Sea-level changes and shelf break prograding sequences during the last 400 ka in the Aegean margins: Subsidence rates and palaeogeographic implications

The subsidence rates of the Aegean margins during the Middle-Upper Pleistocene were evaluated based on new and historical seismic profiling data. High-resolution seismic profiling (AirGun, Sparker and 3.5 kHz) have shown that (at least) four major oblique prograding sequences can be traced below the Aegean marginal slopes at increasing subbottom depths. These palaeo-shelf break glacial delta sediments have been developed during successive low sea-level stands (LST prograding sequences), suggesting continuous and gradual subsidence of the Aegean margins during the last 400 ka. Subsidence rates of the Aegean margins were calculated from the vertical displacement of successive topset-to-foreset transitions (palaeo-shelf break) of the LST prograding sediment sequences.The estimated subsidence rates that were calculated in the active boundaries of the Aegean microplate (North Aegean margins, Gulfs of Patras and Corinth) are high and range from 0.7 to 1.88 m ka^?1, while the lowest values (0.34–0.60 m ka^?1) are related to the low tectonic and seismic activity margins like the margin of Cyclades plateau. Lower subsidence rates (0.34–0.90 m ka^?1) were estimated for the period 146–18 ka BP (oxygen isotopic stages 6–2) and higher (1.46–1.88 m ka^?1) for the period from 425 to 250 ka BP (oxygen isotopic stages 12/10–8). A decrease of about 50% of the subduction rates in the Aegean margins was observed during the last 400 ka.During the isotopic stages 8, 10, 11 and 12, almost the 50–60% of the present Aegean Sea was land with extensive drainage systems and delta plains and large lakes in the central and North Aegean. Marine transgression in the North Aegean was rather occurred during the isotopic 9 interglacial period. The estimated palaeomorphology should imply fan delta development and sediment failures in the steep escarpments of the North Aegean margins and high sedimentation rates and turbidite sediment accumulation in the basins. It is deduced that the Black Sea was isolated from the Mediterranean during the Pleistocene prior oxygen isotopic stage 5.     

Partial pressure and air–sea CO2 flux in the Aegean Sea during February 2006

Data on the distribution of fCO₂ were obtained during a cruise in the Aegean Sea during February 2006. The fCO₂ of surface water (fCO₂^sw) was lower than the atmospheric fCO₂ (fCO₂^atm) throughout the area surveyed and ΔfCO₂ values varied from ?34 to ?61 μatm. The observed under-saturation suggests that surface waters in the Aegean represent a sink for atmospheric CO₂ during the winter of 2006. Higher fCO₂^sw values were recorded in the ‘less warm’ and ‘less saline’ shallow northernmost part of the Aegean Sea implying that the lower seawater temperature and salinity in this area play a crucial role in the spatial distribution of fCO₂^sw.A first estimate of the magnitude of the air–sea CO₂ exchange and the potential role of the Aegean Sea in the transfer of atmospheric CO₂ was also obtained. The air–sea CO₂ fluxes calculated using different gas transfer formulations showed that during February 2006, the Aegean Sea absorbs atmospheric CO₂ at a rate ranging from ?6.2 to ?11.8 mmol m^?2 d^?1 with the shipboard recorded wind speeds and at almost half rate (?3.5 to ?5.5 mmol m^?2 d^?1) with the monthly mean model-derived wind speed. Compared to recent observations from other temperate continental shelves during winter period, the Aegean Sea acts as a moderate to rather strong sink for atmospheric CO₂.Further investigations, including intensive spatial and temporal high-resolution observations, are necessary to elucidate the role of the Aegean Sea in the process of transfer of atmospheric CO₂ into the deep horizons of the Eastern Mediterranean.     

