Complementary Investigative Techniques for Site Assessment with Low-Level Contaminants

A remedial investigation (RI) was performed in an area downgradient from an abandoned missile silo at Vandenberg Air Force Base, California, as part of the United States Air Force Installation Restoration Program (IRP). A number of complementary investigative techniques were used to assure a reliable assessment of site contamination. These included the review of aerial photographs, the use of an organic vapor analyzer (OVA) and carbon adsorption/mass spectrometer (MS) method to conduct a soil-gas survey; magnetic and electromagnetic geophysical surveys; bedrock permeability testing; and the chemical analysis of soil, sediment, surface water, and ground water samples. The results from this investigation revealed the presence of an undocumented landfill and a small trichloroethylene plume in ground water at concentrations ranging from 6.7 ppb to 31 ppb. The investigation also identified local ground water flow direction, provided strong evidence of the location of potential sources of contamination, and defined the downgradient extent of ground water contamination. Because the identified contaminants have not as yet reached the environmentally sensitive wetland at the base of the slope below this facility, there is still time to propose remedial alternatives that would serve to protect this environmentally sensitive area.     

The use of GPR and VES in delineating a contamination plume in a landfill site: a case study in SE Brazil

This paper presents the results of the application of the Ground Penetrating Radar (GPR) method, or Georadar, in outlining a zone of contamination due to solid residues at the waste burial site of Rio Claro in the state of São Paulo, SE Brazil. A total of eight GPR profiles with 50- and 100-MHz antennae were surveyed. Six profiles were located within the landfill site and the remaining two were outside. The main objective of the GPR survey was to evaluate the side extension of contamination. A Vertical Electric Sounding (VES) survey was performed at four points within the site in order to investigate the vertical extent of the contamination plume and to define the bottom of the landfill. Two additional VESs were done outside the landfill with the purpose of determining the top of the ground water table and the geoelectric stratigraphy of the background. From the interpretation of the GPR profiles, it was possible to locate the top of the contamination plume and to infer that it was migrating laterally beyond the limits of the waste disposal site. This was observed along the profile situated close to the highway SP-127, which was about 20 m from the limit of the site. The signature of the contaminant appears as a discontinuous reflector that is believed to be a shallow ground water table. The discontinuity is marked by a shadow zone, which is characteristic of conductive contaminant residues. The contamination did not move far enough to reach a sugar cane plantation located at approximately 100 m from the border of the site. In the regions free from contamination, the ground water table was mapped at approximately 10 m of depth, and it was characterized by a strong and continuous reflector. The radar signal penetrated deep enough and enabled the identification of a second reflector at approximately 14 m deep, interpreted as the contact between the Rio Claro and the Corumbataí formations. The contact is marked by the presence of gravel characterized by ferruginous concretes, which cause the strong amplitude reflection in the GPR profile. Within the landfill site, the quantitative interpretation of the VES results showed the contamination zone. The base of the landfill varies between 11 and 15 m deep. Outside the landfill site, the VES results showed no indication of contamination and allowed the determination of the top of the ground water table and the contact between the Rio Claro and the Corumbataí formations. The results of GPR and VES showed a good agreement and the integrated interpretations were supported by local geology and information from several boreholes, about 17 m depth, on average. The bottom of the landfill reaches a maximum of 14.5 m depth.     

