Biometry of the Late Cretaceous Arkhangelskiella group: ecophenotypes controlled by nutrient flux

This study focuses on the morphometry and taxonomy of the Late Cretaceous coccolith genus Arkhangelskiella. Sixty samples from the Campanian–Maastrichtian interval of DSDP Hole 390A (Blake Nose) were investigated for their contents of Arkhangelskiella spp. In each sample one hundred specimens of Arkhangelskiella spp. were examined by measuring the coccolith length and width, as well as the length and width of the central area. In the samples investigated the Arkhangelskiella group exhibits a large size variation, specimens length varies from 4.95 μm to 14.52 μm. Former taxonomic concepts, based on morphometry, subdivided the Arkhangelskiella group into three species: Arkhangelskiella maastrichtiana, Arkhangelskiella confusa and Arkhangelskiella cymbiformis. Our data show a large variability of the morphometric data (coccolith length, width of the outer rim). There is no indication for three independant species; two of the quoted taxa (1. thick outer rim = Arkhangelskiella maastrichtiana; 2. very thin outer rim = Arkkhangelskiella cymbiformis) seem to be extreme forms of a continuous morphometric lineage. The lower part of the investigated succession (139.92–133.42 mbsf) is dominated by small specimens with an average length of 6.8 μm whereas the upper part (132.86–126.15 mbsf) is characterized by larger specimens (mean 8.7 μm). In DSDP Hole 390A the size increase appears to be very abrupt, within two samples (samples 133.42 mbsf, 132.86 mbsf) the mean size increases by 1.51 μm. Previous morphometric studies of Arkhangelskiella indicate a more continuous size increase throughout the late Campanian–Maastrichtian. The abrupt size increase observed here hints toward a minor hiatus in DSDP Hole 390A separating upper Campanian from lower Maastrichtian sediments. It seems likely that the size increase of Arkhangelskiella reflects changes of various environmental factors like nutrient supply and sea water chemistry (Mg/Ca ratio; Ca concentration). A comparison of morphometric results with previous palaeoecological studies documents a nutrient control for the growth of Arkhangelskiella. Small specimens can be related to more mesotrophic conditions whereas large specimens are linked to oligotrophic surface waters.     

Stable isotopic signatures of the modern land snail Eremina desertorum from a low-latitude (hot) dry desert—A study from the Petrified Forest,New Cairo,Egypt

This study was conducted on recent desert samples—including (1) soils, (2) plants, (3) the shell, and (4) organic matter from modern specimens of the land snail Eremina desertorum—which were collected at several altitudes (316–360 m above sea level) from a site in the New Cairo Petrified Forest. The soils and shell_{E. desertorum} were analyzed for carbonate composition and isotopic composition (δ¹⁸O, δ¹³C). The plants and organic matter_{E. desertorum} were analyzed for organic carbon content and δ¹³C. The soil carbonate, consisting of calcite plus minor dolomite, has δ¹⁸O values from −3.19 to −1.78‰ and δ¹³C values −1.79 to −0.27‰; covariance between the two values accords with arid climatic conditions. The local plants include C3 and C4 types, with the latter being dominant. Each type has distinctive bulk organic carbon δ¹³C values: −26.51 to −25.36‰ for C3-type, and −13.74 to −12.43‰ for C4-type plants.The carbonate of the shell_{E. desertorum} is composed of aragonite plus minor calcite, with relatively homogenous isotopic compositions (δ¹⁸O_mean = −0.28 ± 0.22‰; δ¹³C_mean = −4.46 ± 0.58‰). Most of the δ¹⁸O values (based on a model for oxygen isotope fractionation in an aragonite-water system) are consistent with evaporated water signatures. The organic matter_{E. desertorum} varies only slightly in bulk organic carbon δ¹³C values (−21.78 ± 1.20‰) and these values suggest that the snail consumed more of C3-type than C4-type plants. The overall offset in δ¹³C values (−17.32‰) observed between shell_{E. desertorum} carbonate and organic matter_{E. desertorum} exceeds the value expected for vegetation input, and implies that 30% of carbon in the shell_{E. desertorum} carbonate comes from the consumption of limestone material.     

