Geochemistry and age of metamorphosed felsic igneous rocks with A-type affinities in the Willyama Supergroup, Olary Block, South Australia, and implications for mineral exploration

Leucocratic quartzofeldspathic gneisses form a significant proportion of the lower part of the Palaeoproterozoic Willyama Supergroup sequence in the Olary Block, South Australia and have correlatives in the adjacent Broken Hill Block. Field and geochemical data demonstrate that these rocks were originally rhyolitic volcanics and granite, with A-type affinities consistent with magma production during intracratonic rifting, supporting tectonic models proposed for the Willyama Supergroup in the Broken Hill Block. Although the rocks have characteristic high-field-strength element enrichment, many have undergone extensive pervasive pre- or syn-metamorphic sodic alteration and are typically rich in albite.

Sensitive high resolution ion microprobe (SHRIMP) U-Pb zircon data tightly constrain the depositional and early intrusive history. Zircons from an interpreted metavolcanic rock containing relict quartz phenocrysts yield an age of 1699 ± 10 Ma, whereas a metagranitoid sample has an age of 1703 ± 6 Ma. These results are compatible with recent geochronological data on felsic metavolcanic rocks from the Broken Hill Block (Page and Laing, 1992) and are indicative of widespread magmatism during deposition of the Willyama Supergroup. Nd signatures for the two Olary Block samples imply the presence of a significant component from a depleted mantle source.

The A-type metavolcanic rocks are locally associated with small iron formations, some of which grade into stratiform barite-rich horizons. Although potentially favourable for sediment-hosted exhalative PbZn mineralisation, the Fe- and Ba-rich units, along with transgressive vein and breccia occurrences of Fe oxides ± quartz ± pyrite cutting both the metavolcanic and metagranitoid rocks, may be more prospective for epigenetic Cu-Au mineralisation related to later metamorphic and/or magmatic events. Partial melting of the A-type suite during high grade regional metamorphism at ˜ 1600 ± 20 Ma led to the formation of local volumes of sodic granitoids and pegmatites containing U-Th-Ti-REE-F mineralisation.     

Correlation of the upper devonian rocks of Australia

A heavy mineral concentrate from the undeformed Mundi Mundi Granite N of Broken Hill yielded very few zircons. U‐Th‐Pb measurements on microgram fractions of those extracted showed no indication of the stock's true 1500–1600 Ma intrusive event but revealed something inherited and of an age probably greater than 2 Ga. These zircons, either survivors of those inherited from the magma source or accidental inclusions from the wall rocks, may either represent sedimentary accumulations in the lower Willyama Supergroup with an older craton source i.e. provenance, or indicate the presence of a pre‐Willyama Supergroup basement. Considerable loss of Pb from the zircons is deduced to have occurred at (1) the time of granite intrusion, (2) in the lower Palaeozoic, and, (3) in the case of ²⁰⁸Pb, probably right up to recent time.     

The Redan Geophysical Zone: Part of the Willyama Supergroup? Broken Hill,Australia

The Redan Geophysical Zone forms a regional magnetic high in contrast to the regional magnetic low defined by the main part of the Broken Hill Block. The magnetic rocks are interpreted to dip below the remainder of the Broken Hill Block and there has been speculation that they are significantly older than the Early Proterozoic Willyama Supergroup.

Evaluation of lithological mapping and aeromagnetic data permitted interpretation of a stratigraphic sequence within the Redan Geophysical Zone, consisting of three new formations: the Redan Gneiss, Ednas Gneiss and Mulculca Formation, plus the Lady Brassey Formation, part of the Thackaringa Group. The rocks are considered to belong to the lower part of the Willyama Supergroup and are not an older basement.

Although the Redan Geophysical Zone contains some rock types not found elsewhere in the Broken Hill Block, there are some lithological similarities with the lower part of the Willyama Supergroup: an abundance of albite‐rich rocks, the presence of quartz‐magnetite rocks with Cu and trace Co, and abundant amphibolite/ basic granulite in the Lady Brassey Formation.

The boundary between the Redan Geophysical Zone and the remainder of the Broken Hill Block appears to be conformable, with no evidence of major faulting. Similarly no evidence of unconformities or major displacement of stratigraphic boundaries has been found within the Redan Geophysical Zone. Structural history, fold style and orientation, and metamorphic grade within the Redan Geophysical Zone are similar to adjacent areas of the Broken Hill Block.

