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1.
We present a method to estimate the spatial distribution of dredged material disposed of at sea. Using both dredged sediments and samples of sea-bed sediment from near the Rame Head disposal site, Plymouth, UK, we applied entropy analysis to the <63 μm sediment fraction and combined the results with the trace metal data in the same fraction, to form a series of groups. We interpret the distribution of sediments in one group (F1) to approximate the distribution of material affected by the disposal site. This distribution includes locations close to the disposal site, and also locations <4 km to the SE and SW, <6 km to the NW and <2 km to the N. This approach demonstrates the feasibility of using trace metal analysis of particular grain size fractions to reduce uncertainty in interpreting the spatial distribution of impacts of dredge disposal.  相似文献   

2.
Richards Bay Harbour is South Africa’s premier bulk cargo port. It was constructed in the Mhlathuze estuary in 1976 and over the past 34 years has become South Africa’s most modern and largest cargo handling port. Although no official monitoring programme is in progress various studies by different groups have provided relevant data with respect to changing metal levels in brown mussel tissue (Perna perna) over the last 34 years. Eleven elements were analysed in brown mussels from the main channel in Richards Bay Harbour using ICP-MS. The results indicate that the metal concentrations in the mussel tissue remained relatively constant between 1974 and 2005. The mean metal concentrations increased significantly in 2005 possibly due to the construction of the new coal terminal and associated dredging activities. Mean metal concentrations in the 2008 sampling event were also elevated due to increased run off during an above average rainy season.  相似文献   

3.
In this paper we present the concentrations of Hg, Cd, Se, Pb, Cu, Mn, Zn and Fe in organs of 6 non-common specimens of cetaceans that were stranded along the Israeli Mediterranean coast (IMC), during 2002–2010: two fin whales, one minke whale, one Cuvier’s beaked whale, one rough-toothed dolphin, and one Risso’s dolphin. Most of the specimens were calves stranded by accident. Concentrations of Hg and Cd were low in tissues of the baleen whales and higher in the toothed whales, with maximum concentrations of 1067 mg kg−1 Hg in the liver of the Risso’s dolphin and 29 mg kg−1 Cd in the kidney of the Cuvier’s beaked whale. As far as we are aware, this is the first report of trace elements in baleen whales in the Eastern Mediterranean, and the first report of trace elements in minke whale and rough-toothed dolphin in the Mediterranean.  相似文献   

4.
A series of pristine block-and-ash flow deposits from the May–June 2006 eruption of Merapi represent an exceptional record of small-volume pyroclastic flows generated by gravitational lava-dome collapses over a period of about two months. The deposits form nine overlapping lobes reaching ~ 7 km from the summit in the Gendol River valley on the volcano's southern flank, which were produced by successive flows generated during and after the major dome-collapse event on June 14. Both, single pulse (post-June 14 events) and multiple-pulse pyroclastic flows generated by sustained dome collapses on June 14 are recognised and three types of deposits, spread over an area of 4.7 km², are distinguished, totalling 13.3 × 106 m3: (1) valley-confined basal avalanche deposits (11.7 × 106 m3) in the Gendol River valley, (2) overbank pyroclastic-flow and associated surge deposits (1.4 × 106 m3), where parts of the basal avalanche spread laterally onto interfluves and were subsequently channeled into the surrounding river valleys and (3) dilute ash-cloud surge deposits (0.2 × 106 m3) along valley margins. Variations in the distribution, surface morphology and lithology of the deposits are related to the source materials involved in individual pyroclastic-flow-forming events and varying modes of transport and deposition of the different flows. Inferred flow velocities of the largest block-and-ash flows generated on June 14 vary from 43.8–13.5 m/s for the basal avalanche and from 62.6–24.2 m/s for the ash-cloud surge. The minimum temperatures range from 400 °C for the basal avalanche to 165 °C for the overlying ash cloud. Due to the potential of being re-channeled into adjacent river valleys and flowing laterally away from the main river channel, the overbank pyroclastic flows are considered the most hazardous part of the block-and-ash flow system. The conditions that lead to their development during flow transport and deposition must be taken into account when assessing future pyroclastic flow hazards at Merapi and similar volcanoes elsewhere.  相似文献   

