Inclined K–Ar illite age spectra in brittle fault gouges: effects of fault reactivation and wall‐rock contamination

K–Ar clay fraction ages of brittle faults often vary with grain size, decreasing in the finer size fractions, producing an inclined age–grain‐size spectrum. K–Ar ages and mineralogical characterization of gouges from two normal faults in the Kongsberg silver mines, southern Norway, suggest that inclined spectra derived from brittle fault rocks reflect the mixing of inherited components with authigenic mineral phases. The ages of the coarsest and finest fractions constrain faulting at c. 260–270 Ma and reactivation around 200–210 Ma, respectively. This study demonstrates how wall‐rock contamination influences the K–Ar age of the coarsest size fractions and that authigenic illite and K‐feldspar can crystallize synkinematically under equivalent conditions and thus yield the same K–Ar ages.     

Mineralogy of gouge in north-northeast-striking faults,Sydney region,New South Wales

Gouges formed in north-northeast-striking fault zones of the Sydney region and associated host-rocks were investigated by XRD, SEM, TEM and optical microscopy in order to determine their mineralogy. XRD studies reveal that illite, illite–smectite, kaolinite, quartz and dickite are present in varying proportions. Kübler Indices (0.54–0.71) and low smectite contents in illite–smectite (<10% smectite) in most gouges and host-rocks, indicate the assemblages formed at temperatures between 120 and 150°C. Those at the Heathcote Road, Lucas Heights location formed at lower temperatures (<100°C). SEM images of the clays in host sublitharenites and gouges show a variety of sizes and habits that reflect variations in fluid temperature and rate of crystallisation. SEM studies also reveal that detrital quartz grains exhibit overgrowths and etch pits of varying density, size and shape that are more strongly developed in the gouges than in the host-rocks. These features are thought to be related to higher fluid/rock ratios brought about by major ingress of fluids into the fault zones. The mineral assemblage present and the features exhibited are believed to have formed in response to a thermal event associated with the early stages of the breakup of Gondwana.     

K-Ar Dating of Fault Gouges from the Red River Fault Zone of Vietnam

Constraining the timing of fault zone formation is fundamentally important in terms of geotectonics to understand structural evolution and brittle fault processes.This paper presents the first authigenic illite K-Ar age data from fault gouge samples collected from the Red River Shear Zone at Lao Cai province,Vietnam.The fault gouge samples were separated into three grain-size fractions(0.1 μm,0.1-0.4 μm and 0.4-1.0 μm).The results show that the K-Ar age values decrease from coarser to finer grain fractions(24.1 to 19.2 Ma),suggesting enrichment in finer fraction of morerecently grown authigenic illites.The timing of the fault movement are the lower intercept ages at 0%detrital illite(19.2 ± 0.92 Ma and 19.4 ± 0.49 Ma).In combination with previous geochronological data,this result indicates that the metamorphism of the Day Nui Con Voi(DNCV) metamorphic complex took place before ca.26.8 Ma.At about 26.8 Ma-25 Ma,the fault strongly acted to cause the rapid exhumation of the rocks along the Red River-Ailoa Shan Fault Zone(RR-ASFZ).During brittle deformation,the DNCV slowly uplifted,implying weak movement of the fault.This brittle deformation might have lasted for ca.5 Ma.     

K–Ar dating of fault gouge in the northern Sydney Basin, NSW, Australia—implications for the breakup of Gondwana

The occurrence of synkinematic and authigenic clay minerals is a common feature in fault gouges. Few attempts have been made to date fault gouges. We present the first age data in Australia for synkinematic illite–smectite growth in two fault zones of the northern Sydney Basin, NSW. The faults occur at Burwood Beach, NSW in the northern part of the Sydney Basin and are hosted by Early Permian siltstones, tuffs and coals of the Lambton Formation, Newcastle Coal Measures. The faults are 1.5 m apart, show normal displacement and trend N–S with steep easterly dips. Foliated gouge zones, comminution and dilational breccias are developed along both fault surfaces. K–Ar ages extracted from samples in the gouge and tuffs in the damage zones are 172 (6–10 μm) to 119 Ma (<0.4 μm), respectively. Older ages of 272–281 Ma for the coarse fractions (>2 μm), 237–245 Ma for the <2 μm fraction, 218 Ma for the <0.4 μm fraction and 196 Ma for the <0.1 μm fraction have been obtained from siltstones within and outside the damage zone. We believe the younger ages of 196–237 Ma indicate the time at which diagenetic illite–smectite formed and the 122–150 Ma dates from the <2 μm fraction represent the maximum age of gouge formation. The younger ages are thought to reflect the last slip event occurring on the faults, which is related to the rifting and dispersal of the eastern margin of the Australian continent.     

