The basal ash deposit of the Sovana Eruption (Vulsini Volcanoes, central Italy): the product of a dilute pyroclastic density current

A low aspect ratio, decimeter-thick ash deposit, axisymmetrically distributed around the Latera Caldera (Western Vulsini Volcanoes, central Italy) has been studied by means of field and laboratory investigations. Field studies comprise facies analysis at centimeter scale and maximum clast size and deposit thickness measurements. Grain size and component distribution, chemical composition and particle morphoscopic features have been determined on selected samples. We discuss the co-ignimbrite ash fall vs. pyroclastic surge origin of the deposit and the hydrovolcanic vs. magmatic eruption nature. Complex facies association, textural features and grain size data rule out an ash fall origin for the whole deposit. The hydrovolcanic nature of the eruption has been discarded on the grounds of componentry and morphoscopic features of vitric fragments. We propose that the main body of the ash deposit formed from a radially expanding, dilute, turbulent pyroclastic density current, originated by a continuous collapse of a low-altitude (a few kilometers) eruptive column with a possible radial jet component.     

Chromite in the Paricutin lava flows (1943–1952)

Small euhedral chromite crystals are found in olivine macrophenocrysts (Fo_80–84) from the basaltic andesites (150 ppm Cr) erupted in 1943–1947, and in orthopyroxene macrophenocrysts of the andesites (75 ppm Cr) erupted in 1947–1952. The majority of the chromite octahedra are 5–20 μm in diameter, and some are found in clusters and linear chains of three or more oriented chromite crystals. The composition of the majority of the chromite grains within olivine and orthopyroxene macrophenocrysts is Fe²⁺/(Fe²⁺+Mg)=0.5–0.6, Cr/(Cr+Al)=0.5–0.6 and Fe³⁺/(Fe³⁺+Al+Cr)=0.2–0.3. The chromite crystals in contact with the groundmass are larger, subhedral, and grade in composition from chromite cores to magnetite rims. Comparison of the composition of chromite with those of other volcanic rocks shows that the most primitive Paricutin chromite is richer in total iron and higher in Fe³⁺/(Fe³⁺+Al+Cr) than primary chromite in most lavas. The linear chains of oriented chromite octahedra are found in olivine and orthopyroxene macrophenocrysts, and in the groundmass. These chromite chains are thought to result from diffusion-controlled crystallization because of the very high partition coefficient (1000) of Cr between chromite and melt. We conclude that chromite was a primary phase in the lavas at the time of extrusion and that magnetite only crystallized after extrusion during cooling of the lava flows. The presence of chromite microphenocrysts in andesitic lavas containing as little as 70 ppm Cr can be explained by dissolved H₂O in the melt depressing the liquidus temperature for orthopyroxene such that chromite becomes a liquidus phase. The influence of dissolved H₂O can also explain the lack of plagioclase macrophenocrysts in most of the lavas and the relatively high partition coefficient (20) of Ni between olivine and melt and the high partition coefficient (40) of Cr between orthopyroxene and melt. The liquidus temperature of the basaltic andesite is estimated to have been less than 1140°C, assuming H₂O>1 wt.%, and the log f_O2 to have been above that of the QFM buffer. The chromite and orthopyroxene liquidus temperature of the andesites, assuming H₂O>1 wt.%, is estimated to have been 1100°C or less. The derivation of the later andesites from the earlier basaltic andesites has been explained by a combination of fractional crystallization of olivine, orthopyroxene and plagioclase, and assimilation of xenoliths. The significantly lower Cr, Ni and Mg of the andesites may have been in part due to the separation of olivine macrophenocrysts plus enclosed chromite crystals from the earlier basaltic andesites.     

The Hasan Dagi stratovolcano (Central Anatolia, Turkey): evolution from calc-alkaline to alkaline magmatism in a collision zone