Release,transport and attenuation of metals from an old tailings impoundment

The oxidation of sulfide minerals from mine wastes results in the release of oxidation products to groundwater and surface water. The abandoned high-sulfide Camp tailings impoundment at Sherridon, Manitoba, wherein the tailings have undergone oxidation for more than 70 a, was investigated by hydrogeological, geochemical, and mineralogical techniques. Mineralogical analysis indicates that the unoxidized tailings contain nearly equal proportions of pyrite and pyrrhotite, which make up to 60 wt% of the total tailings, and which are accompanied by minor amounts of chalcopyrite and sphalerite, and minute amounts of galena and arsenopyrite. Extensive oxidation in the upper 50 cm of the tailings has resulted in extremely high concentrations of dissolved SO₄ and metals and As in the tailings pore water (pH < 1, 129,000 mg L⁻¹ Fe, 280,000 mg L⁻¹ SO₄, 55,000 mg L⁻¹ Zn, 7200 mg L⁻¹ Al, 1600 mg L⁻¹ Cu, 260 mg L⁻¹ Mn, 110 mg L⁻¹ Co, 97 mg L⁻¹ Cd, 40 mg L⁻¹ As, 15 mg L⁻¹ Ni, 8 mg L⁻¹ Pb, and 3 mg L⁻¹ Cr). The acid released from sulfide oxidation has been extensive enough to deplete carbonate minerals to 6 m depth and to partly deplete Al-silicate minerals to a 1 m depth. Below 1 m, sulfide oxidation has resulted in the formation of a continuous hardpan layer that is >1 m thick. Geochemical modeling and mineralogical analysis indicate that the hardpan layer consists of secondary melanterite, rozenite, gypsum, jarosite, and goethite. The minerals indicated mainly control the dissolved concentrations of SO₄, Fe, Ca and K. The highest concentrations of dissolved metals are observed directly above and within the massive hardpan layer. Near the water table at a depth of 4 m, most metals and SO₄ sharply decline in concentration. Although dissolved concentrations of metals and SO₄ decrease below the water table, these concentrations remain elevated throughout the tailings, with up to 60,600 mg L⁻¹ Fe and 91,600 mg L⁻¹ SO₄ observed in the deeper groundwater. During precipitation events, surface seeps develop along the flanks of the impoundment and discharge pore water with a geochemical composition that is similar to the composition of water directly above the hardpan. These results suggest that shallow lateral flow of water from a transient perched water table is resulting in higher contaminant loadings than would be predicted if it were assumed that discharge is derived solely from the deeper primary water table. The abundance of residual sulfide minerals, the depletion of aluminosilicate minerals in the upper meter of the tailings and the presence of a significant mass of residual sulfide minerals in this zone after 70 a of oxidation suggest that sulfide oxidation will continue to release acid, metals, and SO₄ to the environment for decades to centuries.     

Mineralogical and microfabric characteristics of magnetite in the Wuyang Precambrian BIFs,southern North China Craton: Implications for genesis and depositional processes of the associated BIFs