Natural Attenuation of Aromatic Hydrocarbons in a Shallow Sand Aquifer

Inadvertent release of petroleum products such as gasoline into the subsurface can initiate ground water contamination, particularly by the toxic, water-soluble and mobile gasoline components: benzene, toluene and xylenes (BTX). This study was undertaken to examine the processes controlling the rate of movement and the persistence of dissolved BTX in ground water in a shallow, unconfined sand aquifer.
Water containing about 7.6 mg/ L total BTX was introduced below the water table and the migration of contaminants through a sandy aquifer was monitored using a dense sampling network. BTX components migrated slightly slower than the ground water due to sorptive retardation. Essentially all the injected mass of BTX was lost within 434 days due to biodegradation. Rates of mass loss were similar for all monoaromatics; benzene was the only component to persist beyond 270 days. Laboratory biodegradation experiments produced similar rates, even when the initial BTX concentration varied.
A dominant control over BTX biodegradation was the availability of dissolved oxygen. BTX persisted at the field site in layers low in dissolved oxygen. Decreasing mass loss rates over time observed in the field experiment are not likely due to first-order deeradation rates, but rather to the persistence of small fractions of BTX mass in anoxic layers.     

Decision Analysis for Leachate Control at a Fractured Rock Landfill

The municipal landfill at the Complexe Environnemental de Saint-Michel (CESM) in Montreal, which is the third largest in North America, is located in a former quarry in fractured limestone. Impressive measures are taken to monitor and control biogas and leachate generated at the site. Leachate containment is presently performed with a pumping well completed within the waste. The efficiency of the well in controlling off-site leachate migration is questioned because field observations strongly suggest that the nearby former Francon quarry is diverting local ground water flow. To address this issue, four additional hydraulic control options are considered: (1) increased pumping at the existing waste well; (2) new pumping wells in the rock on the eastern limit of the site; (3) new injection wells in the rock on the eastern limit; and (4) combination of new injection wells at the same location and new water supply wells upgradient of the landfill. We evaluated the four hydraulic control options at the CESM using two coupled models: (1) a decision model based on an objective function weighting the risk, costs, and benefits of each option translated into dollar units; and (2) a numerical ground water flow model to represent the effect of operational conditions and ascertain success. Decision analysis offers a quantitative unbiased tool to evaluate the potential and relative cost of each option, but qualitative considerations and judgment still must be used for a complete evaluation. Our analysis confirms that scenario 4, which was the intuitively favored option, represents the best containment strategy.     

Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Vertical Delineation of Contamination in Fractured Bedrock Aquifer

The New Jersey Department of Environmental Protection's Technical Regulations require the horizontal and vertical delineation of contamination. Monitor wells screened at increasingly deeper intervals are used to delineate vertical contamination. In New Jersey, the open interval in a bedrock well cannot exceed 7.6 m. Since contamination has been found at depths as great as 91.4 m in a production well in the study area, it would be prohibitively expensive to install monitor wells with 7.6 m open holes at ever-increasing depths until no contamination was found. Isolation of discrete zones in boreholes using pneumatic packers was implemented at a site in north central New Jersey. Ground water samples were collected from selected 6.1 m sections of boreholes drilled into fractured bedrock at three locations on the property and one offsite location. The ground water samples were analyzed in a field laboratory. The analytical results were used to determine the vertical extent of gasoline-related compounds dissolved in the ground water on the property and offsite. These compounds include benzene, ethylbenzene, methyl tertiary butyl ether, toluene, and xylenes. The four boreholes were converted into bedrock monitor wells. The intake interval for each of the wells was selected through evaluation of the vertical distribution of contaminants as determined from analytical results obtained from a field laboratory located onsite. Three wells are used for the recovery of contaminated ground water. The recovered water will be treated at the onsite air-stripping unit. The fourth well is used to chemically and hydraulically monitor the progress of the ground water recovery program.     

Electric-hydraulic conductivity correlation in fractured crystalline bedrock: Central Landfill, Rhode Island, USA

