Hydrological and isotopic characterization of river water,groundwater, and groundwater recharge in the Heihe River basin,northwestern China

We used hydrochemistry and environmental isotope data (δ¹⁸O, δD, tritium, and ¹⁴C) to investigate the characteristics of river water, groundwater, and groundwater recharge in China's Heihe River basin. The river water and groundwater could be characterized as Ca²⁺? Mg²⁺? HCO₃^?? SO₄^2? and Na⁺? Mg²⁺? SO₄^2?? Cl^? types, respectively. Hydrogeochemical modelling using PHREEQC software revealed that the main hydrogeochemical processes are dissolution (except for gypsum and anhydrite) along groundwater flow paths from the upper to middle Heihe reaches. Towards the lower reaches, dolomite and calcite tend to precipitate. The isotopic data for most of the river water and groundwater lie on the global meteoric water line (GMWL) or between the GMWL and the meteoric water line in northwestern China, indicating weak evaporation. No direct relationship existed between recharge and discharge of groundwater in the middle and lower reaches based on the isotope ratios, d‐excess, and ¹⁴C values. On the basis of tritium in precipitation and by adopting an exponential piston‐flow model, we evaluated the mean residence time of shallow groundwater with high tritium activities, which was around 50 years (a). Furthermore, based on the several popular models, it is calculated that the deep groundwaters in piedmont alluvial fan zone of the middle reaches and in southern part of the lower reaches are modern water, whereas the deep groundwaters in the edge of the middle reaches and around Juyan Lake in the lower reaches of Heihe river basin are old water. Copyright © 2010 John Wiley & Sons, Ltd.     

Characteristics of chemistry and stable isotopes in groundwater of Chaobai and Yongding River basin,North China Plain

To identify the groundwater flow system in the North China Plain, the chemical and stable isotopes of the groundwater and surface water were analysed along the Chaobai River and Yongding River basin. According to the field survey, the study area in the North China Plain was classified hydrogeologically into three parts: mountain, piedmont alluvial fan and lowland areas. The change of electrical conductance and pH values coincided with groundwater flow from mountain to lowland areas. The following groundwater types are recognized: Ca? HCO₃ and Ca? Mg? HCO₃ in mountain areas, Ca? Mg? HCO₃ and Na? K? HCO₃ in piedmont alluvial fan areas, and HCO₃? Na in lowland areas. The stable isotope distribution of groundwater in the study area also has a good corresponding relation with other chemical characteristics. Stable isotope signatures reveal a major recharge from precipitation and surface water in the mountain areas. Chemical and stable isotope analysis data suggest that mountain and piedmont alluvial fan areas were the major recharge zones and the lowland areas belong to the main discharge zone. Precipitation and surface water were the major sources for groundwater in the North China Plain. Stable isotopic enrichment of groundwater near the dam area in front of the piedmont alluvial fan areas shows that the dam water infiltrated to the ground after evaporation. As a result, from the stable isotope analysis, isotope value of groundwater tends to deplete from sea level (horizontal ground surface) to both top of the mountain and the bottom of the lowland areas in symmetrically. This suggests that groundwater in the study area is controlled by the altitude effect. Shallow groundwater in the study area belongs to the local flow system and deep groundwater part of the regional flow system. Copyright © 2007 John Wiley & Sons, Ltd.     

Evaluation of historical nitrate sources in groundwater and impact of current irrigation practices on groundwater quality

