Sequence stratigraphic concepts applied to the identification of basin‐filling rhythms in Precambrian successions

The new approaches to stratigraphy, that permit geodynamic interpretations of rock units during mapping, are beginning to be applied to Precambrian successions. Foremost among the new approaches is sequence stratigraphy. In its simplest form, the technique combines the mapping of facies and time‐significant bedding surfaces. The primary surface is the unconformable sequence boundary, or its correlative conformity. However, sequence stratigraphy is not only the documentation of the vertical and internal order of rock units bounded by unconformities, but also the documentation of the hierarchical rank of those units because there are three ranks of unconformity‐bounded sequences. First‐order sequences (megasequences and megasequence sets) record global tectonic cycles. Second‐order sequences (supersequences) record depositional basins or their tectonic stages. Third‐order sequences (depositional sequences) are basin‐filling rhythms. A depositional sequence, regardless of its provenance, geodynamic setting and contained depositional systems, is divided internally into sets of sedimentation units that additively have progradational, aggradational or retrogradational stacking patterns. These patterns record the relationships between the rate of sediment accumulation and the rate at which space was made available for sediment accumulation (or rate of creation of accommodation). Depositional sequences are therefore the non‐random, but not necessarily periodic, cyclic linkage between sediment flux and accommodation, and are a reflection of geodynamic evolution. The importance of eustasy in sequence stratigraphy should be de‐emphasised. Instead the role of the sequence approach in identifying basin‐filling rhythms, whatever their cause, should be stressed. The adaptability of the technique is best viewed by using examples in which tectonic controls were dominant and chaotic responses evident. Despite the uniqueness of each basin‐fill, sequence mapping reveals an order in stratigraphic style that is inherent to basin type, regardless of basin age. Greater acceptance of the sequence approach will add significantly to the revolution in Precambrian geology, because the technique can establish the conformity in stratigraphic style between, and within, the Phanerozoic and Precambrian rock records.     

Soldiers Cap Group iron‐formations,Mt Isa Inlier,Australia, as windows into the hydrothermal evolution of a base‐metal‐bearing Proterozoic rift basin

The Proterozoic Soldiers Cap Group, a product of two major magmatic rift phases separated by clastic sediment deposition, hosts mineralised (e.g. Pegmont Broken Hill‐type deposit) and barren iron oxide‐rich units at three main stratigraphic levels. Evaluation of detailed geological and geochemical features was carried out for one lens of an apatite‐garnet‐rich, laterally extensive (1.9 km) example, the Weatherly Creek iron‐formation, and it was placed in the context of reconnaissance studies of other similar units in the area. Chemical similarities with iron‐formations associated with Broken Hill‐type Pb–Zn deposit iron‐formations are demonstrated here. Concordant contact relationships, mineralogy, geochemical patterns and pre‐deformational alteration all indicate that the Soldiers Cap Group iron‐formations are mainly hydrothermal chemical sediments. Chondrite normalised REE patterns display positive Eu and negative Ce anomalisms, are consistent with components of both high‐temperature, reduced, hydrothermal fluid (≥250°C) and cool oxidised seawater. Major element data suggest a largely mafic provenance for montmorillonitic clays and other detritus during chemical sedimentation, consistent with westward erosion of Cover Sequence 2 volcanic rocks, rather than local mafic sources. Ni enrichment is most consistent with hydrogenous uptake by Mn‐oxides or carbonates. Temperatures inferred from REE data indicate that although they are not strongly enriched, base metals such as Pb and Zn are likely to have been transported and deposited prior to or following iron‐formation deposition. Most chemical sedimentation pre‐dated emplacement of the major mafic igneous sill complexes present in the upper part of the basin. Heating of deep basinal brines in a regional‐scale aquifer by deep‐seated mafic magma chambers is inferred to have driven development of hydrothermal fluids. Three major episodes of extension exhausted this aquifer, but were succeeded by a final climactic extensional phase, which produced widespread voluminous mafic volcanism. The lateral extent of the iron‐formations requires a depositional setting such as a sea‐floor metalliferous sediment blanket or series of brine pools, with iron‐formation deposition likely confined to much smaller fault‐fed areas surrounded by Fe–Mn–P–anomalous sediments. These relationships indicate that in such settings, major sulfide deposits and their associated chemical sediment marker horizons need not overlie major igneous sequences. Rather, the timing of expulsion of hydrothermal fluid reflects the interplay between deep‐seated heating, extension and magmatism.     

