A ∼25 ka Indian Ocean monsoon variability record from the Andaman Sea

Recent paleoclimatic work on terrestrial and marine deposits from Asia and the Indian Ocean has indicated abrupt changes in the strength of the Asian monsoon during the last deglaciation. Comparison of marine paleoclimate records that track salinity changes from Asian rivers can help evaluate the coherence of the Indian Ocean monsoon (IOM) with the larger Asian monsoon. Here we present paired Mg/Ca and δ¹⁸O data on the planktic foraminifer Globigerinoides ruber (white) from Andaman Sea core RC12-344 that provide records of sea-surface temperature (SST) and δ¹⁸O of seawater (δ¹⁸O_sw) over the past 25,000 years (ka) before present (BP). Age control is based on nine accelerator mass spectrometry (AMS) dates on mixed planktic foraminifera. Mg/Ca-SST data indicate that SST was ∼3 °C cooler during the last glacial maximum (LGM) than the late Holocene. Andaman Sea δ¹⁸O_sw exhibited higher than present values during the Lateglacial interval ca 19–15 ka BP and briefly during the Younger Dryas ca 12 ka BP. Lower than present δ¹⁸O_sw values during the BØlling/AllerØd ca 14.5–12.6 ka BP and during the early Holocene ca 10.8–5.5 ka BP are interpreted to indicate lower salinity, reflect some combination of decreased evaporation–precipitation (E–P) over the Andaman Sea and increased Irrawaddy River outflow. Our results are consistent with the suggestion that IOM intensity was stronger than present during the BØlling/AllerØd and early Holocene, and weaker during the late glaciation, Younger Dryas, and the late Holocene. These findings support the hypothesis that rapid climate change during the last deglaciation and Holocene included substantial hydrologic changes in the IOM system that were coherent with the larger Asian monsoon.     

Lateglacial and early Holocene climatic oscillations on the western Svalbard margin,European Arctic

A multi proxy sediment core record on the continental margin off western Svalbard, European Arctic, reflects large climatic and oceanographic oscillations at the Lateglacial–early Holocene transition. Based on studies of planktonic foraminifera, their stable oxygen and carbon isotopic composition and ice rafted debris, we have reconstructed the last 14 cal. ka BP. The period 14–13.5 cal. ka BP was characterized by highly unstable climatic conditions. Short-lived episodes of warming alternated with meltwater pulses and enhanced iceberg rafting. This period correlates to a regional warming of the northern North Atlantic. An overall decrease in meltwater took place during the deglaciation (14–10.8 cal. ka BP). The late Younger Dryas and subsequent transition into the early Holocene is characterized by a reduced flux of planktonic foraminifera and increased iceberg rafting. A major warming took place from 10.8 to 9.7 cal. ka BP, the influence of meltwater ceased and the flux of warm Atlantic Water increased. From 9.7 to 8.8 cal. ka BP, the western Svalbard margin surface waters were significantly warmer than today. This warm period, the thermal maximum, was followed by an abrupt cooling at 8.8. cal. ka BP, caused by an increased influence of Arctic Water from the Arctic Ocean. The results document that the European Arctic was very sensitive to climatic and oceanographic changes at the end of the last glacial and during the Holocene.     

Holocene climate variability in Europe: Evidence from δ18O,textural and extension-rate variations in three speleothems