The Hasan Dagi volcano is one of the two large Plio-Quaternary volcanoes in Cappadocia (Central Anatolia, Turkey). Three stages of edifice construction have been identified for this volcano: Paleovolcano, Mesovolcano and Neovolcano. Most samples from Hasan Dagi volcano are calc-alkaline and define an almost complete trend from basaltic andesite to rhyolite. However, the more recent (Neovolcano) mafic samples are alkaline basalts. The mineralogical and geochemical characteristics of the oldest lavas (Keçikalesi (13 Ma) and Paleo-Hasan Dagi (7 Ma)) are significantly different from those of the younger lavas (Meso- and Neo-Hasan Dagi (<1 Ma)). Calcic plagioclase and pigeonite are typically observed in these older lavas. The Paleovolcano basalts are depleted in alkalis and display a tholeiitic tendency whereas the differentiated lavas are depleted in Na₂O but enriched in K₂O compared to younger lavas. There is an evolution through time towards higher TiO₂, Fe₂O₃^*, MgO, Na₂O and K₂O and lower Al₂O₃ and SiO₂ which is reflected in the basalt compositions. All the basalts display multi-element patterns typical of continental margin magmas with a significant enrichment in LILE (K, Rb, Ba and Th) and LREE and strong (Paleovolcano) to moderate (Meso- and Neovolcano) negative Nb, Zr and Ti anomalies. However, the younger basalts are the most enriched in incompatible elements, in agreement with their alkaline affinities and do not systematically display negative HFSE anomalies. REE data suggest an hydrous amphibole-bearing crystallization history for both Meso- and Neovolcano lavas. The distinction between the older and younger lavas is also apparent in trace element ratios such as Nb/Y, Ti/Y and Th/Y. These ratios indicate the role of a subducted component±crustal contamination in the genesis of the Hasan Dagi lavas, particularly for the oldest lavas (Keçikalesi and Paleo-Hasan Dagi). The decreasing influence of this component through time, over the last 6–7 m.y., has been accompanied by an increasing contribution of melt-enriched lithosphere. Although the range of variation of Sr, Nd and Pb isotopic ratios is small (0.70457–0.70515; 0.51262–0.51273; 18.80–18.94; 15.64–15.69; 38.87–39.10), it also reflects the evolution of the magma sources through time. Indeed, the youngest (Neovolcano) and most primitive basalts display significantly lower ⁸⁷Sr/⁸⁶Sr than the Paleo- and Mesovolcano basalts, whereas the Mesovolcano basalts display more radiogenic Pb than Paleovolcano samples. Magma mixing processes between initially heterogeneous and/or variably contaminated magmas may account for the genesis of the less differentiated and intermediate lavas (48–57% SiO₂). Meso- and Neovolcano differentiated lavas (60–68% SiO₂) are either derived from the analyzed basalts or from more primitive and more depleted magmas by fractional crystallization±some crustal contamination (AFC). Furthermore, the highly differentiated samples (72–75% SiO₂) are not strongly contaminated. The strong calc-alkaline character of Hasan Dagi lavas, in the absence of contemporaneous subduction, must reflect the heritage of the early subduction of the Afro–Arabian plate under the Eurasian plate. The evolution towards alkaline compositions through time is clearly related to the development of extensional tectonics in Central Anatolia in the Late Miocene.     

Damage to structures by pyroclastic flows and surges, inferred from nuclear weapons effects

In order to define the risk from explosive eruptions, one must constrain both the probability of explosive events and the effects, or consequences, of those events. This paper focuses on the effects of pyroclastic flows and surges (here termed ‘pyroclastic density currents', or PDCs) on buildings, infrastructure elements, and to some extent on vehicles. PDCs impart a lateral force to such structures in the form of dynamic pressure, which depends on the bulk density of the PDC (which in turn depends mainly on particle concentration) and its velocity. For reasonable ranges of particle concentration (10⁻³ to 0.5) and velocities (10 to 300 m/s), dynamic pressure on the upstream face of a structure ranges from 0.1 kPa to 10⁴ kPa. Lateral loads ranging up to about 100 kPa were produced during nuclear weapons tests in the 1940s and 1950s that were designed to study the effects of such loading on a variety of structures for civil defense and emergency response purposes in the event of nuclear war. Although considerable simplifications are involved, the data from these weapon tests provide useful analog information for understanding the effects of PDCs. I reviewed data from the nuclear tests, describing the expected damage from different loadings. Tables are provided that define the response of different structural elements (e.g., windows, framing, walls) and whole structures to loading in probabilistic terms, which in principle account for variations in construction quality, orientation, and other factors. Finally, damage documented from historical eruptions at Mt. Lamington (1951), Herculaneum (AD 79 Vesuvius eruption), and St. Pierre (1902 Mt. Pelee eruption) is reviewed. Damage patterns, combined with estimates of velocity, provide an independent estimate of particle concentration in the PDCs. Details of structural damage should be recorded and mapped around future eruptions in order to help refine this aspect of consequence analysis. Another fruitful approach would be to combine numerical simulations of eruption scenarios, which can produce simulated maps of dynamic pressure, with GIS-based data on structures for a given region; the result would be predictions of consequences that could be used for planning and emergency response training.     