5.
Carrying assorted cargo and covered with paints of varying toxicity, lost intermodal containers may take centuries to degrade on the deep seafloor. In June 2004, scientists from Monterey Bay Aquarium Research Institute (MBARI) discovered a recently lost container during a Remotely Operated Vehicle (ROV) dive on a sediment-covered seabed at 1281 m depth in Monterey Bay National Marine Sanctuary (MBNMS). The site was revisited by ROV in March 2011. Analyses of sediment samples and high-definition video indicate that faunal assemblages on the container’s exterior and the seabed within 10 m of the container differed significantly from those up to 500 m. The container surface provides hard substratum for colonization by taxa typically found in rocky habitats. However, some key taxa that dominate rocky areas were absent or rare on the container, perhaps related to its potential toxicity or limited time for colonization and growth. Ecological effects appear to be restricted to the container surface and the benthos within ∼10 m.  相似文献   

6.
The glassfish, Ambassis jacksoniensis, is a key, mid-level species in an estuarine food web on the east coast of Australia. Estuaries are subject to contamination from urban and industrial activities. The biokinetics of Cd, Se and Zn accumulation by glassfish from water and food were assessed using radioisotopes. Metal uptake from water was not regulated over the range of water metal concentrations examined. Metal uptake from food was assessed using brine shrimp (Artemia sp.) fed radio-labelled algae. The assimilation efficiency from food was 9.5 ± 2.5%, 23 ± 2.2% and 4.6 ± 0.6% for Cd, Se and Zn, respectively. The potential for biomagnification was low for all metals. Food is the main metal uptake pathway for glassfish, with 97%, 99% and 98% of the uptake of Cd, Se and Zn, respectively, estimated to be from food.  相似文献   

7.
Beach profile data, collected twice per year at 19 stations over a 25 km length of coastline in Tremadoc Bay, have been analysed to quantify the inter-annual variability in beach levels over a 7 year period and the results compared against the output of a numerical model. Using hourly wind data as forcing, the morphological development of northern Tremadoc Bay was simulated by wave, tidal, longshore transport, total transport and bed level change models. The modelling methodology was efficient and innovative, allowing realistic simulations of long duration with a time step of 1 h, hence capturing the high frequency nature of wind events. The model was run for each of the 7 autumn/winter periods (generally November–April) and the modelled net change in beach levels compared with the data from all 19 stations. The model results had reasonable agreement with the beach profile surveys. However, the observed magnitude of bed level change in the bay lagged the model output by 1 year, indicating that sediment processes acting over a larger area are important in a relatively localised study of inter-annual variability.  相似文献   

8.
The National Airborne Field Experiment 2006 (NAFE’06) was conducted during a three week period of November 2006 in the Murrumbidgee River catchment, located in southeastern Australia. One objective of NAFE’06 was to explore the suitability of the area for SMOS (Soil Moisture and Ocean Salinity) calibration/validation and develop downscaling and assimilation techniques for when SMOS does come on line. Airborne L-band brightness temperature was mapped at 1 km resolution 11 times (every 1–3 days) over a 40 by 55 km area in the Yanco region and 3 times over a 40 by 50 km area that includes Kyeamba Creek catchment. Moreover, multi-resolution, multi-angle and multi-spectral airborne data including surface temperature, surface reflectance (green, read and near infrared), lidar data and aerial photos were acquired over selected areas to develop downscaling algorithms and test multi-angle and multi-spectral retrieval approaches. The near-surface soil moisture was measured extensively on the ground in eight sampling areas concurrently with aircraft flights, and the soil moisture profile was continuously monitored at 41 sites. Preliminary analyses indicate that (i) the uncertainty of a single ground measurement was typically less than 5% vol. (ii) the spatial variability of ground measurements at 1 km resolution was up to 10% vol. and (iii) the validation of 1 km resolution L-band data is facilitated by selecting pixels with a spatial soil moisture variability lower than the point-scale uncertainty. The sensitivity of passive microwave and thermal data is also compared at 1 km resolution to illustrate the multi-spectral synergy for soil moisture monitoring at improved accuracy and resolution. The data described in this paper are available at www.nafe.unimelb.edu.au.  相似文献   

