Permian macro- and miofloral diversity,palynodating and palaeoclimate implications deduced from the coal-bearing sequences of Singrauli coalfield,Son–Mahanadi Basin,central India

The coal-bearing sequences of Barakar and Raniganj formations exposed in Bina and Jhingurdah open-cast collieries, respectively, are analysed for their macro- and miofloral content. The sediment successions primarily comprise of sandstones, shales, claystones and coal seams. In addition to the diverse glossopterid assemblage, four palynoassemblage zones, namely Zones I and II in Bina Colliery and Zones III and IV in Jhingurdah Colliery, have also been recorded in the present study. The megafossil assemblage from the Barakar strata of Bina Colliery comprises of three genera, namely Gangamopteris, Glossopteris and cf. Noeggerathiopsis. Palynoassemblage-I is characterised by the dominance of non-striate bisaccate pollen genus Scheuringipollenites and subdominance of striate bisaccate Faunipollenites and infers these strata to be of Early Permian (Artinskian) age (Lower Barakar Formation). The palynoassemblage has also yielded a large number of naked fossil spore tetrads, which is the first record of spore tetrads from any Artinskian strata in the world and has a significant bearing on the climatic conditions. The palynoassemblage-II is characterised with the dominance of Faunipollenites over Scheuringipollenites and is indicative of Kungurian age (Upper Barakar Formation). The megafossil assemblage from the Raniganj Formation of Jhingurdah Colliery comprises of five genera with 26 species representing four orders, viz., Equisetales, Cordaitales, Cycadales and Glossopteridales. The order Glossopteridales is highly diversified with 23 taxa and the genus Glossopteris, with 22 species, dominates the flora. The mioflora of this colliery is represented by two distinct palynoassemblages. The palynoassemblage-III is correlatable with the palynoflora of Early Permian (Artinskian) Lower Barakar Formation. The assemblage suggests the continuity of older biozones into the younger ones. The palynoassemblage-IV equates the beds with composition V: Striatopodocarpites–Faunipollenites–Gondisporites assemblage zone of Tiwari and Tripathi (1992) of Late Permian (Lopingian) Raniganj Formation in Damodar Basin. The FAD’s of Alisporites, Klausipollenites, Falcisporites, Arcuatipollenites pellucidus and Playfordiaspora cancellosa palynotaxa in this assemblage enhance the end Permian level of the Jhingurdah Top seam, as these elements are the key species to mark the transition of Permian into the Lower Triassic.     

Kink bands in thrust regime: Examples from Srinagar–Garhwal area,Uttarakhand, India

This paper deciphers the late stress systems involved in the development of kink bands in the perspective of thrust regime. In kink bands, the correlation coefficient for α–β plots is positive near thrusts and negative away from thrusts. The plots show nearly linear relationship near thrusts and non-linear relationship away from thrusts. The rotation was prominent mechanism of kink band formation near thrusts and rotation coupled with shearing, along the kink planes away from thrusts. Along thrusts σ ₁ is horizontal E–W trend and it rotates to horizontal N–S trend away from the thrust. The proposed model establishes that (1) the shearing along kink planes led to angular relationship, β < α and (2) the kink planes of conjugate kinks could be used for paleostress analysis even in those cases where shearing along these planes has occurred.     

The nature of MIS 3 stadial–interstadial transitions in Europe: New insights from model–data comparisons