It is concluded that the Broken Hill Block contains no outcropping equivalent of the first cycle of sedimentary/ igneous rocks recognized in the Early Proterozoic of northern Australia.

Albite‐quartz‐hornblende‐magnetite rocks unique to the Redan Geophysical Zone most likely comprised detritus derived directly from an intermediate volcanic suite. Some were altered considerably, while other rocks retained the dacite/andesite composition, except for the addition of Na, an increase in the oxidation state, and partial leaching of some of the more mobile elements. These modifications could have taken place in shallow alkaline evaporitic lakes.

The Redan Geophysical Zone contains some of the elements of a foreland basin adjacent to a continental volcanic arc: a thick stratigraphic sequence, oxidizing evaporitic conditions, and intermediate volcanic detritus. The change from intermediate‐acid volcanism in the earliest formations, to bimodal acid/basic volcanism in the Thackaringa and Broken Hill Groups could correspond with a change from initial continental arc volcanism into bimodal rift volcanism. The case for the arc volcanism is weakened, however, by the relative scarcity of rocks with andesitic compositions and the lack of basaltic andesite compositions. The alternative is that the intermediate to acid volcanism represents only a variation on the later bimodal rift volcanism.     

Clay mineral,geochemical and Sr–Nd isotopic fingerprinting of sediments in the Murray–Darling fluvial system,southeast Australia

The Willyama Supergroup of the Broken Hill region in southern Australia consists of supracrustal sedimentary and magmatic rocks, formed between 1810 and 1600 Ma. A statistical analysis of nearly 2000 SHRIMP U–Pb zircon spot ages, compiled from published and unpublished sources, provides evidence for three distinct tectonostratigraphic successions and four magmatic events during this interval. Succession 1 includes Redan Geophysical Zone gneisses and the lower part of the Thackaringa Group (Cues Formation). These rocks were deposited after 1810 Ma and host granite sills of the first magmatic event (1710–1700 Ma). Succession 2 includes the upper Thackaringa Group (Himalaya Formation), the Broken Hill Group and the Sundown Group and was deposited between 1710 and 1660 Ma. These rocks all contain detrital zircons from the first magmatic event (1710–1700 Ma) and in some cases from the second magmatic event (1690–1680 Ma). The second magmatic event (1690–1680 Ma) was bimodal, resulted from crustal extension, and was coeval with deposition of the Broken Hill Group and deepening of the basin. With this event a mafic sill swarm focused in the Broken Hill Domain. Mafic sills lack any trace of inheritance, unlike the granitoids that commonly contain inherited zircons typical of the supracrustal sediments. Succession 3, the Paragon Group and equivalents were deposited after 1660 Ma, but before a regional metamorphic event at 1600 Ma. Metamorphism was closely followed by inversion of the succession into a fold‐and‐thrust belt, accompanied by a fourth late to post‐orogenic magmatic event (ca 1580 Ma) characterised by granite intrusion and regional acid volcanism (the local equivalents of the Gawler Range Volcanics in South Australia).     

U‐Pb zircon age for the Etheridge Group,Georgetown region,north Queensland: Implications for relationship with the Broken Hill and Mt Isa sequences*

The Einasleigh Metamorphics are the lowest exposed component of the Etheridge Group, part of the Etheridge Province, in the Georgetown region of north Queensland. Previous dating of granites has imposed a younger age limit of about 1550 Ma for the depositional age of the Etheridge Group. Based on SHRIMP U‐Pb analyses of zircon from mafic (1674.9 ±3.3 Ma and 1655.9 ±2.2 Ma) and felsic (1695.8 ± 1.5 Ma and 1684.2 ± 2.1 Ma) intrusive rocks in the Einasleigh Metamorphics, it can now be demonstrated that deposition commenced at about 1700 Ma, and continued for an estimated 100 million years. The stratabound, base‐metal deposits in the Mt Isa Inlier, Broken Hill Block and McArthur Basin formed in the early part of this time span, thereby suggesting potential for these styles of mineralisation in the Georgetown region.     