Chronostratigraphic basin framework for Palaeoproterozoic rocks (1730–1575 Ma) in northern Australia and implications for base‐metal mineralisation

Sequence‐stratigraphic interpretations of outcrop, drillcore, wireline and seismic datasets are integrated with SHRIMP zircon and palaeomagnetic determinations to provide a detailed chrono‐stratigraphic basin framework for the base‐metal‐rich Palaeoproterozoic rocks of the southern McArthur, Lawn Hill and Mt Isa regions. The analysis forms a basis for future correlations across northern Australia. Nine second‐order unconformity‐bounded supersequences are identified. Supersequences have a duration of 10–20 million years; some hitherto‐unrecognised unconformity surfaces record up to 25 million years of missing rock record. The second‐order supersequences contain a series of nested third‐, fourth‐ and fifth‐order sequences many of which can be correlated across the Mt Isa, Lawn Hill and southern McArthur regions. The analysis relates accommodation history to major intraplate tectonic events evident on the apparent polar wander path for northern Australia. Major tectonic events at approximately 1735 Ma, 1700 Ma, 1670 Ma, 1650 Ma, 1640 Ma, 1615 Ma, 1600 Ma and 1575 Ma impacted on accommodation rates and basin shape in northern Australia. Sub‐basin depocentres, the hosts for major sulfide mineralisation, are attributed to reactivated faults that controlled local subsidence. Pb/Pb model ages of 1653 Ma, 1640 Ma and 1575 Ma for the Mt Isa, McArthur River and Century Pb–Zn–Ag deposits, suggest that changes to intraplate stresses at tectonic events of like age resulted in the migration of metal‐bearing fluids into the sub‐basins. A Pb/Pb model age of 1675 for the Broken Hill deposit suggests that intraplate stresses manifest in northern Australia also affected rocks of similar age further south. Magmatic events close to 1700 Ma (Weberra Granite) and 1675 Ma (Sybella Granite) coincide with times of regional incision and the formation of supersequence‐bounding unconformity surfaces.     

Late Palaeozoic arc flank and fore‐arc basin sequence of the New England fold belt in the stanage bay region,central Queensland

Devonian and Carboniferous (Yarrol terrane) rocks, Early Permian strata, and Permian‐(?)Triassic plutons outcrop in the Stanage Bay region of the northern New England Fold Belt. The Early‐(?)Middle Devonian Mt Holly Formation consists mainly of coarse volcaniclastic rocks of intermediate‐silicic provenance, and mafic, intermediate and silicic volcanics. Limestone is abundant in the Duke Island, along with a significant component of quartz sandstone on Hunter Island. Most Carboniferous rocks can be placed in two units, the late Tournaisian‐Namurian Campwyn Volcanics, composed of coarse volcaniclastic sedimentary rocks, silicic ash flow tuff and widespread oolitic limestone, and the conformably overlying Neerkol Formation dominated by volcaniclastic sandstone and siltstone with uncommon pebble conglomerate and scattered silicic ash fall tuff. Strata of uncertain stratigraphic affinity are mapped as ‘undifferentiated Carboniferous’. The Early Permian Youlambie Conglomerate unconformably overlies Carboniferous rocks. It consists of mudstone, sandstone and conglomerate, the last containing clasts of Carboniferous sedimentary rocks, diverse volcanics and rare granitic rocks. Intrusive bodies include the altered and variably strained Tynemouth Diorite of possible Devonian age, and a quartz monzonite mass of likely Late Permian or Triassic age.

The rocks of the Yarrol terrane accumulated in shallow (Mt Holly, Campwyn) and deeper (Neerkol) marine conditions proximal to an active magmatic arc which was probably of continental margin type. The Youlambie Conglomerate was deposited unconformably above the Yarrol terrane in a rift basin. Late Permian regional deformation, which involved east‐west horizontal shortening achieved by folding, cleavage formation and east‐over‐west thrusting, increases in intensity towards the east.     

