Reduction of oil outflows at collisions and groundings through improved vessel design arrangement

The paper discusses active and passive methods of reducing the expected oil outflow from collision and grounding accidents. Active measures refer to actions or decisions taken at the time of an accident, while passive measures refer to features built into the design of the ship. Except in cases of large tides, passive measures appear most efficient in reducing the oil spill rates from collision and grounding accidents. The measures discussed in this study include:

• • main hull design and tank arrangement;

• • structural resistance of hull; and

• • other features, like vacuum systems, piping systems for automatic redistribution of oil in case of pressure drop in tanks.

Only the influence of the main hull design and tank arrangement on the oil outflow has been analysed in detail. A probabilistic outflow model, which simulates damage cases in accordance with observed data from collision and grounding accidents, has been used for a parameter study of the oil spills from a double hull tanker of 280 000 DWT. This has established the optimum position of longitudinal bulkheads to minimize the outflow rates, the variation of the outflow volumes with tank length (number of oil tanks) and the effect of altering main particulars or hull slenderness on outflow rates. Further simplified models are used to assess how these variations in main hull design and tank arrangement will affect the steel weights and associated costs of the analysed designs. The results reveal that a considerable reduction of the pollution risk may be achieved by careful modification of main particulars and tank sizes compared to current design practice.     

Effect of an oil spill from M V Sea Transporter on intertidal meiofauna at Goa,India

Short and long term effects of a fuel oil spill from a grounded ship "M V Sea Transporter" on meiofauna of a sandy beach of central West Coast of India were investigated. A significant reduction in the absolute abundance of meiofauna was observed immediately after 3 days of spillage particularly at Sinquerim beach, the site of spillage. The reduction was most pronounced in density of nematodes and harpacticoid copepods, which were the most dominant groups. Long-term response showed no apparent oil-induced changes at major taxa levels. The population density improved considerably after the cessation of monsoons with a parallel decrease in petroleum hydrocarbon concentration in the sediment. Nematodes recovered more quickly than benthic copepods. No evidence for this could be due to reproductive dynamics in meiobentos. Although the effect of the oil on meiofauna could be seen initially it could not be proved conclusively on a long-term basis. The effects of the oil spill were confounded with seasonal monsoon effects and beach dynamics. The nematode:copepod ratio and the index of trophic diversity (ITD) were inadequate for detecting oil pollution effects. Therefore it may be concluded that in the presence of other environmental factors acting strongly, the effects of oil on meiofauna was strong but of a temporary nature.     

Sea transport of animal and vegetable oils and its environmental consequences

The increasing production––and therefore sea traffic––of vegetable oils has regularly led to spillages during the past 40 years. The accident of Allegra, on October,1st, 1997, in the English Channel gave rise to a spillage of 900 tonnes of palm nut oil. The drift of this solid vegetable oil was followed by aerial observations. Samples of oil were collected in order to analyse its chemical evolution. This study, associated with several bibliographic cases of pollution by non-petroleum oils, shows that drifting oils can mix with floating material to sink or form a crust. They can also be oxidized or disperse and/or be degraded by bacteria. They may also polymerise. The coating properties of vegetable oils act as crude oils to affect sea life, tourism and yachting. As a result, it is necessary to quickly collect the oil after a spillage, using usual equipment (booms and pumps).     

A study on the treatment of antifouling paint waste from shipyard

A study on the treatment of antifouling paint waste from shipyards, including sandblast waste and ship hull washing wastewater, was performed. The sandblast waste could be effectively detoxified by heat treatment, and the efficiency was affected by the temperature of the heating vessel and treatment time. The removal efficiency of total organotin compounds from the sandblast waste was over 99% at 1000 °C and treatment for 1 h. For the treatment of ship hull washing wastewater by the solvent extraction, ship diesel was a good solvent for the tributyltin (TBT) extraction, and the proper amount of solvent was about 10 mL for TBT extraction from 1 L of wastewater. The extraction efficiency of TBT was significantly affected by the agitation intensity. The TBT in the wash wastewater was rapidly extracted within 1 h. The level of the TBT residual in the wastewater extracted for 1 h was 2.8 μg L⁻¹, and this was further decreased to 0.8 after 5 h extraction.     

