Facies architecture of the felsic lava‐dominated host sequence to the Thalanga massive sulfide deposit,Lower Ordovician,northern Queensland

The Thalanga volcanic‐hosted massive sulfide deposit occurs in the Cambro‐Ordovician Mt Windsor Subprovince in northern Queensland. The orebody comprises steeply dipping, stratiform, sheet‐like, polymetallic massive sulfide lenses. Overall, the volcanic facies architecture at Thalanga is dominated by quartz‐ and/or feldspar‐phyric lavas and synvolcanic intrusions that comprise coherent facies and in situ and resedimented autoclastic facies. Systematic phenocryst logging (mineralogy, abundance, size) has been used to discriminate separate emplacement units of rhyolite in the footwall and dacite in the hangingwall. Some of the petrographically different rhyolite and dacite types can also be distinguished using immobile‐element geochemistry. Rhyolitic lavas and intrusions in the footwall are weakly to strongly altered. Apparent clastic textures resulting from hydrothermal alteration and metamorphism are widely developed in the coherent facies. Genuine clastic textures are characterised by clasts with randomly oriented internal laminar or banded fabric (e.g. rotated, flow‐laminated clasts), marked and consistent differences in quartz phenocryst abundance and/or size range between clasts and matrix, and normal grading. Mass‐flow‐emplaced, rhyolitic breccia units delineate palaeo‐sea‐floor positions in the footwall that are potentially prospective for exhalative massive sulfide mineralisation. A comparison of the distribution of clastic and coherent facies with the geometry of strongly altered zones in the footwall indicates that intense hydrothermal fluid flow was independent of the facies arrangement. The massive sulfide lenses conformably overly altered footwall rhyolite and occur in a distinctive facies association which includes coarse quartz‐phenocryst‐rich rhyolitic sills with peperitic contacts and crystal‐rich polymictic breccia. The hangingwall to the orebody consists of largely unaltered dacitic lavas and synvolcanic intrusions and minor dacitic pumice breccia, dacitic breccia and polymictic volcanic breccia. The facies architecture shows that the Thalanga massive sulfide deposit formed in a below‐storm‐wave‐base depositional environment on top of an elevated, lava‐dominated, rhyolitic volcanic centre. A modern analogue for the setting of the Thalanga massive sulfide is the PACMANUS hydrothermal field on the crest of the dacite lava‐dominated Pual Ridge in the eastern Manus backarc basin (Papua New Guinea).     

A sulfur isotope study of volcanogenic massive sulfide deposits of the Eastern Black Sea province,Turkey

Kuroko-type massive sulfide deposits of the Eastern Black Sea province of Turkey are related to the Upper Cretaceous felsic lavas and pyroclastic rocks, and associated with clay and carbonate alteration zones in the footwall and hangingwall lithologies. A complete upward-vertical section of a typical orebody consists of a stringer-disseminated sulfide zone composed mainly of pyrite and chalcopyrite; a massive pyrite zone; a massive yellow ore consisting mainly of chalcopyrite and pyrite; a black ore made up mainly of galena and sphalerite with minor amounts of chalcopyrite, bornite, pyrite and various sulfosalts; and a barite zone. Most of the deposits in the province are associated with gypsum in the footwall or hangingwall. The paragenetic sequence in the massive ore is pyrite, sphalerite, chalcopyrite, bornite, galena and various sulfosalts, with some overlap between the mineral phases. Massive, stringer and disseminated sulfides from eight kuroko-type VMS deposits of the Eastern Black Sea province have a ³⁴S range of 0–7 per mil, consistent with the ³⁴S range of felsic igneous rocks. Sulfides in the massive ore at Madenköy (4.3–6.1 per mil) differ isotopically from sulfides in the stringer zone (6.3–7.2 per mil) suggesting a slightly increased input of H₂S derived from marine sulfate with time. Barite and coarse-grained gypsum have a ³⁴S range of 17.7–21.5 per mil, a few per mil higher than the ³⁴S value of contemporaneous seawater sulfate. The deposits may, therefore, have formed in restricted basins in which bacterial reduction of sulfate was taking place. Fine-grained, disseminated gypsum at Kutlular and Tunca has ³⁴S values (2.6–6.1 per mil) overlapping those of ore sulfides, indicating sulfide oxidation during waning stages of hydrothermal activity.     

Geology and wall rock alteration at the Hercynian Draa Sfar Zn–Pb–Cu massive sulphide deposit, Morocco

