桐柏山花岗岩类Pb、O、Sr同位素特征

本文首次对桐柏山花岗岩类的Ｐｂ、Ｏ、Ｓｒ同位素进行研究。其长石铅同位素组成是２０４Ｐｂ＝１．４００（１．３８９－１．４１１），２０６Ｐｂ／２０４Ｐｂ＝１７．１４８（１６．８４７－１７．４３８），２０７Ｐｂ／２０４Ｐｂ＝１５．４２８（１５．３７８－１５．４８４），２０８Ｐｂ／２０４Ｐｂ＝３７．８８６（３７．５８３－３８．２９６）。与邻区花岗岩类相比，基本相当于胶东地区。全岩矿δ１８Ｏ＝８．４８（７．４９－９．３７）。８７Ｓｒ／８６Ｓｒ（ｉ）＝０．７０９０（０．７０６４－０．７１３８）。这些数据结合岩石矿物特征表明，本区花岗岩类的成因类型属Ⅰ型或同熔型。铅同位素组成揭示本区大地构造可能归属华北地台。     

北大巴山地区沉积黄铁矿的硫、铅同位素及其构造学意义

北大巴山区震旦一志留系地层中黄铁矿的硫、铅同位素资料，为阐明扬子板块北部被动大陆边缘的形成与演化提供了二点认识：（１）在震旦纪裂陷早期，￣（２０６）Ｐｂ／￣＿（２０４）Ｐｂ平均比值为１７．６６，表明其裂陷深度已达到下地壳范围；在寒武纪裂陷晚期及移离早期，平均比值为１９．０３，表明裂陷深度在上、下地壳附近；在志留纪的移离晚期，平均比值为２０．０８，表明此时裂陷深度在上地壳之内。（２）黄铁矿的δ￣（３４）Ｓ，由裂陷早期（Ｚ）—移离晚期（Ｓ＿１）是逐渐增大趋势，从开始的十８．２５‰增高到＋１７．４９‰．表明本区是一个封闭的古海盆环境。     

武当地块基性岩墙群及耀岭河群基性火山岩的Sr、Nd、Pb、O同位素研究

武当地块基性岩墙群与耀岭河群基性火山岩的 Ｓｒ、 Ｎｄ、 Ｐｂ 同位素特征反映它们具相同的混合地幔源区。前者的（８７ Ｓｒ／８６ Ｓｒ）ｉ＝ ０６９０５～０７０６１, ε Ｎ ｄ （ｔ） ＝ － １９～５０, Δ２０８ Ｐｂ／２０４ Ｐｂ＝ ３５４９～１９０２６, Δ２０７ Ｐｂ／２０４ Ｐｂ＝ ４～８５, Ｔｈ／ Ｔａ 低, Ｌａ／ Ｙｂ 变化大;后者的（８７ Ｓｒ／８６ Ｓｒ）ｉ＝ ０６４８７～０７０７５,ε Ｎ ｄ（ｔ）＝ ０１１～３９４, Δ２０８ Ｐｂ／２０４ Ｐｂ＝ － ８１５８～２１９９５, Δ２０７ Ｐｂ／２０４ Ｐｂ＝ ４４４～１６６８, Ｔｈ／ Ｔａ 和 Ｌａ／ Ｙｂ 较高。这指示它们的源区以岩石圈亏损地幔和第２ 类富集地幔为主要混合组分, 耀岭河群基性火山岩曾遭受地壳物质的混染。结合它们具大陆拉斑玄武岩地球化学特征, 代表同源异相裂谷环境的产物推断, 南秦岭基底陆块在新元古代时曾发生过一次重要裂解作用, 并向早古生代秦岭洋盆转变。     

东秦岭陡岭古岛弧和武当古弧后盆地及其地质意义

丹凤－信阳蛇绿混杂带作为秦岭－大别碰撞造山带主缝合带，其南部属于扬子板块北部大陆边缘。研究区域位于东秦岭南翼，是扬子板块北部大陆边缘的一部分。①晚元古－中震旦世，扬子板块北缘为活动型大陆边缘，发育陡岭岛弧和弧后盆地；②晚震旦－－早古生代，扬子板块北缘转为被动型大陆边缘，陡岭岛弧构成边缘地块，武发古弧后盆地演化为边缘盆地；③早古生代晚期，华北板块南缘的秦岭岛弧首先与扬子板块北缘的陡岭国缘地块（古岛弧     

