Winter variability of physical processes and sediment-transport events on the Eel River shelf,northern California

A 5-yr data set of near-bed current and suspended-sediment concentration measured within 2 m of the seabed in 60-m water depth has been analyzed to evaluate the interannual variability of physical processes and sediment transport events on the Eel River continental shelf, northern California. This data set encompasses a wide range of shelf conditions with winter events characterized as: Major Flood (1996/97), strong El Niño (1997/98), strong La Niña (1998/99), and Major Storm (1999/00). Data were collected at a site located 25 km north of the Eel River mouth, on the landward edge of the mid-shelf mud deposit. During the winter months sediment resuspension is forced primarily by near-bed oscillatory flows, and sediment transport occurs both as suspended load and as gravity-driven (fluid-mud) flows. Winter conditions that caused periods of increased sediment transport existed on average for 142 d yr⁻¹ over the total record, ranging between 89 d in the Major Flood year (1996/97) and 171 d in the La Niña year (1998/99). Hourly averaged values of significant wave height varied between 0.5 and 10.7 m and hourly averaged values of near-bed orbital velocities ranged between 0 and 125 cm s⁻¹. During the five winters, sediment threshold conditions were exceeded an average of 35% of the time, ranging from 19% in the Major Flood year (1996/97) to 52% in the La Niña year (1998/99). Mean concentration of suspended sediment, measured at 30 cmab, ranged from values close to 0–8 g l⁻¹. Among winters, major sediment flux events exhibited different patterns due to varying combinations of physical processes including river floods, waves, and shelf circulation. Within winters, the major period of sediment flux varied from a 3-d fluid mud event (Major Flood winter) to a 50-d period of persistent southerlies (El Niño winter) and a winter of continuous storm cycles (La Niña winter). Winter-averaged suspended-sediment concentration appeared to vary in response to river discharge, while total sediment flux responded to storm intensity. The net sediment flux appeared to depend on timing of river discharge and shelf conditions. On the Eel River shelf, the mid-shelf mud deposit apparently is not emplaced by deposition from the river plume, but by secondary processes from the inner shelf including off-shelf transport of sediment suspensions and gravity-driven fluid-mud flows. Thus, these inner-shelf processes redistribute sediment supplied by the Eel River (a point source) making the inner shelf a line source of sediment that forms and nourishes the mid-shelf deposit. Large-scale shelf circulation patterns and interannual variability of the physical forcing are also important in determining the locus of the mid-shelf deposit, and both are influenced by climate variations. Post-depositional alteration of the deposit also depends on the subsequent shelf conditions following major floods.     

Distribution,origin, and potential toxicological significance of polycyclic aromatic hydrocarbons (PAHs) in sediments of Kaohsiung Harbor,Taiwan

Sediment samples were collected from 12 locations of Kaohsiung Harbor, Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Total PAH concentrations varied from 472 to 16,201 ng g⁻¹ dry weight. The highest PAH concentrations were from the industrial zone docks situated in south Kaohsiung Harbor. Diagnostic ratios showed that the possible source of PAHs in the industrial zone dock could be coal combustion while in the other zones it could be petroleum combustion. The toxic equivalent concentrations (TEQ^carc) of PAHs varied from 55 to 1964 ng TEQ g⁻¹ dry weight. Higher total TEQ^carc values were found at industrial zone docks (from 1404 to 1964 ng TEQ g⁻¹ dry weight). As compared with the US Sediment Quality Guidelines (SQGs), the observed levels of PAHs at industrial zone docks exceeded the effects range low (ERL), and could thus cause acute biological damage. However, the lower levels of PAHs at the other zones would probably not exert adverse biological effects.     

Direct measurement of dissolved N2 and denitrification along a subtropical river-estuary gradient,China

The spatial pattern and seasonal variation of denitrification were investigated during 2010–2011 in the Jiulong River Estuary (JRE) in southeast China. Dissolved N₂ was directly measured by changes in the N₂:Ar ratio. The results showed that excess dissolved N₂ ranged from ?9.9 to 76.4 μmol L^?1. Tidal mixing leads to a seaward decline of dissolved gaseous concentrations and water–air fluxes along the river-estuary gradient. Denitrification at freshwater sites varied between seasons, associated with changes in N input and water temperature. The denitrification process was controlled by the nitrate level at freshwater sites, and the excess dissolved N₂ observed at the tidal zone largely originated from upstream water transport. Compared to other estuaries, JRE has a relative low gaseous removal efficiency (E_d = 12% of [DIN]; annual N removal = 24% of DIN load), a fact ascribed to strong tidal mixing, coarse-textured sediment with shallow depth before bedrock and high riverine DIN input.     

