The effect of wave-induced turbulence on intertidal mudflats: Impact of boat traffic and wind

Semi-diurnal and fortnightly surveys were carried out to quantify the effects of wind- and navigation-induced high-energy events on bed sediments above intertidal mudflats. The mudflats are located in the upper fluvial part (Oissel mudflat) and at the mouth (Vasière Nord mudflat) of the macrotidal Seine estuary. Instantaneous flow velocities and mudflat bed elevation were measured at a high frequency and high resolution with an acoustic doppler velocimeter (ADV) and an ALTUS altimeter, respectively. Suspended particulate matter concentrations were estimated by calibrating the ADV acoustic backscattered intensity with bed sediments collected at the study sites. Turbulent bed shear stress values were estimated by the turbulent kinetic energy method, using velocity variances filtered from the wave contribution. Wave shear stress and maximum wave–current shear stress values were calculated with the wave–current interaction (WCI) model, which is based on the bed roughness length, wave orbital velocities and the wave period (T_S). In the fluvial part of the estuary, boat passages occurred unevenly during the surveys and were characterized by long waves (T_S>50 s) induced by the drawdown effect and by short boat-waves (T_S<10 s). Boat waves generated large bottom shear stress values of 0.5 N m⁻² for 2–5 min periods and, in burst of several seconds, larger bottom shear stress values up to 1 N m⁻². At the mouth of the estuary, west south-west wind events generated short waves (T_S<10 s) of H_S values ranging from 0.1 to 0.3 m. In shallow-water environment (water depth <1.5 m), these waves produced bottom shear stress values between 1 and 2 N m⁻². Wave–current shear stress values are one order of magnitude larger than the current-induced shear stress and indicate that navigation and wind are the dominant hydrodynamic forcing parameters above the two mudflats. Bed elevation and SPM concentration time series showed that these high energy events induced erosion processes of up to several centimetres. Critical erosion shear stress (τ_ce) values were determined from the SPM concentration and bed elevation measurements. Rough τ_ce values were found above 0.2 N m⁻² for the Oissel mudflat and about 1 N m⁻² for the Vasière Nord mudflat.     

Origin and evolution of two contrasting thermal groundwaters (CO2-rich and alkaline) in the Jungwon area,South Korea: Hydrochemical and isotopic evidence

In the Jungwon area, South Korea, two contrasting types of deep thermal groundwater (around 20–33 °C) occur together in granite. Compared to shallow groundwater and surface water, thermal groundwaters have significantly lower δ¹⁸O and δD values (> 1‰ lower in δ¹⁸O) and negligible tritium content (mostly < 2 TU), suggesting a relatively high age of these waters (at least pre-thermonuclear period) and relatively long subsurface circulation. However, the hydrochemical evolution yielded two distinct water types. CO₂-rich water (P_CO2 = 0.1 to 2 atm) is characterized by lower pH (5.7–6.4) and higher TDS content (up to 3300 mg/L), whereas alkaline water (P_CO2 = 10^− 4.1–10^− 4.6 atm) has higher pH (9.1–9.5) and lower TDS (< 254 mg/L). Carbon isotope data indicate that the CO₂-rich water is influenced by a local supply of deep CO₂ (potentially, magmatic), which enhanced dissolution of silicate minerals in surrounding rocks and resulted in elevated concentrations of Ca²⁺, Na⁺, Mg²⁺, K⁺, HCO₃⁻ and silica under lower pH conditions. In contrast, the evolution of the alkaline water was characterized by a lesser degree of water–rock (granite) interaction under the negligible inflow of CO₂. The application of chemical thermometers indicates that the alkaline water represents partially equilibrated waters coming from a geothermal reservoir with a temperature of about 40 °C, while the immature characteristics of the CO₂-rich water resulted from the input of CO₂ in Na–HCO₃ waters and subsequent rock leaching.     

