Ion microprobe baddeleyite and zircon ages for Late Archaean mafic dykes of the Pilbara Craton,Western Australia

Ion microprobe U–Th–Pb analyses of baddeleyite and zircon yield precise ages for several mafic intrusions in the Pilbara Craton of Western Australia. Baddeleyite was dated from four dolerite dykes of the north‐northeast‐trending Black Range swarm intruded into granitoid‐greenstone basement in the northern part of the craton. The mean ²⁰⁷Pb*/²⁰⁶Pb* age of 2772 ± 2 Ma, interpreted as an unambiguous age of emplacement for the dykes, is within error of previous ion microprobe U–Pb zircon ages for the Mt Roe flood basalts and confirms that the dykes acted as feeders to the volcanic rocks. The Sylvania Inlier, in the southeastern Pilbara Craton, also contains north‐northeast‐trending dykes that were correlated previously with the Black Range swarm. Based on concordant and discordant zircon analyses from samples of two dykes, the best estimate of the age of the Sylvania dykes is 2747 ± 4 Ma. The Sylvania dykes thus appear to be significantly younger than, and hence unrelated to, the Black Range swarm, but may have acted as feeders to younger volcanic units in the Fortescue Group such as the Kylena Formation.     

A U‐Pb zircon study of the Mesoproterozoic Charleston Granite,Gawler Craton,South Australia

The Charleston Granite from the Gawler Craton, South Australia, has been dated by the ion‐microprobe U‐Pb zircon method at 1585 ± 5 Ma (2σ). This confirms previous interpretations of population‐style U‐Pb zircon analyses which record a slightly older age due to the presence of inherited zircon. Inherited cores are present in many zircon crystals, and while the age of some cores can not be accurately determined due to extreme loss of radiogenic Pb, others have ages of ～ 1780, ～ 1970, and > 3150 Ma. These cores record a diverse crustal heritage for the Charleston Granite and indicate that ancient crustal material (> 3150 Ma) is present at depth in the Gawler Craton. This is also suggested by available Nd isotopic data for both the Charleston Granite and other Gawler Craton Archaean rocks. The Rb‐Sr and K‐Ar biotite ages from the Charleston Granite of 1560 to 1570 Ma are close to the U‐Pb zircon crystallization age and suggest that the granite has not experienced sustained thermal disturbance (> 250° C) since emplacement and cooling. However, a much younger Rb‐Sr total‐rock age of 1443 ± 26 Ma probably reflects low‐temperature disturbance to the Sr isotope system in feldspar.     

The Southward Extension of Cathaysia Block: Evidence from Zircon UPb Dates of Borehole Volcanics in the Northern South China Sea

Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA-ICP-MS zircon U-Pb dating,including basalt and andesite from Borehole SCSV1 and volcanic agglomerate from Borehole SCSV2,respectively.A total of 162 zircon U-Pb dates for them cover an age range from Neoarchean to Eocene,in which the pre-Paleocene data dominate.The Paleogene dates of 62.5±2.2 Ma and 42.1±2.9 Ma are associated with two igneous episodes prior to opening of South China Sea basin.Those pre-Paleocene zircons are inherited zircons mostly with magmatogenic oscillatory zones,and have REE features of crustal zircon.Zircon U-Pb dates of 2518–2481 Ma,1933– 1724 Ma,and 1094–1040 Ma from the SCSV1 volcanics,and 2810–2718 Ma,2458–2421 Ma,and 1850 –993.4 Ma from the SCSV2 volcanics reveal part of Precambrian evolution of the northern South China Sea,well comparable with age records dated from the Cathaysia block.The data of 927.0±6.9 Ma and 781±38 Ma dated from the SCSV2 coincide with amalgamation between Yangtze and Cathaysia blocks and breakup of the Rodinia,respectively.The age records of Caledonian orogeny from the Cathaysia block are widely found from our volcanic samples with concordant mean ages of 432.0±5.8 Ma from the SCSV1 and of 437±15 Ma from the SCSV2.The part of the northern South China Sea resembling the Cathaysia underwent Indosinian and Yanshannian tectonothermal events.Their age signatures from the SCSV1 cover 266.5±3.5 Ma,241.1±6.0 Ma,184.0±4.2 Ma,160.9±4.2 Ma and 102.8±2.6 Ma,and from the SCSV2 are 244±15 Ma,158.1±3.5 Ma,141±13 Ma and 96.3±2.1 Ma.Our pre-Paleogene U-Pb age spectra of zircons from the borehole volcanics indicate that the northern South China Sea underwent an evolution from formation of Precambrian basement,Caledonian orogeny,and Indosinian orogeny to Yanshannian magmatism.This process can be well comparable with the tectonic evolution of South China,largely supporting the areas of the northern South China Sea as part of southward extension of the Cathaysia.     