Draa Sfar is a siliciclastic–felsic, volcanogenic massive sulphide (VMS) Zn–Pb–Cu deposit located 15 km north of Marrakesh within the Jebilet massif of the western Moroccan Meseta. The Draa Sfar deposit occurs within the Sarhlef series, a volcano-sedimentary succession that hosts other massive sulphide deposits (e.g., Hajar, Kettara) within the dominantly siliciclastic sedimentary succession of the lower Central Jebilet. At Draa Sfar, the footwall lithofacies are dominated by grey to black argillite, carbonaceous argillite and intercalated siltstone with localized rhyodacitic flows and domes, associated in situ and transported autoclastic deposits, and lesser dykes of aphanitic basalt and gabbro. Thin- to thick-bedded, black carbonaceous argillite, minor intercalated siltstone, and a large gabbro sill dominate the hanging wall lithofacies. The main lithologies strike NNE–SSW, parallel to a pronounced S1 foliation, and have a low-grade, chlorite–muscovite–quartz–albite–oligoclase metamorphic assemblage. The Draa Sfar deposit consists of two stratabound sulphide orebodies, Tazakourt to the south and Sidi M'Barek to the north. Both orebodies are hosted by argillite in the upper part of the lower volcano-sedimentary unit. The Tazakourt and Sidi M'Barek orebodies are highly deformed, sheet-like bodies of massive pyrrhotite (up to 95% pyrrhotite) with lesser sphalerite, galena, chalcopyrite, and pyrite. The Draa Sfar deposit formed within a restricted, sediment-starved, fault-controlled, anoxic, volcano-sedimentary rift basin. The deposit formed at and below the seafloor within anoxic, pelagic muds.The argillaceous sedimentary rocks that surround the Draa Sfar orebodies are characterized by a pronounced zonation of alteration assemblages and geochemical patterns. In the more proximal volcanic area to the south, the abundance of medium to dark green chlorite progressively increases within the argillite toward the base of the Tazakourt orebody. Chlorite alteration is manifested by the replacement of feldspar and a decrease in muscovite abundance related to a net addition of Fe and Mg and a loss of K and Na. In the volcanically distal and northern Sidi M'Barek orebody alteration within the footwall argillite is characterized by a modal increase of sericite relative to chlorite. A calcite–quartz–muscovite assemblage and a pronounced decrease in chlorite characterize argillite within the immediate hanging wall to the entire Draa Sfar deposit. The sympathetic lateral change from predominantly sericite to chlorite alteration within the footwall argillite with increasing volcanic proximity suggests that the higher temperature part of the hydrothermal system is coincident with a volcanic vent defined by localized rhyodacitic flow/domes within the footwall succession.     

Geology and tectonics of the Boa Vista Basin (Paraíba, northeastern Brazil) and geochemistry of associated Cenozoic tholeiitic magmatism

The Boa Vista Basin (BVB) is located approximately 60 km southwest of Campina Grande, Paraíba, northeastern Brazil. It has a half-graben geometry controlled by dip-slip normal faults striking NE–SW. From the base to the top, the BVB is composed of (1) a lower volcanic unit of altered basalts and basaltic andesites overlying Precambrian basement rocks, (2) an intermediate unit of bentonitic shales that pass upward to medium- to coarse-grained sandstones and conglomerates and downward to sandstones and siltstones, and (3) an upper volcanic unit of massive to vesiculated basaltic flows grading to pillowed or autobrecciated basalts. These basalts show porphyritic (olivine and augite microphenocrysts), glomeroporphyritic, intersetal, pilotaxitic, and variolitic textures. They are medium-K, Fe-rich tholeiites with SiO₂ of 50.2–53.3 wt%, magnesium number of 50.54–60.21 wt%, total alkali of 2.15–3.92 wt%, and TiO₂ of 1.8–1.9 wt% and are related by low-pressure fractionation of olivine, plagioclase, magnetite, ilmenite, and apatite. They are LREE-enriched (La_N/Yb_N=8.54–44.14) with no significant europium anomaly. Trace element modeling suggests a garnet-bearing metasomatised lherzolite as their source. The geological context and geochemistry of the basalts suggest a close connection between reactivated deep-rooted Precambrian shear zones, which channeled mantle-derived Tertiary tholeiitic magmas, and continental rifting in northeastern Brazil.     

Mass,volume and chemical changes in the alteration zone at the Norbec mine,Noranda, Quebec

A funnel-shaped alteration pipe in Archean rhyolite and andesite below massive sulphide Zn-Cu ores at the Norbec mine in northwestern Quebec was outlined from drill core samples, geochemical parameters, and normative alteration mineralogy. The pipe has a mass of 37.9 million tonnes giving a volume of 13 × 10⁶ m³, which represents volume increase of 10% relative to the unaltered host volcanic rocks. A bulk chemical composition was calculated using weighting procedures for volumes of influence for the samples. Net mobile mass change, or chemical flux, for the alteration pipe was + 5.8 × 10⁶ tonnes; inclusion of the massive ore lens yields a flux of + 9.6 × 10⁶ tonnes for the whole hydrothermal system. The largest additions to the system in millions of tonnes were: FeO(+4.2), SiO₂(+3.8), S(+1.8), K₂O(+0.55), and MgO(+0.5); the only depletions were Na₂O (–1.4), and CaO(–0.44). Base and precious metals accounted for 3.4% of the total element flux.     

Timing and role of the Maranhão River Thrust in the evolution of the Neoproterozoic Brasília Belt and Tocantins Province, central Brazil