The growth dynamics of Karenia brevis within discrete blooms on the West Florida Shelf

As part of the ECOHAB: Florida Program, we studied three large blooms of the harmful bloom forming dinoflagellate Karenia brevis. These blooms formed on the West Florida Shelf during Fall of 2000 off Panama City, and during Fall 2001 and Fall 2002 off the coastline between Tampa Bay and Charlotte Harbor. We suggest that these blooms represent two different stages of development, with the 2000 and 2001 blooms in an active growth or maintenance phase and the 2002 bloom in the early bloom initiation phase. Each bloom was highly productive with vertically integrated primary production values of 0.47–0.61, 0.39–1.33 and 0.65 g C m⁻² d⁻¹ for the 2000, 2001 and 2002 K. brevis blooms, respectively. Carbon specific growth rates were low during each of these blooms with values remaining fairly uniform with depth corresponding to generation times of 3–5 days. Nitrogen assimilation by K. brevis was highest during 2001 with values ranging from 0.15 to 2.14 μmol N L⁻¹ d⁻¹ and lower generally for 2000 and 2002 (0.01–0.64 and 0.66–0.76 μmol N L⁻¹ d⁻¹ for 2000 and 2002, respectively). The highest K. brevis cell densities occurred during the 2001 bloom and ranged from 400 to 800 cells mL⁻¹. Cell densities were lower for each of the 2000 and 2002 blooms relative to those for 2001 with densities ranging from 100 to 500 cells mL⁻¹. The 2000 and 2001 blooms were dominated by K. brevis in terms of its contribution to the total chlorophyll a (chl a) pool with K. brevis accounting generally for >70% of the observed chl a. For those populations that were dominated by K. brevis (e.g. 2000 and 2001), phytoplankton C biomass (C_p,0) constituted <30% of the total particulate organic carbon (POC). However, in 2002 when diatoms and K. brevis each contributed about the same to the total chl a, C_p,0 was >72% of the POC. The fraction of the total chl a that could be attributed to K. brevis was most highly correlated with POC, chl a and salinity. Nitrogen assimilation rate and primary production were highly correlated with a greater correlation coefficient than all other comparisons.     

Rates of hydrothermal cooling of new oceanic upper crust derived from lithium-geospeedometry

Episodic emplacement and cooling of lavas and dikes at mid-ocean ridges leads to large fluctuations in hydrothermal fluxes and biological activity. However, the processes operating beneath the seafloor during these transient events such as permeability creation and dike cooling are poorly understood. We have developed a new approach to determine the cooling rate of the sheeted dike complex based on the extent of diffusion of lithium from plagioclase into clinopyroxene during cooling. We have calibrated this Li-geospeedometer using new high-temperature experiments to determine both the temperature dependence of the partitioning of Li between plagioclase and clinopyroxene and the diffusion coefficient for Li in clinopyroxene. Application of this method to lavas and dikes from ODP Hole 504B shows that cooling rates vary dramatically with depth in the upper oceanic crust. Extremely rapid cooling rates (> 450 °C hr^− 1) in the upper part of the sheeted dike complex are sufficient to power hydrothermal megaplume formation within the overlying water column.     

Effects of an estuarine plume-associated bloom on the carbonate system in the lower reaches of the Pearl River estuary and the coastal zone of the northern South China Sea

We observed a phytoplankton bloom downstream of a large estuarine plume induced by heavy precipitation during a cruise conducted in the Pearl River estuary and the northern South China Sea in May–June 2001. The plume delivered a significant amount of nutrients into the estuary and the adjacent coastal region, and enhanced stratification stimulating a phytoplankton bloom in the region near and offshore of Hong Kong. A several fold increase (0.2–1.8 μg Chl L⁻¹) in biomass (Chl a) was observed during the bloom. During the bloom event, the surface water phytoplankton community structure significantly shifted from a pico-phytoplankton dominated community to one dominated by micro-phytoplankton (>20 μm). In addition to increased Chl a, we observed a significant drawdown of pCO₂, biological uptake of dissolved inorganic carbon (DIC) and an associated enhancement of dissolved oxygen and pH, demonstrating enhanced photosynthesis during the bloom. During the bloom, we estimated a net DIC drawdown of 100–150 μmol kg⁻¹ and a TAlk increase of 0–50 μmol kg⁻¹. The mean sea–air CO₂ flux at the peak of the bloom was estimated to be as high as ∼−18 mmol m⁻² d⁻¹. For an average surface water depth of 5 m, a very high apparent biological CO₂ consumption rate of 70–110 mmol m⁻² d⁻¹ was estimated. This value is 2–6 times higher than the estimated air–sea exchange rate.     