Silurian-Devonian and Jurassic Thermal Events in the Ordos Basin, China: Indications from K-Ar Dating on Illites

In the Ordos basin, two distinct thermal events of different ages have been identified for the first time by means of K-Ar dating combined with illite crystallinity analysis. For the Late Triassic and Late Permian samples, the K-Ar ages of the < 0.2μm fractions (159-173 Ma) reflect an illitization age related to the Yanshanian movement and indicate a short thermal event in the Middle Jurassic; the K-Ar ages of the <2 μm fractions (210-308 Ma) are interpreted as mixed ages of detrital material and authigenic illites. The K-Ar ages of both < 0.2μm and < 2μm fractions of a Middle Cambrian sample (368 Ma and 419 Ma) correspond to the ages of the metamorphism and earliest granite intrusion in the northern Caledonian Qinling fold zone (380-420 Ma) and show a thermal event during Silurian-Devonian time.     

Fault gouge analyses: K–Ar illite dating,clay mineralogy and tectonic significance—a study from the Sierras Pampeanas,Argentina

We introduce a method for the detailed interpretation of K–Ar illite fine-fraction ages of fault gouges from non-sedimentary host rocks. Ages are cross-evaluated with several independent parameters, e.g. illite crystallinity, illite polytype quantification, grain size, mineralogical observations, K–Ar muscovite and biotite host-rock cooling ages as well as low-temperature thermochronological data (AFT, AHe, ZHe). This interpretation approach is applied to a regional study in order to constrain the ‘deformation path’ of the Eastern Sierras Pampeanas in NW Argentina. In the course of this study, a large number of gouge-bearing fault zones were systematically sampled and analysed. Obtained K–Ar illite fine-fraction ages range from Devonian to Cretaceous times, documenting a long-lasting brittle fault activity in this region. Ages >320 Ma are synchronous with a period of intra-Carboniferous compressional tectonism, whereas Permo-Triassic ages are contemporaneous to a flat-slab subduction episode of the Farallon plate beneath the South American plate. Middle to Late Permian and Early Triassic ages as well as Early Jurassic to Middle Cretaceous ages correlate with extensional tectonics in this region. Additionally, K–Ar illite ages reveal a propagation of brittle deformation from north to south in the Sierras de Córdoba and San Luis. Data integrity and consistency with other chronometers and geological evidence show that the here suggested interpretation is valid and can provide a powerful tool to evaluate cooling and deformation histories. Despite of that, we could show that the reliability of fault gouge data strongly depends on the regional cooling.     

K‐Ar illite age constraints on the Proterozoic formation and reactivation history of a brittle fault in Fennoscandia

K‐Ar ages of authigenic illite from two drill‐core gouge samples of a fault in the Palaeoproterozoic basement of Finland record two distinct faulting events. The older sample yields apparent ages from 1240 ± 26 to 1006 ± 21 Ma for four grain size fractions between 6 and <0.1 μm. The second sample is structurally younger and yields statistically distinct ages ranging from 978 ± 20 to 886 ± 18 Ma. We interpret the ages of the <0.1 m fractions, which are the youngest, as representing the actual time of faulting. XRD analysis and age modelling exclude significant age contamination of the finest dated fractions with inherited host rock components. These results provide therefore an example of meaningful isotopic dating of illite‐type clay material formed during Precambrian faulting, demonstrate and constrain fault reactivation and give evidence for brittle Sveconorwegian Mesoproterozoic shortening and Neoproterozoic extension in Fennoscandia.     