Tidally-induced sediment transport patterns in the upper Bay of Fundy: A numerical study

The Minas Basin, the eastern end of the Bay of Fundy, is well known for its high tide ranges and strong tidal currents, which can be exploited to extract electricity power. The properties of the tidally-induced sediment transport in the Minas Basin, where significant changes in tidal processes may occur due to a recently proposed tidal power project, have been studied with a three-dimensional hydrodynamic model, an empirical bed load sediment transport model and surface sediment concentrations derived from the remotely-sensed images. The hydrodynamic model was evaluated against independent observational data, which include tidal elevation, tidal current (in the full water column and bottom layer), residual current profile and tidal asymmetry indicators. The evaluation shows that the model is in good agreement with the observations.The sediment transport includes two components, bed load and suspended particulate load. The bed load is calculated using the modelled bottom shear stress and the observed grain size data. The estimated features of bed load transport roughly agree with the observed patterns of the erosion and deposition in the Minas Basin and Cobequid Bay. The transport of the suspended load is estimated using the modelled velocity fields and the surface sediment concentration derived from remote-sensing images. The comparisons between the modelled results and the limited observations illustrate that the observed directions of suspended sediment transport are basically reproduced by the model. The modelled net suspended sediment input into the Minas Basin through Minas Passage is 2.4×10⁶ m³ yr^?1, which is comparable to the observed value of 1.6×10⁶ m³ yr^?1.The variations of the bed load and the suspended load in space and time are also presented. The total net transport, defined as the mean value of the sum of bed and suspended load transports during the tidal cycle, shows strong spatial variability. The magnitude of the transport flux ranges from 0.1 to 0.2 kg m^?1 s^?1 in Minas Channel and Minas Passage, 0.1 kg m^?1 s^?1 in Cobequid Bay, to 0.01 kg m^?1 s^?1 in the central Minas Basin and Southern Bight. In Minas Channel, the sediment transport follows the structure of the tidal residual circulation, which features a large anticlockwise gyre. The sediment in Minas Passage moves eastward and deposits into the central Minas Basin. However, the sediment from the eastern part of the Basin moves westward and deposits in the central Minas Basin as well. In the Cobequid Bay, sediment moves eastward and deposits in the upper bay.     

Flow patterns at the Chesapeake Bay entrance

The spatial and temporal variability of water entering and leaving the Chesapeake Bay estuary was determined with a spatial resolution of 75 m. The four cruises during which the observations were made took place under different conditions of freshwater discharge, tidal phase, and wind forcing. The tidal variability of the flows was dominated by the semidiurnal constituents that displayed greatest amplitudes and phase lags near the surface and in the channels that lie at the north and south sides of the entrance. The subtidal variability of the flows was classified into two general scenarios. The first scenario occurred during variable or persistently non-southwesterly winds. Under these conditions there was surface outflow and bottom inflow in the two channels, inflow over the shoal between the two channels, and possible anticyclonic gyre formation over the shoal. The flow pattern in the channels was produced by gravitational circulation and wind forcing. Over the shoal it was caused by tidal rectification and wind forcing. The second scenario occurred during persistently southwesterly winds. The anticyclonic gyre over the shoal vanished suggesting that wind forcing dominated the tidal rectification mechanism over the shoal, while gravitational circulation and wind forcing continued to cause the flows in the channels. In both scenarios, most of the volume exchange took place in the channels.     

