Analytical methods that use natural heat as a tracer to quantify surface water–groundwater exchange, evaluated using field temperature records

Two methods applying natural heat as a tracer to quantify surface water–groundwater exchange were evaluated using field data. Arrays capable of monitoring and recording the streambed response to diurnal temperature variations in the surface water were deployed for a 2-month period in three locations in perennial pools at Maules Creek, New South Wales, Australia. Multi-level array design, field deployment and parameter estimation are discussed. The applicability of analytical solutions derived from the heat transport equation to the streambed environments was analysed using the recorded temperature time series. The stream was found to lose water to the aquifer, which was supported by simultaneously recorded hydraulic gradients. However, the one-dimensional (1D) analytical solutions did not adequately describe the observed streambed thermal response at two locations. The resulting artefacts in the estimated flow velocities are discussed. It was hypothesised that the artefacts originate from model limitation due to streambed heterogeneity and application of 1D solutions to multi-dimensional and dynamic streambed flow. This consequently imposes limitations on the field applicability of the methods. Nevertheless, in combination with time series of surface water and streambed water levels, the use of heat as a tracer provided a powerful tool for better understanding the shallow hydrogeological system.     

Numerical simulation of the effect of heavy groundwater abstraction on groundwater–surface water interaction in Langat Basin, Selangor, Malaysia

The paper aims at evaluating the interaction between ground and surface water along the Langat River in Malaysia through the development of a numerical simulation. Malaysia has been experiencing a rapid economic growth since the last few decades, driven by many factors such as agriculture, industry, and the like. The demand for water in these sectors has increased so tremendously that surface water has been utilized in conjunction to groundwater. Approximately 18,184 m³ of water per day is obtained from the aquifer to supply to the steel factory. There are also workshops, petroleum stations, and houses in the area thus causing the water quantity and quality to degrade. In terms of quantity, the pumping activity has altered the interaction between the groundwater and surface water. Therefore, a numerical model was proposed and two aquifer layers were simulated, with the first layer being approximately >20 m in depth and the second layer >100 m. The recharge estimated from the tank model was input into the groundwater modeling. The effects of the surface water to the aquifer were included in the simulation by defining the river conductance, river bed, and river level. The calibrated model (error about 0.9 m) was achieved and applied to predict the flow pattern in its natural state without the pumping and with the pumping states. As a result, in the first scenario, the stream was in an effluent condition influenced by the groundwater from the northeast to the west. A hyporheic flow occurred and was observed from the contour map. The flow system was changed in the second scenario when the pumping activity was included in the simulation. The groundwater lost its original function but received leakage from the stream near the pumping sites. The findings of this study will help the local authorities and other researchers to understand the aquifer system in the area and assist in the preparation of a sustainable groundwater management.     

Physicochemical studies of magma and of related phenomena conducted in U.S.S.R. in 1957–1959

A review of 174 Soviet publications on physicochemical studies in magmatism, post-magmatic phenomena, origins of rocks, minerals ores, and related subjects, with particular attention to the impact of the derivations of Korzhinskiy of the Phase Rule upon modern physical chemistry in petrology. — V.P. Sokoloff     

Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

Quantification of groundwater–surface water interactions using environmental isotopes: A case study of Bringi Watershed,Kashmir Himalayas,India

Environmental isotopes including \({\updelta }^{18}\)O, \({\updelta }^{2}\)H and \(^{3}\)H of precipitation, streams and springs were determined in the mountainous Bringi catchment of Kashmir Himalaya, dominated by carbonate lithology. The isotopic signature of winter precipitation is reflected in stream and spring water in late spring and is, therefore, representative of snow melting. The spring waters in September bear the enriched isotopic signatures of summer rainfall. The strong correlation (\(r^{2} = 0.97\)) between the isotopic composition of streams and springs indicates the streams and springs either share similar catchments or the springs are recharged by the streams. Chloride mass balance and isotopic mass balance studies suggest that the surface recharge component averages 337.35 m\(^{3}\)/s, which is about 75% of total stream discharge during the high flow period. Similarly, the contribution of surface water to groundwater recharge during the low flow period averages 7.5 m\(^{3}\)/s, which is about 18.6% of total stream flow. Furthermore, the mean residence time of the springs calculated from the tritium decay equation is very short (<1 year). The residence time is longer for Kongamnag and short for Achabalnag, which is further supported by dye testing.     

