Baddeleyite and zircon U-Pb ages of the ultramafic rocks in Chigu Tso area,Southeastern Tibet and their constraints on the timing of Comei Large Igneous Province

A suite of ultramafic and mafic rocks developed in the Chigu Tso area, eastern Tethyan Himalaya. Baddeleyite and zircon U-Pb ages acquired by SIMS and LA-ICP-MS from olivine pyroxenite rocks in the Chigu Tso area are 138.9±3.0 Ma and 139.0±1.9 Ma, respectively. These two Early Cretaceous ages are similar with the ages of the more abundant mafic rocks in the eastern Tethyan Himalaya, indicating that this suite of ultramafic and mafic rocks in the Chigu Tso area should be included in the outcrop area of the Comei Large Igneous Province (LIP). These ultramafic rocks provide significant evidence that the involvement of mantle plume/hot spot activities in the formation of the Comei LIP. Baddeleyite U-Pb dating by SIMS is one reliable and convenient method to constrain the formation time of ultramafic rocks. The dating results of baddeleyite and zircon from the olivine pyroxenite samples in this paper are consistent with each other within analytical uncertainties, suggesting that baddeleyite and zircon were both formed during the same magmatic process. The consistency of baddeleyite U-Pb ages in the Chigu Tso area with zircon U-Pb ages for a large number of Early Cretaceous mafic rocks in the eastern Tethyan Himalaya further support that zircon grains from such mafic rocks yielding Early Cretaceous ages are also magmatic in origin.     

U-Pb dating of magmatic zircon and metamorphic baddeleyite in the Ligurian eclogites (Voltri Massif,Western Alps)

U-Pb geochronology with ion microprobe (SHRIMP) analysis has been carried out on eclogite-facies rocks of the Beigua Unit, an ophiolitic slice of the Voltri Massif, Western Alps. The investigated samples are eclogites and high-pressure metasomatic rocks (metarodingites and centimetre-sized Ti-clinohumite-bearing dykes). Zircon contained in an eclogitic metagabbro and a metarodingite preserves magmatic zoning patterns and trace element compositions. The zircon ages of 160±1 and 161±3 Ma are interpreted to date the crystallization of the gabbroic protoliths. Ti-clinohumite dykes in the same unit contain baddeleyite crystals in textural equilibrium with Ti-clinohumite, diopside, chlorite and magnetite, which form the eclogite-facies assemblage in these rocks. Baddeleyite also contains inclusions of such minerals, indicating its formation at high pressure. The baddeleyite has cathodoluminescence intensity and chaotic patterns similar to metamorphic zircon. It contains a significant amount of Hf (1.3–1.7 wt%), traces of Ti, Y, Nb, Ta, REE, U and Th. Its chondrite-normalised trace element pattern has strong enrichment in middle REE, positive Ce-anomaly and small negative Eu-anomaly. This represents the first report of baddeleyite formed during regional metamorphism, and suggests that this mineral could (re)crystallize easier than zircon under low-temperature, high-pressure conditions. The age of the baddeleyite is interpreted as likely dating the eclogite-facies metamorphism in the Beigua Unit at 33.6±1.0 Ma. This age is very close to the Early Oligocene age of the overlying Tertiary continental breccias and conglomerates, which contains clasts of high-pressure rocks. This sedimentary record, which is unique for Alpine high-pressure units, is direct evidence of fast exhumation of the Beigua eclogites. The young age for the HP metamorphism of the Beigua ophiolite makes a revision of either the palaeogeography prior to collision, or of the subduction setting in the entire region, necessary.Editorial responsibility: J. Hoefs     

Geochronology of high-pressure mafic granulite dykes in SW Sweden: tracking the P–T–t path of metamorphism using Hf isotopes in zircon and baddeleyite