Upscaling of saturated conductivity for Hortonian runoff modelling

Stochastic and deterministic upscaling techniques are developed that upscale saturated conductivity at the support of 0.04 m² to representative actual infiltration (I_b) for support units (blocks) of 10¹–10⁴ m², as a function of steady state rainfall and runon to the block, under Hortonian runoff (infiltration excess overland flow). Parameters in the upscaling techniques represent the surface runoff flow pattern and the spatial probability distribution of saturated conductivity within the 10¹–10⁴ m² block. The stochastic upscaling technique represents the spatial process of infiltration and runoff using a simple process-imitating model, estimating I_b using Monte Carlo simulation. The deterministic upscaling technique aggregates these processes by a deterministic function relating rainfall and runon to I_b. The stochastic upscaling technique is shown to be capable to upscale saturated conductivity derived from ring infiltrometers to I_b values of plots (1 m²) corresponding to measured I_b values using rainfall simulators. It is shown that both upscaling techniques can be used to estimate I_b for each time step and each block in transient rainfall–runoff models, giving better estimates of cumulative runoff from a hillslope and a small catchment than model runs that do not use upscaling techniques.     

Benthic oxygen fluxes and sediment properties on the northeastern New Zealand continental shelf

We examined spatial variations in benthic remineralisation (measured as sediment oxygen consumption (SOC)) and sediment properties on the northeastern New Zealand continental shelf and slope to assess the importance of benthic mineralisation in this ecosystem and to provide data for more complete global carbon budgets. SOC measured in dark incubations conducted in early summer ranged from 128 μmol m⁻² h⁻¹ at the deepest (360 m) to 1222 μmol m⁻² h⁻¹ at the shallowest (4.2 m) site and decreased significantly with water depth (p<0.001, r²=0.78, SOC=1222.8−456.3×log₁₀[water depth], n=14 sites). These rates were in the range found on continental shelves elsewhere (64–1750 μmol m⁻² h⁻¹, n=30 studies) and had a very similar distribution with water depth. SOC was also measured in light incubations at seven sites (4.2–35 m water depth) to examine the effects of microphytobenthos and accounted for 42–106% of rates measured in the dark. Measurements of near-bed light intensities suggested that microphytobenthos production was not solely regulated by light intensity but evidently influenced by other factors. A two-dimensional PCA ordination of surface sediment properties accounted for 83.3% of the total variance in the data and divided the study area into three clusters that corresponded well to its spatial division into the shallow (<30 m) Firth of Thames, the Hauraki Gulf (30–50 m) and the northern shelf-slope region. In the Firth of Thames sediments were very fine-grained with low CaCO₃ and high total organic matter and pigment content, and low C:N ratios. The northern shelf-slope sediments showed the opposite trends to the Firth of Thames and those in the Hauraki Gulf had mostly intermediate values. Dark SOC was significantly correlated with sediment organic matter, carbon, nitrogen, pigments and silt/clay content (p<0.05, r=0.55–0.85) but a multiple linear regression revealed that water depth was the only significant predictor. Calculations suggest that approximately 13%, 10% and 34% of primary production is remineralised in the sediments of the northern shelf-slope region, Hauraki Gulf and Firth of Thames, respectively, indicating a strong benthic–pelagic coupling on the northeastern New Zealand continental shelf that was particularly pronounced in the Firth of Thames due to its shallow depth and significant terrestrial and riverine inputs.     

Critical erosion profiles in macro-tidal estuary sediments: Implications for the stability of intertidal mud and the slope of mud banks

Vertical profiles of the critical erosion threshold (τ_crit) in sediment have been measured at 11 stations along the axis of the Tamar Estuary and at a single station in a tributary of the Tamar at St. John's Ford. The τ_crit of surface sediment increased from 0.04 Pa in the upper, brackish estuary to 0.09 Pa in the lower estuary. In the upper estuary τ_crit only increased slightly with depth whereas in the marine estuary τ_crit increased rapidly from 0.09 Pa at the surface to 0.25 Pa at 15 cm below the sediment surface. The results showed that the relationship between τ_crit and bulk density (ρ_b) obtained previously for surface sediment was also applicable to sediments from depths of 10–15 cm and probably deeper. Profiles of ρ_b were measured to depths of 70 cm using a corer. In the lower (marine) estuary ρ_b increased with depth in the sediment from 1580 kg m⁻³ at the surface to 1720 kg m⁻³ at 70 cm. In the upper estuary ρ_b values were lower at 1170–1200 kg m⁻³ and profiles were almost homogeneous indicating that consolidation was not occurring. The mid-estuary was transitional between these two situations. These results are consistent with the seasonal accumulation and loss of ‘mobile’ sediment observed previously in the upper estuary with changes in river flow, and with the apparent stability of intertidal mud in the lower marine estuary deduced from historical bathymetric survey records. The slopes of the intertidal mud banks ranged from 1–2% in the lower estuary to 20–25% in mid-estuary but, instead of continuing to increase in steepness towards the head as the estuary became narrower, the measured slopes actually decreased. It is speculated that the lack of consolidation through continual mobilisation and settlement cycles combined with an increase in silt content in the upper estuary resulted in sediment that lacked the mechanical strength to maintain steep slopes.     

