Patterns of Chemical Changes During Environmental Alteration of Hydrocarbon Fuels

This paper discusses major environmental alteration processes and describes a set of chemical tests that have been developed to monitor compositional changes in hydrocarbon fuels released into the environment. The methods examine various homologous series of hydrocarbons including straight chain (paraffins or n-alkanes), branched chain (isoparaffins or isoprenoids), alicyclic (naphthenes or alkylated cyclohexanes), polycyclic (steranes and terpanes), and aromatic structures (benzene, toluene, ethylbenzene. xylenes, alkylated benzenes, polycyclic aromatic hydrocarbons, and aromatic steranes). Each one of these groups of hydrocarbons has a different tolerance to environmental alteration by evaporation, dissolution (water washing), and biodegradation. When used as an analytical system on environmental samples, the data obtained provide information on fuel type recognition patterns and on degradation levels of the various fuels, allowing for an estimate of residence time.     

Composition and sources of pollutant hydrocarbons in the Severn Estuary

Hydrocarbon distributions in sediment from the Severn Estuary can be explained mainly in terms of a pollutant origin. The aliphatic hydrocarbon distribution is similar to that found in biodegraded crude oils. The distribution of polycyclic aromatic hydrocarbons, including the carcinogen benzo(a)pyrene, is similar to that derived from the pyrolysis of fossil fuels, especially petroleum.     

Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides in water columns from the Pearl River and the Macao harbor in the Pearl River Delta in South China

Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) were measured in suspended particles and dissolved phase from the Baiertang water column and the Macao water column samples as collected from the Guangzhou channel of the Pearl River and the Macao harbor, where the sediments were heavily contaminated with organic pollutants. Total OCPs concentration varies from 23.4 to 61.7 ng/l in Baiertang water column and from 25.2 to 67.8 ng/l in Macao column, while total PAHs concentration varies from 987.1 to 2878.5 ng/l in the Baiertang water column and from 944.0 to 6654.6 ng/l in the Macao column. The vertical distribution profiles of pollutants and the partition of pollutants between particles and dissolved phases indicate that the sediments in Baiertang act as an important source of selected pollutants, and the pollutants in water of this region were mainly originated from the release and re-suspension of contaminants residing in the sediments. The sediments in Macao harbor act as a reservoir for organochlorine pesticides, such as DDTs mainly introduced by river inflow from Xijiang and PAHs input by brackish water from the Lingdingyang estuary. Combustion of fossil fuels and petroleum input are the main sources of PAHs in the Macao water column, while combustion of fossil fuels and coal is responsible for the PAHs in the Baiertang water column. The ratios of DDT/(DDD+DDE) for the Macao water column samples demonstrate that such chemicals were input into this region in recent times.     

CO2 Capture and Geologic Storage: The Possibilities

Carbon dioxide (CO₂) capture and geologic storage has been postulated as one possible method to stabilize the atmospheric concentration of CO₂ by injecting and storing it in deep geologic formations. This issue paper analyzes the viability of capture and geologic storage of becoming an effective method to aid in stabilizing the atmospheric concentration of CO₂. It is herein shown that such viability is contingent on overcoming major obstacles that are hydrogeological, technical, and economic in nature. Our analysis indicates that capture and geologic storage is likely to have negligible success in reducing the atmospheric buildup of CO₂ in the coming decades. The magnitude of the anthropogenic emissions of CO₂ indicates that a transition of the world economy away from reliance on fossil fuels might be the only path to stabilize its atmospheric concentration.     

Projecting future sea level

Through the use of fossil fuels as an energy source, mankind is slowly changing the constitution of the atmosphere. The emission of CO₂ and other greenhouse gases changes the radiative properties of the earth/atmosphere system, and as a result climate is expected to become warmer. As a starting point for the sea-level rise scenario discussed here it is assumed that the globally-averaged increase of surface air temperatures will amount to 2 to 4°C in the second half of the next century (i.e. around 2085 AD). One of the consequences of this warming is an accelerated rise in sea level, caused by thermal expansion of ocean water and further retreat of mountain glaciers. The Greenland Ice Sheet will also decrease in size, but on the other hand, Antarctica is expected to grow slightly due to increased snowfall. Taken together, the projection for future sea level presented here suggest that by 2085 AD, global sea-level stand will be 28–66 cm higher than the present level, which implies a rate of sea-level rise of about 2 to 4 times that observed during the last 100 yr. Our scenario does not include a contribution resulting from the possible collapse of the West Antarctic Ice Sheet. If this collapse is indeed likely to occur after the major peripheral ice shelves have thinned considerably, the effects on sea level will be small in the coming 100 yr. First, the oceans surrounding Antarctica must have warmed sufficiently to reduce the winter sea-ice extent to allow circumpolar deep water to penetrate into the sub-shelf cavities, thus increasing basal melt rates on the ice shelves. Of course, on longer time scales, West Antarctica could become the major contributor to rising sea level.     