Progressive,episodic deformation in the Mexican Fold–Thrust Belt (central Mexico): evidence from isotopic dating of folds and faults

We used illite Ar/Ar dating to obtain absolute ages of folds and shear zones formed within the Mexican Fold–Thrust Belt (MFTB). The methodology takes advantage of illite dating in folded, clay-bearing layers and the ability to obtain accurate ages from small-size fractions of illite using encapsulated Ar analysis. We applied our approach to a cross-section that involves folded Aptian–Cenomanian shale-bentonitic layers interbedded with carbonates of the Zimapán (ZB) and Tampico–Misantla (TMB) Cretaceous basins in central-eastern Mexico. Basinal carbonates were buried by syn-tectonic turbidites and inverted during the formation of the MFTB in the Late Cretaceous. Results from folds and shear zones record different pulses of deformation within this thin-skinned orogenic wedge.

Mineralogical compositions, variations in illite polytypes, illite crystallite size (CS), and Ar/Ar ages were obtained from several size fractions in limbs and hinges of the folds and in the shear zones. 1M_d-illite polytype (with CS of 6–9 nm) dominates in two folds in the TMB while 2M₁-illlite (with CS of 14–30 nm) dominates in the third fold, in the ZB, and in the fold/shear zone. From west (higher grade) to east (lower grade): Ar retention ages indicate shearing occurred at ~84 Ma in the westernmost shear zone, folding at ~82 Ma in the ZB with subsequent localized shearing at ~77 Ma, and Ar total gas ages constrain the time of folding at ~64 Ma on the west side of the TMB and ~44 Ma on the eastern edge. These results are consistent with the age and distribution of syn-tectonic turbidites and indicate episodic progression of deformation from west to east.     

New stratigraphic,geochronological, and structural data from the southern Guanajuato Mining District,México: implications for the caldera hypothesis

Abstract

The Cenozoic stratigraphy of the southern Guanajuato Mining District (GMD) was established 40 years ago. The existence of a caldera structure that produced the Cenozoic volcanic cover was postulated and the world-class silver ore deposit of the Oligocene age has been closely related to magmatism. In this context, we present a new geological map of the southern GMD, U–Pb and Ar–Ar ages of the volcanic units, and structural data for the Cenozoic faults. Our results document that the volcanic centre was active between ca. 33.5 Ma and ca. 31.3 Ma, coeval with NW–SE normal faulting. We propose that the Bufa, Calderones, and Cedro formations are stratigraphic units directly related to the volcanic centre. Although the younger Chichíndaro Rhyolite scarcely crops out within the study area, it appears to be more extensive outside of the study area, forming part of the rhyolitic volcanism of the Mesa Central of Mexico. In the study area, the Chichíndaro Rhyolite buries major faults, demonstrating that it was emplaced after the peak of faulting. The two main structures are the El Cubo and Veta Madre grabens; also there are several faulted and brecciated zones where silver–gold mineralization was emplaced. The extension direction changed from NE to NW producing normal faulting, reactivating older structures and allowing dike intrusion. The extensional phase continued to be active throughout the Oligocene. The age of the volcanic event and a new K–Ar age of the Veta Madre vein of 29.8 ± 0.8 Ma (K–Ar in adularia) indicate that the hydrothermal event began immediately after the emplacement of the Cedro Formation. The emplacement of the Chichíndaro Rhyolite allowed hydrothermal activity to be active for two million years or more.     

K‐Ar dating of Permian and Tertiary igneous activity in the Southeastern Sydney Basin,New South Wales

The southern part of the Sydney Basin of New South Wales is comprised mainly of Permian and Triassic marine to freshwater clastic sedimentary rocks. Within this sequence there are six latite extrusive units, several medium‐sized monzonite intrusions and a large number of small to medium‐sized basic to intermediate intrusions. Thin basaltic flows were extruded onto the Tertiary topographic surface. All of these rocks are relatively undeformed.

Radiometric (K‐Ar) dating has previously been carried out on Mesozoic and Tertiary intrusions and flows of the southwestern portion of the Sydney Basin. However, relatively few Permian, and no post‐Permian, K‐Ar dates have been published for the southeastern portion of the basin. The present investigation provides nine K‐Ar dates from the latter area.