Inter-annual and seasonal variations in the air–sea CO2 balance in the central Baltic Sea and the Kattegat

We estimated the net annual air–sea exchange of carbon dioxide (CO₂) using monitoring data from the East Gotland Sea, Bornholm Sea, and Kattegat for the 1993–2009 period. Wind speed and the sea surface partial pressure of CO₂ (pCO₂^w), calculated from pH, total alkalinity, temperature, and salinity, were used for the flux calculations. We demonstrate that regions in the central Baltic Sea and the Kattegat alternate between being sinks (−) and sources (+) of CO₂ within the −4.2 to +5.2 mol m⁻² yr⁻¹ range. On average, for the 1994–2008 period, the East Gotland Sea was a source of CO₂ (1.64 mol m⁻² yr⁻¹), the Bornholm Sea was a source (2.34 mol m⁻² yr⁻¹), and the Kattegat was a sink (−1.16 mol m⁻² yr⁻¹). Large inter-annual and regional variations in the air–sea balance were observed. We used two parameterizations for the gas transfer velocity (k) and the choice varied the air–sea exchange by a factor of two. Inter-annual variations in pCO₂^w between summers were controlled by the maximum concentration of phosphate in winter. Inter-annual variations in the CO₂ flux and gas transfer velocity were larger between winters than between summers. This indicates that the inter-annual variability in the total flux was controlled by winter conditions. The large differences between the central Baltic Sea and Kattegat were considered to depend partly on the differences in the mixed layer depth.     

Kaguyak dome field and its Holocene caldera,Alaska Peninsula

Kaguyak Caldera lies in a remote corner of Katmai National Park, 375 km SW of Anchorage, Alaska. The 2.5-by-3-km caldera collapsed ~ 5.8 ± 0.2 ka (¹⁴C age) during emplacement of a radial apron of poorly pumiceous crystal-rich dacitic pyroclastic flows (61–67% SiO₂). Proximal pumice-fall deposits are thin and sparsely preserved, but an oxidized coignimbrite ash is found as far as the Valley of Ten Thousand Smokes, 80 km southwest. Postcaldera events include filling the 150-m-deep caldera lake, emplacement of two intracaldera domes (61.5–64.5% SiO₂), and phreatic ejection of lakefloor sediments onto the caldera rim. CO₂ and H₂S bubble up through the lake, weakly but widely. Geochemical analyses (n = 148), including pre-and post-caldera lavas (53–74% SiO₂), define one of the lowest-K arc suites in Alaska. The precaldera edifice was not a stratocone but was, instead, nine contiguous but discrete clusters of lava domes, themselves stacks of rhyolite to basalt exogenous lobes and flows. Four extracaldera clusters are mid-to-late Pleistocene, but the other five are younger than 60 ka, were truncated by the collapse, and now make up the steep inner walls. The climactic ignimbrite was preceded by ~ 200 years by radial emplacement of a 100-m-thick sheet of block-rich glassy lava breccia (62–65.5% SiO₂). Filling the notches between the truncated dome clusters, the breccia now makes up three segments of the steep caldera wall, which beheads gullies incised into the breccia deposit prior to caldera formation. They were probably shed by a large lava dome extruding where the lake is today.     