Precambrian Banded Iron Formations (BIFs) are widely distributed in the North China Craton (NCC). Among them, the Wuyang BIFs located in the southern margin of NCC occur in the Late Archaean Tieshanmiao Formation and can be subdivided in two different sub-types: (i) quartz–magnetite BIFs (QMB), consisting of magnetite, fine-microcrystalline quartz and minor calcite and (ii) pyroxene–magnetite BIFs (PMB), composed of pyroxene, fine-microcrystalline quartz and subordinate feldspars. Both sub-types display apparent discrepancies in terms of petrography and mineral composition.As shown in Electron BackScattered Diffraction (EBSD) images and micrographs, magnetite grains from the QMB range in size from tens up to hundreds of μm, whereas magnetite crystals from the PMB can be up to a few tens of μm across. The X-ray diffraction (XRD) structural data indicate that magnetite from both BIF sub-types is equiaxed (cubic) and was generated by sedimentary metamorphic processes. The cell parameters of magnetite in the QMB are a = b = c = 8.396 Å and Z = 8, which deviate slightly from these of magnetite in the PMB: a = b = c = 8.394 Å and Z = 8. The analytical results of Raman spectroscopy analysis revealed micro-structural signatures of both magnetite (Raman shifts near 552 cm⁻¹ and 673 cm⁻¹) and hematite (Raman shifts near 227 cm⁻¹, 295 cm⁻¹ and 413 cm⁻¹). In magnetite from both QMB and PMB, the crystallinity degree is similar for magnetite micro-structures but varies significantly for hematite micro-structures. Oxygen fugacity (fO₂) conditions fluctuated during the recrystallization of magnetite in the QMB, whereas no evident variation of fO₂ occurred during the formation of magnetite in the PMB. Analytical results of laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) show that the Si, Al and Mg abundances are higher in magnetite from the QMB, whereas the Ti and Mn contents are more elevated in magnetite from the PMB. Magnetite composition also denotes that both BIF sub-types are sedimentary-metamorphic origin, whereas the deposition of PMB was also affected by volcanic activities. Overall data indicate that the differences in the depositional environment of each BIF sub-type are due to the involvement of volcanic eruption processes in the genesis of the PMB. Thus, this paper indicated that the QMB was deposited by chemical deposition at the long-term interval of volcanic eruptions, and the PMB were the product of chemical deposition affected by the volcanic eruption.     

Mercury deposition and methylmercury formation in Narraguinnep Reservoir,southwestern Colorado,USA

Narraguinnep Reservoir in southwestern Colorado is one of several water bodies in Colorado with a mercury (Hg) advisory as Hg in fish tissue exceed the 0.3 μg/g guideline to protect human health recommended by the State of Colorado. Concentrations of Hg and methyl-Hg were measured in reservoir bottom sediment and pore water extracted from this sediment. Rates of Hg methylation and methyl-Hg demethylation were also measured in reservoir bottom sediment. The objective of this study was to evaluate potential sources of Hg in the region and evaluate the potential of reservoir sediment to generate methyl-Hg, a human neurotoxin and the dominant form of Hg in fish. Concentrations of Hg (ranged from 1.1 to 5.8 ng/L, n = 15) and methyl-Hg (ranged from 0.05 to 0.14 ng/L, n = 15) in pore water generally were highest at the sediment/water interface, and overall, Hg correlated with methyl-Hg in pore water (R² = 0.60, p = 0007, n = 15). Net Hg methylation flux in the top 3 cm of reservoir bottom sediment varied from 0.08 to 0.56 ng/m²/day (mean = 0.28 ng/m²/day, n = 5), which corresponded to an overall methyl-Hg production for the entire reservoir of 0.53 g/year. No significant point sources of Hg contamination are known to this reservoir or its supply waters, although several coal-fired power plants in the region emit Hg-bearing particulates. Narraguinnep Reservoir is located about 80 km downwind from two of the largest power plants, which together emit about 950 kg-Hg/year. Magnetic minerals separated from reservoir sediment contained spherical magnetite-bearing particles characteristic of coal-fired electric power plant fly ash. The presence of fly-ash magnetite in post-1970 sediment from Narraguinnep Reservoir indicates that the likely source of Hg to the catchment basin for this reservoir has been from airborne emissions from power plants, most of which began operation in the late-1960s and early 1970s in this region.     

Application of precise 142Nd/144Nd analysis of small samples to inclusions in diamonds (Finsch,South Africa) and Hadean Zircons (Jack Hills,Western Australia)

¹⁴⁶Sm–¹⁴²Nd and ¹⁴⁷Sm–¹⁴³Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe ²⁰⁷Pb/²⁰⁶Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?¹⁴²Nd = ? 6 ± 12 ppm, ?¹⁴³Nd = ? 32.5, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.1150. These results do not confirm previous claims for a 30 ppm ¹⁴²Nd excess in South African cratonic mantle. The lack of a ¹⁴²Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?¹⁴²Nd = 8 ± 10 ppm, ?¹⁴³Nd = 45 ± 1, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.5891. Back-calculation of this present-day ?¹⁴³Nd yields an unrealistic estimate for the initial ?¹⁴³Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the ¹⁴⁷Sm–¹⁴³Nd system. Examination of ^146,147Sm–^142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of ¹⁴⁶Sm–¹⁴²Nd systematics in Jack Hills zircons.     