Remote sensing and geoelectrical methods were used to find water-bearing fractures in the Scituate granite under the Central Landfill of Rhode Island. These studies were necessary to evaluate the integrity of the sanitary landfill and for planning safe landfill extensions. The most useful results were obtained with fracture trace analysis using Landsat and SLAR imagery in combination with ground-based resistivity measurements using Schlumberger vertical electrical soundings based on the assumption of horizontally layered strata. Test borings and packer tests confirmed, in the presence of a lineament and low bedrock resistivity, the probable existence of high bedrock fracture density and high average hydraulic conductivity. However, not every lineament was found to be associated with high fracture density and high hydraulic conductivity. Lineaments alone are not a reliable basis for characterising a landfill site as being affected by fractured bedrock. Horizontal fractures were found in borings located away from lineaments. High values of hydraulic conductivity were correlated with low bedrock resistivities. Bedrock resistivities between 60 and 700 Ω m were associated with average hydraulic conductivities between 4 and 60 cm/day. In some cases very low resistivities were confined to the upper part of the bedrock where the hydraulic conductivity was very large. These types of fractures apparently become narrower in aperture with depth. Bedrock zones having resistivities greater than 1000 Ω m showed, without exception, no flow to the test wells. Plots of bedrock resistivity versus the average hydraulic conductivity indicate that the resistivity decreases with increasing hydraulic conductivity. This relationship is inverse to that found in most unconsolidated sediments and is useful for estimating the hydraulic conductivity in groundwater surveys in fractured bedrock. In appropriate settings such as the Central Landfill site in New England, this electric-hydraulic correlation relationship, supplemented by lineament trace analysis, can be used effectively to estimate the hydraulic conductivity in bedrock from only a limited number of resistivity depth soundings and test wells.     

Utilization of Shallow Geophysical Sensing at Two Abandoned Municipal/Industrial Waste Landfills on the Missouri River Floodplain

In the past 30 to 40 years, floodplain areas of large rivers, such as the Missouri River, have been extensively used for large industrial and municipal landfills. Many of these sites are now causing varying degrees of ground water contamination. Rapid geophysical characterization techniques have proven useful for delineation of anomalous areas indicative of potential contaminant plumes. These methods have also resulted in a cost effective approach to the location and number of monitoring wells.
An effective technique to initially characterize ground water contamination at such landfills along the Missouri River in northwestern Missouri involved a combination of electrical resistivity and electromagnetic conductivity methods. Resistivity was used to obtain soundings of the alluvium by using a modified Wenner array and to corroborate shallow electromagnetic conductivity measurements by using short Wenner array electrode spacings.
Upon confirmation of similar measurements of the upper soils for the two methods, numerous electromagnetic conductivity traverses were made at each landfill site. The data generated from these surveys were graphed and contoured to delineate anomalous areas. Based on the geophysical study, a ground water monitoring well network was then designed for each landfill.
As a result, a minimal number of wells were required to initially characterize the ground water quality at these two sites. In general, analysis of water samples from these wells displayed good correlation with the geophysical results.     

Analytical and Numerical Modeling of Solute Intrusion,Recovery, and Rebound in Fractured Bedrock

Contaminated groundwater in fractured bedrock can expose ecosystems to undesired levels of risk for extended periods due to prolonged back-diffusion from rock matrix to permeable fractures. Therefore, it is key to characterize the diffusive mass loading (intrusion) of contaminants into the rock matrix for successful management of contaminated bedrock sites. Even the most detailed site characterization techniques often fail to delineate contamination in rock matrix. This study presents a set of analytical solutions to estimate diffusive mass intrusion into matrix blocks, it is recovered by pumping and concentration rebound when pumping ceases. The analytical models were validated by comparing the results with (1) numerical model results using the same model parameters and (2) observed chloride mass recovery, rebound concentration, and concentration in pumped groundwater at a highly fractured bedrock site in Alberta, Canada. It is also demonstrated that the analytical solutions can be used to estimate the total mass stored in the fractured bedrock prior to any remediation thereby providing insights into site contamination history. The predictive results of the analytical models clearly show that successful remediation by pumping depends largely on diffusive intrusion period. The results of initial mass from the analytical model was used to successfully calibrate a three-dimensional discrete fracture network numerical model further highlighting the utility of the simple analytical solutions in supplementing the more detailed site numerical modeling. Overall, the study shows the utility of simple analytical methods to support long-term management of a contaminated fractured bedrock site including site investigations and complex numerical modeling.     