A low-angle thrust fault places high-PT granulites (hangingwall) of the Internal Zone of the Neoproterozoic Brasília Belt (Tocantins Province, central Brazil) in contact with a lower-grade footwall (External Zone) comprised of nappes of distal passive margin- and back-arc basin-related supracrustals. The footwall units were emplaced at  750 Ma onto proximal sedimentary rocks (Paranoá Group) of the São Francisco paleo-continent passive margin. The high-PT belt is comprised of 645–630 Ma granulite-facies paragneiss and orthogneiss, and mafic–ultramafic complexes that include three major layered intrusions and metavolcanic rocks granulitized at  750 Ma. These complexes occur within lower-grade metasedimentary rocks in the hangingwall of the Maranhão River Thrust, which forms the Internal Zone–External Zone boundary fault to the north of the Pirineus Zone of High Strain. Detailed lithostructural studies carried out in Maranhão River Thrust hangingwall and footwall metasedimentary rocks between the Niquelândia and Barro Alto complexes, and also to the east of these, indicate the same lithotypes and Sm–Nd isotopic signatures, and the same D₁–D₂ progressive deformation and greenschist-facies metamorphism. Additionally, footwall metasedimentary rocks exclusively display a post-D₂ deformation indicating that the Maranhão River Thrust propagated through upper crustal rocks of the Paranoá Group relatively late during the tectonic evolution of the belt. Fault propagation was a consequence of intraplate underthrusting during granulite exhumation. The results allow for a better tectonic understanding of the Brasília Belt and the Tocantins Province, as well as explaining the presence of the Pirineus Zone of High Strain.     

Distribution of gold, arsenic, antimony and tungsten around the Dest-Or Orebody, Noranda district, Abitibi, Quebec

The Dest-Or epigenetic Au deposit occurs in a breccia zone within gabbro, basalt and andesite of the Archean Upper Deguisier Formation. It is located approximately 30 km NE of Noranda. Quebec and 2.5 km N of the Porcupine-Destor Fault, an important vertical shear zone that extends east-west for more than 100 km. The known orebody contains 2.44 Mt of ore at 4.29 g/t Au.Host rocks of the Upper Deguisier Formation typically contain 3.6 ppb Au, 0.8 ppm Sb and 4.5 ppm As. The Au values are comparable to those of tholeiitic mafic rocks elsewhere in the world. but Sb and As values are a little higher.Gold values on approximately 30% of the area of the Dest-Or and Bassignac properties define a log-normal distribution with a median at 9.4 ppb Au (P₁₆ at 3.1 and P₈₄ at 27). These are referred to as ore zone halos: they envelop orebody halos which in turn envelop orebodies.An orebody halo can best be defined by close sampling in the immediate vicinity of a known orebody. Around the Dest-Or orebody, this halo is approximately 100 m wide (60 m on the hanging wall and 40 m on the footwall), and it has a median value at 37 ppb Au (P₁₆ at 17 and P₈₄ at 74).Gold enrichment in the orebody is 1900 times background value. There are also lesser but significant Sb and As enrichments (20 /sX each). High W values occur in the ore ( > 30 ppm W), but background values were too low ( <5 ppm) to be established with confidence.Gold analyses in the 0.2–100 ppb range can be gainfully used in the search for blind gold ore deposits: As, Sb and W can also be used, but anomalies are less extensive and enrichment is also less pronounced.     

The application of stepwise discriminant analysis to geochemical data from the host rocks of the Sullivan Pb-Zn-Ag deposit, Kimberley, B.C., Canada

The Sullivan Pb-Zn-Ag massive sulphide deposit in southeastern British Columbia occurs within middle Proterozoic argillite, siltstone and quartz wacke of the Purcell Group. Rock samples were collected from the hangingwall and footwall of the eastern section of the mine and from outcrop up to 50 km from the Sullivan deposit. The samples were analyzed for Cu, Pb, Zn, S, Mn, Ba, Fe, K, Ca, Na and specific conductance. A stepwise discriminant analysis applied to the analytical data determined the group of variables that differentiate between hangingwall, footwall and outcrop or “Background” samples. Hangingwall and footwall rock samples were most effectively discriminated from “background” rock samples on the basis of specific conductance with Cu, Pb, S, Na, and Ba selected as less efficient discriminators. The variables that discriminate hangingwall from footwall rock samples are Cu, Zn and S. The selection of the discriminating variables in each case can be explained in terms of the chemical changes that occur as a result of host rock alteration and sulphide deposition during the mineralizing event at the Sullivan deposit.Stepwise discriminant analysis was used to reduce a number of potential pathfinder variables to an optimum group of pathfinder variables. These optimum pathfinders represent the variables that most effectively differentiate the host rocks of the Sullivan deposit from rocks outside of the mineralized zone that apparently do not contain massive sulphide mineralization.     

Geochemical dispersion in wallrocks associated with the Norbec deposit, Noranda, Quebec

Increasing emphasis is being given to the search for blind mineral deposits and the presence of geochemical dispersion halos in wallrocks may significantly enhance the chances of exploration success. Accordingly, the nature of wallrock dispersion associated with the Lake Dufault Cu-Zn-Au-Ag massive sulphide deposit, Noranda, Quebec, was examined to see if any such patterns existed. On the basis of relatively well defined geology, the area offered an opportunity to establish the relation between geochemical alteration and metallogeny, texture, structure and mineralogy.Anomalous element contents spatially related to mineralization are confined to the stratigraphic footwall (Waite Rhyolite) where Na₂O, SiO₂ and possibly CaO depletions and total Fe₁ Mn and MgO enrichments can be related to the hydrothermal vent. Dispersion halos 150–500 m in diameter are at least twice as wide as the obvious mineralogical alteration halo. Cu, Zn, Ag and S distributions show roughly similar patterns which are not obviously related to the main alteration pipe but do reveal broad enrichment zones in the general area of mineralization.The dispersion appears to be partly controlled by texture. Because of greater primary permeability, the halos produced in rhyolite breccia are wider and better defined than those in more massive rhyolites. On a wider scale (10 km²) dispersion patterns are related to the fault and fracture systems of the area.As many as five stages of metamorphism have affected the area, altering all rocks to some extent. Samples can be classified petrographically into alteration groups, both related and unrelated to mineralization. Comparison of these groups reveals the inadequacy of certain elements for outlining alteration related to mineralization. For example, the range of K₂O in relatively unaltered rhyolite overlaps the composition of all other groups, including those related to mineralization. Similarly apparent is that the distribution of certain elements, e.g., Na₂O, may adequately define one part of an alteration zone such as the sericite-rich zone, but not another.It is concluded that careful use of lithogeochemistry in conjunction with detailed geological mapping and core logging can provide information otherwise obtainable only by time-consuming petrographic analysis. Thus it can be a potent weapon in the search for blind ore deposits.     