Origin of a barite-sulfide ore deposit in the Mykonos intrusion,cyclades: Trace element,isotopic, fluid inclusion and raman spectroscopy evidence

The polymetallic Mykonos vein system in the Cyclades, Greece, consists of 15 tension-gashes filled with barite, quartz, pyrite, sphalerite, chalcopyrite and galena in ca. 13.5 Ma, I-type, Mykonos monzogranite. Zones of silica and chlorite–muscovite alteration are associated with the veins and overprint pervasive silicification, phyllic and argillic alteration that affected large parts of the monzogranite. The mineralization cements breccias and consists of an early barite–silica–pyrite–sphalerite–chalcopyrite assemblage followed by later argentiferous galena. A combination of fluid inclusion and stable isotope data suggests that the barite and associated mineralization were deposited from fluids containing 2 to 17 wt.% NaCl equivalent, at temperatures of ~ 225° to 370 °C, under a hydrostatic pressure of ≤ 100 bars. The mineralizing fluids boiled and were saturated in H₂S and SO₂.Calculated δ¹⁸O_H2O and δD_H2O, initial ⁸⁷Sr/⁸⁶Sr isotope compositions and the trace and REEs elements contents are consistent with a model in which the mineralizing fluids were derived during alteration of the Mykonos intrusion and subsequently mixed with Miocene seawater. Heterogeneities in the calculated δ³⁴S_SO4^− 2 and δ³⁴S_H2S compositions of the ore fluids indicate two distinct sources for sulfur, namely of magmatic and seawater origin, and precipitation due to reduction of the SO₄^− 2 during fluid mixing. The physicochemical conditions of the fluids were pH = 5.0 to 6.2, logf_S2 = − 13.8 to − 12.5, logf_O2 = − 31.9 to − 30.9, logf_H2S(g) = − 1.9 to − 1.7, logf_Te2 = − 7.9 and logα(SO₄^− 2_(aq)/H₂S_(aq)) = + 2.6 to + 5.5. We propose that retrograde mesothermal hydrothermal alteration of the Mykonos monzogranite released barium and silica from the alkali feldspars. Barite was precipitated due to mixing of SO₄^− 2-rich Miocene seawater with the ascending Ba-rich magmatic fluid venting upwards in the pluton.     

Preliminary estimates of regolith generation and mobility in the Susquehanna Shale Hills Critical Zone Observatory,Pennsylvania, using meteoric 10Be

This study seeks to quantify the rate and timing of regolith generation in the Critical Zone at the Susquehanna Shale Hills Critical Zone Observatory (SSHO). Meteoric ¹⁰Be depth profiles were determined using measurements from 30 hillslope soil and bedrock core samples in an effort to constrain ¹⁰Be inventories. The SSHO is located in the temperate climate zone of central Pennsylvania and comprises a first-order watershed developed entirely on a Fe-rich, organic-poor, Silurian-aged shale. Two major perturbations to the landscape have occurred at SSHO in the geologically recent past, including significant and sustained periglacial activity until after the retreat of the Laurentide ice sheet (～21 ka) and deforestation during early colonial land-use. Bulk soil samples (n = 16) were collected at three locations along a planar hillslope on the southern ridge of the catchment, representing the ridge top, mid-slope and valley floor. Rock chip samples (n = 14) were also collected from a 24 m deep core drilled into the northern ridge top. All meteoric ¹⁰Be concentration profiles show a declining trend with depth, with most of the ¹⁰Be retained in the uppermost decimeters of the soil. Meteoric ¹⁰Be inventories are higher at the mid-slope and valley floor sample sites, at 3.71 ± 0.02 × 10¹⁰ at/cm² and 3.69 ± 0.02 × 10¹⁰ at/cm², than at the ridge top site (1.90 ± 0.01 × 10¹⁰ at/cm²). The ¹⁰Be inventory at the convex ridge top site implies a minimum residence time of ～10.6 ka, or if erosion is steady, an erosion rate of 19.4 ± 0.2 m/My.     