Time-series O isotope profiles for three U–Th dated stalagmites have revealed that for much of the Holocene, a site on the Atlantic seaboard (SW Ireland) exhibits first-order δ¹⁸O trends that are almost exactly out of phase with coupled δ¹⁸O curves from two southern European sites (SE France and NW Italy). In the Irish stalagmite (CC3 from Crag Cave, SW Ireland), low δ¹⁸O at 10,000 cal yr BP reflects cool conditions. By the early to mid-Holocene (9000–6000 cal yr BP) δ¹⁸O had increased, reflecting the onset of warmer conditions on the Atlantic seaboard. This shift to higher δ¹⁸O was accompanied by a marked increase in the stalagmite extension rate, reinforcing our interpretation that this was a period of relative warmth. Except for an episode of increased extension rate about 5500 yr ago, δ¹⁸O in the Crag stalagmite exhibits a gradual decrease, accompanied by declining extension rates between 7800 and 3500 cal yr BP, interpreted as a cooling trend. There is evidence for increases in both δ¹⁸O and stalagmite extension rate in the period from 3500 cal yr BP to the present day suggesting a return to warmer conditions on the Atlantic seaboard. In the stalagmite from NW Italy (ER76, Grotta di Ernesto, Trentino province) the early-Holocene (c. 9200-7800 cal yr BP) is characterised by high δ¹⁸O, probably indicative of warm and/or dry conditions. Exceptionally low δ¹⁸O from 7800 to 6900 cal yr BP at this site reflects a well-defined wet phase (Cerin wet phase). In the last three millennia, this stalagmite exhibits a shift to lower δ¹⁸O, interpreted as some combination of cooler and/or wetter conditions. Unlike the Irish stalagmite, the Italian sample does not show a correlation between δ¹⁸O and extension rate. Instead, its extension rate correlates roughly with δ¹³C, presumably reflecting a climate-driven vegetation change. In the early Holocene, δ¹⁸O in the French stalagmite (CL26, Grotte de Clamouse, Herault province, SE France) was low relative to its Holocene average. For much of the period since c. 3500 cal yr BP this stalagmite exhibits higher δ¹⁸O than in the early Holocene, suggesting warmer conditions. Like the Irish stalagmite, the French sample exhibits a well-defined correlation between δ¹⁸O and extension rate. Had drip-water availability been the dominant control on δ¹⁸O at this semi-arid site then higher δ¹⁸O would have been accompanied by lower, not higher extension rates. This suggests strongly that temperature rather than rainfall amount was the dominant control at this site. While conclusions regarding the patterns of climate variability on a continent scale must remain tentative because of the limited number of stalagmites studied we argue that early Holocene warm conditions on the Atlantic seaboard (Irish site) coincided with relatively cool conditions at the Clamouse site. By c. 3500 yr ago the pattern appears to have been reversed.     

Persistent sea surface temperature and declined sea surface salinity in the northwestern tropical Pacific over the past 7500 years

To understand Holocene climate evolutions in low-latitude region of the western Pacific, paired δ¹⁸O and Mg/Ca records of planktonic foraminifer Globigerinoides ruber (250–300 μm, sensu stricto, s.s.) from a marine core ORI715-21 (121.5°E, 22.7°N, water depth 760 m) underneath the Kuroshio Current (KC) off eastern Taiwan were analyzed. Over the past 7500 years, the geochemical proxy-inferred sea surface temperature (SST) hovered around 27–28 °C and seawater δ¹⁸O (δ¹⁸O_W) slowly decreased 0.2–0.4‰ for two KC sites at 22.7° and 25.3°N. Comparison with a published high-SST and high-salinity equatorial tropical Pacific record, MD98-2181 located at the Mindanao Current (MC) at 6.3°N, reveals an anomalous time interval at 3.5–1.5 kyr ago (before 1950 AD). SST gradient between the MC site and two KC site decrease from 1.5–2.0 °C to only 0–1 °C, and δ¹⁸O_W from 0.1–0.3‰ to 0‰ for this 2-kyr time window. The high SST and low gradient could result from a northward shift of the North Equatorial Current, which implies a weakened KC. The long-term descending δ¹⁸O_W and increasing precipitation in the entire low-latitude western Pacific and the gradually decreasing East Asian summer monsoonal rainfall during middle-to-late Holocene is likely caused by different land and ocean responses to solar insolation and/or enhanced moisture transportation from the Atlantic to Pacific associated with the southward movement of ITCZ.     

Fluvio–sedimentary response of the monsoon-fed Indian rivers to Late Pleistocene–Holocene changes in monsoon strength: reconstruction based on existing 14C dates

The primary objective of the present study is to identify major phases of alluviation in the Indian region since the abrupt Deglacial intensification of the monsoon (∼15 cal ka BP) on the basis of analysis of 68 radiocarbon dates from two major hydro-geomorphic regions of India: the Central Ganga Basin (CGB) and the Deccan Peninsula (DP). The recognition of main phases of alluviation and incision has been achieved by evaluating the temporal distribution and clustering of the radiocarbon dates from alluvial sequences. The clusters were detected on the basis of the interpretation of the summed probability distribution plots derived by using OxCal version 4.0.1 and CALPAL (version May 2006) software packages.The summed probability plots reveal that periods of alluviation in the CGB, represented by three clusters (13.9–12.3, 11.9–11.2 and 9.8–9.0 cal ka BP) occur roughly before the onset of Early Holocene monsoon optimum phase. Two other clusters occur in the intervals 3.6–2.8 and 1.1–0.9 cal ka BP. The peak monsoon period generally lacks clusters of radiocarbon dates implying fluvial erosion and channel incision. This period also shows clustering of radiocarbon dates of the abandoned channels. In comparison, ¹⁴C dates from DP alluvial units form clusters at 16.4–14, 12.8–11.2, 10.8–8.9, 8.1–6.7 and 5.1–3.9 cal ka BP, indicating an association with the Deglacial–Early Holocene humid phase. Alluviation in the DP appears to have continued, more or less, uninterrupted till the middle of the Holocene epoch. The beginning and end of the discernible gap in the radiocarbon dates of CGB (9.0–3.6 cal ka) broadly corresponds with the two well-established short-term events of the Holocene, 8.2 and 4.2 ka cal BP. In comparison, the prominent gap of DP radiocarbon dates (3.9–2.1 ka cal BP) approximately begins with the 4.2 ka cal BP short-term event (onset of aridity) and ends with the 2.0 ka cal BP enhanced monsoon event.Notwithstanding the inter-regional differences in the fluvio–sedimentary response in the India region, the clusters of radiocarbon dates indicate that the century to millennium scale variations in fluvial activity in the Indian subcontinent were intimately linked to long-term fluctuations in the monsoon strength during the Late Quaternary.     