Selected trace metals (As,Cd and Hg) distribution and contamination in the coastal wetland sediment of the northern Beibu Gulf,South China Sea

Contamination with As, Cd and Hg, their spatial and temporal distribution are reported from the coastal wetland sediments of the northern Beibu Gulf, South China Sea. The content of As, Cd, Hg and TOC in surface sediments is 8.1 ± 5.8 μg g^?1, 0.08 ± 0.14 μg g^?1, 0.034 ± 0.028 μg g^?1 and 0.45 ± 0.39%, respectively. The mean sedimentation rates are 0.93–1.37 cm year^?1 during 1920s to 2008 determined by ²¹⁰Pb and ¹³⁷Cs dating in three cores. The vertical profiles of As, Cd and Hg content in the cores retrieved from Qin and Nanliu River estuaries show increasing trends during 1985–2008 due to anthropogenic impact caused by local economic development. Locally the surface sediments have potential ecological risk of As to benthos according to the NOAA sediment quality guidelines.     

A quantitative examination of modern sedimentary lithofacies formation on the glacially influenced Gulf of Alaska continental shelf

Continental-shelf lithofacies are described from a series of cores collected in the northern Gulf of Alaska, a high-energy paraglacial shelf experiencing rapid rates of sediment accumulation. Short-lived tracers (²³⁴Th and chlorophyll-a) indicate that during the annual peak in fluvial sediment input (summer), biologic sediment mixing coefficients in the surficial seabed are generally lower than other coastal environments (<20 cm² yr⁻¹) and mixing extends downward <10 cm.²¹⁰Pb geochronology indicates that sediment accumulation rates (time scales of 10–100 yr) are 0.1–3 cm yr⁻¹. The measured bioturbation and accumulation rates lead to predictions of moderate to bioturbated lithofacies, as observed. Primary depositional fabric is preferentially preserved where sediment accumulation rates >2 cm yr⁻¹ and non-steady sediment deposition occurs. Depositional fabric is also observed in strata at 50–100 m water depths and is similar in appearance to beds that may form through deposition of wave-induced fluid-mud flows, which have been observed forming on other shelves with moderate to high wave energy. Five general lithofacies can be identified for the study area: inner-shelf sand facies, interbedded sandy mud facies, moderate-to-well-bioturbated mud facies, gravelly mud facies, and Tertiary bedrock facies. The moderate-to-well-bioturbated mud facies is areally dominant, representing over 50% of the shelf area, although roughly equal volumes (∼0.4 km³) of strata with some preservation of primary fabric are annually accumulating. Lithofacies on this paraglacial shelf generally resemble mid- and low-latitude allochthonous shelf strata to a much greater degree than Holocene glacimarine strata formed on shelves dominated by icebergs and floating ice shelves. Paraglacial strata may be differentiated from non-glacial shelf strata by lower organic carbon concentrations, a relatively lower degree of bioturbation, and increased preservation of primary depositional fabric.     

A synthesis of morphological evolutions and Holocene stratigraphy of a wave-dominated estuary: The Arcachon lagoon,SW France

This work presents the first synthesis of secular to millenary morphological evolutions and stratigraphy of a wave-dominated estuary, the Arcachon lagoon, from a combination of unpublished bathymetric maps (1865 and 2001), core results and high-resolution seismic profiles recorded for the first time in this lagoon. The Arcachon lagoon is located on the Atlantic coast of France, facing the wave-dominated shelf of the Bay of Biscay. It is a mesotidal semi-enclosed environment of about 160 km².The sediment budget of the Arcachon lagoon was computed by subtracting the 1865 bathymetric map from that of 2001. The computed volume difference is low (?9.9±35×10⁶ m³ in 136 yrs) and is the result of the balance between erosion and accretion that occurs within tidal channels and tidal flats, respectively. This morphological evolution pattern is explained by low sediment supply and also by the tidal distortion resulting from the morphology of the lagoon. Deep channels connected to the inlet are dominated by ebb currents inducing erosion. Tidal flats and transverse channels display weak or flood-dominated tidal currents leading to the deposition of silts. The areas of tidal flat siltation locally correlate with the presence of oyster farms, suggesting the influence of Man on the lagoon sediment-fill. Transverse channel-infill is related to weak tidal currents resulting from the hydraulically inefficient orientation of these channels which served as an ancient drainage network.Evidence for tidal channel-infill and channel abandonment are also provided by seismic profiling and cores. The upper stratigraphic succession of the lagoon (about 10 m thick) includes four main stratigraphic units dominated by channel-fills. The two lower units (around 7500–2800 yrs BP) display tabular-shape sandy channels interpreted to be records of the open estuarine phase of the Arcachon lagoon. The two upper units (around 2800 yrs BP to present-day) display U-shaped mixed sand-and-mud channel-fills interpreted to be records of the closure of the lagoon. Given that the basal estuarine units are transgressive and the upper lagoonal units are regressive, the main stratigraphic change at around 2800 yrs BP is interpreted as being the maximum flooding surface (MFS). This late MFS is explained by the low sediment supply. It is proposed that the transition from the estuarine to the lagoonal phase is related to the development of the Cap-Ferret spit in response to an increase in the ratio between wave power to tide power. This change in wave-to-tide ratio may be triggered by wave power increase following the Subboreal/Subatlantic climate instability or a decrease in tide power following a decrease in tidal prism related to the lagoon sediment-fill.Thus, the evolution of the Arcachon lagoon over the last millenaries was mainly controlled by its spit development, leading to a wave-dominated estuary in terms of its geomorphology. Once it was partially closed, extensive mud flats developed in the lagoon which became ebb-dominated.     

