Neoarchaean impact spherule layers in the Fortescue and Hamersley Groups,Western Australia: stratigraphic and depositional implications of re-correlation

Previously, two layers containing impact melt spherules, the Wittenoom spherule layer and the Carawine spherule layer, exposed in the main outcrop area and Oakover River area, respectively, of the Neoarchaean?–?Palaeoproterozoic Hamersley Basin of Western Australia, were correlated. Subsequent discovery and study of the Jeerinah spherule layer in the main outcrop area, as well as a new Carawine spherule layer exposure now suggest that the Carawine and Jeerinah spherule layers are correlates. The previous Wittenoom?–?Carawine correlation was based on the presence of spherules and sedimentological consistency: both layers comprise sediment gravity flows, and the Wittenoom spherule layer was interpreted as the downflow equivalent of the Carawine layer. However, the Jeerinah spherule layer also consists of sediment gravity flows, which could be related to the Carawine layer. Since all three layers reflect events triggered by oceanic impacts, these similarities are not surprising, but they do eliminate sedimentology as a correlation tool. However, two compositional trends suggest that the Carawine and Jeerinah layers are correlates: (i) the textures of their spherules are very similar and are distinctly different from the Wittenoom layer; and (ii) only the Carawine and Jeerinah layers contain irregular impact melt particles. The latter observation is strong evidence as irregular particles are unknown in any other early Precambrian spherule layers in Western Australia. While triggered by the same impact, it is unlikely that the Carawine and Jeerinah spherule layers were deposited by the same sediment gravity flows, as they contain very different intraclast populations.     

The Cretaceous–Palaeogene boundary at Gorgonilla Island,Colombia, South America

The discovery of a new Cretaceous/Palaeogene (K/Pg) bathyal marine sequence on Gorgonilla Island, SW Colombia, extends the presence of Chicxulub impact spherule deposits to the Pacific region of northern South America and to the Eastern Pacific Ocean. The Gorgonilla spherule layer is approximately 20 mm thick and consists of extraordinarily well‐preserved glass spherules up to 1.1 mm in diameter. About 70–90% of the spherules are vitrified, and their chemical composition is consistent with Haiti (Beloc) impact glass spherules. Normal size‐grading, delicate spherule textures, welded melt components and an absence of bioturbation or traction transport suggest that the Gorgonilla spherule layer represents an almost undisturbed settling deposit.     

Discovery of Cosmic Spherules from the Mesoproterozoic Strata and its Significance—in Case of the Ming Tombs Area, Beijing

This study covers cosmic spherules derived from the Mesoproterozoic Dahongyu Formation in the Ming Tombs area, Beijing. The cosmic spherules include iron oxide cosmic spherules, carbonaceous chondrites, and atomic iron “steely bead”-shaped cosmic spherules. The mineral assemblage of silicon carbide, forsterite, zircon, and glass spherules and fragments were picked from melt-silicified carbonate of the Mesoproterozoic Dahongyu Formation (ca. 1625 Ma). Cosmic spherule assemblages are solely discovered from sedimentary rocks in China. Platinum group elements (PGE) were determined for the first time in cosmic spherules and associated minerals. PGE comparative observation between meteorite and cosmic spherules is presented in this study. It is recognized that an extraterrestrial meteorite impact event might have occurred in the Dahongyu Stage. The main evidence is a large number of iron cosmic spherules in silicified oncolitic limestone, and associated cosmic silicon carbide, glass spherules, and fragments, as well as the presence of forsterite. The impact-volcanic crater is characteristic of a big black shale block dropped into the bended silicified limestone.     

A dual-layer Chicxulub ejecta sequence with shocked carbonates from the Cretaceous-Paleogene (K-Pg) boundary, Demerara Rise, western Atlantic