Storm‐dominated sedimentation in a protected basin fringed by coral reefs,Nara Inlet,Whitsunday Islands,Great Barrier Reef,Australia

Hydrodynamic data and samples of bed sediment were collected from Nara Inlet, a small incised embayment in the Whitsunday Islands, central Great Barrier Reef. Measured tidal currents in the inlet do not exceed 0.2 ms^–1 even at spring tides. Swell waves dominate much of the inner shelf of the Great Barrier Reef but are absent from in the inlet due to the presence of a fringing reef at the inlet mouth. On the silty sand floor of the inlet, particle size decreases towards the inlet head. Most of the bed is too coarse to be remobilised by fair‐weather wave and tides, and we predict that bedload sediment transport thresholds are only exceeded in the inlet during cyclones. The observed distribution of bed sediments is consistent with landward dispersal of sediment under storm conditions. Over 20 m of (presumably Holocene) sediments occurs in the inlet and the seismic character of the infill is consistent with the observed textural variation of the modern sediments. We infer that sediment accumulation on the floor of the inlet has been storm dominated throughout much of the Holocene.     

Tectonic inversion in a segmented foreland basin from extensional to piggy back settings: The Tucumán basin in NW Argentina

The Tucumán foreland basin is bounded by: 1) basement cored ranges with elevations over 6000 m in the west; 2) inverted extensional grabens to the north; 3) basement thrust blocks in the south and 4) basement cored small ranges in the east. This foreland basin is located between two geological provinces: the Sierras Pampeanas and the Santa Bárbara system.Cretaceous Salta rifting extended southwards covering the entire eastern part of the province of Tucumán in NW Argentina. Syn-rift and post-rift deposits can be recognized in accordance with their architectural geometries. Foreland basin sediments progressively covered the rift deposits as the Andean orogen propagated towards the east.Despite some early studies, the Tucumán basin is poorly documented. For the present study, 44 sections of 2D seismic surveys amounting to more than 730 km were used to describe the structure and the depositional evolution of the basin. The present structure is the result of a long sequence of events that includes a compressional deformation during the Paleozoic, a rifting stage during the Cretaceous and a foreland stage during the late Cenozoic. Although tectonic inversion, which has played a role during the foreland stage since the Miocene, can be observed in many sectors of the basin, it is more prominent along the margins. Reactivation of old basement discontinuities and inversion of Cretaceous normal faults produced the compartmentalization of the foreland, giving rise to the present shape of the Tucumán basin. This evolution is recorded in the Neogene deposits.     

Study of a Neogene basin dynamics: The “Bizerte basin”, northeastern Tunisia: relevance to the global Messinian Salinity Crisis

The Messinian sediments of northeastern Tunisia were deposited under an active tectonic setting. They are organized in sequences indicating a transitional deposit from margin – littoral to lacustrine – continental facies. These series unconformably overlie the Serravallian–Tortonian silty clays packages, and are overlain by the transgressive Early Pliocene marl (Zanclean). The presence of evaporitic strata points out to the Messinian Salinity Crisis described in the peripheral basins of the western Mediterranean. The Messinian sedimentation was found to have been closely controlled by transtensive tectonics and differential subsidence at a large spatio-temporal scale. It is organized in sequences typical of a depositional environment controlled by eustatism, tectonic and maybe by climate changes. Despite the existence of some local specific sedimentological characteristics, our results corroborate previous findings that pointed out to the Messinian times as a singular period all around the Mediterranean Basin. Field and subsurface seismic profile data helped reconstructing either the sedimentary or tectonic unconformities existing between the studied Messinian series and older Neogene successions.     

Is the central Arctic Ocean a sediment starved basin?