Paleomagnetism and U–Pb geochronology of the Black Range dykes,Pilbara Craton,Western Australia: a Neoarchean crossing of the polar circle

We report a new paleomagnetic pole for the Black Range Dolerite Suite of dykes, Pilbara craton, Western Australia. We replicate previous paleomagnetic results from the Black Range Dyke itself, but find that its magnetic remanence direction lies at the margin of a distribution of nine dyke mean directions. We also report two new minimum ID-TIMS ²⁰⁷Pb/²⁰⁶Pb baddeleyite ages from the swarm, one from the Black Range Dyke itself (>2769 ± 1 Ma) and another from a parallel dyke whose remanence direction lies near the centre of the dataset (>2764 ± 3 Ma). Both ages are slightly younger than a previous combined SHRIMP ²⁰⁷Pb/²⁰⁶Pb baddeleyite weighted mean date from the same swarm, with slight discordance interpreted as being caused by thin metamorphic zircon overgrowths. The updated Black Range suite mean remanence direction (D = 031.5°, I = 78.7°, k = 40, α₉₅ = 8.3°) corresponds to a paleomagnetic pole calculated from the mean of nine virtual geomagnetic poles at 03.8°S, 130.4°E, K = 13 and A₉₅ = 15.0°. The pole's reliability is bolstered by a positive inverse baked-contact test on a younger Round Hummock dyke, a tentatively positive phreatomagmatic conglomerate test, and dissimilarity to all younger paleomagnetic poles from the Pilbara region and contiguous portions of Australia. The Black Range pole is distinct from that of the Mt Roe Basalt (or so-called ‘Package 1’ of the Fortescue Group), which had previously been correlated with the Black Range dykes based on regional stratigraphy and imprecise SHRIMP U–Pb ages. We suggest that the Mt Roe Basalt is penecontemporaneous to the Black Range dykes, but with a slight age difference resolvable by paleomagnetic directions through a time of rapid drift of the Pilbara craton across the Neoarchean polar circle.     

Ages of internal granitoids in the Southern Cross region,Yilgarn Craton,Western Australia,and their crustal evolution and tectonic implications