Four extrusive and intrusive units have been confirmed as Permian in age (238 ± 6; 241 ± 4; 245 ± 6; and 251 ± 5 m.y.). Five post‐Permian (on stratigraphic criteria) intrusions yielded Tertiary ages (26.2 ± 3.0; 47.9 ± 2.5; 49.0 ± 4.0; 49.4 ± 2.0; and 58.8 ± 3.5 m.y.). The Permian ages agree with previously published K‐Ar data from the southeastern Sydney Basin, and the Tertiary ages complement and extend the data from the southwestern portion of the basin. However, no Mesozoic K‐Ar dates were obtained from the southeastern Sydney Basin. The Tertiary intrusions may have been emplaced as a result of rifting between Australia and New Zealand, or between Australia and Antarctica, or both.     

K–Ar dating of authigenic minerals in siliciclastic sequences: an example from the south Sanfranciscana Basin (Western Minas Gerais,Brazil)

K–Ar dating was applied on authigenic potassic minerals which are abundant in sandstones from the south of the Sanfranciscana Basin, Western Minas Gerais State, central Brazil. The Quintinos Member fluvial sandstones (Três Barras Formation, Areado Group) contain significant amounts of authigenic K‐feldspar as microcrystals of adularia and sanidine habits. The ages of these microcrystals cluster into three groups: 106.1 ± 2.2, 89.9 ± 1.9 and 88.8 ± 1.8 Ma (from Albian to Coniacian). The older age of 106.1 ± 2.2 Ma was obtained from the coarse fraction analysed (10–20 µm) that can contain a mixture of detrital potassic minerals (K‐feldspar, muscovite, biotite and illite) and different authigenesis of K‐feldspar (overgrowths and microcrystals). Thus, only the younger ages were interpreted as precipitation of K‐feldspar microcrystals during the Late Cretaceous into the Quintinos Member sandstones. Moreover, these ages can document the formation of microcrystals within a few million years after deposition of the sandstones. The ages of authigenic illite from the Capacete Formation epiclastic sandstones (Mata da Corda Group) range from 88.5 ± 1.9 to 71.5 ± 1.9 Ma (Coniacian–Campanian). These results suggest the timing of the illitization event in these sandstones as well as a synchrony with K‐feldspar authigenesis in the Quintinos Member sandstones. These results are well constrained and are in agreement with stratigraphic, biostratigraphic and radiometric ages previously reported for the Sanfranciscana Basin. Copyright © 2014 John Wiley & Sons, Ltd.     

Further evidence for a Jurassic mineralizing event in central Europe: K–Ar dating of hydrothermal alteration and fluid inclusion systematics in wall rocks of the Käfersteige fluorite vein deposit in the northern Black Forest, Germany

The hydrothermal fluorite vein deposit of `Käfersteige' ranks among the biggest in central Europe. It is located along the suture zone that separates the Moldanubian and Saxothuringian units in the northern Black Forest, and is hosted in Bunter sandstone and underlying granitic basement. K–Ar ages of authigenic illite from the wall rocks give a Jurassic formation age of around 145?Ma for the deposit. Age data scatter down to 80?Ma in illite from the clay gouge and indicate a younger Cretaceous-Tertiary hydrothermal overprint. The pyrophyllite component in authigenic illite from wall rocks and the re-equilibration of illite suggest a formation temperature around 200?°C. Secondary fluid inclusions in quartz from the wall rocks define a syn-mineralization fluid episode involving Ca–Mg–K–Na–Cl-rich brines (about 27 wt% NaCl_eq) with a T _h of about 125?°C, and a post-mineralization Na–Cl-rich fluid overprint with a T _h of about 100?°C. Both generations of fluid inclusions relate to the final event of each cycle, while authigenic illite composition and re-equilibration of illite in the clay gouge may document initial temperatures of formation. The Upper Jurassic fluid system can be traced all over western Europe. It is probably an expression of continent-wide rifting and concomitant regional fluid circulation in connection with major tectonic disturbances, magmatism and abnormal heat flow during the opening of the North Atlantic ocean. The younger barren fluid overprint could be related to the onset of the Alpine orogeny.     