Factors controlling sediment yield in a major South American drainage basin: the Magdalena River,Colombia

The Magdalena River, a major fluvial system draining most of the Colombian Andes, has the highest sediment yield of any medium-sized or large river in South America. We examined sediment yield and its response to control variables in the Magdalena drainage basin based on a multi-year dataset of sediment loads from 32 tributary catchments. Various morphometric, hydrologic, and climatic variables were estimated in order to understand and predict the variation in sediment yield. Sediment yield varies from 128 to 2200 t km⁻² yr⁻¹ for catchments ranging from 320 to 59,600 km². The mean sediment yield for 32 sub-basins within the Magdalena basin is ∼690 t km⁻² yr⁻¹. Mean annual runoff is the dominant control and explains 51% of the observed variance in sediment yield. A multiple regression model, including two control variables, runoff and maximum water discharge, explains 58% of the variance. This model is efficient (ME=0.89) and is a valuable tool for predicting total sediment yield from tributary catchments in the Magdalena basin. Multiple correlations for those basins corresponding to the upper Magdalena, middle basin, Eastern Cordillera, and catchment areas greater than 2000 km², explain 75, 77, 89, and 78% of the variance in sediment yield, respectively. Although more variance is explained when dataset are grouped into categories, the models are less efficient (ME<0.72). Within the spatially distributed models, six catchment variables predict sediment yield, including runoff, precipitation, precipitation peakedness, mean elevation, mean water discharge, and relief. These estimators are related to the relative importance of climate and weathering, hillslope erosion, and fluvial transport processes. Time series analysis indicates that significant increases in sediment load have occurred over 68% of the catchment area, while 31% have experienced a decreasing trend in sediment load and thus yield. Land use analysis and increasing sediment load trends indicate that erosion within the catchment has increased over the last 10–20 years.     

Water mass variation in the Mediterranean and Black Seas

The mass-induced sea level variability and the net mass transport between Mediterranean Sea and Black Sea are derived for the interval between August 2002 and July 2008 from satellite-based observations and from model data. We construct in each basin two time series representing the basin mean mass signal in terms of equivalent water height. The first series is obtained from steric-corrected altimetry while the other is deduced from GRACE data corrected for the contamination by continental hydrology. The series show a good agreement in terms of annual and inter-annual signals, which is in line with earlier works, although different model corrections influence the consistency in terms of seasonal signal and trend.In the Mediterranean Sea, we obtain the best agreement using a steric correction from the regional oceanographic model MFSTEP and a continental hydrological leakage correction derived from the global continental hydrological model WaterGAP2. The inter-annual time series show a correlation of 0.85 and a root mean square (RMS) difference of 15 mm. The two estimates have similar accuracy and their annual amplitude and phase agree within 3 mm and 23 days respectively. The GRACE-derived mass-induced sea level variability yields an annual amplitude of 27 ± 5 mm peaking in December and a trend of 5.3 ± 1.9 mm/yr, which deviates within 3 mm/yr from the altimetry-derived estimate.In the Black Sea, the series are less consistent, with lower accuracy of the GRACE-derived estimate, but still show a promising agreement considering the smaller size of the basin. The best agreement is realized choosing the corrections from WaterGAP2 and from the regional oceanographic model NEMO. The inter-annual time series have a correlation and RMS differences of 0.68 and 55 mm, their annual amplitude and phase agree within 4 mm and 6 days respectively. The GRACE-derived seawater mass signal has an annual amplitude of 32 ± 4 mm peaking in April. On inter-annual time scales, the mass-induced sea level variability is stronger than in the Mediterranean Sea, with an increase from 2003 to 2005 followed by a decrease from 2006 to 2008.Based on mass conservation, the mass-induced sea level variations, river runoff and precipitation minus evaporation are combined to derive the strait flows between the basins and with the Atlantic Ocean. At the Gibraltar strait, the net inflow varies annually with an amplitude of 52 ± 10 × 10⁻³ Sv peaking end of September (1 Sv = 10⁶ m³ s⁻¹). The inflow through the Bosphorus strait displays an annual amplitude of 13 ± 3 ×10⁻³ Sv peaking in the middle of March. Additionally, an increase of the Gibraltar net inflow (3.4 ± 0.8 × 10⁻³ Sv/yr) is detected.     