Southern Cross, where gold deposits are sited in narrow greenstone belts surrounding granitoid domes, was one of the earliest gold mining centres in Western Australia. SHRIMP U–Pb zircon and Pb‐isotope studies of the largest granitoid dome, the Ghooli Dome (80 × 40 km), provide important constraints on the crustal evolution and structural history of the central part of the Archaean Yilgarn Craton, Western Australia, which includes Southern Cross. The north‐northwest‐south‐southeast‐oriented ovoid Ghooli Dome has a broadly concentric foliation that is subhorizontal or gently dipping in its central parts and subvertical along its margins. Foliated granitoids in the dome are dated at ca 2724 ± 5 and 2688 ± 3 Ma using the SHRIMP U–Pb zircon and Pb–Pb isochron methods, respectively. These new data, together with the published SHRIMP U–Pb zircon age of 2691 ± 7 Ma at another locality, 20 km from the centre of the Koolyanobbing Shear Zone, suggest that the Ghooli Dome was emplaced at ca 2.72–2.69 Ga. Because the Ghooli Dome and the other domes, which are enveloped by narrow greenstone belts, are cut by the >650 km‐long and 6–15 km‐wide Koolyanobbing Shear Zone, the ca 2.69 Ga age is interpreted as the maximum age of the last major movement on this structure. The pre‐2.69 Ga history, if any, of the shear zone remains unknown. The shear zone is intruded by an undeformed porphyritic granitoid which has a SHRIMP U–Pb zircon age of 2656 ± 4 Ma. This age is, thus, the minimum age of major movement along this shear zone. Post‐gold mineralisation pegmatitic‐leucogranite from the Nevoria gold mine has a SHRIMP U–Pb zircon age of 2634 ± 4 Ma, with xenocrystic zircon cores of ca 2893 ± 6 Ma, constraining the minimum age of gold mineralisation there to ca 2.63 Ga. The ca 2.72–2.69 Ga granitoids also contain ca 2.98 and 2.78 Ga xenocrystic zircon cores, suggesting an extensive crustal prehistory for their source. Whereas there is a general temporal relationship between the periods of older (ca 3.0 Ga) and younger (ca 2.80 and 2.73 Ga) volcanism and the older (2.98, 2.78 and 2.72–2.69 Ga) granitoid intrusions, there is no known volcanism temporally associated with the 2.65–2.63 Ga granitoid intrusions in the Yilgarn Craton. Other heat sources and/or tectonic processes, required for the generation of these intrusions, are interpreted to be related to a lithospheric delamination event related to continental collision.     

Geochronology of high-pressure mafic granulite dykes in SW Sweden: tracking the P–T–t path of metamorphism using Hf isotopes in zircon and baddeleyite

Although the U–Pb zircon chronometer has been widely used for dating metamorphism in moderate‐ to high‐grade rocks, it is generally difficult to link the U–Pb age of zircon to specific metamorphic reactions. In this study, the initial Hf isotopic composition of secondary zircon is compared with the evolution of Hf isotopic composition of the bulk sample, back‐projected from the measured value through time. This approach may enhance the interpretation of radiometric ages performed on metamorphic mineral assemblages. Here, U–Pb, Sm–Nd and Lu–Hf geochronology and thermobarometry have been integrated and applied to two metamorphosed diabase dykes in the Sveconorwegian orogen, SW Sweden. The dykes are located ～5 km east of the NNE‐trending Göta Älv deformation zone in the Idefjorden terrane, and trend parallel to this zone. The Lunden dyke is recrystallized into a coronitic, granulite facies assemblage. U–Pb isotopic analyses of baddeleyite in this dyke indicate an emplacement age of c. 1300 Ma. Thermobarometric techniques applied to garnet and omphacitic clinopyroxene coronas indicate high‐pressure metamorphism at ～15 kbar and ～740 °C. The growth of polycrystalline zircon at the expense of baddeleyite occurred at 1046 ± 6 Ma. The identical Hf isotopic composition of polycrystalline zircon and baddeleyite shows that the baddeleyite‐to‐zircon transition took place before Hf equilibration among the other metamorphic minerals and, hence the c. 1046 Ma age of polycrystalline zircon sets an upper age limit of metamorphism of this sample. The Haregården dyke is recrystallized into a granoblastic transitional upper amphibolite to granulite facies assemblage. The estimated P–T conditions are ～10 kbar and ～700 °C. Analyses of small (～30 μm), clear and round zircon in this sample yield a Concordia U–Pb age of 1026 ± 4 Ma, which is indistinguishable from the Lu‐Hf and Sm‐Nd mineral isochron ages of 1027 ± 9 and 1022 ± 34 Ma, respectively. This type of secondary zircon plots at the lower end of the Lu‐Hf isochron and indicates simultaneous growth with garnet at c. 1026 Ma, a time when Hf isotopic equilibrium among minerals must have been reached.     