Although the U–Pb zircon chronometer has been widely used for dating metamorphism in moderate‐ to high‐grade rocks, it is generally difficult to link the U–Pb age of zircon to specific metamorphic reactions. In this study, the initial Hf isotopic composition of secondary zircon is compared with the evolution of Hf isotopic composition of the bulk sample, back‐projected from the measured value through time. This approach may enhance the interpretation of radiometric ages performed on metamorphic mineral assemblages. Here, U–Pb, Sm–Nd and Lu–Hf geochronology and thermobarometry have been integrated and applied to two metamorphosed diabase dykes in the Sveconorwegian orogen, SW Sweden. The dykes are located ～5 km east of the NNE‐trending Göta Älv deformation zone in the Idefjorden terrane, and trend parallel to this zone. The Lunden dyke is recrystallized into a coronitic, granulite facies assemblage. U–Pb isotopic analyses of baddeleyite in this dyke indicate an emplacement age of c. 1300 Ma. Thermobarometric techniques applied to garnet and omphacitic clinopyroxene coronas indicate high‐pressure metamorphism at ～15 kbar and ～740 °C. The growth of polycrystalline zircon at the expense of baddeleyite occurred at 1046 ± 6 Ma. The identical Hf isotopic composition of polycrystalline zircon and baddeleyite shows that the baddeleyite‐to‐zircon transition took place before Hf equilibration among the other metamorphic minerals and, hence the c. 1046 Ma age of polycrystalline zircon sets an upper age limit of metamorphism of this sample. The Haregården dyke is recrystallized into a granoblastic transitional upper amphibolite to granulite facies assemblage. The estimated P–T conditions are ～10 kbar and ～700 °C. Analyses of small (～30 μm), clear and round zircon in this sample yield a Concordia U–Pb age of 1026 ± 4 Ma, which is indistinguishable from the Lu‐Hf and Sm‐Nd mineral isochron ages of 1027 ± 9 and 1022 ± 34 Ma, respectively. This type of secondary zircon plots at the lower end of the Lu‐Hf isochron and indicates simultaneous growth with garnet at c. 1026 Ma, a time when Hf isotopic equilibrium among minerals must have been reached.     

拉萨地体东南部林芝杂岩形成与变质演化的锆石U-Pb年代学限定

本文对拉萨地体东南部林芝地区分布的变质岩进行了岩相学和锆石年代学研究。结果表明,林芝杂岩中的变质沉积岩主要由片麻岩和片岩组成,它们经历了中压角闪岩相变质作用。变质岩中的锆石多由继承的碎屑岩浆核和新生的变质边组成。继承锆石核给出了新太古代至晚古生代的年龄范围,其主要年龄峰值在～1560Ma、～1190Ma、～620Ma和～340Ma,而锆石变质边给出了53Ma和27Ma的变质年龄。这一结果表明,林芝杂岩中的变质沉积岩很可能形成在古生代,其物质源区具有Grenville和Pan-Africa期造山作用的构造热事件记录。这一研究和已有的成果进一步证明,拉萨地体起源于Gondwana大陆北缘,在新生代印度与欧亚大陆的碰撞/俯冲过程中,拉萨地体作为俯冲带的上盘经历了多期变质作用改造。本研究为拉萨地体起源与多期构造演化提供了重要信息。     

Chronology of multiphase emplacement of the Salmi rapakivi granite-anorthosite complex, Baltic Shield: implications for magmatic evolution

The U-Pb dating of 18 samples, representing the principal rock types of the 4000 km² Salmi anorthosite-rapakivi granite complex and its satellite Uljalegi pluton, southeastern Baltic (Fennoscandian) Shield, reveals that six temporally distinct episodes of igneous activity occurred in a timespan of 17 million years. From oldest to youngest they are: (1) gabbronorite and monzonite at 1546.7 Ma; (2) syenogranite at 1543.4 Ma; (3) early wiborgite and pyterlite at 1540.6–1537.9 Ma; (4) biotite granite and more evolved granite at 1538.4–1535 Ma; (5) late pyterlite at 1535.2 Ma; (6) olivine gabbro and biotite-amphibole granite at 1530 Ma. The resolvable intervals between magmatic episodes are 3.5–5.0 million years. Early wiborgite and pyterlite (3, above) and biotite granite (4, above) probably crystallized from multiple magma intrusions. Age differences of 3.4±1.5 million years between zircon and baddeleyite in olivine gabbro (6, above) are probably a result of xenocrystic origin of baddeleyite extracted from an earlier mafic phase of the Salmi complex. The ages and chemical features of early and late zircon populations, together with our modeling of magma crystallization and zircon growth, show that the duration of magma crystallization and Pb-diffusion in zircon was short lived and insignificant compared to the precision of dating of about ±1–2 million years. Hence, the range of U-Pb ages for each of the major rock types may approximate the emplacement intervals of their respective magmas. Average rate of magma emplacement was about 0.01 km³/year for the most voluminous phase of early biotite-amphibole rapakivi granite, and about 0.0024 km³/year for the Salmi complex as a whole. Compositional changes of the Salmi magmas over time are in agreement with the model of magmatism related to lithospheric extension. Received: 2 August 1996 / Accepted 19 December 1996     

Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.     