Late-glacial to Holocene transition in northern Spain deduced from land-snail shelly accumulations

Shells of the helicid Cepaea nemoralis were studied using taphonomic, isotopic and morphometric measurements to estimate late glacial–Holocene (~ 12.1–6.3 cal ka BP) environmental conditions in northern Spain. Higher taphonomic alteration among Holocene shells suggests lower sedimentation rates or higher shell-destruction rates than during glacial conditions. Shells preserved the aragonitic composition despite differing degree of skeleton damage. Shell δ¹³C values were ? 10.3 ± 1.1‰, ? 8.2 ± 2.3‰, and ? 7.3 ± 1.6‰ for modern, Holocene and late-glacial individuals, respectively. Higher δ¹³C values during the late-glacial and some Holocene periods imply higher water stress of C₃ plants and/or higher limestone contribution than today. Intrashell δ¹³C values were higher during juvenile stages suggesting higher limestone ingestion to promote shell growth. Shell δ¹⁸O values were ? 1.1 ± 0.7‰, ? 0.9 ± 0.8‰ and ? 0.1 ± 0.7‰ for modern, Holocene and late-glacial specimens, respectively. A snail flux-balance model suggests that during ~ 12.1 ? 10.9 cal ka BP conditions were drier and became wetter at ~ 8.4 ? 6.3 cal ka BP and today. Intrashell δ¹⁸O profiles reveal that glacial individuals experienced more extreme seasonality than interglacial shells, despite possible larger hibernation periods. Shell size correlated positively with δ¹⁸O values, suggesting that growth rates and ultimate adult size of C. nemoralis may respond to climate fluctuation in northern Spain.     

AMS 14C chronology of the world's southernmost woolly mammoth (Mammuthus primigenius Blum.)

The world's definite southernmost woolly mammoth record is a molar from Ji’nan (around 36°N), Shandong Province, China. AMS ¹⁴C dating of the specimen, gave a conventional ¹⁴C age of 33,150±250 BP. The period of 40–30 ka BP corresponds to the later phase of the Marine Oxygen Isotope Stage 3 (MIS 3a), recognized as the global interstadial of the last glacial period. However, it is known that the winter monsoon strengthened in Asia during the period 35–33 ka BP, and the age of the woolly mammoth specimen from Ji’nan corresponds to that age. The specimen suggests that this area became cold and dry in 33 ka BP, and grassland or open forest, suitable habitat for woolly mammoths, developed during this short time span. This age is similar to the age of the southernmost woolly mammoth record in Europe, therefore supporting a hypothesis by Porter and An [1995. Correlation between climate events in the North Atlantic and China during the last glaciation. Nature 375, 305–308] that an important component of Chinese palaeoclimates may be linked to changes in North Atlantic oceanic conditions.     

Climatic and environmental changes in north-western Russia between 15,000 and 8000 cal yr BP: a review