U/Pb and Pb/Pb zircon ages for arc-related intrusions of the Bolu Massif (W Pontides, NW Turkey): evidence for Late Precambrian (Cadomian) age

We present new U/Pb and Pb/Pb radiometric age data from two tectono-stratigraphic units of the regionally extensive Bolu Massif, in the W Pontides (İstanbul Fragment), N Turkey. A structurally lower unit (Sünnice Group) is cut by small meta-granitic intrusions, whereas the structurally higher unit comprises meta-volcanic rocks (Çaşurtepe Fm) cut by meta-granitic plutons (Tüllükiriş and Kapıkaya plutons). U/Pb single-crystal dating of zircons from the Kapıkaya Pluton yielded a concordant cluster, with a mean ²³⁸U/²⁰⁶Pb age of 565.3 ± 1.9 Ma. Zircons from the Tüllükiriş Pluton (affected by Pb loss) gave a ²⁰⁷Pb/²⁰⁶Pb age of 576 ± 6 Ma age (Late Precambrian). Small meta-granitic intrusions cutting the Sünnice Group yielded a less precise ²⁰⁷Pb/²⁰⁶Pb age of 262 ± 19 Ma (Early Permian). The older ages from the Bolu Massif confirm the existence of latest Precambrian arc magmatism related to subduction of a Cadomian ocean. We infer that the Bolu Massif represents a fragment of a Cadomian active margin. Cadomian orogenic units were dispersed as exotic terranes throughout the Variscan and Tethyan orogens, and the Bolu Massif probably reached its present position prior to latest Palaeozoic time. Our dating results also confirm that NW Turkey was affected by Hercynian magmatism related to subduction of Palaeotethys, as inferred for other areas of the Pontides.     

Geochronology and Significance of Granites Associated with Gold Deposits in the Jidong Area, China

The Jidong area is located on the north margin of the North China craton. It is a nucleus composed of the oldest rocks in China. Precambrian metamorphic rocks with various Phanerozoic granitoids invaded are widespread. Gold deposits here have close spatial relations to granitoids. Some deposits occur within them and others in the outer zone of the contact belt of the intrusion, extending thousands of metres. There have been controversial views in regard to the relations of the deposits to the intrusions although traditional techniques have been used to date the intrusions. In order to solve such a problem, the SHRIMP technique was adopted to date the U-Pb ages of zircon collected from the Yuerya intrusion which hosts the large-sized Yuerya Au deposit and Qingshankou intrusion 2 km away from the Jinchangyu (larger-sized) Au deposit. Analysis shows that the ages of 175±1 Ma and 174±3 Ma for Yuerya intrusion and the age of 199±2 Ma for Qingshankou granite indicate the Early Yanshanian stage of the Meso-     

Qingbaikouan and Crygenian in South China: Constraints by SHRIMP Zircon U-Pb dating

The Qingbaikouan System is the lowest unit of the Neoproterozoic Erathem in Chinese stratigraphic succession,and it now provides a precise geochronological framework and geological time scale for mapping and stratal correlation in China.However,a sensitive high-resolution ion microprobe （SHRIMP） U-Pb zircon age date （1368±12 Ma） obtained from a bentonite in the Qingbaikouan Xiamaling Formation indicates that it belongs to the Mesoproterozoic Erathem instead.This change is a milestone in understanding the Precambrian Stratigraphic Time Scale in China,and it has had great influence on Precambrian correlations in Asia.Otherwise,a large amount of geochronological work has been done in the ＂Jiangnan Orogen Belt＂ of South China,and new isotopic data have redefined the traditional recognition of metamorphosed Mesoproterozoic strata from the Sibao orogeny to the Neoproterozoic Erathem.Based on SHRIMP zircon U-Pb age data,the authors regard the Sibao orogeny （equal to the Wuling orogeny） as a movement at ca 820 Ma,meaning that the Sibao orogeny was not equivalent to the Grenvillian orogeny.Finally,we report here the first SHRIMP U-Pb age of the boundary between the top of the Qingbaikouan Gongdong Formation （786.8±5.6 Ma） and the bottom of the Chang＇an （diamictite） Formation （778.4±5.2 Ma）,which is the age of the lowest diamictite of the Nanhuan System in China.     