Chromatographic separation of diasteriomeric isoprenoids for the identification of fossil oil contamination

In aliphatic hydrocarbon fractions of crude oils eight acyclic isoprenoid alkanes were separated from accompanying n-alkanes and iso-alkanes by high-performance glasscapillary gas chromatography. Four of these: 2,6,10-trimethyltetradecane (V), norpristane (IV), pristane (III), and phytane (II) could be resolved further to reveal a doublet produced by the different diastereoisomers.In these doublets the front peak represents stereoisomers formed during maturation of crude oil while the rear peak indicates the respective hydrocarbons carrying the original biogenic precursor configuration. This appearance of doublets demonstrates the loss of stereospecificity in hydrocarbons derived from phytol (I). By using the front peaks as diagenetic ‘maturity markers’ attributable to fossil fuels, hydrocarbon mixtures extracted from sea water samples contaminated with fossil oil could be investigated in detail. The quantitative relationship between recent biogenic and fossil fuel hydrocarbons could be determined in extracts in the lower boiling point range.     

Paleoenvironmental interpretations of Quaternary reef deposits based on comparisons of 10 selected modern and fossil larger foraminifera from the Ryukyu Islands, Japan

Abstract A new method for reconstructing depositional environments of larger foraminifera‐bearing limestones is proposed. First, depth and spatial distributions of empty tests of 10 foraminiferal taxa in a 1–2 mm size fraction were examined using 32 surface sediment samples collected from depths shallower than 200 m, located to the west of Miyako Island, Ryukyu Islands, northwest Pacific. Distributional ranges of empty tests in the 1–2 mm size fraction appear to be more limited than those including other size fractions in previous reports, partly because larger empty tests of each taxon are less easily transported than smaller ones. Multivariate analyses (Q‐mode cluster analysis and non‐metric multidimensional scaling ordination) based on binary (presence/absence) data of the 10 taxa delineate four sample groups, each of which corresponds to different depositional environments: nearshore zone/bay inlet; back‐reef to fore‐reef; outer shelf to shelf slope; and shelf slope distant from coral reefs. Next, these modern data were applied to reconstruct the depositional environment of a rock section distributed in the Shiratorizaki area (Irabu Island, Ryukyu Islands), which consists of larger foraminiferal limestone of the Pleistocene Ryukyu Group. Multivariate analyses were performed on the fossil plus the modern foraminiferal data to explore the possible relationship of the fossil associations with variations in modern associations, demonstrating that the fossil foraminiferal associations resemble the modern outer shelf associations. The modern analog technique was also applied to estimate paleobathymetry using fossil foraminiferal data. The results indicate that the section studied was deposited in outer shelf environments at depths between 53.5 and 98.6 m. These paleoenvironmental interpretations are consistent with previous studies based on sedimentary facies and the computer‐based expert system. The modern dataset and methods used in our work would be particularly useful for paleoenvironmental reconstructions of Quaternary reef and shelf carbonates along active margins of the northwest Pacific.     

Effect of human‐controlled hydrological regime on the source,transport, and flux of particulate organic carbon from the lower Huanghe (Yellow River)

Evaluating the role of fluvial transfer of terrestrial organic carbon (OC) and subsequent burial in the global carbon cycle requires the sources and fluxes of fluvial OC to be assessed, which remains poorly constrained in the Huanghe (Yellow River). Here, we report the elemental, stable isotopic, and radiocarbon activity of particulate organic carbon (POC) sampled at the outlet of Huanghe in 2012–2013. We show that the Huanghe riverine POC can be explained by binary mixing of fossil (POC_fossil) and non‐fossil (POC_non‐fossil) components, the former may reach ~40% of the total POC. The Huanghe POC_non‐fossil is mostly sourced from C3 plants, with a mean residence time of c. 2200 years. The current human‐controlled hydrological regime strongly influenced the POC sources, transport modes, and fluxes. In 2012–2013, the Huanghe delivered 0.73 Tg (1 Tg = 10¹² g) of POC to the sea, and about 28% of the annual POC flux occurred within a short human induced flood event. Globally, the Huanghe should be one of the largest rivers in the transfer and re‐burial of fossil OC. However, the fate of Huanghe fossil OC is still unconstrained and needs to be further investigated. Copyright © 2015 John Wiley & Sons, Ltd.     

