Heavy metals in surface sediments from nine estuaries along the coast of Bohai Bay,Northern China

Concentrations of heavy metals in river water and sediment were investigated in nine estuaries along the coast of Bohai Bay, Northern China. Multivariate statistical techniques such as principal component analysis and cluster analysis, in combination with metal concentration analysis and correlation analysis, were used to identify the possible sources of the metals and the pollution pattern in nine estuaries along the coast of Bohai Bay. The environmental risks of metals, evaluated by sediment quality guidelines and background values, revealed Hg contamination in the estuaries. However, levels of Cd in estuarine sediments were low, and they were less than those levels in river sediments, partly due to the high mobility and dilution of river or seawater. Cd did not contribute to sediment deposits in estuaries. High organic matter from effluents from large municipal sewage treatment plants was predominantly responsible for restricting Hg mobility from the river to Bohai Bay.     

华北渤海湾盆地大震的构造特征

渤海湾盆地是地震活动强烈的地区，记载有7级以上大地震6次。前人对几次大震的具体构造条件已做过大量研究。笔者基于已有的工作，通过对盆地构造发育早第三纪断陷和晚第三纪以来拗陷两个阶段的不同构造后性和区域地震构造格局的分析，以及大震区构造的剖析，综合研究了大震的构造特征。其中最根本的是，盆地发育的断陷阶段因北西—南东向水平拉张作用，于地壳上部形成了由北北东—北东向太行山山前断裂带等大型拆离断裂拉张滑脱控制的伸展断裂系统；拗陷阶段受北东东—南西西向水平挤压，正发育着一套地壳共轭剪切破裂系统。前者与地震关系不大，后者对地震孕育和发生有着重要的控制作用。     

Temporal and spatial trends of total petroleum hydrocarbons in the seawater of Bohai Bay, China from 1996 to 2005

The temporal and spatial distribution of total petroleum hydrocarbons (TPH) in the seawater of Tianjin Bohai Bay during 1996-2005 was investigated for the first time. TPH concentrations in 480 seawater samples collected from 16 stations during a 10-year span were quantified by ultra-violet fluorescence spectroscopy. Petroleum hydrocarbons were ubiquitous in the seawater, and their concentrations were highly variable, ranging from 23.7 to 508 μg L⁻¹. TPH concentrations in the seawater varied with seasons, showing a decreasing order of winter > spring > summer. Over the 10-year period, TPH at all stations steadily decreased. The highest values obtained were at stations near the port areas and Dagu outfall where shipping activities and land-based waste water discharges were the major sources of pollution. Our results provided the background information on the extent of TPH contamination in the seawater and highlighted the need to further control TPH pollution in Tianjin Bohai Bay.     

渤海湾盆地冀中坳陷现今地热特征

渤海湾盆地冀中坳陷是我国最典型的潜山油气藏富集区.本文借助117口钻井地层测温资料和45块实测岩石热导率数据系统研究了冀中坳陷现今地温梯度、大地热流、热岩石圈厚度、岩石圈热结构等地热特征参数.研究表明,冀中坳陷0~3000 m统一深度现今地温梯度为20.8~41.0℃·km-1,平均值为31.6℃·km-1,比未校正值减小1~3℃·km-1;现今大地热流介于48.7~79.7 mW·m-2,平均值为59.2 mW·m-2.平面上,冀中坳陷现今地温梯度和热流由西向东(从盆地边缘向内部)逐渐增大,并且凸起区地温梯度和热流相对较高,而凹陷区则偏低,与基底地形起伏具有很好的对应关系.同时,冀中坳陷腹部高热流凸起区广泛分布地热田.冀中坳陷现今热岩石圈厚度为98~109 km,其岩石圈热结构为一典型的"冷壳热幔"型.本研究不仅对冀中坳陷油气勘探与地热能开发具有重要的指导意义,而且为深部岩石圈研究(华北克拉通破坏科学问题)提供了新依据.     