A 2D integrated FEM model for surface water–groundwater flow of slopes under rainfall condition

Numerical modeling of water infiltration in slopes under rainfall conditions, especially under rainstorm conditions, is a fundamental problem for slope stability assessment. To obtain representative results, surface water–groundwater flow models are incorporated in the simulation. Based on finite element representation of Richards’ equation and of kinematic wave equations, an integrated 2D numerical model (IMCR2D) of the surface water–groundwater system was established. The model has a symmetrical matrix that modifies the flux boundary according to the runoff solution on the slope. IMCR2D was verified using two laboratory experiments, and it showed good agreement with numerical and experimental results. Additional numerical examples were used to study the effect of flux supply from runoff on infiltration. In comparison with SimMd (an existing method), IMCR2D displayed advantages in cases where surface runoff develops in an upper low-permeability section of the slope and flows down into a high-permeability section of the slope. To illustrate the advantages of the new method, the seepage field and stability condition of a case study in the Three Gorges Hydroelectric Reservoir were analyzed using IMCR2D and SimMd. The deformation of a landslide in part reflects its stability, and therefore, we also used displacement monitoring data to estimate the variation of stability conditions from that aspect. Comparison of the two numerical models indicated that flux supply greatly affects the seepage field, and that rainfall plays an important role in landslide stability evaluation, but only when considering flux supply from upper slope surface runoff.     

Measurement of pesticides in surface water and sediment of Caspian Sea, Iran

Background: With development of intensive agriculture in the agricultural regions of the Northern provinces (Caspian Sea coasts), which involves frequent pesticide use in highly mechanized cash-crop cultures. To investigate and provide information on pest…     

A comparative study of shallow groundwater level simulation with WA–ANN and ITS model in a coastal island of south China

Accurate and reliable prediction of shallow groundwater level is a critical component in water resources management. Two nonlinear models, WA–ANN method based on discrete wavelet transform (WA) and artificial neural network (ANN) and integrated time series (ITS) model, were developed to predict groundwater level fluctuations of a shallow coastal aquifer (Fujian Province, China). The two models were testified with the monitored groundwater level from 2000 to 2011. Two representative wells are selected with different locations within the study area. The error criteria were estimated using the coefficient of determination (R ²), Nash–Sutcliffe model efficiency coefficient (E), and root-mean-square error (RMSE). The best model was determined based on the RMSE of prediction using independent test data set. The WA–ANN models were found to provide more accurate monthly average groundwater level forecasts compared to the ITS models. The results of the study indicate the potential of WA–ANN models in forecasting groundwater levels. It is recommended that additional studies explore this proposed method, which can be used in turn to facilitate the development and implementation of more effective and sustainable groundwater management strategies.     

Quantification of the water balance and hydrogeological processes of groundwater–lake interactions in the Pampa Plain, Argentina

This paper gives an account of the assessment and quantification of the water balance and the hydrogeological processes related to lake–groundwater interaction in the Pampa Plain by using hydrogeochemical, isotopic and flow numerical modeling techniques. La Salada is a permanent shallow lake, with an area of 5.8 km², located on the SE of Buenos Aires Province. A total of 29 lake water samples and 15 groundwater samples were collected for both hydrochemical analysis and environmental stable isotope determination. Water table depths were measured in wells closed to the lake. Groundwater samples appear grouped on the Local Meteoric Water Line, suggesting a well-mixed system and that rainfall is the main recharge source to the aquifer. Water evaporation process within La Salada is also corroborated by its isotopic composition. The model that best adjusts to La Salada Lake hydrochemical processes includes evaporation from groundwater, calcite precipitation with CO₂ release and cationic exchange. The annual water balance terms for the lake basin indicates for each hydrological component the following values: 1.16 E⁰⁸ m³ rainfall, 8.15 E⁰⁷ m³ evapotranspiration, 1.90 E⁰⁶ m³ runoff, 1.55 E⁰⁷ m³ groundwater recharge, 6.01 E⁰⁶ m³ groundwater discharge to the lake, 9.54 E⁰⁶ m³ groundwater discharge to the river, 5.00 E⁰⁵ m³ urban extraction and 4.90 E⁰⁶ m³ lake evaporation. Integrated analysis of hydrochemical and isotopic information helped to calibrate the groundwater flow model, to validate the conceptual model and to quantitatively assess the basin water balance.     

Geochemical characterization of surface water and spring water in SE Kashmir Valley,western Himalaya: Implications to water–rock interaction

Water samples from precipitation, glacier melt, snow melt, glacial lake, streams and karst springs were collected across SE of Kashmir Valley, to understand the hydrogeochemical processes governing the evolution of the water in a natural and non-industrial area of western Himalayas. The time series data on solute chemistry suggest that the hydrochemical processes controlling the chemistry of spring waters is more complex than the surface water. This is attributed to more time available for infiltrating water to interact with the diverse host lithology. Total dissolved solids (TDS), in general, increases with decrease in altitude. However, high TDS of some streams at higher altitudes and low TDS of some springs at lower altitudes indicated contribution of high TDS waters from glacial lakes and low TDS waters from streams, respectively. The results show that some karst springs are recharged by surface water; Achabalnag by the Bringi stream and Andernag and Martandnag by the Liddar stream. Calcite dissolution, dedolomitization and silicate weathering were found to be the main processes controlling the chemistry of the spring waters and calcite dissolution as the dominant process in controlling the chemistry of the surface waters. The spring waters were undersaturated with respect to calcite and dolomite in most of the seasons except in November, which is attributed to the replenishment of the CO₂ by recharging waters during most of the seasons.     

