Palaeoecology and biostratigraphy of early Cretaceous (Aptian) calcareous nannofossils and the δCcarb isotope record from NE Iran

Upper Barremian-Lower Aptian sediments of the Sarcheshmeh and Sanganeh formations in the Kopet Dagh area, northeast Iran were studied with regard to their calcareous nannofossil content and their δ¹³C_carb signal. The sediments are composed mainly of marlstones, argillaceous limestones and limestones. Based on the occurrence of biostratigraphic index taxa, the calcareous nannofossil zones NC5, NC6 and the NC7A Subzone were recognised. The calcareous nannofossils and the δ¹³C_carb data enable recognition of the early Aptian Oceanic Anoxic Event 1a (OAE 1a). The deposits of the OAE 1a interval are characterised by the rarity of nannoconids and a sharp negative δ¹³C_carb excursion (1.36‰), followed by an abrupt positive δ¹³C_carb excursion of 4-5‰; both events have been recognised elsewhere in OAE 1a deposits in the Tethys. In the OAE 1a interval, the relative abundance of Watznaueria barnesiae/Watznaueria fossacincta is higher (more than 40%) than that of Biscutum spp., Discorhabdus spp. and Zeugrhabdotus spp., which indicates dissolution. In the upper part of the section, the higher relative abundance of mesotrophic and oligotrophic taxa (Watznaueria spp. and nannoconids respectively) and the enhanced relative abundance of eutrophic taxa (Biscutum spp., Discorhabdus spp., Zeugrhabdotus spp.) is indicative of an environment with slightly increased nutrient content. The presence of warm water taxa (Rhagodiscus asper and nannoconids) and the absence of cool water taxa (Repagulum and Crucibiscutum) suggest warm surface-water conditions.     

Deciphering late Quaternary land snail shell δO and δC from Franchthi Cave (Argolid,Greece)

This paper investigates the stable isotopic composition from late Pleistocene–Holocene (~ 13 to ~ 10.5 cal ka BP) shells of the land snail Helix figulina, from Franchthi Cave (Greece). It explores the palaeoclimatic and palaeoenvironmental implications of the isotope palaeoecology of archaeological shells at the time of human occupation of the cave. Modern shells from around the cave were also analysed and their isotopic signatures compared with those of the archaeological shells. The carbon isotope composition of modern shells depicts the consumption of C₃ vegetation. Shell oxygen isotopic values are consistent with other Mediterranean snail shells from coastal areas. Combining empirical linear regression and an evaporative model, the δ¹⁸Os suggest that modern snails in the study area are active during periods of higher relative humidity and lower rainfall δ¹⁸O, probably at night. Late glacial and early Holocene δ¹⁸Os show lower values compared to modern ones. Early Holocene δ¹⁸Os values likely track enhanced moisture and isotopic changes in the precipitation source. By contrast, lower late glacial δ¹⁸O could reflect lower temperatures and δ¹⁸Op, compared to the present day. Shell carbon isotope values indicate the presence of C₃ vegetation as main source of carbon to late glacial and early Holocene snails.     

The δ18O and δ13C records in an aragonite stalagmite from Furong Cave,Chongqing, China: A-2000-year record of monsoonal climate

A 7-cm long aragonite stalagmite, FR0510-1, from Furong Cave, Chongqing, was dated by ²¹⁰Pb and ²³⁰Th methods, revealing a-2000-year record of climate history under the influence of the East Asian Monsoon. The FR0510-1 record resembles Dongge Cave DA record on 10–100-year scales, but quite different from the Wanxiang Cave WX42B record, indicating that while stalagmite δ¹⁸O record represents local/regional moisture change, spatial variability of the monsoonal rainfall over eastern China must take into account. During the past 2000 years, climate in Chongqing was relatively wet in the intervals of 50 BC–AD 250, AD 1150–1450 and AD 1600–1950, and relatively dry during the periods of AD 250–1150 and AD 1450–1600. Dry conditions were prevailing over the Medieval Warm Period, whereas wet climates were dominant during the most time of the Little Ice Age in Chongqing area.     