Multi-proxy palaeoenvironmental studies of nine sediment sequences from four areas in north-western Russia reveal significant changes in climate, lake productivity and vegetation during the Lateglacial and early Holocene that show some degree of correlation with changes reconstructed from sites throughout the North Atlantic region. At Lake Nero in the Rostov-Jaroslavl’ area, which is outside the maximum limit of the Scandinavian Ice Sheet, sedimentation recommenced shortly after 15 cal ka BP in response to increases in temperature and humidity during Greenland Interstadial 1 (GI-1; Bølling-Allerød). However, climatic amelioration during GI-1 was slow to increase lake organic productivity or trigger large-scale changes in much of northwestern Russia. In general, this region was characterised by long-lasting lake-ice cover, low lake productivity, soil erosion, and dwarf shrub and herb tundra until the end of Greenland Stadial 1 (GS-1; Younger Dryas). At some sites, distinct increases in lake organic productivity, mean summer temperatures and humidity and the expansion of forest trees coincide with rapid warming at the beginning of the Holocene and the increasing influence of warm air masses from the North Atlantic. At other sites, particularly on the Karelian Isthmus, but also in Russian Karelia, the delayed response of limnic and terrestrial environments to early Holocene warming is likely related to the cold surface waters of the Baltic Ice Lake, the proximity of the Scandinavian Ice Sheet and associated strengthened easterlies, and/or extensive permafrost and stagnant ice. These multi-proxy studies underscore the importance of local conditions in modifying the response of individual lakes and their catchments.While Lateglacial vegetation was dominated by Betula nana and Salix shrubs and various herbs, pollen and plant macrofossils suggest that Betula pubescens trees became established as early as 14–13 cal ka BP in the Rostov-Jaroslavl’ area. In general, our data sets suggest that trees migrated from the southeast to the west and then spread later to the northeast and northwest, paralleling the direction of ice retreat, with Betula pubescens immigrating first, followed by Pinus sylvestris and Picea abies. However, palaeoecological records from Lake Terebenskoye in the Valdai Highlands suggest that the arrival of Picea abies preceded other trees in that area and that it colonised tundra communities as early as 12 cal ka BP. Since Lateglacial vegetation change in north-western Russia was time-transgressive, independent measures of palaeoclimate (e.g., chironomid-based palaeotemperature estimates) are needed for this region.     

Oceanic and atmospheric forcing of early Holocene ice shelf retreat,George VI Ice Shelf,Antarctica Peninsula

We use lake sediment records from an epishelf lake on Alexander Island to provide a detailed picture of the Holocene history of George VI Ice Shelf (GVI-IS). Core analyses included; micropaleontology (diatoms/foraminifera), stable isotope (δ¹⁸O, δ¹³C), geochemistry (total organic carbon (TOC), total nitrogen (TN), C/N ratios) and grain-size analyses. These data provide robust evidence for one period of past ice shelf absence during the early Holocene. The timing of this period has been constrained by 10 AMS ¹⁴C dates performed on mono-specific foraminifera samples. These dates suggest that GVI-IS was absent between c 9600 cal yr BP and c 7730 cal yr BP. This early Holocene collapse immediately followed a period of maximum Holocene warmth that is recorded in some Antarctic ice cores and coincides with an influx of warmer ocean water onto the western Antarctic Peninsula (AP) shelf at c 9000 cal yr BP. The absence of a currently extant ice shelf during this time interval suggests that early Holocene ocean-atmosphere variability in the AP was greater than that measured in recent decades.     

Synchronous climate anomalies in the western North Pacific and North Atlantic regions during the last 14,000 years

A peat cellulose δ¹⁸O record spanning around 14,000 years from the Hani peat mire in northeastern China reveals several abrupt temperature anomalies in the period from the last deglaciation through the Holocene. The timing of these anomalies coincides well with the notable cooling events recorded respectively using the GISP2 ice core and ice-rafted sediment of the North Atlantic Ocean, such as the Older Dryas, Inter-Allerød, Younger Dryas, and the nine ice-rafted debris events. The results demonstrate that this repeating pattern of abrupt temperature deterioration is not limited to the North Atlantic area at high latitude but also exists in the western North Pacific region at middle latitude. The synchronous temperature anomalies possibly are resulted from the joint effects of meltwater discharge into the North Atlantic Ocean and reduced solar activity. In the period from around 8600 to 8200 cal. yrs BP the Hani peat record shows a broad δ¹⁸O peak that may reflect compound climate signals resulting from the two kinds of forcing factors: the temperature drop related to reduced solar activity at around 8600–8250 cal. yrs BP, and the temperature anomaly attributed to the meltwater effect at around 8220 ± 70 cal. yrs BP. This result may provide palaeo-temperature evidence for existence of the sharp “8.2 k” event in the western North Pacific region. In addition, our results have revealed that in the period from the last deglaciation through the Holocene the synchronous temperature anomalies before and after the “8.2 k” event seem to be related to meltwater outflow and reduced solar activity, respectively. It is important that the all temperature anomalies—whether because of reduced solar activity in the late Holocene or from meltwater discharge in the early Holocene—are accompanied by an abrupt decline in the Indian Ocean summer monsoon and abrupt strengthening of the East Asian summer monsoon. It is likely that reduced solar activity and meltwater outflow appear to modulate Earth system changes in the same direction. The influences could be compounded. Reduced solar activity and meltwater outburst both appear to act as triggers for occurrence of the El Niño phenomenon in the equatorial Pacific Ocean, which may result in broad teleconnections between the temperature anomaly in the Northern Hemisphere and abrupt variation of the Asian monsoon.     