15 abrupt warming transitions perturbed glacial climate in Greenland during Marine Isotope Stage 3 (MIS 3, 60–27 ka BP). One hypothesis states that the 8–16 °C warming between Greenland Stadials (GS) and Interstadials (GI) was caused by enhanced heat transport to the North Atlantic region after a resumption of the Atlantic Meridional Overturning Circulation (AMOC) from a weak or shutdown stadial mode. This hypothesis also predicts warming over Europe, a prediction poorly constrained by data due to the paucity of well-dated quantitative temperature records. We therefore use a new evidence from biotic proxies and a climate model simulation to study the characteristics of a GS–GI transition in continental Europe and the link to enhanced AMOC strength. We compare reconstructed climatic and vegetation changes between a stadial and subsequent interstadial – correlated to GS15 and GI14 (～55 ka BP) – with a simulated AMOC resumption using a three-dimensional earth system model setup with early-MIS 3 boundary conditions. Over western Europe (12°W–15°E), we simulate twice the annual precipitation, a 17 °C warmer coldest month, a 8 °C warmer warmest month, 1300 °C-day more growing degree days with baseline 5 °C (GDD5) and potential vegetation allowing tree cover after the transition. However, the combined effect of frequent killing frosts, <20 mm summer precipitation and too few GDD5 after the transition suggest a northern tree limit lying at ～50°N during GI14. With these 3 climatic limiting factors we provide a possible explanation for the absence of forests north of 48°N during MIS 3 interstadials with mild summers. Finally, apart from a large model bias in warmest month surface air temperatures, our simulation is in reasonable agreement with reconstructed climatic and vegetation changes in Europe, thus further supporting the hypothesis.     

Utilization of SPOT 5 data for mapping gold mineralized diorite–tonalite intrusion,Bulghah gold mine area,Saudi Arabia

The present study utilizes the processed SPOT 5 data to discriminate and to generate 1:10,000 geologic image map to delineate the mineralized diorite–tonalite intrusion around Bulghah gold mine area, Saudi Arabia. The rock units exposed in the area include gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite. Gold mineralization at Bulghah mine is hosted mainly by Syn- to Late-tectonic diorite–tonalite intrusion aligned along N–S direction and is associated mainly with cataclastic zones and quartz veins. Gossans and jasparoidal gossans (Hulayfah group), recorded at the western side of Bulghah mine area as discontinuous small lenses, can be easily discriminated on 4/2 and 4/3 band ratio SPOT images by their white and black image signatures, respectively. Granitoids (gneissose granite and alkali granite) are easily discriminated in 3/2 ratio image, in which gneissose granite has gray image signature, whereas alkali granite has dark gray image signature. On the SPOT false color composite band ratios image (3/2 R, 4/2 G, and 4/3 B), gossan, marble, Hulayfah volcanics, diorite–tonalite, gneissose granite, and alkali granite have sky blue, blood red, bluish light brown, orange, brick red, and deep blue colors, respectively. Fusion of the false color composite SPOT ratios image (3/2 R, 4/2 G, and 4/3 B) with the high spatial resolution SPOT pan image is performed using IHS transformation method. The fused image is used to delineate the mineralized diorite–tonalite intrusion and to produce 1:10,000 geologic image map for Bulghah gold mine area. The present study reveals the usefulness of the processed SPOT 5 data for adding new extensions at the southern and northern boundaries of diorite–tonalite intrusion.     

Episodic crustal growth in the Bundelkhand craton of central India shield: Constraints from petrogenesis of the tonalite–trondhjemite–granodiorite gneisses and K-rich granites of Bundelkhand tectonic zone

Tonalite–trondhjemite–granodiorite gneisses (TTG) and K-rich granites are extensively exposed in the Mesoarchean to Paleoproterozoic Bundelkhand craton of central India. The TTGs rocks are coarse- grained with biotite, plagioclase feldspar, K-feldspar and amphibole as major constituent phases. The major minerals constituting the K-rich granites are K-feldspar, plagioclase feldspar and biotite. They are also medium to coarse grained. Mineral chemical studies show that the amphiboles of TTG are calcic amphibole hastingsite, plagioclase feldspars are mostly of oligoclase composition, K-feldspars are near pure end members and biotites are solid solutions between annite and siderophyllite components. The K-rich granites have biotites of siderophyllite–annite composition similar to those of TTGs, plagioclase feldspars are oligoclase in composition, potassic feldspars have \(\hbox {X}_{\mathrm{K}}\) ranging from 0.97 to 0.99 and are devoid of any amphibole. The tonalite–trondhjemite–granodiorite gneiss samples have high \(\hbox {SiO}_{2}\) (64.17–74.52 wt%), \(\hbox {Na}_{2}\hbox {O}\) (3.11–5.90 wt%), low Mg# (30–47) and HREE contents, with moderate \((\hbox {La/Yb})_{\mathrm{CN}}\) values (14.7–33.50) and Sr/Y ratios (4.85–98.7). These geochemical characteristics suggest formation of the TTG by partial melting of the hydrous basaltic crust at pressures and depths where garnet and amphibole were stable phases in the Paleo-Mesoarchean. The K-rich granite samples show high \(\hbox {SiO}_{2}\) (64.72–76.73 wt%), \(\hbox {K}_{2}\hbox {O}\) (4.31–5.42), low \(\hbox {Na}_{2}\hbox {O}\) (2.75–3.31 wt%), Mg# (24–40) and HREE contents, with moderate to high \((\hbox {La/Yb})_{\mathrm{CN}}\) values (9.26–29.75) and Sr/Y ratios (1.52–24). They differ from their TTG in having elevated concentrations of incompatible elements like K, Zr, Th, and REE. These geochemical features indicate formation of the K-granites by anhydrous partial melting of the Paleo-Mesoarchean TTG or mafic crustal materials in an extensional regime. Combined with previous studies it is interpreted that two stages of continental accretion (at 3.59–3.33 and 3.2–3.0 Ga) and reworking (at 2.5–1.9 Ga) occurred in the Bundelkhand craton from Archaean to Paleoproterozoic.     