Numerous short sediment cores have been retrieved from the central Arctic Ocean, many of which have been assigned sedimentation rates on the order of mm/ka implying that the Arctic Basin was starved of sediments during Plio–Pleistocene times. A review of both shorter-term sedimentation rates, through analysis of available sediment core data, and longer-term sedimentation rates, through estimates of total sediment thickness and bedrock age, suggests that cm/ka-scale rates are pervasive in the central Arctic Ocean. This is not surprising considering the physiographic setting of the Arctic Ocean, being a small land-locked basin since its initial opening during Early Cretaceous times. We thus conclude that the central Arctic Ocean has not been a sediment starved basin, either during Plio–Pleistocene times or during pre-Pliocene times. Rigorous chronstratigraphic analysis permits correlation of sediment cores over a distance of ∼2600 km, from the northwestern Amerasia Basin to the northwestern Eurasia Basin via the Lomonosov Ridge, using paleomagnetic, biostratigraphic, and cyclostratigraphic data.     

Optical and infra‐red studies on high‐temperature Alkali Feldspars

In ternary feldspars of essentially one phase, calcium content has a dominant influence on the optic axial angle. In such feldspars and also in binary feldspars from solvsbergite rocks, variations of cooling histories do not significantly affect the optic axial angle. In ternary feldspars which are unmixed into two or three prominent phases, Al/Si ordering has an important effect on the 2V value. A recent suggestion of several writers that in feldspars the alkali structural site may be partially occupied by (H3O)+ ions is applied as a possible way to explain a correlation observed between petrographical features of the rocks and the optic axial angles of their feldspar phenocrysts.     

Anoxia in the Domanik basin of the Timan–Pechora region

Analysis of the carbon isotopic composition in aryl carotenoid derivatives, including isorenieratene, in bitumen from domanikoid rocks of the sections cropping out along the Chut River revealed that they contain anomalously heavy carbon, which is determined by the formation of these compounds from green sulfur bacteria of the family Chlorobiaceae. These bacteria use the peculiar process of carbon fixing as HCO₃^? in the reversed tricarboxilic acid cycle. The fact of hydrosulfuric contamination of the photic water layer in the Domanik basin is confirmed by the plurality of data. Anoxity in shelf water of the middle Frasnian Timan–Pechora basin is evident from lithological features such as, for example, lamination of some rocks and mass death of the fauna.     

Tectonostratigraphic history of the Neogene Maimará basin,Northwest Argentina

This paper presents the tectonostratigraphic evolution of the Maimará Basin and explores the relationship between the clastic sediments and pyroclastic deposits in the basin and the evolution of the adjacent orogeny and magmatic arc. The sedimentary facies in this part of the basin include, in ascending order, an ephemeral fluvial system, a deep braided fluvial system and a medial to distal ephemeral fluvial system. We interpret that Maimará Formation accumulated in a basin that has developed two stages of accumulation. Stage 1 extended from 7 to 6.4 Ma and included accelerated tectonic uplift in the source areas, and it corresponds to the ephemeral fluvial system deposits. Stage 2, which extended from 6.4 to 4.8 Ma, corresponds to a tectonically quiescent period and included the development of the deep braided fluvial system deposits. The contact between the Maimará and Tilcara formations is always characterized by a regional unconformity and, in the study area, also shows pronounced erosion.Rare earth element and other chemical characteristics of the tuff intervals in the Maimará Formation fall into two distinct groups suggesting the tuffs were erupted from two distinct late Miocene source regions. The first and most abundant group has characteristics that best match tuffs erupted from the Guacha, Pacana and Pastos Grandes calderas, which are located 200 and 230 km west of the study area at 22º-23º30′S latitude. The members the second group are chemically most similar to the Merihuaca Ignimbrite from the Cerro Galán caldera 290 km south-southwest of the studied section. The distinctive geochemical characteristics are excellent tools to reconstruct the stratigraphic evolution of the Neogene Maimará basin from 6.4 to 4.8 Ma.     