Evidence for multiple Palaeoproterozoic thermal events and magmatism adjacent to the Broken Hill Pb---Zn---Ag orebody, Australia

Thermal events at 1690-1680, 1660-1640 and 1600-1570 Ma have been resolved by SHRIMP U---Pb geochronological study on zircons and monazites from seven localities near to the Broken Hill Pb---Zn---Ag orebody, Australia. The earliest-recognized thermal event included intrusion of now deformed granites such as Rasp Ridge Gneiss and Alma Gneiss and intrusion of gabbro at Round Hill. Previously these have been interpreted as volcanic in origin, and have been assigned to different stratigraphic units of the Palaeoproterozoic Willyama Supergroup. Because these rocks are intrusions, they should be removed from the Supergroup stratigraphic sequence. The 1640–1660 Ma thermal event reached upper amphibolite to granulite conditions and produced melt segregations in parts of the Rasp Ridge Gneiss. Granites of this age are the Purnamoota Road Gneiss, previously correlated with 1690-1680 Ma rocks assigned to the Hores Gneiss stratigraphic unit, and granitic veins within Sundown Group metapelites. The 1600-1570 Ma thermal event also reached upper amphibolite to granulite conditions. The only possible 1600-1570 Ma intrusive rock reported in this study is ‘Lf-leucogneiss’ (granite) at the Purnamoota Road locality. Melt segregations of this age have been found in the Round Hill gabbro and metamorphic segregations have been found in the Purnamoota Road Gneiss. The granite intrusions and segregations are absolute time markers for fabric development and therefore can be used to re-evaluate tectonothermal evolution of rocks close to the Broken Hill Pb---Zn orebody. Within the studied rocks several discrete high grade deformation phases have been observed. The earliest detected deformation is older than 1640–1660 Ma, but syn- or post 1690 Ma. A later deformation phase can be constrained to be pre-or syn 1640–1660 Ma and a yet later deformation phase to be syn- or post- 1600-1570 Ma. The current consensus classifies the Broken Hill Pb---Zn---Ag orebody as the metamorphosed equivalent of classic SEDEX (sedimentary-exhalative) deposits, deposited at ca 1690 Ma. This interpretation heavily relies on the Hores Gneiss being a volcanic marker horizon, because the orebody is situated, apparently conformably, within the Hores Gneiss. However, results of this study show that rocks assigned to the Hores Gneiss are of different age, thus do not form a reliable marker horizon. The present results suggest that in the Thackaringa and Broken Hill Groups in the vicinity of Broken Hill, true supracrustal rocks are ≥ 1690 Ma, rather than ca 1690 Ma as previously suggested. Large parts of rocks surrounding the orebody are intrusions and together with their host supracrustal rocks were metamorphosed and locally remelted at 1660-1640 and 1600-1570 Ma.     

Evolution of the Proto-Tethys in the Baoshan block along the East Gondwana margin: constraints from early Palaeozoic magmatism

Zircon U–Pb ages and geochemical and isotopic data for Late Ordovician granites in the Baoshan Block reveal the early Palaeozoic tectonic evolution of the margin of East Gondwana. The granites are high-K, calc-alkaline, metaluminous to strongly peraluminous rocks with A/CNK values of 0.93–1.18, are enriched in SiO₂, K₂O, and Rb, and depleted in Nb, P, Ti, Eu, and heavy rare earth elements, which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed at ca. 445 Ma. High initial ⁸⁷Sr/⁸⁶Sr ratios of 0.719761–0.726754, negative ?_Nd(t) values of –6.6 to –8.3, and two-stage model ages of 1.52–1.64 Ga suggest a crustal origin, with the magmas derived from the partial melting of ancient metagreywacke at high temperature. A synthesis of data for the early Palaeozoic igneous rocks in the Baoshan Block and adjacent Tengchong Block indicates two stages of flare-up of granitic and mafic magmatism caused by different tectonic settings along the East Gondwana margin. Late Cambrian to Early Ordovician granitic rocks (ca. 490 Ma) were produced when underplated mafic magmas induced crustal melting along the margin of East Gondwana related to the break-off of subducted Proto-Tethyan oceanic slab. In addition, the cession of the mafic magmatism between late Cambrian-Early Ordovician and Late Ordovician could have been caused by the collision of the Baoshan Block and outward micro-continent along the margin of East Gondwana and crust and lithosphere thickening. The Late Ordovician granites in the Baoshan Block were produced in an extensional setting resulting from the delamination of an already thickened crust and lithospheric mantle followed by the injection of synchronous mafic magma.     