Late Pleistocene submarine mass movements: occurrence and causes

An extensive study of Late Pleistocene continental slope submarine mass movements was undertaken. Twenty-six well-dated mass movements occurred during the last 45 ka BP in the North Atlantic sector. A latitudinal trend is observed: between 45 and 12 ka BP most events occur in the mid- to low-latitudes, post-12 ka BP high-latitude occurring events dominate. A cluster of events is associated with the Last Glacial sea level lowstand and Termination 1B. Further events are associated with Termination 1A and the Holocene. Prior to 23 ka BP no clear relationship with the ice core atmospheric methane record is observed, in contrast during and following the deglaciation there is a possible relationship with atmospheric methane. High-latitude mass movements are primarily controlled by cyrospheric-induced variations in sedimentation and local sea level. In high latitudes, the glaciation subdues mass movement activity through reduced seisimicity, sediment supply and ocean temperatures. Deglaciation increases the sediment supply, seisimicity and ocean temperatures, thus increasing the likelihood of continental slope failures. For example the Storegga event coincides with high isostatic uplift and postglacial seisimicity, while the Andøya and Trænadjupet events occur before and after the peak rates respectively. In contrast low latitudes experience greater risk of slope failures during glacial periods from falling sea levels, although during the deglacial and interglacial period there is a potential for failure from changes in deposition centres and rates, as well as warming ocean temperatures potentially leading to dissociation of gas hydrates. The ongoing rapid deglaciation of coastal Greenland and Antarctica and consequent rapid input of sediment, isostatic uplift, crustal stress release and warming bottom water temperature at the shelf break will increase the risk of continental slope failure in these regions.     

A paleoclimate record of the last 17,600 years in stalagmites from the B7 cave,Sauerland, Germany

Petrographical and geochemical parameters of stalagmites from the B7 cave in Iserlohn–Letmathe (Northern Rhenish Massif, NW Germany) record Late- and postglacial climate changes (temperature and/or precipitation). Fabrics and microfacies of the stalagmite profiles lead to a differentiation of four hierarchies of rhythms. Clastic layers in the stalagmites are caused by flooding events and are time markers. Twenty-four TIMS Th/U-age-dates provide a time calibration of stalagmite growth phases. One stalagmite reveals an early growth period between 17.6 and 16.7 ka BP. Between 9.6 and 5.5 ka BP (Atlantic episode of the Holocene) the growth rate of the stalagmites was higher than before and after this time, with dominant light-porous microfacial laminae and high δ¹⁸O and δ¹³C values representing partly kinetic fractionation effects. This part of the Holocene is interpreted as a mainly warm episode with frequent interruptions of dripping. Within the past 4 ka the profiles with predominant dark compact facies reveal low isotopic values which may be interpreted as a temperature proxy record. The stalagmite records resemble records from an Irish stalagmite. Correlation with the Δ¹⁴C record from European tree rings suggests that colder periods in the North Atlantic were accompanied by drier winters in central Europe.     

Holocene glacier and deep water dynamics,Adélie Land region,East Antarctica

This study presents a high-resolution multi-proxy investigation of sediment core MD03-2601 and documents major glacier oscillations and deep water activity during the Holocene in the Adélie Land region, East Antarctica. A comparison with surface ocean conditions reveals synchronous changes of glaciers, sea ice and deep water formation at Milankovitch and sub-Milankovitch time scales. We report (1) a deglaciation of the Adélie Land continental shelf from 11 to 8.5 cal ka BP, which occurred in two phases of effective glacier grounding-line retreat at 10.6 and 9 cal ka BP, associated with active deep water formation; (2) a rapid glacier and sea ice readvance centred around 7.7 cal ka BP; and (3) five rapid expansions of the glacier–sea ice systems, during the Mid to Late Holocene, associated to a long-term increase of deep water formation. At Milankovich time scales, we show that the precessionnal component of insolation at high and low latitudes explains the major trend of the glacier–sea ice–ocean system throughout the Holocene, in the Adélie Land region. In addition, the orbitally-forced seasonality seems to control the coastal deep water formation via the sea ice–ocean coupling, which could lead to opposite patterns between north and south high latitudes during the Mid to Late Holocene. At sub-Milankovitch time scales, there are eight events of glacier–sea ice retreat and expansion that occurred during atmospheric cooling events over East Antarctica. Comparisons of our results with other peri-Antarctic records and model simulations from high southern latitudes may suggest that our interpretation on glacier–sea ice–ocean interactions and their Holocene evolutions reflect a more global Antarctic Holocene pattern.     