Response of U‐Pb Zircon and Rb‐Sr total‐rock and mineral systems to low‐grade regional metamorphism in proterozoic igneous rocks,mount Isa,Australia

A detailed Rb‐Sr total‐rock and mineral and U‐Pb zircon study has been made on suites of Proterozoic silicic volcanic rocks and granitic intrusions, from near Mt Isa, northwest Queensland. Stratigraphically consistent U‐Pb zircon ages within the basement igneous succession show that the oldest recognized crustal development was the outpouring of acid volcanics (Leichhardt Metamorphics) 1865 ± 3 m.y. ago, which are intruded by coeval, epizonal granites and granodiorites (Kalkadoon Granite) whose pooled U‐Pb age is 1862 ⁺²⁷ _‐21 m.y. A younger rhyolitic suite (Argylla Formation) within the basement succession has an age of 1777 ± 7 m.y., and a third acid volcanic unit (Carters Bore Rhyolite), much higher again in the sequence, crystallized 1678 ± 1 m.y. ago.

All of these rocks are altered in various degrees by low‐grade metamorphic events, and in at least one area, these events were accompanied by, and can be partly related to, emplacement of a syntectonic, foliated granitic batholith (Wonga Granite) between 1670 and 1625 m.y. ago. Rocks that significantly predate this earliest recognized metamorphism, have had their primary Rb‐Sr total‐rock systematics profoundly disturbed, as evidenced by 10 to 15% lowering of most Rb‐Sr isochron ages, and a general grouping of many of the lowered ages (some of which are in conflict with unequivocal geological relationships) within the 1600–1700 m.y. interval. Such isochrons possess anomalously high initial ⁸⁷Sr/⁸⁶Sr ratios, and some have a slightly curved array of isotopic data points. Disturbance of the Rb‐Sr total‐rock ages is attributed primarily to mild hydrothermal leaching, which resulted in the loss of Sr (relatively enriched in ⁸⁷Sr in the Sr‐poor (high Rb/Sr) rocks as compared with the Sr‐rich rocks).     

Middle Triassic pteridosperms (Pinophyta) of the Timan–Pechora basin

The collection of fossil plants sampled by geologists from VNIGRI at the end of the 20th century from Triassic continental sections drilled by many wells and cropping out in several natural localities and stored at the Museum of Petroleum Geology and Paleontology of the same institute was critically revised. The use of the epidermal method for the study of plant remains with consideration of recent publications dedicated to continental sections of Central Europe made it possible to substantially broaden the taxonomic composition of the Triassic flora and first specify the composition of its pteridosperm representatives. Unlike the Triassic floras of Western Europe, the pteridosperms the Pechora region appeared to be relatively diverse. They number 37 species of 11 genera, which are confined to the upper part of the Triassic sequence: Anguran and Naryan-Mar formations and their analogs. The Middle Triassic, mainly, Ladinian, age of these formations is reliably substantiated both by paleontological (vertebrate and palynological) data and by results of the comparative analysis of the Anguran–Naryan-Mar taphofloras and coeval European type floras dated back to the Anisian–Ladinian by marine faunal remains. The stratigraphic significance of pteridospermous plant remains becomes undoubted for continental sections of the Timan–Pechora basin, while the genera Scytophyllum, Kalantarium, and Kirjamkenia may be considered with respect to their diversity and abundance as representing orthostratigraphic taxa.     