Geographies of identity theft in the U.S.: understanding spatial and demographic patterns, 2002–2006

Identity theft is among the fastest growing white-collar crimes in the United States, although official recognition of it as a criminal act is a relatively recent development. Utilizing theoretical framework established in crime geography, GIS mapping and spatial statistics are employed to conduct a spatial analysis of identity theft in the U.S. from 2002 to 2006. Distinct regional variations, such as high rates in the western and southwestern states, and low rates in New England and the central plains states, are identified for identity theft. Significant spatial patterns of identity theft victims alongside social demographic variables are also revealed in order to better understand the regional patterns that may suggest underlying social causes contributing to identity theft. Potential social variables, such as race/ethnicity and urban–rural populations, are shown to have similar patterns that may be directly associated with U.S. identity theft victims.     

Spatial–temporal characteristics of surface water quality in the Taihu Basin,China

Taihu Basin is one of the most developed and industrialized regions in China. In the last two decades, rapid development of economy as well as an increase in population has resulted in an increase of pollutants produced and discharged into rivers and lakes. Much more attention has been paid on the serious water pollution problems due to high frequency of algal blooming. The dataset, obtained during the period 2001–2002 from the Water Resources Protection Bureau of the Taihu Basin, consisted of eight physicochemical variables surveyed monthly at 22 sampling sites in the Taihu Basin, China. Principal component analysis (PCA) and cluster analysis (CA) were used to identify the characteristics of the surface water quality in the studied area. The temporal and spatial variations of water quality were also evaluated by using the fuzzy synthetic evaluation (FSE) method. PCA extracted the first two principal components (PCs), explaining 86.18% of the total variance of the raw data. Especially, PC1 (73.72%) had strong positive correlation with DO, and was negatively associated with COD_Mn, COD, BOD, NH₄ ⁺–N, TP and TN. PC2 (12.46%) was characterized by pH. CA showed that most sites were highly polluted by industrial and domestic wastewater which contributed significantly to PC1. The sites located in the west of Lake Taihu were influenced by farmland runoff which may contribute to nitrogen pollution of Lake Taihu, whereas the monitoring sites in the eastern of Lake Taihu demonstrated that urban residential subsistence and domestic wastewater are the major contaminants. FSE indicates that there is no obvious variance between 2001 and 2002 among most sites. Only several sites free from point-source pollution appear to exhibit good water quality through the studied period.     

Isotopes (δD and δ18O) in precipitation, groundwater and surface water in the Ordos Plateau, China: implications with respect to groundwater recharge and circulation

The characteristics of δD and δ¹⁸O in precipitation, groundwater and surface water have been used to understand the groundwater flow system in the Ordos Plateau, north-central China. The slope of the local meteoric water line (LMWL) is smaller than that of the global meteoric water line (GMWL), which signifies secondary evaporation during rainfall. The distribution of stable isotopes of precipitation is influenced by temperature and the amount of precipitation. The lake water is enriched isotopically due to evaporation and its isotopic composition is closely related to the source of recharge and location in the groundwater flow systems. River water is enriched isotopically, indicating that it suffers evaporation. The deep groundwater (more than 150?m) is depleted in heavy isotopes relative to the shallow groundwater (less than 150?m), suggesting that deep groundwater may have been recharged during the late Pleistocene and early Holocene, when the climate was wetter and colder than at present. All groundwater samples plot around the LMWL, implying groundwater is of meteoric origin. Shallow groundwater has undergone evaporation and the average evaporation loss is 53%. There are two recharge mechanisms: preferential flow, and the mixture of evaporated soil moisture and subsequent rain.     

Mesozoic–Cenozoic sedimentary rock records and applications for provenance of sediments and affiliation of the Simao Terrane,SW China