Age of granite emplacement in the Norseman region of Western Australia

Ion probe U‐Th‐Pb dating of zircons from the Late Archaean granites of the Norseman region of the southeastern Yilgarn shows the existence of two distinct magmatic episodes. Large regional tonalite and granodiorite plutons were emplaced between 2685 and 2690 Ma, whereas large regional granite, and small tonalite and leucogranite plutons that intrude the greenstones have ages of 2660–2665 Ma. A small body of granite that intrudes the western edge of the greenstones has an inferred emplacement of 2672 ± 7Ma, and contains inherited zircon that is ～2800 Ma. The monzogranite core from a second pluton in a similar structural position also contains ～2800 Ma zircon; this age is similar to published Sm‐Nd and Rb‐Sr whole rock ages for banded gneisses associated with other members of this suite of domal plutons and is interpreted as representing the age of a significant component within the source region for these distinctive rocks.

Available geochemical and isotopic data are interpreted as indicating derivation of both the older granodiorite and younger granite suites through anatexis of pre‐existing crust of broadly andesitic composition, whereas both the domal granites and the small, late tonalite plutons could have been derived by anatexis of heterogeneous material similar to that represented by the banded gneisses.

If regional metamorphism was related to the emplacement of large volumes of felsic magma within the upper crust, as suggested by Binns et al. (1976), then the Norseman area has probably undergone two periods of regional metamorphism of comparable intensity at approximately 2660 and 2685 Ma.     

Sourcing Olive Jars Using U‐Pb Ages of Detrital Zircons: A Study of 16th Century Olive Jars Recovered from the Solomon Islands

We present U‐Pb ages of zircons extracted from olive jars recovered from two sites associated with Alvaro de Mendaña y Neyra's colonising expedition to the Solomon Islands, c. 1595–1596 A.D. The olive jars were previously associated with Panamanian and Peruvian origins based on petrological and geochemical studies. To further define provenance, 143 zircons were extracted from five olive jar sherds, analyzed and dated. The resultant U‐Pb ages range from the Archaean to the Cenozoic (2977.2 ± 29.0–3.2 ± 4.0 Ma), but the dominance of Cretaceous and Palaeogene ages (∼ 90% of the total age population is between ∼ 145 and 23 Ma) supports a Peruvian origin based on comparative geology, with the Coastal Batholith of Peru a prime candidate area of ceramic production. These results are significant for the characterization of 16th Century Peruvian‐made pottery and our understanding of its production and trade.     

Ordovician high-grade metamorphism of a newly recognised late Neoproterozoic terrane in the northern Harts Range,central Australia

Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800–875 °C and >9–10 kbar) and subsequent decompression in a kilometre‐scale, E‐W striking zone of noncoaxial, high‐grade (c. 700–735 °C and 5.8–6.4 kbar) deformation. However, new SHRIMP U‐Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta‐volcaniclastics) yield ²⁰⁶Pb/²³⁸U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield ²⁰⁶Pb/²³⁸U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400–300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475–460 Ma & 400–300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300–1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed.     