Stratigraphic subdivision and correlation of the upper part of the Willyama Complex,New South Wales

Within the complexly deformed and metamorphosed middle Precambrian Willyama Complex in western New South Wales, two distinct sedimentary sequences are recognized at the top of the succession. The fine‐grained carbonaceous Bijerkerno Beds conformably overlie a very thick psammopelitic unit termed the Wookookaroo Beds. These two sequences record different depositional histories, though they probably have similar source areas. The base of the Wookookaroo Beds is terminated against a significant tectono‐stratigraphic boundary, which may represent a major stratigraphic break within the Willyama Complex. Beneath this boundary, felsic and mafic gneisses and high‐grade metasediments are correlated with mine‐sequence rocks such as are developed within the vicinity of the main Broken Hill lode. Correlations between the stratigraphy, as established at Bijerkerno, and other areas from the Willyama Complex, help provide a fuller understanding of this Precambrian terrain.     

Cathaysian slivers in the Philippine island arc: geochronologic and geochemical evidence from sedimentary formations of the west Central Philippines

The use of geodynamic information contained in sedimentary rocks has only recently been extended into the tectonic reconstruction studies of the Philippine archipelago vis-à-vis the rest of the Southeast Asian region. We present here a comparative assessment of clastic units from the western Central Philippines, particularly from the islands of Mindoro, Panay and Palawan, and propose their likely association with sources of Cathaysian origin. Geochronological data from sedimentary formations in the study areas register U–Pb dating peaks at 185–140 Ma, 140–120 Ma and 112–90 Ma. These are similar to those observed of detrital zircons from rocks of Cathaysian origin in Taiwan and Southern China that chronicle the Yanshanian magmatic events. These same formations also record an older intercept at 1.9–1.85 Ga that likely corresponds to a regional continental orogenic episode recorded in the late Paleoproterozoic Cathaysian block. Major (e.g. Al₂O₃/TiO₂) and trace-element (e.g. Y/Ni vs Cr/V) signatures of these sedimentary formations reflect stronger influences from granitic sources than mafic–ultramafic inputs that should otherwise be expected, considering their current oceanic island arc settings. Their La/Th and Th–Co–Zr/10 ratios also reveal continental island arc and active or passive continental margin depositional settings typical of rocks from the Palawan Microcontinental Block. New geochronological and geochemical data from the clastic rocks of northwest Mindoro, in addition to those already published for the other regions of the Palawan Microcontinental Block, provide further evidence for the amalgamation of fragments of Cathaysian origin within the Philippine island arc system.     

A structural metamorphic study of the Broken Hill Block, NSW, Australia

The prograde pressure–temperature (P–T) path for the complexly polydeformed Proterozoic Broken Hill Block (Australia) has been reconstructed through detailed structural analysis in conjunction with calculation of compositionally specific P–T pseudosections of pelitic rock units within a high‐temperature shear zone that formed early in the tectonic evolution of the terrane. Whilst the overall P–T path for the Broken Hill Block has been interpreted to be anticlockwise, the prograde portion of this path has been unresolved. Our results have constrained part of this prograde path, showing an early heating event (M1) at P–T conditions of at least c. 600 °C and c. 2.8–4.2 kbar, associated with an elevated geothermal gradient (c. 41–61 °C km^?1). This event is interpreted to be the result of rifting at c. 1.69–1.67 Ga, or at c. 1.64–1.61 in the Broken Hill Block. Early rifting was followed by an episode of lithospheric thermal relaxation and burial, during which time sag‐phase sediments of the upper Broken Hill stratigraphy (Paragon Group) were deposited. Following sedimentation, a second tectonothermal event (M2/D2) occurred. This event is associated with peak low‐pressure granulite facies metamorphism (c. 1.6 Ga) and attained conditions of at least 740 °C at c. 5 kbar. A regionally pervasive, high‐temperature fabric (S2) developed during the M2/D2 event, and deformation was accommodated along lithology‐parallel, high‐temperature shear zones. The larger‐scale deformation regime (extensional or shortening) of this event remains unresolved. The M2/D2 event was terminated by intense crustal shortening during the Olarian Orogeny, during which time the first mappable folds within the Broken Hill Block developed.     

