Recycling of Cathode Ray Tubes (CRTs) in Electronic Waste

The management of used electrical and electronic equipment (EEE) or e‐waste is a significant problem worldwide due to rapid uptake of the technology and early obsolescence of EEE. Cathode ray tubes (CRTs) from used televisions and computer monitors represent a major e‐waste problem as they consist of glass with different compositions. The front panel is a lead‐free barium‐strontium glass whereas parts such as the funnel hidden inside are composed of glass with lead oxides. Regulations require the glass from waste CRTs to be recycled or re‐utilized. Closed‐loop recycling and open‐loop recycling are two principal ways of recycling CRT glass. The aim of this paper is to examine the technical characteristics and composition of the CRTs, its generation, environmental impacts and related regulatory requirements and to review the current technologies and their limitations for recycling CRT glass and its end use.     

A Mini‐Review of E‐Waste Management in Brazil: Perspectives and Challenges

The accelerated production and replacement of new electrical and electronic equipment demonstrates a tendency for the proportional increase in the generation of e‐waste. Developing countries experience similar social and environmental consequences from this trend, which compounds the other challenges associated with the already poor solid waste management in these regions. Moreover, the dangerous composition of some e‐waste amplifies the problems related to managing these materials. This mini‐review presents a brief overview of e‐waste management in Brazil, including technical aspects, scientific studies, and the challenges ahead. With the Brazilian National Policy of Solid Waste already in place, technical and scientific studies endorse measures that range from incorporating the informal recycling sector into the e‐waste management sector to encouraging the expansion of the recycling industry. All such actions, combined with an intensified commitment of electronic equipment manufacturers to reverse logistics, can improve e‐waste management in Brazil.     

Coupling between landslides and eroding stream channels reconstructed from spruce tree rings (examples from the Carpathians and Sudetes – Central Europe)

The analysis of the positive feedback between landslides and erosion requires determination of the precise temporal and spatial relations between events of colluvium delivery and fluvial erosion. In our study we use decennial datasets on the occurrence of landsliding and erosion achieved through dendrochronological methods. Four sites covering areas of landslide slopes and adjacent valley floors with stream channels were studied. Landsliding on slopes was dated from the tree‐ring eccentricity developed in stems tilted due to bedrock instability. Erosion in channels was dated using the wood anatomy of roots exposed by erosion of the soil cover. Analysis of the temporal relations between dated landsliding, erosion and precipitation record has revealed that two types of repeating sequences can be observed: (1) rainfall → landsliding → erosion; (2) rainfall → erosion → landsliding. These sequences are an indication of the occurrence of slope‐channel positive feedback in the sites studied. In the first type, landsliding triggered by rainfall delivers colluvia into the valley floor and causes its narrowing, which in turn causes increased erosion. In the second type erosion triggered by rainfall disturbs the slope equilibrium and causes landsliding. Landsliding and erosion, once triggered by precipitation, can occur alternately in years with average precipitation and reinforce one another. Bidirectional coupling between landsliding and channel erosion was shown notably through the effects of channel shifting and forced sinuosity and by increased erosion of the slopes opposite the active landslides. Observations also suggest that the repetition of sequences described over longer periods of time can lead to a general widening of the valley floor at the expense of slopes and to a gradual change of the valley cross‐profile from narrow, V‐shaped into a wide flat‐bottomed. Thus landsliding–erosion coupling/positive feedback was recognized as an important factor shaping hillslope–valley topography of the mid‐mountain areas studied. Copyright © 2014 John Wiley & Sons, Ltd.     

An updated method for estimating landslide‐event magnitude

Summary statistics derived from the frequency–area distribution (FAD) of inventories of triggered landslides allows for direct comparison of landslides triggered by one event (e.g. earthquake, rainstorm) with another. Such comparisons are vital to understand links between the landslide‐event and the environmental characteristics of the area affected. This could lead to methods for rapid estimation of landslide‐event magnitude, which in turn could lead to estimates of the total triggered landslide area. Previous studies proposed that the FAD of landslides follows an inverse power‐law, which provides the basis to model the size distribution of landslides and to estimate landslide‐event magnitude (mLS), which quantifies the severity of the event. In this study, we use a much larger collection of earthquake‐induced landslide (EQIL) inventories (n=45) than previous studies to show that size distributions are much more variable than previously assumed. We present an updated model and propose a method for estimating mLS and its uncertainty that better fits the observations and is more reproducible, robust, and consistent than existing methods. We validate our model by computing mLS for all of the inventories in our dataset and comparing that with the total landslide areas of the inventories. We show that our method is able to estimate the total landslide area of the events in this larger inventory dataset more successfully than the existing methods. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.     