Abstract

Large-scale agricultural activities cause deterioration of groundwater resources throughout the world. This study focuses on the irrigated agricultural district of Jinghuiqu in Shaanxi, China. The objectives are to identify the main sources and processes that control nitrate transport, and to assess the impact of long-term irrigation practices on nitrate leaching. The hydrogeochemistry of major solute constituents and stable isotope ratios of NO₃ ^? in groundwater were used to identify historical sources of contamination and transformation processes occurring in the shallow groundwater of the Jinghuiqu irrigation district. The N-NO₃ ^? concentrations in groundwater ranged from 0.0 to more than 100 mg L^?1 in April 1990, and from 0.47 to 42.0 mg L^?1 in December 2009. Our measurements of N-NO₃ ^? show that the main reasons for this dramatic decline in N-NO₃ ^? concentrations from 1990 to 2009 are denitrification, which controls nitrogen types, together with the sharp decline of the groundwater table. The isotope ratios in collected samples showed that the source of nitrate was mainly manure, a result that corresponds with historical data showing that manure was the main nitrate source before the 1980s, and that fertilizers became dominant thereafter. A numerical model was then used to evaluate future impacts of current irrigation practices on groundwater sources. The HYDRUS-1D model was employed first to evaluate the water movement and the N-NO₃ ^? solute transport for a single irrigation pulse experiment carried out under field conditions, and then in evaluating the long-term impact of irrigation on N-NO₃ ^? leaching. Simulations showed that, after introducing irrigation, the downward drainage fluxes of N-NO₃ ^?, and the N-NO₃ ^? and N-tot concentrations increased at all depths within the 2-m soil profile. This indicates that N concentrations below 1-m depth and in the groundwater could become even more elevated with increased future irrigation.

Editor D. Koutsoyiannis

Citation Liu, X.-H., Sun, S.-J., Ji, P., and ?im?nek, J., 2013. Evaluation of historical nitrate sources in groundwater and impact of current irrigation practices on groundwater quality. Hydrological Sciences Journal, 58 (1), 1–15.     

The use of isotopes in evolving groundwater circulation models of regional continental aquifers: The case of the Guarani Aquifer System

The Guarani Aquifer System (GAS) has been studied since the 1970s, a time frame that coincides with the advent of isotopic techniques in Brazil. The GAS isotope data from many studies are organized in different phases: (a) the advent of isotope techniques, (b) consolidation and new applications, (c) isotope assessments and hydrochemistry evolution, and (d) a roadmap to a new conceptual model. The reasons behind the phases, their methodological approaches, and impacts on the regional flow conceptual models are examined. Starting with local δ²H and δ¹⁸O assessments of values for water fingerprinting and estimates of recharge palaeoclimate scenarios, studies evolved to more integrated approaches based on multiple tracers. Stable isotope application techniques were consolidated during the 1980s, when new dating approaches dealing with radiogenic and heavy isotopes were introduced. Through the execution of an international transboundary project, the GAS was studied and extensively sampled for isotopes. These results have triggered wider application of isotope techniques, reflecting also world research trends. Presently, hydrochemical evolution models along flow lines from recharge to discharge areas, across large‐scale tectonic features within the entire sedimentary basin, are being combined with residence time estimates at GAS outcrop areas and deep confined units. In a complex system, it is normal that many, and even contradictory hypotheses are proposed, but isotope techniques provide a unique chance to test them. Stable isotope assessments are still needed near recharge areas, and they can be combined with groundwater classical dating procedures, complemented by newer techniques (³H‐³He, CFCs, and SF₆)_. Recent noble gas sampling and world pioneer analytical efforts focused on the confined units in the GAS will certainly led to new findings on the overall GAS circulation. The objective of this article is to discuss how isotope information can contribute to the evolution of conceptual groundwater flow models for regional continental aquifers, such as the GAS.     

Using stable water isotopes to identify spatio-temporal controls on groundwater recharge in two contrasting East African aquifer systems

Understanding the spatio-temporal variability in groundwater recharge is a prerequisite to sustainable management of aquifers. Spatial analysis of groundwater stable isotopes uncovered predominant controls on groundwater recharge in the Nairobi aquifer system (NAS) and the South Coast aquifer (SC), two exemplar East African aquifers relied upon by 7 million people. We analysed 368 samples for stable isotopes and basic physico-chemical parameters. The NAS groundwater isotopes are controlled by precipitation orographic effects and enriched recharge from impounded lakes/wetlands; the SC isotopes are correlated with water-table depth influencing evapotranspiration. Global Network of Isotopes in Precipitation (GNIP) data revealed groundwater recharge during months of heavy rains in the NAS, whilst the SC experiences spatio-temporally diffuse recharge. Inferred “isoscapes” show: in the NAS, (1) direct, rapid recharge favoured by faults, well-drained soils and ample rainfall in uplands, (2) delayed recharge from impounded lakes and wetlands in mid-lands, and (3) focused, event-based recharge in floodplains; and in the SC, diffuse recharge complicated by significant water-table evapotranspiration processes.     