Results of U-Pb dating of zircon and baddeleyite from the Noril’sk-1 ultramafic-mafic intrusion (Russia)

We present for the first time the mineralogical and isotope-geochemical particularities of zircon and baddeleyite from various rocks of the economic ore-bearing Noril’sk-1 intrusion located in the northwestern part of the Siberian platform. The ultramafic-mafic Noril’sk-1 intrusion hosts one of the world’s major economic platinum-group-element (PGE)-Cu-Ni sulphide deposits.A detailed study of crystal morphology and internal structure identify four zircon populations, characterized by different U-Pb (SHRIMP-II) ages. The U-Pb ages of baddeleyite and the defined zircon populations cover a significant time span (from 290 ± 2.8 to 226.7 ± 0.9 Ma). The established U-Pb ages imply that crystallization of baddeleyite and zircon populations corresponds to several stages of protracted evolution of the ore-forming magmatic system (290 ± 2.8, 261.3 ± 1.6, 245.7 ± 1.1, 236.5 ± 1.8, and 226.7 ± 0.9 Ma, respectively) that served as the favorable factor for accumulation of magmas and ores of unique scales and concentrations.     

Origin of biotite-hornblende-garnet coronas between oxides and plagioclase in olivine metagabbros,Adirondack region,New York

Complex multivariant reactions involving Fe-Ti oxide minerals, plagioclase and olivine have produced coronas of biotite, hornblende and garnet between ilmenite and plagioclase in Adirondack olivine metagabbros. Both the biotite (6–10% TiO₂) and the hornblende (3–6% TiO₂) are exceptionally Titanium-rich. The garnet is nearly identical in composition to the garnet in coronas around olivine in the same rocks. The coronas form in two stages:

1. Plagioclase+Fe-Ti Oxides+Olivine+water =Hornblende+Spinel+Orthopyroxene±Biotite +more-sodic Plagioclase
2. Hornblende+Orthopyroxene±Spinel+Plagioclase =Garnet+Clinopyroxene+more-sodic Plagioclase

The Orthopyroxene and part of the clinopyroxene form adjacent to olivine. Both reactions are linked by exchange of Mg²⁺ and Fe²⁺ with the reactions forming pyroxene and garnet coronas around olivine in the same rocks. The reactions occur under granulite fades metamorphic conditions, either during isobaric cooling or with increasing pressure at high temperature.     

大兴安岭南部扎赉特旗团发村晚古生代沉积岩源区和时代限定

大兴安岭南部扎赉特旗地区分布着一套晚古生代地层,由砂岩、粉砂岩和泥岩组成,由于缺乏古生物化石和年代学证据,前人依据地层对比将其定为晚二叠世林西组。本次工作在详细地野外地质调查基础上,运用锆石LA-ICP-MS U-Pb测年技术,对三个砂岩样品(样品号:18TF-01、18YSL-04和18XBL-01)中的碎屑锆石进行了测定,共获得219颗碎屑锆石U-Pb年龄值,其主要分布在243~269Ma,273~298Ma,305~339Ma,350~377 Ma,445~507 Ma和754~1053 Ma六个年龄区间。其中获得最年轻的一组锆石的谐和年龄为245 Ma,并结合区域上侵入该地层花岗岩的年龄,限定其沉积时代可能为中三叠世。根据碎屑锆石的年龄值特征反映出该地层具有多物源供给的特点,其中年龄为243~269Ma的碎屑物质源区主要来自于古亚洲洋闭合及碰撞造山相关的岛弧花岗岩类;年龄为273~298 Ma主要来自于大石寨组火山岩;年龄为305~339 Ma可能主要来自于格根敖包组火山岩;350~377 Ma的碎屑锆石可能源于北部大民山组火山岩;年龄为754~1053 Ma的碎屑锆石与漠河杂岩、兴华渡口群及佳木斯微陆块中元古代的岩浆事件有关;较古老~1800 Ma的碎屑锆石可能来自于古亚洲洋中微陆块或结晶基底。砂岩中锆石的形成年龄与地层沉积年龄较为相近,显示出汇聚背景下的特征。因此,综合砂岩物质组成、锆石年龄特征及弧-盆之间时空关系,显示中三叠世该地区可能形成于汇聚背景下的弧前盆地。     