40Ar/39Ar and K–Ar geochronology of magmatic and hydrothermal events in a classic low-suphidation epithermal bonanza deposit: El Peñon, northern Chile

The epithermal El Peñon gold–silver deposit consists of quartz–adularia veins emplaced within a late Upper Paleocene rhyolitic dome complex, located in the Paleocene–Lower Eocene Au–Ag belt of northern Chile. Detailed K–Ar and ⁴⁰Ar/³⁹Ar geochronology on volcano–plutonic rocks and hydrothermal minerals were carried out to constrain magmatic and hydrothermal events. The Paleocene to Lower Eocene magmatism in the El Peñon area is confined to a rhomb-shaped basin, which was controlled by N–S trending normal faults and both NE- and NW-trending transtensional fault systems. The earliest products of the basin-filling sequences comprise of Middle to Upper Paleocene (～59–55 Ma) welded rhyolitic ignimbrites and andesitic to dacitic lavas, with occasional dacitic dome complexes. Later, rhyolitic and dacitic dome complexes (～55–52 Ma) represent the waning stages of volcanism during the latest Upper Paleocene and the earliest Eocene. Lower Eocene porphyry intrusives (～48–43 Ma) mark the end of the magmatism in the basin and a change to a compressive tectonomagmatic regime. ⁴⁰Ar/³⁹Ar geochronology of hydrothermal adularia from the El Peñon deposit yields ages between 51.0±0.6 and 53.1±0.5 Ma. These results suggest that mineralization occurred slightly after the emplacement of the El Peñon rhyolitic dome at 54.5±0.6 Ma (⁴⁰Ar/³⁹Ar age) and was closely tied to later dacitic–rhyodacitic bodies of 52 to 53 Ma (K–Ar ages), probably as short-lived pulses related to single volcanic events.     

Patterns of mineral transformations in clay gouge,with examples from low-angle normal fault rocks in the western USA

Neoformed minerals in shallow fault rocks are increasingly recognized as key to the behavior of faults in the elasto-frictional regime, but neither the conditions nor the processes which wall-rock is transformed into clay minerals are well understood. Yet, understanding of these mineral transformations is required to predict the mechanical and seismogenic behavior of faults. We therefore present a systematic study of clay gouge mineralogy from 30 outcrops of 17 low-angle normal faults (LANF's) in the American Cordillera to demonstrate the range and type of clay transformations in natural fault gouges. The sampled faults juxtapose a wide and representative range of wall rock types, including sedimentary, metamorphic and igneous rocks under shallow-crustal conditions. Clay mineral transformations were observed in all but one of 28 faults; one fault contains only mechanically derived clay-rich gouge, which formed entirely by cataclasis.Clay mineral transformations observed in gouges show four general patterns: 1) growth of authigenic 1M_d illite, either by transformation of fragmental 2M₁ illite or muscovite, or growth after the dissolution of K-feldspar. Illitization of fragmental illite–smectite is observed in LANF gouges, but is less common than reported from faults with sedimentary wall rocks; 2) ‘retrograde diagenesis’ of an early mechanically derived chlorite-rich gouge to authigenic chlorite–smectite and saponite (Mg-rich tri-octahedral smectite); 3) reaction of mechanically derived chlorite-rich gouges with Mg-rich fluids at low temperatures (50–150 °C) to produce localized lenses of one of two assemblages: sepiolite + saponite + talc + lizardite or palygorskite +/− chlorite +/− quartz; and 4) growth of authigenic di-octahedral smectite from alteration of acidic volcanic wall rocks. These transformation groups are consistent with patterns observed in fault rocks elsewhere. The main controls for the type of neoformed clay in gouge appear to be wall-rock chemistry and fluid chemistry, and temperatures in the range of 60–180 °C.     