扬子板块西缘挖角地区晋宁期岩浆作用及大地构造意义

四川省石棉县挖角地区花岗岩体位于扬子板块西缘与松潘-甘孜地块的结合部位,本文通过详细的野外地质调查,结合岩石学、岩相学、LA-ICP-MS U-Pb年代学和MC-ICP-MS Hf同位素组成研究,厘定了岩体形成时代,探讨了岩浆来源。LA-ICP-MS锆石U-Pb测年结果表明,挖角二长花岗岩形成年代介于852±33Ma和847±44Ma之间,处于晋宁期晚青白口世,与全球Rodinia期泛大陆形成密切相关。锆石原位Lu-Hf同位素组成表明,2个样品的εHf(t)值分别为+3. 9～+9. 3和-8. 0～+6. 5,为典型的壳-幔混合型; Hf同位素的二阶段模式年龄(tDM2)分别为1. 14～1. 49Ga和1. 33～2. 24Ga,均值分别为1. 32Ga和1. 52Ga,表明岩浆源区以中元古代古老地壳基底的部分熔融为主,形成过程中有幔源及古元古代古老地壳物质的贡献。挖角地区晋宁期二长花岗岩体锆石U-Pb年代学和Hf同位素组成,反映了扬子板块西缘晚青白口世岩浆活动期和源区特征,其成因与全球Rodinia泛大陆形成期间岩浆活动和与壳幔混合作用密切相关。本文研究成果,为解释扬子板块西缘的构造演化提供了新的资料证据。     

冀西北水泉沟正长岩杂岩体的成因

水泉沟碱性正长岩杂岩体侵入于太古宇桑干群变质岩中，岩体主要由碱性长石正长岩、角闪碱长正长岩、正长岩、石英碱长正长岩等组成，属碱性岩系列，在岩石的石英颗粒中见有熔融包体的存在。岩石的稀土元素分布模式呈平滑的右倾模式，无明显的铕异常。岩石的Ｐｂ同位素组成为２０６Ｐｂ／２０４Ｐｂ＝１６．４５７～１８．２８６、２０７Ｐｂ／２０４Ｐｂ＝１５．２７０～１５．４７２、２０８Ｐｂ／２０４Ｐｂ＝３６．５３９～３７．３９３，石英的δ１８Ｏ值为８．０‰～８．５‰，（８７Ｓｒ／８６Ｓｒ）ｉ≈０．７０５，岩石的ｔＤＭ为１．６～１．９Ｇａ，εＮｄ（ｔ）为－７．４５～－１３．１，明显大于区域基底的εＮｄ（ｔ）值（－２０±）。以上结果表明，岩体为上地幔和下地壳物质部分熔融的产物。岩体角闪石３９Ａｒ－４０Ａｒ年龄３２７Ｍａ，为海西期岩浆作用的产物     

北大巴山地区沉积黄铁矿的硫,铅同位素及其构造学意义

北大巴山区震坦－志留系地层中黄铁矿的硫、铅同位素资料，为阐明扬子板块北部被动大陆边缘的形成与演化提供了二点认识：（１）在震旦纪裂陷早期，＾２０６Ｐｂ／＾２０４Ｐｂ平均比值为１７．６６，表明其裂陷深度已达到了下地壳范围；在寒武纪裂陷晚期及移离早期，平均比值为１９．０３，表明裂陷在上、下地壳附近；在志留纪的移离晚期，平均比例为２０．０８，表明此时裂陷深度在上地壳之内。（２）黄铁矿的δ＾３４Ｓ，由裂陷早     

我国矽卡岩型铜矿床同位素地质特征及其“三位一体”成矿模式

总结了典型折矽卡岩型铜矿床同位素地质地球化学特征，认为我国矽卡岩型铜矿床成矿岩体（＾８７Ｓｒ／＾８６Ｓｒ）ｉ一般在０．７０６￣０．７１０变化，岩体为幔壳混合源型。矿石铅同位素组成均匀、稳定，特别是铀铅，＾２０６Ｐｂ／＾２０４Ｐｂ＝１７．０７５￣１８．１００，＾２０７Ｐｂ／＾２０４Ｐｂ＝１５．３３７￣１５．６３５，比值变化小，而＾２０８Ｐｂ／＾２０４Ｐｂ比值变化稍大，矿石铅源主要来自成矿岩体。矿石δ     

汉诺坝玄武岩中辉石岩类包体Nd、Sr、Pb同位素及其成因信息

对汉诺坝地区的１２个辉石岩和１个麻粒岩包体进行了Ｎｄ、Ｓｒ、Ｐｂ同位素测定，发现辉石岩组成有很大变化，１４３Ｎｄ／１４４Ｎｄ比值为０．５１１６０—０．５１３１４，８７Ｓｒ／８６Ｓｒ比值为０．７０２９—０．７０８６，２０６Ｐｂ／２０４Ｐｂ比值为１５．９４２—１８．６８３，２０７Ｐｂ／２０４Ｐｂ比值为１５．２６４—１５．５６９，２０８Ｐｂ／２０４Ｐｂ比值为３６．２１３—３８．７４４，显示了其复杂成因ｑ推测具有高Ｓｒ、低Ｎｄ和低Ｐｂ同位素组成的辉石岩是地幔早期富集的产物，与麻粒岩、辉长岩包体有类似成因；具有弱至中等亏损的Ｎｄ、Ｓｒ同位素和高放射成因Ｐｂ的辉石岩是亏损地幔近期富集或交代的产物     