Spatial and temporal variability of phytoplankton and environmental factors in a temperate estuary of South America (Atlantic coast,Argentina)

A spatial and temporal study on data collected along the longitudinal gradient of the Principal Channel of Bahía Blanca estuary, Argentina, was carried out during 1992–1993. At nine stations, phytoplankton abundance, chlorophyll a (Chl-a) concentration, inorganic nutrient levels, Secchi disk depth, euphotic depth:mixing depth ratio (Z_eu:Z_m), salinity and temperature were recorded. Phytoplankton abundance, Chl-a concentration and nutrient levels decreased towards the outer zone of the estuary. The inner zone (stations 1 and 2), which was characterized by high turbidity, high nutrient concentrations and high Z_eu:Z_m (>0.16, [critical mixing ratio]), registered the highest phytoplankton abundance and Chl-a concentrations. Temporal variability of data was also noteworthy in this zone. The highest biomass values thus corresponded to June, July, August and the beginning of spring (18 μg Chl-a L⁻¹ and 9×10⁶ cells L⁻¹) concomitantly with a diatom bloom. In the middle zone (stations 3–6), a strong phytoplankton biomass decrease was observed and it coincided with both deep-mixed depths and low Z_eu:Z_m (<0.16). The outer zone (stations 7–9), which was characterized by low phytoplankton biomass values and low nutrient levels all along the year, was the area mostly influenced by waters from the adjacent continental shelf. In view of the above, it can be concluded that the most important primary production in the Bahía Blanca would be produced in the shallow inner zone during winter, being the spatial reach of the phytoplankton biomass principally limited to estuarine waters. Presumably, less than 5% of such biomass may reach the coastal area of the estuary.     

High thresholds for avoidance of sonar by free-ranging long-finned pilot whales (Globicephala melas)

The potential effects of exposing marine mammals to military sonar is a current concern. Dose–response relationships are useful for predicting potential environmental impacts of specific operations. To reveal behavioral response thresholds of exposure to sonar, we conducted 18 exposure/control approaches to 6 long-finned pilot whales. Source level and proximity of sonar transmitting one of two frequency bands (1–2 kHz and 6–7 kHz) were increased during exposure sessions. The 2-dimensional movement tracks were analyzed using a changepoint method to identify the avoidance response thresholds which were used to estimate dose–response relationships. No support for an effect of sonar frequency or previous exposures on the probability of response was found. Estimated response thresholds at which 50% of population show avoidance (SPL_max = 170 dB re 1 μPa, SEL_cum = 173 dB re 1 μPa² s) were higher than previously found for other cetaceans. The US Navy currently uses a generic dose–response relationship to predict the responses of cetaceans to naval active sonar, which has been found to underestimate behavioural impacts on killer whales and beaked whales. The navy curve appears to match more closely our results with long-finned pilot whales, though it might underestimate the probability of avoidance for pilot-whales at long distances from sonar sources.     

Nutrient availability in support of Karenia brevis blooms on the central West Florida Shelf: What keeps Karenia blooming?

Identifying nutrient sources, primarily nitrogen (N) and phosphorus (P), sufficient to support high biomass blooms of the red tide dinoflagellate, Karenia brevis, has remained problematic. The West Florida Shelf is oligotrophic, yet populations >10⁶ cells L⁻¹ frequently occur and blooms can persist for months. Here we examine the magnitude and variety of sources for N and P that are available to support blooms. Annual average in situ or background concentrations of inorganic N in the region where blooms occur range 0.02–0.2 μM while inorganic P ranges 0.025–0.24 μM. Such concentrations would be sufficient to support the growth of populations up to ∼3×10⁴ cells L⁻¹ with at least a 1 d turnover rate. Organic N concentrations average 1–2 orders of magnitude greater than inorganic N, 8–14 μM while organic P concentrations average 0.2–0.5 μM. Concentrations of organic N are sufficient to support blooms >10⁵ cells L⁻¹ but the extent to which this complex mixture of N species is utilizable is unknown. Other sources of nutrients included in our analysis are aerial deposition, estuarine flux, benthic flux, zooplankton excretion, N₂-fixation, and subsequent release of organic and inorganic N by Trichodesmium spp., and release of N and P from dead and decaying fish killed by the blooms. Inputs based on atmospheric deposition, benthic flux, and N₂-fixation, were minor contributors to the flux required to support growth of populations >2.6×10⁴ cells L⁻¹. N and P from decaying fish could theoretically maintain populations at moderate concentrations but insufficient data on the flux and subsequent mixing rates does not allow us to calculate average values. Zooplankton excretion rates, based on measured zooplankton population estimates and excretion rates could also supply all of the N and P required to support populations of 10⁵ and 10⁶ cells L⁻¹, respectively, but excretion is considered as “regenerated” nutrient input and can only maintain biomass rather than contribute to “new” biomass. The combined estuarine flux from Tampa Bay, Charlotte Harbor, and the Caloosahatchee River can supply a varying, but at times significant level of N and P to meet growth and photosynthesis requirements for populations of approximately 10⁵ cells L⁻¹ or below. Estimates of remineralization of dead fish could supply a significant proportion of bloom maintenance requirements but the rate of supply must still be determined. Overall, a combination of sources is required to maintain populations >10⁶ cells L⁻¹.     