Time-Domain Moment Tensors for shallow (h ≤ 40 km) earthquakes in the broader Aegean Sea for the years 2006 and 2007: The database of the Aristotle University of Thessaloniki

We present a catalog of moment tensor (MT) solutions and moment magnitudes, M_w, for 119 shallow (h ≤ 40 km) earthquakes in Greece and its surrounding lands (34°N–42°N, 19°E–30°E) for the years 2006 and 2007, computed with the 1D Time-Domain Moment Tensor inversion method (TDMT_INV code of Dreger, 2003). Magnitudes range from 3.2 ≤ M_w ≤ 5.7. Green's functions (GF) have been pre-computed to build a library, for a number of velocity profiles applicable to the broader Aegean Sea region, to be used in the inversion of observed broad band waveforms (10–50 s). All MT solutions are the outcome of a long series of tests of different reported source locations and hypocenter depths. Quality factors have been assigned to each MT solution based on the number of stations used in the inversion and the goodness of fit between observed and synthetic waveforms. In general, the focal mechanisms are compatible with previous knowledge on the seismotectonics of the Aegean area. The new data provide evidence for strike-slip faulting along NW–SE trending structures at the lower part of Axios basin, close to the heavily industrialized, and presently subsiding, region of the city of Thessaloniki. Normal faulting along E–W trending planes is observed at the Strimon basin, and in Orfanou Gulf in northern Greece. A sequence of events in the east Aegean Sea close to the coastline with western Anatolia sheds light on an active structure bounding the north coastline of Psara–Chios Islands about 20–25 km in length exhibiting right lateral strike-slip faulting.     

137Cs baseline levels in the Mediterranean and Black Sea: A cross-basin survey of the CIESM Mediterranean Mussel Watch programme

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify ¹³⁷Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured ¹³⁷Cs levels were found to be very low (usually <1 Bq kg⁻¹ wet wt) ¹³⁷Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.     

Quantification of seep-related methane gas emissions at Tommeliten,North Sea

Tommeliten is a prominent methane seep area in the Central North Sea. Previous surveys revealed shallow gas-bearing sediments and methane gas ebullition into the water column. In this study, the in situ methane flux at Tommeliten is re-assessed and the potential methane transport to the atmosphere is discussed, with regards to the hydrographic setting and gas bubble modeling. We have compiled previous data, acquired new video and acoustic evidence of gas bubble release, and have measured the methane concentration, and its C-isotopic composition in the water column. Parametric subbottom sonar data reveal the three-dimensional extent of shallow gas and morphologic features relevant for gas migration. Five methane ebullition areas are identified and the main seepage area appears to be 21 times larger than previously estimated. Our video, hydroacoustic, subbottom, and chemical data suggest that ～1.5×10⁶ mol CH₄/yr (～26 tons CH₄/yr) of methane gas is being released from the seepage area of Tommeliten. Methane concentration profiles in the vicinity of the gas seeps show values of up to 268 nM (～100 times background) close to the seafloor. A decrease in δ¹³C-CH₄ values at 40 m water depth indicates an unknown additional biogenic methane source within the well oxygenated thermocline between 30 and 40 m water depth. Numerical modeling of the methane bubbles due to their migration and dissolution was performed to estimate the bubble-derived vertical methane transport, the fate of this methane in the water column, and finally the flux to the atmosphere. Modeling indicates that less than ～4% of the gas initially released at the seafloor is transported via bubbles into the mixed layer and, ultimately, to the atmosphere. However, because of the strong seasonality of mixing in the North Sea, this flux is expected to increase as mixing increases, and almost all of the methane released at the seafloor could be transferred into the atmosphere in the stormy fall and winter time.     

Latitudinal patterns of export production recorded in surface sediments of the Chilean Patagonian fjords (41–55°S) as a response to water column productivity