An up to ∼2-cm thick Chicxulub ejecta deposit marking the Cretaceous-Paleogene (K-Pg) boundary (the “K-T” boundary) was recovered in six holes drilled during ODP Leg 207 (Demerara Rise, tropical western Atlantic). Stunning features of this deposit are its uniformity over an area of 30 km² and the total absence of bioturbation, allowing documentation of the original sedimentary sequence. High-resolution mineralogical, petrological, elemental, isotopic (Sr-Nd), and rock magnetic data reveal a distinct microstratigraphy and a range of ejecta components. The deposit is normally graded and composed predominantly of rounded, 0.1- to max. 1-mm sized spherules. Spherules are altered to dioctahedral aluminous smectite, though occasionally relict Si-Al-rich hydrated glass is also present, suggesting acidic precursor lithologies. Spherule textures vary from hollow to vesicle-rich to massive; some show in situ collapse, others include distinct Fe-Mg-Ca-Ti-rich melt globules and lath-shaped Al-rich quench crystals. Both altered glass spherules and the clay matrix (Site 1259B) display strongly negative values (−17) indicating uptake of Nd from contemporaneous ocean water during alteration. Finally, Fe-Mg-rich spherules, shocked quartz and feldspar grains, few lithic clasts, as well as abundant accretionary and porous carbonate clasts are concentrated in the uppermost 0.5-0.7 mm of the deposit. The carbonate clasts display in part very unusual textures, which are interpreted to be of shock-metamorphic origin. The preservation of delicate spherule textures, normal grading with lack of evidence for traction transport, and sub-millimeter scale compositional trends provide evidence for this spherule deposit representing a primary air-fall deposit not affected by significant reworking.The ODP Leg 207 spherule deposit is the first known dual-layer K-Pg boundary in marine settings; it incorporates compositional and stratigraphic aspects of both proximal and distal marine sites. Its stratigraphy strongly resembles the dual-layer K-Pg boundary deposits in the terrestrial Western Interior of North America (although there carbonate phases are not preserved). The occurrence of a dual ejecta layer in these quite different sedimentary environments - separated by several thousands of kilometers - provides additional evidence for an original sedimentary sequence. Therefore, the layered nature of the deposit may document compositional differences between ballistic Chicxulub ejecta forming the majority of the spherule deposit, and material falling out from the vapor (ejecta) plume, which is concentrated in the uppermost part.     

Trace element concentrations in silicate spherules from oceanic sediments

The possible existence of meteoritic spherules was investigated among several silicate spherules separated from oceanic sediments and analyzed by means of INAA (instrumental neutron activation analysis).A 0.72 mg glassy spherule was found to have uniform enrichment of 4 ~ 5 for the refractory REE (rare earth elements) and Sc with substantial depletion of Ce relative to chondritic abundances. This implies that this spherule is meteoritic in origin and that the enrichment of refractory elements was established by high temperature heating in a high O/H environment, possibly at the time of entering the Earth's atmosphere.The other three analyzed spherules showed major and trace element abundances that are consistent with an origin in the oceanic environment.     

Geochemistry of Cenozoic microtektites and clinopyroxene-bearing spherules

We have determined the major and trace element compositions of 176 individual microtektites/spherules from the Australasian, Ivory Coast, and North American microtektite and clinopyroxene-bearing (cpx) spherule layers. Trace element contents for up to 30 trace elements were determined by instrumental neutron activation analysis (INAA), and major element compositions were determined using energy dispersive X-ray (EDX) analysis in combination with a scanning electron microscope (SEM). In addition, petrographic data were obtained for the cpx spherules using the SEM and EDX. This is the first trace element study of individual Australasian microtektites, and the data revealed the presence of a previously unrecognized group of Australasian microtektites with high contents of Ni (up to 471 ppm). In previous studies the high-Mg (HMg) Australasian microtektites were thought to be related to the HMg Australasian tektites, but our trace element data suggest that the high-Ni (HNi) Australasian microtektites, rather than the high-Mg microtektites, are related to the high-Mg Australasian tektites. We find that Cenozoic microtektites/spherules from a given layer can be distinguished from microtektites/spherules from other layers as a group, but it is not always possible to determine which layer an individual microtektite/spherule came from based only on trace element compositions. The cpx spherules and most of the microtektites have Cr, Co, and Ni contents that are higher than the average contents of these elements in the upper continental crust, suggesting the presence of a meteoritic component. The highest Cr, Co, and Ni contents are found in the cpx spherules (and low-Si cpx-related microtektites). Unetched to slightly etched cpx spherules have Ni/Cr and Ni/Co ratios that generally lie along mixing curves between the average upper continental crust and chondrites. The best fit appears to be with an LL chondrite. The moderately to heavily etched cpx spherules have values that lie off the mixing curves in a direction that suggests Ni loss, probably as a result of solution of a Ni-rich phase (olivine?). The Ni-rich Australasian microtektites also have Ni values that lie close to mixing curves between the average upper continental crust and chondrites. However, both the cpx spherules and HNi Australasian microtektites appear to have Ir (and to a lesser extent Au) contents that are much too low to have Ni/Ir ratios similar to chondritic values. We have no explanation for the low-Ir and -Au contents except to speculate that they may be the result of a complex fractionation process. The Ivory Coast and North American microtektites do not have high enough siderophile element contents to reach any firm conclusions regarding the presence of, or nature of, a meteoritic component in them. Trace element compositions are consistent with derivation of the Cenozoic microtektite/spherule layers from upper continental crust. The normal Australasian microtektites appear to have been derived from a graywacke or lithic arenite with a range in clay and quartz content. The source rock for the high-Mg Australasian microtektites is not known, but the HMg microtektites do not appear to be normal Australasian microtektites that were simply contaminated by meteorites or ultramafic rocks. The average Ivory Coast microtektite composition can be matched with a mixture of target rocks at the Bosumtwi crater. The average composition of the North American microtektites suggests an arkosic source rock, but with graywacke and quartz-rich end members. However, we could not match the composition of the North American microtektites with lithologies in impact breccias recovered from the Chesapeake Bay impact structure that is believed to be the source crater. Likewise, we could not match the composition of the cpx spherules with mixtures of basement rocks and overlying sedimentary deposits (for which compositional data are available) at the Popigai impact crater that may be the source crater for the cpx spherules. This may be because the cpx spherules were derived, in large part, from clastic surface rocks (sandstones and shales) for which no compositional data are available.     