Electron paramagnetic resonance (EPR) spectroscopy in massive sulphide exploration, Rosebery mine area, western Tasmania, Australia

Electron paramagnetic resonance (EPR) spectroscopy of hot HNO₃ insoluble residues of rock powders is used as a new exploration technique for the volcanic-hosted massive sulphide (VHMS) deposit in the Rosebery mine area. The EPR signal intensities measured in 326.5±5 mT sweeps are strong in the altered rocks, and show a negative correlation with Ca, Na and Sr, and a positive correlation with K/Na, Rb/Sr and (K × Rb)/(Ca × Na × Sr). The EPR intensities measured in 326.5±100 mT sweeps show high values in the footwall pyroclastics, host rocks and hanging wall pyroclastics near and around the Rosebery deposit, and correlate positively with K, Fe, Mn, Ba, F, Rb, Zn, Pb and Zr. The Rosebery deposit and associated footwall alteration zone are located at the intersection of two elongated paramagnetic halos. The first is characterized by strong intensities of [AlO₄]° signals measured at magnetic flux density sweeps over 326.5±5 mT, trends NE–SW, and passes discordantly from the west to the east the White Spur Formation, altered footwall (footwall alteration zone), host rock of the Rosebery deposit, hanging wall and Mount Black Volcanics. The second, largely stratabound, halo is defined by strong intensities of Mn²⁺ sextets observed at magnetic flux density sweeps over 326.5±100 mT, runs N–S following the stratigraphic trend, and outlines the mineralized host rock and footwall alteration zone. It also extends toward the south into the unaltered footwall and hanging wall rocks. The first type of halo is considered to be related to wall rock alteration due to the VHMS mineralization processes as well to later Devonian metamorphism, and the second is thought to be related to massive sulphide mineralization alone.     

Draa Sfar, Morocco: A Visean (331 Ma) pyrrhotite-rich, polymetallic volcanogenic massive sulphide deposit in a Hercynian sediment-dominant terrane

Draa Sfar is a Visean, stratabound, volcanogenic massive sulphide ore deposit hosted by a Hercynian carbonaceous, black shale-rich succession of the Jebilet terrane, Morocco. The ore deposit contains 10 Mt grading 5.3 wt.% Zn, 2 wt.% Pb, and 0.3 wt.% Cu within two main massive sulphides orebodies, Tazakourt (Zn-rich) and Sidi M'Barek (Zn–Cu rich). Pyrrhotite is by far the dominant sulphide (70 to 95% of total sulphides), sphalerite is fairly abundant, chalcopyrite and galena are accessory, pyrite, arsenopyrite and bismuth minerals are rare. Pyrrhotite is monoclinic and mineralogical criteria indicate that it is of primary origin and not formed during metamorphism. Its composition is very homogeneous, close to Fe₇S₈, and its absolute magnetic susceptibility is 2.10^− 3 SI/g. Ar–Ar dating of hydrothermal sericites from a coherent rhyolite flow or dome within the immediate deposit footwall indicates an age of 331.7 ± 7.9 Ma for the Draa Sfar deposit and rhyolite volcanism.The Draa Sfar deposit has undergone a low-grade regional metamorphic event that caused pervasive recrystallization, followed by a ductile–brittle deformation event that has locally imparted a mylonitic texture to the sulphides and, in part, is responsible for the elongated and sheet-like morphology of the sulphide orebodies. Lead isotope data fall into two compositional end-members. The least radiogenic end-member, (²⁰⁶Pb/²⁰⁴Pb = 18.28), is characteristic of the Tazakourt orebody, whereas the more radiogenic end-member (²⁰⁶Pb/²⁰⁴Pb  18.80) is associated with the Sidi M'Barek orebody, giving a mixing trend between the two end-members. Lead isotope compositions at Draa Sfar testify to a significant continental crust source for the base metals, but are different than those of the Hajar and South Iberian Pyrite Belt VMS deposits.The abundance of pyrrhotite versus pyrite in the orebodies is attributed to low fO₂ conditions and neither a high temperature nor a low aH₂S (below 10^− 3) is required. The highly anoxic conditions required to stabilize pyrrhotite over pyrite are consistent with formation of the deposit within a restricted, sediment-starved, anoxic basin characterized by the deposition of carbonaceous, pelagic sediments along the flank of a rhyolitic flow-dome complex that was buried by pelitic sediments. Deposition of sulphides likely occurred at and below the seafloor within anoxic and carbonaceous muds.Draa Sfar and other Moroccan volcanogenic massive sulphide deposits occur in an epicontinental volcanic domain within the outer zone of the Hercynian belt and formed within a sedimentary environment that has a high pelagic component. In spite of the diachronous emplacement between the IPB deposits (late Devonian to Visean) and Moroccan deposits (Dinantian), all were formed around 340 ± 10 Ma following a major phase of the Devonian compression.     