The Chilean Patagonian fjords region (41–56°S) is characterized by highly complex geomorphology and hydrographic conditions, and strong seasonal and latitudinal patterns in precipitation, freshwater discharge, glacier coverage, and light regime; all of these directly affect biological production in the water column. In this study, we compiled published and new information on water column properties (primary production, nutrients) and surface sediment characteristics (biogenic opal, organic carbon, molar C/N, bulk sedimentary δ¹³C_org) from the Chilean Patagonian fjords between 41°S and 55°S, describing herein the latitudinal pattern of water column productivity and its imprint in the underlying sediments. Based on information collected at 188 water column and 118 sediment sampling sites, we grouped the Chilean fjords into four main zones: Inner Sea of Chiloé (41° to ～44°S), Northern Patagonia (44° to ～47°S), Central Patagonia (48–51°S), and Southern Patagonia (Magellan Strait region between 52° and 55°S). Primary production in the Chilean Patagonian fjords was the highest in spring–summer, reflecting the seasonal pattern of water column productivity. A clear north–south latitudinal pattern in primary production was observed, with the highest average spring and summer estimates in the Inner Sea of Chiloé (2427 and 5860 mg C m^?2 d^?1) and Northern Patagonia (1667 and 2616 mg C m^?2 d^?1). This pattern was closely related to the higher availability of nutrients, greater solar radiation, and extended photoperiod during the productive season in these two zones. The lowest spring value was found in Caleta Tortel, Central Patagonia (91 mg C m^?2 d^?1), a site heavily influenced by glacier meltwater and river discharge loaded with glacial sediments. Biogenic opal, an important constituent of the Chilean fjord surface sediments (Si_OPAL ～1–13%), reproduced the general north–south pattern of primary production and was directly related to water column silicic acid concentrations. Surface sediments were also rich in organic carbon content and the highest values corresponded to locations far away from glacier influence, sites within fjords, and/or semi-enclosed and protected basins, reflecting both autochthonous (water column productivity) and allochthonous sources (contribution of terrestrial organic matter from fluvial input to the fjords). A gradient was observed from the more oceanic sites to the fjord heads (west–east) in terms of bulk sedimentary δ¹³C_org and C/N ratios; the more depleted (δ¹³C_org ?26‰) and higher C/N (23) values corresponded to areas close to rivers and glaciers. A comparison of the Chilean Patagonian fjords with other fjord systems in the world revealed high variability in primary production for all fjord systems as well as similar surface sediment geochemistry due to the mixing of marine and terrestrial organic carbon.     

GPS-derived velocity field of the Iznik-Mekece segment of the North Anatolian Fault Zone

Space-based tectonic studies on the western part of the North Anatolian Fault Zone (NAFZ) have been conducted over two decades. After the August 17, 1999, Izmit earthquake (M_w = 7.4), this region attracted greater scientific interest, and the collected data became more valuable. The Geodesy Department of the Kandilli Observatory and Earthquake Research Institute (KOERI) at Bogazici University established three micro-geodetic networks to the east of Akyazi, east of Iznik, and west of Lake Sapanca in the eastern part of the Marmara region; GPS data have been continually collected at these locations since 1994. The NAFZ branches out in the western part of the Marmara region and extends up to the Aegean Sea. Segments of the fault passing through the Marmara Sea are considered active, and this has increased concern regarding imminent earthquakes. Conventional geodetic measurements made between 1990 and 1994 are not sufficient for monitoring small movements. However, GPS has played a very important role in detecting such deformations in the area after 1994. The Iznik network, with 10 points, is bilaterally located on the Iznik-Mekece fault. Six years of GPS data for 2004–2010 collected for the monitoring of crustal deformation showed that the Iznik-Mekece fault segment moves westward at about 22 ± 1 mm/yr with respect to the Eurasia fixed reference frame. The GPS observations show that there is no strain accumulation in the area.     

Quantities,composition, and sources of beach debris in Korea from the results of nationwide monitoring

This study assessed the levels of marine debris pollution and identified its main sources in Korea. The surveys were bimonthly conducted by NGO leaders and volunteers on 20 beaches from March 2008 to November 2009. The quantities of marine debris were estimated at 480.9 (±267.7) count ⋅ 100 m⁻¹ for number, 86.5 (±78.6) kg ⋅ 100 m⁻¹ for weight, and 0.48 (±0.38) m³ ⋅ 100 m⁻¹ for volume. The level of marine debris pollution on the Korean beaches was comparable to that in the coastal areas of the North Atlantic ocean and South Africa. Plastics and styrofoam occupied the majority of debris composition in terms of number (66.7%) and volume (62.3%). The main sources of debris were fishing activities including commercial fisheries and marine aquaculture (51.3%). Especially styrofoam buoy from aquaculture was the biggest contributor to marine debris pollution on these beaches.     