Multiple provenance of detrital zircons from the Permian–Triassic boundary in the Bükk Mts., Hungary

Detailed zircon analyses were carried out on samples from the Bálvány North section, which contains the Permian–Triassic boundary. A fine-grained sandstone bed within the “boundary shale” contains a significant amount of zircon crystals. Pupin morphological, scanning electron microscopy [secondary electron, back-scattered electron, cathodoluminescence (CL)] and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) investigations were done in selected single grains to combine morphological information with radiometric ages, and infer the provenance of zircons. Three populations are distinguished on the basis of Pupin morphology. Their centres of gravity are S17, S2 and P1. The LA-ICP-MS radiometric ages reveal three main age groups and a smaller one, apart from a few scattered old ages. The largest group, comprising ca. 50% of the measured grains, has an age of 470–440 Ma. The two other main groups, which together represent ca. 25% of the measured grains, are around 280 and 600 Ma. The 280 Ma group contains slightly more grains than the 600 Ma group. A small group has an age of 370–340 Ma. In addition, there are some older grains with ages of 850, 969, 1,050 and 2,150 Ma. Based on the zircon morphology no clear separation of the different age groups could be made. Both the 280 Ma and the 470–440 Ma age groups tend to show zircon crystals derived from three types of sources: crustal granites, calc-alkaline granitoids and alkali granites and/or their volcanic equivalents. Zircons in the 450 Ma group have a magmatic rim around their altered, relict core, as revealed by CL images. Post-magmatic processes also affected the rim. The age of the core is possibly reset during the formation of the magmatic rim. This suggestion is supported by the LA-ICP-MS data, because no difference was seen between the core and the rim. The different roundness of the zircons, the well-sorted crystals and the at least five different source rocks indicate previous concentration of the grains, before their transportation into the “boundary shale”. Austroalpine and Southern Alpine rocks could be the sources of the zircon crystals, which fit well into the paleogeographical model of the area, which suggests that the Bükk Mts. was located in the foreground of the Alpine units.     

阿拉善地块南缘野芨里镁铁-超镁铁质岩体锆石U-Pb年龄及其地质意义

阿拉善地块南缘北大山地区野芨里镁铁-超镁铁质岩体主要由单辉橄榄岩、二辉橄榄岩、橄榄辉长岩组成。岩体局部发现了硫化物,主要由磁黄铁矿、镍黄铁矿与黄铜矿组成,指示岩浆结晶过程中发生了硫化物不混溶作用。岩石地球化学分析显示野芨里岩体属于铁质超基性岩,富集大离子亲石元素,相对亏损高场强元素,具有明显的Nb,Ta负异常,微量元素比值指示岩浆在上升过程中受到了中上地壳物质混染。橄榄辉长岩中锆石SHRIMP U-Pb年龄为286.6±2.5 Ma,属于早二叠世。结合区域构造演化,认为野芨里岩体形成背景可能与古亚洲洋的闭合或俯冲之后的伸展作用相关。     

In situ U–Pb dating of zircon formed from retrograde garnet breakdown during decompression in Rogaland, SW Norway

Regionally metamorphosed metapelites from Rogaland, SW Norway, contain zircon formed during the decompression reaction garnet + sillimanite + quartz → cordierite. The zircon, which occurs as inclusions in cordierite coronas around garnet, is texturally, chemically and isotopically distinct from older zircon in other textural settings in the matrix. A SHRIMP U–Pb age of 955 ± 8 Ma based on analyses in thin section on the decompression zircon from the cordierite coronas, therefore dates a point on the retrograde path, estimated from garnet–cordierite equilibria to be 5.6 kbar, 710 °C. This population was under‐represented in conventional SHRIMP analyses of individual zircon in a mono‐mineralic grain mount and, in the absence of a textural context, its significance unknown. The dominant age identified from SHRIMP analyses of the grain mount, in combination with analyses from matrix zircon in thin section, was 1035 ± 9 Ma. Based on the lack of consistent textural relationships with any specific minerals in thin section, as well as rare earth element chemistry, the 1035‐Ma population is interpreted to represent zircon growth during incipient migmatization of the rocks at 6–8 kbar and c. 700 °C. This is consistent with previous estimates for the age of regional M₁ metamorphism during the Sveconorwegian Orogeny. The most important outcome of this study is the successful analysis of zircon grains in a specific, well‐constrained reaction texture. Not only does this allow a precise point on the regional P–T path to be dated, but it also emphasizes the possibility of zircon formation during the retrograde component of a typical metamorphic cycle.     

