-frontal phase progressed. Currents during MC storms were moderate and northerly during the pre-frontal phase, but became much stronger and southeasterly during the post-frontal phase. Shear velocity was high during both the pre- and post-frontal phases of the storm, although sediment transport was highest following the frontal passage. Mean and overall sediment transport was directed southeasterly during MC storms, with low-frequency and wind-wave flows producing northerly transport. In summary, the data sets presented here are unique and offer insight into the morphosedimentary dynamics of mid-latitude, micro-tidal coasts during extratropical storms.     

The 20th-century development and expansion of Louisiana shelf hypoxia,Gulf of Mexico

Since systematic measurements of Louisiana continental-shelf waters were initiated in 1985, hypoxia (oxygen content <2 mg L⁻¹) has increased considerably in an area termed the dead zone. Monitoring and modeling studies have concluded that the expansion of the Louisiana shelf dead zone is related to increased anthropogenically derived nutrient delivery from the Mississippi River drainage basin, physical and hydrographical changes of the Louisiana Shelf, and possibly coastal erosion of wetlands in southern Louisiana. In order to track the development and expansion of seasonal low-oxygen conditions on the Louisiana shelf prior to 1985, we used a specific low-oxygen foraminiferal faunal proxy, the PEB index, which has been shown statistically to represent the modern Louisiana hypoxia zone. We constructed a network of 13 PEB records with excess ²¹⁰Pb-derived chronologies to establish the development of low-oxygen and hypoxic conditions over a large portion of the modern dead zone for the last 100 years. The PEB index record indicates that areas of low-oxygen bottom water began to appear in the early 1910s in isolated hotspots near the Mississippi Delta and rapidly expanded across the entire Louisiana shelf beginning in the 1950s. Since ~1950, the percentage of PEB species has steadily increased over a large portion of the modern dead zone. By 1960, subsurface low-oxygen conditions were occurring seasonally over a large part of the geographic area now known as the dead zone. The long-term trends in the PEB index are consistent with the 20th-century observational and proxy data for low oxygen and hypoxia.     

Stakeholder perceptions of the northern Gulf of Mexico grouper and tilefish individual fishing quota program

The Gulf of Mexico Fishery Management Council determined that previous management of the grouper and tilefish fisheries in the northern Gulf of Mexico were not meeting management goals, and developed a catch shares program using individual fishing quotas (IFQs) beginning in January 2010 in order to more effectively manage these fisheries. An IFQ is a management method in which individual fishers and corporations are allocated the right to harvest a percentage of a fishery's total allowable catch, thus specifying how much of a particular species each fisher can harvest. This study makes use of a mail out survey to document the perceptions of fishers, seafood wholesalers, fisheries managers, and academics with an interest in the (northern) Gulf of Mexico grouper and tilefish IFQ program. While fishers, seafood dealers, fisheries managers, and academics all acknowledge that the IFQ program will create some problems, commercial fishers and dealers were far more skeptical of the alleged benefits of IFQs. Moreover, larger commercial operators were more inclined to agree with managers and academics that the IFQ program will produce several benefits for their operations and the fisheries. Some smaller operators believe that they will be driven to ignore the new rules or be forced out of business. In the future, the Gulf Council might do two things: put a bit more effort into making fishers aware of the potential benefits of IFQs, and develop alternatives with more flexibility perhaps working more closely with communities of fishers, who prize their independent way of life above all else.     

Seismic expression of sedimentary volcanism on the continental slope,northern Gulf of Mexico

High-resolution geophysical data define acoustically amorphous, mounded structures on the upper, middle, and lower continental slope of the northern Gulf of Mexico. Physical samples and observations within this unique seismic facies show gassy sediments, sometimes in hydrated form and, in places, as chemosynthetic communities. The geologic setting of these mounds suggests that the process of formation falls on the continuum of mud volcanoes to mud diapirs.     

Occurrence of larval fishes in the surf zone of a northern Gulf of Mexico barrier island

Larval fishes were collected from the surf zone of Horn Island, Mississippi between March 1978 and April 1979. A standardized total of 39 435 larvae were taken from 222 collections in the inner and outer surf zone regions, representing fish in 69 taxa. Overall, considerably more larvae were collected in the outer surf zone (78·3%) than in the inner surf zone (21·7%). Engraulids, Chloroscombrus chrysurus and Symphurus spp. were the most abundant larvae taken from the outer surf zone while engraulids, Leiostomus xanthurus, Brevoortia patronus and Trinectes maculatus were the numerically dominant larvae in the inner surf zone. Seasonal peaks in abundance occurred at the outer surf zone stations during May and June and at the inner surf zone stations during December. Larval densities were significantly greater in night collections than in day collections.The occurrence of early larvae, late larvae and juveniles suggests that the surf zone habitat is important to several species of coastal marine fishes. Menticirrhus littoralis, Harengula jaguana and Trachinotus carolinus appear to most readily utilize the surf zone as a nursery area.