Glacial–interglacial sediment transport to the Meiji Drift,northwest Pacific Ocean: Evidence for timing of Beringian outwashing

A large sediment deposit known as the Meiji Drift, located in the northwestern Pacific Ocean, is thought to have formed from deep water exiting the Bering Sea, although no notable deep water forms there presently. We determine the terrigenous sources since 140 ka to the drift using bulk sediment ⁴⁰Ar–³⁹Ar and Nd isotopic analyses on the silt-sized (20–63 μm) terrigenous fraction from Ocean Drilling Program (ODP) Site 884 to reconstruct paleo-circulation patterns. There are large changes in both isotopic tracers, varying on glacial–interglacial cycles. During glacial intervals, bulk sediment ⁴⁰Ar–³⁹Ar ages range between 40 and 80 Ma, while Nd isotopic values range from ε_Nd = ? 1 to + 2. During interglacial intervals, sediments become much younger and more radiogenic, with bulk sediment ages falling to 2–15 Ma and Nd isotopic values ranging between ε_Nd = + 5 and + 9. These data and quantitative comparison to potential source rocks indicate that the young Kamchatkan and Aleutian Arcs, lying NW and NE of the Meiji Drift, contribute the majority of sediment during interglacials. Conversely, older source rocks, such as those drained by the Yukon River and northeast Russia are the dominant origin of sediments during glacials. Mixing model calculations suggest that as much as 35–45% of the sediment deposited in the Meiji Drift during glacials is from the Bering Sea. It remains unclear whether thermohaline-type circulation or focussing of Bering Sea flow lead to the glacial–interglacial sediment source changes observed here.     

Suspended microplastics in the surface water of the Yangtze Estuary System,China: First observations on occurrence,distribution

Levels of microplastics (MPs) in China are completely unknown. This study characterizes suspended MPs quantitatively and qualitatively for the Yangtze Estuary and East China Sea. MPs were extracted via a floatation method. MPs were counted and categorized according to shape and size under a stereomicroscope. The MP densities were 4137.3 ± 2461.5 and 0.167 ± 0.138 n/m³, respectively, in the estuarine and the sea samples. Plastic abundances varied significantly in the estuary. Higher densities in three sea trawls confirmed that rivers were the important sources of MP to the marine environment. Plastic particles (>5 mm) were observed with a maximum size of 12.46 mm, but MPs (0.5–5 mm) constituted more than 90% by number of items. The most frequent geometries were fibres, followed by granules and films. Plastic spherules occurred sparsely. Transparent and coloured plastics comprised the majority of the particles. This study provides clues in understanding the fate and potential sources of MPs.     

Selected trace metals (As,Cd and Hg) distribution and contamination in the coastal wetland sediment of the northern Beibu Gulf,South China Sea

Contamination with As, Cd and Hg, their spatial and temporal distribution are reported from the coastal wetland sediments of the northern Beibu Gulf, South China Sea. The content of As, Cd, Hg and TOC in surface sediments is 8.1 ± 5.8 μg g^?1, 0.08 ± 0.14 μg g^?1, 0.034 ± 0.028 μg g^?1 and 0.45 ± 0.39%, respectively. The mean sedimentation rates are 0.93–1.37 cm year^?1 during 1920s to 2008 determined by ²¹⁰Pb and ¹³⁷Cs dating in three cores. The vertical profiles of As, Cd and Hg content in the cores retrieved from Qin and Nanliu River estuaries show increasing trends during 1985–2008 due to anthropogenic impact caused by local economic development. Locally the surface sediments have potential ecological risk of As to benthos according to the NOAA sediment quality guidelines.     

Inorganic carbon and nutrient fluxes on the Arctic Shelf

Historic data from the Russian-American Hydrochemical Atlas of Arctic Ocean together with data from the TRANSDRIFT II 1994 and TUNDRA 1994 cruises have been used to assess the spatial and inter-annual variability of carbon and nutrient fluxes, as well as air–sea CO₂ exchange in the Laptev and western East Siberian Seas during the summer season. Budget computations using summer data of dissolved inorganic phosphate (DIP), dissolved inorganic nitrogen (DIN) and dissolved inorganic carbon (DIC) gives that the Laptev Sea shelf is a net sink of DIP and DIN of 2.5×10⁶, 23.2×10⁶ mol d⁻¹, respectively, while it is a net source of DIC (excluding air–sea exchange) of 1249×10⁶ mol d⁻¹. In the East Siberian Seas the budget computations give 0.5×10⁶, −11.4×10⁶ and −173×10⁶ mol d⁻¹ (minus being a sink) for DIP, DIN, and DIC, respectively. In summers, the Laptev Sea Shelf is net autotrophic while the East-Siberian Sea Shelf is net heterotrophic, and both systems are weak net denitrifying. The Laptev Sea Shelf takes up 2.1 mmol CO₂ m⁻² d⁻¹ from atmosphere, whereas the western part of the East-Siberian Sea Shelf loose 0.3 mmol CO₂ m⁻² d⁻¹ to the atmosphere. The variability of DIP, DIN and DIC fluxes during summer in the different regions of the Laptev and East Siberian Seas depends on bottom topography, river runoff, exchange with surrounding seas and wind field.     