The regional significance of Cretaceous magmatism and metamorphism in Fiordland, New Zealand, from U–Pb zircon geochronology

The western Fiordland Orthogneiss (WFO) is an extensive composite metagabbroic to dioritic arc batholith that was emplaced at c. 20–25 km crustal depth into Palaeozoic and Mesozoic gneiss during collision and accretion of the arc with the Mesozoic Pacific Gondwana margin. Sensitive high‐resolution ion microprobe U–Pb zircon data from central and northern Fiordland indicate that WFO plutons were emplaced throughout the early Cretaceous (123.6 ± 3.0, 121.8 ± 1.7, 120.0 ± 2.6 and 115.6 ± 2.4 Ma). Emplacement of the WFO synchronous with regional deformation and collisional‐style orogenesis is illustrated by (i) coeval ages of a post‐D1 dyke (123.6 ± 3.0 Ma) and its host pluton (121.8 ± 1.7 Ma) at Mt Daniel and (ii) coeval ages of pluton emplacement and metamorphism/deformation of proximal paragneiss in George and Doubtful Sounds. The coincidence emplacement and metamorphic ages indicate that the WFO was regionally significant as a heat source for amphibolite to granulite facies metamorphism. The age spectra of detrital zircon populations were characterized for four paragneiss samples. A paragneiss from Doubtful Sound shows a similar age spectrum to other central Fiordland and Westland paragneiss and SE Australian Ordovician sedimentary rocks, with age peaks at 600–500 and 1100–900 Ma, a smaller peak at c. 1400 Ma, and a minor Archean component. Similarly, one sample of the George Sound paragneiss has a significant Palaeozoic to Archean age spectrum, however zircon populations from the George Sound paragneiss are dominated by Permo‐Triassic components and thus are markedly different from any of those previously studied in Fiordland.     

Age and nature of Cryogenian diamictites at Aksu,Northwest China: implications for Sturtian tectonics and climate

The Neoproterozoic succession in the Aksu region of northwestern China forms an unconformable boundary with the lower Precambrian Aksu basement group and consists of the Qiaoenbrak, Yuermeinak, Sugetbrak, and Chigebrak Formations. The two lowermost units include distinct glaciogenic diamictites that indicate distinct episodes of glaciation. In this study, we report the LA-ICP-MS U–Pb ages of detrital zircons and geochemical data from the lower Neoproterozoic strata. The age of the detrital zircon constrains the maximum depositional age to between 769 ± 10 and 727 ± 8 Ma for the Qiaoenbrak diamictites, which are associated with the Kaigas glaciation that occurred during the early Cryogenian period. The youngest detrital zircon age of 719 ± 9 Ma corresponds to the maximum depositional age of the Yuermeinak diamictites, which are associated with the Sturtian glaciation. The detrital zircons from the lower Neoproterozoic strata in the Aksu area indicated four peak ages of 2484, 1948, 861, and 647–581 Ma, which are consistent with the major tectonic episodes in the Tarim Block. The peak age of 2484 Ma represents an Archaean basement, which participated in the worldwide continental nuclei growth event from the late Neoarchaean to the early Palaeoproterozoic. The peak age of 1948 Ma may be associated with the assembly of the Columbia supercontinent, and the 861 and 647–581 Ma are likely associated with the break-up of the Rodinia supercontinent. The combination of geological and geochemical characteristics between the Qiaoenbrak Formation and Aksu Group indicates that the Qiaoenbrak Formation may be penecontemporaneous with the Aksu Group in an active continental margin tectonic setting. Following the break-up of the Rodinia supercontinent, the margin of the Aksu evolved into a passive margin and the Yuermeinak and Sugetbrak Formations were deposited.     

The Dabieshan Coesite-bearing Eclogite Terrain-A Late Archaean Ultra - high- Pressure Metamorphic Belt

A U -Pb zircon age of 2774±24 Ma for eclogite from the Bixiling rock body of Anhui Province, central China, indicates that the Dabieshan coesite-bearing eclogite was probably formed in the Late Archaean. A phengite Ar-Ar isochron age of 662±13 Ma for the eclogite confines also an upper limit age of its subsequent retrograde metamorphism in the Precambrian. The results of isotopic dating for such type of eclogite coincide with the geological features of its restricted occurrence within the Archaean metamaorphic terrain composed of the Dabie Group. It is believed that the Dabieshan coesite-bearing eclogite terrain might be a Late Archaean ultra-high-pressure metamorphic belt. The Dabie Mountains area was the eastward extension of the southern Qinling structural belt during the Triassic. Both the Dabie Group and the coesite-bearing eclogite hosted therein underwent a late-stage dynamic metamorphic event. The present authors have obtained a muscovite Ar-Ar isochron age of 192.6±2.8 Ma from plagioclase gn     