The Las Matras tonalitic–trondhjemitic pluton,central Argentina: Grenvillian-age constraints,geochemical characteristics,and regional implications

The N–S trending belt with Grenvillian-age rocks developed in central western Argentina represents the basement of an allochthonous terrane derived from Laurentia during the Early Paleozoic. The Las Matras pluton (36°46′S, 67°07′W) is located at the southern extension of this belt in the Las Matras Block. It consists of a low-Al tonalitic to trondhjemitic facies characteristic of an arc magmatism. Isotopic studies yielded Grenvillian Rb–Sr (1212±47 Ma) and Sm–Nd (1188±47 Ma) ages which, due to the undeformed and non-metamorphosed character of the pluton, are interpreted to represent a crystallization age of around 1200 Ma. Although this age is slightly older than available dates from other exposures of the same belt, and the undeformed feature is also distinctive for Las Matras, the depleted Sr and Nd isotopic signatures of the pluton agree with those from other magmatic rocks involved in that belt. The differences found between Las Matras and the northern exposures indicate that this belt with Grenvillian-age rocks comprises regions of non-homogeneous evolution. Although the correlation of the Lower Paleozoic platform carbonates from the sedimentary cover of the Grenvillian-age basement rocks suggests the surroundings of the Southern Grenville Province (Texas and northern Mexico) as the probable detachment site for the Argentine belt, comparison of magmatic and tectonic processes involved in these basement rocks does not indicate similar evolutions. This fact can suggest an independent evolution of the Argentine belt prior to amalgamation to the Laurentian Grenville orogen.     

Early Proterozoic central-type volcano in the Pechenga structure and its relation to the ore-bearing gabbro-wehrlite complex of the Kola Peninsula

The Zapolyarnyi volcanic center is confined to the boundary between the oldest volcanic formations (I and II) of the Pechenga complex. Its structure and rock association are significantly different from those of numerous eruptive centers of areal basaltic volcanism in the Pechenga structure. It is an oval-shaped body, 700 × 300 m in size, composed of volcanic eruptive lava breccia. The clastic material of the breccia includes angular and partially molten fragments of granites, pegmatoid granites, epidosites, quartz, and feldspars embedded in basaltic lava. The basalts are titanium-rich and iron-rich varieties enriched in large-ion lithophile elements (Rb, Ba, and Sr); they are similar in composition, including Rb-Sr and Sm-Nd isotopic characteristics, to the ferropicrites of the youngest volcanic formation (IV) and their differentiation products. The basalts of the volcanic center show ε_Nd(T) values from ?3.13 to ?1.17. In general, these rocks definitely represent the vent facies of an Early Proterozoic central-type volcano. The age of the basalt of the volcanic center is 1918 ± 3 Ma (U-Pb method on zircon) and is similar to the previously determined age of volcanics of volcanic formation IV (1990 ± 40 Ma, Sm-Nd method). The rocks of this formation participated 2000–1900 Ma ago in the formation of the volcanoplutonic ore-bearing ferropicrite-gabbro-wehrlite association of the Pechenga structure. The age of the ore-bearing Pilguyarvi gabbro-wehrlite intrusion was constrained between 1987 ± 5 Ma (U-Pb method on zircon) and 1980 ± 10 Ma (U-Pb method on baddeleyite). In addition, the first data were obtained for the age of comagmatic olivine norites of the Nyasyucka dike complex in the northeastern flank of the Pechenga structure (1941 ± 3 Ma, U-Pb method on baddeleyite) and the peridotites of the Allarechka ore field in the southern framing of the Pechenga structure (1918 ± 29 Ma, U-Pb method on zircon), which were previously considered Archean. Taking into account the geological and geochemical characteristics of the rocks of the Zapolyarnyi paleovolcano and the identical age of the Ludikovian intrusions, it can be concluded that the basalts of the paleovolcano were formed during late stages of the evolution of Early Proterozoic basic-ultrabasic magmatism, which was characterized by extensive explosive activity and strong magmatic differentiation responsible for the generation of the ore-bearing intrusions of the ferropicrite-gabbro-wehrlite association.     