Retrograde Schists of the Amphibolite Facies at broken hill,New South Wales

Aluminous, mafic, felsic, calcareous, and sulphide‐rich rocks have been involved in localized deformation and retrograde metamorphism at Broken Hill, western New South Wales, where retrograde schist‐zones intersect high‐grade, regional metamorphic rocks of the lower granulite facies (or the amphibolite‐granulite facies transition). Although technically retrograde, the schists contain mineral assemblages indicative of the lower amphibolite facies. The schist‐zones were formed by local folding, apparently as part of the third stage of deformation in the Broken Hill area.     

Geochemistry and zircon U–Pb–Hf isotopes of the 780 Ma I-type granites in the western Yangtze Block: petrogenesis and crustal evolution

ABSTRACT

Neoproterozoic I-type granites could provide vital insights into the crust–mantle interaction and the crustal evolution along the western Yangtze Block, South China. This paper presents new zircon U–Pb ages, bulk-rock geochemistry, and in situ zircon Lu–Hf isotope on the Dalu I-type granites from the southwestern Yangtze Block. Zircon U–Pb dating show the crystallization ages of 781.1 ± 2.8 Ma for granodiorites and 779.8 ± 2.0 Ma for granites, respectively. The Dalu granodiorites are Na-rich, calc-alkaline, metaluminous to slightly peraluminous (A/CNK = 0.94–1.08). Zircons from granodiorite have positive εHf(t) values (+2.16 to +7.39) with crustal model ages of 1.21–1.54 Ga, indicating juvenile mafic lower crust source. The Dalu granites are high-K calc-alkaline, peraluminous rocks. They have variable zircon εHf(t) values (?4.65 to +5.80) with crustal model ages of 1.31–1.97 Ga, suggesting that they were derived from the mature metasediment-derived melts by the mixing of newly formed mafic lower crust-derived melts. The geochemical variations in Dalu pluton is dominated not only by the different source rocks but also by the different melting temperatures. Combining with the geochemistry and isotopic compositions of I-type granitoids and tectonic setting in the western Yangtze Block, we propose that the Dalu I-type granodiorites–granites associations are the magmatic response from different crustal levels, which were induced by the heat anomaly due to the asthenosphere upwelling in the subduction-related setting.     

Episodic shear zone associated fluid flow in the Curnamona Province, South Australia

Two distinct generations of fluid flow associated with shear zone activity have been identified in Willyama Supergroup rocks of the southern Curnamona Province in northeastern South Australia. Fluids in the first event are inferred to have been sourced from the devolatilisation of Willyama Supergroup metasedimentary rocks during prograde metamorphism associated with the (1.61–1.58 Ga) Mesoproterozoic Olarian Orogeny. The second episode of fluid flow occurred during the (c. 500 Ma) Cambrian Delamerian Orogeny and resulted in localised rehydration of the Willyama Supergroup. Fluids were isotopically light and most likely sourced from prograde Delamerian metamorphism and dehydration of fault rocks and entrained meteoric waters that originally were involved in (c. 700 Ma) Neoproterozoic Adelaidean rifting. A key outcome of this study is the identification of this previously unrecognised fluid flow system that was active during the Delamerian Orogeny.     

Stratiform and stratabound tungsten mineralisation in the Broken Hill Block,N.S.W.

The Early‐Middle Proterozoic Broken Hill Block contains three types of W occurrences, which show close stratigraphic control. All three types occur within a relatively narrow stratigraphic interval (the ‘Mine Sequence’ Suite of Stevens et al., 1980) comprising a highly variable group of metamorphosed silicic and mafic volcanics, clastic sediments, and exhalative and chemical sediments containing base metals. The first type includes occurrences of W and base metals in bedded calc‐silicate rocks. In the second type, W occurs in layered to non‐layered calcsilicate rocks associated with amphibolite; these are intimately associated in a narrow stratigraphic interval containing abundant, small, Broken Hill type deposits. The third type comprises stratabound, W‐bearing pegmatites, which have been remobilised from quartz‐feldspar‐biotite gneiss and bedded quartz‐tourmaline rocks. Tungsten has been mined only from the third type and only in small quantities. The three types of tungsten deposits show a close spatial relationship with stratiform and stratabound Pb‐Zn mineralisation, including the Broken Hill type. The Pb‐Zn and W deposits are inferred to be genetically related.     