On the tidal heating of Enceladus

Enceladus, one of Saturn's moons, shows significant volcanic activity identified by the Cassini spacecraft. The aim of the present study is to investigate – with the adaptation of mathematical tools used in geodynamics – the extent of tidal heating due to the mean motion resonance with Dione. For the purpose of calculations a two-layer model of Enceladus was used. The inner part of the model is a “rocky core” with a relative radius 0.55, while the outer part is composed of water ice. The results of model calculations show that the effective tidal heating is not uniformly distributed within Enceladus. It was found for the selected model of Enceladus, that the tidal heating is maximum within the depth interval (25–75) km. Due to the inhomogeneity within Enceladus, 85% of the tidal energy is generated in a volume that contains just 39% of its mass. In time intervals of 3.0 × 10⁸ and 5.3 × 10⁸ years the temperature increase in the relative depth range 0.70 ≤ r/a_E ≤ 0.90 is approximately 270 and 370 K, respectively.     

Effects of environmental stresses on the responses of mangrove plants to spent lubricating oil

The influence of different environmental stresses, including salinity (5–35‰), tidal cycle (6/6, 12/12 and 24/24 h of high/low tidal regimes) and nutrient addition (1–6 times background nitrogen and phosphorus content) on Bruguiera gymnorrhiza and Aegiceras corniculatum grown in sediment contaminated with spent lubricating oil (7.5 L m⁻²) were investigated. The oil-treated 1-year-old mangrove seedlings subject to low (5‰) and high (35‰) salinity had significantly more reduction in growth, more release of superoxide radical (O₂⁻) and higher activity of superoxide dismutase (SOD) than those subject to moderate salinity (15‰). Extended flooding (24/24 h of high/low tidal regime) enhanced O₂⁻ release and malondialdehyde (MDA) content in both oil-treated species but had little negative effects on biomass production (P > 0.05) except the stem of A. corniculatum (P = 0.012). The addition of nutrients had no beneficial or even posed harmful effects on the growth and cellular responses of the oil-treated seedlings.     

Interactive influence of water level,sediment heterogeneity,and plant density on the growth performance and root characteristics of Carex brevicuspis

Water level, sediment heterogeneity, and plant density are important factors that determine plant growth, distribution, and community structure. In the present study, we investigated the effects of these factors on the growth and root characteristics of Carex brevicuspis. We conducted an outdoor experiment to monitor biomass accumulation and allocation, relative root distribution mass ratio, longest root length, and total N and P contents of C. brevicuspis plants. We used a factorial design with two water levels (0 cm and −15 cm relative to the soil surface, named high and low water level treatments, respectively), three sediment types (sand/clay sediment with 0–15 cm of sand and 15–30 cm of clay; mixed sediment with 0–30 cm mixture of sand and clay with 1:1 volumw ratio; and clay/sand sediment with 0–15 cm of clay and 15–30 cm of sand), and three plant densities (88 plants per m², 354 plants per m², and 708 plants per m²). Biomass accumulation decreased with increasing plant density and was significantly higher in the low water level and the clay/sand sediment than in the high water level and the other two sediment types. The shoot:root ratio was markedly higher in the high water level than in the low water level and decreased with increasing plant density; further, in the high water level, it was significantly lower in the sand/clay sediment than in the other two sediment types. The relative root distribution mass ratio was markedly higher in the high water level treatments than in the low water level treatments. Further, in the high water level treatments, the relative root distribution mass ratio increased with increasing plant density in the clay/sand sediment and was lower in the sand/clay sediment than in the other two sediment types. The longest root length was significantly lower in the high water level than in the low water level and increased with increasing plant density in the sand/clay sediment in the high water level. Total N content in the plants was influenced only by sediment type; on the other hand, total P content was markedly higher in the high water level than in the low water level. Our data indicate that growth of C. brevicuspis was limited by higher water level, higher density and sand/clay sediment. Plants can increase shoot:root ratio and develop shallow root system to acclimate to high water level and thus could adjust shoot:root ratio and root characteristics, e.g. decrease their shoot:root ratio and allocating more root and increasing root length to the nutrient rich layer to acclimate to conditions of higher density and sediment heterogeneity.     