Lewis Ponds, a hybrid carbonate and volcanic-hosted polymetallic massive sulphide deposit, New South Wales, Australia

The Lewis Ponds Zn–Pb–Cu–Ag–Au deposit, located in the eastern Lachlan Fold Belt, central western New South Wales, exhibits the characteristics of both volcanic-hosted massive sulphide and carbonate-hosted replacement deposits. Two stratabound massive to disseminated sulphide zones, Main and Toms, occur in a tightly folded Upper Silurian sequence of marine felsic volcanic and sedimentary rocks. They have a combined indicated resource of 5.7 Mt grading 3.5% Zn, 2.0% Pb, 0.19% Cu, 97 g/t Ag and 1.9 g/t Au. Main Zone is hosted by a thick unit of poorly sorted mixed provenance breccia, limestone-clast breccia and quartz crystal-rich sandstone, whereas Toms Zone occurs in the overlying siltstone. Pretectonic carbonate–chalcopyrite–pyrite and quartz–pyrite stringer veins occur in the footwall porphyritic dacite, south of Toms Zone. Strongly sheared dolomite–chalcopyrite–pyrrhotite veins directly underlie the Toms massive sulphide lens. The mineralized zones consist predominantly of pyrite, sphalerite and galena. Paragenetically early framboidal, dendritic and botryoidal pyrite aggregates and tabular pyrrhotite pseudomorphs of sulphate occur throughout the breccia and sandstone beds that host Main Zone, but are rarely preserved in the annealed massive sulphide in Toms Zone. Main and Toms zones are associated with a semi-conformable hydrothermal alteration envelope, characterized by texturally destructive chlorite-, dolomite- and quartz-rich assemblages. Dolomite, chlorite, quartz, calcite and sulphides have selectively replaced breccia and sandstone beds in the Main Zone host sequence, whereas the underlying porphyritic dacite is weakly sericite altered. Vuggy and botryoidal textures resulted from partial dissolution of the dolomite-altered sedimentary rocks and unimpeded growth of base metal sulphides, carbonate and quartz into open cavities. The intense chlorite-rich alteration assemblage, underlying Toms Zone, grades outward into a weak pervasive sericite–quartz assemblage with distance from the massive sulphide lens. Limestone clasts and hydrothermal dolomite at Lewis Ponds are enriched in light carbon and oxygen isotopes. The dolomite yielded ¹³C_VPDB values of –11 to +1 and ¹⁸O_VSMOW values of 6 to 16. Liquid–vapour fluid inclusions in the dolomite have low salinities (1.4–7.7 equiv. wt% NaCl) and homogenization temperatures (166–232°C for 1,000 m water depth). Dolomitization probably involved fluid mixing or fluid–rock interactions between evolved heated seawater and the limestone-bearing facies, prior to and during mineralization. ³⁴S_VCDT values range from 2.0 to 5.0 in the massive sulphide and 3.9 to 7.4 in the footwall carbonate–chalcopyrite–pyrite stringer veins, indicating that the hydrothermal fluid may have contained mamgatic sulphur and a component of partially reduced seawater. The sulphide mineral assemblages at Lewis Ponds are consistent with moderate to strongly reduced conditions during diagenesis and mineralization. Low temperature dolomitization of limestone-bearing facies in the Main Zone host sequence created secondary porosity and provided a reactive host for fluid-rock interactions. Main Zone formed by lateral fluid flow and sub-seafloor replacement of the poorly sorted breccia and sandstone beds. Base metal sulphide deposition probably resulted from dissolution of dolomite, fluid mixing and increased fluid pH. Pyrite, sphalerite and galena precipitated from a relatively low temperature, 150–250°C hydrothermal fluid. In contrast, Toms Zone was emplaced into fine-grained sediment at or near the seafloor, above a zone of focused up-flowing hydrothermal fluids. Copper-rich assemblages were deposited in the Toms Zone footwall and massive sulphide lenses in Main and Toms zones as the hydrothermal system intensified. During the D₁ deformation, fracture-controlled fluids within the Lewis Ponds fault zone and adjacent footwall volcanic succession remobilized sulphides into syntectonic quartz veins. Lewis Ponds is a rare example of a synvolcanic sub-seafloor hydrothermal system developed within fossiliferous limestone-bearing facies. The close spatial association between limestone, hydrothermal dolomite, massive sulphide and dacite provides a basis for new exploration targets elsewhere in New South Wales.Editorial handling: D. Lentz     

Mineral assemblages of the Francisco I. Madero Zn–Cu–Pb–(Ag) deposit, Zacatecas, Mexico: Implications for ore deposit genesis