Testing models of mid to late Holocene sea-level change,North Queensland,Australia

Understanding the nature of global ice-equivalent eustatic sea-level changes during the mid to late Holocene is important to our understanding of how ice sheets will respond to future climate change. This study re-analyses the indicative meaning and age control of existing relative sea-level (RSL) data from Cleveland Bay, North Queensland, Australia and presents new RSL data from a foraminifera-based transfer function as a preliminary test of global geophysical models in this region during the mid to late Holocene. The foraminifera-based transfer function produces reliable RSL estimates, consistent through the mid to late Holocene at different locations in Cleveland Bay. Analysis of the combined RSL database reveals that RSL rose above present between 8 and 6.2 ka cal. BP, with the peak of the sea-level highstand c. 2.8 m above present at c. 5 ka cal. BP, remaining relatively stable above +1.5 m from 6.2 until at least 2.3 ka cal. BP, falling to present in the last millennia. This long period of sea level above present in the mid to late Holocene suggests a gradual rather than abrupt end to global ice melt, which must have continued into the late Holocene. This new analysis also shows no evidence for episodic fluctuations within the highstand, although they cannot be entirely ruled out by this study. This study demonstrates that more sea-level data needs to be collected from locations uncontaminated by glacio-isostasy, hydro-isostasy and tectonic effects, in order to better constrain the late Holocene melt histories of the large polar ice sheets.     

Stable isotope composition of subfossil Cerastoderma glaucum shells from the Szczecin Bay brackish deposits and its palaeogeographical implications (South Baltic Coast,Poland)

The environmental conditions of the Szczecin Bay, which existed prior to Szczecin Lagoon, have been reconstructed on the basis of the stable carbon and oxygen isotope (¹⁸O and ¹³C) analysis and radiocarbon dates obtained for subfossil shells of Cerastoderma (Cardium) glaucum. The shells in the collected core were well preserved in their life positions, representing a geochemical record of past temperature variation over the middle Holocene. Three major periods with different thermal conditions have been distinguished in the interval ~ 6000–4300 cal yr BP, when the important Littorina regional transgression took place. During the first period, 6000–5250 cal yr BP, water temperature decreased by 1.4°C, and then remained constant over the second period (5250–4750 cal yr BP). In contrast, during the third period (4750–4300 cal yr BP) both δ-values were highly variable and the mean summer temperature (March–November) increased by about 3.5°C. During first two periods, δ¹⁸O and δ¹³C were significantly correlated, indicating stability of the environmental conditions.     

Paleoclimate variability in central Taiwan during the past 30 Kyrs reflected by pollen, δ13CTOC,and n-alkane-δD records in a peat sequence from Toushe Basin

A total of 233 samples from the upper 16 m of the Toushe peat core retrieved in central Taiwan were measured for TOC and δ¹³C_TOC values. From these samples, 17 selected samples with large δ¹³C_TOC fluctuations were analyzed for n-alkane and δD of the C27 and C29 n-alkanes. Combining with the detailed high-resolution pollen and geochemical records, this study reveals more detailed climatic variations in terms of temperature and precipitation as well as abrupt climatic events during the past 30 Kyrs. Before the Last Glacial Maximum (LGM), climate was cold and damp with predominantly woodland vegetation in Toushe Basin, and turned to cold and dry after 25 Kyr BP. Climatic conditions there were the worst during LGM over the past 30 Kyrs, especially around 23 and 18 Kyr BP when the woodland was diminished and C4 grass was dominated. Although short durations of relatively wet conditions could be found at 17, 16 and 14 Kyr BP, cold and dry climates were prevailing during 29.5–28, 24–22, 17–15 and 13–11.5 Kyr BP, corresponding to Heinrich (H) Events 3, 2, 1, and Younger Dryas (YD), respectively. During the early Holocene, dry climate occurred at ∼11, ∼10, 9.7–9.2 and ∼8 Kyr BP; whereas wet condition appeared at 10.3, 9.8, 9–7.5 Kyr BP. In the middle Holocene, climate kept warm and moderate wet in the first half period, but many dry events existed in the second half following a cold and dry event at 6 Kyr BP. After a sharply warm peak at 5.2 Kyr BP, the climate in Toushe turned to cold quickly, and tree/shrub vegetation disappeared completely with the replacement of C3 grasses. In the late Holocene, climate was relatively wetter with predominant C3 grasses in the basin. Our climatic interpretations based on the peat records agree well with the Greenland ice core and Chinese speleothem records on millennium time scales during the last glacial period. Dry climates corresponding to weakening of the East Asian Summer Monsoon (EASM) during the Heinrich events and Younger Dryas in central Taiwan and eastern China demonstrate the climatic forcing on such long time scales in concert with regional monsoon climate. However, the discrepancies exist between our peat record and the Dongge/Hulu stalagmite record on: (1) the age of H2; (2) climate intensities of LGM and H1; and (3) wetness condition during Holocene. These observations call for further study on high-resolution climatic changes especially on moisture budget in the East Asian monsoonal region.     

