Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

Equifinality of formal (DREAM) and informal (GLUE) Bayesian approaches in hydrologic modeling?

In recent years, a strong debate has emerged in the hydrologic literature regarding what constitutes an appropriate framework for uncertainty estimation. Particularly, there is strong disagreement whether an uncertainty framework should have its roots within a proper statistical (Bayesian) context, or whether such a framework should be based on a different philosophy and implement informal measures and weaker inference to summarize parameter and predictive distributions. In this paper, we compare a formal Bayesian approach using Markov Chain Monte Carlo (MCMC) with generalized likelihood uncertainty estimation (GLUE) for assessing uncertainty in conceptual watershed modeling. Our formal Bayesian approach is implemented using the recently developed differential evolution adaptive metropolis (DREAM) MCMC scheme with a likelihood function that explicitly considers model structural, input and parameter uncertainty. Our results demonstrate that DREAM and GLUE can generate very similar estimates of total streamflow uncertainty. This suggests that formal and informal Bayesian approaches have more common ground than the hydrologic literature and ongoing debate might suggest. The main advantage of formal approaches is, however, that they attempt to disentangle the effect of forcing, parameter and model structural error on total predictive uncertainty. This is key to improving hydrologic theory and to better understand and predict the flow of water through catchments.     

Farmers’ awareness and perception of Lake Ziway (Ethiopia) and its watershed management

The article examines how heads of farmers’ households perceive the socioeconomic benefits of Lake Ziway (Ethiopia), the causes of its current degradation, and the state of land and water use management in its watershed. The investigation was based on in-depth empirical field work including a survey with 635 heads of smallholder farmers’ households via interview using semi-structured questionnaires. Further, water abstraction was estimated from three districts that border with the lake. Respondents believe that Lake Ziway provides a number of individual and collective benefits for local communities, private companies and public institution. They stated, however, that the lake is under pressure from the floriculture industry and other investment projects, high population growth and subsequent expansion of settlements and irrigation farms, high applications of agrochemicals, soil erosion, uncontrolled water abstraction, and deforestation in the watershed. The respondents further believe that these activities are degrading the lake water quality, shrinking its water volume and decreasing its fish population. After examining government’s efforts to address these activities, the majority of respondents believe that the government role in the whole watershed is weak. This study contributes to better understand the local socio-ecological coherences and the problems Lake Ziway and its watershed are facing. It also provides information regarding long-term sustainable land and water use planning strategies for the lake and management of its watershed, which could also be applied to other lakes in Ethiopia, and beyond.     

Crustal structure of Northwest Zagros (Kermanshah) and Central Iran (Yazd and Isfahan) using teleseismic Ps converted phases

Receiver functions are widely employed to detect P-to-S converted waves and are especially useful to image seismic discontinuities in the crust. In this study we used the P receiver function technique to investigate the velocity structure of the crust beneath the Northwest Zagros and Central Iran and map out the lateral variation of the Moho boundary within this area. Our dataset includes teleseismic data (M _b ≥ 5.5, epicentral distance from 30° to 95°) recorded at 12 three-component short-period stations of Kermanshah, Isfahan and Yazd telemetry seismic networks. Our results obtained from P receiver functions indicate clear Ps conversions at the Moho boundary. The Moho depths were firstly estimated from the delay time of the Moho converted phase relative to the direct P wave beneath each network. Then, we used the P receiver function inversion to find the properties of the Moho discontinuity such as depth and velocity contrast. Our results obtained from PRF are in good agreement with those obtained from the P receiver function modeling. We found an average Moho depth of about 42 km beneath the Northwest Zagros increasing toward the Sanandaj-Sirjan Metamorphic Zone and reaches 51 km, where two crusts (Zagros and Central Iran) are assumed to be superposed. The Moho depth decreases toward the Urmieh-Dokhtar Cenozoic volcanic belt and reaches 43 km beneath this area. We found a relatively flat Moho beneath the Central Iran where, the average crustal thickness is about 42 km. Our P receiver function modeling revealed a shear wave velocity of 3.6 km/s in the crust of Northwest Zagros and Central Iran increasing to 4.5 km/s beneath the Moho boundary. The average shear wave velocity in the crust of UDMA as SSZ is 3.6 km/s, which reaches to 4.0 km/s while in SSZ increases to 4.3 km/s beneath the Moho.     