The Francisco I. Madero deposit, central Mexico, occurs in the Mesozoic Guerrero Terrane, which hosts many ore deposits, both Cretaceous (volcanogenic massive sulfides) and Tertiary (epithermal and skarn deposits). It is hosted by a 600 m-thick calcareous-pelitic unit, of Lower Cretaceous age, crosscut by porphyritic dikes that strike NW–SE. A thick felsic volcanic Tertiary sequence, consisting of andesites and rhyolitic ignimbrites, unconformably overlies the Cretaceous series. At the base, the mineralization consists of several mantos developed within calcareous beds. They are dominantly composed of sphalerite, pyrrhotite and pyrite with minor chalcopyrite, arsenopyrite and galena. At the top of the orebody, there are calcic skarns formed through prograde and retrograde stages. The resulting mineral assemblages are rich in manganoan hedenbergite (Hd_75–28Di_40–4Jh_40–20), andraditic garnets (Adr_100–62Grs_38–0), epidote (Ep_95–36Czo_60–5Pie_8–0), chamosite, calcite and quartz. The temperature of ore deposition, estimated by chlorite and arsenopyrite geothermometry, ranges from 243° to 277 °C and from 300° to 340 °C, respectively. The pressure estimated from sphalerite geobarometry averages 2.1 kbar. This value corresponds to a moderately deep skarn and agrees with the high Cu content of the deposit. Paragenesis, P–T conditions and geological characteristics are compatible with a distal, dike-related, Zn skarn deposit. Its style of mineralization is similar to that of many high-temperature carbonate replacement skarn deposits in the Southern Cordillera.     

Composition and age of tertiary sills and dykes, Jameson Land Basin, East Greenland: relation to regional flood volcanism

The Paleozoic–Mesozoic Jameson Land Basin (East Greenland) is intruded by a sill complex and by a swarm of ESE trending dykes. Together with dykes of the inner Scoresby Sund fjord, they form a regional Early Tertiary intrusive complex located 200–400 km inland of the East Greenland rifted continental margin. Most of the intrusive rocks in the Jameson Land Basin are geochemically coherent and consist of evolved plagioclase–augite–olivine saturated, uncontaminated high-Ti basalt with 48.5–50.2 wt.% SiO₂, 2.2–3.2 wt.% TiO₂, 5.1–7.4 wt.% MgO, 9–17 ppm Nb and La/Yb_N=2.8–3.6. Minor tholeiitic rock types are: (a) low-Ti basalt (49.7 wt.% SiO₂, 1.7 wt.% TiO₂, 6.8 wt.% MgO, 2.6 ppm Nb and La/Yb_N=0.5) akin to oceanic basalts; (b) very-high-Ti basalt (48.6 wt.% SiO₂, 4.1 wt.% TiO₂, 5.1 wt.% MgO and 21 ppm Nb); and (c) plagioclase ultraphyric basalt. The tholeiitic dolerites are cut by alkali basalt (43.7–47.3 wt.% SiO₂, 4.1–5.1 wt.% TiO₂, 4.9–6.2 wt.% MgO, 29–46 ppm Nb and La/Yb_N=16–17) sills and dykes.Modelling of high-field-strength and rare-earth elements indicate that the high-Ti basalts formed from 6–10% melting of approximately equal proportions of garnet- and spinel-bearing mantle of slightly depleted composition beneath thick continental lithosphere. Conversely, dolerite intrusions and flood basalts of similar compositional kindred from adjacent but more rift-proximal occurrences in Northeast Greenland formed from shallower melting of dominantly spinel-bearing mantle beneath extended and thinned continental lithosphere. These variations in lithospheric thickness suggest the continent–ocean transition of the East Greenland rifted volcanic margin is sharp and narrow.⁴⁰Ar–³⁹Ar dating and paleomagnetism show that the high-Ti dolerites were emplaced at 53–52 Ma (most likely during C23r) and hence surprisingly postdate the main flood volcanism by 2–5 Ma and the inception of seafloor spreading between Greenland and Europe by 1–2 Ma. The formation of tholeiitic and alkaline magmas emplaced into the Jameson Land Basin corroborates to the importance of post-breakup magmatism along the East Greenland volcanic rifted margin. Upwelling of the ancestral Iceland mantle plume under central Greenland at 53–52 Ma (rather than under the active rift), perhaps accompanied by a failed attempt to shift the rift zone westward towards the plume axis, may have triggered post-breakup continental magmatism of the Jameson Land Basin and the inner Scoresby Sund region, along preexisting structural lineaments.     

Geochemistry of the Siberian Trap of the Noril'sk area,USSR, with implications for the relative contributions of crust and mantle to flood basalt magmatism

The sequence investigated of the Siberian Trap at Noril'sk, USSR, consists of at least 45 flows that have been divided into six lava suites. The lower three suites consist of alkalic to subalkalic basalts (the Ivakinsky suite), overlain by nonporphyritic basalts (the Syverminsky suite), and porphyritic and picritic basalts (the Gudchikhinsky suite). The upper three suites are tholeiitic. The uppermost 750 m of dominantly non-porphyritic basalt belong to the Mokulaevsky suite and are characterized by a nearly constant Mg number (0.54–0.56), SiO₂ (48.2–49.1 wt%), Ce (12–18 ppm), and Ce/Yb (5–8). The underlying 1100 m of dominantly porphyritic basalt belong to the Morongovsky and Nadezhdinsky suites. There is a continuous increase in SiO₂ (48.1–55.2 wt%), Ce (12–41 ppm), and Ce/Yb (5–18) from the top of the Mokulaevsky to the base of the Nadezhdinsky with little change in the Mg number (0.53–0.59). Mokulaevsky magmas have trace element signatures similar to slightly contaminated transitional type mid-ocean ridge basalts. The change in major and trace element geochemistry in the upper three suites is consistent with a decline in the degree of anatexis and assimilation of tonalitic upper crust by Mokulaevsky magma. The Nadezhdinsky and underlaying lavas thicken within and thus appear to be related to an elongate basin centred on the Noril'sk-Talnakh mining camp. The Mokulaevsky and Morongovsky lavas thicken to the east and appear to be related to a basin centred more than 100 km to the east of the Noril'sk region; these magmas may have risen up out of a different conduit system.     