Distributions of polychlorinated biphenyls in the Daliao River estuary of Liaodong Bay,Bohai Sea (China)

The distributions of 41 polychlorinated biphenyls (PCBs) were determined in the aqueous phase, suspended particulate matter (SPM), and sediment of the Daliao River estuary in Liaodong Bay, Bohai Sea (China). The total PCB concentrations ranged from 5.51 to 40.28 ng L⁻¹ in the surface water, from 6.78 to 66.55 ng L⁻¹ dry weight in the SPM, and from 0.83 to 7.29 ng g⁻¹ dry weight in the sediment. The PCB concentrations in water, SPM, and sediment were moderate relative to those reported for other estuary and marine systems around the world. Sedimentary PCB concentrations decreased offshore due to the active deposition of laterally transported river-borne particles. The predominance of the highly chlorinated congeners for the water, SPM, and sediment samples are an indication of either a lack of degradation or the presence of nearby or recent releases into the environment.     

Decadal record of sediment export to the deep sea via Eel Canyon

An active upper-canyon system, Eel Canyon, was studied to determine its role as a conduit and/or sink for terrigenous material over decadal timescales and to assess the sedimentary record preserved by transport processes. These data are used to (1) link seasonal fluctuations in sediment transport and deposition to preserved stratigraphic signatures, and (2) assess sediment storage and removal in the upper Eel Canyon (100–850 m water depth) over decadal timescales. Previous research has shown that upper thalwegs commonly experience gravity-driven flows during winter (November–March), due to increased sediment supply from Eel River flooding and intense storms that produce energetic wave/current conditions. Thick winter deposits composed of recently discharged fluvial sediment are formed in upper thalwegs, with distinct short- and long-lived radioisotopic and textural signatures (detectable ⁷Be and ²³⁴Th_xs, lowered ²¹⁰Pb activity, elevated clay content, and physical structures). Box and kasten cores were collected in the upper canyon (thalwegs and walls) to measure these signatures in recent and preserved winter deposits, and to calculate 100-yr accumulation rates. Non-bioturbated deposits (that have signatures indicative of rapid accretion by gravity-driven flows during the winter) are common in the upper canyon thalwegs. Short-lived radioisotopes (⁷Be and ²³⁴Th) show that sediment delivery to the upper thalweg varies temporally, sometimes beginning at the onset of river flooding, and at other times beginning during fall/early winter dry-storm events. In contrast, bioturbated deposits (which do not have signatures indicative of rapid deposition) are found on canyon walls.Non-bioturbated winter deposits are easily identified in the decadal record of thalwegs by decreases in ²¹⁰Pb activity and increases in clay content. Stacking of multiple years of winter deposits (∼10 cm preserved per winter) results in non-steady-state ²¹⁰Pb profiles and high decadal accumulation rates. However, down-core changes in ²¹⁰Pb profiles show that slope failures are actively redistributing these winter deposits. Partial or total removal of multiple winter deposits appears to happen periodically (every ∼13 yr), which will inhibit preservation of the longer decadal record. 100-yr accumulation rates were calculated in the thalwegs from the resulting ²¹⁰Pb profiles (i.e., the result of winter accretion and decadal removal by failures). Accumulation rates are much higher in thalwegs (1–6 cm/yr) than walls (0.1–0.8 cm/yr), which is likely the result of differing sediment delivery processes (via gravity-driven flows and nepheloid layers, respectively). At least 2.6±1.4% of the Eel River sediment budget is accumulating in the upper canyon over 100-yr timescales. However, this value greatly underestimates the total amount entering the canyon system because minimum accumulation rates were used in many areas (due to limited core length) and slope failures are moving sediment out of the budget area.     