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.     

OSL chronology of Quaternary terraced deposits outcropping between Mt. Etna volcano and the Catania Plain (Sicily,southern Italy)

In this paper we tested the applicability of the Optically Stimulated Luminescence (OSL) technique through Single-Aliquot Regenerative-dose (SAR) protocol, on single grain quartz extracted from alluvial–coastal sediments. Five samples were collected from deposits belonging to a flight of seven orders of coastal–alluvial terraces outcropping in the area between Mt. Etna volcano and the Catania Plain (Sicily, southern Italy), at the front of the Sicilian fold and thrust system. After various performance tests, we obtained OSL ages ranging between 240 ± 12 and 80 ± 4 ka, consistent with the normal evolutionary model of a terraced sequence, moving from the highest to the lowest elevation. Obtained data allowed us to determine a mean uplift rate of 1.2 mm/year during the last 240 ka, mostly related to regional uplift processes coupled with sea-level changes. Moreover, terraces belonging to the two highest orders are folded, forming a large anticline. According to our results, the frontal thrust of the Sicilian chain was active between 236 and 197 ka ago, even though seismological and geodetic data suggest current activity to the back.     

Ground and marine magnetic surveys of the lower eastern flank of Etna volcano (Italy)

In 1996 and 1997, two high-resolution magnetic surveys, one on land and the other at sea, were carried out on the lower eastern flank of Mount Etna. The magnetic surveys, covering an area of about 400 km², aimed to elucidate the relationships between the main tectonic and morphologic features of this flank of Mount Etna. Major features include widespread NNW- and NNE-trending active faults and the Valle del Bove, a depression considered to be the source area of the Chiancone deposit, the largest Etnean volcaniclastic sequence. Magnetic surveys show anomalies that roughly follow the trend of active main structures. Although few magnetization measurements are available for the most representative outcrops of the lower eastern side of Mount Etna, interpretation of the anomalies defines the underground geometry of the Chiancone deposit and its relationship with volcano stratigraphic units and the underlying sedimentary rocks. In particular, a volume of about 14 km³ was ascribed to the Chiancone deposit. Such a large amount of material was likely produced by a catastrophic event, and deposited at different periods at the exit of the Valle del Bove in an area produced by the interaction, on a regional scale, of the main tectonic structures affecting this flank of the volcano.     

The occurrence of Mt Barca flank eruption in the evolution of the NW periphery of Etna volcano (Italy)

Geological surveys, tephrostratigraphic study, and ⁴⁰Ar/³⁹Ar age determinations have allowed us to chronologically constrain the geological evolution of the lower NW flank of Etna volcano and to reconstruct the eruptive style of the Mt Barca flank eruption. This peripheral sector of the Mt Etna edifice, corresponding to the upper Simeto valley, was invaded by the Ellittico volcano lava flows between 41 and 29 ka ago when the Mt Barca eruption occurred. The vent of this flank eruption is located at about 15 km away from the summit craters, close to the town of Bronte. The Mt Barca eruption was characterized by a vigorous explosive activity that produced pyroclastic deposits dispersed eastward and minor effusive activity with the emission of a 1.1-km-long lava flow. Explosive activity was characterized by a phreatomagmatic phase followed by a magmatic one. The geological setting of this peripheral sector of the volcano favors the interaction between the rising magma and the shallow groundwater hosted in the volcanic pile resting on the impermeable sedimentary basement. This process produced phreatomagmatic activity in the first phase of the eruption, forming a pyroclastic fall deposit made of high-density, poorly vesicular scoria lapilli and lithic clasts. Conversely, during the second phase, a typical strombolian fall deposit formed. In terms of hazard assessment, the possible occurrence of this type of highly explosive flank eruption, at lower elevation in the densely inhabited areas, increases the volcanic risk in the Etnean region and widens the already known hazard scenario.     

Lava-flow hazard on the SE flank of Mt. Etna (Southern Italy)

A method for mapping lava-flow hazard on the SE flank of Mt. Etna (Sicily, Southern Italy) by applying the Cellular Automata model SCIARA_-fv is described, together with employed techniques of calibration and validation through a parallel Genetic Algorithm. The study area is partly urbanised; it has repeatedly been affected by lava flows from flank eruptions in historical time, and shows evidence of a dominant SSE-trending fracture system. Moreover, a dormant deep-seated gravitational deformation, associated with a larger volcano-tectonic phenomenon, affects the whole south-eastern flank of the volcano.     