Constraints on the nature of the subvolcanic reservoir at South Sister volcano,Oregon from U-series dating combined with sub-crystal trace-element analysis of plagioclase and zircon

We present sub-crystal-scale ²³⁸U–²³⁰Th zircon ages and ²³⁸U–²³⁰Th–²²⁶Ra plagioclase ages of bulk mineral separates from the Holocene (2.0–2.3 ka) eruptions of the Rock Mesa (RM) and Devil's Hills (DH) rhyolites at South Sister volcano, Oregon. We link these age data with sub-crystal trace-element analyses of zircon and plagioclase to provide insight into the subvolcanic system at South Sister, as an example of a small-volume continental arc volcano. Our results document the presence of coeval yet physically-distinct regions within the magma reservoir and constrain the timescales over which these heterogeneities existed. Zircons from the RM and DH dominantly record ages from 20 to 80 ka, with some grains recording ages > 350 ka, whereas plagioclase records ²³⁰Th–²²⁶Ra ages of 2.3–6.8 ka (RM) and 4.0–9.6 ka (DH-3) and a ²³⁸U–²³⁰Th age of 10 ± 34 ka (DH-3). We interpret zircons with ages < 350 ka as antecrysts inherited from a longer lived upper-crustal magma reservoir from which the rhyolites were generated, based on crystallization ages coeval with earlier periods of silicic volcanism at South Sister, the undersaturated nature of the RM and DH magmas with respect to zircon, and Ti-in-zircon temperatures consistent with low-temperature (< 815 °C) crystallization. In contrast, plagioclase ages are near the eruption age and dominantly preserve information about the recent (< 10 ka), higher-temperature evolution of the host magmas. Although zircon and plagioclase record different crystallization ages, each phase crystallized over the same time period in the RM compared to DH rhyolites. Linking these crystal age data with sub-crystal trace-element analyses demonstrates that zircon and plagioclase have distinct trace-element characteristics between eruptions, which require that the RM and DH crystals (and therefore magmas) were derived from distinct regions that had evolved independently for > 50 ka within a heterogeneous magmatic system and coexisted as physically-distinct, dominantly-liquid bodies prior to eruption. Thus, we favor a model where rhyolites are generated in independent batches by accumulation of evolved liquids in a heterogeneous, largely crystalline reservoir. Similarities in crystal age and chemical data to that at other young silicic systems (e.g., Mount St. Helens, Okataina Caldera Complex) suggest that this model may be more generally applicable to silicic magmas.     

Pliocene climate change of the Southwest Pacific and the impact of ocean gateways

The transition from the early Pliocene “Warmhouse” towards the present “Icehouse” climate and the role of Gateway dynamics are intensively debated. Both, the constrictions of the Central American Seaway and the Indonesian Gateway affected ocean circulation and climate during the Pliocene epoch. Here, we use combined δ¹⁸O and Mg/Ca ratios of planktonic foraminifera (marine protozoa) from surface and subsurface levels to reconstruct the thermal structure and changes in salinities from the Southwest Pacific Deep Sea Drilling Project (DSDP) Site 590B from 6.5 to 2.5 Ma. Our data suggest a gradual cooling of ~ 2 °C and freshening of the sea surface during ~ 4.6–4 Ma with an increased meridional temperature gradient between the West Pacific Warm Pool and the Southwest Pacific when the closing of the Central American Seaway reached a critical threshold. After ~ 3.5 Ma, the restricted Indonesian Gateway might have amplified the East Australian Current, allowing enhanced heat transport towards the Southwest Pacific with reduced meridional temperature gradients when the global climate gradually cooled. At the same time our data suggest a cooling and freshening of Subantarctic Mode Water (SAMW) or/and an increased northward flow of SAMW towards Site 590B, possibly a first step towards the present Antarctic Frontal System.     