Basement configuration of the Jhagadia–Rajpipla profile in the western part of Deccan syneclise,India from travel-time inversion of seismic refraction and wide-angle reflection data

2-D velocity structure up to the basement is derived by travel-time inversion of the first arrival seismic refraction and wide-angle reflection data along the SW–NE trending Jhagadia–Rajpipla profile, located on the western part of Deccan syneclise in the Narmada–Tapti region. The study region is mostly covered by alluvium. Inversion of refraction and wide-angle reflection data reveals four layered velocity structure above the basement. The first two layers with P-wave velocities of 1.95–2.3 km s^?1 and 2.7–3.05 km s^?1 represent the Recent and Quaternary sediments respectively. The thickness of these sediments varies from 0.15 km to 3.4 km. The third layer with a P-wave velocity of 4.8–5.1 km s^?1 corresponds to the Deccan volcanics, whose thickness varies from 0.5 km to 1.0 km. Presence of a low velocity zone (LVZ) below the high velocity volcanic rocks in the study area is inferred from the travel-time ‘skip’ and amplitude decay of the first arrival refraction data and the wide-angle reflection from top of the LVZ present immediately after the first arrival refraction from Deccan Trap layer. The thickness of the low velocity Mesozoic sediments varies from 0.3 km to 1.7 km. The basement with a P-wave velocity of 5.9–6.15 km s^?1 lies at a depth of 4.9 km near Jhagadia and shallows to 1.2 km towards northeast near Rajpipla. The results indicate presence of low velocity Mesozoic sediments hidden below the Deccan Trap layer in the western part of the Deccan syneclise.     

Petrography and geochemistry of the Proterozoic sandstones of Somanpalli Group from Pomburna area,Eastern Belt of Pranhita–Godavari Valley,central India: Implications for provenance,weathering and tectonic setting

In this paper, we, for the first time, report geochemistry of sandstone from Somanpalli Group from Pomburna area in the Eastern Belt of Pranhita–Godavari (PG) Valley, central India and studied to infer their provenance, intensity of paleo-weathering and depositional tectonic setting. Petrographic study of sandstones show QFL modal composition of arenite. Chemical results show high \(\hbox {SiO}_{2}\) and CIA but lower \(\hbox {Al}_{2}\hbox {O}_{3}, \hbox {TiO}_{2}\), Rb, Sr, \(\hbox {K}_{2}\hbox {O}\) indicating mixed sources. Major elements chemistry parameters such as, \(\hbox {K}_{2}\hbox {O/Al}_{2}\hbox {O}_{3}\) ratio and positive correlation of Rb with \(\hbox {K}_{2}\hbox {O}\), reflects a warm and humid climate for study area. The tectonic discrimination plots (\(\hbox {SiO}_{2}/20\)–\(\hbox {K}_{2}\hbox {O} + \hbox {Na}_{2}\hbox {O}\)–\(\hbox {TiO}_{2} + \hbox {Fe}_{2}\hbox {O}_{3} + \hbox {MgO};\,\hbox {K}_{2}\hbox {O}/\hbox {Na}_{2}\hbox {O}\) vs. \(\hbox {SiO}_{2}\); Th–Sc–Zr/20) indicate dominantly passive margin and slight active tectonic setting. Concentrations of Zr, Nb, Y, and Th are higher compared to the UCC values and the trends in Th/Cr, Th/Co, La/Sc and Cr/Zr ratios support a felsic and mafic source for these sandstones and deposition in passive margin basin. Chondrite normalized REE pattern reflects LREE depletion, negative Eu anomaly and flat HREE similar to UCC, felsic components. ICV value (0.95) also supports tectonically quiescent passive margin settings. CIA values (74) indicate high degree of chemical weathering and warm and humid paleoclimatic condition.     