New insights into the spatial variability of the surface water carbon dioxide in varying sea ice conditions in the Arctic Ocean

In the summer of 2005, continuous surface water measurements of fugacity of CO₂ (fCO₂^sw), salinity and temperature were performed onboard the IB Oden along the Northwest Passage from Cape Farwell (South Greenland) to the Chukchi Sea. The aim was to investigate the importance of sea ice and river runoff on the spatial variability of fCO₂ and the sea–air CO₂ fluxes in the Arctic Ocean. Additional data was obtained from measurements of total alkalinity (A_T) by discrete surface water and water column sampling in the Canadian Arctic Archipelago (CAA), on the Mackenzie shelf, and in the Bering Strait. The linear relationship between A_T and salinity was used to evaluate and calculate the relative fractions of sea ice melt water and river runoff along the cruise track. High-frequency fCO₂^sw data showed rapid changes, due to variable sea ice conditions, freshwater addition, physical upwelling and biological processes. The fCO₂^sw varied between 102 and 678 μatm. Under the sea ice in the CAA and the northern Chukchi Sea, fCO₂^sw were largely CO₂ undersaturated of approximately 100 μatm lower than the atmospheric level. This suggested CO₂ uptake by biological production and limited sea–air CO₂ gas exchange due to the ice cover. In open areas, such as the relatively fresh water of the Mackenzie shelf and the Bering Strait, the fCO₂^sw values were close to the atmospheric CO₂ level. Upwelling of saline and relatively warm water at the Cape Bathurst caused a dramatic fCO₂^sw increase of about 100 μatm relative to the values in the CAA. At the southern part of the Chukchi Peninsula we found the highest fCO₂^sw values and the water was CO₂ supersaturated, likely due to upwelling. In the study area, the calculated sea–air CO₂ flux varied between an oceanic CO₂ sink of 140 mmol m⁻² d⁻¹ and an oceanic source of 18 mmol m⁻² d⁻¹. However, in the CAA and the northern Chukchi Sea, the sea ice cover prevented gas exchange, and the CO₂ fluxes were probably negligible at this time of the year. Assuming that the water was exposed to the atmosphere by total melting and gas exchange would be the only process, the CO₂ undersaturated water in the ice-covered areas will not have the time to reach the atmospheric CO₂ value, before the formation of new sea ice. This study highlights the value of using high-frequency measurements to gain increased insight into the variable and complex conditions, encountered on the shelves in the Arctic Ocean.     

Low-temperature hydrothermal alteration of intra-caldera tuffs,Miocene Tejeda caldera,Gran Canaria,Canary Islands

The Miocene Tejeda caldera on Gran Canaria erupted ~ 20 rhyolite–trachyte ignimbrites (Mogán Group 14–13.3 Ma), followed by ~ 20 phonolitic lava flows and ignimbrites (Fataga Group 13–8.5 Ma). Upper-Mogán tuffs have been severely altered immediately within the caldera margin, whereas extra-caldera Mogán ignimbrites, and overlying Fataga units, are apparently unaltered. The altered intra-caldera samples contain minerals characteristic of secondary fluid–rock interaction (clays, zeolites, adularia), and relics of the primary mineral assemblage identified in unaltered ignimbrites (K-feldspar, plagioclase, pyroxene, amphibole, and groundmass quartz). Major and trace-element data indicate that Si, Na, K, Pb, Sr, and Rb, were strongly mobilized during fluid–rock interaction, whereas Ti, Zr, and Nb behaved in a more refractory manner, experiencing only minor mobilization. The δ¹⁸O values of the altered intra-caldera tuffs are significantly higher than in unaltered extra-caldera ignimbrites, consistent with an overall low-temperature alteration environment. Unaltered extra-caldera ignimbrites have δD values between − 110‰ and − 173‰, which may reflect Rayleigh-type magma degassing and/or post-depositional vapour release. The δD values of the altered intra-caldera tuffs range from − 52‰ to − 131‰, with ambient meteoric water at the alteration site estimated at ca. − 15‰. Interaction and equilibration of the intra-caldera tuffs with ambient meteoric water at low temperature can only account for whole-rock δD values of around − 45‰, given that ?D_clay–water is ca. − 30‰ at 100 °C, and decreases in magnitude at higher temperatures. All altered tuff samples have δD values that are substantially lower than − 45‰, indicating interaction with a meteoric water source with a δD value more negative than − 15‰, which may have been produced in low-temperature steam fumaroles. Supported by numerical modeling, our Gran Canaria data reflect the near-surface, epithermal part of a larger, fault-controlled hydrothermal system associated with the emplacement of the high-level Fataga magma chamber system. In this near-surface environment, fluid temperatures probably did not exceed 200–250 °C.     