Characterizing seasonal groundwater storage in alpine catchments using time-lapse gravimetry,water stable isotopes and water balance methods

Alpine areas play a major role in water supply in downstream valleys by releasing water during warm and dry periods. However, the hydrogeology of alpine catchments, which are particularly exposed to the effects of climate change, is currently not well understood. Increasing our knowledge of alpine hydrogeological processes is thus of considerable importance for any forward-looking hydrological investigations in alpine areas. The objectives of this study are to quantify seasonal groundwater storage variations in a small Swiss alpine catchment and to evaluate the capabilities of time-lapse gravimetry in the identification of zones of high groundwater storage fluctuations. Time-lapse gravimetric measurements enable rapid localisation of zones of dynamic groundwater storage changes and help to highlight aquifers with a higher storage decrease. Temperature sensors enable measurement of the temporal trend in stream and spring drying in the post-snowmelt period. Stable isotope measurements allow us to identify the origin of surface water exiting the catchment. The results improve our comprehension of a conceptual schema highlighting two different hydrogeological systems: (a) a shallow, rapidly depleted one fed directly by snowmelt and (b) a deeper one, with a slower recession, fed by main recharge during peak snowmelt and emerging at the lower part of the catchment below the talus and moraine of the catchment where bedrock is exposed. These dynamics confirm the high variability of storage in the talus and moraine aquifers and highlight the dominant role of Quaternary deposits and their connectivity to store water over seasonal and multi-year time-scales. The mechanisms explaining the importance of Quaternary deposits are the combination of moraine and talus with different permeabilities allowing the storage of sufficient quantities of water permitting continuous release during drier periods of the year.     

Groundwater flow path determination during riverbank filtration affected by groundwater exploitation: a case study of Liao River,Northeast China

The groundwater flow path plays an important role in maintaining hydrological and ecological quality and security, which are important in the comprehensive management and use of both groundwater and surface water. In this study, an integrated multi-tracer-constrained framework was used to determine the groundwater flow path. The results show that there are shallow and deep flow paths in riverbank filtration, controlled by the different permeabilities of riverbed sediments and aquifers at different depths. The contribution of river water to shallow groundwater is less than that to deep groundwater because of the low permeability of the riverbed sediment in the dense muddy layer in the shallow slope of the river valley. This contribution decreases with increasing distance from the Liao River. The shallow groundwater quality is better than the deep groundwater quality because of its longer residence time.     

Environmental isotopes and hydrochemical study applied to surface water and groundwater interaction in the Awash River basin

An environmental isotope and hydrochemical study was carried out to conceptualize the surface water and groundwater interaction and to explore the groundwater flow pattern in relation to the geological setting. More emphasis is given to the Afar Depression where groundwater is a vital source of water supply. Conventional field hydrogeological study and river discharge records support the isotope and hydrochemical analysis. The region is tectonically active, comprising rift volcanic terrain bordered by highlands. The result revealed that recent meteoric water is the major source of recharge. Three distinct groundwater zones were identified associated with the highlands, transitional escarpment and the rift. Towards the rift, the ionic concentration and isotopic enrichment (δ²H and δ^18degO) increases following the groundwater flow paths, which is strongly controlled by axial rift faults. The groundwater flow converges to the seismically active volcano–tectonic depressions with internal drainage and to the Awash River. Within the Afar Depression, at least four groundwater regimen are identified: (1) fresh and shallow groundwater associated with alluvial deposits ultimately recharged by isotopically depleted recent highland rainfall and the evaporated Awash River; (2) cold and relatively younger groundwater within localized fractured volcanics showing mixed origin in axial fault zones; (3) old groundwater with very high ionic concentration and low isotopic signature localized in deep volcanic aquifers; and (4) old and hot saline groundwaters connected to geothermal systems. The study demonstrated that dependable groundwater can only be obtained from the first two aquifer types in aerially restricted zones in flat plains following river courses, local wadis and volcano–tectonic depressions. The conventional hydrogeological survey and discharge records indicate substantial channel losses from the Awash River, which becomes a more dominant source of recharge in central and lower Awash valleys. Copyright © 2007 John Wiley & Sons, Ltd.     