南极乔治王岛中——新生代岩浆岩Sr—Nd—Pb同位素组成及源区特征

对乔治王岛１１个火山岩和２个侵入岩样品做了Ｓｒ－Ｎｄ－Ｐｂ同位素分析，其中（８７Ｓｒ／８６Ｓｒ）ｉ＝０．７０３２６～０．７０３９２，εＮｄ＝３．０２～６．７２，２０６Ｐｂ／２０４Ｐｂ＝１７．７７６～１８．５１５，２０７Ｐｂ／２０４Ｐｂ＝１５．．５０６～１５．５７１，２０８Ｐｂ／２０４Ｐｂ＝３７．８６８～３８．３０８。根据以上同位素组成及其相互关系并结合岩石学和微量元素特征及火山岩中熔融包裹体成分，得出以下结论：（１）研究的乔治王岛岩浆岩起源于亏损地幔（ＤＭＭ）和地幔流体交代成因的富集地幔ＥＭＩ混合形成的源区；（２）该源区具有广义Ｄｕｐａｌ异常，它正是由于ＥＭＩ组份加入即通过流体交代作用而产生的；（３）流体主要是俯冲深海沉积物脱碳酸盐作用而释放出的富ＣＯ２流体。     

Roles of xenomelts,xenoliths, xenocrysts,xenovolatiles, residues,and skarns in the genesis,transport, and localization of magmatic Fe-Ni-Cu-PGE sulfides and chromite

Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.     

深部矿井水煤共采水文地质数值分析

针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。     

Coprecipitation of Ti,Mo, Sn and Sb with fluorides and application to determination of B,Ti, Zr,Nb, Mo,Sn, Sb,Hf and Ta by ICP-MS

We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l^− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO₂.     

Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid

Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.     

Distribution of Cu,Co, As,and Fe in mine waste,sediment, soil,and water in and around mineral deposits and mines of the Idaho Cobalt Belt,USA

The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Dielectric constants of apatite,epidote, vesuvianite,and zoisite,and the oxide additivity rule

The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ _a=9.93 tan δ=0.006 κ′ _c=9.79 tan δ=0.005 vesuvianitel κ′ _a=10.02 tan δ=0.002 κ′ _c=9.85 tan δ=0.003 zoisite1 κ′ _a =10.49 tan δ=0.0006 κ′ _b =15.31 tan δ=0.0008 κ′ _c=9.51 tan δ=0.0008 zoisite2 κ′ _a =10.55 tan δ=0.0011 κ′ _b =15.45 tan δ=0.0013 κ′ _c=9.39 tan δ=0.0008 epidote κ′ ₁₁= 9.52 tan δ=0.0008 κ′ ₂₂=17.1 tan δ=0.0009 κ′ ₃₃= 9.37 tan δ=0.0006 fluorapatite1 κ′ _a =10.48 tan δ=0.0008 κ′ _c = 8.72 tan δ=0.0114 fluorapatite2 κ′ _a =10.40 tan δ=0.0010 κ′ _c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α _D (mineral)=∑ α _D (oxides) for vesuvianite is ～ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (V_o) is believed to affect the total polarizabilities, the variation of V_o in these Ca minerals is too small to observe the effect.     

Geochemistry and petrology of selected coal samples from Sumatra, Kalimantan, Sulawesi, and Papua, Indonesia

Indonesia has become the world's largest exporter of thermal coal and is a major supplier to the Asian coal market, particularly as the People's Republic of China is now (2007) and perhaps may remain a net importer of coal. Indonesia has had a long history of coal production, mainly in Sumatra and Kalimantan, but only in the last two decades have government and commercial forces resulted in a remarkable coal boom. A recent assessment of Indonesian coal-bed methane (CBM) potential has motivated active CBM exploration. Most of the coal is Paleogene and Neogene, low to moderate rank and has low ash yield and sulfur (generally < 10 and < 1 wt.%, respectively). Active tectonic and igneous activity has resulted in significant rank increase in some coal basins. Eight coal samples are described that represent the major export and/or resource potential of Sumatra, Kalimantan, Sulawesi, and Papua. Detailed geochemistry, including proximate and ultimate analysis, sulfur forms, and major, minor, and trace element determinations are presented. Organic petrology and vitrinite reflectance data reflect various precursor flora assemblages and rank variations, including sample composites from active igneous and tectonic areas. A comparison of Hazardous Air Pollutants (HAPs) elements abundance with world and US averages show that the Indonesian coals have low combustion pollution potential.