Pharmaceuticals and Other Organic Waste Water Contaminants Within a Leachate Plume Downgradient of a Municipal Landfill

Ground water samples collected from the Norman Landfill research site in central Oklahoma were analyzed as part of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program's national reconnaissance of pharmaceuticals and other organic waste water contaminants (OWCs) in ground water. Five sites, four of which are located downgradient of the landfill, were sampled in 2000 and analyzed for 76 OWCs using four research methods developed by the USGS. OWCs were detected in water samples from all of the sites sampled, with 22 of the 76 OWCs being detected at least once. Cholesterol (a plant and animal steroid), was detected at all five sites and was the only compound detected in a well upgradient of the landfill. N,N-diethyltoluamide (DEBT used in insect repellent) and tri(2-chloroethyl) phosphate (fire-retardant) were detected in water samples from all four sites located within the landfill-derived leachate plume. The sites closest to the landfill had more detections and greater concentrations of each of the detected compounds than sites located farther away. Detection of multiple OWCs occurred in the four sites located within the leachate plume, with a minimum of four and a maximum of 17 OWCs detected. Because the landfill was established in the 1920s and closed in 1985, many compounds detected in the leachate plume were likely disposed of decades ago. These results indicate the potential for long-term persistence and transport of some OWCs in ground water.     

Convergent Radial Tracing of Viral and Solute Transport in Gneiss Saprolite

Deeply weathered crystalline rock aquifer systems comprising unconsolidated saprolite and underlying fractured bedrock (saprock) underlie 40% of sub-Saharan Africa. The vulnerability of this aquifer system to contamination, particularly in rapidly urbanizing areas, remains poorly understood. In order to assess solute and viral transport in saprolite derived from Precambrian gneiss, forced-gradient tracer experiments using chloride and Escherichia coli phage ΦX174 were conducted in southeastern Uganda. The bacteriophage tracer was largely unrecovered; adsorption to the weathered crystalline rock matrix is inferred and enabled by the low pH (5.7) of site ground water and the bacteriophage's relatively high isoelectric point (pI = 6.6). Detection of the applied ΦX174 phage in the pumping well discharge at early times during the experiment traces showed, however, that average ground water flow velocities exceed that of the inert solute tracer, chloride. This latter finding is consistent with observations in other hydrogeological environments where statistically extreme sets of microscopic flow velocities are considered to transport low numbers of fecal pathogens and their proxies along a selected range of linked ground water pathways. Application of a radial advection-dispersion model with an exponentially decaying source term to the recovered chloride tracer estimates a dispersivity (α) of 0.8 ± 0.1 m over a distance of 4.15 m. Specific yield (S_y) is estimated to be 0.02 from volume balance calculations based on tracer experiments. As single-site observations, our estimates of saprolite S_y and α are tentative but provide a starting point for assessing the vulnerability of saprolite aquifers in sub-Saharan Africa to contamination and estimating quantitatively the impact of climate and abstraction on ground water storage.     

A Simple Method for Measuring the Vertically of Small-Diameter Driven Wells

The presence of stones, solid waste, and other obstructions can deflect small-diameter driven wells during installation, leading to deviations of the well from its intended position. This could lead to erroneous results, especially for measurements of ground water levels by water level meters. A simple method was developed to measure deviations from the intended positions of well screens and determine correction factors required for proper measurement of ground water levels in nonvertical wells. The method is based upon measurement of the hydrostatic pressure in the bottom of a water column, which is established in the well lube. The method was used to correct water level measurement in wells driven through a landfill site. Errors of up to 27 cm in water level were observed at the landfill site. The correction of the water level measurements had a significant effect on estimated local ground water flow directions.     