Kinetic Studies and Anaerobic Co‐digestion of Vegetable Market Waste and Sewage Sludge

The effect of anaerobic co‐digestion of vegetable market waste and sewage sludge was studied extensively. The effects of co‐digestion were compared with the separate digestion of vegetable market waste and sewage sludge. The batch studies were carried out using three bench scale reactors having 1.5 L working volume. The cumulative biogas production shows that the organic waste available from the vegetable waste contains easily biodegradable organic matter compared with the sewage sludge. First order reaction kinetics is maintained throughout the methanation fermentation. The reductions in volatile solids (VS) in the three reactors were in the range of 63–65 %. The specific gas production for vegetable waste was higher (0.75 L biogas/g VS_in and 1.17 L biogas/g VS_des) than for the sewage sludge (0.43 L biogas/g VS_in and 0.68 L biogas/g VS_des). Consequently, the specific gas production for the co‐digestion of the mixture of vegetable waste and sewage sludge (0.68 L biogas/g VS_in and 1.04 L biogas/g VS_des) was considerably higher than for the sewage sludge only. Batch kinetics of anaerobic digestion is useful in predicting the performance of digesters and for the design of appropriate digesters.     

Hazardous Waste Pollution Prevention Using Clay with Admixtures

Landfill is the most commonly used method for disposal of waste materials since it is one of the least expensive methods. In order to dispose of any hazardous material to a landfill, a liner is used, which protects the underlying land and groundwater since it acts as a barrier to fluid movement. Of the various methods available for providing improved and more effective properties of landfills, methods involving the use of bentonite, cement, lime, gypsum, etc., have been explored in the laboratory. The aim is to overcome the problem and deficiencies of the existing liners. It is observed from the experimental results that the metal concentrations of the input waste solution can be reduced to 80–98% using a soil‐cement admixture, 60–95% using a soil‐gypsum mixture, 45–95% using a soil‐bentonite mixture, 50–90% for soil, 35–80% using a soil‐lime mixture, as liner materials. The permeation rate of different metals through the different soil‐admixture media depends on various factors. A simple mathematical treatment of the phenomenon related to the permeation of liquid through the admixture of the clay and other components has been developed. The experimental results show satisfactory agreement with the predictions.     

Regeneration and Reuse of a Seaweed‐Based Biosorbent in Single and Multi‐Metal Systems

A seaweed‐waste material resulting from the processing of Ascophyllum nodosum was previously shown to be very efficient at removing Zn(II), Ni(II) and Al(III) both in single and multi‐metal waste streams. In this study, the regeneration of the biosorbent using an acid wash resulted in the release of high metal concentrations during multiple desorption cycles. Maximum desorption efficiencies (DE) of 183, 122 and 91% were achieved for Zn(II), Ni(II) and Al(III), respectively, for subsequent metal loading cycles, significantly exceeding the desorption rates observed for conventional sorbents. The regeneration of the sorbent was accomplished with very little loss in metal removal efficiency (RE) for both single and multi‐metal systems. Values of 92, 96 and 94% RE were achieved for Zn(II), Ni(II) and Al(III), respectively, for the 5^th sorption cycle in single metal aqueous solutions. A slight decrease was observed for the same metals in multi‐metal systems with maximum REs of 85, 82 and 82% for Zn(II), Ni(II) and Al(III), respectively. This study showed that the novel sorbent derived from a seaweed industrial waste would be suitable for multiple metal sorption cycles without any significant loss in RE.     

Prediction of the median IDA curve by employing a limited number of ground motion records

A methodology has been proposed which can be used to reduce the number of ground motion records needed for the reliable prediction of the median seismic response of structures by means of incremental dynamic analysis (IDA). This methodology is presently limited to predictions of the median IDA curve only. The reduction in the number of ground motion records needed to predict the median IDA curve is achieved by introducing a precedence list of ground motion records. The determination of such a list is an optimization problem, which is solved in the paper by means of (1) a genetic algorithm and (2) a proposed simple procedure. The seismic response of a simple, computationally non‐demanding structural model has been used as input data for the optimization problem. The presented example is a three‐storey‐reinforced concrete building, subjected to two sets of ground motion records, one a free‐field set and the other a near‐field set. It is shown that the median IDA curves can be predicted with acceptable accuracy by employing only four ground motion records instead of the 24 or 30 records, which are the total number of ground motion records for the free‐field and near‐field sets, respectively. Copyright © 2007 John Wiley & Sons, Ltd.     