Continental ca 1.7 – 1.69 Ga Fe-rich metatholeiites in the Curnamona Province,Australia: a record of melting of a heterogeneous,subduction-modified lithospheric mantle

Mg-rich and Fe-rich metatholeiites intruded the Willyama Supergroup of the southern Australian Curnamona Province in the Late Palaeoproterozoic at ca 1700 Ma and 1685 Ma, respectively. Intrusion of the Fe-rich metatholeiites occurred during a period of punctuated extension in the Willyama basin. Major-element concentrations are variable (SiO₂ 45.4 – 56.5 wt%; Fe₂O₃? 8.5 – 20.7; TiO₂ 0.46 – 2.52 wt%; Mg# 70.5 – 29.1) and, in conjunction with trace-element data, support near-closed-system fractionation of a mantle-derived melt with little or no replenishment. Fractionation produced progressively Fe-rich derivative melts. Crystallising phases were dominated by clinopyroxene and olivine, whereas Fe – (Ti) oxide crystallisation was hindered. Primitive mantle-normalised immobile trace elements are characterised by variable Th, Nb, Sr, P and Ti anomalies. Chondrite-normalised rare-earth element patterns for the most primitive, Mg-rich samples from the western Broken Hill Domain have La_N/Sm_N < 1, whereas the most evolved Fe-rich samples from the Olary Domain have ratios of La_N/Sm_N > 1. Initial εNd values range between – 2.2 and + 2.7 for the majority of the samples, with the isotopic compositions showing no correlation with differentiation or assimilation. The combined geochemical and isotopic data suggest that the southern Curnamona Province metatholeiites were extracted from a depleted mantle in the western Broken Hill Domain, and a variably enriched, heterogeneous subcontinental lithospheric mantle in the Olary Domain. Magmatism most likely occurred in a backarc basin or intracontinental setting. It is speculated that the geochemically enriched mantle component was derived from subduction-related processes, probably related to pre-Willyama basin accretionary processes along the southern and eastern margins of the North Australian Craton.     

Geochronological constraints on early volcanic evolution of the Pilbara Block,Western Australia

U‐Pb isotopic systems of zircons from the Boobina and Spinaway Porphyries from the Precambrian Pilbara Block of Western Australia indicate ages of 3307± 19 Ma and 2768 ± 16 Ma, respectively. The Boobina Porphyry intrudes upper members of the Archaean greenstones of the Warrawoona Group. The Spinaway Porphyry intrudes basal units of the unconformably overlying volcanics and sediments of the Mt Bruce Supergroup. The age of the Boobina Porphyry, together with previous zircon U‐Pb and whole rock Sm‐Nd age determinations on stratigraphically older units, indicate that early Archaean volcanism in the Pilbara took place between 3560 Ma and 3300 Ma. On the basis of the age determination of the Spinaway Porphyry, and the chronometric definition of 2500 Ma for the Archaean—Proterozoic boundary, by the International Subcommis‐sion on Precambrian Stratigraphy (James H. L. 1978, Precambrian Res. 7, 193–204), the lower units of the Mt Bruce Supergroup should now be assigned to the Archaean.     

Petrogenesis and Geodynamic Implications of Late Jurassic Diorite Porphyry in the Neoproterozoic Ophiolitic Mélange of NE Jiangxi (South China)