Heavy metal contamination and ecological risk in Spartina alterniflora marsh in intertidal sediments of Bohai Bay,China

To investigate the effects of Spartina alterniflora on heavy metals pollution of intertidal sediments, sediment cores of a S. alterniflora salt marsh and a mudflat in Bohai Bay, China were analyzed. The results showed that S. alterniflora caused higher total C and P, but lower bulk density and electrical conductivity. The levels of Cd, Cu and Pb were higher in S. alterniflora sediment. Both Cd and Zn were higher than the probable effect level at both sites, indicating their toxicological importance. The geo-accumulation and potential ecological risk indexes revealed higher metal contamination in S. alterniflora sediment. Multivariate analysis implied that anthropogenic activities altered mobility and bioavailability of heavy metals. The percentage of mobile heavy metals was higher in S. alterniflora sediment, indicating improvement of conversion from the immobilized fraction to the mobilized fraction. These findings indicate that S. alterniflora may facilitate accumulation of heavy metals and increase their bioavailability and mobility.     

利用接收函数研究渤海湾盆地沉积层结构

对布设于渤海湾盆地地区的70个台站2006年9月—2009年9月记录到的895个远震数据进行接收函数计算,发现位于沉积层上的台站记录的接收函数震相较为复杂,由沉积层基底的转换波、多次波及莫霍面转换波、多次波共同构成,且随着沉积层厚度的增加,沉积层基底转换波、多次波与莫霍面转换波、多次波震相相互叠加,使之无法分辨出莫霍面转换波及多次波到时.为此,本文利用相邻算法对沉积层模型进行搜索, 以获取与实际波形误差最小的波形相对应的模型,即台站下方的沉积层结构.结果显示：① 渤海湾盆地由NNE向展布的坳陷带与隆起带组成,冀中坳陷带的沉积层厚度为3—6 km, 坳陷带内沿NE-NNE向分布着带状凹陷带与凸起带相间的次级构造,而且其东侧靠近沧县隆起区的凹陷带沉积层基底埋深最大,体现了渤海湾盆地基底受正断层控制而形成的半地堑(地堑)-半地垒(地垒)构造;② 隆起带的波速比v_P/v_S大于坳陷带的波速比,推测与隆起带下第三系地层的缺失有关, 坳陷带内高波速比地区与地热田的分布相对应, 说明沉积层内高温环境下波速比较高;③ 隆起带内的S波平均速度较坳陷带内的S波平均速度小,且冀中坳陷带内沉积层较厚地区对应的S波平均速度比其它地区更大, 说明渤海湾地区沉积层厚度与沉积层内的S波平均速度成反比关系,推测与下第三系地层的厚度有关,且下第三系地层越厚的地区,S波平均速度越大.以上结果表明,利用接收函数研究的结果与通过地质、地热等方面的研究结果存在着良好的对应关系.     

Total petroleum hydrocarbons and heavy metals in the surface sediments of Bohai Bay,China: Long-term variations in pollution status and adverse biological risk

Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3–535 μg/g, 58–332 μg/g, 7.2–63 μg/g, 4.3–138 μg/g, 0–0.98 μg/g, and 0.10–0.68 μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay.     

Effects of suspended particles on the growth of two dominant phytoplankton species of Bohai Bay,China

Suspended particles (SP) are increasing dramatically in Bohai Bay, China and may affect the growth and composition of phytoplankton assembly. To determine the effects of SP on the growth of two dominant phytoplankton species, Phaeodactylum tricornutum Bohlin and Gymnodinium sp., we cultured and tested their growth characteristics under SP concentrations ranging from 0 g L⁻¹ to 0.8 g L⁻¹. Our results show that the increase in the SP concentrations results in significant decrease in the maximum cell densities and the maximum specific growth rates of these two species. The half maximal inhibitory concentration (IC₅₀) of SP to P. tricornutum and Gymnodinium sp. were 1.07 g L⁻¹ and 0.68 g L⁻¹ respectively, indicating the inhibitory effect of SP on Gymnodinium sp. was greater than on P. tricornutum. These results suggest that SP inhibits the growth of the two algal species and P. tricornutum is more tolerant to SP than Gymnodinium sp.     