9.
Samples of the polychaete Chaetopterus variopedatus, worm tubes, commensal crab Polyonyx gibbesi and sediments were collected in eight sites in Todos os Santos Bay, Brazil, in order to evaluate the potential use of the polychaetes and crabs as biomonitors and to assess the relationships and accumulation of trace and major elements in different benthic compartments. Trace and major elements were determined by ICP OES. Organic carbon, total nitrogen and sulfur were determined by CNS elemental analyser. Tubes, crabs and polychaetes were important in the retention of trace and major elements. Metals that presented the highest accumulation in polychaetes (i.e. Mg > Al > Fe > Zn > Mn > Co > Cu > Ba > Cr) where the same for crabs (i.e. Mg > Al > Fe > Mn > Co > Zn > Cu > Ba > Cr). High concentrations of Al, Ba, Cr, Mn and Fe, from terrigenous sources, were observed in tubes, which presented accumulation factors up to 81.5 for Mn. Sedentary polychaetes are seen as good biomonitor alternatives for metal contamination studies, because they are one of the most abundant taxon in the benthic system, live in direct contact with sediments, are present in broad distributions and can also handle relatively high concentrations of metals ensuring chronic exposition. The possibility to work with not only the polychaete but also its tube offers advantages compared to bivalves that generally do not accumulate certain metals in very high levels.  相似文献   

10.
The threats of wide-scale coral bleaching and reef demise associated with anthropogenic climate change are widely known. Here, the additional role of poor water quality in lowering the thermal tolerance (i.e. bleaching ‘resistance’) of symbiotic reef corals is considered. In particular, a quantitative linkage is established between terrestrially-sourced dissolved inorganic nitrogen (DIN) loading and the upper thermal bleaching thresholds of inshore reefs on the Great Barrier Reef, Australia. Significantly, this biophysical linkage provides concrete evidence for the oft-expressed belief that improved coral reef management will increase the regional-scale survival prospects of corals reefs to global climate change. Indeed, for inshore reef areas with a high runoff exposure risk, it is shown that the potential benefit of this ‘local’ management imperative is equivalent to ∼2.0-2.5 °C in relation to the upper thermal bleaching limit; though in this case, a potentially cost-prohibitive reduction in end-of-river DIN of >50-80% would be required. An integrated socio-economic modelling framework is outlined that will assist future efforts to understand (optimise) the alternate tradeoffs that the water quality/coral bleaching linkage presents.  相似文献   

11.
The vertical distribution of trace metals in sediment cores was investigated to evaluate the extent and the historical record of metal pollution over 30 years in the artificial Lake Shihwa in Korea. A marked increase of trace metals after 1980 was observed due to the operation of two large industrial complexes and dike construction for a reclamation project. There was a decreasing trend of metal concentrations with the distance from the pollution source. The enrichment factor and pollution load index of the metals indicated that the metal pollution was mainly derived from Cu, Zn and Cd loads due to anthropogenic activities. The concentrations of Cr, Ni, Cu, Zn, As and Pb in the upper part of all core sediments exceeded the ERL criteria of NOAA. Our results indicate that inadequate planning and management of industrialization and a large reclamation project accomplished by dike construction have continued to strongly accelerate metal pollution in Lake Shihwa.  相似文献   