Stratigraphic updating and correlation of Late Barremian–Early Aptian Urgonian successions and their marly cover,in their type region (Orgon-Apt,SE France)

Comparing the stratigraphy of the rudist bearing limestones of Orgon (the type locality for the Urgonian stage of d'Orbigny) with that of the Urgonian limestones of the Monts de Vaucluse-Apt region, where the stratotype of the Aptian sensu d'Orbigny is located, shows that the corresponding platform carbonates have distinctive ages, late Barremian (Gehrartia sartousiana zone), and Bedoulian (Deshayesites oglanlensis to the middle part of the Deshayesites deshayesi zone) respectively. Nevertheless the Upper Barremian Orgon limestones are still present in the western part of the Monts de Vaucluse where they are capped by a Palorbitolina lenticularis–Heteraster oblongus (Pa1) guide level, ascribed to the Imerites giraudi zone. The overlying rudist beds are characterized by the presence of Caprinidae (Offneria-Pachytraga-Praecaprina assemblage), and spread over the Monts de Vaucluse-Apt region; they also extend to the Mont Ventoux, and to the eastern Languedoc too. These latter beds, assigned to the early Bedoulian, i.e. the D. oglanlensis–D. weissi zones, are interrupted by a drowning discontinuity capped by Palorbitolina beds (Pa2) overlain by bioclastic or coral limestones of early late Bedoulian age (lower part of the D. deshayesi zone). The succeeding marly cover, including marly limestones and the lowermost part of the “Gargas marls”, which marks the regional demise of shallow carbonates, is ascribed to the late Bedoulian (Deshayesites grandis subzone and Dufrenoyia furcata zone) and represents the lowermost part of the “Aptian” sensu d'Orbigny.     

Isotopic Composition (δ13C, δ18O) and Origin of Manganese Carbonate Ores of the Usa Deposit (Kuznetskii Alatau)

Isotopic compositions of carbon and oxygen are studied in different (rhodochrosite, calcareous-rhodochrosite, and chlorite–rhodochrosite) types of manganese carbonate ores from the Usa deposit (Kuznetskii Alatau). The ¹³C value varies from –18.4 to –0.7, while the ¹⁸O value ranges between 18.4 and 23.0. Host rocks are characterized by higher values of ¹³C (–1.9 to 1.0) and ¹⁸O (21.2 to 24.3). The obtained isotope data suggest an active participation of oxidized organic carbon in the formation of manganese carbonates. Manganese carbonate ores of the deposit are probably related to metasomatic processes.     

Palaeomonsoon and palaeoproductivity records of δ18O, δ{13}C and CaCO3 variations in the northern Indian Ocean sedimentsC and CaCO3 variations in the northern Indian Ocean sediments

δ¹⁸ O and δ¹³C of G.sacculifer have been measured in five cores from the northern Indian Ocean. In addition, high resolution analysis (1 to 2 cm) was performed on one core (SK-20-185) for both δ¹⁸O and gd¹³C in five species of planktonic foraminifera. CaCO₃ variation was measured in two cores. The results, presented here, show that

Tree-ring growth recovers,but δ13C and δ15N do not change,after the removal of point-source air pollution: a case study for poplar (Populus cathayana) in northwestern China

Pollution from urban centers and fossil fuel combustion can decrease forest growth and interfere with physiological processes. To evaluate whether tree growth and the carbon isotope ratio (δ¹³C) and nitrogen isotope ratio (δ¹⁵N) in tree rings can serve as proxies for air pollution, this study compared these indices for poplar (Populus cathayana) growing at urban and suburban locations in Lanzhou, in northwestern China. Basal area increment values were much lower at the urban site than in the suburbs from 1985 to 2009, were negatively correlated with NO₂ (r = ?0.56, p < 0.01) and SO₂ (r = ?0.52, p < 0.05) emissions from 1990 to 2009, and increased abruptly after the Lanzhou urban steel factory closed. Urban tree-ring δ¹³C values were not significantly correlated with NO₂ and SO₂ concentrations, and did not differ significantly between the two sites, indicating that other environmental effects (such as precipitation) masked the pollution effects. Tree-ring δ¹⁵N values in the urban samples were much higher than the suburban values. Such differences may be attributable to uptake of ¹⁵N-enriched compounds caused by a higher urban N deposition rate. Tree growth is a promising tool for detecting ecophysiological responses of trees to both diffuse and point-source air pollution, but δ¹³C and δ¹⁵N in poplar were not sensitive to point-source air pollution in a heavily polluted environment.     