Water mass variation in the Mediterranean and Black Seas

The mass-induced sea level variability and the net mass transport between Mediterranean Sea and Black Sea are derived for the interval between August 2002 and July 2008 from satellite-based observations and from model data. We construct in each basin two time series representing the basin mean mass signal in terms of equivalent water height. The first series is obtained from steric-corrected altimetry while the other is deduced from GRACE data corrected for the contamination by continental hydrology. The series show a good agreement in terms of annual and inter-annual signals, which is in line with earlier works, although different model corrections influence the consistency in terms of seasonal signal and trend.In the Mediterranean Sea, we obtain the best agreement using a steric correction from the regional oceanographic model MFSTEP and a continental hydrological leakage correction derived from the global continental hydrological model WaterGAP2. The inter-annual time series show a correlation of 0.85 and a root mean square (RMS) difference of 15 mm. The two estimates have similar accuracy and their annual amplitude and phase agree within 3 mm and 23 days respectively. The GRACE-derived mass-induced sea level variability yields an annual amplitude of 27 ± 5 mm peaking in December and a trend of 5.3 ± 1.9 mm/yr, which deviates within 3 mm/yr from the altimetry-derived estimate.In the Black Sea, the series are less consistent, with lower accuracy of the GRACE-derived estimate, but still show a promising agreement considering the smaller size of the basin. The best agreement is realized choosing the corrections from WaterGAP2 and from the regional oceanographic model NEMO. The inter-annual time series have a correlation and RMS differences of 0.68 and 55 mm, their annual amplitude and phase agree within 4 mm and 6 days respectively. The GRACE-derived seawater mass signal has an annual amplitude of 32 ± 4 mm peaking in April. On inter-annual time scales, the mass-induced sea level variability is stronger than in the Mediterranean Sea, with an increase from 2003 to 2005 followed by a decrease from 2006 to 2008.Based on mass conservation, the mass-induced sea level variations, river runoff and precipitation minus evaporation are combined to derive the strait flows between the basins and with the Atlantic Ocean. At the Gibraltar strait, the net inflow varies annually with an amplitude of 52 ± 10 × 10⁻³ Sv peaking end of September (1 Sv = 10⁶ m³ s⁻¹). The inflow through the Bosphorus strait displays an annual amplitude of 13 ± 3 ×10⁻³ Sv peaking in the middle of March. Additionally, an increase of the Gibraltar net inflow (3.4 ± 0.8 × 10⁻³ Sv/yr) is detected.     

Geochemical component relationships in MORB from the Mid-Atlantic Ridge, 22–35°N

New trace element and Hf, Nd, and Pb isotope data are reported for 22 basalts collected between 22°N and 35°N on the Mid-Atlantic Ridge. (La / Sm)_N ratios identify the presence of enriched (E)-MORB in the northernmost part of this area and normal (N)-MORB elsewhere. A negative correlation is observed when ¹⁴³Nd / ¹⁴⁴Nd is plotted against ²⁰⁶Pb / ²⁰⁴Pb, ²⁰⁷Pb / ²⁰⁴Pb, and ²⁰⁸Pb / ²⁰⁴Pb, whereas ¹⁷⁶Hf / ¹⁷⁷Hf appears not to correlate with any of the other isotopic ratios. The E-MORB samples are characterized by high ²⁰⁶Pb / ²⁰⁴Pb, ²⁰⁷Pb / ²⁰⁴Pb, ²⁰⁸Pb / ²⁰⁴Pb, and low ¹⁴³Nd / ¹⁴⁴Nd. Principal Component Analysis (PCA) of Pb isotopes alone identifies three, and only three, significant geochemical end-members (‘components’). Including Nd and Hf isotopic data in the PCA produces spurious components, partly because of curved mixing relationships, and partly because of fractionation during melting. Our preferred interpretation of why ¹⁷⁶Hf / ¹⁷⁷Hf is decoupled from the other isotopic ratios is, as inferred from recent experimental data, that the Hf isotopic compositions of the melt and the residue fail to equilibrate during melting. A strong correlation between (Sr / Nd)_N and (Eu / Eu*)_N indicates that plagioclase is a residual phase of N-MORB, but not of E-MORB melting. The three end-members identified in this study are the depleted mantle, a common-type component, and an enriched plume-type end-member. The common, or ‘C’-type, end-member is characteristic of E-MORB and may itself be a mixture containing recycled oceanic crust (the MORB suite, terrigenous sediments, and/or oceanic plateaus). The plume-type end-member is likely to represent the lower mantle and may involve some primordial material. It is shown that mantle isochrons in general and the Pb–Pb isochron in particular do not characterize a specific geodynamic process acting to create mantle heterogeneities.     

