Continental slope sea level and flow variability induced by lateral movements of the Gulf Stream in the Middle Atlantic Bight

As described by [Csanady, G.T., Hamilton, P., 1988. Circulation of slope water. Continental Shelf Research 8, 565–624], the flow regime over the slope of the southern Middle Atlantic Bight (MAB) includes a current reversal in which southwestward flow over the upper and middle slope becomes entrained in the northeastward current adjacent to the Gulf Stream. In this paper we use satellite-derived data to quantify how lateral motions of the Gulf Stream impact this current system. In our analysis, the Gulf Stream’s thermal front is delineated using a two-year time series of sea surface temperature derived from NOAA/AVHRR satellite data. Lateral motions of the Gulf Stream are represented in terms of temporal variations of the area, east of 73°W, between the Gulf Stream thermal front and the shelf edge. Variations of slope water flow within this area are represented by anomalies of geostrophic velocity as derived from the time series of the sea level anomaly determined from TOPEX/POSEIDON satellite altimeter data. A strong statistical relationship is found between Gulf Stream displacements and parabathic flow over the continental slope. It is such that the southwestward flow over the slope is accelerated when the Gulf Stream is relatively far from the shelf edge, and is decelerated (and perhaps even reversed) when the Gulf Stream is close to the shelf edge. This relationship between Gulf Stream displacements and parabathic flow is also observed in numerical simulations produced by the Miami Isopycnic Coordinate Model. In qualitative terms, it is consistent with the notion that when the Gulf Stream is closer to the 200-m isobath, it is capable of entraining a larger fraction of shelf water masses. Alternatively, when the Gulf Stream is far from the shelf-break, more water is advected into the MAB slope region from the northeast. Analysis of the diabathic flow indicates that much of the cross-slope transport by which the southwestward flow entering the study region is transferred to the northeastward flow exiting the region occurs in a narrow band roughly centered at 36.75°N, order 150 km north of Cape Hatteras. This transport, and thus the cyclonic circulation of the southern MAB, strengthens when the Gulf Stream is relatively close to the shelf edge, and weakens when the Gulf Stream is far from the shelf edge.     

Dissolved iodine in waters overlying and in the Orca Basin,Gulf of Mexico

The distribution and speciation of iodine, a biophilic redox-sensitive trace element, in waters overlying and in the Orca Basin, Gulf of Mexico, which contains hypersaline, anoxic and yet non-sulfide-bearing brine have been determined. The distribution of iodate and iodide in the oxic waters overlying the anoxic brine are similar to those reported in other oceans. However, in the oxic-anoxic mixing zone, iodate disappears while the concentration of iodide reaches a maximum of 8.1 μM, the highest concentration ever reported in open oceans. There is also a maximum in specific iodine of 30.7 nM‰^?1 at this depth. Specific iodine in oxic seawater is only about 10–14 nM ‰^?1. These features may be explained by the preferential dissolution of biogenic particles that have accumulated in a strong pycnocline. In the anoxic brine proper, the concentration of iodide is 3.8 μM and can be explained almost entirely by the simultaneous mobilization of chloride and iodide during the dissolution of evaporite beds as the specific iodine of 14.5 nM‰^?1 is only slightly higher than those observed in the oxic waters.     

Invertebrate communities associated with hard bottom habitats in the South Atlantic Bight

Epibenthic invertebrates associated with nine hard bottom areas in the South Atlantic Bight between South Carolina and northern Florida were collected with dredge, trawl, suction and grab samplers to evaluate species composition, biomass, abundance, diversity, spatial distributions, and seasonality (winter and summer). Species composition changed noticeably with depth and season. Inner and outer shelf stations were least similar in species composition. Middle shelf areas were transitional and contained taxa characteristic of both inner and outer sites. Bryozoa (88 taxa), Cnidaria (85 taxa), Porifera (67 taxa), Annelida (261 taxa) and Mollusca (203 taxa) represented the richest taxonomic groups of the 1175 taxa collected. Both diversity (1175 total taxa) and biomass (1995 kg total) of invertebrates from hard bottom areas exceeded those reported in the literature for sand bottom communities. Sponges accounted for >60% of the total invertebrate biomass collected by dredge and trawl during both seasons. High diversity values were attributed primarily to habitat complexity and did not exhibit any discernible pattern with depth or latitude.     

