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Recent Developments in Trace Element Analysis by ICP-AES and ICP-MS with Particular Reference to Geological and Environmental Samples 总被引:1,自引:1,他引:1
Kathryn L. Linge 《Geostandards and Geoanalytical Research》2005,29(1):7-22
This review describes recent developments in trace element analysis using inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS). It aims to focus on the application of ICP techniques to geological and environmental samples. Therefore, fundamental studies in ICP-MS and ICP-AES instrumentation have largely been ignored. Whereas the majority of literature reviewed related to ICP-MS, indicating that ICP-MS is now the preferred technique for all geological analysis, there is still a steady development of ICP-AES to environmental applications. It is clear that true flexibility in elemental analysis can only be achieved by combining the advantages of both ICP-AES and ICP-MS. Two particular groups of elements (long-lived radionuclide and the platinum-group elements) stood out as warranting dedicated sections describing analytical developments these areas. 相似文献
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A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC) 总被引:1,自引:0,他引:1
Delphine Yeghicheyan Jean Carignan Michel Valladon Martine Bouhnik Le Coz Florence Le Cornec Maryse Castrec-Rouelle Michel Robert Luc Aquilina Emmanuel Aubry Carine Churlaud Aline Dia Samuel Deberdt Bernard Dupré Rémi Freydier Gérard Gruau Odile Hénin Anne-Marie de Kersabiec Joël Macé Luc Marin Nicole Morin Patrice Petitjean Elodie Serrat 《Geostandards and Geoanalytical Research》2001,25(2-3):465-474
The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories. 相似文献
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M.-Riitta Juvonen ras Bartha Tuula M. Lakomaa Leena A. Soikkeli Eva Bertalan Eeva I. Kallio Maria Ballok 《Geostandards and Geoanalytical Research》2004,28(1):123-130
We compared the recovery of gold, palladium and platinum by two fire assaying procedures, using nickel sulfide and lead as collectors. The presence of appreciable amounts of sulfide minerals in the sample caused interferences in both procedures. An in-house reference sample, a reference sample of high-grade sulfide ore and samples of high sulfide content from the Recsk porphyry copper ore in Hungary were analysed by both methods. The elements were determined by inductively coupled plasma-atomic emission (ICP-AES) and/or inductively coupled plasma-mass spectrometry (ICP-MS). It was found that for the sulfide ore samples, the recoveries of Au and Pd are sometimes lower by nickel sulfide fire assay than by lead fire assay. Recovery of Re by nickel sulfide fire assay was found to be low: the average recovery of five repeated analyses of the reference sample NIST SRM 330 was 9% with a relative standard deviation of 48%. Increasing the amount of S in the fusion flux gave better recovery. 相似文献
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Chunsheng Li Chifang Chai Xiaolin Li Xueying Mao 《Geostandards and Geoanalytical Research》1998,22(2):195-197
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Kathryn L. Linge 《Geostandards and Geoanalytical Research》2006,30(3):157-174
This review describes significant developments in trace element determination using inductively coupled plasma-atomic emission spectrometry (ICP-AES) and inductively coupled plasma-mass spectrometry (ICP-MS) that were reported in 2004 and 2005. It focuses on the application of ICP techniques to geological and environmental samples; fundamental studies in ICP-MS and ICP-AES instrumentation are not included. The literature reviewed indicated that the majority of new publications concerned advances in ICP-MS analysis rather than ICP-AES. However, ICP-AES developments are still being published, particularly in the areas of sample preconcentration and sample introduction. The trend in increasing publication of developments in hyphenated speciation techniques looks set to persist as knowledge of elemental speciation becomes critical for many environmental studies. Collision or reactions cells were the most reported technique for spectral interference removal in ICP-MS, probably reflecting the growing adoption of cell instruments in laboratories during the last few years. 相似文献
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Determination of Rare Earth Elements in Geological Reference Materials: A Comparative Study by INAA and ICP-MS 总被引:3,自引:0,他引:3
Fung Dai Kin M. Isabel Prudêncio M. Ângela Gouveia Erik Magnusson 《Geostandards and Geoanalytical Research》1999,23(1):47-58