东太湖沉积物中多环芳烃-菲系列化合物的来源探讨

本文用索氏抽取法提取了东太湖的沉积物和水生植物中的可溶性有机质,用不同极性溶剂在硅胶／氧化铝柱上分离了饱和烃、芳烃、酮馏分,利用GC-MS至芳烃组分进行了鉴定分析,并对其中重要多环芳烃－菲系列化合物的来源进行了探讨。     

Aliphatic and aromatic hydrocarbons in benthic invertebrates from two sites in Antarctica

Samples of marine benthic invertebrates collected from two sites in the Antarctic have been analysed for both aliphatic and aromatic hydrocarbons in order to establish baseline concentrations for some classes of hydrocarbons.Samples from Signy Island, a pristine site, contained low concentrations of the hydrocarbons determined, whereas those from King Edward Cove, South Georgia, contained significantly higher concentrations. King Edward Cove has a known history of pollution from whaling operations.Platt & Mackie (1979) have suggested that the hydrocarbons in sediments from King Edward Cove are a result of the world-wide dissemination of the pyrolysis products of fossil fuels. Our work suggests, in contrast, that the hydrocarbons in the benthos are derived from local sources.     

Recent history provides sustainable African water quality project insight

Small-scale projects to provide clean drinking water undertaken in the developing world can contribute to significantly improving the livelihood of rural communities. There has been a historical tendency to poorly plan such projects leading to an unsustainable future. Recent history indicates three simple steps to ensuring successful and enduring clean water projects. First, identification of need by the indigenous community provides ownership in the project. Second, a partnership between key individuals in the indigenous community with the donor provides for ambassadors on both sides of the project. Finally, an exit strategy by the donors for the indigenous communities ensures local sustainability for the future. The study site is the village of Geisha in northern Malawi, Africa. Sustainable implementation approaches are discussed in this case study as well as the various lessons learned. Improved project processes ensure sustainable small-scale water quality projects by donor organizations in developing countries.     

The acute toxicity of motor fuels to brackish water organisms

The addition of synthetic additives, such as methanol and methyl tertiary butyl ether (MTBE) to the base fuel, with the aim of raising the octane content of motor fuel, is currently of special interest in Sweden. A question, which has to be solved, is whether it is preferable to carry the additives by ship in separate tanks, because of the probable enhanced toxicity of the motor fuels by the addition of solvents, or not. The acute toxicity of these blend fuels has been compared with the acute toxicity of base fuel, gasoline and low leaded gasoline. As test organisms, two representative species of the Baltic Sea have been used, the harpacticoid Nitocra spinipes and the bleak, Alburnus alburnus. The results of the tests show that the acute toxicity of base fuel to aquatic organisms is not increased by the addition of 15% methanol or 5% MTBE.     

The impact of climate change on extreme precipitation in Sicily,Italy

Increasing precipitation extremes are one of the possible consequences of a warmer climate. These may exceed the capacity of urban drainage systems, and thus impact the urban environment. Because short‐duration precipitation events are primarily responsible for flooding in urban systems, it is important to assess the response of extreme precipitation at hourly (or sub‐hourly) scales to a warming climate. This study aims to evaluate the projected changes in extreme rainfall events across the region of Sicily (Italy) and, for two urban areas, to assess possible changes in Depth‐Duration‐Frequency (DDF) curves. We used Regional Climate Model outputs from Coordinated Regional Climate Downscaling Experiment for Europe area ensemble simulations at a ~12 km spatial resolution, for the current period and 2 future horizons under the Representative Concentration Pathways 8.5 scenario. Extreme events at the daily scale were first investigated by comparing the quantiles estimated from rain gauge observations and Regional Climate Model outputs. Second, we implemented a temporal downscaling approach to estimate rainfall for sub‐daily durations from the modelled daily precipitation, and, lastly, we analysed future projections at daily and sub‐daily scales. A frequency distribution was fitted to annual maxima time series for the sub‐daily durations to derive the DDF curves for 2 future time horizons and the 2 urban areas. The overall results showed a raising of the growth curves for the future horizons, indicating an increase in the intensity of extreme precipitation, especially for the shortest durations. The DDF curves highlight a general increase of extreme quantiles for the 2 urban areas, thus underlining the risk of failure of the existing urban drainage systems under more severe events.     