Iron-Titanium Oxide Geothermometry and Petrogenesis of Lava Flows and Dykes from Mandla Lobe of the Eastern Deccan Volcanic Province, India

Compositional studies on different forms of magnetite, ulvospinel, ilmenite and hematite mineral phases occurring in 37 lava flows and 6 dykes of the Mandla lobe are presented in this paper. Ilmenite (0001) in equilibrium with titanomanetite show high values of temperature of equilibration, ranging from 1172–974°C, for high alumina quartz normative tholeiitic lava flows of Chemical Type - A; 1129–1229°C for low alumina quartz normative tholeiitic lava flows of Chemical Type - B; 1283–1124°C for tholeiitic lava flows of Chemical Type - F and 1243°C and 99O°C for two diopside olivine normative tholeiite flows of Chemical Type D. High olivine normative flows of Chemical Type - G and H show 1095°C and 1092°C respectively. Whereas, high hypersthene normative tholeiite flow of Chemical me C shows temperature of 1187°C. Data plots disposition over iron-titanium oxide equilibration temperature vs – logfo₂, diagram for Mandla lava flows and other parts of the Deccan (Igatpuri, Mahabaleshwer, Nagpur and Sagar areas) revealed that tholeiitic (evolved) basalt of the eastern Deccan volcanic province formed at high temperatures whereas, picritic (primitive) lavas of Igatpuri and tholeiitic basalt of Mahabaleshwar areas were formed at low temperatures. Mahabaleshwer basalts follow FMQ (fayalite-magnetite-quartz) buffer curve but, plots of the Mandla basalts lie above this curve indicating higher temperatures of crystallisation of ilmenite-titanomagnetite than that of the lava flows from other parts of Deccan 'Raps. The eastern Deccan Traps are most evolved types of lava as characterised by its low Mg-number and Ni content whereas, Igatpuri lava flows are picritic (primitive), having high Mg-number and Ni contents. Temperature vs FeO + Fe₂O₃ / FeO + Fe₂O₃ + MgO ratio data plots for Mandla and other Deccan lava flows and liquidus data for Hawaiian tholeiites, indicated that Igatpuri basalts lie parallel to the liquidus line of Hawaiian tholeiite but at lower temperatures. Large data plots of Mandla lava flows lie along the liquidus line of the Hawaiian lava. The highly vesicular nature of compound lava flows having large amount of volatile is responsible for low temperature values whereas, lava flows represented by high temperatures show high modal values of glass and opaque minerals.     

A potassium-rich Alkalic Suite from the Deccan Traps,Rajpipla, India

The Rajpipla Alkalic Suite is the most potassium-enriched group of basaltic rocks so far described from the Deccan Traps. In the same area however early tholeiitic flows and late tholeiitic dykes show the potassium-poor nature characteristic of most Deccan Trap magmas. The rocks of the alkalic suite are highly porphyritic and their major element variation can be interpreted in terms of crystal fractionation dominated by clinopyroxene. Plagioclase, which is an important phenocryst phase, has fractionated only in relatively small amounts as a result of a lack of density contrast between it and the liquids. A dyke-like form for the magma chambers in which fractionation has taken place is postulated to account for the abundance of highly porphyritic types. The Rajpipla area is also notable as being one of the few Deccan localities where rhyolites are found.Abbreviations AB ankaramitic basalt - PB porphyritic basalt - PTB porphyritic trachybasalt - FPM feldsparphyric mugearite - M mugearite - TR trachyte - P. RHY potassic rhyolite - Th. B. tholeiitic basalt - Th. D. tholeiitic dolerite - Af alkali feldspar     

Lithogeochemistry of wainaleka Cu-Zn volcanogenic deposit, Viti Levu, Fiji, and possible applications for exploration in tropical terrains