Ordinary chondrite-related giant (>800 μm) cosmic spherules from the Transantarctic Mountains, Antarctica

In order to identify the parent bodies of cosmic spherules (melted micrometeorites) with porphyritic olivine (PO) and cryptocrystalline (CC) textures, we measured the oxygen isotopic composition of 15 giant (>800 μm) cosmic spherules recovered in the Transantarctic Mountains, Antarctica, with IR-laser fluorination/mass spectrometry, and we conducted a characterization of their petrographic and magnetic properties. Samples include 6, 8 and 1 spherules of PO, CC and barred olivine (BO) textural types, respectively. Eleven spherules (∼70% of the total: 4/6 PO and 6/8 CC, and the BO spherule) are related to ordinary chondrites based on oxygen isotopic compositions. Olivines in ordinary chondrite-related spherules have compositions Fa_8.5-11.8, they are Ni-poor to Ni-rich (0.04-1.12 wt.%), and tend to be richer in CaO than other spherules (0.10-0.17 wt.%). Ordinary-chondrite related spherules also have high magnetite contents (∼2-12 wt.%). One PO and one CC spherules are related to previously identified ¹⁷O-enriched cosmic spherules for which the parent body is unknown. One CC spherule has an oxygen isotopic signature relating it to CM/CR carbonaceous chondrites. The majority of PO/CC cosmic spherules derive from ordinary chondrites; this result exemplifies how the texture of cosmic spherules is not only controlled by atmospheric entry heating conditions but also depends on the parent body, whether be it through orbital parameters (entry angle and velocity), or chemistry, mineralogy, or grain size of the precursor.     

Tsunami backwash deposits with Chicxulub impact ejecta and dinosaur remains from the Cretaceous–Palaeogene boundary in the La Popa Basin,Mexico