The crustal fluid evolution and the causes of earthquakes(Ⅲ)

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Stability of arsenopyrite and As(III) in low-temperature acidic solutions

Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy…     

Seismic Intensity Zoning Map of China (1990) and Its Explanation

The Seismic Intensity Zoning Map of China(1990)was based on the probabilistic method of seismic hazard analysis.In compiling the map,the characteristics of inhomogeneity of earthquake distribution both in space and time in China are considered sufficiently,and some necessary modifications in the model of seismic hazard analysis are carried out.Based on the analysis of the seismic activity and seismotectonic environment,26 seismic provinces are divided first as the statistical elements of the seismicity analysis; the seismic potential source areas are then divided in the seismic provinces.The 733 potential source areas with various upper limit magnitudes have been divided in the country.According to the reliable time domain of earthquake data with various magnitude intervals,the b values in magnitude-frequency relationship are calculated in the seismic provinces.According to the analysis of the inhomogeneity of seismicity distribution both in space and time,the annual average occurrence rates of the eart     

Contrasting responses of oligochaetes (Annelida) and chironomids (Diptera) to the abatement of eutrophication in Lake Neuchâtel

: Lake Neuchâtel (Switzerland) has been recovering from human-induced eutrophication since 1982. Oligochaetes and chironomid larvae were used to monitor the recovery of sediment at a depth of 40 m. In oligochaete communities, the mean proportion of individuals belonging to species indicative of oligotrophic conditions (mostly Spirosperma velutinus and Stylodrilus heringianus) increased from 16 % in 1984 to 33 % in 1992, but decreased to 11 % in 1997. Based on oligochaetes, benthic conditions deteriorated in 1997 whereas, based on the increase of oligotrophic chironomids (mostly Micropsectra), they improved. This difference was attributed to the impact of large planktonic algae whose sedimentation had altered oxygen concentrations at the water-sediment interface. Oligochaetes were more affected than chironomids because they are less mobile and they depend more on the inner sediment for their food and reproduction than the latter. However, based on the combined response of oligochaetes and chironomids, benthic recovery was stalled in 1997 but was not reversed.     

Intercalibration of international and domestic ~(40)Ar/~(39)Ar dating standards

40Ar/39Ar method is a high precision dating means, of which the age is obtained by contrasting the un- known sample with those of standards. Usually the age of standard is determined by K-Ar method in which the 38Ar spike should be added for measurement. However, the absolute concentration of 38Ar spike is measured through the calibrated standards in turn, al- though occasionally the concentration of 38Ar spike is determined by other dating methods, such as Rb-Sr, U-Pb methods, which is kn…     

Measurements of biomarker levels in flounder (Platichthys flesus) and blue mussel (Mytilus trossulus) from the Gulf of Gdańsk (southern Baltic)

In the framework of the EU funded BEEP project a set of biomarkers, gross morphometric indices and tissue concentrations of selected organic pollutants were measured in flounder (Platichthys flesus) and mussels (Mytilus trossulus) collected twice a year (April and October) from three sites in the inner Gulf of Gdańsk between autumn 2001 and spring 2003. In flounder, seasonal differences in most biomarkers were observed, but no correlations with tissue pollutant levels could be found. In mussels, highly variable levels in biomarker responses were seen, but no clear seasonal or spatial trends, directly related to tissue concentrations, could be established. The observed biomarkers distribution the study sites are probably mostly caused by interannual, seasonal and individual variability and, in case of flounder, possibly by exchange of stocks between the sampling sites.     

Spatial and Temporal Dynamics of Sources and Water Regime of the Ugol’naya-Dionisiya River (Anadyr Lowland,Chukotka)

Water Resources - For the first time, by analyzing the spatial variations and diurnal dynamics of the water regime of the small river of the Anadyr Lowland, the main sources were studied and the...     