Seismic imaging of the shallow subsurface: shear-wave case histories

Obtaining high-resolution images of the geology and hydrogeology of the subsurface in the depth range from ground level to 50 m is one of the major challenges of modern geophysics. The methods which are commonly used (such as compressional-wave surveys and ground-penetrating radar) often suffer from adverse effects caused by the near-surface conditions, changes in water saturation and various sources of noise. This paper demonstrates some of the advantages offered by the use of shear-wave seismology and by the combination of shear- and compressional-wave seismic methods in shallow subsurface investigations.
Multicomponent shallow seismic tests were carried out at four different sites to examine the effectiveness of different acquisition geometries under a variety of near-surface geological conditions. Near-surface conditions encountered at the sites included thick clays, clay/sand sequences overlying Chalk, mudstone overlying granodiorite bedrock and landfill material.
Under all conditions, shear-wave data acquisition was found to have advantages over compressional-wave acquisition for the investigation of the shallow subsurface. Shear head waves, being unaffected by water saturation, achieved penetration to greater depths at a site in Crewkerne, Dorset where compressional head-wave penetration was limited to the near-surface layers. Better vertical resolution was achieved at shallow depths using shear-wave reflection energy at a landfill site. Shear-wave reflections from shallow interfaces were in some cases less affected by noise compared with the equivalent compressional-wave reflections. Combinations of shear- and compressional-wave data recording allowed the measurement of a Poisson's ratio log and gave indications of seismic anisotropy at two sites where dipping clay layers were present.     

First results on determination of cosmogenic 36Cl in limestone from the Yenicekale Complex in the Hittite capital of Hattusha (Turkey)

We have measured ³⁶Cl in three rock surfaces of the Yenicekale building complex in Hattusha (Bo?azköy, Turkey). Hattusha was the capital of Hittite Empire which lasted from about 1650/1600 to 1200 BC. At Yenicekale, Hittite masons flattened the summit of an outcropping limestone knoll to form an artificial platform as the foundation for a building. Next they built a circuit wall along the lateral precipices of the flattened bedrock platform. We took one sample from the limestone bedrock platform and two samples from limestone building blocks of the circuit wall for cosmogenic ³⁶Cl analysis. Calculated exposure ages are 20 ± 1 ka for the sample from the bedrock platform and 24 ± 1 ka and 52 ± 2 ka for the circuit wall blocks. These exposure ages are significantly older than the age expected based on the estimated time of construction between 3.2 ka and 3.7 ka. We conclude that the sampled surfaces contain significant inherited cosmogenic ³⁶Cl. We cannot directly determine exposure ages for the building complex based on these three samples. On the other hand we may use the measured concentrations to determine how much of the rock was removed from the platform during flattening. To this end we modeled the variation of ³⁶Cl production with depth at Yenicekale using the results from the bedrock sample. We conclude that the Hittite masons removed only around 3 m from top of the limestone block. This means that the volume of rock removed from the bedrock platform is significantly less than the volume in the circuit wall atop the platform. They did not gain enough rock from this flattening to make the building. In agreement with this, the first results of our detailed microfacies analysis indicate that many of the building blocks are not of the same facies as the underlying limestone and must have been quarried elsewhere. Although we were not able to exposure date the Yenicekale complex due to the presence of inherited ³⁶Cl, our data suggest that Hittite masons excavated (most of) the building stones not at Yenicekale, but in quarries outside of Hattusha and then transported them to the construction site. These quarries have not yet been identified.     

Pesticide residues in ground water of the San Joaquin Valley, California

A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.

Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.

Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils.     