我国高放废物处置库的选址与能动断层研究

随着我国核电工业建设步伐的加快,高放废物处置库的场址选择成为当前极为紧迫的课题。本文分析了甘肃北山高放废物处置库的选址现状,提出应加快相关核安全法规的建设以指导场址的选择;应对北山地区补充地震地质调查工作,特别是对区内的几条断层要进行断层能动性的研究。这对场址的适宜性是一个带有颠覆性的问题。     

Enhancing the Performance of Anaerobic Digestion of Dairy Manure through Phase‐Separation

Anaerobic digestion (AD) is an effective way to convert animal manures into profitable by‐products while simultaneously reducing the pollution of water, air, and soil caused by these wastes. Conventional high‐rate anaerobic reactors cannot effectively process animal manures with high solids‐containing wastes. The two‐phase configuration for AD has several advantages over conventional one‐phase processes, e. g., increased stability of the process, smaller size and cost efficient process configurations. In the present study, the experiments were carried out in a two‐phase system composed of an acidogenic reactor and a methanogenic reactor, and in a one‐phase system composed of only a methanogenic reactor. The reactors were operated as unmixed (without an external mixing aid), unsophisticated, and daily‐fed mode. It was found that the two‐phase configuration was more efficient than the one‐phase system. The biogas production in the two‐phase system at a hydraulic retention time (HRT) of 8.6 days (only methanogenic phase) was calculated to be 42% higher at an organic loading rate (OLR) of 3.5 g VS/L·day than that of the one‐phase with a HRT of 20 days. This translates into significant performance improvement and reduced volume requirement. This finding represents a further step in the achievement of wider use of simple anaerobic reactor configurations for waste treatment in rural areas.     

Design of store‐release covers to minimize deep drainage in the mining and waste‐disposal industries: results from a modelling analyses based on ecophysiological principles

Sustainable long‐term storage of municipal waste and waste rock from mining activities in waste dumps (either above or below the land surface) requires minimization of percolation of rainwater into and then through stored waste material. There has been increasing attention given to the use of store‐release covers (transpirational covers) to achieve this. However, the design of such covers remains problematic because of the unique combinations of weather, vegetation composition, soils and their interactions that determine the efficacy of each design that could be available for the construction of the covers. The aim of the work described here was to use ecophysiological knowledge of soil‐plant‐atmosphere (SPA) interactions through the application of a detailed mechanistic model of the SPA continuum. We examined the relative influence of soil depth, soil texture, leaf area index and rainfall as determinants of rates of evapotranspiration and water budget for several different theoretical cover designs. We show that minimizing deep drainage requires a cover that has the following attributes: (i) a water storage capacity that is large enough to store the volume of water that is received as rainfall in above‐average wet months/seasons; (ii) a root distribution that explores the entire depth of the cover; (iii) a leaf area index that is present all year sufficient to evapotranspire monthly rainfall; and (iv) takes into account the intra‐annual and inter‐annual variability in rainfall and other climatic variables that drive ET. Copyright © 2012 John Wiley & Sons, Ltd.     

Filtering action of embedded massive foundations: New analytical expressions and evidence from 2 instrumented buildings

This paper deals with the effect of the foundation mass on the filtering action exerted by embedded foundations. The system under examination comprises a rigid rectangular foundation embedded in a homogeneous isotropic viscoelastic half‐space under harmonic shear waves propagating vertically. The problem is addressed both theoretically and numerically by means of a hybrid approach, where the foundation mass is explicitly included in the kinematic interaction between the foundation and the surrounding soil, thus referring to a “quasi‐kinematic” interaction problem. Based on the results of an extensive parametric study, it is shown that the filtering problem depends essentially on three dimensionless parameters, i.e.: the dimensionless frequency of the input motion, the foundation width‐to‐embedment depth ratio, and the foundation‐to‐soil mass density ratio. In complements to the translational and rotational kinematic interaction factors that are commonly adopted to quantify the filtering effect of rigid massless foundations on the free‐field motion, an additional kinematic interaction factor is introduced, referring to the horizontal motion at the top of a rigid massive foundation. New analytical expressions for the above kinematic interaction factors are proposed and compared with foundation‐to‐free‐field transfer functions computed from available earthquake recordings on two instrumented buildings in LA (California) and Thessaloniki (Greece). Results indicate that the foundation mass can have a strong beneficial effect on the filtering action with increasing foundation‐to‐soil mass density and foundation width‐to‐embedment depth ratios.     

A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.     