Age and nature of eclogites in the Huwan shear zone,and the multi-stage evolution of the Qinling-Dabie-Sulu orogen,central China

In situ LA-ICPMS U-Pb, trace element, and Hf isotope data in zircon demonstrate a Carboniferous age for eclogite-facies metamorphism in Siluro-Devonian protoliths in the Huwan shear zone, Dabie Mountains, Central China. This age contrasts with the more prevailing Triassic age for high- to ultrahigh pressure (HP to UHP) metamorphism in the Qinling-Dabie-Sulu orogen. Metamorphic zircon in two eclogite samples from Sujiahe is characterized by low Th/U ratios, small negative Eu anomalies, flat HREE patterns, and low ¹⁷⁶Lu/¹⁷⁷Hf ratios. These geochemical signatures suggest that the zircon crystallized in the presence of garnet and in the absence of plagioclase feldspar. Furthermore, temperatures of ~ 655 and ~ 638 °C, calculated using the Ti content of zircon, are consistent with their formation during eclogite-facies metamorphism. The weighted mean ²⁰⁶Pb/²³⁸U age of 309 ± 4 Ma (2δ) for this zircon improves previous age estimates for eclogite-facies metamorphism in the Huwan shear zone, ranging from 420 to 220 Ma. Metamorphic zircon from one eclogite sample from Hujiawan, most likely formed during prograde metamorphism, yields an equivalent age estimate of 312 ± 11 Ma. Magmatic zircon cores in the three samples yield ages for the magmatic protoliths of the eclogites ranging from 420 ± 7 to 406 ± 5 Ma, and post-dating the middle Paleozoic collision of the North China and the Qinling terrain. The zircon crystals in the three eclogite samples display a large variation of ε_Hf (t) values of ? 4.9 to 21.3. The metamorphic zircon overgrowths show the same range of ε_Hf (t) values as those of the inherited magmatic crystal interiors. This suggests that the metamorphic zircon overgrowths may have formed by dissolution-reprecipitation of pre-existing magmatic zircon thereby preserving their original Hf isotopic composition. The high ε_Hf (t) values suggest that the protoliths were derived from depleted mantle sources, most likely Paleotethyan oceanic crust; while the low ε_Hf (t) values are attributed to crustal contamination. Some eclogites in the Huwan shear zone have a distinctive signature of continental crust most probably derived from the Yangtze Craton. The coexistence of Paleozoic oceanic crust and Neoproterozoic continental crust with similar metamorphic ages in the Huwan shear zone implies that Paleozoic Paleotethyan oceanic crust was produced within a marginal basin of the northern Yangtze Craton. The opening of the Paleo-Tethyan ocean was slightly younger than the collision of the North China Craton and the Qinling terrain during the Late Paleozoic in the Qinling-Dabie-Sulu orogen. Subduction of the Paleo-Tethyan oceanic crust and associated continental basement resulted in the 309 ± 2 Ma (2σ) eclogite-facies metamorphism in the Huwan shear zone. The subsequent Triassic continent-continent collision led to the final coalescence of the Yangtze and Sino-Korean cratons. Amalgamation of the Yangtze and North China cratons was, therefore, a multistage process extending over at least 200 Ma.     