中国主体能源——煤炭的第二深度空间勘探、开发和高效利用

化石能源包括石油、天然气和煤炭,它们是一次性不可再生能源.我国与世界发达国家相比在能源结构上存在很大差异,在全球范围内化石能源结构中多以石油为主体,而我国基于本土的优势资源和特点则以煤炭为主体.随着我国工业化的进程和经济的腾飞对化石能源的需求日益大幅度的增加,使得煤炭资源的深层勘探,即第二深度空间(500～2000 m)的勘探与开采必须迅速提上日程.当然在开采过程中的难度亦必随之增大,特别是深层复杂构造与岩石的物理-力学属性;机械化的适宜采掘技术;高浓度的大量瓦斯溢出;介质与结构的高应力状态;地下温度的升高和大量涌水等灾害.因此必须引入当代高、新技术,强化高精度探测与数据采集和对介质破裂过程的高分辨动态监测与防范.同时必须提高煤炭的高效和多元化综合利用;特别是煤炭液化和发展洁净煤技术,以达在我国能源结构中的主体能源--煤炭能发挥更大的效能并造福于人类!     

Peatland restoration: controls on sediment production and reductions in carbon and pollutant export

Peatlands are an important store of soil carbon, and play a vital role in global carbon cycling, and when located in close proximity to urban and industrial areas, can also act as sinks of atmospherically deposited heavy metals. Large areas of the UK's blanket peat are significantly degraded and actively eroding which negatively impacts carbon and pollutant storage. The restoration of eroding UK peatlands is a major conservation concern, and over the last decade measures have been taken to try to control erosion and restore large areas of degraded peat. This study utilizes a sediment source fingerprinting approach to assess the effect of restoration practices on sediment production, and carbon and pollutant export in the Peak District National Park, southern Pennines (UK). Suspended sediment was collected using time integrated mass flux samplers (TIMS), deployed across three field areas which represent the surface conditions exhibited through an erosion–restoration cycle: (i) intact; (ii) actively eroding; and (iii) recently re‐vegetated. Anthropogenic pollutants stored near the peat's surface have allowed material mobilized by sheet erosion to be distinguished from sediment eroded from gully walls. Re‐vegetation of eroding gully systems is most effective at stabilizing interfluve surfaces, switching the locus of sediment production from contaminated surface peat to relatively ‘clean’ gully walls. The stabilization of eroding surfaces reduces particulate organic carbon (POC) and lead (Pb) fluxes by two orders of magnitude, to levels comparable with those of an intact peatland, thus maintaining this important carbon and pollutant store. The re‐vegetation of gully floors also plays a key role in decoupling eroding surfaces from the fluvial system, and further reducing the flux of material. These findings indicate that the restoration practices have been effective over a relatively short timescale, and will help target and refine future restoration initiatives. Copyright © 2014 John Wiley & Sons, Ltd.     

Mars Global Digital Dune Database (MGD3): north polar region (MC‐1) distribution,applications, and volume estimates

The Mars Global Digital Dune Database (MGD³) now extends from 90°N to 65°S. The recently released north polar portion (MC‐1) of MGD³ adds ~844 000 km² of moderate‐ to large‐size dark dunes to the previously released equatorial portion (MC‐2 to MC‐29) of the database. The database, available in GIS‐ and tabular‐format in USGS Open‐File Reports, makes it possible to examine global dune distribution patterns and to compare dunes with other global data sets (e.g. atmospheric models). MGD³ can also be used by researchers to identify areas suitable for more focused studies. The utility of MGD³ is demonstrated through three example applications. First, the uneven geographic distribution of the dunes is discussed and described. Second, dune‐derived wind direction and its role as ground truth for atmospheric models is reviewed. Comparisons between dune‐derived winds and global and mesoscale atmospheric models suggest that local topography may have an important influence on dune‐forming winds. Third, the methods used here to estimate north polar dune volume are presented and these methods and estimates (1130 km³ to 3250 km³) are compared with those of previous researchers (1158 km³ to 15 000 km³). In the near future, MGD³ will be extended to include the south polar region. Published in 2011. This article is a US Government work and is in the public domain in the USA.     