Marine and human activity influences on the groundwater quality of southern Korinthos area (Greece)

In this paper the groundwater quality of the southern part of Korinthos region (north‐east Peloponnese) is discussed. The geology is characterized by a thick sequence of Neogene marls alternating with sandstones, overlain by superficial Quaternary deposits. The latter consist of a mixture of loose materials such as conglomerates, marly sandstones, sands and clay to silty sands. The area is crossed by a fault system parallel to the coastline, and the Quaternary sediments have formed extended Tyrrhenian marine terraces. Two aquifers have been identified in the area. The first is unconfined and occurs within the Quaternary sediments whereas the other is a deep confined aquifer occurring within the underlying Neogene marl series. Analysis of hydrochemical evolution over the past 30 years has indicated significant deterioration of quality owing to seawater intrusion and nitrate pollution. The various sources of pollution have rendered, to a large extent, shallow groundwater unsuitable not only for potable water supply but also for irrigation purposes. However, this is not the case for the deeper confined aquifer. Statistical analysis was used to explore the evolution of salinization during the years 1968 and 1998. In view of the alarming conditions caused by the documented groundwater quality deterioration, the need for integrated water resources management is stressed to maintain the socio‐economic growth of the region studied. Copyright © 2003 John Wiley & Sons, Ltd.     

A study of soil water movement combining soil water potential with stable isotopes at two sites of shallow groundwater areas in the North China Plain

In the shallow groundwater areas of the North China Plain (NCP), precipitation infiltration and evapotranspiration in the vertical direction are the main processes of the water cycle, in which the unsaturated zone plays an important role in the transformation process between precipitation and groundwater. In this paper, two typical sites in Cangzhou (CZ) and Hengshui (HS) of Hebei province with shallow water tables were selected to analyse the relationship among precipitation, soil water and groundwater. At each site, precipitation, soil water at depths 10, 20, 30, 50, 70, 100, 150, 200, 300 cm, and groundwater were sampled to analyse the stable isotope compositions of hydrogen and oxygen. The soil water potentials at the corresponding depths were observed. Although the climates at the two sites are similar, there are some differences in the infiltration process, soil water movement and groundwater recharge sources. Evaporation occurred at the upper depths, which led to the decrease of soil potential and the enrichment of heavy isotopes. At the CZ site, precipitation infiltrated with piston mode, and an obvious mixture effect existed during the infiltration process. Preferential flow may exist in the soil above 100 cm depth. However, at the HS site soil water moved in piston mode, and groundwater was mainly recharged by precipitation. When precipitation recharged the groundwater it experienced a strong evaporation effect. The results of the soil water movement mechanism provides the transformation relationship among precipitation, soil water and groundwater in the middle and eastern NCP. Copyright © 2009 John Wiley & Sons, Ltd.     

Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta,Botswana

The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ¹⁸O and δ¹³C_DIC). The δD and δ¹⁸O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (<10 m) groundwater are Ca–Na–HCO₃ type and the deep (≥10 m) groundwater is Na–K–HCO₃ to HCO₃–Cl–SO₄ to Cl–SO₄–HCO₃. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ¹³C_DIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.     