40Ar/39Ar ages and 40Ar* concentrations of fine-grained sediment fractions from North Atlantic Heinrich layers

New K/Ar ages based on ⁴⁰Ar/³⁹Ar incremental heating of <2- and 2–20-μm size fractions of the well-characterized, carbonate-bearing Heinrich layers of core V28-82 in the eastern North Atlantic are 846–1049 Ma, overlapping with conventional K/Ar ages from the same Heinrich layers on the Dreizack seamounts of 844–1074 Ma. This agreement suggests the equivalence of the methods in fine-grained terrigenous sediments. Additionally, Heinrich layer H2 yielded a ⁴⁰Ar/³⁹Ar-based K/Ar age of 970±4 from Orphan Knoll in the southern Labrador Sea, within the range found in eastern North Atlantic Heinrich layers. Thus, the K/Ar data are robust in their indication of a dominant Labrador Sea ice-rafted source to even the finest sediment fraction in the eastern North Atlantic during the massive detrital carbonate-bearing Heinrich events of the last glacial cycle (H1, H2, H4, H5). Close correspondence of the radiogenic argon concentration (⁴⁰Ar*) from the de-carbonated <63-μm fractions from V28-82 with the <2- and 2–16-μm fractions from the Driezack seamounts demonstrates that this measurement is a rapid and reliable method for correlating these layers within their belt of distribution.A ⁴⁰Ar/³⁹Ar-based K/Ar age of 433±5 million years for H11 in V28-82 is within the range of published data from background sediments in the eastern North Atlantic, and is consistent with published results across this interval in the Driezack seamounts. In contrast, the ⁴⁰Ar/³⁹Ar-based K/Ar age of H11 in the western Atlantic core EW9303-JPC37 is 614±5 million years. A brick red sample from approximately the interval of H3 of core EW9303-GGC40 yielded a ⁴⁰Ar/³⁹Ar-based K/Ar age of 567±1 million years, comparable to the published range of 523–543 Ma from the 2–16-μm fractions from that interval on the Dreizack seamounts. Both JPC37 and GGC40 are located in the path of the North Atlantic Drift. The older ages from western samples of H3 and H11 may result from dilution of a Hudson Strait source or an elevated age from southeastern Laurentide sources.     

When will it end? Long-lived intracontinental reactivation in central Australia

The post-Mesoproterozoic tectonometamorphic history of the Musgrave Province, central Australia, has previously been solely attributed to intracontinental compressional deformation during the 580 -520 Ma Petermann Orogeny. However, our new structurally controlled multi-mineral geochronology results,from two north-trending transects, indicate protracted reactivation of the Australian continental interior over ca. 715 million years. The earliest events are identified in the hinterland of the orogen along the western transect. The first tectonothermal event, at ca. 715 Ma, is indicated by40 Ar/39 Ar muscovite and U e Pb titanite ages. Another previously unrecognised tectonometamorphic event is dated at ca. 630 Ma by Ue Pb analyses of metamorphic zircon rims. This event was followed by continuous cooling and exhumation of the hinterland and core of the orogen along numerous faults, including the Woodroffe Thrust,from ca. 625 Ma to 565 Ma as indicated by muscovite, biotite, and hornblende40 Ar/39 Ar cooling ages. We therefore propose that the Petermann Orogeny commenced as early as ca. 630 Ma. Along the eastern transect,40 Ar/39 Ar muscovite and zircon(Ue Th)/He data indicate exhumation of the foreland fold and thrust system to shallow crustal levels between ca. 550 Ma and 520 Ma, while the core of the orogen was undergoing exhumation to mid-crustal levels and cooling below 600-660℃. Subsequent cooling to 150 -220℃ of the core of the orogen occurred between ca. 480 Ma and 400 Ma(zircon [Ue Th]/He data)during reactivation of the Woodroffe Thrust, coincident with the 450 -300 Ma Alice Springs Orogeny.Exhumation of the footwall of the Woodroffe Thrust to shallow depths occurred at ca. 200 Ma. More recent tectonic activity is also evident as on the 21 May, 2016(Sydney date), a magnitude 6.1 earthquake occurred, and the resolved focal mechanism indicates that compressive stress and exhumation along the Woodroffe Thrust is continuing to the present day. Overall, these results demonstrate repeated amagmatic reactivation of the continental interior of Australia for ca. 715 million years, including at least 600 million years of reactivation along the Woodroffe Thrust alone. Estimated cooling rates agree with previously reported rates and suggest slow cooling of 0.9 -7.0℃/Ma in the core of the Petermann Orogen between ca. 570 Ma and 400 Ma. The long-lived, amagmatic, intracontinental reactivation of central Australia is a remarkable example of stress transmission, strain localization and cratonization-hindering processes that highlights the complexity of Continental Tectonics with regards to the rigid-plate paradigm of Plate Tectonics.     