Structure of the Outokumpu ore district and ophiolite-hosted Cu–Co–Zn–Ni–Ag–Au sulfide deposits revealed from 3D modeling and 2D high-resolution seismic reflection data

The Outokumpu district within the North Karelia Schist Belt in eastern Finland hosts a number of Cu–Co–Zn–Ni–Ag–Au sulfide deposits that are associated with Palaeoproterozoic ophiolitic metaserpentinites derived from depleted mantle peridotites that were subsequently tectonically interleaved with allochthonous metaturbidites. The metaperidotites have been extensively metasomatized to quartz–carbonate–calc–silicate rocks of the Outokumpu assemblage. The Outokumpu area has been affected by a multiple-phase tectonic history comprising various phases of folding and shearing followed by several faulting events. Future exploration has to expand the search into deeper areas and requires knowledge of the subsurface geology. In order to unravel the complex structure 3D geologic models of different scales have been built using a variety of information including geological aeromagnetic and gravity maps, digital terrain models, and mine cross sections as well as data like drill core logs combined with observations from underground mine galleries, structural measurements, aeromagnetic data, and seismic surveys. For crustal structures, data from seismic surveys lines have been reprocessed for our purpose. Both deposit-scale and regional-scale models allow the reconstruction of a sequence of structural events. The mined ore has formed during remobilization of a proto-ore and is closely related to shear zones (thrusts) that truncate the Outokumpu assemblage. Later faults dismembered the ore explaining the variable depth of the different ore bodies along the Outokumpu ore zone. On larger scale at least four km-scale thrust sheets, separated by major listric shear zones can be identified in the ore belt, which are internally further imbricated by subordinate shear zones. These thrusts separate a number of lens-shape metaperidotite bodies that are probably surrounded by Outokumpu assemblage rocks. Thrust stacking was followed by at least three stages of faulting that divided the ore belt into fault-bounded blocks with heterogeneous displacements: (i) faulting along NW-dipping faults with unresolved kinematics, (ii) reverse faulting along c. 50°–60° SE-dipping faults, and (iii) SW–NE to SSW–NNE striking faults which may have formed at an earlier stage and have been reactivated.The specific Outokumpu alteration assemblage around metaperidotite bodies combined with shear zones acting as path ways for fluids are the main vectors to mineralization. Seismic reflection data do not provide a simple tool to directly detect the sites of Outokumpu assemblage bodies at depth but they identify strong reflector zones which are characteristic for though not exclusive to the assemblage, shear zones can be recognized as curved dislocations in the seismic lines. Our study shows that 3D modeling, when used in combination with surface geology and other geophysical data and good knowledge about the structural evolution clearly improves the interpretation of reflectors and enables the identification of strong reflector packages as Outokumpu assemblage that, due to absent geological control, have first been mapped as “unknown reflector”. It thus enhances the chances for locating potentially economic horizons at depth and to delineate target areas for detailed exploration.     