Using dual isotopic data to track the sources and behaviors of dissolved sulfate in the western North China Plain

This paper investigated the sources and behaviors of sulfate in groundwater of the western North China Plain using sulfur and oxygen isotopic ratios. The groundwaters can be categorized into karst groundwater (KGW), coal mine drainage (CMD) and pore water (subsurface saturated water in interstices of unconsolidated sediment). Pore water in alluvial plain sediments could be further classified into unconfined groundwater (UGW) with depth of less than 30 m and confined groundwater (CGW) with depth of more than 60 m. The isotopic compositions of KGW varied from 9.3‰ to 11.3‰ for δ³⁴S_SO4 with the median value of 10.3‰ (n = 4) and 7.9‰ to 15.6‰ for δ¹⁸O_SO4 with the median value of 14.3‰ (n = 4) respectively, indicating gypsum dissolution in karst aquifers. δ³⁴S_SO4 and δ¹⁸O_SO4 values of sulfate in CMD ranged from 10.8‰ to 12.4‰ and 4.8‰ to 8.7‰ respectively. On the basis of groundwater flow path and geomorphological setting, the pore water samples were divided as three groups: (1) alluvial–proluvial fan (II₁) group with high sulfate concentration (median values of 2.37 mM and 1.95 mM for UGW and CGW, respectively) and positive δ³⁴S_SO4 and δ¹⁸O_SO4 values (median values of 8.8‰ and 6.9‰ for UGW, 12.0‰ and 8.0‰ for CGW); (2) proluvial slope (II₂) group with low sulfate concentration (median values of 1.56 mM and 0.84 mM for UGW and CGW, respectively) and similar δ³⁴S_SO4 and δ¹⁸O_SO4 values (median values of 9.0‰ and 7.4‰ for UGW, 10.2‰ and 7.7‰ for CGW); and (3) low-lying zone (II₃) group with moderate sulfate concentration (median values of 2.13 mM and 1.17 mM for UGW and CGW, respectively) and more positive δ³⁴S_SO4 and δ¹⁸O_SO4 values (median values of 10.7‰ and 7.7‰ for UGW, 20.1‰ and 8.8‰ for CGW). In the present study, three major sources of sulfate could be differentiated as following: sulfate dissolved from Ordovician to Permian rocks (δ³⁴S_SO4 = 10–35‰ and δ¹⁸O_SO4 = 7–20‰), soil sulfate (δ³⁴S_SO4 = 5.9‰ and δ¹⁸O_SO4 = 5.8‰) and sewage water (δ³⁴S_SO4 = 10.0‰ and δ¹⁸O_SO4 = 7.6‰). Kinetic fractionations of sulfur and oxygen isotopes as a result of bacterial sulfate reduction (BSR) were found to be evident in the confined aquifer in stagnant zone (II₃), and enrichment factors of sulfate–sulfur and sulfate–oxygen isotopes calculated by Rayleigh equation were −12.1‰ and −4.7‰ respectively along the flow direction of groundwater at depths of 60–100 m. The results obtained in this study confirm that detailed hydrogeological settings and identification of anthropogenic sources are critical for elucidating evolution of δ³⁴S_SO4 and δ¹⁸O_SO4 values along with groundwater flow path, and this work also provides a useful framework for understanding sulfur cycling in alluvial plain aquifers.     

Revised radiocarbon ages on woolly rhinoceros (Coelodonta antiquitatis) from western central Scotland: significance for timing the extinction of woolly rhinoceros in Britain and the onset of the LGM in central Scotland

Woolly rhinoceros bones, from a number of sites in Britain, have been AMS radiocarbon dated following ultrafiltration pre-treatment. These determinations give a coherent set of ages between >50 and c. 35 cal ka BP. The youngest (35,864–34,765 cal BP) come from the area around Bishopbriggs in western central Scotland and are derived from glaciofluvial sand and gravel overlain by till, both deposited during the Last Glacial Maximum (LGM) glaciation. A previous radiocarbon date from the site suggested that woolly rhinoceros lived c. 27 ¹⁴C ka BP and the region was ice-free at the time. This date has had significant influence on the timing of extinction of woolly rhinoceros and the onset of glaciation over Britain during the LGM. The new dates revise this earlier determination and confirm that woolly rhinoceros became extinct in Britain after c. 35 cal ka BP, that central Scotland was ice-free at this time, and glaciation extended across this region sometime after 35 cal ka BP.     