12.
Sediment transport and the potential for erosion or deposition have been investigated on the Palos Verdes (PV) and San Pedro shelves in southern California to help assess the fate of an effluent-affected deposit contaminated with DDT and PCBs. Bottom boundary layer measurements at two 60-m sites in spring 2004 were used to set model parameters and evaluate a one-dimensional (vertical) model of local, steady-state resuspension, and suspended-sediment transport. The model demonstrated skill (Brier scores up to 0.75) reproducing the magnitudes of bottom shear stress, current speeds, and suspended-sediment concentrations measured during an April transport event, but the model tended to underpredict observed rotation in the bottom-boundary layer, possibly because the model did not account for the effects of temperature–salinity stratification. The model was run with wave input estimated from a nearby buoy and current input from four to six years of measurements at thirteen sites on the 35- and 65-m isobaths on the PV and San Pedro shelves. Sediment characteristics and erodibility were based on gentle wet-sieve analysis and erosion-chamber measurements. Modeled flow and sediment transport were mostly alongshelf toward the northwest on the PV shelf with a significant offshore component. The 95th percentile of bottom shear stresses ranged from 0.09 to 0.16 Pa at the 65-m sites, and the lowest values were in the middle of the PV shelf, near the Whites Point sewage outfalls where the effluent-affected layer is thickest. Long-term mean transport rates varied from 0.9 to 4.8 metric tons m−1 yr−1 along the 65-m isobaths on the PV shelf, and were much higher at the 35-m sites. Gradients in modeled alongshore transport rates suggest that, in the absence of a supply of sediment from the outfalls or PV coast, erosion at rates of ∼0.2 mm yr−1 might occur in the region southeast of the outfalls. These rates are small compared to some estimates of background natural sedimentation rates (∼5 mm yr−1), but do not preclude higher localized rates near abrupt transitions in sediment characteristics. However, low particle settling velocities and strong currents result in transport length-scales that are long relative to the narrow width of the PV shelf, which combined with the significant offshore component in transport, means that transport of resuspended sediment towards deep water is as likely as transport along the axis of the effluent-affected deposit.  相似文献   

13.
This paper examines concentrations of trace contaminants in oysters placed in inshore and offshore waters before and after the change to offshore disposal of sewage near Sydney, NSW, Australia. The ability to compare inshore and offshore concentrations before and after the event allows the formulation of unconfounded conclusions about the impact of sewage on the availablity of trace contaminants in the coastal environment and the effect of the change in the method of disposal of Sydney's sewage on the availability of those contaminants.

The data show clearly that the diversion of sewage from nearshore to offshore areas has resulted in a significant drop in the concentrations of organochlorines in oysters deployed near sewage outfalls in the nearshore region. In offshore areas, there were no differences detected among regions prior to the commissioning of deepwater outfalls. In the post commissioning period there were a number of instances when trace metal concentrations in the regions were different from each other, but these differences were not correlated with proximity to the sewage outfalls nor was a particular metal consistently elevated, so it was concluded that the causes of difference were not related to the presence of the sewage outfalls.

This study has demonstrated that oysters were useful indicators of trace metal and organochlorine contamination of marine waters; that relatively high levels of contamination of inshore waters near sewage outfalls prior to deepwater sewage disposal were reduced, to be not different from other parts of Sydney's coastline after the commencement of deepwater discharge, and that there was no concommitant increase in accumulation of contaminants in offshore waters. Further, preliminary indications are that Sydney's coastal waters are not very heavily contaminated by trace contaminants in comparison to areas of NSW with much lower levels of development. Concentrations of organochlorines are, however, high in comparison to data from similarly developed areas of the USA.  相似文献   


14.
Ecotoxicological studies, using the tropical marine diatom, Nitzschia closterium (72-h growth rate), were undertaken to assess potential issues relating to the discharge from an alumina refinery in northern Australia. The studies assessed: (i) the species’ upper thermal tolerance; (ii) the effects of three signature metals, aluminium (Al), vanadium (V) and gallium (Ga) (at 32 °C); and (iii) the effects of wastewater (at 27 and 32 °C). The critical thermal maximum and median inhibition temperature for N. closterium were 32.7 °C and 33.1 °C, respectively. Single metal toxicity tests found that N. closterium was more sensitive to Al compared to Ga and V, with IC50s (95% confidence limits) of 190 (140-280), 19,640 (11,600-25,200) and 42,000 (32,770-56,000) μg L−1, respectively. The undiluted wastewater samples were of low toxicity to N. closterium (IC50s > 100% wastewater). Environmental chemistry data suggested that the key metals and discharge are a very low risk to this species.  相似文献   