Petrogenesis of a late-Variscan rhyodacite at the Ossa Morena-Central Iberian zones boundary,Iberian Massif,Central Portugal: Evidence for the involvement of lithospheric mantle and meta-igneous lower crust

A late-Variscan rhyodacite is exposed at the contact between the Ossa Morena Zone and the Central Iberian Zone of the Iberian Massif, Central Portugal. Dykes of rhyodacite intruded the Série Negra Unit and the Sardoal Complex that are part of the Cadomian basement. The igneous crystallization age of the rhyodacite (308 ± 1 Ma) was obtained on igneous monazite by the ID-TIMS U-Pb method. It is broadly coeval with the emplacement of late-Variscan granitoids during the last deformation phase of the Variscan Orogeny (ca. 304–314 Ma) and with the development of the large late-Variscan strike-slip shear zones (ca. 307 Ma). The rhyodacite samples are calc-alkaline, show identical composition and belong to the same magmatic sequence. The rhyodacite isotopic signatures (Sm-Nd and δ¹⁸O) are consistent with depleted-mantle juvenile sources and the contribution of the meta-igneous lower crust. The input of mantle juvenile sources is related to Variscan reactivation of lithospheric fractures. The inherited Neoproterozoic (ca. 619 Ma) and Mesoproterozoic (ca. 1054 Ma) zircon ages, are similar to those of the Central Iberian Zone. This suggests that lower crust of the Central Iberian Zone was involved in the magma generation of the rhyodacite. Coeval late-Variscan magmatic rocks display a larger contribution from ancient crustal components, which may be attributed to the smaller volume and faster cooling rate of the rhyodacite and consequent lower melting of the crust. Mixing of juvenile mantle-derived melts with melts from the lower continental crust was followed by fractional crystallization of garnet and amphibole that remained in the source. Fractional crystallization of plagioclase, biotite, quartz and zircon occurred in shallower magma chambers. Fractional crystallization of zircon was not significant.     

Age and radiogenic isotopic composition of a late- to post-tectonic anorthosite in the Grenville Province: the Labrieville massif, Quebec

The Labrieville anorthosite massif (LBV) is found in the Central Granulite Terrain of the Grenville Structural Province, but it displays no evidence of post-emplacement deformation or metamorphism, implying intrusion following peak Grenvillian metamorphic conditions. We report U---Pb zircon dates of 1008±3.4 Ma for border leucogabbro and 1010±5.6 Ma for a cogenetic jotunite dike intruding anorthosite. We interpret these dates as igneous crystallization ages, and regard 1010 Ma as a reasonable estimate of the emplacement age for LBV. LBV is thus the youngest massif anorthosite yet recognized in North America, and its age is consistent with late-tectonic emplacement relative to the 1.1-1.0 Ga Grenville Orogeny. We also report a U---Pb date of 1015±1.8 Ma for metamorphic zircon in a country rock amphibolite. This could reflect the age of Grenvillian regional metamorphism, or perhaps a later heating episode resulting from the intrusion of numerous “late” felsic plutons in this area.

Rb---Sr, Sm---Nd and U---Th---Pb isotopic compositions for four rock types (anorthosite, jotunite, leucogabbro and a plagioclase megacryst) span narrow ranges in each case, consistent with comagmatism among these units. I_Sr (T=1010 Ma) range from 0.7032–0.7034 and are among the lowest yet reported for anorthosite in the Grenville Province. Initial ε_Nd-values are positive (+0.8 to +2.5), like other Grenville anorthosites. Pb-isotopic compositions lie near the model mantle evolution curve of Zartman and Doe (1981), implying no involvement of significantly older crust in the petrogenesis of these rocks. Collectively, these data suggest a source for LBV in the mantle or mafic lower crust. LBV is a compositionally extreme anorthosite characterized by alkalic plagioclase (An₃₂Or₁₂) and high levels of Sr (2000 ppm) and Ba (1000 ppm). These properties cannot be attributed to simple crustal contamination of mantle-derived basalt. We suggest, alternatively, that LBV's compositional features may be linked with its late-tectonic character, perhaps reflecting partial melting of mafic lower crust brought about by crustal thickening during the Grenville Orogeny.     