中国渤海湾盆地上地壳岩石成分模型(英文)

许多地震属性,比如地震的纵横波速度,泊松比,声波阻抗,都能用来区分不同的岩石类型,利用拉梅阻抗作为进一步的约束来代替声波阻抗能更好的降低结果的非唯一性。我们用这种方法构建了渤海湾地区一条剖面的岩石成分模型。我们简要介绍了区分岩石类型的地震参数,重点在于不同的参数组合对于分辨岩石类型的敏感性。为了与室温常压条件下测得的有代表性的岩石的地震波速度和密度进行对比,我们首先需要做温度和压力的校正。接着,我们需要用已知资料和实验测得的各种岩石样品做对比,来确定研究区的岩石类型。我们收集了渤中凹陷一条剖面的纵波速度资料。该剖面10km深范围内的属于同种岩石类型的不同岩石最终通过地震波速度、泊松比、密度、声波阻抗、以及拉梅阻抗综合约束。     

渤海南部莱州湾Lz908孔沉积物的岩石磁学性质

亚洲大陆边缘海和陆表海在区域的物质和能量交换以及区域气候与环境演化过程中扮演了关键角色.磁性地层学和环境磁学方法是建立年代框架和环境演变序列的有效手段,但是,由于该地区边缘海和陆表海沉积物中磁性矿物来源十分复杂,磁性地层学和环境磁学研究的重要基础是要精细地解译沉积物的岩石磁学性质.为此,本文利用渤海南部莱州湾Lz908孔与钻孔附近的现代沉积物样品进行了详细的岩石磁学对比研究.结果显示,渤海南部沉积物中的磁性矿物主要是较粗颗粒(较大的准单畴至多畴)磁铁矿,还有少量磁赤铁矿,部分沉积物还含有赤铁矿和针铁矿,其中磁铁矿是特征剩磁的主要载体;莱州湾现代河流-海洋沉积物和钻孔样品之间的磁性特征无显著差异,说明莱州湾沉积物堆积之后尚未经历明显的沉积后期改造.     

渤海湾盆地新生代拉张中心迁移的热-流变机制

在区域拉张应力作用下, 岩石圈拉张减薄, 减薄的中心地带成为拉张中心, 渤海湾盆地新生代期间拉张中心具有自西向东、自南向北的迁移规律.为了探究渤海湾盆地新生代期间拉张中心的迁移与岩石圈热-流变结构的关系, 本文在构造-热演化模拟的基础上, 对渤海湾盆地各坳陷新生代岩石圈热-流变结构进行了计算.结果表明: 渤海湾盆地新生代岩石圈拉张中心的迁移主要受岩石圈流变强度的非均匀性所控制.拉张中心开始位于岩石圈强度最低的济阳坳陷, 拉张及伴随的的热冷却过程使得济阳坳陷岩石圈强度增大, 并且超过了渤中坳陷岩石圈强度, 因此, 沙四段时期, 拉张中心迁移到了渤中坳陷; 沙三段时期, 拉张中心迁移到了黄骅以及辽东湾坳陷.这是由于拉张速度较慢时(对于约90 km厚度的岩石圈而言, 如果初始地壳厚度＞34 km, 拉张速度0.5 cm·a^-1), 拉张初期会造成岩石圈强度的降低, 但随着拉张的持续进行, 岩石圈整体强度反而增加.孔店组时期, 在岩石圈强度较大的冀中及临清坳陷形成拉张中心可能是叠加了其他地质因素(如前期构造、断裂活动、远程应力等)的影响.东营组时期, 在岩石圈强度较大的渤中坳陷形成拉张中心, 这可能是该时期岩石圈强度同时受到了郯庐断裂带的活动或小规模的地幔对流的影响, 导致其实际强度比模拟计算的强度更低, 因而使得应变集中在渤中以及辽东湾坳陷.