Differential timing of vertical-axis block rotations in the northern Ryukyu Arc: Paleomagnetic evidence from the Koshikijima Islands,Japan

Over 300 samples for paleomagnetic analysis and K–Ar dating were collected from 27 sites at NW–SE and NE–SW trending dike swarms (herein, NW dikes and NE dikes, respectively) in the Koshikijima Islands, northern Ryukyu Arc. The NW dikes are Middle Miocene in age and have directions (D = ? 37.7^°, I = 51.8^°, α₉₅ = 9.6^°, and κ = 40.8) that are deflected westward relative to the stable eastern Asian continent. Conversely, the NE dikes, of Late Miocene age, have directions (D = 16.1^°, I = 57.7^°, α₉₅ = 7.1^°, and κ = 41.9) that show no such deflection. These differences are interpreted as indicating that the Koshikijima Islands underwent approximately 40^° of counter-clockwise rotation during the Middle to Late Miocene. A synthesis of the paleomagnetic and structural data suggests a three-stage history of extensional deformation: (1) displacement upon normal faults (F₁ faults) without vertical-axis block rotation, (2) strike-slip reactivation of F₁ faults and oblique-normal displacement on NE–SW-trending faults (F₂ faults) with vertical-axis block rotation, and (3) oblique-normal displacement on F₂ faults without vertical-axis block rotation. Regional differences in the timing and amount of counter-clockwise vertical-axis block rotations indicate that the northern Ryukyu Arc rotated as several distinct rigid blocks.     

Shear wave attenuation characteristics over the Central India Tectonic Zone and its surroundings

The study area lies between latitude 18–26°N and longitude 73–83°E, and mainly covers the Central India Tectonic Zone (CITZ). The frequency-dependent shear wave quality factor (Q_s) has been estimated over the CITZ and its surroundings using Double Spectral Ratio (DSR) method. We have considered 25 local earthquakes with magnitude (M_L) varies from 3.0 to 4.7 recorded at 11 stations running under national seismic network. The Fast Fourier Transformed (FFT) spectra were computed from the recorded waveform having time-window from onset of S-phase to 1.0 s and for a frequency-band of 0.1–10 Hz. Three different shear wave velocities (i.e., 3.87, 3.39 and 3.96 km/s) were obtained over the study area based on a pair of earthquakes recorded at a pair of stations. The low Q_s values of 51–96 at 1 Hz (i.e., Q_s = 51f^0.49; Q_s = 90f^0.488 and Q_s = 96f^0.53) were found in the area covering the Son–Narmada–Tapti (SONATA) lineament, CITZ, eastern part of the Satpura fold belt, Vindhyan and Gondwana basins, Godavari and Mahanadi grabens, and southern part of Gangetic plain. Intermediate Q_s values of the order of 204–277 (i.e., Q_s = 204f^0.56 and Q_s = 277f^0.55) were noted in the cartonic areas, namely, Bundelkhand, Dharwar-Bhandara and Bastar. While the higher Q_s values of 391–628 at 1 Hz (i.e., Q_s = 391f^0.49, Q_s = 409f^0.48, Q_s = 417f^0.48, Q_s = 500f^0.66, Q_s = 585f^0.65 and Q_s = 628f^0.69) were found in the eastern part of the SONATA, CITZ, and the northeastern part of the Satpura fold belt. The low Q_s values might be attributing to the more heterogeneous SONATA rift system. Low Q_s values further may presumably be associated with lower-level of seismicity and apparently account for higher tectonic stress accumulation over long duration. The long-term accumulated stress is generally released through occasional triggering of moderate magnitude earthquakes in the SONATA zone. Surrounding the SONATA region, the higher Q_s values possibly accounts for a more homogeneous subsurface structure along the SONATA zone.     