U–Pb Dating of Hydrothermal Zircons from the Neoproterozoic Liushanyan VMS Cu–Zn Deposit,Central China: Evidence for a Triassic Deformation Event

The Liushanyan deposit is an important volcanic‐host massive sulfide (VMS) Cu–Zn deposit in the Qinling‐Tongbai‐Dabie orogenic belt, central China, with reserve of 2.38 Mt Cu and 16.11 Mt Zn. Orebodies occur in the meta‐quartz keratophyre of the Liushanyan formation. In this paper, we present textural features and laser ablation ICP‐MS U–Pb dating results of zircons from the ore‐bearing mylonitized meta‐quartz keratophyre. The hydrothermal zircons are distinct from metamorphic zircons in this rock, showing low cathodoluminescence (CL) response and hydrothermal rims (black in CL images). They have relatively flat light rare earth element patterns and high La content and low (Sm/La)_N and Ce/Ce* values. These features are typical of hydrothermal zircons. The cores of metamorphic zircons yield a weighted mean ²⁰⁶Pb/²³⁸U age of 900 ± 26 Ma, interpreted as the volcanic and related VMS mineralizing age. Two much younger events are also recorded by zircons in this rock: (i) the Early Silurian amphibolites–greenschist facies metamorphism at 435 ± 26 Ma; and (ii) the growth of hydrothermal zircons at ca. 241 ± 1 Ma, associated with the ductile shear deformation. The Silurian metamorphic event is probably associated with the arc–continent collision, while the Triassic ductile deformation event formed in the final continent–continent collision setting.     

Young porphyries,old zircons: new constraints on the timing of deformation and gold mineralisation in the Eastern Goldfields from SHRIMP U–Pb zircon dating at the Kanowna Belle Gold Mine,Western Australia

The Kanowna Belle Gold Mine is a Late Archaean orogenic lode-gold deposit hosted by felsic volcaniclastic and intrusive rocks (porphyries) of the Kalgoorlie Terrane, Western Australia. Rare gold occurs in fragments of veins and alteration that form clasts within the Black Flag Group volcaniclastic rocks at the Kanowna Belle mine, indicating that epithermal gold mineralisation accompanied Black Flag Group volcanism. The SHRIMP U–Pb zircon age of the volcaniclastic unit is 2668±9 Ma, and xenocrystic zircons with ∼2.68, 2.70 and 2.71 Ga age groupings are common. The Black Flag Group rocks are faulted by a D1 thrust, and ∼2670 Ma is thus an older limit for regional D1 deformation. Although SHRIMP U–Pb zircon ages of felsic porphyries commonly give the best constraints on the timing of deformation and structurally controlled gold mineralisation, the data are complex and dates from single samples can be ambiguous. Four Porphyry samples from the Kanowna Belle Gold Mine were analysed. Backscattered electron and cathodoluminescence imaging show that most magmatic zircon in the porphyries is either high-U and metamict, or restricted to rims on older xenocrysts that are too narrow to be dated by SHRIMP. Some porphyries appear to have been saturated with zircon at source and contain only xenocrystic zircons. Zircons that are interpreted to be magmatic in a sample of the mineralised Kanowna Belle Porphyry gives a mean age of 2655±6 Ma. The Kanowna Belle Porphyry is cross cut by regional D2 fabrics and ∼2655 Ma is thus the maximum age for regional D2 deformation. This is a maximum age for epigenetic lode-gold mineralisation. The age of resetting of high-U zircon grains (2.63 Ga) and the age of ore-related Pb–Pb galenas (2.63 Ga) serves as an approximate date for lode-gold mineralisation. If the complex zircon history of the felsic porphyries at Kanowna Belle is typical of this suite throughout the Eastern Goldfields Province, it is clear that existing single zircon dates from this Province require reevaluation, backed up by careful backscattered and cathodoluminescence imaging and textural studies.     