Volcanology,history and myths of the Lake Albano maar (Colli Albani volcano,Italy)

The polygenetic Albano maar is the most recent centre of the Colli Albani volcano, located just few kilometres to the south-east of Roma. Presently the maar hosts a 167.5 m deep crater lake, the deepest in Europe. The maar is to be considered quiescent, as phreatic activity is documented throughout the Holocene. This paper illustrates the close relationships between the activity of the maar and the history of settlement in the Roman region as recorded in the geology, archaeology, history and legends of the area. Severe fluctuations of the groundwater table and catastrophic overflows of the Lake Albano from the maar rim had occurred prior to and after the early prehistoric settlements dated in the maar area at the Eneolithic times (ca. III millennium B.C.). Repeated lahars occurred along the northwestern slope of the maar filling in the paleodrainage network and forming a vast plain. Paleohydraulic analyses on fluvial and lahar deposits originated from the Holocene phreatic activity of the Albano maar indicate sediment–water flows in excess of hundreds of cubic metres per second. Absolute age determinations of the paleosoil underlying one of the most recent deposits of the lahar succession at 5800 ± 100 yr B.P. (¹⁴C CAL) are in perfect agreement with the age of the overlying Eneolithic age settlements. The last catastrophic overflow is described in the Roman literature as a consequence of the anger of Poseidon against the Romans in 398 B.C. for their war against the Etruscans. In 394 B.C. the Romans decided to prevent the repetition of such events by the excavation through the maar crater wall of a 1.5 km long drain tunnel, which is still operational, keeping the lake 70 m below the lowest point of the maar rim. This tunnel drain may be regarded as the first prevention device for volcanic hazard in history and shows an unprecedented development of the engineering technology under the pressure of hazard perception. The surprising and still largely unknown results of this study are very important to redefine the hazard of the Roman region.     

Volatile-rich magma injection into the feeding system during the 2001 eruption of Mt. Etna (Italy): its role on explosive activity and change in rheology of lavas

The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.     

The 1997 Umbria-Marche (Italy) earthquake sequence: analysis of the data recorded by the local and temporary networks

We present some preliminary results obtained from thejoined analysis of the data collected by the permanentand the temporary networks operating in the area ofthe earthquake sequence that followed (andanticipated) the 26 September, Central Italy, mainshocks. In particular, these earthquake data haveallowed us to determine a well constrainedwave-velocity model (both P and S) with stationcorrections which demonstrated to produce robusthypocentral locations. These velocity modelswith station corrections have been used forre-locating the whole September 1997–July 1998subset of data of the permanent network, and theprevious background seismicity, starting from May1996. The focal mechanisms of the largest events werealso obtained from an analysis of the first-motionpolarities.Our results indicate that 1) the seismic activityaligns on a SE-NW trend for a total length of about50 km of extension; 2) the focal depth of theseevents is restricted to the range 0–9 km; 3) mostevents can be related to sub-parallel SW dipping faultplanes; 4) focal mechanisms of the largest shocks(M_L > 4) show a coherent behaviour, withnormal fault solution on SSE-NNW striking, SW dippingplanes; 5) the space-time evolution of the activitydisplays a discontinuous mode of energy release, withdifferent episodes of activation and an apparentclustering of aftershocks at the edges of the areaswhich presumably ruptured in the main shocks.     

Temporal Variability of Major and Trace Element Concentrations in the Groundwaters of Mt. Etna (Italy): Effects of Transient Input of Magmatic Fluids Highlighted by Means of Cluster Analysis

Data for major, minor and trace elements in groundwaters from Mt. Etna volcano collected in 1994, 1995 and 1997 were analyzed using Cluster Analysis (CA). Two groups of sampling sites were identified (named clusters A and B), mainly on the basis of their different salinity and content of dissolved CO₂. The highest levels of both of these parameters were observed in the sites of cluster A, located in the lower south-western and central eastern flanks of the volcano. For both of the statistical groups CA was repeated, taking into account the mean values of each parameter in time, and the results allowed us to recognize four distinct groups of parameters for each group of sites on the basis of their temporal patterns. Four different types of temporal patterns were recognized: concave, convex, increasing, decreasing. The observed changes were basically interpreted as a result of the different response of dissolved chemical elements to changes in the aqueous environment and/or in their solubility/mobility in water due to different rates of input of magmatic gases to Etna’s aquifers. The main changes occurred in 1995, when Etna’s volcanic activity resumed after a two-year period of rest. The temporal changes of the majority of the studied parameters (water temperature, water conductivity, Eh, pH, Al, Mg, B, Ca, Cl⁻, Hg, Mn, Mo, Na, Ni, Se, Si, Sr, Cr Zn and pCO₂) were not cluster-dependent, therefore they were not apparently affected by differences in water salinity between the two groups of sampling sites. A limited number of parameters (Ti, K, Li, HCO₃⁻, As, Fe, SO₄²⁻, Cu and V), however, manifested different behaviors, depending on the cluster of sites to which they belonged, thus suggesting their apparent dependency on water salinity.     