Mesozoic magmatism is widespread in the eastern South China Block and has a close genetic relationship with intensive polymetallic mineralization. However, proper tectonic driver remains elusive to reconcile the broad intracontinental magmatic province. This study presents integrated zircon U-Pb dating, Hf isotopes and whole-rock geochemistry of the Xiwan dioritic porphyry in the NE Jiangxi ophiolitic mélange. Zircon U-Pb dating by SIMS and LA-ICP-MS methods yielded an emplacement age of ～160 Ma for the Xiwan diorite, confirming its inclusion into the Mesozoic magmatic province in SE China, instead of a component of the Neoproterozoic ophiolitic mélange genetically. The dioritic rocks have low Si02(58.08 wt%-59.15 wt%), and high Na_2 O(5.00 wt%-5.21 wt%) and MgO(4.60 wt%-5.24 wt%) contents with low TFeO/MgO ratios(1.02-1.09). They show an adakitic geochemical affinity but exhibit relatively low Sr/Y ratios(24.8-31.1) and high Y contents(14.6-18.3 ppm) compared to the Dexing adakitic porphyries. In addition, the Xiwan diorites have moderately evolved zircon Hf isotopic compositions(ε_(Hf)(t)=-6.1--0.1; T_(DM2)=1597-1219 Ma). These elemental and isotopic signatures suggest that the Xiwan diorite formed through partial melting of a remnant arc lower crust(i.e., early Neoproterozoic mafic arc-related rocks) in response to the underplating of coeval mafic magmas. In conjunction with the temporal-spatial distribution and complex geochemical characteristics of the Mesozoic magmatism, our case study attests to the feasibility of a flat-slab subduction model in developing the broad intracontinental magmatic province in SE China. The flat-slab delamination tends to trigger an asthenospheric upwelling and thus results in extensive partial melting of the overlying lithospheric mantle and lower crustal materials in an extensional setting during the Mesozoic.     

Convergence History of the Songliao and Jiamusi Blocks in the Eastern End of Central Asian Orogenic Belt: Evidence from Detrital Zircons of Late Paleozoic Sedimentary Rocks

Central Asian Orogenic Belt(CAOB) is one of the largest accretionary orogenic belts in the world. The eastern segment of CAOB is dominated by Paleozoic Paleo Asian Ocean tectonic regime, Mesozoic Paleo-Pacific tectonic regime and Mongolian-Okhotsk tectonic regime. The Songliao and Jiamusi blocks are located in the easternmost part of the CAOB and are the key region to solve the problem about overprinting processes of multiple tectonic regimes. It is generally believed that the Mudanjiang Ocean between the two blocks was finally closed in the Mesozoic, but the Paleozoic magmatism also developed along the Mudanjiang suture zone, while on both sides of the suture zone, there were comparable Paleozoic strata, indicating that the two blocks had converged during the Paleozoic, and the evolution history of the two blocks in the Late Paleozoic remains controversial. The Carboniferous-Permian terrestrial strata mainly developed in Binxian, Wuchang and Tieli on Songliao Block, Baoqing and Mishan on Jiamusi Block. Samples from the Songliao and Jiamusi blocks in the Late Carboniferous-Early Permian and Late Permian are collected for comparative analysis. The LAICP-MS zircon U-Pb dating results show that the maximum depositional age of Middle Permian Tumenling Formation and Late Permian Hongshan Formation in Songliao Block is ～260 Ma, while that of Tatouhe Formation and Carboniferous strata in Jiamusi Block are ～290 Ma and ～300 Ma, respectively, which supports the previous stratigraphic division scheme. The age peaks of ～290–300 Ma, ～400 Ma, ～500 Ma appeared in the Late Carboniferous to Early Permian strata of Jiamusi Block and the Middle Permian strata of Songliao Block. The age peak of ～500 Ma in the Middle Permian strata of Songliao Block may come from the Cambrian basement, Mashan Complex, of Jiamusi Block, while the age peaks of ～420–440 Ma in the Carboniferous strata of Jiamusi Block may come from the Silurian magmatic arc in Zhangguangcai Range in the eastern margin of Songliao Block, reflects the history that they had been potential sources of each other, indicating that they may have combined in the Paleozoic. The Hongshan Formation of Songliao Block in the Late Permian lacks the age peak of ～500 Ma, which indicate that Jiamusi Block was not the provenance of Songliao Block in the Late Permian, that is, there was a palaeogeographic isolation between the two blocks. Combined with the ～210 Ma bimodal volcanic rocks developed along the Mudanjiang suture zone reported previously, we believe that the oceanic basin between the Songliao and Jiamusi blocks should have been connected in Late Permian and reopened during Late Permian to Late Triassic.     