The Erzincan (Turkey) Earthquake (Ms 6.8) of March 13, 1992 and its Aftershock Sequence

—The Erzincan strike-slip earthquake of March 13, 1992 ruptured a section of the North Anatolian fault (NAF) at the northern margin of the Erzincan basin. The focal depth of about 10 km was less than given by ISC and NEIC. Erzincan and the surrounding villages were considerably damaged. In the Erzincan basin and in the neighbouring mountains a seismic network of ten stations was installed. It was operating continuously from March 21 through June 16, 1992. More than 3,000 aftershocks were recorded of which 505 could be located. The spectral parameters of 394 and the fault-plane solutions of 53 aftershocks were determined. For the given region the frequency dependent coda Q was derived as Q _c = 122 f ^0.68. The aftershock area increased with time, reflecting the process of stress redistribution. Some events clustered in the immediate vicinity of the town of Erzincan close to the epicentre of the main event and seem to trace the NAF. Their source mechanism is similar to that of the main event (strike slip). About 150 aftershocks clustered in the southeastern part of the Erzincan basin where a concentration of the events in a small volume of 5 × 5 × 3 km³ was observed. The majority of fault-plane solutions available for these aftershocks showed a normal faulting mechanism with an east-west directed extension. Most of the aftershocks southeast of the basin clustered between two lineaments that were mapped by satellite images. The P-wave velocity below the Erzincan basin, derived from travel-time residual analysis, is lower compared to areas NE and SW of the basin. Three-dimen sional stress modelling of the Erzincan region qualitatively explains the occurrence of the aftershocks southeast of the basin. The calculated displacement distribution which exhibits the north-westward motion of the basin and tension at its southeastern margin, caused by the Erzincan earthquake, is in agreement with derived fault-plane solutions.     

The co-transport of Cd(Ⅱ) and nZnO in saturated soil packed column:effects of ionic strength and pH

The rapid development and widespread use of ZnO nanoparticles(nZnO) in various industries have raised concerns about their potential environmental impact.Therefore,understanding the fate and role of nZnO in the natural environment is crucial for mitigating their hazardous effects on the environment and human safety.The purpose of the present study was to provide scientific support for understanding and eliminating the joint risk of nanoparticle and heavy metal pollution in the soil environment b...     

Disequilibria between ~(210)Po and ~(210)Pb in surface waters of the southern South China Sea and their implications

Naturally occurring 210Po (half-life 138.4d) is the granddaughter of 210Pb (half-life 22.3a), both are members of 238U decay series and have been inten-sively utilized to study kinetic aspects of material cy-cling in the ocean[1]. Based on radioactive disequilibria in the 226Ra-210Pb-210Po system, oceanographical processes with different timescales have been widely studied. Rama et al.[2] first detected excess 210Pb rela-tive to its precursor 226Ra in surface waters, and considered this exc…     

An EXAFS investigation of the mechanism of competitive sorption between Co(Ⅱ) and Ni(Ⅱ) at γ-alumina/solution interface

Co(Ⅱ)and Ni(Ⅱ)are two common toxic heavy metals,and may simultaneously exist in contaminated water,soil,and sediment systems in Earth’s surface environment.Under this circumstance,competitive adsorption between the two metals may influence their migration,toxicity,and bioavailability.In this research,the competitive sorption of Co(Ⅱ)and Ni(Ⅱ)on γ-Al_2O_3was studied using both macroscopic sorption experiments and extended X-ray absorption fine structure(EXAFS)spectroscopy.Results suggest that Ni(Ⅱ)reduced the amount of Co(Ⅱ)sorption in a binary-solute system at pH 6.0.This is because both Co(Ⅱ)and Ni(Ⅱ)form inner-sphere surface complexes during sorption on γ-Al_2O_3and compete for the surface reactive sites.However,Co(Ⅱ)exhibited a negligible influence on sorption amount of Ni(Ⅱ)under the same conditions,which suggests Ni(Ⅱ)has a stronger affinity to alumina surface.At pH 7.5,Co(Ⅱ)and Ni(Ⅱ)sorption density were much higher than that at pH 6.0,but there no mutual competitive effect was observed.EXAFS analysis further revealed that formation of layered double-hydrated precipitates was the dominant sorption mechanism for both Co(Ⅱ)and Ni(Ⅱ)at pH 7.5.Because this type of sorption does not rely on surface reactive sites,there was no competition between Co(Ⅱ)and Ni(Ⅱ).This finding sheds light on risk assessment and remediation of Ni/Co pollution.     