Phosphorus retention and release by sediments in the eutrophic Mai Po Marshes,Hong Kong

This study examined the phosphorus retention and release characteristics of sediments in the eutrophic Mai Po Marshes in Hong Kong. Results of chemical fractionation show that the sum of inorganic P pools exceeded 50% of the total sediment P content, with the redox-sensitive iron-bound P (Fe(OOH) ≈ P) being the dominant P fraction. Given the considerable average Fe(OOH) ≈ P concentration of 912 μg g⁻¹, Mai Po sediments demonstrated a great potential to release bioavailable P under low sediment redox potentials. This was further supported by the high mean anaerobic P flux of 31.8 mg m⁻² d⁻¹ recorded in Mai Po sediment cores, indicating the role of bottom sediments as a net P source. Although sediments in Mai Po had appreciable Langmuir adsorption maxima (1642–3582 mg kg⁻¹), the high zero equilibrium P concentrations (0.02–0.51 mg L⁻¹) obtained suggest that sediment sorption processes would contribute to sustaining the eutrophic conditions in overlying water column even with a further reduction in external P load. Concerted efforts should be made to reduce internal loading of P, especially under reducing conditions, to complement the implementation of zero discharge policy for Deep Bay for effective eutrophication abatement and long-term water quality improvement in the Mai Po Marshes.     

Spatial and seasonal variability of sediment oxygen consumption and nutrient fluxes at the sediment water interface in a sub-tropical lagoon (New Caledonia)

In order to quantify the spatial and seasonal variations of sediment oxygen consumption and nutrient fluxes, we performed a spatial survey in the south west lagoon of New Caledonia during the two major seasons (dry and wet) based on a network of 11 sampling stations. Stations were selected along two barrier reef to land transects representing most types of sediments encountered in the lagoon. Fluxes were measured using ex-situ sediment incubations and compared to sediment characteristics. Sediment oxygen consumption (SOC) varied between 500 and 2000 μmol m⁻² h⁻¹, depending on season and stations. Nutrient effluxes from sediment were highly variable with highest fluxes measured in muddy sediments near the coast. Inter-sample variability was as high as seasonal differences so that no seasonally driven temperature effect could be observed on benthic nutrient fluxes in our temperature range. Nutrient fluxes, generally directed from the sediment to the water column, varied between −5.0 and 70.0 μmol m⁻² h⁻¹ for ammonia and between −2.5 and +12.5 μmol m⁻² h⁻¹ for PO₄ and NO₂₊₃. SOC and nutrient fluxes were compared to pelagic primary production rates in order to highlight the tight coupling existing between the benthic and pelagic compartments in this shallow tropical lagoon. Under specific occasions of low pelagic productivity, oxygen sediment consumption and related carbon and nutrient fluxes could balance nearly all net primary production in the lagoon. These biogeochemical estimates point to the functional importance of sediment biogeochemistry in the lagoon of New Caledonia.     

Polycyclic aromatic hydrocarbons in the coastal water,surface sediment and mullet Liza klunzingeri from northern part of Hormuz strait (Persian Gulf)

The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in mullet (Liza klunzingeri), water and sediment from northern part of Hormuz strait (Persian Gulf). The concentration levels of total PAHs in L. klunzingeri, water and sediment were 133.99–268.57 ng g⁻¹ dry weight, 3.12–5.88 ng l⁻¹ and 42.29–228.9 ng g⁻¹ dry weight, respectively. Based on isomer ratios, analysis of the PAHs source in the sediment demonstrated that the PAHs come from pyrogenic and petrogenic origin. Risk assessment showed PAHs threshold concentrations to occasionally be exceeded in the study area.     