Geochemical and isotopic evidence for a magmatic-hydrothermal origin of the polymetallic vein-type Zn-Pb deposits in the northwest margin of Jiangnan Orogen,South China

Polymetallic vein-type Zn-Pb deposits are located in the Xiangxi–Qiandong zinc-lead metallogenic belt (XQMB) of the northwestern margin of the Jiangnan Orogen, South China. Ores are mainly found in fault-bounded quartz veins hosted in the upper part of the Banxi Group that consists of low-grade metamorphic sandstone, siltstone with minor tuff interbeds. The Zn-Pb deposits primarily contain sphalerite, galena, chalcopyrite and pyrite, accompanied by quartz and minor calcite. Zinc, lead, copper, indium and gallium are enriched in these ores. Investigation of the ore fluid reveals low temperature (87–262 °C) with scattered salinity (range from 2.73 to 26.64 wt% NaCl_eqv.). Hydrogen and oxygen isotopic compositions of fluid inclusions in quartz indicate mixing of magmatic hydrothermal fluid and meteoric water (δ¹⁸O_{H2O SMOW} = 0.2‰ to 4.2‰; δD_{H2O SMOW} = −126‰ to −80‰). Carbon and oxygen isotopic composition of carbonate samples indicate the magmatic hydrothermal origin of CO₃²⁻ or CO₂ in ore-forming fluid (δ¹³C_PDB = −6.9‰ to −5.7‰, δ¹⁸O_SMOW = 11.3‰ to 12.7‰). Sulfur and lead isotopic compositions (δ³⁴S_VCDT = 8.8–14.2‰ and ²⁰⁶Pb/²⁰⁴Pb = 17.156–17.209, ²⁰⁷Pb/²⁰⁴Pb = 15.532–15.508, ²⁰⁸Pb/²⁰⁴Pb = 37.282–37.546) demonstrate that sulfur sources were relatively uniform, and low radiogenic lead isotopic compositions indicate that ore metals were derived from a relatively unradiogenic source, probably by mixing of mantle with crust. Therefore, polymetallic vein-type Zn-Pb mineralization in this area probably arose from a magmatic-related hydrothermal system, and the deposition of sulfides occurred in response to cooling and boiling of magmatic hydrothermal fluids (high salinity, high δ¹⁸O_H2O and δD_H2O and metal-bearing), and is mainly the result of emplacement into open space and mixing with meteoric water (low salinity, low δ¹⁸O_H2O and δD_H2O). This study provides direct evidence that magmatism was involved in the ore-forming processes of the low temperature metallogenic district, South China, and it raises awareness about the presence of polymetallic vein-type Zn-Pb deposits in the northwest margin of Jiangnan Orogen and their potential as a source of zinc, copper, indium and gallium.     

Ore-forming process of the Huijiabao gold district,southwestern Guizhou Province,China: Evidence from fluid inclusions and stable isotopes

The Huijiabao gold district is one of the major producers for Carlin-type gold deposits in southwestern Guizhou Province, China, including Taipingdong, Zimudang, Shuiyindong, Bojitian and other gold deposits/occurrences. Petrographic observation, microthermometric study and Laser Raman spectroscopy were carried out on the fluid inclusions within representative minerals in various mineralization stages from these four gold deposits. Five types of fluid inclusions have been recognized in hydrothermal minerals of different ore-forming stages: aqueous inclusions, CO₂ inclusions, CO₂–H₂O inclusions, hydrocarbon inclusions, and hydrocarbon–H₂O inclusions. The ore-forming fluids are characterized by a H₂O + CO₂ + CH₄ ± N₂ system with medium to low temperature and low salinity. From early mineralization stage to later ones, the compositions of the ore-forming fluids experienced an evolution of H₂O + NaCl → H₂O + NaCl + CO₂ + CH₄ ± N₂ → H₂O + NaCl ± CH₄ ± CO₂ with a slight decrease in homogenization temperature and salinity. The δ¹⁸O values of the main-stage quartz vary from 15.2‰ to 24.1‰, while the δD_H2O and calculated δ¹⁸O_H2O values of the ore-forming fluids range from −56.9 to −116.3‰ and from 2.12‰ to 12.7‰, respectively. The δ¹³C_PDB and δ¹⁸O_SMOW values of hydrothermal calcite change in the range of −9.1‰ to −0.5‰ and 11.1–23.2‰, respectively. Stable isotopic characteristics indicate that the ore-forming fluid was mainly composed of ore- and hydrocarbon-bearing basinal fluid. The dynamic fractionation of the sulfur in the diagenetic pyrite is controlled by bacterial reduction of marine sulfates. The hydrothermal sulfides and the diagenetic pyrite from the host rocks are very similar in their sulfur isotopic composition, suggesting that the sulfur in the ore-forming fluids was mainly derived from dissolution of diagenetic pyrite. The study of fluid inclusions indicates that immiscibility of H₂O–NaCl–CO₂ fluids took place during the main mineralization stage and caused the precipitation and enrichment of gold.