胶东地区蓬莱群沉积岩碎屑锆石年龄和物源

分布于鲁东胶北地区蓬莱群为一套浅变质沉积岩，角度不整合覆盖在太古宙胶东群、元古宙粉子山群上。关于蓬莱群的沉积时代尚存较大的争议，认为是震旦纪或古生代沉积形成的。蓬莱群和五莲杂岩、北淮阳变质岩带都是位于大别-苏鲁超高压变质造山带北部的重要岩石构造单元。本文报道蓬莱群沉积岩碎屑锆石年龄和始同位素分析资料，并探讨其可能的物质来源。 在栖霞地区采集了14个蓬莱群样品，主要岩石为石英岩、千枚岩、片岩、页岩，从其中4个挑出了锆石样品。分选出的碎屑锆石均为浅棕色，浑圆状，反映锆石经历了搬运作用。CL图像显示绝大多数锆石颗粒具有清晰的韵律环带内部结构，具有岩浆成因特征。在中国科学院地质与地球物理所固体同位素地球化学实验室IsoProbe-T质谱计上，采用即蒸即测方法，测得锆石207Pb/206Pb比值，其对应的年龄值主要分布在1000~1800 Ma,峰值为1200 Ma和1600 Ma左右（图1)。应用中国科学院地质与地球物理所多通道等离子质谱计Neptune MC-ICP-MS测定碎屑锆石 同位素组成。根据所获得的同位素组成，计算得到比同位素模式年龄TDM(Hf）分布在1300~3200 Ma之间，峰值为1700 Ma左右；对应的初始εHf(1200 Ma）和εHf (1600 Ma）平均值分别为-5.8和2.9（图2)。 碎屑锆石1350~1800 Ma年龄段，特别是峰期的1600 Ma，可能对应全球广泛分布的非造山事件，可能和Columbia超大陆的裂解有一定的联系。大部分锆石初始εHf (1600 Ma）值大于0，可以说明岩浆来源为幔源。而1050~1300 Ma的锆石则可能与Rodinia超大陆的汇聚形成阶段或Grenville造山事件有较密切的联系。华北克拉通大量地出露太古宙末期（2500 Ma左右）和早元古代末期(1800 Ma左右）的岩石，但在所分析的蓬莱群沉积岩几乎没有显示，可能可以排除华北克拉通为主要的沉积物源。所获得的碎屑锆石年龄虽在扬子板块有一定的出露，但缺少与Rodinia裂解有关的晚元古代700~800 Ma的岩浆锆石信息。上述资料可能暗示沉积时代为1000~800 Ma之间，但与目前的古生物证据不吻合。因此，这些碎屑锆石年龄和铅同位素数据尚不能肯定蓬莱群变质沉积岩是来源于扬子陆块，还是游离于华北、扬子的一个微陆块。如果是一个微陆块，该微陆块与Columbia裂解作用和Grenville造山作用有关，但可能未遭受到Rodinia超大陆裂解事件的影响。     

Identification of repeated Alpine (ultra) high-pressure metamorphic events by U–Pb SHRIMP geochronology and REE geochemistry of zircon: the Rhodope zone of Northern Greece