Relative sea-level change, climate, and sequence boundaries: insights from the Kimmeridgian to Berriasian platform carbonates of Mount Salève (E France)

The present study analyses the stratal architecture of the Late Jurassic (Kimmeridgian) to Early Cretaceous (Berriasian) sedimentary succession of Mount Salève (E France), and four Berriasian stratigraphic intervals containing four sequence-boundary zones reflecting lowering trends of the relative sea-level evolution. Massive Kimmeridgian limestones characterized by the presence of colonial corals appear to be stacked in an aggrading pattern. These non-bedded thick deposits, which are interpreted to have formed in balance between relative sea-level rise and carbonate accumulation, suggest a keep-up transgressive system. Above, well-bedded Tithonian-to-Berriasian peritidal carbonates reflect a general loss of accommodation. These strata are interpreted as a highstand normal-regressive unit. During the early phase of this major normal regression, the vertical repetition of upper intertidal/lower supratidal lithofacies indicates an aggrading depositional system. This is in agreement with an early stage of a highstand phase of relative sea level. The Berriasian sequence-boundary zones investigated (up to 4 m thick) developed under different climatic conditions and correspond to higher-frequency, forced- and normal-regressive stages of relative sea-level changes. According to the classical sequence-stratigraphic principles, these sequence-boundary zones comprise more than one candidate surface for a sequence boundary. Three sequence-boundary zones studied in Early Berriasian rocks lack coarse siliciclastic grains, contain a calcrete crust, as well as marly levels with higher abundances of illite with respect to kaolinite, and exhibit fossilized algal-microbial laminites with desiccation polygons. These sedimentary features are consistent with more arid conditions. A sequence-boundary zone interpreted for the Late Berriasian corresponds to a coal horizon. The strata above and below this coal contain abundant quartz and marly intervals with a higher kaolinite content when compared to the illite content. Accordingly, this Late Berriasian sequence-boundary zone was formed under a more humid climate. The major transgressive–regressive cycle of relative sea level identified and the climate change from more arid to more humid conditions recognized during the Late Berriasian have been reported also from other European basins. Therefore, the Kimmeridgian to Berriasian carbonate succession of Mount Salève reflects major oceanographic and climatic changes affecting the northern margin of the Alpine Tethys ocean and thus constitutes a reliable comparative example for the analysis of other coeval sedimentary records. In addition, the stratigraphic intervals including sequence-boundary zones characterized in this study constitute potential outcrop analogues for sequence-boundary reflectors mapped on seismic profiles of subsurface peritidal carbonate successions. The detailed sedimentological analyses provided here highlight that on occasions the classical principles of sequence stratigraphy developed on seismic data are difficult to apply in outcrop. A sequence-boundary reflector when seen in outcrop may present successive subaerial exposure surfaces, which formed due to high-frequency sea-level changes that were superimposed on the longer-term trend of relative sea-level fall.     

Carbonate microfacies and chemostratigraphy of a late Aptian–early Albian marine distal section from the primitive South Atlantic (SE Brazilian continental margin): Record of global ocean-climate changes?