     

Seismic tomography of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions

In the Bohai Bay Basin and its adjacent regions(112°―124°E,34°―42°N),there exists abundant gas-petroleum while modern inter-plate seismic activity is robust.Although the tectonic structure of this region is very complicated,plenty of geological,geophysical and geochemical data and results are obtained through previous researches.On the basis of absorbing previous results,especially various kinds of geological and geophysical results,we collect and process the arrival time of P-wave phases of local events and tele-seismic events recorded by the station within this region from 1978 to 2004,build the responding initial model,and image the velocity structure of the crust and upper mantle of this region via tomography.The perturbation images of various depths and velocity profiles imply that the velocity structure of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions is mainly influenced by the surface tectonic units,and is characterized by "Stripped along east-west,and zoned along south-north";some large-scaled faults penetrate Moho and lithosphere,and provide the channels for the basic lava or hot mass upwelling from the mantle.     

Control of differential tectonic evolution on petroleum occurrence in Bohai Bay Basin

The Bohai Bay Basin(BBB)is the most petroliferous Cenozoic basin in the east of China.It consists of seven depressions.Each depression has been subjected to different stress states and then has experienced varying faulting processes since the Neogene,especially during the Neotectonism(from the Pliocene to the present).On the basis of the investigation of fault patterns,fault densities and fault activity rates(FARs)for each depression,this paper demonstrates the discrepancy of faulting development and evolution across the BBB.The dynamic mechanism for the differences in faulting is also discussed by the analysis of the regional stress state.The Bozhong Depression is just situated in the transtensional zone induced by the two active strike-slip faults,namely Yingkou-Weifang and Beijing-Penglai.In this depression,the major faults which cut through the Paleogene or the Cenozoic have had higher than 10 m/Ma FARs since the Neogene,and the highest FARs have reached or exceeded 25 m/Ma during the Neotectonism.As a result,most of the petroleum has migrated along these major faults and accumulated within the Neogene.In contrast,in the other depressions of the BBB away from the Bozhong Depression,the FARs of the major faults were decreased to lower than 10 m/Ma since the Neogene,and tended to be zero during the Neotectonism.Therefore,the major faults could not serve as vertical conduits for petroleum migration,and the petroleum was entrapped in the Paleogene.Consequently,the faulting since the Neogene,especially during the Neotectonism,controlled the petroleum richness in vertical strata.     

Organochlorine pesticides in sediments of Laizhou Bay and its adjacent rivers, North China

Organochlorine pesticides (HCHs, DDTs and HCB) have been investigated in sediments of Laizhou Bay and its adjacent rivers. The average concentrations of HCHs, DDTs and HCBs are 0.09 ng/g dw, 0.59 and 0.05 for marine sediments and 0.55, 8.6 and 1.1 for riverine sediments, respectively. Laizhou Bay is less contaminated by HCHs and DDTs in comparison with other coastal regions around the world, including the other two biggest bays in Bohai Sea. Fresh input of lindane and dicofol-type DDT were found in several riverine sites. Relatively strong TOC-dependence of HCB distribution in the entire studied area suggested no point source existed and/or water-sediment equilibrium achieved. No significant difference of α/γ-HCH ratios have been observed between marine and riverine sediments. However, o,p′-DDT/p,p′-DDT ratios varied largely between the two regions.     

The control of syndepositional faulting on the Eogene sedimentary basin fills of the Dongying and Zhanhua sags, Bohai Bay Basin

CopyrightbyScienceinChinaPress2004Theconfigurationandpredictionofdepositionalsystemsinasedimentarybasinhavelongbeenoneofthemajortasksofbasinanalysisandsedimentarygeologicalresearch.Intermsofsequencestratigraphy,originallyestablishedinstudyoftectonicallytablecontinentalmargins,thesealevelchangehasbeenusedtoeffectivelyinterpretandpredictthedistributionandevolutionofdepositionalsystemsinthesebasins[1,2].Butintectonicallyactivebasins,tectonismmaycontrolpredominatelythearchitectureandevolutionofth…     

Linking the toxic metals to benthic community alteration: A case study of ecological status in the Bohai Bay

Ecological effects and quality status of sediments in the Bohai Bay (North China) were studied by incorporating the traditional chemical analysis and benthic community structure. In the present study, paired sediments from 20 stations were sampled for chemical analysis and benthic assemblages. The overall results demonstrated that sediment impairment mainly appeared in the southern part of the Bay. The results obtained from the principal component analysis regarding benthic data and potential explanatory factors indicated that As, Hg and petroleum hydrocarbons (PHs) were responsible for the distribution of macrofaunal assemblages. Canonical correspondence analysis further showed As was significantly correlated to the benthic alteration, which provided evidence of ecological relevance to chemical substances of concern. Overall, this study revealed the metal contamination in the Bohai Bay was not as severe as previously regarded. Yet, further investigation is still needed considering the complexity of sediment matrices.     