ABSTRACT

As the north part of Simao Terrane, Lanping Basin is located between the Sanjiang Tethys Orogen (STO) and Yangtze Block, also the junction zone between the Gondwanaland and Cathaysian old land (Pan Huaxia mainland), which includes Yangtze and Cathaysian Blocks. The aim of this study is to decipher the provenance of the sedimentary units in the Lanping Basin and affiliation of Simao Terrane by the U-Pb ages, Hf isotope of detrital zircons and whole-rock geochemistry. The whole-rock geochemistry and the mineral composition indicate that most of the Triassic–Paleocene sedimentary rocks are derived from the upper crust and exhibit recycled orogen features. The detrital zircon U-Pb ages from the North Simao Terrane are consistent with the magmatic events during Early Neoproterozoic and Permian in the Western Yangtze Block. And the detrital zircons ages from North Simao Terrane show same distribution features as the Permian–Triassic magmatic rocks, which are distributed in the Simao Terrane and along major sutures. These comparisons suggest that the clastic sediments in Lanping Basin (North Simao Terrane) are derived from Early Neoproterozoic and Permian magmatic rocks from Western Yangtze Block, Permian–Triassic magmatic rocks from Simao Terrane, along Jinshajiang, Garz-Litang and Ailaoshan Sutures. The comparison of the detrital zircon age distributions shows that Simao Terrane and Yangtze Block exhibited similarity tectonic setting in the evolution history, especially during Paleoproterozoic–Late Paleozoic. This suggests that the Simao Terrane is part of Cathaysian old land, although Simao Terrane was separated from Yangtze Block for short period during Early Paleozoic. Besides, the Hf mapping, stratigraphic succession, paleogeography and paleomagnetism in SW China support that Simao Terrane has a Cathaysian old land-affinity, rather than one involving Gondwanaland.     

Using subsurface metazoan fauna to indicate groundwater–surface water interactions in the Nakdong River floodplain, South Korea

Hydrological interactions between surface water and groundwater (GW) can be described using hydrochemical and biological methods. Surface water–groundwater interactions and their effects on groundwater invertebrate communities were studied in the Nakdong River floodplain in South Korea. Furthermore, the GW-Fauna-Index, a promising new index for assessing the strength of surface-water influence on groundwater, was tested. The influence of surface water on groundwater decreased with increasing depth and distance from the river. While hydrochemistry prevailingly reflected the origin of the waters in the study area (i.e. whether alluvial or from adjacent rock), faunal communities seemed to display an affinity to surface-water intrusion. Fauna reacted quickly to changes in hydrology, and temporal changes in faunal community structure were significantly linked to the hydrological situation in the floodplain. The metazoan faunal community and the GW-Fauna-Index allow a distinction between surface and subsurface waters with varying degrees of exchange. The results indicate that hydrological conditions are reflected by faunal assemblages on a high spatiotemporal resolution, and that surface-water intrusion can be estimated using the GW-Fauna-Index.     

A spatial–temporal analysis of low birth weight prevalence in Georgia, USA

Low birth weight (LBW), defined as a live birth weighing <2,500 g, is a significant public health problem in the United States, especially a few states including Georgia. Although much work has been done to study the epidemiology of LBW in various regions, the spatial–temporal patterns of LBW prevalence in Georgia remain unclear to a large degree. This paper investigates the temporal trend of LBW rates over a time span of 11 years and the spatial clusters of LBW prevalence in the state of Georgia at the county level. Comparison is also made between race and gender groups, and between county groups of different socioeconomic statuses to uncover disparities. Results showed a steady and prevalent increase of LBW rate in the state over the study period. Three counties and two county clusters with significantly higher LBW rates than the state rate were detected for 1999–2001, while one more county and two more county clusters of high LBW rates were detected for 2007–2009. More urbanized counties were found to have a relatively lower LBW rate when compared with the less urbanized ones as groups. The findings from this paper are expected to provide valuable insights to better understanding the etiology of LBW and more effective allocating prenatal health care resources in the future.     

A multi-period optimization model for conjunctive surface water–ground water use via aquifer storage and recovery in Corpus Christi,Texas

The present study develops and evaluates a decision support system for the conjunctive management of the current surface and proposed aquifer storage and recovery (ASR) facility of the city of Corpus Christi, TX using a simulation–optimization approach. The objective of the model is to maximize water storage in the surface and subsurface storage units while meeting (1) the freshwater inflow requirements to the Corpus Christi estuary and (2) the water demands of the city and its service area. The model is parameterized using streamflow data from the U. S. Geological Survey gauging stations on the Nueces River and its tributaries as well as long-term climatic data and regional hydrogeologic information. Results indicate that a single-well field ASR facility is capable of storing approximately 925 ha-m (7,500 ac-ft) of water over a 5-year period in the Evangeline Aquifer with a total potential storage of about 2,715 ha-m (22,000 ac-ft) of water over the jurisdictional area of the Corpus Christi Aquifer Storage and Recovery Conservation District. Surplus surface water sources are seen to contribute approximately 49–96 % of the water stored in the ASR during the simulation period. The remaining storage came from either Choke Canyon Reservoir or Lake Corpus Christi, which also resulted in a slight reduction in evapotranspiration in both reservoirs. The analysis indicates that the proposed ASR system is not limited on the supply side but multiple well fields may be required to increase the storage capacity within the aquifer.