Late Aptian–early Albian limestones from the eastern Brazilian continental margin record the early evolution of the South Atlantic Ocean. In Tethyan and North Atlantic domains, a planktic foraminiferal turnover and organic-rich deposits related to Oceanic Anoxic Event 1b (OAE 1b) point to major ocean-climate changes through this interval. Coeval organic-rich deposits of the South Atlantic Ocean have been interpreted as the product of restricted circulation rather than attributed to a global event. However, previous investigations of the early marine phase of South Atlantic lack data from more distal facies, making correlations to global events difficult. Here, we present C, O, and Sr isotopes, elemental geochemistry, TOC and pyrolysis data, as well as a microfacies analysis of an upper Aptian–lower Albian distal section from the Campos Basin (southeastern Brazil). Our focus is on the paleoenvironmental characterization of and the possible association between organic-rich deposits and major perturbations related to Aptian–Albian transition. Five microfacies associations (MA) were identified in the informal units I and III, which were deposited in the neritic region on a carbonate ramp. Organic-rich deposits were described in unit III, composed of planktic-dominated wackestones interbedded with black shales, in a distal dysoxic to anoxic environment. The carbonates ⁸⁷Sr/⁸⁶Sr ratios showed a drastic increase (0.7072–0.7074), interpreted as enhanced chemical weathering, supported by the increase of continental input to the top of section. This trend was accompanied by a long-term δ¹³C_carb negative excursion, which were assigned to the latest late Aptian–early Albian interval of the isotope reference curves, in accordance with the described occurrence of Colomiella recta. This scenario matches those proposed for the late Aptian–early Albian transition and OAE 1b set, as an enhanced greenhouse stage, pointing to the influence of the referred ocean-climate changes on the deposition of organic-rich deposits of the early South Atlantic Ocean. This investigation gives more evidences that these perturbations were a widespread event, as a product of broad-scale disturbances in the global carbon cycle which also controlled organic deposition and preservation on restricted settings.     

Chemistry,isotope values (δD, δ18O, δ34SSO4) and temperatures of the water inflows in two Gotthard tunnels,Swiss Alps

Water inflows in the Gotthard Highway Tunnel and in the Gotthard Exploration Tunnel are meteoric waters infiltrating at different elevations, on both sides of an important orographic divide. Limited interaction of meteoric waters with gneissic rocks produces Ca–HCO₃ and Na–Ca–HCO₃ waters, whereas prolonged interaction of meteoric waters with the same rocks generates Na–HCO₃ to Na–SO₄ waters. Waters circulating in Triassic carbonate-evaporite rocks have a Ca–SO₄ composition. Calcium-Na–SO₄ waters are also present. They can be produced through interaction of either Na–HCO₃ waters with anhydrite or Ca–SO₄ waters with a local gneissic rock, as suggested by reaction path modeling. An analogous simulation indicates that Na–HCO₃ waters are generated through interaction of Ca–HCO₃ waters with a local gneissic rock. The two main SO₄-sources present in the Alps are leaching of upper Triassic sulfate minerals and oxidative dissolution of sulfide minerals of crystalline rocks. Values of δ³⁴S_SO4 < ∼+9‰ are due to oxidative dissolution of sulfide minerals, whereas δ³⁴S_SO4 >∼+9‰ are controlled either by bacterial SO₄ reduction or leaching of upper Triassic sulfate minerals. Most waters have temperatures similar to the expected values for a geothermal gradient of 22°C/km and are close to thermal equilibrium with rocks. However relatively large, descending flows of cold waters and ascending flows of warm waters are present in both tunnels and determine substantial cooling and heating, respectively, of the interacting rocks. The most import upflow zone of warm, Na-rich waters is below Guspisbach, in the Gotthard Highway Tunnel, at 6.2–9.0 km from the southern portal. These warm waters have equilibrium temperatures of 65–75°C and therefore constitute an important low-enthalpy geothermal resource.     

Isotopic Composition (δ13C and δ18O) and Genesis of Mn-bearing Sediments in the Ushkatyn-III Deposit,Central Kazakhstan

Lithology and Mineral Resources - The Ushkatyn-III deposit is located 300 km west of Karaganda (Central Kazakhstan). It is classified as a weakly metamorphosed Atasu-type hydrothermal-sedimentary...     