Mineral distribution and provenance of heavy mineral sands (zircon,ilmenite, rutile) deposits from the NW Murray Basin,far western NSW,Australia

Abstract

There is significant economic interest in the Murray Basin of southeastern Australia as it is proving to be a major heavy mineral sands (HMS) province that will be one of Australia’s major source for production of rutile, zircon and ilmenite. The distribution and provenance of HMS resources in the Murray Basin is poorly understood because of its huge size, limited exploration and the complex depositional, structural and weathering mechanisms in their development. In this paper, we focus on the Copi North and Magic deposits some 130–180?km south of Broken Hill, NSW. The heavy mineral assemblages of the Copi North and Magic deposits are very similar, with the main economic minerals being ilmenite, leucoxene, pseudorutile, rutile and zircon. Intensive fracturing and brecciation are identified in many samples and are inferred to have been initially caused by multi-stage deformational processes associated with metamorphism and then further developed through alluvial and eolian transportation. Both deposits are classified as ‘medium sands, symmetrical, mesokurtic and moderately well-sorted’. The majority of economic minerals are of low to medium sphericity and subrounded, along with abundant polished eolian quartz grains. The Copi North deposit has coarser and more poorly sorted sediments with higher HMS grades and magnetics content than the Magic deposit, reflecting a higher energy depositional environment. The main source for the HMS for the Copi North and Magic deposits is largely ascribed to the Broken Hill Block. Previous studies have shown that the Broken Hill orebody underwent substantial sub-aerial weathering over hundreds of millions of years. In addition, the complex metamorphic events experienced by the Broken Hill Block were capable of forming the broad series of minerals identified within the Copi North and Magic deposits. The HMS were believed to have been transported through paleovalleys near the Mulculca Fault in a southeast direction representing a feeder system into the NW Murray Basin. Both deposits feature a relatively linear geometry (roughly parallel to the strike of the paleoshoreline), with high HMS grades, modest tonnages, and coarser sediments when compared to WIM-style offshore deposits. Compared to other strandline HMS deposits of the Murray Basin, they are smaller in size although have similar high grades of 3.7–6.9% THM and similar proportions of the HMS assemblage of ilmenite, leucoxene, rutile and zircon. Deposits of similar size and grade are likely to occur throughout the northern part of the Murray Basin.

1. KEY POINTS

2. Both the Copi North and Magic deposits contain similar mineral assemblages with the provenance of the heavy minerals ascribed to the Broken Hill Block.

3. A relatively high energy inshore environment is inferred for the Copi North deposit while a lower energy environment associated with either a foreshore or backshore environment is inferred for the Magic deposit.

4. Deposits of similar mineralogy, grades and size are likely to occur elsewhere throughout the northern Murray Basin.

     

Aspects of the structural and late thermal evolution of the Redbank Thrust system,central Australia: Constraints from the Speares Metamorphics

We present new data on the field geology and late thermal evolution of the Redbank Thrust system in the Arunta Block of central Australia. Geochronological and field data from the Speares Metamorphics are also used to relate the thermal evolution of the Redbank Thrust system to the structural evolution of the region. We show that several stages in the evolution might be discerned. An originally sedimentary sequence was intruded by mafic intrusions and then deformed during partial melting to form the principal foliation observed in the region (D1). This sequence was then folded during D2 into upright folds with north‐ to northeast‐plunging fold axes. These events are likely to correlate with the Strangways and/or Argilke and Chewings Orogenies known from previous studies. Subsequently, the Redbank Thrust was initiated during D3. This event is recognised by deflection of the host rocks into the shear zone and might therefore have been associated with a component of strike‐slip motion. It occurred probably at or before 1500–1400 Ma. Subsequent north‐over‐south thrust motion in the Redbank Thrust formed the intense mylonitic fabric and folded the mylonitic fabric during D4 into asymmetric folds with shallow fold axes. New ⁴⁰Ar/³⁹Ar K‐feldspar ages from three samples collected from variably deformed branches of the Redbank Thrust and undeformed rocks in the Speares Metamorphics suggest that most parts of the Redbank Thrust system cooled relatively slowly after metamorphism and deformation in the Mesoproterozoic so that the D4 thrusting might have been very long‐lived. Minimum ages of the K‐feldspar age spectra show that the entire region cooled below 200°C by approximately 300 Ma. Apatite fission track ages from nine samples show that cooling through the apatite partial annealing zone occurred during Cretaceous time (ca 150–70 Ma) and modelled cooling histories are consistent with the cooling rates obtained from the K‐feldspar data. They indicate that final exhumation of the Redbank Thrust system occurred probably in response to erosion, possibly driven by rifting around the margins of Australia.