Polycyclic aromatic hydrocarbon (PAHs) and hopanes in stranded tar-balls on the coasts of Peninsular Malaysia: applications of biomarkers for identifying sources of oil pollution

Malaysian coasts are subjected to various threats of petroleum pollution including routine and accidental oil spill from tankers, spillage of crude oils from inland and offshore oil fields, and run-off from land-based human activities. Due to its strategic location, the Straits of Malacca serves as a major shipping lane. This paper expands the utility of biomarker compounds, hopanes, in identifying the source of tar-balls stranded on Malaysian coasts. 20 tar-ball samples collected from the east and west coast were analyzed for hopanes and polycyclic aromatic hydrocarbons (PAHs). Four of the 13 tar-ball samples collected from the west coast of Peninsular Malaysia were identified as the Middle East crude oil (MECO) based on their biomarker signatures, suggesting tanker-derived sources significantly contributing the petroleum pollution in the Straits of Malacca. The tar-balls found on the east coast seem to originate from the offshore oil platforms in the South China Sea. The presence of South East Asian crude oil (SEACO) tar-balls on the west coast carry several plausible explanations. Some of the tar-balls could have been transported via sea currents from the east coast. The tankers carrying SEACO to other countries could have accidentally spilt the oil as well. Furthermore, discharge of tank washings and ballast water from the tankers were suggested based on the abundance in higher molecular weight n-alkanes and the absence of unresolved complex mixture (UCM) in the tar-ball samples. The other possibilities are that the tar-balls may have been originated from the Sumatran oil fields and spillage of domestic oil from oil refineries in Port Dickson and Malacca. The results of PAHs analysis suggest that all the tar-ball samples have undergone various extent of weathering through evaporation, dissolution and photo-oxidation.     

Concept design and hydrodynamic optimization of an innovative SWATH USV by CFD methods

The paper presents the main characteristics of an innovative platform which has been conceived and designed to extend the operational capabilities of current unmanned surface vehicles in terms of platform stability in waves and of powering requirement at a relatively high speed. The main idea which rules the project is the realization of a small autonomous surface unit (about 6 m in length) capable of undertaking several tasks in the marine environment even with moderate rough sea conditions. The designed vessel has the ability to locate, recover, and launch other members of the autonomous fleet (like AUVs or other underwater devices) and at the same time could carry out a surveillance service of the surrounding areas. To manage these tasks, the vehicle is designed to provide a fairly good autonomy which is needed to face intermediate-range missions (100 nautical miles). The choice of a small waterplane area twin hull (SWATH) form has been motivated by its excellent properties of seakeeping qualities, combined with a non-conventional low resistance underwater hull shape, currently under patenting process, which is able to reduce to a minimum the resistance of the vessel especially at higher speeds. To obtain the most efficient profile of the underwater bodies, a systematic optimization with an automatic procedure based on a parametric definition of the geometry, a state-of-the-art computational fluid dynamics (CFD) flow solver, and a differential evolution global minimization algorithm have been created and used. As expected, all the final CFD computations on the best design have demonstrated the superior efficiency of the developed unconventional SWATH technology with respect to different alternatives of current hull typologies.     

Quantifying potential propagule pressure of aquatic invasive species from the commercial shipping industry in Canada

We quantify and compare different measures of potential propagule pressure (PPP) of aquatic invasive species (AIS) from commercial vessels in Canada. We used ship arrivals and ballast water discharge volumes as proxies for PPP from ballast water organisms, and wetted surface area (WSA) as a proxy for hull fouling PPP, to determine their relative contributions to total PPP. For three regions studied, PPP proxies correlated significantly across ports and some vessel categories. Relative contributions of ship arrivals, ballast discharge, and WSAs to PPP, evidenced by non-significant correlations across these measures, varied across regions, ports, vessel types, and seasons. Flow-through (dominant on east and west coasts) and empty-refill (in Great Lakes-St. Lawrence region) were the major ballast water exchange methods employed by the vessels surveyed. These methods have different biological efficacy for AIS removal, influencing PPP. Our study illustrates benefits and limitations of using different PPP proxies to estimate invasion risk.     