Distribution,fluxes and bacterial consumption of total organic carbon in a populated Mediterranean Gulf

Saronikos Gulf (Greece) practically constitutes the sea border of the metropolitan city of Athens and the alongshore outskirts, and it receives the treated wastes of ∼4 million people from a point source that discharges on the sea bottom at ∼65 m water depth. Total organic carbon (TOC) was measured in 477 seawater samples collected in the Saronikos Gulf, during 10 cruises, from August 2001 to May 2004 and analyzed with the High Temperature Catalytic Oxidation method (HTCO). TOC concentrations ranged from 49 to 198 μmol C L⁻¹ in agreement with other Mediterranean coastal waters. The highest TOC concentrations were found in the upper waters (0–75 m), whereas in the deeper parts of the Gulf (between 100 and 400 m) TOC concentrations were kept constantly low (49–70 μmol C L⁻¹). A general pattern towards higher TOC concentrations during summer was also observed. Calculations of non-refractory (labile+semi-labile) organic material based on a one-dimensional (1D) conceptual model showed that it corresponds to 33% of the bulk TOC during summer and to 27% during winter. Bacterial production (BP) was measured at selected stations of ∼70–80 m depth using the [³H] leucine method. Depth integrated BP values varied from 2.8 to 10.9 mmol m⁻² d⁻¹, whereas extraordinary high integrated BP values (126 and 140 mmol m⁻² d⁻¹) were observed at the station over the treated sewage outflow. From the turnover time, τ, of the non-refractory TOC by bacteria it was implied that organic matter in the effluents is extremely labile (2–58 days). Moreover, τ values at the other sites showed that during summer non-refractory organic material resisted bacterial degradation (1–8 months), whereas during early spring it was easily degradable (20–50 days). The balance of TOC fluxes for the Inner Gulf for June and September 2003 showed that the Inner Gulf acts as a net producer of TOC during summer. Our results suggest that the presence of the Athens treated sewage outfall does not contribute to the observed summer accumulation of TOC in the Inner Gulf and other causes such as increased bacteria predation and/or nutrient limitation must be responsible.     

A case study of airborne and satellite remote sensing of a spring bloom event in the Gulf of Finland

The concentrations of chlorophyll-a (chl-a), total suspended solids (TSS) and the absorption coefficient of colored dissolved organic matter (a_CDOM(400)) are estimated in Case II waters using medium resolution imaging spectrometer (MERIS) satellite (full resolution [FR] level 1b, 300 m resolution) and AISA airborne spectrometer data acquired during a spring bloom in the Gulf of Finland, Baltic Sea on April 27, 2004. The accuracy of the estimation is analyzed using empirical band-ratio algorithms together with in situ observations that include water samples analyzed in a laboratory (variation ranges: 22–130 μg/l, 2.9–20 mg/l, and 1.29–2.61 m⁻¹ for chl-a, TSS and a_CDOM(400), respectively). Additional in situ estimates (transects) on these characteristics are available through absorption and scattering coefficients measured with an ac-9 absorption and attenuation meter installed in a flow-through system. The retrieval accuracy (R²) of all three water quality characteristics with MERIS data is close to or above 0.9, while the RMSE is 7.8 μg/l (22%), 0.74 mg/l (16%) and 0.08 m⁻¹ (5%), for chl-a, TSS and a_CDOM(400), respectively. The validity of the chl-a algorithm is tested using nine additional data points. The BIAS-error for these points is 5.2 μg/l and the RMSE is 10.6 μg/l. The effects of changes in the atmospheric characteristics on band-ratio algorithms in cases where no concurrent in situ reference data are available are analyzed using the MODerate spectral resolution atmospheric TRANSmittance algorithm and computer model (MODTRAN). The additional error due to these changes is estimated to be below 20% for the applied ratio algorithms. The water quality data available in the level 2 MERIS-product distributed by the European Space Agency did not include valid results for the date investigated here.     