Age and origin of charoitite,Malyy Murun massif,Siberia, Russia

Сharoitite consists of gem-quality mineral charoite and subordinate quartz, aegirine, K-feldspar, tinaksite, canasite, and some other minerals. This rock type is known only from one locality in the world associated with the Early Cretaceous (131.3 ± 2.4 Ma, K–Ar age) Malyy Murun syenite massif, Siberia, Russia. Although charoitite mineralogy is well known, there is disagreement whether it reflects metasomatic or magmatic activity. In order to understand when the charoitites formed we attempted to date it by ⁴⁰Ar/³⁹Ar incremental step-heating and laser ablation techniques. Our results show that the fibrous structure of water-bearing charoite does not retain radiogenic argon. Laser ablation ⁴⁰Ar/³⁹Ar for K-feldspar and tinaksite from the charoitite yielded several age clusters even from the same mineral grain. The oldest cluster of 134.1 ± 2.9 Ma for the K-feldspar agrees with the age of the Malyy Murun syenites. The youngest age of 113.3 ± 3.4 Ma for charoitite K-feldspar overlaps with the youngest of published K–Ar ages (112 ± 5 Ma) for one K-feldspar sample of the Malyy Murun syenite. Tinaksite is characterized by a similar spread of ages (from 133.0 ± 3 Ma to 115.7 ± 4.3 Ma) within a single grain. We suggest that charoitites originated due to the interaction of metasomatic agents derived from the Malyy Murun magma and country rocks. Timing of magma emplacement and charoitite crystallization is reflected by the older cluster of ages, whereas the younger ages are due to a secondary process.     

P–T–time (phengite Ar closure) history of spatially close-outcropping HP and UHP oceanic eclogites (southwestern Tianshan): implication for a potential deep juxtaposing process during exhumation?

ABSTRACT

The Chinese southwestern Tianshan HP–UHP/LT metamorphic complex possesses well-preserved mafic layers, tectonic slices/blocks, boudins/lens of different sizes, and lithology embedded within dominant metavolcanoclastics. A recent study on the ultra-high pressure (UHP) eclogite revealed a short timescale of exhumation (≤10 Ma, ~315 ± 5 Ma). However, controversies still exist on some key questions: (1) the reasonable interpretation of spatially close-outcropped high pressure (HP) and UHP slices with respect to regional geodynamics, and (2) if the previous regional scatter Ar–Ar ages proved the existence of internally coherent sub-belts or troubled by dating on samples with notable ⁴⁰Ar retention. This study focusses on detailed P–T–time (phengite Ar closure) recovery of samples from a HP eclogite lens and its host rock, the UHP thick-layered eclogite. Based on data from bulk–rock, microprobe analysis, and muscovite Ar–Ar chronological dating, we link phengite growth to potential garnet growth stages via thermodynamic modelling. Facilitated by the P–T–Ar retention% graph, we collect all the regional muscovite Ar–Ar data together with results in this study for evaluating the significance of regional muscovite Ar–Ar ages and set back to geodynamics. According to modelling results, the HP lens eclogite reached peak metamorphism at ~550°C, 2.50 GPa with an Ar–Ar muscovite plateau age of 316.9 ± 1.0 Ma that could date the mass phengite growth event during prograde metamorphism. In contrast, the UHP layered eclogite experienced UHP peak burial at ~510°C, 2.95 GPa, and then to HP peak metamorphism at ~560°C, 2.60 GPa with ~311.6 ± 0.7 Ma plateau age that may constrain the cooling age during early exhumation. Noteworthy, both of them share a quite similar early exhumation path despite bearing contrasting prograde metamorphic experiences. With considering updated regional exhumation pattern, this might imply the existence of a potential deep juxtaposing (capture) process between HP slices and exhumating UHP complex, at about 45–60 km depth along subduction plate interface.     