Prevention of oil spill from shipping by modelling of dynamic risk

This paper presents a new dynamic environmental risk model, with intended use within a new, dynamical approach for risk based ship traffic prioritisation. The philosophy behind this newly developed approach is that shipping risk can be reduced by directing efforts towards ships and areas that have been identified as high priority (high risk), prior to a potential accident. The risk model proposed in this paper separates itself from previous models by drawing on available information on dynamic factors and by focusing on the ship's surroundings. The model estimates the environmental risk of drift grounding accidents for oil tankers in real time and in forecast mode, combining the probability of grounding with oil spill impact on the coastline. Results show that the inherent dynamic risk introduced by an oil tanker sailing along the North Norwegian coast depends, not surprisingly, significantly upon wind and ocean currents, as well as tug position and cargo oil type. Results of this study indicate that the risk model is well suited for real time risk assessment, and effectively separates low risk and high risk situations. The model is well suited as a tool to prioritise oil tankers and coastal segments. This enables dynamic risk based positioning of tugs, using both real-time and projected risk, for effective support in case of a drifting ship situation.     

Observations on surface pollution in the Indian Ocean and South China Sea during the Sindbad Voyage (1980–1981)

Analysis of 159 visual observations on tar balls, oil slicks and other surface pollutants in the Indian Ocean and South China Sea form the basis of this study. Observations were made between November 1980 and June 1981 aboard a replica of an ancient Arab sailing vessel, Sohar, during the ‘Sindbad Voyage’. The vessel, being both small and slow-moving, provided an almost ideal platform from which to make visual observations on surface pollution. Tar balls were encountered in more than 20% of the observations, and show a progressive increase in occurrence from Malaysia/Indonesia (<15%) towards the Gulf region (>60%). In contrast, oil slicks and other forms of surface pollution were encountered less frequently. The results are discussed in the light of observations made during the Marine Pollution [Petroleum] Monitoring Pilot Project (MAPMOPP).     

Pollution and the offshore oil industry

Exploration and exploitation of the North Sea oil field has caused a good deal of concern about the possibility of major pollution. Three major accidents to offshore wells are examined to discover the risk and likely consequences of a blow-out in the North Sea.     

Ground Water Contamination in Kuwait Resulting from the 1991 Gulf War: A Preliminary Assessment

A large number of oil wells in Kuwait were damaged and ignited by the retreating Iraqi troops during the 1991 Gulf War. The resulting spillage of huge volumes of crude oil on the surface gave rise to oil lakes and crude oil–impregnated soil. Moreover, products of crude oil combustion had spread over a large tract of the ground surface, causing widespread contamination of soil. Hydrocarbon contamination of ground water by the infiltrating runoff water carrying the contaminants from the surface soil to the water table and/or through direct contact with the crude oil leaking through the damaged casing in the subsurface was feared. This preliminary study was carried out to investigate the extent and nature of this possible contamination of ground water. The results indicate that the shallow fresh water lenses present under the Umm Al-Aish water field and in the southeastern parts of the Raudhatain water field in North Kuwait were affected by hydrocarbon pollution. Standard methods like the determination of the contents of the total petroleum hydrocarbon by the Fourier transform infrared method and 16 polyaromatic hydrocarbons using the gas chromatography-mass spectrometry method did not work well, possibly due to the environmental degradation of the crude oil over time. The fluorescence methods and the total organic carbon and total organic matter gave better indications of the intensity and the extent of ground water pollution. The brackish water fields of South and Central Kuwait were, however, free of any indications of hydrocarbon contamination.     

Superoleophillic electrospun polystrene/exofoliated graphite fibre for selective removal of crude oil from water

During oil spills, the aquatic environment is greatly endangered because oil floats on water making the penetration of sunlight difficult therefore primary productivity is compromised, birds and aquatic organisms are totally eliminated within a short period. It is therefore essential to remove the oil from the water bodies after the spillage. This work reports on the fabrication of oil loving electrospun polystyrene-exofoliated graphite fibre with hydrophobic and oleophillic surface properties. The fibre was applied for the selective adsorption of crude oil from simulated crude oil spillage on water. The maximum oil adsorption capacity of the EPS/EG was 1.15 kg/g in 20 min while the lowest oil adsorption capacity was 0.81 kg/g in 10 min. Cheap oil adsorbent was developed with superoleophillic and superhydrophobic properties.     