Groundwater contamination assessment in Al-Quwy’yia area of central Saudi Arabia using transient electromagnetic and 2D electrical resistivity tomography

Groundwater contamination is one of the most significant problems in arid countries. Al-Quwiy’yia region is an example of an area where the groundwater is contaminated as a result of infiltration of waste water in low-lying areas adjacent to inhabited zones. Such contamination poses significant environmental threats for the surrounding environment and groundwater. Surface observations and spatial distribution of contamination observed in the shallow aquifer indicate that the main contamination sources were from sewage as well as from waste water dumping. However, the main source of water supply for the whole area is groundwater abstracted from the relatively shallow aquifer. Therefore, the transient electromagnetic method (TEM) and 2D electrical resistivity tomography (2D ERT) have been applied close to the waste water dump site to characterize the response of pollution plumes. Both of these geoelectrical techniques are sensitive to electrical conductivity as well as to other physical properties, which are greatly influenced by the polluted groundwater. Therefore, it is possible to profile the contamination plumes, both vertically and horizontally, in the vicinity of the measured stations. The ERT profiles gave detailed information about the lateral distribution of the contaminated groundwater, whereas the TEM demonstrated the vertical extensions.     

Kinematics of the crust around the Tanggula Shan in North–Central Tibet: Constraints from paleomagnetic data

We have conducted a paleomagnetic investigation on the Middle–Upper Jurassic marine strata exposed in the hanging wall of the Tanggula Thrust system near the Yanshiping area, northern Tibet. Progressive demagnetization experiments successfully isolated stable magnetization over a broad spectrum of demagnetization temperatures. The mean direction of the characteristic remanent magnetizations for the Middle–Late Jurassic Yanshiping Group in stratigraphic coordinates (D/I (Declination/Inclination) = 5.6°/60.3°, k = 22.9, α95 = 12.9°, N = 7 s) is much more clustered than the mean direction in geographic coordinates (D/I = 345.5°/37.2°, k = 2.5, α95 = 48.4°), indicating magnetization was not acquired after folding. Although the conventional fold test is positive, incremental untilting test on the characteristic remanent magnetization reveals that a maximum value of precision parameter k occurs at 82.1 ± 4.6% untilting (D/I = 3.3°/57.8°, k = 43.9, α95 = 9.2°), which indicates the ChRMs are probably acquired during Late Cretaceous folding. This synfolding magnetization component is therefore secondary. The corresponding pole position (84.4°N, 119.4°E with dp/dm = 13.5/9.9°) is inconsistent with Jurassic–Early Cretaceous paleopoles of the region, but the paleolatitude is consistent with the Late Cretaceous paleolatitude observed in the Qiangtang terrane and its periphery. The synfolding component is carried by both magnetite and hematite, which were identified by isothermal remnant magnetization acquisition experiments, unblocking temperatures of stable magnetic components, and Curie temperature determination and correlated with observed hydrothermal veins. Available geological evidences indicate that the synfolding magnetization is probably the result of chemical remagnetization caused by orogenic fluids or hydrothermal sources during the early uplift of the Tibetan Plateau.     

Detachment folding in a Lower Cambrian–Upper Permian karst reservoir: 3D model of the Yubei 3D area (eastern Markit Slope,Tarim Basin,Northwest China)

A three-dimensional (3D) structural modeling of the Lower Cambrian–Upper Permian Yubei 3D area was performed to understand its structural evolution. This model reproduces the present-day structure of the basin and comprises 11 horizons within Lower Cambrian to Upper Permian rocks. The analysis is based on 3D depth views and faults. The results image salt movements due to tectonics and/or burial. From these observations, this paper deduces that salt structures are correlated to the main faults and tectonic events. From the model analysis, we interpret the timing and geometry of Tarim Basin tectonics. The fault geometry can be resolved based on the strike of the fault, the morphology of hanging wall strata, and the stratigraphic distribution. Emphasis is placed on gypsum rock detachment, considering its movements during the Middle Caledonian event and decoupling effects during tectonic evolution. Moreover, we point to the structural control of the Paleozoic basement and the crustal architecture (Yubei 3D Zone) on the geometry of the Tarim Basin.     

Distribution of interstellar plasma in the direction of PSR B0525+21 from data obtained on a ground–space interferometer

Observations on the RadioAstron ground–space interferometer with the participation of the Green Bank and Arecibo ground telescopes at 1668 MHz have enabled studies of the characteristics of the interstellar plasma in the direction of the pulsar PSR B0525+21. The maximum projected baseline for the ground–space interferometer was 233 600 km. The scintillations in these observations were strong, and the spectrum of inhomogeneties in the interstellar plasma was a power law with index n = 3.74, corresponding to a Kolmogorov spectrum. A new method for estimating the size of the scattering disk was applied to estimate the scattering angle (scattering disk radius) in the direction toward PSR B0525+21, θ _scat = 0.028 ± 0.002 milliarcsecond. The scattering in this direction occurs in a plasma layer located at a distance of 0.1Z from the pulsar, where Z is the distance from the pulsar to the observer. For the adopted distance Z = 1.6 kpc, the screen is located at a distance of 1.44 kpc from the observer.     