The La Popa Basin in north‐eastern Mexico features outstanding, continuous three‐dimensional exposures of the Cretaceous–Palaeogene boundary event deposit in shallow shelf environments pierced by salt stocks. In the area to the south‐east of the El Papalote diapir, the Cretaceous–Palaeogene deposit consists of two superimposed sedimentary units and erosively overlies upper Maastrichtian sand‐siltstones with soft‐sediment deformation and liquefaction structures. The basal unit 1 is an up to 8 m thick chaotic, carbonate‐rich bed that discontinuously fills incised gutters and channels. Besides abundant silicic and carbonate ejecta spherules from the Chicxulub impact, unit 1 includes large sandstone boulders and abundant shallow‐water debris (for example, mud clasts, algae, bivalve shells, gastropod shells and vertebrate remains). Unit 1 is conformably overlain by unit 2. Distal to the diapir, unit 2 consists of a centimetre to decimetre‐thick conglomeratic, coarse bioclast and spherule‐bearing sandstone bed. Closer to the diapir, unit 2 becomes a metre‐thick series of four to eight conglomeratic to fine‐grained graded sandstone beds rich in shell debris and ejecta spherules. Unit 2 is conformably overlain by structureless to parallel laminated sandstone beds that may mark the return to the pre‐event depositional regime. The sedimentary characteristics of the Cretaceous–Palaeogene deposit, including its erosive base, its sheet‐like geometry, the presence of multiple, graded beds, evidence for upper flow regime conditions and the absence of bioturbation, support an origin by a short‐term multiphase depositional event. The occurrence of soft‐sediment deformation structures (for example, liquefaction) below the Cretaceous–Palaeogene deposit suggests that earthquakes were the first to occur at La Popa. Then, shelf collapse and strong backflow from the first tsunami waves may have triggered erosion and deposition by violent ejecta‐rich hyperconcentrated density flows (unit 1). Subsequently, a series of concentrated density flows resulting from tsunami backwash surges may have deposited the multiple‐graded bedding structures of unit 2. The specific depositional sequence and the Fe‐Mg‐rich as well as Si‐K‐rich composition of the ejecta spherules both provide a critical link to the well‐known deep marine Cretaceous–Palaeogene boundary sites in the adjacent Burgos basin in north‐eastern Mexico. Moreover, the pulse‐like input of Chicxulub ejecta material at the base of the event deposit allows for correlation with other Cretaceous–Palaeogene boundary sites in the Gulf of Mexico and the Atlantic, as well as in Central and Northern America. The presence of diverse dinosaur and mosasur bones and teeth in the event deposit is the first observation of such remains together with Chicxulub ejecta material. These findings indicate that dinosaurs lived in the area during the latest Maastrichtian and suggest that the tsunami waves not only eroded deltas and estuaries but the coastal plain as well.     

Fe-rich and K-rich mafic spherules from slumped and channelized Chicxulub ejecta deposits in the northern La Sierrita area,NE Mexico

Spherule deposits, commonly interpreted as ejecta from the Chicxulub impact at Yucatán, Mexico, are present in many K-T (Cretaceous-Tertiary) sections. Geological mapping of the northern La Sierrita area, NE Mexico, revealed the presence of (1) multiple spherule deposits embedded in late Maastrichtian marls, which are folded or disaggregated (breccia-like). They are up to 6 m thick, locally present in two outcrop areas, and show limited lateral continuity. These deposits consist of mm-cm sized spherical to drop-shaped vesiculated spherules, angular to filamentous (ejecta-) fragments and abundant carbonate. They are interpreted as primary ejecta fallout deposits that have been affected by subsequent local slumps-slides, liquefaction, and debris flows; welded components suggest an initial ground surge-like ejecta-dispersion mode. (2) A spherule deposit, 10-60 cm thick that constitutes the base of a channelized sand-siltstone deposit at, or close to, the K-T boundary and is characterized by wide lateral continuity. It is of similar petrologic composition to deposit (1), though slightly enriched in terrigeneous detritus, thus reflecting influx from proximal shelf areas. It is interpreted to result from debris flows and turbidite currents, though no size sorting and abrasion of ejecta has been observed. Petrological, mineralogical, and geochemical criteria suggest that ejecta components from both types of spherule deposits are similar and originated from the Chicxulub impact, with multiple deposits produced by subsequent remolding, reworking, and redeposition. Spherules and fragments have an Fe- (25-30 wt%), Al-, Mg-rich and Si-poor (<25 wt% SiO₂) composition, and are altered to chlorite and iron-oxides, though rare K-rich mafic glass (~50 wt% SiO₂; 5-8 wt% K) is also present. They contain Ti-, Fe-, K-rich schlieren, Fe-, Mg-rich globules, and rare µm-sized metallic and sulfidic Ni-, Co-rich inclusions. Carbonate as clasts and within spherules and fragments shows textures indicative of quenching and/or liquid immiscibility. Although potential ejecta fractionation and alteration make accurate evaluation difficult, this composition suggests an ejecta origin mainly from mafic lithologies and carbonaceous sediments, in addition to a contribution from intermediate felsic rocks and the possibility of meteoritic contamination.     