最小二乘逆时偏移中黏弹性和各向异性的校正:以渤海湾地区地震数据为例

地下介质中存在黏弹性和各向异性,在应用最小二乘逆时偏移时,如果没有对黏弹性和各向异性的影响进行校正,在观测数据和模拟数据的匹配过程中就会发生错误,最终使得最小二乘逆时偏移无法得到准确的成像结果.因此,本论文首先对最小二乘逆时偏移的黏弹性和各向异性进行分别校正,然后对两种影响进行同时校正.在实际资料试算部分,通过对渤海湾数据进行测试,分别采用常规声波最小二乘逆时偏移、补偿黏弹性的最小二乘逆时偏移、校正各向异性的最小二乘逆时偏移及同时校正两种性质的最小二乘逆时偏移进行比较测试,证明了在同时校正了黏弹性和各向异性影响之后,最小二乘逆时偏移得到了更高质量的成像结果,具体表现在低频噪音压制、震源效应压制、深部能量改善、分辨率提升、目的层刻画等方面都明显优于其他三种最小二乘逆时偏移的成像结果,同时也证明了同时校正黏弹性和各向异性最小二乘逆时偏移方法的正确性及在实际资料处理中的适用性.

     

Concentration and fractionation of trace metals in surface sediments of intertidal Bohai Bay, China

Surface sediments from intertidal Bohai Bay were sampled for the geochemical and environmental assessment of six trace metals (Cd, Cr, Cu, Ni, Pb and Zn). Results indicate that sediment grain size plays an important role in controlling the distribution and fractionation of them. Metal concentrations in clayey silt sediments are all clearly higher than in sand and silty sand ones. Cd and Pb in clayey silt sediments are more mobile than in sand and silty sand ones. Two sediment quality guidelines and two geochemical normalization methods (index of geoaccumulation and enrichment factor) were used to judge the potential risk and accumulation of metals. According to the mean probable effects level quotient, the combination of studied metals may have a 21% probability of being toxic. The sediments with high fraction of clay and silt have been contaminated by trace metals to various degrees, among which Cr contributes the most to contamination.     

Near surface velocity and QS structure of the Quaternary sediment in Bohai basin,China

Heavily populated by Beijing and Tianjin cities, Bohai basin is a seismically active Cenozoic basin suffering from huge lost by devastating earthquakes, such as Tangshan earthquake. The attenuation (Q_P and Q_S) of the surficial Quaternary sediment has not been studied at natural seismic frequency (1?10 Hz), which is crucial to earthquake hazards study. Borehole seismic records of micro earthquake provide us a good way to study the velocity and attenuation of the surficial structure (0?500 m). We found that there are two pulses well separated with simple waveforms on borehole seismic records from the 2006 M_W4.9 Wen'an earthquake sequence. Then we performed waveform modeling with generalized ray theory (GRT) to confirm that the two pulses are direct wave and surface reflected wave, and found that the average v_P and v_S of the top 300 m in this region are about 1.8 km/s and 0.42 km/s, leading to high v_P/v_S ratio of 4.3. We also modeled surface reflected wave with propagating matrix method to constrain QS and the near surface velocity structure. Our modeling indicates that Q_S is at least 30, or probably up to 100, much larger than the typically assumed extremely low Q (~10), but consistent with Q_S modeling in Mississippi embayment. Also, the velocity gradient just beneath the free surface (0?50 m) is very large and velocity increases gradually at larger depth. Our modeling demonstrates the importance of borehole seismic records in resolving shallow velocity and attenuation structure, and hence may help in earthquake hazard simulation.