The Geochemistry of Boron in a Landfill Monitoring Program

Ground water monitoring data collected during the past eight years at a permitted municipal solid waste (MSW) disposal facility located in the midwestern United States indicated fluctuations in typical leachate indicator parameter concentrations. Apparent trends in the data inferred leachate outbreak, generating suspicion as to the integrity of the landfill liner. Eight ground water monitoring wells were installed in three distinct geologic units at the landfill facility, including glacial drift, silurian dolomite, and a post-glacial peat fen, which is downgradient from the landfill. Piezometer nests were used to define ground water gradients at the site. Using boron as an indicator, the occurrence of analytes of concern in the downgradient monitoring wells were shown to be indicative of the natural geochemistry of site ground water. This work emphasizes the importance of understanding site hydrogeology during the interpretation of ground water quality data.     

The Application of a Statistical Trend Analysis Model to Ground Water Monitoring Data from Solid Waste Landfills

A statistical trend methodology is used to compare ground water quality between eight landfill sites in western Michigan as a case study. Monitoring data were collected over a 15-year period on 36 parameters at an upgradient and downgradient well selected at each of the eight sites. This yielded a total of 576 monitoring data sets available for analysis. New trend and contamination indices are introduced that are used to compare ground water contamination between these eight sites. These indices are used to assess each landfill's relative potential for environmental harm.
Many questions remain unanswered, but what is demonstrated here is that this type of methodology has the potential to be used to assess trends of ground water chemistry concentrations at landfill sues in a region. A specific purpose of such an assessment could be to provide a quantified basis for the prioritization of funds allocated for cleanup of contaminated landfill sites. Having a technical capability to reduce large amounts of ground water monitoring data to appropriate summaries, which then can be used to assess environmental contamination between several sites, could also have important economic and health implications in other settings. Hopefully this paper will encourage further development of such technologies for these purposes.     

Soil Gas Screening for Chlorinated Solvents at Three Contaminated Karst Sites in Tennessee

Soil gas was sampled using active sampling techniques and passive collectors at three sites in Tennessee to evaluate the effectiveness of these techniques for locating chlorinated solvent sources and flowpaths in karst aquifers. Actively collected soil gas samples were analyzed in the field with a portable gas chromatograph, and the passive soil gas collectors were analyzed in the lab with gas chromatography/mass spectrometry. Results of the sampling indicate that the effectiveness of both techniques is highly dependent on the distribution of the contaminants in the subsurface, the geomorphic and hydrogeologic characteristics of the site, and, in one case, on seasonal conditions. Both active and passive techniques identified areas of elevated subsurface chlorinated solvent concentrations at a landfill site where contamination remains concentrated in the regolith. Neither technique detected chlorinated solvents known to be moving in the bedrock at a manufacturing site characterized by thick regolith and an absence of surficial karst features. Passive soil gas sampling had varied success detecting flowpaths for chloroform in the bedrock at a train derailment site characterized by shallow regolith and abundant surficial karst features. At the train derailment site, delineation of the contaminant flowpath through passive soil gas sampling was stronger and more detailed under winter conditions than summer.     

Characterization and identification of na-cl sources in ground water

Elevated concentrations of sodium (Na+) and chloride (Cl-) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br), and iodide (I) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I and Br; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources.     

A BOREHOLE MAGNETOMETRIC RESISTIVITY EXPERIMENT*

A borehole magnetometric resistivity (MMR) experiment is described in which an attempt is made to determine the extent and orientation of zones of fissuring within an otherwise massive sequence of carboniferous limestone. The region under investigation lies beneath a landfill site and the main parameter of interest is the direction of flow of ground water, which will be influenced by the orientation of the faults or fissures within the rock. The MMR method possesses some extremely advantageous features for application to hydro-geological problems of this kind. The method is sensitive to electrical current channelling within an otherwise relatively resistive medium, and the detection of the magnetic field within the borehole does not depend upon electrical contact of the receiver with the ground. Consequently, the method can be used in dry or plastic-cased boreholes. A direction of maximum electrical current flow is deduced from the MMR data which coincides with the predominant direction of jointing within the region. We are most grateful to the Water Research Centre, Medmenham, Berkshire, for supporting this research and particularly to Dr M. Fleet and Mr K. Beesley for their help and advice.