Dissolved titanium distributions in the Mid-Atlantic Bight

Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.     

The seasonal cycle of arsenic in estuarine and nearshore waters of the South Atlantic Bight

Arsenic concentrations vary with season on the continental shelf of the South Atlantic Bight. During periods of high winds in the winter and early spring, inorganic arsenic concentrations are reduced to as little as 20% of typical open ocean concentrations by sorption onto resuspended sediments or incorporation into phytoplankton. In the early fall, arsenic sequestered in sediments in the spring is regenerated and returned to the water column, creating elevated arsenic concentrations in the nearshore zone that are up to 50% greater than open ocean concentrations. Arsenic in the adjacent estuaries is nearly conservative over the seasonal cycle, although its distribution in the estuaries is greatly affected by the seasonal changes in arsenic concentrations in the nearshore waters.     

Influence of the interaction between the Atlantic and the Arctic Ocean on the Gulf Stream

Numerical experiments with the circulation model of the North Atlantic based on the splitting algorithms in the σ-coordinate system with a spatial resolution allowing for reproducing synoptic eddies were performed in two versions: with the Arctic Ocean and without it (boundary along 78°N). They showed that the account for the water exchange with the Arctic is fundamentally important for reproducing jet dynamics at the western boundary of the Atlantic down to the subtropical zone. The influence of the conditions at the liquid boundary that separates the Atlantic and the Arctic extends not only over the subarctic area [29] but is also “transferred” by the Labrador Current and the Slope Water Current (SWC) to the area of the Gulf Stream proper. One cannot properly describe the detachment of the Gulf Stream from the coast without adequate reproducing of the Labrador Current and SWC. An hypothesis is posed that the location of the detachment region at 35°N is caused by strong vertical motions at the interface between the SWC and the Gulf Stream jet with horizontal velocities that are almost equal to those at the exit from the Florida Strait. A comparison of the model circulation with that retrieved from the hydrological data and the drift of neutral buoyancy floats [14, 22] showed both qualitative and quantitative coincidences of the features of the northward warm water transfer such as the streamline around the so-called northwestern “corner” (motion “along the topography”) and the jet-wise transport of these waters from Labrador to the northeast inside a kind of “pipeline,” which is limited in the upper baroclinic layer 1 km thick by mean velocity contour lines of about 10 cm/s. A comparison between the experimental [19] and model fields of the ocean level showed that, at the absence of direct representation of the water (mass) exchange between the Atlantic and the Arctic Ocean, the decrease of the gradient velocities in the Gulf Stream may reach 30%.     

Response of the Gulf Stream transport to characteristic high and low phases of the North Atlantic Oscillation

We investigate an ambiguity in the current understanding of the Gulf Stream (GS) transport in response to the North Atlantic Oscillation (NAO). While some investigations (discussed herein) suggest enhanced transport during low NAO phases, other studies suggest enhanced transport in high NAO phases. NAO-induced variability in the western North Atlantic is studied by using a 1/6°-resolution basin-scale Regional Ocean Modeling System (ROMS) model. Results indicate that the western boundary current limb of the GS, upstream of Cape Hatteras, exhibit enhanced transport during low-NAO phases. However, further downstream of Cape Hatteras, after the GS separates from the coast, diminished GS transport is seen during low-NAO phases. The converse is true for high NAO phases for both segments of the GS system. Model results show the Deep Western Boundary Current (DWBC), the northern recirculation gyre and the southern recirculation gyre intensify (weaken) during the high (low) NAO periods.     