15.
Long-term historical records of rainfall (P), runoff (Q) and other climatic factors were used to investigate hydrological variability and trends in the Volta River Basin over the period 1901-2002. Potential (Ep) and actual evaporation (E), rainfall variability index (δ), Budyko’s aridity index (IA), evaporation ratio (CE) and runoff ratio (CQ) were estimated from the available hydroclimatological records. Mann-Kendall trend analysis and non-parametric Sen’s slope estimates were performed on the respective time series variables to detect monotonic trend direction and magnitude of change over time.Rainfall variability index showed that 1968 was the wettest year (δ = +1.75) while 1983 was the driest (δ = −3.03), with the last three decades being drier than any other comparable period in the hydrological history of the Volta. An increase of 0.2 mm/yr2 (P < 0.05) was observed in Ep for the 1901-1969 sub-series while an increased of 1.8 mm/yr2 (P < 0.01) was recorded since 1970. Rainfall increased at the rate of 0.7 mm/yr2 or 49 mm/yr between 1901 and 1969, whereas a decrease of 0.2 mm/yr2 (6 mm/yr) was estimated for 1970-2002 sub-series. Runoff increased significantly at the rate of 0.8 mm/yr (23 mm/yr) since 1970. Runoff before dam construction was higher (87.5 mm/yr) and more varied (CV = 41.5%) than the post-dam period with value of 73.5 mm/yr (CV = 23.9%). A 10% relative decrease in P resulted in a 16% decrease in Q between 1936 and 1998. Since 1970, all the months showed increasing runoff trends with significant slopes (P < 0.05) in 9 out of the 12 months. Possible causes, such as climate change and land cover change, on the detected changes in hydroclimatology are briefly discussed.  相似文献   

16.
Organotins, especially tributyltins (TBT) are highly toxic to many marine organisms. These compounds are introduced in marine waters by ship trafficking, ship scrapping activities, as antifouling compounds and sewage disposal. Marine fishes, crustaceans and molluscans are easily prone to organotins contamination. In view of this, a baseline monitoring study was conducted in order to establish the levels of organotins in edible marine fishes, bivalves, shrimps, squids and crabs collected from Mumbai, Goa and Karwar on the west coast of India. At these locations average organotin concentration found in fishes, clams, shrimps, squids and crabs was 108, 852, 179, 70 and 89 ng Sn g−1 dw, respectively. In all the samples butyltins dominated over phenyltins. The levels of organotins suggest that all the organisms were contaminated with organotins and their consumption may pose health problems to humans.  相似文献   

17.
Using in situ, continuous, high frequency (8–16 Hz) measurements of velocity, suspended sediment concentration (SSC), and salinity, we investigate the factors affecting near-bed sediment flux during and after a meteorological event (cold front) on an intertidal flat in central San Francisco Bay. Hydrodynamic forcing occurs over many frequency bands including wind wave, ocean swell, seiching (500–1000 s), tidal, and infra-tidal frequencies, and varies greatly over the time scale of hours and days. Sediment fluxes occur primarily due to variations in flow and SSC at three different scales: residual (tidally averaged), tidal, and seiching. During the meteorological event, sediment fluxes are dominated by increases in tidally averaged SSC and flow. Runoff and wind-induced circulation contribute to an order of magnitude increase in tidally averaged offshore flow, while waves and seiching motions from wind forcing cause an order of magnitude increase in tidally averaged SSC. Sediment fluxes during calm periods are dominated by asymmetries in SSC over a tidal cycle. Freshwater forcing produces sharp salinity fronts which trap sediment and sweep by the sensors over short (∼30 min) time scales, and occur primarily during the flood. The resulting flood dominance in SSC is magnified or reversed by variations in wind forcing between the flood and ebb. Long-term records show that more than half of wind events (sustained speeds of greater than 5 m/s) occur for 3 h or less, suggesting that asymmetric wind forcing over a tidal cycle commonly occurs. Seiching associated with wind and its variation produces onshore sediment transport. Overall, the changing hydrodynamic and meteorological forcing influence sediment flux at both short (minutes) and long (days) time scales.  相似文献   