Persistent sea surface temperature and declined sea surface salinity in the northwestern tropical Pacific over the past 7500 years

To understand Holocene climate evolutions in low-latitude region of the western Pacific, paired δ¹⁸O and Mg/Ca records of planktonic foraminifer Globigerinoides ruber (250–300 μm, sensu stricto, s.s.) from a marine core ORI715-21 (121.5°E, 22.7°N, water depth 760 m) underneath the Kuroshio Current (KC) off eastern Taiwan were analyzed. Over the past 7500 years, the geochemical proxy-inferred sea surface temperature (SST) hovered around 27–28 °C and seawater δ¹⁸O (δ¹⁸O_W) slowly decreased 0.2–0.4‰ for two KC sites at 22.7° and 25.3°N. Comparison with a published high-SST and high-salinity equatorial tropical Pacific record, MD98-2181 located at the Mindanao Current (MC) at 6.3°N, reveals an anomalous time interval at 3.5–1.5 kyr ago (before 1950 AD). SST gradient between the MC site and two KC site decrease from 1.5–2.0 °C to only 0–1 °C, and δ¹⁸O_W from 0.1–0.3‰ to 0‰ for this 2-kyr time window. The high SST and low gradient could result from a northward shift of the North Equatorial Current, which implies a weakened KC. The long-term descending δ¹⁸O_W and increasing precipitation in the entire low-latitude western Pacific and the gradually decreasing East Asian summer monsoonal rainfall during middle-to-late Holocene is likely caused by different land and ocean responses to solar insolation and/or enhanced moisture transportation from the Atlantic to Pacific associated with the southward movement of ITCZ.     

Kappa (k) derived from accelerograms recorded in the 2008 Wenchuan mainshock,Sichuan, China

High-frequency spectral decay factor, kappa (k), in the accelerograms of the Wenchuan mainshock was measured using strong motion data from 52 stations within 311 km of the epicenter. The derived k range from 0.0034 s to 0.0468 s. The correlation of k versus fault distance was given, which is k = 0.01288 + 5.9068 × 10^–5 R for the N-S component, k = 0.01881 + 1.4219 × 10^–5 R for the E-W component, and k = 0.00855 + 5.6086 × 10^–5 R for the U-D component. The analysis on the spatial variation of k demonstrates that k relates to source effect and propagation effect besides local site effect. Ground motions for the 52 stations were simulated using derived k and compared to actual recordings in terms of waveforms, amplitude spectra and response spectra. The results show agreement at shorter periods (<1 s), but a slight overestimation at longer periods (1–7 s).     

Petrogenesis and tectonic settings of the Late Carboniferous Jiamantieliek and Baogutu ore-bearing porphyry intrusions in the southern West Junggar,NW China

Porphyry Cu deposits occurred in the southern West Junggar of Xinjiang, NW China and are represented by the Baogutu and newly-discovered Jiamantieliek porphyry Cu deposits. Petrographical and geochemical studies show that both Jiamantieliek and Baogutu ore-bearing intrusions comprise main-stage diorite stock and minor late-stage diorite porphyry dikes and are the calc-alkaline intermediate intrusions. Based on U–Pb zircon SHRIMP analyses, the Jiamantieliek intrusion formed in 313 ± 4 Ma and 310 ± 5 Ma, while, based on U–Pb zircon SIMS analyses, the Baogutu intrusion formed in 313 ± 2 Ma and 312 ± 2 Ma. Rocks in the Jiamantieliek intrusion are enriched in light rare earth elements (LREE) and large ion lithophile elements (LILE) with negative Nb anomaly. Their isotopic compositions (ε_Nd(t) = +1.6 to +3.4, (⁸⁷Sr/⁸⁶Sr)_i = 0.70369–0.70401, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.31–5.41) suggest a mixing origin from depleted to enriched mantle sources. In the Baogutu intrusion, the rocks are similar to those of the Jiamantieliek intrusion. Their Sr-Nd-Pb isotopic composition (ε_Nd(t) = +4.4 to +6.0, (⁸⁷Sr/⁸⁶Sr)_i = 0.70368–0.70385, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.34–5.42) shows a more depleted mantle source. These features suggest generation in an island arc. The Jiamantieliek and Baogutu intrusions have similar characteristics, indicating that a relatively uniform and integrated source region has existed in the southern West Junggar since the Palaeozoic. A larger contribution of calc-alkaline magma would be required to generate the Jiamantieliek intrusion, which may reflect the development of magma arc maturation towards the western section of the southern West Junggar.     