Discovery of Cosmic Dust in Gold Deposits in Northwestern Sichuan and Its Significance

Abstract In recent years, a considerable amount of microscopic spherules have been found in concentrates recovered from some stratabound gold deposits occurring in Middle-Upper Triassic turbidite series in northwestern Sichuan. Study indicates that these spherules are cosmic dust. It is the first time that cosmic dust of extraterrestrial origin has been found in hydrothermal gold deposits in China. The spherules are steel-grey in colour and show metallic luster. Their grain size is commonly less than 100 μm. According to their composition, they belong to chromium - rich iron cosmic dust. The spherules have complex and diverse microscopic structures and textures, i.e. they show a very distinct Widmanstāten structure. The variation of cosmic dust content in gold deposits exhibits a positive correlation with the mineralization intensities and hydrothermal alteration. Such a relation indicates that the ore substances may transport not only mechanically but also may chemically in hydrothermal solutions.     

Anthropogenic and impact spherules: Morphological similarity and chemical distinction – A case study from India and its implications

This paper provides first report of silica-rich anthropogenic spherules of varying colour, shape, size, surface texture and chemical composition found in road-deposited sediments (RDS) of Allahabad city, Uttar Pradesh, India. Morphological details and lithophile elemental composition of the silica-rich spherules are compared to microtektites and impact spherules from India to demonstrate their striking morphological similarities and chemical variability. This study suggests the need to use spherule data carefully while assigning an impact origin to spherule-finds or spherule-bearing lithological horizons.     

北方前寒武纪长城系常州沟组的宇宙尘

河北滦县、蓟县、北京十三陵三个地方的常州沟组宇宙尘是在人工重砂的重矿物中发现的,产在古老沉积岩地层中的砾岩和砂岩里,大部分是铁质宇宙尘,形态各异,表面构造多种多样,内部构造各有不同,具Fe—Ni金属,核与壳的化学元素分布不匀匀,化学成分与深海宇宙尘相似。     

Spherules from the Late Cretaceous Phosphorite of the Fatehgarh Formation,Barmer Basin,India

A first report of discovery of spherules, glassy balls, highly magnetic fine dust and microbracciated matrix in the Fatehgarh Formation of Barmer Basin, Rajasthan, India is being presented in this paper. The Fatehgarh Formation is a mixed siliciclastic, carbonate and phosphorite formation of Cretaceous age in the Barmer Basin that comprises sediments of Middle Jurassic to Lower Eocene age. The phosphorite zone in the Fatehgarh Formation is ∼8 metre-thick zone that comprises phosphatic sandstone, bone bed, bedded phosphorite and phosphatic and non phosphatic gastropod beds. The spherules occur in a thin phosphatic-clay mud and silt band of bone bed, which also yielded a very rich and diverse microvertebrate assemblage with a dominant Late Cretaceous (Maastrichtian) form of Igdabatis along with forms comprising of Semionodontid, Lapisosteum and Enchodontid. The end Cretaceous is marked for a mass extinction of numerous species including dinosaurs. An extraterrestrial impact is interpreted as the reason for this mass extinction. Whether these spherules are related to the volcanic source or K/T Boundary impact ejecta found at Caribbean and Gulf of Mexico region needs detailed chemical and age characterization for which study is in progress.     

南极碳质球粒陨石中两个富尖晶石球粒状难熔包体的岩石学和矿物化学特征

富尖晶石球粒状CAI(富Ca-Al难熔包体)是球粒陨石中一种特殊类型的CAI,在南极格罗夫山碳质球粒陨石GRV020025和GRV021579中共发现两个富尖晶石球粒状CAI———GRV020025-3RI8和GRV021579-3RI5。GRV020025-3RI8具有占统治地位的尖晶石,在球粒的最外边存在严重蚀变的不规则边,钙钛矿主要分布在靠近边的位置。与GRV020025-3RI8比较,GRV021579-3RI5的尖晶石中的钙钛矿消失,深绿辉石出现,薄薄的蚀变层位于尖晶石核和富钙辉石边之间。两个富尖晶石球粒状CAI的尖晶石均具有低含量FeO和ZnO的特征,而且GRV021579-3RI5具有较GRV020025-3RI8更高的TiO2含量。岩石学和矿物化学特征表明,GRV020025-3RI8和GRV021579-3RI5都经历过熔融结晶过程,它们的蚀变均发生在非氧化的含水或无水的环境中。     