Isotopic Composition (δ13C, δ18O) and Genesis of Carbonates from Phosphorite Deposits in the Lesser Karatau (Kazakhstan)

Lithology and Mineral Resources - The study of structural features along with carbon and oxygen isotope compositions made it possible to discriminate lithological rocks in deposits of the Karatau...     

Stable isotope(δ~(13)C_(ker),δ~(13)C_(carb),δ~(18)O_(carb)) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance

This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin,NW China.The total organic carbon abundance,hydrocarbon-generating precursor biospecies,and stable isotope ratios of organics and carbonate(δ~(13)C_(ker),δ~(13)C_(carb) and δ~(18)O_(carb)) were comprehensively studied for their possible correlative constraints during sedimentary evolution.The results revealed that the δ~(13)C_(ker)(VPDB) of Cambrian kerogens along the outcrop section varied from-34.6‰ to-28.4‰,indicating an increasing tendency from the lower Cambrian to the upper Cambrian.This was on the whole accompanied by the variation in the δ~(13)C_(carb) and δ~(18)O_(carb) along the profile,which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass.The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin.Hence,the ~(13)C-enriched crude oils from well TD2∈might have been derived from a localized stratum of Cambrian source rocks.The results from this study showed the possibility of multiple source kitchens in the Cambrian-lower Ordovician portion of Tarim Basin.     

Sr chemostratigrphy, δ<Superscript>13</Superscript>C,and δ<Superscript>18</Superscript>O of rocks in the Crimean carbonate platform (Late Jurassic,northern Peri-Tethys)

The paper presents the results of study of the Sr, C, and O isotope compositions in Upper Jurassic carbonate rocks of the Baidar Valley and Demerdzhi Plateau in the Crimean Mountains represented by different facies of the carbonate platform at the northern active margin of the Tethys. The ⁸⁷Sr/⁸⁶Sr value in them varies from 0.70699 to 0.70728. Based on the Sr chemostratigraphic correlation, the age of massive and layered limestones in the western part of the Ai-Petri and Baidar yailas (pastures) is estimated as late Kimmeridgian–early Tithonian, whereas the age of flyschoids of the Baidar Valley are estimated as late Tithonian–early Berriasian. The nearly synchronous formation of carbonate breccias of the Baidar Valley and Demerdzhi Plateau in late Tithonian–early Berriasian is substantiated. A summary section of Upper Jurassic rocks is compiled based on the Sr chemostratigraphic data. It has been established that δ¹⁸O values in the studied carbonate sediments vary from–2.9 to 1.3‰ (V-PDB). At the same time, shallow-water sediments in the internal part and the edge of the Crimean carbonate platform are depleted in ¹⁸O (–2.9 to +0.1‰) relative to sediments on the slope and foothill (–0.5 to +1.3‰). It is demonstrated that δ¹³C values do not depend on the facies properties and decrease in younger carbonate sediments from 3–3.5‰ to 1–1.5‰ in line with the Late Jurassic general trend. The δ¹³C values obtained for the Crimean carbonate platform turned out to be 0.5–1‰ higher than the values typical of the deep-water marine setting at the western margin of the Tethys. These discrepancies are likely related to peculiarities of water circulation and high bioproductivity in marine waters of the northern Peri-Tethys.     

Isotopic Composition (δ<Superscript>13</Superscript>C, δ<Superscript>18</Superscript>O) and the Origin of Carbonates from Manganese Deposits of the Southern Urals

Isotopic compositions of carbon (δ¹³C from −51.4 to −10.8 PDB) and oxygen (δ¹⁸O from 14.4 to 21.4 SMOW) were studied in rhodochrosite and calcite from manganese ores in the South Faizuly and Kyzyltash deposits of the southern Urals. The geological, petrographic, and isotopic data indicate that the studied carbonates are diagenetic formations. It is suggested that the main ore element (Mn) was delivered to the marine basin with hydrothermal solutions percolating in the oceanic crust. Manganese precipitated on the oceanic bottom as oxides near solution discharge zones. Manganese carbonates formed in sediments as a result of the oxidation of organic matter by manganese oxides. High biological productivity of the environment was caused by proximity to the hydrothermal vent that provided favorable biogeochemical conditions for the development of biocoenosis. Anomalously low ¹³C values in the South Faizuly deposit testify to the large-scale oxidation of methane in the course of manganese carbonate formation.__________Translated from Litologiya i Poleznye Iskopaemye, No. 4, 2005, pp. 416–429.Original Russian Text Copyright © 2005 by Kuleshov, Brusnitsyn.     