Geolithological and anthropogenic controls on the hydrochemistry of the Volturno river (Southern Italy)

The present work aims to study the main chemical and physical water parameters in the upper and middle Volturno river catchment (southern Italy), between the Capo Volturno springs and the confluence with the Calore river. This study makes use of morphology, geolithology, tectonic, land use, and physico‐chemical (pH, electrical conductivity, redox potential, temperature, major ions, and ²²²Rn) data for the identification of the main sources of surface and groundwaters in the Volturno catchment and of their evolution and mixing both in base flow and peak flow conditions. The study was also performed to assess whether the alteration due to potential anthropogenic contamination may hamper the identification of natural “primitive” sources of surface waters, especially in the populated and farmed plains far from the river headwaters. Our data suggest that water chemistry of this stretch of the Volturno river is dominated mainly by lithology and, only marginally, by the intense exogenous activities and that this trend is appreciable in both base flow and peak flow conditions. The proposed simple geochemical approach based on easy‐to‐sample matrices and on cost‐effective standard methods is a valuable tool to address catchment functionality especially in upland areas, where complex geologic and structural settings, heterogeneous groundwater flow, and logistical issues are the rule rather than the exception. Because the upper and middle Volturno catchment is comparable with numerous valleys of the Mediterranean area, this study could be a reference for analogous applications.     

Volcanic geomorphology and tectonics of the Aeolian archipelago (Southern Italy) based on integrated DEM data

The geomorphological and morphometric analysis of the sea floor topography surrounding the Aeolian Islands, South Tyrrhenian Sea, Italy, provides insights into the relationships between the volcanological evolution of the islands and their tectonic features. We constructed geomorphological maps of the submarine portions of the seven large edifices constituting the islands on the basis of a DEM with a 5 m resolution step. These maps include constructional and destructional landforms such as submarine volcanic vents located west of Lipari and north of Alicudi, and hummocky surfaces recognised north of Lipari and Salina. The latter landforms, together with the occurrence of large scars affecting the main edifices on land, suggest that sector collapses affected some islands. Geomorphological data indicate that the location of subaerial and submarine vents is strongly controlled by local tectonic structures striking WNW-ESE (Alicudi-Filicudi sector), NNW-SSE (Salina-Lipari-Vulcano sector) and NE-SW (Panarea-Stromboli sector). The islands can be divided into two groups on the basis of some morphometric parameters: a first group with a pancake-like shape, Dp/D (abrasion platform diameter/basal diameter) higher than 0.40 and H/D (total height/basal diameter) lower than 0.13, and a second group with a conical shape, characterised by Dp/D lower than 0.34 and H/D higher than 0.14. These ratios and other morphometric parameters reflect the different volcanological and structural evolution of the Aeolian Islands. The pancake-like shaped complexes have been created, in addition to their submarine stage, by extrusive and highly explosive activity, whereas the cone-shaped edifices have been characterised by effusive or moderate explosive activity.Editorial responsibility: C Kilburn     

青虾生长规律与群体组成的研究

报道了上海川沙县孙桥河道青虾的生长呈明显的阶段性,如雄虾的第一阶段（1990年6—11月）的生长方程为L_t=3.38[1-e~(-0.4943(t+0.1674)];第二阶段（1991年2—6月）的生长方程为L_t=6.57/(1+e~(2.1805-0.2787t);它们的拐点分别为2.07月龄和11.97月龄。渔获群体分析结果表明,月龄为0-15月,体长范围为1.30—6.58cm,体重范围为0.060—13.39g;一年出现两个群体,其中夏季群体生活期从当年7月至翌年10月,数量大,占群体数量80％以上;秋季群体生活期从当年9月至翌年12月,约占群体数量20％左右。群体中一般雄虾数量多于雌虾数量,月性比(?)在0.61—1.35之间变动。