Data was obtained for the rare earth elements (REE) by instrumental neutron activation analysis (INAA) and inductively coupled plasma-mass spectrometry (ICP-MS) in twenty geological reference materials. In general, the precision obtained by ICP-MS is better for the light REE, decreasing with increasing atomic number. This is partly a result of the occurrence of the heavy REE at low concentrations. The precision of the data obtained by INAA is good (5% RSD). The data obtained also showed that for the elements determined by both methods, the accuracy is similar for the light REE and better for the middle and heavy REEs by INAA. Higher uncertainty is achieved by ICP-MS mainly for elements at very low concentrations, occurring at about ten times the chondritic values. 相似文献
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建立了一种利用New Wave UP 213 nm激光和ThermoFisher X Series2四极杆等离子体质谱法直接测定硅酸盐矿物中54种元素的分析方法。该方法以40Ca为内标、玻璃标准参考物质NIST SRM 610为外标,通过调节载气流量、激光频率、激光能量、激光剥蚀斑径降低元素分馏效应,并对NIST SRM 612进行测定,测定结果满足分析要求,54种元素的相对标准偏差大都低于10%,可应用于地质学分析研究。 相似文献
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DETERMINATION OF TRACE ELEMENTS IN 11 CHINESE GEOLOGICAL REFERENCE MATERIALS BY ICP-MS 总被引:1,自引:0,他引:1
More than 40 trace elements in 11 Chinese geological reference materials (stream sediments) GSD-1 to GSD-7 and GSD-9 to GSD-12 were determined by inductively coupled plasma-mass spectrometry (ICP-MS). Open acid digestions were used to prepare samples for the determination of most elements. However, for the measurement of Y, Zr and Hf, it was found necessary to use an alkali fusion in order to make fully quantitative measurements. The results obtained in this work are generally in good agreement with the recommended values from the sub-ppm level to > several hundred ppm and illustrate the versatility of the technique, particularly for some less well characterised elements. 相似文献
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Determination of Bromine and Iodine in Twenty-three Geochemical Reference Materials by ICP-MS 总被引:1,自引:0,他引:1
Trace amounts (from nanogram to microgram levels) of bromine and iodine were determined by inductively coupled plasma-mass spectrometry (ICP-MS) in twenty-three geochemical reference materials issued by the GSJ, USGS, IAEA etc. The pyrohydrolysis technique was used to separate bromine and iodine from samples analysed in the form of powder. The accuracy and precision of the experimental values were assessed by the comparative analysis of well established reference materials such as USGS AGV-1, BCR-1 and IGGE GBW07312. The measured values agreed well with reported values within a 10% error range. We also report reliable new data for these elements in these geochemical reference materials. 相似文献
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锍镍试金-电感耦合等离子体质谱法测定硫铁矿中铂族元素 总被引:4,自引:1,他引:4
锍镍试金常用于富集常规地质样品中的铂族元素(PGEs);而用于富集硫铁矿中的PGEs鲜有报道。硫铁矿中硫和铁的含量较高,采用常规的试金配方不能得到较好的锍扣,影响下一步样品的溶解和过滤。本文对锍镍试金-电感耦合等离子体质谱法测定硫铁矿中PGEs的流程进行改进。针对硫铁矿中硫和铁含量高的特点,在不减少称样量的情况下,调整常规锍镍试金中的试剂配方,获得了理想的锍扣和熔渣,使锍扣富集PGEs的能力达到最佳,且避免了由于反应时间过长而造成PGEs损失。同时利用硫化铁易剥落和粉化的特点,省去了锍扣的机械粉碎工序,简化了流程,避免了碎扣时的机械损失和样品间可能的交叉污染。结果表明,高含量的铁对PGEs的测定无显著影响。加标回收试验显示PGEs全流程回收率大于94%。按10 g取样量计算,方法检出限分别为Ru 0.018 ng/g,Rh 0.017ng/g,Pd 0.18 ng/g,Os 0.019 ng/g,Ir 0.013 ng/g,Pt 0.11 ng/g。实际样品分析和加标回收试验表明,改进后的锍镍试金-电感耦合等离子体质谱测定流程可以满足大多数硫铁矿中PGEs的测定要求。 相似文献
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Groundwater arsenic distribution in South-western Uruguay 总被引:1,自引:0,他引:1
A. Manganelli C. Goso R. Guerequiz J. L. Fernández Turiel M. García Vallès D. Gimeno C. Pérez 《Environmental Geology》2007,53(4):827-834
This is the first specific information regarding arsenic distribution of groundwater in SW Uruguay. Twenty-eight wells were
sampled on the aquifers of Mercedes, Raigón and Chuy in five localities. The pH, specific conductivity and temperature were
determined in the field. The hydrochemical characterization (major and trace elements) was carried out by both inductively
coupled plasma-optical emission spectrometry and inductively coupled plasma-mass spectrometry. The occurring arsenic concentrations
exceed the recommended threshold for drinking water of the World Health Organization (10 μg/l of As) in 22 samples, with more
than 50 μg/l of As in two cases. The median, minimum and maximum concentrations were 0.1, 16.9 and 58.0 μg/l of As, respectively.
The studied aquifers present a horizontal and a vertical variation of the concentrations as a whole as well as individually.
The highest values were observed in the Mercedes Aquifer in the areas near the Uruguay River. 相似文献