Dissolved inorganic and organic iodine in the Chesapeake Bay and adjacent Atlantic waters: Speciation changes through an estuarine system

The distributions of iodate, iodide and dissolved organic iodine (DOI) were determined in two deep sub-basins in the Chesapeake Bay, the shallow waters at the mouth of the Bay and the adjacent North Atlantic between the late spring and the early fall along the net flow-path of the water entering and exiting the Chesapeake Bay by using an improved analytical scheme designed for the quantitative recovery of DOI. The concentration of R-DOI found in the surface mixed layer in the upper Bay was about twice of those found at the same location in previous studies. (R-X was the concentration of a dissolved iodine species X that had been normalized to a constant salinity of 35.) Thus, DOI in estuarine waters might have been underestimated significantly in the earlier studies. Following the water along its net flow-path, iodate initially constituted more than 60% of total iodine (TI) in the source water in the Middle Atlantic Bight off the Delmarva Peninsula. As this water entered the Chesapeake Bay through the northern part of its mouth, the concentration of R-iodate decreased while that of R-iodide increased progressively until the former became undetectable in the surface mixed layer while the latter reached a maximum of 0.42 μM in the deep water in the upper Bay. Then, the concentration of R-iodate rebounded while that of R-iodide decreased in the outflowing water that exited through the southern part of the mouth of the Bay and was later entrained by the Gulf Stream. The concentration of R-DOI in the surface waters followed the same pattern as R-iodide and reached a maximum of 0.20 μM in the upper Bay. However, R-DOI was depleted in the deep water in the sub-basins. Its concentration dropped to around the detection limit in the suboxic waters in the upper Bay. R-TI in the Bay far exceeded that in the incoming Middle Atlantic Bight water and reached 0.55 μM in the upper Bay. These distributions of the iodine species suggest that, as water from the Middle Atlantic Bight intruded into the Chesapeake Bay, in the well oxygenated surface mixed layer, iodate was reduced to iodide, and the inorganic iodine species could also be converted to DOI. In the deep water, iodate and DOI were converted to iodide. Superimposed on these inter-conversions among the iodine species, dissolved iodine, possibly in the form of iodide, was also added to the water column from the underlying sediments and the process was especially significant in the suboxic deep water in the upper Bay. Mixing between the surface mixed layer and the deep water could also have increased the concentrations of iodide and total iodine in the former.     

Variability of hydrophysical characteristics in the Gulf Stream

We consider the interannual variability of the intensity of the Gulf Stream and interannual fluctuations of seawater parameters in the Gulf Stream and in the Labrador Current during intense climate warming. We show that this intensity has increased during this period. The scales of fluctuations and their contribution to variance in the initial time series was determined from wavelet analysis of the Gulf Stream north wall. We noted a considerable decrease in water density of the main branch of the Gulf Stream, caused by the increase in temperature due to global climate warming, and an absence of trends in water density of the main branch of the Labrador Current.     

On anticyclonic spin-off eddies in the Gulf Stream

The eddy formation determined as an anticyclonic spin-off eddy of the Gulf Stream is analysed from the CTD data of surveys made in the Gulf Stream region. The differences in its structure and conditions of formation from cyclonic eddies of this type observed previously are examined. Barotropic instability of the Gulf Stream's main jet is considered as a possible reason for such unstable disturbances existing at the south boundary of the Gulf Stream.Translated by M. M. Trufanov.     

Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Interannual variability

Systematic water sampling for characterization of chromophoric dissolved organic matter (CDOM) in the coastal South Atlantic Bight, was conducted as part of the long term Coastal Ocean Research and Monitoring Program (CORMP). Water samples were collected during a 3.5 year period, from October 2001 until March 2005, in the vicinity of the Cape Fear River (CFR) outlet and in adjacent Onslow Bay (OB). During this study there were two divergent hydrological and meteorological conditions in the CFR drainage area: a severe drought in 2002, followed by the very wet year of 2003. CDOM was characterized optically by the absorption coefficient at 350 nm, the spectral slope coefficient (S), and by Excitation Emission Matrix (EEM) fluorescence. Parallel Factor Analysis (PARAFAC) was used to assess CDOM composition from EEM spectra and six components were identified: three terrestrial humic-like components, one marine humic-like component and two protein-like components. Terrestrial humic-like components contributed most to dissolved organic matter (DOM) fluorescence in the low salinity plume of the CFR. The contribution of terrestrial humic-like components to DOM fluorescence in OB was much smaller than in the CFR plume area. Protein-like components contributed significantly to DOM fluorescence in the coastal ocean of OB and they dominated DOM fluorescence in the Gulf Stream waters. Hydrological conditions during the observation period significantly impacted both concentration and composition of CDOM found in the estuary and coastal ocean. In the CFR plume, there was an order of magnitude difference in CDOM absorption and fluorescence intensity between samples collected during the drought compared to the wet period. During the drought, CDOM in the CFR plume was composed of equal proportions of terrestrial humic-like components (ca. 60% of the total fluorescence intensity) with a significant contribution of proteinaceous substances (ca. 20% of the total fluorescence). During high river flow, CDOM was composed mostly of humic substances (nearly 75% of total fluorescence) with minor contributions by proteinaceous substances. The impact of changes in fresh water discharge patterns on CDOM concentration and composition was also observed in OB, though to a lesser degree.     

Dissolved and particulate tin in North Atlantic seawater

A study of tin concentrations in the North Atlantic Ocean has revealed concentrations much lower than previously reported. Concentrations of dissolved tin in surface water are in the range of non-detectable (< 1.5 pM) to 16 pM. Almost all depth profiles have maxima in tin concentrations from 50 to 200 m depth. These maxima can be as high as 16 pM. In most depth profiles, dissolved tin is at or below detection limits at depths exceeding 1000 m.     

Numerical Simulation of the Gulf Stream and the Deep Circulation

The Gulf Stream system has been numerically simulated with relatively high resolution and realistic forcing. The surface fluxes of the simulation were obtained from archives of calculations from the Eta-29 km model which is an National Center for Environment Prediction (NCEP) operational atmospheric prediction model; synoptic fields are available every 3 hour. A comparison between experiments with and without surface fluxes shows that the effect of the surface wind stress and heat fluxes on the Gulf Stream path and separation is closely related to the intensification of deep circulations in the northern region. Additionally, the separation of the Gulf Stream and the downslope movement of the Deep Western Boundary Current (DWBC) are reproduced in the model results. The model DWBC crosses under the Gulf Stream southeast of Cape Hatteras and then feeds the deep cyclonic recirculation east of the Bahamas. The model successfully reproduces the cross-sectional vertical structures of the Gulf Stream, such as the asymmetry of the velocity profile, and this structure is sustained along the downstream axis. The distribution of Root Mean Square (RMS) elevation anomaly of the model shows that the eddy activity of the Gulf Stream is realistically reproduced by the model physics. The entrainment of the upper layer slope current into the Gulf Stream occurs near cross-over; the converging cross-stream flow is nearly barotropic. This revised version was published online in August 2006 with corrections to the Cover Date.     

Dissolved organic carbon and apparent oxygen utilization in the Atlantic Ocean

Dissolved organic carbon (DOC) distributions along two Atlantic Meridional Transects conducted in 2005 in the region between 47°N and 34°S showed clear latitudinal patterns. The DOC concentrations in the epipelagic zone (0–100 m) were the highest (70–90 µM) in tropical and subtropical waters with stable mixed layers, and lowest (50–55 µM) at the poleward extremities of the transects due to deep convective mixing supplying low DOC waters to the surface. A decrease in DOC occurred with depth, and lowest DOC concentrations (41–45 µM) in the 100–300 m depth range were observed in the equatorial region due to upwelling of low DOC waters. A strong relationship between DOC and AOU was observed in the σ–t 26–26.5 isopycnal layer which underlies the euphotic zone and outcrops at the poleward extremities of the North and South Atlantic Subtropical Gyres (NASG and SASG) in the region ventilating the thermocline waters. Our observations reveal significant north–south variability in the DOC–AOU relationship. The gradient of the relationship suggests that 52% of the AOU in the σ–t 26–26.5 density range was driven by DOC degradation in the NASG and 36% in the SASG, with the remainder due to the remineralisation of sinking particulate material. We assess possible causes for the greater contribution of DOC remineralisation in the NASG compared to the SASG.     