Use of stable water isotopes to assess sources and influences of slope groundwater on slope failure

This study employs stable oxygen and hydrogen isotopes as natural tracers to assess the headwater of a landslide next to a drainage divide and the importance of the slope's headwater in the study area. The study is undertaken near Wu‐She Township in the mountains of central Taiwan. Because a reservoir is located on the other side of the divide, this study evaluates the relationship between the reservoir water and headwater of the landslide as well. Over a 1‐year period, water samples from September 2008 to September 2009, including local precipitation (LP), Wu‐She Reservoir's water (WSRW), slope groundwater (SGW), upper‐reach stream water (USTW), and down‐reach stream water (DSTW), were analysed for deuterium (δD) and oxygen (δ¹⁸O) stable isotopes. Results indicate that WSRW is the predominant component in SGW: approximately 70% of SGW originates from WSRW and 30% from LP based on a two end‐member mass‐balance mixing model for δ¹⁸O. The similar two end‐member mixing model is also employed to assess the contributions of USTW and SGW to DSTW. Model results indicate that SGW is the major source of DSTW with a contribution of about 67%. Accordingly, about 47% of DSTW sources from the WSRW. In short, owing to reservoir leakage, WSRW contributes the greater part of both SGW and DSTW. Plentiful WSRW in SGW threatens the stability of the slope in the divide area. To avoid subsequent continuous slope failure, necessary mitigation steps are required. Copyright © 2011 John Wiley & Sons, Ltd.     

Chloride,hydrochemical and isotope methods of groundwater recharge estimation in eastern Mediterranean areas: a case study in Jordan

Jordan is classified as an arid to semi‐arid country with a population according to 1999 estimates of 4·8 millions inhabitants and a growth rate of 3·4%. Efficient use of Jordan's scarce water is becoming increasingly important as the urban population grows. This study was carried out within the framework of the joint European Research project ‘Groundwater recharge in the eastern Mediterranean’ and describes a combined methodology for groundwater recharge estimation in Jordan, the chloride method, as well as isotopic and hydrochemical approaches. Recharge estimations using the chloride method range from 14 mm year^?1 (mean annual precipitation of 500 mm) for a shallow and stony soil to values of 3·7 mm year^?1 for a thick desert soil (mean annual precipitation of 100 mm) and values of well below 1 mm year^?1 for thick alluvial deposits (mean annual rainfall of 250 mm). Isotopically, most of the groundwater in the Hammad basin, east Jordan, falls below the global meteoric water line and far away from the Mediterranean meteoric water line, suggesting that the waters are ancient and were recharged in a climate different than Mediterranean. Tritium levels in the groundwater of the Hammad basin are less than the detection limit (<1·3 TU). However, three samples in east Hammad, where the aquifer is unconfined, present tritium values between 1 and 4 TU. Copyright © 2007 John Wiley & Sons, Ltd.     

Identifying the origin of groundwater for water resources sustainable management in an arid oasis,China

ABSTRACT

Many oases are experiencing severe groundwater depletion due to increased population, expanding agriculture and economic development. For sustainable development, quantifying groundwater recharge resources are fundamentally important. In this study, stable isotope techniques were employed to identify recharge sources of groundwater and quantitatively evaluate their contribution ratios in the Dunhuang Oasis, northwest China. Our findings indicate that heavy isotopes in shallow groundwater are more negative than those in deep groundwater, which is attributed to shallow groundwater that was modern and deep groundwater that was old. Irrigated return water and lateral groundwater flow from the Qilian Mountains are considered as the two main sources of shallow groundwater, accounting for 35% and 65% of the total recharge, respectively. Thus, as the main groundwater source of the Dunhuang Oasis, the Qilian Mountain Front should be protected against over-exploitation. Our results provide not only fundamental knowledge for groundwater management of aquifers of the Oasis, but also valuable water management information for other similar arid oases worldwide.     

