Temperature of an active lava channel from spectral measurements,Kilauea Volcano,Hawaii

A narrow band spectroradiometer was used to determine the characteristic temperatures of a very active channeled lava flow for the phase 50 eruption of Pu'u 'O'o on the East Rift Zone of Kilauea Volcano, Hawaii. During the twilight of 19 February 1992, 14 spectra of this activity were acquired over a 51 minute interval [18.29 to 19.20 Hawaiian Standard Time (HST)], from which the thermal distribution of energy of two 18 m² areas, one near the center and one near the margin of the flow, may be investigated. A twocomponent thermal mixing model applied to the data taken of the center of the channel gave, in the most powerful instance (1.8x10⁵ W/m²), a crust temperature of 940° C, a hot component temperature of 1120°C and a hot radiating area of 60% of the total area. A simultaneous spectrum acquired near the channeled flow margin yielded a crust temperature of 586° C and a hot area of only 1.2% of the total area radiating at 1130° C. Average radiant flux densities recorded for the center of the lava channel (1.3x10⁵ W/m² average) are much greater than previous measurements of lava lakes (4.9x10³ W/m²) or recently emplaced lava flows (maximum of 7.2x10⁴ W/m²). The energetic nature of this eruption is shown by satellite measurements made at 02.33 HST on 22 February 1992 by the Advanced Very High Resolution Radiometer in Band 2 (0.72–1.10 m). These show the utility of using existing satellites with moderate resolution (1 km x 1 km pixels) and high temporal coverage (eight overpasses each day for Hawaii) as potential thermal alarms for rapidly assessing the hazard potential of large volcanic eruptions.     

Evaluation of gases,condensates, and SO2 emissions from Augustine volcano,Alaska: the degassing of a Cl-rich volcanic system

After the March–April 1986 explosive eruption a comprehensive gas study at Augustine was undertaken in the summers of 1986 and 1987. Airborne COSPEC measurements indicate that passive SO₂ emission rates declined exponentially during this period from 380±45 metric tons/day (T/D) on 7/24/86 to 27±6 T/D on 8/24/87. These data are consistent with the hypothesis that the Augustine magma reservoir has become more degassed as volcanic activity decreased after the spring 1986 eruption. Gas samples collected in 1987 from an 870°C fumarole on the andesitic lava dome show various degrees of disequilibrium due to oxidation of reduced gas species and condensation (and loss) of H₂O in the intake tube of the sampling apparatus. Thermochemical restoration of the data permits removal of these effects to infer an equilibrium composition of the gases. Although not conclusive, this restoration is consistent with the idea that the gases were in equilibrium at 870°C with an oxygen fugacity near the Ni–NiO buffer. These restored gas compositions show that, relative to other convergent plate volcanoes, the Augustine gases are very HCl rich (5.3–6.0 mol% HCl), S rich (7.1 mol% total S), and H₂O poor (83.9–84.8 mol% H₂O). Values of D and ¹⁸O suggest that the H₂O in the dome gases is a mixture of primary magmatic water (PMW) and local seawater. Part of the Cl in the Augustine volcanic gases probably comes from this shallow seawater source. Additional Cl may come from subducted oceanic crust because data by Johnston (1978) show that Cl-rich glass inclusions in olivine crystals contain hornblende, which is evidence for a deep source (>25km) for part of the Cl. Gas samples collected in 1986 from 390°–642°C fumaroles on a ramp surrounding the inner summit crater have been oxidized so severely that restoration to an equilibrium composition is not possible. H and O isotope data suggest that these gases are variable mixtures of seawater, FMW, and meteoric steam. These samples are much more H₂O-rich (92%–97% H₂O) than the dome gases, possibly due to a larger meteoric steam component. The 1986 samples also have higher Cl/S, S/C, and F/Cl ratios, which imply that the magmatic component in these gases is from the more degassed 1976 magma. Thus, the 1987 samples from the lava dome are better indicators than the 1986 samples of degassing within the Augustine magma reservoir, even though they were collected a year later and contain a significant seawater component. Future gas studies at Augustine should emphasize fumaroles on active lava domes. Condensates collected from the same lava-dome fumarole have enrichments ot 10⁷–10² in Cl, Br, F, B, Cd, As, S, Bi, Pb, Sb, Mo, Zn, Cu, K, Li, Na, Si, and Ni. Lower-temperature (200°–650°C) fumaroles around the volcano are generally less enriched in highly volatile elements. However, these lower-termperature fumaroles have higher concentration of rock-forming elements, probably derived from the wall rock.     