Cosmogenic 3He exposure dating of the Quaternary basalts from Fogo,Cape Verdes: Implications for rift zone and magmatic reorganisation

We have used cosmogenic ³He to date pre- and post-collapse lava flows from southwestern Fogo, Cape Verdes, in order to date rift zone magmatic reorganisation following the lateral collapse of the flank of the Monte Amarelo volcano. The post-collapse flows have exposure ages ranging from 62 to 11 ka. The analysis of multiple flow tops on each lava flows, often at different elevations, provides an internal check for age consistency and the exposures ages conform with stratigraphic level. The exposure ages suggest that volcanic activity along the western branch of the triple-armed rift zone was more or less continuous from before 62 ka to approximately 11 ka. The absence of magmatic activity for the last 11 kyr reflects a structural reconfiguration of the volcano and may be related to renewed flank instability. This volcanic hiatus is similar in duration to that observed in the Canary Islands. Replicate ³He exposure ages of a pre-collapse flow (123.0 ± 5.2 ka) brackets the time of the Monte Amarelo collapse between 62 ka and 123 ka. Reproducible cosmogenic ³He exposure ages of less than 123 ka from flows away from major erosion features demonstrates that the technique is a viable alternative to the radiocarbon, K/Ar and ⁴⁰Ar/³⁹Ar chronometers for dating recent volcanism in arid climate zones.     

Lithospheric contributions to high-MgO basanites from the Cumbre Vieja Volcano,La Palma,Canary Islands and evidence for temporal variation in plume influence

New geochemical and isotopic data are presented from the oldest part of the Cumbre Vieja volcano, La Palma (Canary Islands), located near the assumed emergence of the Canary mantle plume. The volcanics comprise a suite dominated by basanite flows with subordinate amounts of phono-tephrite, tephri-phonolite and phonolite flows and intrusives. Two compositionally different basanite groups have been identified, both with HIMU (high-μ)-type incompatible trace element characteristics: Primitive high-MgO basanites (10.7–12.1% MgO), found only at the base of a stratigraphic profile near Fuencaliente on the south coast, and intermediate-MgO basanites (6.0–7.3% MgO), exposed in the upper part of the profile and widespread on the east coast of La Palma. The high-MgO basanites are interpreted as near-primary mantle melts (primary composition 14–15% MgO) derived by progressive melting (2.9% to 4.5%) of a common lithospheric mantle source. Model calculations indicate that it is not possible to generate the intermediate-MgO basanites from the high-MgO group by crystal fractionation of observed phenocrysts. Relative to intermediate-MgO basanites, the high-MgO flows have lower concentrations of LIL and HFS elements, except for Ti, which is markedly enriched in the primitive rocks (3.7–4.7% TiO₂ vs 3.4–3.9% TiO₂). Fuencaliente volcanics display limited temporal isotopic variations suggested to be a result of mixing of melts originating from the rising plume and the metazomatized lithospheric mantle. ⁸⁷Sr / ⁸⁶Sr and ¹⁴³Nd / ¹⁴⁴Nd ratios range 0.70305–0.70311 and 0.51285–0.51291, respectively, while the corresponding ranges in Pb-isotope ratios are ²⁰⁶Pb / ²⁰⁴Pb = 19.46–19.64, ²⁰⁷Pb / ²⁰⁴Pb = 15.55–15.61, and ²⁰⁸Pb / ²⁰⁴Pb = 39.16–39.53. The overall variation of the Cumbre Vieja isotopic data can be accounted for by mixtures of three mantle components in the proportions 72–79% plume source (LVC = low velocity component), 9–16% depleted mantle (DM) and up to 12% enriched mantle (EMI). Negative Δ7 / 4 Pb (− 0.6 to − 5.4) in the Cumbre Vieja volcanics suggest derivation from a young HIMU mantle source. The relative abundance of plume source material increase in younger rocks in the Fuencaliente section, suggesting waning plume–lithosphere interaction during the emplacement of this part of the Cumbre Vieja volcano. The high-MgO volcanics define regular and systematic geochemical trends, interpreted as partial melting trends, when plotted against abundances of highly incompatible elements (P, Ce). Evaluation of minor and trace element variation in consecutive melts suggests control by residual amphibole, phlogopite, garnet and a Ti-bearing phase, possibly ilmenite. The melting mode changed gradually, allowing increasing input from residual phlogopite during partial melting. The residual mineralogy constrains the source region of the high-MgO basanites to the lowermost oceanic lithospheric mantle, presumably around 100 km depths.