Isotopes and geochemistry in a managed aquifer recharge scheme: a case study of fresh water injection at the Damascus University Campus,Syria

A combination of stable isotopes (¹⁸O and ²H) and hydrochemistry has been applied to investigate storage processes in relation to aquifer storage and recovery (ASR) of the shallow alluvial Quaternary aquifer in Damascus basin. The stored water, entirely taken from the Figeh springs during flood periods, was injected in a single well having a brackish groundwater. Water samples were collected from four observation wells drilled in the Damascus University Campus (DUC) site during a 3‐year period (2006–2008). The injectant water, which deviates in its chemical and isotopic signatures from that of the ambient groundwater, shows that the stored water plume remains within close proximity to the injection well (IW) (<≈ 100 m). Thus, only two wells (W13 and W14) located at a distance less than 80 m from the injection point were affected by this injection. The observation wells located at longer distances from the IW (≈145 m and ≈ 600 m for wells W15 and WHz, respectively) were completely unaffected by the injection. Although most of the chemical and isotopic parameters usefully reflected the mixing process that occurs between the injectant water and ambient groundwater, the stable isotope (¹⁸O) and chloride (Cl⁻) were the most sensitive parameters that quickly reflect this signature. Using a simple mass balance, the calculated proportion of injectant water reaching the well W13 was in the range of 50–90%. This proportion was even lower (30–55%) in the case of well W14. Although the drought event prevailing during this study did not much help to inject further amounts of water, higher than the injected volume (0·2416 M m³) and also not favourable to better evaluate the fate and subsurface hydrological processes, these findings offer encouragement to continue the ASR activities, as an alternative way for better management of water resources in this basin facing intensive problems. Copyright © 2010 John Wiley & Sons, Ltd.     

Environmental isotopic and hydrochemical characteristics of groundwater systems in Daying and Qicun geothermal fields,Xinzhou Basin,Shanxi, China

The conceptual hydrogeological model of the low to medium temperature Daying and Qicun geothermal fields has been proposed, based on hydrochemical characteristics and isotopic compositions. The two geothermal fields are located in the Xinzhou basin of Shanxi, China and exhibit similarities in their broad‐scale flow patterns. Geothermal water is derived from the regional groundwater flow system of the basin and is characterized by Cl·SO₄‐Na type. Thermal water is hydrochemically distinct from cold groundwater having higher total dissolved solids (TDS) (>0·8 g/l) and Sr contents, but relatively low Ca, Mg and HCO₃ contents. Most shallow groundwater belongs to local flow systems which are subject to evaporation and mixing with irrigation returns. The groundwater residence times estimated by tritium and ¹⁴C activities indicate that deep non‐thermal groundwater (130–160 m) in the Daying region range from modern (post‐1950s) in the piedmont area to more than 9·4 ka BP (Before Present) in the downriver area and imply that this water belong to an intermediate flow system. Thermal water in the two geothermal fields contains no detectable active ¹⁴C, indicating long residence times (>50 ka), consistent with this water being part of a large regional flow system. The mean recharge elevation estimated by using the obtained relationship Altitude (m) = ? 23·8 × δ²H (‰ ) ? 121·3, is 1980 and 1880 m for the Daying and Qicun geothermal fields, respectively. The annual infiltration rates in the Daying and Qicun geothermal fields can be estimated to be 9029 × 10³ and 4107 × 10³ m³/a, respectively. The variable ⁸⁶Sr/⁸⁷Sr values in the thermal and non‐thermal groundwater in the two fields reflect different lithologies encountered along the flow path(s) and possibly different extents of water‐rock interaction. Based on the analysis of groundwater flow systems in the two geothermal fields, hydrogeochemical inverse modelling was performed to indicate the possible water‐rock interaction processes that occur under different scenarios. Copyright © 2010 John Wiley & Sons, Ltd.     