Spherules from the Late Cretaceous Phosphorite of the Fatehgarh Formation, Barmer Basin, India

A first report of discovery of spherules, glassy balls, highly magnetic fine dust and microbracciated matrix in the Fatehgarh Formation of Barmer Basin, Rajasthan, India is being presented in this paper. The Fatehgarh Formation is a mixed siliciclastic, carbonate and phosphorite formation of Cretaceous age in the Barmer Basin that comprises sediments of Middle Jurassic to Lower Eocene age. The phosphorite zone in the Fatehgarh Formation is 8 metre-thick zone that comprises phosphatic sandstone, bone bed, bedded phosphorite and phosphatic and non phosphatic gastropod beds. The spherules occur in a thin phosphatic-clay mud and silt band of bone bed, which also yielded a very rich and diverse microvertebrate assemblage with a dominant Late Cretaceous (Maastrichtian) form of Igdabatis along with forms comprising of Semionodontid, Lapisosteum and Enchodontid. The end Cretaceous is marked for a mass extinction of numerous species including dinosaurs. An extraterrestrial impact is interpreted as the reason for this mass extinction. Whether these spherules are related to the volcanic source or K/T Boundary impact ejecta found at Caribbean and Gulf of Mexico region needs detailed chemical and age characterization for which study is in progress.     

Coupled asteroid impacts and banded iron-formations,Fortescue and Hamersley Groups,Pilbara, Western Australia

Asteroid impact spherule layers and tsunami deposits underlying banded iron-formations in the Fortescue and Hamersley Groups have been further investigated to test their potential stratigraphic relationships. This work has included new observations related to the ca 2.63 Ga Jeerinah Impact Layer (JIL) and impact spherules associated with the 4th Shale-Macroband of the Dales Gorge Iron Member (DGS4) of the Brockman Iron Formation. A unit of impact spherules (microkrystite) correlated with the ca 2.63 Ga JIL is observed within a >100 m-thick fragmental-intraclast breccia pile in drill cores near Roy Hill. The sequence represents significant thickening of the impact/tsunami unit relative to the JIL type section at Hesta, as well as relative to the 20–30 m-thick ca 2.63 Ga Carawine Dolomite spherule-bearing mega-breccia. The ca 2.48 Ga-old Dales Gorge Member of the Brockman Iron Formation is underlain by an ?0.5 m-thick rip-up clast breccia located at the top of the ca 2.50 Ga Mt McRae Shale, and is interpreted as a tsunami deposit. We suggest that the presence of impact ejecta and tsunami units stratigraphically beneath a number of banded iron-formations, and units of ferruginous shale in the Pilbara and South Africa may result from a genetic relationship. For example, it could be that under Archean atmospheric conditions, mafic volcanism triggered by large asteroid impacts enriched the oceans in soluble FeO. If so, seasonal microbial and/or photolytic oxidation to ferric oxide could have caused precipitation of Fe₂O₃ and silica. In view of the possible occurrence of depositional gaps and paraconformities between impact ejecta units and overlying ferruginous sediments, these relationships require further testing by isotopic age studies.     

Electron microprobe analysis and ore microscopic study of magnetic spherules and grains collected from the Greenland ice

Numerous magnetic spherules and grains collected from the Greenland ice and suspected of being of cosmic origin were studied microscopically and with the microprobe. Seven types of spherules and grams were recognized.Several magnetite spherules contain metallic cores. The metallic cores of three spherules are composed of nearly pure Fe with traces of Ni. The metallic nuclei of two other spherules contain appreciable amounts of Ni; the nucleus of one of these is composed of a Ni-rich NiFe alloy (96.9% Ni), and that of the other contains 3% Ni. This latter spherule is probably of cosmic origin, perhaps formed in the fusion crust of an iron meteorite. Its magnetic shell contains no detectable Ni.The majority of the spherules consist of magnetite, which is more or less transected by martite lamellae [parallel to {111} planes of the magnetite]. One composite grain of titanomagnetite, ilmenite, hematite, and pyroxene was also found. This grain is of terrestrial origin, probably derived from the metamorphic crystalline complex of Greenland. The mineralogy and chemistry of the observed magnetite spherules and grains are discussed in detail.This work was begun at Smithsonian Astrophysical Observatory, Cambridge, Massachusetts, where it was supported in part by Grant GA-855 from the National Science Foundation, and completed at Max-Planck-Institut für Kernphysik, Heidelberg.     