Água Bonita pull apart basin and its relationship to Transbrasiliano Lineament

The Transbrasiliano Lineament (TBL), a NE-SW trending strike slip system at least 2700 km long, is one of the main structures of the South American Platform. This lineament, along with other structures, influenced greatly the installation and depositional history of the Paraná and Parnaíba sedimentary basins. The Água Bonita Basin (ABB) occurs at an intermediate position between both basins. This work aims to provide information on the origin and evolution of the Água Bonita Basin, considered a Silurian-Devonian basin, as well as its relationship with the Transbrasiliano Lineament.Geological, aero and ground geophysics data were used to determine a structural geological model for the ABB located in the Brasilia Fold Belt in the Tocantins tectonic province. The airborne geophysical magnetic data used in the study were acquired in the 1970s by the existing 147 ground gravity stations in addition to the 498 new ground gravity and geodetic stations that were added to the existing ones.The analysis of the outcrops allowed identifying the sedimentary facies associations providing new information on the depositional environments. The compilation of existing data, satellite images analysis, geological maps and shaded relief provided an integrated model for the study area.A geological model was proposed for the ABB based on the interpretation, integration, depth analysis and 2D gravity forward modeling according to a theoretical model for an extensional duplex in a strike slip system with flower structures. We observed several segmented gravity anomalies, which were interpreted as steps/faults. This interpretation is consistent with a pull apart basin. According to the depth data estimated by this model, the maximum thickness of the Água Bonita Formation is 1.6 km and 2.4 km for the precursor rift. The basin has two dextral faults on each border, whose main fault of the TBL strike slip system and the master fault controlling the ABB are observed on the east border of the rift phase. Lineaments perpendicular to the west edge, in addition to those crossing the ABB in the N65E, delineate peculiar magnetic, gravity and geological signatures in the northern part of the basin. The basin is located in the weak region of the TBL and its main eastern fault is dipping sub-vertically to the west. This fault modeled up to the 8 km depth using the gravity data, was also observed in the Tilt Angle of the Total Horizontal Gradient (TAHG) matched filter grid result at approximately 8 km, however this may not be this fault maximum depth.Three main sedimentary-tectonic stages were observed, (i) a Pre-Devonian precursor rift present in the Água Bonita Basin and Jaibaras Group; (ii) the sag stage developed during the Devonian, when the Paleozoic basins of Paraná, Parnaíba and Água Bonita Basin were connected evidenced by the sedimentary facies and similar thicknesses; and (iii) the Pos-devonian rocks that are probably not preserved in the Água Bonita Basin.     

Groundwater quality assessment in Oropos–Kalamos basin,Attica, Greece

Groundwater samples were collected from 25 sampling sites of the Oropos–Kalamos basin aiming to describe the groundwater quality in relation to geology, lithology and anthropogenic activities of the study area. Chromium speciation analysis, factor analysis, GIS database and geochemical data proved successful tools for the identification of natural and anthropogenic factors controlling the geochemical data variability and for the identification of the redox couple controlling Cr speciation. A Durov diagram is used to classify groundwater quality into five types: Ca–HCO₃, Mg–HCO₃, Na–Cl, Mg–Cl and Ca–Cl. The groundwater quality of Oropos–Kalamos is influenced by various natural and anthropogenic factors. Evaluation of water quality for drinking and irrigation purposes is discussed.     

The Tyrrhenian back－arc basin and subduction of the Ionian lithosphere

A deep, narrow, and distorted Benioff zone, plunging from the Ionian Sea towards the southern Tyrrhenian basin, is the remnant of a long and eastward migrating subduction of eastern Mediterranean lithosphere. From Oligocene to Recent, subduction generated the Western Mediterranean and the Tyrrhenian back-arc basins, as well as an accretionary wedge constituting the SouthernAoenninic Arc.In the Tyrrhenian Sea, stretching started in late Miocene and eventually produced two small oceanic areas: the Vavilov Plain during Pliocene (in the centralsector) and the Marsili Plain during Quaternary (in the southeastern sector). They are separated by a thicker crustal sector, called the Issel Bridge. Back-arc exten-sion was rapid and discontinuous, and affected a land locked area where continental elements of various sizesoccurred. Discontinuities in extension were mirrored bychanges in nature of the lithosphere scraped off to form the Southern Apenninic Arc. Part of the tectonic units of the southern Apennines, accreted into the wedge from late Miocene to Pliocene, had originally been laid down on thinned conti-nental lithosphere, which should constitute the deep portion of the present slab. After Plio-cene, only Ionian oceanic lithosphere wassubducted, because the large buoyancy of thewide and not thinned continental lithosphere of Apulia and Africa (Sicily) preserved the seelements from roll back of subduction. After Pliocene, the passively retreating oceanic slabhad to adjust and distort according to the geometry of these continental elements.The late onset of arc volcanism in respect to the duration of extension in the Tyrrhenian-Ionian system may find an expla-nation considering an initial stage of subduc-tion of thinned continental lithosphere. The strong Pleistocene vertical movements that occurred in the whole southeastern system(subsidence in the back-arc basin and upliftin the orogenic arc) may instead be related to the distortion of the oceanic slab.