Vertical distribution of the sound speed in the Gulf Stream system

Using archived historical data on the temperature/salinity distribution, this paper describes the structure of the mean seasonal and the actual field of the computed speed of sound in the Gulf Stream region. The formation of acoustic channels of large, medium, and small size is considered, depending on the vertical thermohaline structure of waters. The paper provides statistical characteristics of the sound speed field and acoustic channels of waters interacting in the Gulf Stream system. Translated by Vladimir A. Puchkin.     

Dissolved organic carbon in sediments from the eastern North Atlantic

Profiles of dissolved organic carbon (DOC) were measured in the pore water of sediments from 1000, 2000 and 3500 m water depth in the eastern North Atlantic. A net DOC accumulation in the pore waters was observed, which followed closely the zonation of microbial respiration in these sediments. The concentration of pore water DOC in the zone of oxic respiration was elevated relative to that in the bottom ocean water. The resulting upward gradient across the sediment–water interface indicated a steady state diffusive benthic flux, F_DOC, of 0.25–0.44 mmol m⁻² day⁻¹ from these sediments. Subsequent increase in the concentration of DOC in the pore water occurred only in the sediments from 1000 and 2000 m water depth that supported anoxic respiration, leading to a deep concentration maximum. By contrast, in the sediments from 3500 m water depth, a deep concentration minimum was measured, coincident with minimal postoxic respiration in this near-abyssal setting. The gradient-based F_DOC represented approximately 14% of the total remineralized organic carbon (TCR=sum of F_DOC and depth-integrated organic carbon oxidation rate) in the sediments from 1000 and 2000 m water depth, while it was 36% of the TCR in the sediments from 3500 m water depth. A covariance of particulate organic carbon (POC) and pore water DOC with depth in the sediments was evident, more consistently at the deepest site. While the covariance can be related to biotic processes in these sediments, an alternative interpretation suggests a possible contribution of sorption to the biotic control on sedimentary organic carbon cycling. The steady state diagenetic conditions in which this may occur can be conceivable for some organic-poor deep-sea locations, but direct evidence is clearly required to validate them.     

Climatological Estimation of Environmental Uncertainty Over the Middle Atlantic Bight Shelf and Slope

Historical hydrographic data are used to determine the spatial and seasonal patterns of uncertainty in thermohaline and sound-speed fields in a well-sampled region, the continental shelf and slope in the Middle Atlantic Bight (MAB). Several different historical databases are combined to produce two-dimensional (2-D) plan view and cross-shelf fields of temperature, salinity, and sound speed in two separate regions, the New England shelf and the shelf off Delaware and Maryland. In addition, spatial maps of the sound-speed fields reveal that the maximum variance of the sound speed occurs at the edge of the continental shelf, in the vicinity of the shelfbreak front. The standard deviation of the sound speed was largest during the spring and summer, with magnitudes as large as 14 m/s in a narrow band coinciding with the mean position of the shelfbreak front. During spring the peak in variance was located near the surface outcrop of the front, but during summer the maximum variance was centered at a depth of 30 m, immediately beneath the seasonal thermocline. Comparisons with both synoptic measurements from the Shelfbreak PRIMER experiment as well as moored time series from the Nantucket Shoals Flux Experiment confirm that the shelfbreak front is a "hotspot" of uncertainty (maximum variance), and that the vertical structure of the peak variance is dependent on the presence or absence of the seasonal thermocline