Sm‐Nd and Rb‐Sr dating of Archaean gneisses,eastern Yilgarn Block,Western Australia

Sm‐Nd and Rb‐Sr isotopic data for Archaean gneisses from three localities within the eastern Yilgarn Block of Western Australia indicate that the gneisses define a precise Rb‐Sr whole rock isochron age of 2780 ± 60 Ma and an initial ⁸⁷Sr/⁸⁶Sr of 0.7007 ± 5. The Sm‐Nd isotopic data do not correspond to a single linear array, but form two coherent groups that are consistent with a c. 2800 Ma age of crust formation, with variable initial Nd. These results indicate that the gneiss protoliths existed as continental crust for a maximum period of only c. 100 Ma, and probably for a much shorter time, prior to the formation of the 2790 ±30 Ma greenstones.     

Age relationships in supracrustal sequences of the northern part of the Murchison Terrane,Archaean Yilgarn Craton,Western Australia: A combined field and zircon U–Pb study

Mapping carried out in the northern Murchison Terrane of the Archaean Yilgarn Craton, Western Australia, shows that correlation of units between isolated greenstone belts is very difficult and an informal stratigraphic subdivision is proposed where the greenstone sequences have been divided into a number of assemblages. The assemblages may not necessarily be time equivalent throughout the region. The lower units (Assemblages 1–3) consist of ultramafic, mafic and intermediate volcanic rocks deposited without significant breaks in volcanism. Felsic volcanic packages (Assemblage 4) are conformable with underlying units, but are spatially restricted. Discordant units of graphitic sedimentary rocks are developed along major crustal structures (Assemblage 5). SHRIMP and conventional U–Pb study of zircons reveal that felsic volcanic rocks of Assemblage 4 in the Dalgaranga Greenstone Belt were emplaced at 2747 ± 5 Ma, whereas those in the adjacent Meekatharra — Mt Magnet Greenstone Belt range in age from 2762 ± 6 to 2716 ± 4 Ma. The age of emplacement of a differentiated gabbro sill in the Dalgaranga Greenstone Belt at 2719 ± 6 Ma places a maximum age on major folding in the belt. The presence of 2.9–3.0 Ga inherited zircons in some of the felsic volcanic rocks indicates contamination with, or reworking of, underlying 3 Ga sialic crust. This distinguishes the Murchison Terrane from the central parts of the Eastern Goldfields terranes to the south, where there is no evidence for a 3 Ga imprint in zircons from volcanic or granitic rocks, and also from the Narryer Gneiss Terrane to the north and west, which is composed of older gneisses and granitoids. The ca 2.76–2.71 Ga felsic volcanism in the Murchison Terrane is significantly older than 2.71–2.67 Ga felsic volcanism in the Eastern Goldfields lending support to models advocating assemblage of the craton by terrane accretion.     

Precise conventional and SHRIMP baddeleyite U‐Pb age for the Binneringie Dyke,near Narrogin,Western Australia

A precise baddeleyite U‐Pb age of 2418 ± 3 Ma is reported for the westerly extension of the Binneringie Dyke in the south‐western Yilgarn Craton of Western Australia. The Binneringie Dyke is a member of the large and extensive Widgiemooltha dyke swarm that trends east‐west across the craton. This age is similar to ages of major dyke swarms In other Archaean Cratons and supports the hypothesis that dykes of the Widgiemooltha swarm are part of a worldwide Palaeoproterozoic mafic magmatic event at ca 2420 Ma.