An Apatite II permeable reactive barrier to remediate groundwater containing Zn,Pb and Cd

Phosphate-induced metal stabilization involving the reactive medium Apatite II™ [Ca_10−xNa_x(PO₄)_6−x(CO₃)_x(OH)₂], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO₄ and NO₃. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d’Alene River, Idaho. Microbially mediated SO₄ reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb₁₀(PO₄)₆(OH,Cl)₂] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L⁻¹), has reduced Zn to near background in this region (about 100 μg L⁻¹), and has reduced SO₄ by between 100 and 200 mg L⁻¹ and NO₃ to below detection (50 μg L⁻¹). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).     

Short-lived radioactive nuclides in meteorites and early solar system processes

Now extinct, short-lived radioactive nuclides, such as ⁷Be (T_1/2 = 53 days), ¹⁰Be (T_1/2 = 1.5 Ma), ²⁶Al (T_1/2 = 0.74 Ma), ³⁶Cl (T_1/2 = 0.3 Ma), ⁴¹Ca (T_1/2 = 0.1 Ma), ⁵³Mn (T_1/2 = 3.7 Ma) and ⁶⁰Fe (T_1/2 = 1.5 Ma), were present in the protosolar nebula when the various components of meteorites formed. The presence of these radioactive isotopes requires a ‘last-minute’ origin, either nucleosynthesis in a massive star dying close in space and time to the nascent solar system or production by local irradiation of part of the protosolar disk by high-energy solar cosmic rays. In this review, we list: (i) the different observations indicating the existence of multiple origins for short-lived radioactive nuclides, namely ⁷Be, ¹⁰Be and ³⁶Cl for irradiation scenario and ⁶⁰Fe for injection scenario; (ii) the constraints that exist on their distribution (homogeneous or heterogeneous) in the accretion disk; (iii) the constraints they brought on the timescales of nebular processes (from Ca–Al-rich inclusions to chondrules) and of the accretion and differentiation of planetesimals.     

Hydro-geochemical and isotopic fluid evolution of the Los Azufres geothermal field,Central Mexico

Hydrothermal alteration at Los Azufres geothermal field is mostly propylitic with a progressive dehydration with depth and temperature increase. Argillic and advanced argillic zones overlie the propylitic zone owing to the activity of gases in the system. The deepest fluid inclusions (proto-fluid) are liquid-rich with low salinity, with NaCl dominant fluid type and ice melting temperatures (T_mi) near zero (0 °C), and salinities of 0.8 wt% NaCl equivalent. The homogenization temperature (T_h)  = 325 ± 5 °C. The boiling zone shows T_h = ±300 °C and apparent salinities between 1 and 4.9 wt% NaCl equivalent, implying a vaporization process and a very important participation of non-condensable gases (NCGs), mostly CO₂. Positive clathrate melting temperatures (fusion) with T_h = 150 °C are observed in the upper part of the geothermal reservoir (from 0 to 700 m depth). These could well be the evidence of a high gas concentration. The current water produced at the geothermal wells is NaCl rich (geothermal brine) and is fully equilibrated with the host rock at temperatures between T = 300 and 340 °C. The hot spring waters are acid-sulfate, indicating that they are derived from meteoric water heated by geothermal steam. The NCGs related to the steam dominant zone are composed mostly of CO₂ (80–98% of all the gases). The gases represent between 2 and 9 wt% of the total mass of the fluid of the reservoir.The authors interpret the evolution of this system as deep liquid water boiling when ascending through fractures connected to the surface. Boiling is caused by a drop of pressure, which favors an increase in the steam phase within the brine ascending towards the surface. During this ascent, the fluid becomes steam-dominant in the shallowest zone, and mixes with meteoric water in perched aquifers. Stable isotope compositions (δ¹⁸O–δD) of the geothermal brine indicate mixing between meteoric water and a minor magmatic component. The enrichment in δ¹⁸O is due to the rock–water interaction at relatively high temperatures. δ¹³C stable isotope data show a magmatic source with a minor meteoric contribution for CO₂. The initial isotopic value δ³⁴S_RES = −2.3‰, which implies a magmatic source. More negative values are observed for shallow pyrite and range from δ³⁴S (FeS₂) = −4‰ to −4.9‰, indicating boiling. The same fractionation tendencies are observed for fluids in the reservoir from results for δ¹⁸O.     