U–Pb sensitive high resolution ion microprobe (SHRIMP) zircon geochronology, combined with REE geochemistry, has been applied in order to gain insight into the complex polymetamorphic history of the (ultra) high pressure [(U)HP] zone of Rhodope. Dating included a paragneiss of Central Rhodope, for which (U)HP conditions have been suggested, an amphibolitized eclogite, as well as a leucosome from a migmatized orthogneiss at the immediate contact to the amphibolitized eclogite, West Rhodope. The youngest detrital zircon cores of the paragneiss yielded ca. 560 Ma. This date indicates a maximum age for sedimentation in this part of Central Rhodope. The concentration of detrital core ages of the paragneiss between 670–560 Ma and around 2 Ga is consistent with a Gondwana provenance of the eroded rocks in this area of Central Rhodope. Metamorphic zircon rims of the same paragneiss yielded a lower intercept ²⁰⁶Pb/²³⁸U age of 148.8±2.2 Ma. Variable post-148.8 Ma Pb-loss in the outermost zircon rims of the paragneiss, in combination with previous K–Ar and SHRIMP-data, suggest that this rock of Central Rhodope underwent an additional Upper Eocene (ca. 40 Ma) metamorphic/fluid event. In West Rhodope, the co-magmatic zircon cores of the amphibolitized eclogite yielded a lower intercept ²⁰⁶Pb/²³⁸U age of 245.6±3.9 Ma, which is interpreted as the time of crystallization of the gabbroic protolith. The metamorphic zircon rims of the same rock gave a lower intercept ²⁰⁶Pb/²³⁸U age of 51.0±1.0 Ma. REE data on the metamorphic rims of the zircons from both the paragneiss of Central Rhodope and the amphibolitized eclogite of West Rhodope show no Eu anomaly in the chondrite-normalized patterns, indicating that they formed at least under HP conditions. Flat or nearly flat HREE profiles of the same zircons are consistent with the growth of garnet at the time of zircon formation. Low Nb and Ta contents of the zircon rims in the amphibolitized eclogite indicate concurrent growth of rutile. Based on the REE characteristics, the 148.8±2.2 Ma age of the garnet–kyanite paragneiss, Central Rhodope and the 51.0±1.0 Ma age of the amphibolitized eclogite, West Rhodope are interpreted to reflect the time close to the (U)HP and HP metamorphic peaks, respectively, with a good approximation. The magmatic zircon cores of the leucosome in the migmatized orthogneiss, West Rhodope, gave a lower intercept ²⁰⁶Pb/²³⁸U age of 294.3±2.4 Ma for the crystallization of the granitoid protolith of the orthogneiss. Two oscillatory zircon rims around the Hercynian cores, yielded ages of 39.7±1.2 and 38.1±0.8 Ma (2σ errors), which are interpreted as the time of leucosome formation during migmatization. The zircons in the leucosome do not show the 51 Ma old HP metamorphism identified in the neighboring amphibolitized eclogite, possibly because the two rock types were brought together tectonically after 51 Ma. If one takes into account the two previously determined ages of ca. 73 Ma for (U)HP metamorphism in East Rhodope, as well as the ca. 42 Ma for HP metamorphism in Thermes area, Central Rhodope, four distinct events of (U)HP metamorphism throughout Alpine times can be distinguished: 149, 73, 51 and 42 Ma. Thus, it is envisaged that the Rhodope consists of different terranes, which resulted from multiple Alpine subductions and collisions of micro-continents, rather similar to the presently accepted picture in the Central and Western Alps. It is likely that these microcontinents were rifted off from thinned continental margins of Gondwana, between the African and the European plates before the onset of Alpine convergence.     

新疆东天山突出山铜铁矿区岩浆岩年代学、地球化学特征及地质意义

突出山铜铁矿床赋存于上石炭统底坎尔组火山岩中, 地质特征表明矿床成因为火山热液交代型。矿区玄武岩具有高Al、Na, 贫K、P、Ti的特点, 属于钙碱性系列火山岩。岩石具有轻稀土元素、大离子亲石元素相对富集和高场强元素相对亏损的特点。微量元素特征表明岩石与俯冲带流体作用有关, 经历了橄榄石(±辉石)和铬铁矿的结晶分异作用, 形成于石炭纪弧后盆地环境, 指示铁矿床的成矿环境为弧后盆地环境。矿区闪长岩和钾长花岗岩的锆石LA-ICP-MS U-Pb谐和年龄分别为326.2±1.6 Ma与318.2±2.5 Ma, 均为石炭纪岩浆活动的产物。根据闪长岩、钾长花岗岩、矿体与底坎尔组火山岩的穿插关系, 限定矿床的铁成矿作用时间为底坎尔组火山岩的形成时代, 早于闪长岩的形成时代(326 Ma), 而铜成矿作用时间与闪长岩的形成时代相近或稍晚。     

闽西南下古生界东坑口组与魏坊组地层层序与物源区特征——来自碎屑锆石LA-ICP-MS U-Pb测年的约束

闽西南地区下古生界魏坊组与东坑口组地层层序长期以来一直存在争议。应用LA-ICP-MS U-Pb测年,对闽西南地区下古生界魏坊组与东坑口组进行了120颗碎屑锆石的U-Pb测年,获得锆石年龄范围为506~3431Ma,主要分布于511~2796Ma之间,主要峰值年龄为964Ma,次要峰值年龄为514Ma,并存在813Ma、1231Ma、2483Ma的次级峰。年龄谱特征显示,魏坊组沉积早于东坑口组,东坑口组时代不属于中上寒武世。下古生界物源以964Ma峰值为代表,反映Grenville构造热事件的物源最显著。还获得了较丰富的峰值年龄为514Ma的泛非期构造热事件年龄,以及古太古代锆石年龄记录,为闽西南地区下古生界地层层序的确立和物源研究提供了重要新资料。