The first U–Pb isotope age data of island arc and continental–margin magmatism in the central part of the Koryak Highlands and U–Pb age of ore-controlling granitoids of the talyayigin ore field

Precision U–Pb (SHRIMP-II) isotope geochronological data, obtained for the first time, make it possible to suggest that sediments of the Neocomian primitive island arc sequence are missed or poorly developed in the South-Western part of the Mainitskii terrane of the Koryak Highlands. However, Late Albian mature island arc tuff and tuffaceous–turbidite formations are common. This enables us to extend the age range of the Mainitskii island arc from the Early Neocomian to the Late Albian and to suggest a two-stage pattern of its development. The isotope-geochronological data obtained for plagiogranite and moderately acid subvolcanics, previously attributed to the Koryak–Western Kamchatka volcanoplutonic belt, indicate that it is possible to combine them into the Middle Miocene postsubduction? polygenic complex. In addition, owing to modern high-precision isotope–geochronological methods, it has become possible to determine the age of gold–sulfide mineralization of the Talyaigin ore field, paragenetically related to the manifestations of the Middle Miocene Vilyuneiveem complex.     

New data on the evolution of the Tan–Lu fault belt: constraints from geological–geophysical surveys in the southern segment

The Tan–Lu fault is a well-known active fault belt in eastern China that has been the focus of geologic studies over the past 40 years. Since the late 1990s, numerous geophysical and geological investigations of this dislocation zone have been carried out by Chinese oil companies, as well as by universities. However, its deep structure, active periods of slip, and fault mechanism remain obscure. This study focuses on the deep structures within the Jiashan–Lujiang segment of the Tan–Lu fault belt, using high-precision geophysical tools, including magnetotelluric and magnetic sounding, and artificial seismic exploration using active source methods. Our results suggest that this segment is composed of several sub-faults. The southern part of the Tan–Lu fault belt, along the Jiashan–Lujiang sub-fault, can be divided into two parts on the basis of contrasting geological features. The Chihe–Taihu sub-fault is taken as the boundary between the two. The region east of the Chihe–Taihu sub-fault is dominated by strike–slip activity along several sub-faults. Only the Jiashan–Lujiang sub-fault is exposed at the surface, forming a large, positive flower structure, the result of late Middle Jurassic to early Late Jurassic strike–slip movement along the dislocation zone. Three sub-faults are present in Dingyuan County, two of which disappear in the southern Hefei Basin. Only the Chihe–Taihu sub-fault extends to the eastern edge of this basin, creating a half-graben depression that formed during the Early Cretaceous. Our results indicate that the present-day deep structure of the southern portion of the Tan–Lu fault zone is the result of a combination of strike–slip and extensional tectonics.     

Inversion of calcite twin data,paleostress reconstruction and multiphase weak deformation in cratonic interior – Evidence from the Proterozoic Cuddapah basin,India

Paleostress orientations from mechanically twinned calcite in carbonate rocks and veins in the neighborhood of large faults were investigated to comment on the nature of weak upper crustal stresses affecting sedimentary successions within the Proterozoic Cuddapah basin, India. Application of Turner's P–B–T method and Spang's Numerical dynamic analysis on Cuddapah samples provided paleostress orientations comparable to those derived from fault-slip inversion. Results from the neighborhood of E–W faults cutting through the Paleoproterozoic Papaghni and Chitravati groups and the Neoproterozoic Kurnool Group in the western Cuddapah basin, reveal existence of multiple deformation events − (1) NE–SW σ₃ in strike-slip to extensional regime along with an additional event having NW–SE σ_3, for lower Cuddapah samples; (2) compressional/transpressional event with ESE–WNW or NNE–SSW σ₁ mainly from younger Kurnool samples.Integrating results from calcite twin data inversion, fault-slip analysis and regional geology we propose that late Mesoproterozoic crustal extension led to initial opening of the Kurnool sub-basin, subsequently influenced by weak compressional deformation. The dynamic analysis of calcite twins thus constrains the stress regimes influencing basin initiation in the southern Indian cratonic interior and subsequent basin inversion in relation to craton margin mobile belts and plausible global tectonic events in the Proterozoic.     