The effect of oil pollution on the reproduction and feeding behaviour of the sea anemone Actinia equina

The effects of oil pollution on the sea anemone Actinia equina were investigated. Chronic pollution with 2.5 ml.l^?1 crude oil resulted, for about seven weeks, in ejection of increased numbers of the young which are normally brooded within the gastric cavity. Subsequently the numbers of surviving young being produced fell to zero, and the ovaries were found to be regressed and lacking ova. The anemones were also more frequently observed with tentacles expanded and mouth open, but the response to food offered to the tentacles was slow or absent. In separate tests it was found that crude oil presented on filter paper to the anemones could act as a feeding inducer, but that it interfered with or diluted the action of natural feeding inducers present in fish muscle extract. These effects are comparable with those which oil pollution has been found by other workers to have upon other anthozoans—the corals.     

The Dona Marika oil spill

Last August, 3,000 tons of petrol (gasolene) was spilled in Milford Haven when the tanker, Dona Marika, ran aground. Since most documented oil spills in British waters have been of crude oil, there is considerable interest in knowing the damage caused by this spillage of a refined oil product.     

Nanoporous polystyrene fibers for oil spill cleanup

The development of oil sorbents with high sorption capacity, low cost, scalable fabrication, and high selectivity is of great significance for water environmental protection, especially for oil spillage on seawater. In this work, we report nanoporous polystyrene (PS) fibers prepared via a one-step electrospinning process used as oil sorbents for oil spill cleanup. The oleophilic-hydrophobic PS oil sorbent with highly porous structures shows a motor oil sorption capacity of 113.87 g/g, approximately 3-4 times that of natural sorbents and nonwoven polypropylene fibrous mats. Additionally, the sorbents also exhibit a relatively high sorption capacity for edible oils, such as bean oil (111.80 g/g) and sunflower seed oil (96.89 g/g). The oil sorption mechanism of the PS sorbent and the sorption kinetics were investigated. Our nanoporous material has great potential for use in wastewater treatment, oil accident remediation and environmental protection.     

Chemical contamination of a coral reef by the grounding of a cruise ship in Bermuda

Bulk metal analyses of surficial sediments collected around the Norwegian Crown cruise ship grounding site in Bermuda indicated significant but localized contamination of reef sediments by copper and zinc, caused by the stripping of the tri-butyltin (TBT)-free antifouling (AF) paint (Intersmooth 460) from the underside of the hull. Highest copper and zinc values were found in heavily compacted and red-pigmented sediments inside the impact scar and were comparable to levels found close to slip ways of local boat yards where AF paints from hull stripping and cleaning processes are washed into the sea. The re-distribution of AF contaminated sediments by storms and deposition on nearby reefs constitutes a significant ecological risk that could delay recovery processes and reduce the effectiveness of remediation efforts. Whilst the ecotoxicological effects of AF paint particles interspersed with sediment is unknown, and in need of further study, it is argued that the significance of AF paint contamination of grounding sites has been overlooked.     

Model-based long-term reconstruction of weather-driven variations in chronic oil pollution along the German North Sea coast

Lagrangian passive tracer transport simulations covering the 46-year period 1958-2003 were utilized to compare the exposures of different parts of the German North Sea coast to ship-related chronic oil pollution. Assuming the spatial distribution of oil releases to be proportional to estimated ship traffic density, detailed drift reconstructions allowed for the reconstruction of wind-induced inter-annual variations in coastal pollution. For the winter months, a statistical relationship between simulated advective transports and prevailing sea surface pressure fields was established via Canonical Correlation Analysis. Wind effects were found to be more important for the northern (Schleswig-Holstein) than for the southern (Lower Saxony) part of the German North Sea coast. For Schleswig-Holstein, simulations showed consensus with beached bird survey data from this region. Proper identification of weather-driven inter-annual and spatial variations in monitoring data helps to avert misjudgments with regard to trends in the general level of chronic oil pollution.     

An assessment of an oil spill in Gladstone, Australia – Impacts on intertidal areas at one month post-spill

In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments.Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.     

An assessment of an oil spill in Gladstone, Australia - impacts on intertidal areas at one month post-spill

In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments. Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.     

Acute toxicity of alkyl leads to some marine organisms

Following the wreck of the cargo ship Cavtat in the Adriatic Sea and the danger of pollution by alkyl lead antiknock compounds, the acute toxicity of alkyl leads to marine organisms at different trophic levels has been determined in the laboratory.