Multiple extreme environmental conditions of intermittent soda pans in the Carpathian Basin (Central Europe)

Soda lakes and pans represent saline ecosystems with unique chemical composition, occurring on all continents. The purpose of this study was to identify and characterise the main environmental gradients and trophic state that prevail in the soda pans (n = 84) of the Carpathian Basin in Central Europe. Underwater light conditions, dissolved organic matter, phosphorus and chlorophyll a were investigated in 84 pans during 2009–2010. Besides, water temperature was measured hourly with an automatic sensor throughout one year in a selected pan. The pans were very shallow (median depth: 15 cm), and their extremely high turbidity (Secchi depth median: 3 cm, min: 0.5 cm) was caused by high concentrations of inorganic suspended solids (median: 0.4 g L⁻¹, max: 16 g L⁻¹), which was the dominant (>50%) contributing factor to the vertical attenuation coefficient in 67 pans (80%). All pans were polyhumic (median DOC: 47 mg L⁻¹), and total phosphorus concentration was also extremely high (median: 2 mg L⁻¹, max: 32 mg L⁻¹). The daily water temperature maximum (44 °C) and fluctuation maximum (28 °C) were extremely high during summertime. The combination of environmental boundaries: shallowness, daily water temperature fluctuation, intermittent hydroperiod, high turbidity, polyhumic organic carbon concentration, high alkalinity and hypertrophy represent a unique extreme aquatic ecosystem.     

Nature of decadal-scale sediment accumulation on the western shelf of the Mississippi River delta

Sediment delivered to coastal systems by rivers (15×10⁹ tons) plays a key role in the global carbon and nutrient cycles, as deltas and continental shelves are considered to be the main repositories of organic matter in marine sediments. The Mississippi River, delivering more than 60% of the total dissolved and suspended materials from the conterminous US, dominates coastal and margin processes in the northern Gulf of Mexico. Draining approximately 41% of the conterminous US, the Mississippi and Atchafalaya river system deliver approximately 2×10⁸ tons of suspended matter to the northern Gulf shelf each year. Unlike previous work, this study provides a comprehensive evaluation of sediment accumulation covering majority of the shelf (<150 m water depth) west of the Mississippi Delta from 92 cores collected throughout the last 15 years. This provides a unique and invaluable data set of the spatial and modern temporal variations of the sediment accumulation in this dynamic coastal environment.Three types of ²¹⁰Pb profiles were observed from short cores (15–45 cm) collected on the shelf. Proximal to Southwest Pass in 30–100 m water depths, non-steady-state profiles were observed indicating rapid accumulation. Sediment accumulation rates in this area are typically >2.5 cm yr⁻¹ (>1.8 g cm⁻² yr⁻¹). Kasten cores (∼200 cm in length) collected near Southwest Pass also indicate rapid deposition (>4 cm yr⁻¹; >3 g cm⁻² yr⁻¹) on a longer timescale than that captured in the box cores. Near shore (<20 m), profiles are dominated by sediments reworked by waves and currents with no accumulation (the exception is an area just south of Barataria Bay where accumulation occurs). The remainder of the shelf (distal of Southwest Pass) is dominated by steady-state accumulation beneath a ∼10-cm thick mixed layer. Sediment accumulation rates for the distal shelf are typically <0.7 cm yr⁻¹ (<0.5 g cm⁻² yr⁻¹). A preliminary sediment budget based on the distribution of ²¹⁰Pb accumulation rates indicates that 40–50% of the sediment delivered by the river is transported out of the study region. Sediment is moved to distal regions of the shelf/slope through two different mechanisms. Along-isobath sediment movement occurs by normal resuspension processes west of the delta, whereas delivery of sediments south and southwest of the delta may be also be influenced by mass movement events on varying timescales.     

Baseline concentrations of faecal sterols and assessment of sewage input into different inlets of Admiralty Bay,King George Island,Antarctica

The Antarctic region is one of the best preserved environments in the world. However, human activities such as the input of sewage result in the alteration of this pristine site. We report baseline values of faecal sterols in Admiralty Bay, Antarctica. Four sediment cores were collected during the 2006/2007 austral summer at the Ezcurra (THP and BAR), Mackelar (REF) and Martel (BTP) inlets. Concentrations of faecal sterols (coprostanol + epicoprostanol) were <0.16 μg g⁻¹, suggesting no sewage contamination and probable “biogenic” contributions for these compounds. Baseline values, calculated using the mean concentration of faecal sterols in core layers for THP, BAR, REF and BTP, were 0.04 ± 0.02, 0.03 ± 0.01, 0.07 ± 0.01 and 0.04 ± 0.02 μg g⁻¹, respectively. These results established as natural contributions of faecal sterols, suggesting that these markers can be useful indicators of human-derived faecal input and contributing to monitoring programs to prevent anthropogenic impacts.