Timing and formation of porphyry Cu–Mo mineralization in the Chuquicamata district, northern Chile: new constraints from the Toki cluster

The recently discovered Toki cluster, which includes the Toki, Quetena, Genoveva, Miranda, and Opache porphyry Cu–Mo prospects, is located 15 km south–southwest of the Chuquicamata–Radomiro Tomic mines in northern Chile. These prospects occur in an area of 5?×?6 km and are completely covered with Neogene alluvial deposits. Inferred resources for the cluster are estimated at about 20 Mt of fine copper, with Toki and Quetena contributing ～88 % of these resources. Mineralization in these deposits is associated with tonalite porphyries that intruded andesites and dacites of the Collahuasi Group and intrusions of the Fortuna–Los Picos Granodioritic Complex. Hypogene mineralization in the Toki cluster consists mainly of chalcopyrite–bornite with minor molybdenite with mineralization grading outward to a chalcopyrite–pyrite zone and ultimately to a pyrite halo. Alteration is dominantly of the potassic type with K-feldspar and hydrothermal biotite. Sericitic alteration is relatively restricted to late quartz–pyrite veins (D-type veins). Previous K–Ar geochronology for the cluster yielded ages within a range of 34 to 40 Ma. Four new Re–Os ages for Toki indicate that molybdenite mineralization occurred in a single pulse at ～38 Ma. Re–Os ages for three different molybdenite samples from Quetena are within error of the Toki mineralization ages. These ages are concordant with a new zircon U–Pb age of 38.6?±?0.7 Ma from the tonalite porphyry in Quetena. Two Re–Os ages for Genoveva (38.1?±?0.2 and 38.0?±?0.2 Ma) are also within error of the Toki and Quetena molybdenite ages. Four Re–Os molybdenite ages for Opache range between 36.4 and 37.6 Ma. The Miranda prospect is the youngest with an age of ～36 Ma. Four new Re–Os ages for the Chuquicamata deposit range between 33 and 32 Ma, whereas nine new ⁴⁰Ar/³⁹Ar ages of biotite, muscovite, and K-feldspar range between 32 and 31 Ma. Analyzed molybdenites have Re and Os concentrations that vary between 21–3,099 ppm and 8–1,231 ppb, respectively. The highest Re and Os concentrations are found in the Toki prospect. Three new ⁴⁰Ar/³⁹Ar ages for the Toki cluster are younger than the Re–Os mineralization ages. The age spectra for these three samples show evidence of excess argon and have similar inverse isochron ages of 35 Ma that probably reflect a late hydrothermal phyllic event. The new geochronological data presented here for the Toki cluster indicate that molybdenite mineralization occurred within a very short period, probably within 2 Ma, and synchronously (at ～38 Ma) in three mineralization centers (Toki, Quetena, and Genoveva). Furthermore, mineralization at the Toki cluster preceded the emplacement of the Chuquicamata deposit (35–31 Ma) and indicates that porphyry Cu–Mo mineralization occurred episodically over a period of several million years in the Chuquicamata district.     

Exhumation and uplift of the Sierras Pampeanas: preliminary implications from K–Ar fault gouge dating and low-T thermochronology in the Sierra de Comechingones (Argentina)

The Sierras Pampeanas in central and north-western Argentina constitute a distinct morphotectonic feature between 27°S and 33°S. The last stage of uplift and deformation in this area are interpreted to be closely related to the Andean flat-slab subduction of the Nazca plate beneath the South American plate. K–Ar fault gouge dating and low-temperature thermochronology along two transects within the Sierra de Comechingones reveal a minimum age for the onset of brittle deformation about 340 Ma, very low exhumation rates since Late Paleozoic time, as well as a total exhumation of about 2.3 km since the Late Cretaceous. New Ar–Ar ages (7.54–1.91 Ma) of volcanic rocks from the San Luis volcanic belt support the eastward propagation of the flat-slab magmatic front, confirming the onset of flat-slab related deformation in this region at 11.2 Ma. Although low-temperature thermochronology does not clearly constrain the signal of the Andean uplift, it is understood that the current structural relief related to the Comechingones range has been achieved after the exhumation of both fault walls (circa 80–70 Ma).