The role of gravity waves in tropospheric processes

Summary The nature and the role of gravity waves in the troposphere is briefly discussed and reviewed. After describing some basic properties of gravity waves and their generation mechanisms, we analyze their ability to influence phase changes, trigger and organize convective cells, to produce and interact with turbulence, and to affect diffusive processes in the atmosphere. Throughout, the emphasis is placed on the physical processes involved in the interaction of gravity waves with mesoscale and planetary boundary layer phenomena. Also discussed and reviewed are those remote sensing devices which are particularly useful in revealing and measuring such waves. Finally, an attempt is made to outline possible lines of future work for the purpose of fully understanding the role of gravity waves in mesoscale and microscale dynamics.     

Effects of offshore platforms on soft-bottom macro-benthic assemblages: a case study in a Mediterranean gas field

The exploitation of fossil fuels in the Mediterranean Sea will likely lead to an increase in the number of offshore platforms, a recognized threat for marine biodiversity. To date, in this basin, few attempts have been made to assess the impact of offshore gas and oil platforms on the biodiversity of benthic assemblages. Here, we adopted a structured experimental design coupled with high taxonomic resolution to outline putative effects of gas platforms on soft-bottom macrofauna assemblages in the North Ionian Sea. The analysis was based on a total of 20,295 specimens of 405 taxa, almost entirely identified at species level. Multivariate and univariate analyses showed idiosyncratic patterns of assemblage change with increasing distance from the platforms. Potential reasons underlying such inconsistency are analyzed and the view that structured experimental monitoring is a crucial tool to quantify the extent and magnitude of potential threats and to provide sound baseline information on biodiversity patterns is supported.     

Determination of Critical Factors in Implementing River Clean‐Up Projects: A Malaysian Case Study

Fast economic growth of a country contributes to the increase of activities that can also bring negative impacts on the rivers. Contamination of rivers, sedimentation, coastal erosion, decrease of aquatic life, and also flooding are some of these universal impacts. There are several rivers around the world, which are categorized as very polluted and require cleaning‐up operations. Several factors have been identified to be influencing factors in the success or otherwise of the implementation and operation of these projects. This study examined the factors related to the steps taken to clean‐up and rehabilitate these rivers and deduce by utilizing factor analysis the most critical success factors from the results obtained. A responsible river community is by far the most effective way to keep a river basin clean. Very often, however, cleaning‐up operations are necessary to revive and maintain the quality of the river so that it can be save to use as an important source of water for human consumption. It was found that community awareness was the most critical cluster of factors determining the success of the clean‐up work.     

Climate change impact on Caspian Sea wave conditions in the Noshahr Port

Excessive usage of fossil fuels and high emission of greenhouse gases have increased the earth’s temperature and consequently have led to changes in wind and wave regimes. The main effects of climate change on oceans are warming of the ocean water, melting of ice, acidification of ocean water, and change in the ocean currents. The main effects of climate change on coastal regions are change in the coast hydrodynamics, sea level rise, change in wave height, coastal erosion, coastal structure damage, food shortage, and storms. Due to the importance of waves in the coastal zone and its effect on erosion and sedimentation, it is necessary to study wave changes. In this study, the effect of climate change on wave specifications was evaluated in the southern coast of the Caspian Sea in Noshahr Port. To simulate wave parameters, the third generation spectral Simulating WAves Nearshore (SWAN) model was used. Wave modeling was carried out using the SWAN numerical model for two 30-yearly periods, including the control period (1984 to 2014) and the future period (2051 to 2080). For wave modeling in the control period, the European Center for Average Weather Forecast wind field was used, and for the future period, a downscaled wind field from Coordinated Regional Downscaling Experiment projection, which was sponsored by World Climate Research Programme, based on the most recent emission scenarios RCP2.6, RCP4.5, and RCP8.5, was used. The model results were calibrated and verified with buoy-recorded data. The effect of the climate change on the wave parameters was evaluated by studying the differences between the patterns in three scenarios and the control period. Results showed that the 30-year maximum significant wave height will increase because of climate change, and the wave direction will not change. In addition, the intensity of storms will increase in the future.