Central Paratethys paleoenvironment during the Badenian (Middle Miocene): evidence from foraminifera and stable isotope (δ<Superscript>13</Superscript>C and δ<Superscript>18</Superscript>O) study in the Vienna Basin (Slovakia)

Stable isotope data of the foraminiferal carbonate shells and bulk sediment samples from the Central Paratethys were investigated to contribute to better knowledge of the paleoenvironmental changes in Badenian (Middle Miocene). Five benthic (Uvigerina semiornata, U. aculeata, Ammonia beccarii, Elphidium sp. and Heterolepa dutemplei) and three planktonic taxa (Globigerina bulloides, G. diplostoma and Globigerinoides trilobus), characterising the bottom, intermediate and superficial layers of the water column, were selected from the Vienna Basin (W Slovakia). The foraminiferal fauna and its isotope signal point out to temperature-stratified, nutrient-rich and consequently less-oxygenated marine water during the Middle/Late Badenian. Negative carbon isotope ratios indicate increased input of ¹²C-enriched organic matter to the bottom of the Vienna Basin. Positive benthic δ¹⁸O implies that the global cooling tendency recorded in the Middle Miocene has also affected the intramountain Vienna Basin. In this time, the Central Paratethys has been in the process of isolation. Our stable isotope trend suggests that the communication with Mediterranean Sea has been still more or less active on the south of Vienna Basin (Slovak part) in the Late Badenian, whereas the seawater exchange towards north was apparently reduced already during the Middle Badenian.     

Geochemistry of isotopes (δ<Superscript>13</Superscript>C, δ<Superscript>18</Superscript>O) and formation conditions of lower-middle permian rocks in the Soyana River region (Arkhangel’sk district)

The results of study of the isotopic-lithological compositions of carbonate and terrigenous-carbonate rocks in the Soyana River section (northern East European Platform, Arkhangel’sk district) are presented. The results make it possible to identify 10 main lithotypes and show a wide variation range of δ¹³C (from −2.2 to +3.6‰, PDB) and δ¹⁸O (from 22.5 to 30.5‰, SMOW). These lithological features and isotopic compositions suggest that the rocks were formed in a shallow-marine setting characterized by rapidly changing sedimentation conditions in various facies (and/or paleoecological) zones: inlets, lagoons, supralittoral, littoral, and shoals. Periods of aridization and humidization are recorded. The results also indicate numerous synsedimentary short-term hiatuses and stages of increased continental runoff—episodic pulsatory input of clastic material with the continental paleoflows.     

Geochemistry of isotopes (δ<Superscript>13</Superscript>C and δ<Superscript>18</Superscript>O) and depositional environment of the upper Kazanian carbonate sediments in the Volga-Vyatka interfluve

This work reports the results of lithological and isotopic study of carbonate rocks from the Pechishchi stratotype section (Kazan) and three adjacent sections of Kazanian rocks of the Volga-Vyatka region at the eastern Russian Platform. These sections were recovered by the Kremeshki, Popovtsevo, and Chimbulat quarries (near the town of Sovetsk, southeastern Kirov district). Lithological features and wide variations of δ¹³C (from −6.0 to 6.8‰) and δ¹⁸ O (from 22.9 to 33.4 ‰) indicate that the rocks were formed in a shallow-marine basin with rapidly varying conditions of sedimentation which characterize different facies (and/or paleoecological) zones: lagoonal, supralittoral, littoral, shoal. They also suggest processes of postsedimentary alteration (mainly, under supergene conditions). Numerous short-term hiatuses are also recorded.