A small Kuroko-type Cu-Zn deposit exhibiting metal zoning and alteration assemblages comparable with documented proximal volcanogenic deposits, occurs at the top of a felsic fragmental pile, mantling a large sodic rhyolite domal complex. The domal complex occurs within predominantly mafic to intermediate lavas and volcaniclastic rocks with low-potash island-arc tholeiitic affinities, representing the basal section of the early Tertiary (Eocene to middle Miocene) Wainimala Group near the southern coast of Viti Levu, Fiji.Lithogeochemical trends identified in analyses of rock chip samples from traverses across the domal complex reflect alteration zoning. Sodium, Ca and Sr are strongly depleted within the quartz-sericite foot-wall alteration zone (Zone I) 200 m below mineralization. Potassium, Rb and weaker Mn, Zn and Co depletion and Cu, Pb and Mg enrichment define clay-sericite (Zone II) and clay carbonate (Zone III) footwall alteration 600 to 1200 m below mineralization. Hanging-wall albite-chlorite-calcite-zeolite alteration (Zone IV) is accompanied by enhanced Zn, Pb, Co, Mn, Sr and Na values.Significant mine-scale lithogeochemical trends obtained from systematic sampling of a mineralized borehole section include K and Rb enrichment in the zone of strongest quartz-sericite alteration associated with mineralization and broad depletion of Mn, Na, Ca and Sr within altered footwall fragmental rocks. Minor Cu, Pb, Zn and Ag enrichment has accompanied low-grade propylitic alteration of hanging-wall rocks up to 50 m above mineralization. Analysis of weathered bedrock samples from traverses above the mineralized borehole section indicates that primary geochemical trends occur in the weathered zone. Outcropping gossan has strongly anomalous Cu (535 ppm-21.5%), Zn (3300 ppm-6.15%), Pb (420–8200 ppm), As (200–7000 ppm) and Hg (33–670 ppm) values.Application of lithogeochemistry as a follow-up exploration method in a tropical area such as Wainaleka was investigated as a possible replacement for ridge, spur and base-of-slope soil sampling techniques. Ridge-top auger samples and creek outcrop samples were collected at approximately 100 m intervals and a density of 70/km². Elements (including Cu, Pb, Zn, Mn, Rb, Sr, Na, K, Ca and Mg) were selected for analysis because of specific associations with mineralization and alteration, and low analytical costs. Single- and multi-element dispersions effectively outline mineralization and attendant alteration.     

Emplacement,crystallization and alteration of spinifex-textured komatiitic basalt flows in the Archaean Nondweni greenstone belt,southern Kaapvaal Craton,South Africa

A well exposed succession of spinifex-textured komatiite flows is reported from the Archaean Nondweni greenstone belt located near the southern margin of the Kaapvaal Craton. The flows are relatively thin (1–5 m) compared to similar occurrences in other greenstone belts. They are characterised by well developed cone structures of highly elongate amphibole crystals (after augite) which fan downwards from the tops of the flows. Extreme development of coned spinifex has not been reported from other greenstone belts and points to specific thermal conditions prevailing in the Nondweni environment. The zones of bladed spinifex are contained between layers of random spinifex and overlie a lower cumulus layer originally of augite, orthopyroxene and minor olivine. The observed major and trace element distributions through a 1.7 m thick spinifex-textured flow are consistent with a model involving concentration of phenocryst phases resulting in significant fractionation upwards in the flow. Approximately 40% of the spinifex-textured phenocrysts grew in situ after the lithological units were established. Collapse and displacement of the coned crystal networks, originally attached to the top of the flow, are shown to have influenced the distribution of liquid within the flow and accentuated the fractionation. Associated with the spinifex-textured units are massive aphyric and brecciated flows which show distinct chemical cycles through the succession. The brecciated zones have compositions with <18% MgO and are characterised by ovoid bodies that are not pillows and may represent magmatic reworking and movement of a partly congealed flow. Post-solidus alteration is considered to have caused early hydration of the original mineralogy and also introduced SiO₂ and Na₂O into the upper part of the flow by way of microfractures. The observed alteration is different to that of Mid-Ocean Ridge basalts, and a subaerial/shallow water environment is suggested.     

Metabasalts and metagabbros from the Llano Uplift,Texas: Petrologic and geochemical characterization with emphasis on tectonic setting

The 1.0-1.2 b.y. old rocks of the southeastern Llano Uplift, Texas include a 7 km thick sequence of amphibolite-grade, stratified, mafic metasedimentary rock (Packsaddle Schist) which is intruded by a varied suite of syntectonic and late-kinematic intrusions. The metasediments contain large blocks of serpentinized peridotite (Coal Creek serpentinite) and coarse hornblendite and metagabbro. Prior to the end of maximum deformation, the sequence was intruded by low to medium-K₂O tholeiitic basalts (0.40-0.72% K₂O). Late-kinematic low-K₂O tholeiitic basalts (0.38-0.40% K₂O) were intruded as dikes into the folded rocks. The Coal Creek serpentinite contains both syntectonic and late-kinematic low-K₂O tholeiitic metabasalts (0.13–0.36% K₂O). The Llano metabasalts and metagabbros are characterized by low Cr (67–378 ppm) and Ni (36–170 ppm), variable Rb (1.5–14.7 ppm), Sr (140–1229 ppm), TiO₂ (0.40–2.20%), P (568–2707 ppm), and Zr (18–230 ppm), and Y (16–45 ppm), Co (40–57 ppm), and Sc (36–49 ppm) similar to modern MORB. The metabasalts have La abundances from 7 to 39 times chondritic and exhibit light REE enrichment with ¦La/Sm¦_N from 1.13 to 1.45 and ¦La/Yb¦_N from 1.12 to 2.99. The metabasalts show a strong correlation of increasing Zr, Ti, and Y and decreasing Eu/Eu^* (1.56–1.00), CaO/TiO₂, Al₂O₃/TiO₂, and MgO/ MgO+FeO^* with increasing REE enrichment (La_N). The Llano metabasalts and metagabbros have initial ⁸⁷Sr/⁸⁶Sr=0.7029±0.0001. A likely petrogenetic model for these metabasalts is an island arc in which events from early arc development to final late-kinematic intrusion were dominated by tholeiitic volcanism and intrusion. The chemical systematics of the Llano mafic metaigneous rocks suggest they are products of fractionation of olivine, clinopyroxene, and plagioclase from more primitive basaltic magmas generated beneath the island arc complex.