The Cretaceous–Tertiary transition in Guatemala: limestone breccia deposits from the South Petén basin

Limestone breccia deposits in southern Mexico, Guatemala and Belize have recently been interpreted as proximal to distal ballistic fallout deposits, generated by a bolide impact that struck Yucatan at K/T boundary time. We review the age, lithology and the depositional environment of five K/T boundary sections in the South Petén area of Guatemala (Caribe, Aserradero, Chisec, Actela, Chemal) in order to evaluate the nature and origin of K/T limestone breccia deposition. The sections are located 500?km south of the proposed impact site at Chicxulub and trend in an east–west direction from the Guatemala/Mexico border to southern Belize. In four of the five sections examined, a breccia unit up to 50?m thick overlies reef-bearing shallow-water limestones of late Cretaceous (Campanian-Maastrichtian) age. Rhythmically bedded limestones, marls and siltstones of early Danian age overlie the breccia and were deposited under middle-to outer-neritic conditions. The breccia consists of differently coloured layers of shallow-water limestones. Clast size generally decreases upsection to thin layers of predominantly rounded clasts, and these fine-grained rudstones grade into grainstones at the top. In at least one section (EI Caribe) diagenetically altered glass spherules are present in the uppermost layers of the grainstone. These glass spherules are of stratigraphic position and chemical composition similar to black and yellow glass from Beloc, Haiti and Mimbral, Mexico, which some workers have chemically linked to melt glass within the breccia of the Chicxulub cores. We suggest that breccia deposition in Guatemala may have been multi-event, over an extended time period, and related to the collision of the Yucatan and Chortis plates as well as related to a major impact or volcanic event at the end of the Cretaceous.     

Trace element geochemistry of K-rich impact spherules from howardites

The howardite–eucrite–diogenite (HED) achondrites are a group of meteorites that probably originate from the asteroid Vesta. Howardites are complex polymict breccias that sometimes contain, in addition to various rock debris, impact melt glasses which show an impressive range of compositions. In this paper we report on the geochemistry and O isotopes of a series of 6 Saharan polymict breccias (4 howardites and 2 polymict eucrites), and on the trace element abundances of high-K impact spherules found in two of them, Northwest Africa (NWA) 1664 and 1769, which are likely paired.The high-K impact spherules found in the howardites NWA 1664 and NWA 1769 display remarkable trace element patterns. Compared to eucrites or howardites, they all show prominent enrichments in Cs, Rb, K, Li and Ba, strong depletion in Na, while the REE and other refractory elements are unfractionated. These features could not have been generated during impact melting of their host howardites, nor other normal HED target materials. The involvement of Na-poor rocks, and possibly rocks of granitic composition, appears likely. Although these lithologies cannot be well constrained at present, our results demonstrate that the surface of Vesta is certainly more diverse than previously thought. Indeed, despite the large number of available HED meteorites (about 1000 different meteorites), the latter are probably not sufficient to describe the whole surface of their parent body.     

地质记录中的微球粒

地质记录中的微球粒根据成因可以分为宇宙尘、地外物体撞击成因微球粒、火山成因微球粒、生物成因微球粒、沉积作用微球粒和现代微球形飞灰等。宇宙尘含有丰富的宇宙物质,出现Fe、Ni核心和方铁矿等,具有宇宙尖晶石和宇宙不丰富的元素的亏损是判断宇宙尘的关键特征。撞击事件可以产生近源区的撞击熔融玻璃球和远源区的撞击汽云凝结球两类微球粒,常与其他撞击成因矿物伴生。火山微球粒是在低粘稠度的岩浆岩喷发形成的玻璃质火山灰中,有球形、液滴形和哑铃形的微颗粒。这三种成因的微球粒在各种地层中的赋存对于地层对比和地史事件研究中有着非常重要的意义,为判断和研究不同的地质事件提供了一个很好的媒介,因此长期以来一直是微球粒研究的主要对象。另外,在现代工业生产过程中也可以产生大量微球形飞灰,这些飞灰经常包含非常复杂的表面纹饰和独特的化学组成,比如高的ZnO含量等。