Surface‐wave inversion for a P‐velocity profile with a constant depth gradient of the squared slowness

Surface waves are often used to estimate a near‐surface shear‐velocity profile. The inverse problem is solved for the locally one‐dimensional problem of a set of homogeneous horizontal elastic layers. The result is a set of shear velocities, one for each layer. To obtain a P‐wave velocity profile, the P‐guided waves should be included in the inversion scheme. As an alternative to a multi‐layered model, we consider a simple smooth acoustic constant‐density velocity model, which has a negative constant vertical depth gradient of the squared P‐wave slowness and is bounded by a free surface at the top and a homogeneous half‐space at the bottom. The exact solution involves Airy functions and provides an analytical expression for the dispersion equation. If the ratio is sufficiently small, the dispersion curves can be picked from the seismic data and inverted for the continuous P‐wave velocity profile. The potential advantages of our model are its low computational cost and the fact that the result can serve as a smooth starting model for full‐waveform inversion. For the latter, a smooth initial model is often preferred over a rough one. We test the inversion approach on synthetic elastic data computed for a single‐layer P‐wave model and on field data, both with a small ratio. We find that a single‐layer model can recover either the shallow or deeper part of the profile but not both, when compared with the result of a multi‐layer inversion that we use as a reference. An extension of our analytic model to two layers above a homogeneous half‐space, each with a constant vertical gradient of the squared P‐wave slowness and connected in a continuous manner, improves the fit of the picked dispersion curves. The resulting profile resembles a smooth approximation of the multi‐layered one but contains, of course, less detail. As it turns out, our method does not degrade as gracefully as, for instance, diving‐wave tomography, and we can only hope to fit a subset of the dispersion curves. Therefore, the applicability of the method is limited to cases where the ratio is small and the profile is sufficiently simple. A further extension of the two‐layer model to more layers, each with a constant depth gradient of the squared slowness, might improve the fit of the modal structure but at an increased cost.     

Research Note: Near‐surface layer replacement for sparse data: is interpolation needed?

Near‐surface problem is a common challenge faced by land seismic data processing, where often, due to near‐surface anomalies, events of interest are obscured. One method to handle this challenge is near‐surface layer replacement, which is a wavefield reconstruction process based on downward wavefield extrapolation with the near‐surface velocity model and upward wavefield extrapolation with a replacement velocity model. This requires, in theory, that the original wavefield should be densely sampled. In reality, data acquisition is always sparse due to economic reasons, and as a result in the near‐surface layer replacement data interpolation should be resorted to. For datasets with near‐surface challenges, because of the complex event behaviour, a suitable interpolation scheme by itself is a challenging problem, and this, in turn, makes it difficult to carry out the near‐surface layer replacement. In this research note, we first point out that the final objective of the near‐surface layer replacement is not to obtain a newly reconstructed wavefield but to obtain a better final image. Next, based upon this finding, we propose a new thinking, interpolation‐free near‐surface layer replacement, which can handle complex datasets without any interpolation. Data volume expansion is the key idea, and with its help, the interpolation‐free near‐surface layer replacement is capable of preserving the valuable information of areas of interest in the original dataset. Two datasets, i.e., a two‐dimensional synthetic dataset and a three‐dimensional field dataset, are used to demonstrate this idea. One conclusion that can be drawn is that an attempt to interpolate data before layer replacement may deteriorate the final image after layer replacement, whereas interpolation‐free near‐surface layer replacement preserves all image details in the subsurface.     

Contaminant transport in one‐dimensional single fractured media: semi‐analytical solution for three‐member decay chain with pulse and Heaviside input sources

A semi‐analytical solution of the one‐dimensional transport for considering a three‐member decay chain in a single fracture with pulse and Heaviside input sources has been studied using the Laplace transform and its numerical inversion. The results reveal that breakthrough curves of dimensionless concentration for the decay chain of Np‐237, U‐233, and Th‐229 in the fracture can be well demonstrated in the temporal and spatial domains. The conditions with and without retardation effects are also compared. During the preliminary screening phase the solutions are suitable for performance assessment on radioactive waste disposal sites under a one‐dimensional single fracture condition. Copyright © 2007 John Wiley & Sons, Ltd.     

Monitoring of organic micropollutants in Ghana by combination of pellet watch with sediment analysis: E-waste as a source of PCBs

Plastic resin pellets collected at 11 beaches covering the whole Ghanaian coastline were analyzed for polychlorinated biphenyls (PCBs). PCB concentrations (∑13 congeners) were higher in Accra, capital city, and Tema (39–69 ng/g-pellets) than those in rural coastal towns (1–15 ng/g-pellets) which are close to global background, indicating local inputs of PCBs. River sediments were also analyzed for PCBs together with molecular markers. Sedimentary PCBs concentrations were highest at a site (AR02) downstream of an electronic waste (e-waste) scrapyard. At the site (AR02), concentration of linear alkylbenzenes (LABs), a marker of municipal wastewater, was lower than another site (AR03) which is located at the downstream of downtown Accra. This result suggests that PCBs are introduced more to the river from the e-waste site than from activities in downtown Accra. PAHs concentrations were relatively higher in urban areas with strong petrogenic signature. Abundance of triphenylbenzenes suggested plastic combustion near e-waste scrapyard.