Nd-isotope and geochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite suite of rocks in the southern Bastar craton,central India: petrogenesis and tectonic significance

ABSTRACT

Nd-isotope and lithogeochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite (BN) suite of rocks from the southern Bastar craton, central India, are presented to understand their nature, origin, and tectonic setting of emplacement. Various types of evidence, such as field relationships, radiometric metamorphic ages, and the global distribution of BN magmatism, suggest emplacement in an intracratonic rift setting, commonly around 2.4–2.5 Ga. On the basis of geochemistry these high-Si high-Mg rocks are classified as high-Ca boninites, high-Mg norites, and high-Mg diorites. Nd-isotope data indicate that the high-Mg norite and the high-Mg diorite samples are similar, whereas the high-Ca boninites have a different isotopic character. The high-Mg norite and the high-Mg diorite samples have younger T_DM model ages than the high-Ca boninites. Geochemical and Nd-isotopic characteristics of the studied rocks indicate some prospect of crustal contamination; however, the possibility of mantle metasomatism during ancient subduction event cannot be ignored. Trace-element modelling suggests that the high-Ca boninites may have crystallized from a magma generated by a comparatively greater percentage of melting of a lherzolite mantle source than the source for the other two varieties. Furthermore, the high-Ca boninite rocks are most likely derived from an Archaean subduction process (the Whundo-type), whereas the other two types are the products of the interaction of subduction-modified refractory mantle wedge and a plume, around the Neoarchaean–Palaeoproterozoic boundary. The emplacement of the high-Mg norites and the high-Mg diorites may be linked to crustal thickening and associated cratonization at the end of the Archaean.     

The nature of the stability of an incommensurate 3D structural modulation in Baikal lazurite: Experimental data at 550°C

The nature of the stability of an incommensurate 3D modulation (ITM) in the structure of Baikal lazurite was evaluated using the methods of experimental geochemistry and X-ray photoelectron spectroscopy. It was shown that ITM with a period of 4.6a is preserved in the lazurite structure at 550°C almost without changes within the time interval from t = 100 h to at least 2000 h, although its initial (t = 0) development was not restored. In contrast to higher temperatures (≥ 600°C), the activities of gas species have no significant influence on the process of modulation release, except for the region of low O₂, S₂, and SO₂ fugacities, where the type of modulation changes, and the monosulfide ion appears in the lazurite composition. At T = 550°C and probably at lower temperatures, SO₂ fugacity ceases to be the critical parameter of ITM existence. The ordered state of polysulfide and sulfate clusters corresponding to the ITM period of Baikal cubic lazurite is stable at T = 550°C and is an example of forced equilibrium. It develops in response to a crystal chemical event occurring at a temperature of T _x within 600–550°C and is related to the thermal compression of the structure resulting in the isolation of structural cages containing clusters with different states of sulfur. Their mutual interaction, which leads to the rapid release of the modulation at higher temperatures owing to the equalizing of cluster sizes in the cages, ceases. As a result, the proportions of reduced (S₂²⁻, and S _x ²⁻) and oxidized (SO₄²⁻, So₃²⁻, and S₂O₃²⁻ sulfur species show negligible variations, and there is only partial reduction of sulfate to sulfite and thiosulfate. Lazurite samples with disulfide and polysulfide ions behave similarly, which suggests that an important condition for the preservation of ITM is the presence of sulfur-bearing anions with different sizes rather than particular sulfur species in structural cages. The degree of ordering in the distribution of clusters attained at T _x remains unchanged owing to the development of forced equilibrium maintained by the energy balance between framework deformation and cluster ordering. Natural lazurite with an ITM structure could not form at temperatures higher than T _x , i.e., above 550–600°C