Mineralogical and geochemical evolution of the 1982–1983 Galunggung eruption (Indonesia)

Pyroclastic deposits from the 1982–1983 eruption of Galunggung volcano (Java, Indonesia) reflect preeruptive magmatic evolution which is of interest because of: (1) its duration of nine months, compared to a few hours or days for most historical eruptions; (2) the diversity of eruptive styles, from ash and scoria flows to phreatomagmatic explosions, and to the strombolian activity that marked the end of the eruption; and (3) the progressive variation in chemical composition with time, from andesite (58 wt.% SiO₂) to high-Mg basalt (47 wt.% SiO₂). The 1982–1983 Galunggung basalts are rather primitive: 10 to 12 wt% MgO, 180 to 200 ppm Ni and 550 to 700 ppm Cr. Despite the presence of about 40% phenocrysts, they may represent the most primitive basalts recognized in western Java. Basalts contain phenocrysts of olivine (Fo_90-80), diopside-salite, and plagioclase (An_95-75). Andesites contain plagioclase (An_80–60), augite, hypersthene (En_67-64), and titanomagnetite. The distribution of mineral compositions in each petrographic type is nearly unimodal, although scarce plagioclase and olivine xenocrysts have been observed. Abundance of gabbroic cumulates associated with the pyroclastic flows and evolution of mineral compositions from high-Mg basalts to andesites support crystal fractionation as the main differentiation mechanism, although magma mixing of basaltic andesite and andesite cannot be excluded. Major and trace element trends, which display rough decreases of MgO, CaO, Ni, Cr with increasing degree of differentiation and also linear positive correlations of hygromagmaphile elements, are compatible with both processes. However, some discrepancies are observed between major and trace element modelling, which may be explained to some extent by the influence of in situ crystallization and/or magma mixing. The constancy of ¹⁴³Nd/¹⁴⁴Nd (0.51286±3), ²³⁰Th/²³²Th (0.65±0.02), Th/U (4.08±0.07) ratios, and to a lesser extent ¹⁸O values (+5.8 to +6.4 % SMOW) and ⁸⁷Sr/⁸⁶Sr ratios (0.70440 to 0.70468) is compatible with a magmatic evolution through fractional crystallization without significant crustal contamination. Nevertheless low-¹⁸O and high ⁸⁷Sr/⁸⁶Sr values in basaltic andesites may be due to the introduction of meteoric fluids into the Galunggung magma.     

Source mechanism and stress analysis of 23 October 2011 Van Earthquake (Mw = 7.1) and aftershocks

On 23 October 2011 at 1341 local time, a strong earthquake (Mw?=?7.1) occurred east of Lake Van (KOERI; Kandilli Observatory and Earthquake Research Institute). The focal parameters of the main shock and 29 aftershocks with M?≥?4.0 were obtained from regional broadband seismic data from KOERI network by using Regional Moment Tensor Inversion Code (Dreger 2002). It is confirmed that the main shock had thrust faulting mechanism. The stress tensor analysis was completed using the focal mechanism solutions and the software developed by (Gephart Comp Geosci 16: 953-989, 1990). The maximum principal stress (P compressional) of the main shock is aligned in a N-S (NNW/SSE) direction and the tensional axis (T dilatation) is aligned in an E-W (ENE-WSW) direction. The b value is calculated as 0.96 using the maximum likelihood method (Utsu 1999).