Three-dimensional stability analysis of a longitudinally inclined shallow tunnel face

The tunnel inclination angle (δ) generally exists in urban and cross-river (sea) tunnels; hence, its effect should be considered in the stability analysis of a tunnel face. However, the influence of this tunnel inclination angle is rarely studied. In this paper, considering the effects of the tunnel inclination angle and the tunneling length (L), the optimal upper-bound solutions of the active and passive failure pressures were obtained using sequential quadratic programming (SQP) based on the upper-bound limit analysis. The effects of the dimensionless parameters on the pressures and failure modes were investigated. The results show that the tunnel inclination angle δ and the dimensionless parameter L/D (D is the section diameter of the tunnel) significantly affect active and passive stabilities. The difference in the results between δ = −10° and δ = 10° is mostly greater than 10% and reaches 80% when the internal friction angle (φ) is large. When the value of δ is zero, L/D does not affect on the result. The maximum difference in the results between L/D = 0 and L/D = 5 are 92.5% (passive failure) and 36.3% (active failure). For the active failure mode, with increasing of φ, the curves, which have δ values of −10°, 0° and 10°, intersect at a particular point when φ reaches a specific value.     

Boron content of Lake Ulubat sediment: A key to interpret the morphological history of NW Anatolia,Turkey

Freshwater Lake Ulubat (c. 1.5 m deep and c. 138 km²) receives sediment from a 10.414 km² area in the seismically active Susurluk Drainage Basin (SDB) of NW Turkey. The B and trace element contents of the lake infill seem to be a link between the fresh landforms of the SDB and the lacustrine sediment. Deposition in Lake Ulubat has been 1.60 cm a⁻¹ for the last 50 a according to radionucleides; however the sedimentation rate over the last millennium was 0.37 cm a⁻¹ based on ¹⁴C dating. The B content of the lacustrine infill displays a slight increase at 0.50 m and a drastic increase at 4 m depth occurring c. 31 a and c. 1070 a ago, respectively. Probably the topmost change corresponds to the start of open mining in the SDB and the second one to the natural trenching of borate ore-deposits. These dates also show indirectly a 1.4 cm a⁻¹ erosion rate during the last millennium as the borate beds were trenched up to 15 m. By extrapolation, it is possible to establish that the formation of some of the present morphological features of the southern Marmara region, especially river incision, began in the late Pleistocene, and developed especially over the last 75 ka.     

An Apatite II permeable reactive barrier to remediate groundwater containing Zn,Pb and Cd

Phosphate-induced metal stabilization involving the reactive medium Apatite II™ [Ca_10−xNa_x(PO₄)_6−x(CO₃)_x(OH)₂], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO₄ and NO₃. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d’Alene River, Idaho. Microbially mediated SO₄ reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb₁₀(PO₄)₆(OH,Cl)₂] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L⁻¹), has reduced Zn to near background in this region (about 100 μg L⁻¹), and has reduced SO₄ by between 100 and 200 mg L⁻¹ and NO₃ to below detection (50 μg L⁻¹). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).