Benthic fluxes of dissolved inorganic carbon in the Tinto–Odiel system (SW of Spain)

The benthic fluxes (diffusive and with chambers) of dissolved inorganic carbon (DIC), dissolved oxygen (DO) and total alkalinity (TA) have been calculated in summertime in the estuary system formed by the mouths of the Tinto and Odiel rivers (SW of Spain). An increase of DIC in interstitial water with depth was found for all stations showing values of up to 28 mM at a depth of 5 cm. The diffusive fluxes of DIC and TA obtained ranging between 1.8–7.8 and 1.5–7.3 mmol m⁻² d⁻¹, respectively. These intervals are in agreement with those found for other coastal systems. Considering the plots of DIC vs. alkalinity (ΔDIC/ΔTA) in the first 30 cm of interstitial water, it was deduced that sulphate reduction and the oxidation of sulphides seem to have special relevance in the sediments of the stations studied. The benthic fluxes of inorganic carbon and DO measured by benthic chambers were variable, presenting elevated values (309–433 mmol DIC m⁻² d⁻¹ and 50–120 mmol DO m⁻² d⁻¹). The most elevated fluxes of DIC were seen at the stations with high anthropogenic influence (close to populated areas and industrial discharges). A great proportion of these fluxes are due to CaCO₃ dissolution processes, which constitute an estimated 49% of total DIC flux. DIC and DO benthic flux quotients were far in excess of unity, indicating the significance processes of anaerobic degradation of organic material at the stations studied.     

Diffusional losses of amended anaerobic electron acceptors in sediment field microcosms

Hudson River sediment microcosms from Piles Creek (PC), Piermont Marsh (PM), and Iona Island (II) were amended with ∼100 mM nitrate or sulfate to stimulate anaerobic bioremediation. Nitrate and sulfate decreased over two years of field incubation and the fraction of these losses due to diffusion to the water column was predicted using Fick’s law. Apparent diffusion (D_app) values of 1-4 × 10⁻¹⁰ m² s⁻¹ predicted the majority of loss/gain from/to the sediments by 700 d, but not at all times. Effective diffusion (D_eff) values predicted by the porosity function (D_eff = D_mol ε^4/3) were larger than those observed in the field, and field data indicates a cube power relationship: D_eff = D_mol ε³. D_app greatly increased in surficial layers at PM and PC in year two, suggesting that bioadvection caused by bioturbating organisms had occurred. The effects of bioturbation on transport to/from the sediments are modeled, and results can be applied to various sediment treatment scenarios such as capping.     

Comparison of the attenuation properties for two different areas in eastern Anatolia,Turkey

In this study, the attenuation properties of the crust and the quality factor of S wave in eastern Anatolia (Turkey) were determined by local earthquakes for two different areas, Oltu and Erzurum. Seismic wave attenuation can be changed with high pressure or structural effects. Therefore, we argued that the estimation of attenuation coefficient in seismic active zones in Eastern Anatolia is a very useful tool to determine seismic activities. It uses regional waveform data set from two stations, OLT and ERZ, for 95 events that occurred in these regions between 2001 and 2005. The attenuation has been determined using the Chobra–Alexeev model based on the epicenter distance–amplitude relations. This model allows for investigation of the effects of variations in attenuation properties for different areas. We introduced a new magnitude formula for these areas using the amplitude normalization methods for reference values M_L=4, so as to correct effects of the magnitudes. We also determined velocity of seismic waves. The average attenuation coefficient (α), average quality factor (Q_s) and P and S waves velocities were obtained with normalized amplitude values for Erzurum (ERZ) and Oltu (OLT) as 0.0135 km⁻¹, 37, 6.20 km/s and 3.38 km/s and 0.0151, 34, 6.13 and 3.48.