18.
Winter observations of shelf and slope hydrography and currents in the inner Gulf of Tehuantepec are analysed from two field studies in 1989 and 1996 to specify the variability of near-shore conditions under varying wind stress. During the winter period frequent outbursts of ‘Norte’ winds over the central Gulf result in persistent alongshore inflows along both its eastern and western coasts. Wind-induced variability on time scales of several days strongly influences the shelf currents, but has greater effect on its western coast because of the generation and separation of anticyclonic eddies there. The steadier inflow (∼0.2 m s−1) on the eastern shelf is evident in a strong down-bowing of shallow isosurfaces towards the coast within 100 km of shore, below a wedge of warmer, fresher and lighter water. This persistent entry of less saline (33.4–34.0), warmer water from the southeast clearly originates in buoyancy input by rivers along the Central American coast, but is augmented by a general shoreward tendency (0.2 m s−1) in the southeastern Gulf. The resultant shallow tongue of anomalous water is generally swept offshore in the head of the Gulf and mixed away by the strong outflow and vertical overturning of the frequent ‘Norte’ events but during wind relaxations the warm, low-salinity coastal flow may briefly extend further west. In the head of the Gulf, flow is predominantly offshore (<0.2 m s−1) as the alongshore component alternates eastward and westward in association with elevation or depression, respectively, of the pycnocline against the shore. More saline, open ocean water is introduced from the north-western side of the Gulf by the inflow along the west coast. During extended wind relaxations, the flow becomes predominantly eastward beyond the shelf while nearshore the coastally trapped buoyant inflow from the southeast penetrates across the entire head of the gulf at least as far as its western limit. On the basis of these and other recent observations, it seems that the accepted view of a broad, persistent Costa Rica Coastal Current (CRCC) is the result of averaging over many relatively sparse observations and that the instantaneous CRCC is a highly variable and convoluted flow around and between constantly changing eddies. The buoyancy-driven shelf current reported here forms a hitherto unrecognized, but major, component of this CRCC system.  相似文献   

19.
The growth of maritime transport and oil exploitation activities may increase the risk of oil spills. Thus, plans and actions to prevent or mitigate impacts are needed to minimize the effects caused by oil. However, tools used worldwide to support contingency plans have not been integrated, thus leading to failure in establishing priority areas. This investigation aimed to develop indices of environmental vulnerability to oil (IEVO), by combining information about environmental sensibility to oil and results of numerical modeling of spilled oil. To achieve that, a case study concerning to oil spills scenarios in a subtropical coastal area was designed, and IEVOs were calculated and presented in maps, in order to make the information about the areas’ vulnerability more easily visualized. For summer, the extension of coastline potentially affected by oil was approximately 150 km, and most of the coastline presented medium to high vulnerability. For winter, 230 km coastline would be affected, from which 75% were classified as medium to high vulnerability. Thus, IEVO maps allowed a rapid and clearer interpretation of the vulnerability of the mapped region, facilitating the planning process and the actions in response to an oil spill.  相似文献   

20.
Sub-inertial across-shelf flows over the central mid-Atlantic Bight were examined using long-range CODAR SeaSonde type HF-radar surface velocities for the period August 2002 through February 2004. Across-shelf flow in this region was found to be episodic, with offshore flow occurring six times more often than onshore flow. Several recurring spatial patterns in offshore flow are identified, and two of these patterns emerge as statistically significant using empirical orthogonal functions. The most common type of offshore flow was a shelf-wide flow with events occurring throughout the year. The most energetic and well-defined shelf-wide flow events occurred during October through April, when the water column was less stratified. Other offshore flow patterns were more localized, with a flow at the bend or ‘point’ in the New Jersey coast being most common and most energetic. The offshore flow events identified here are capable of driving significant offshore transport, with more than one-third of offshore flow episodes having potential transport distances of greater than 14 km. In addition, clusters of multiple offshore flow events are shown to be capable of transporting near-surface material across much of the continental shelf.  相似文献   

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