Quantitative evaluation of groundwater recharge and evaporation intensity with stable oxygen and hydrogen isotopes in a semi‐arid region,Northwest China

Yinchuan Basin, a semi‐arid area located in Northwest China, is currently subject to increasing pressure from the altered hydrology due to the anthropogenic activities as well as increasing water demands for regional development. Sustainable water management across the region must be underpinned by a clear understanding of the factors that constrain water supply in this area. We measured the stable isotope of oxygen and hydrogen to determine the likely processes that control the interrelations among precipitation, surface water (Yellow River), and groundwater. The hydrogen and oxygen values demonstrate that 2 primary hydrochemical processes, mixing and evaporation/condensation, occurred in the Basin. Recharge proportions of precipitation and Yellow River were quantitatively evaluated based on the isotope mass balance method. The proportions of the Yellow River and atmospheric precipitation recharge are 87.7% and 12.3%, respectively. The evaporation proportions calculated with ¹⁸O and D by Rayleigh fractional equation are close to each other, which demonstrate that evaporation intensity increases following the flow direction of the Yellow River. The findings obtained in this study are useful for recognizing the significance of Yellow River to Yinchuan Basin, and some optimal allocation schemes can be adopted for a prospective development of this reputed area in Northwest China.     

Optimal allocation of water quantity and waste load in the Northwest Pearl River Delta,China

The Northwest Pearl River Delta is one of the most developed areas in China and has faced serious water problems because of its fast economic growth, urbanisation and other developments. It is widely believed that an integrated management of the socio-economic factors cross individual administrative cities is an effective way to solve the water problems. To serve this purpose, this paper aims to develop an integrated model for the optimal allocation of water quantity and waste load. In order to consider the interaction between water quantity and waste load allocation, the Saint-Venant equations were used to simulate dynamic water flow for the water quantity allocation, whereas the one dimensional advection–dispersion mass transport equation was used to simulate water quality for the waste load allocation. In addition to the maximisation of the economic benefits, which is often considered as an objective of optimal water resource allocation models, the minimisation of water shortages and maximisation of waste load were also introduced as objectives of the model. To solve the multi-objective allocation model, a second generation non-dominated sorting genetic algorithm was employed because of its computational efficiency and running time. The results indicate that it is a serious task to reduce the COD in the Northwest Pearl River Delta since the maximum waste load allocations under water quality targets is less than the present amount of waste discharged into rivers in the study area.     

Stable isotopic and geochemical identification of groundwater evolution and recharge sources in the arid Shule River Basin of Northwestern China

Stable isotopic (δD_VSMOW and δ¹⁸O_VSMOW) and geochemical signatures were employed to constrain the geochemical evolution and sources of groundwater recharge in the arid Shule River Basin, Northwestern China, where extensive groundwater extraction occurs for agricultural and domestic supply. Springs in the mountain front of the Qilian Mountains, the Yumen‐Tashi groundwater (YTG), and the Guazhou groundwater (GZG) were Ca‐HCO₃, Ca‐Mg‐HCO₃‐SO₄ and Na‐Mg‐SO₄‐Cl type waters, respectively. Total dissolved solids (TDS) and major ion (Mg²⁺, Na⁺, Ca²⁺, K⁺, SO₄^2?, Cl^? and NO₃^?) concentrations of groundwater gradually increase from the mountain front to the lower reaches of the Guazhou Basin. Geochemical evolution in groundwater was possibly due to a combination of mineral dissolution, mixing processes and evapotranspiration along groundwater flow paths. The isotopic and geochemical variations in melt water, springs, river water, YTG and GZG, together with the end‐member mixing analysis (EMMA) indicate that the springs in the mountain front mainly originate from precipitation, the infiltration of melt water and river in the upper reaches; the lateral groundwater from the mountain front and river water in the middle reaches are probably effective recharge sources for the YTG, while contribution of precipitation to YTG is extremely limited; the GZG is mainly recharged by lateral groundwater flow from the Yumen‐Tashi Basin and irrigation return flow. The general characteristics of groundwater in the Shule River Basin have been initially identified, and the results should facilitate integrated management of groundwater and surface water resources in the study area. Copyright © 2015 John Wiley & Sons, Ltd.