Mid-latitude atmospheres,winter and summer

Summary Winter and summer Mid-Latitude (45^oN) atmospheres to 90 km, two of a family of nine atmospheres supplemental to the U.S. Standard Atmosphere (1962), provide information on atmospheric structure by seasons rather than the mean annual data shown in the Standard, which is described for reference. Principal data sources for constructing these atmospheres consisted of summaries of Northern Hemisphere radiosonde observations at stations near, 45^oN, and observations made from rockets and instruments released by rockets, from nearly a dozen Northern Hemisphere launching sites.Winter and summer temperature-height profiles begin with surface temperatures of –1° and +21 °C, respectively, and contain three isothermal layers: –58°C at 19 to 27 km in winter and –57.5°C at 13 to 17 km in summer; –7.5° and +2.5°C at 47 to 52 km; and –79.5 and –99°C at 80 to 90 km, respectively. The temperature-height curve for the U.S. Standard has a surface temperature of +15°C with isothermal regions at 11 to 20 km (–56.5°C), 47 to 52 km (–2.5°C), and 80 to 90 km (–92.5°C). In all three atmospheres, temperature gradients for various segments are linear with geopotential, height. Humidity is incorporated into the lowest 10 km of the Supplemental Atmospheres, whereas the Standard is dry. Figures and tables depict temperature, relative humidity, pressure, and density for winter and summer, and temperature, pressure, density, speed of sound, and dynamic viscosity for the U.S. Standard Atmosphere.The Supplemental Atmospheres are mutually consistent; zonal wind profiles, computed from the geostrophic wind equation and selected pressure heights, compare favorably with existing radiosonde and rocket wind observations.     

Infrared surveillance of crater lakes using satellite data

Under optimum circumstances, thermal infrared data recorded from satellites can measure water surface temperatures to accuracies of a few tenths of a degree Celsius. Such techniques are applied here to evaluate volcanic crater lake temperatures. At present, band 6 of the Landsat Thematic Mapper (TM) is the most pertinent sensor in this respect, although its nominal 120 × 120 m “footprint” only permits useful measurements of circular lakes exceeding 340 m in diameter. In addition, the radiative properties of the atmosphere between sensor and target at the instant of observation should be well-characterised in order to make confident measurements of surface temperatures with single-band infrared data.An analysis is presented of three TM band-6 images of the crater lake at Poás volcano, Costa Rica, recorded on February 6, 1986, March 13, 1987, and May 10, 1988. In the February 1986 scene, the band-6-derived water surface temperature is 36°C which is 3°C less than a field measurement made in the same month. Since the satellite measurement was integrated over some 14,400 m² of the lake surface, while the field measurement was obtained at a single point below the surface, the former may be more representative of surface heat losses. Subsequent TM data reveal an increasing discrepancy between contemporaneous field and satellite observations, probably because the lake diameter had decreased to 250 m by March 1987, and to less than 200 m by mid-1988, greatly reducing the likelihood of obtaining a pure “lake” pixel.The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) which is earmarked for orbit on the first of NASA's Earth Observing System satellite platforms later this decade has five discrete spectral bands in the thermal infrared region and will produce data composed of 90 × 90 m pixels. These specifications could enable the determination of water surface temperatures of > 250 m diameter crater lakes by algorithms that implicitly account for atmospheric effects.     

The hydrothermal system of Volcan Puracé, Colombia

This paper presents chemical and isotopic data for thermal waters, gases and S deposits from Volcan Puracé (summit elevation 4600 m) in SW Colombia. Hot gas discharges from fumaroles in and around the summit crater, and thermal waters discharge from three areas on its flanks. The waters from all areas have D values of-75±1, indicating a single recharge area at high elevation on the volcano. Aircorrected values of³He/⁴He in thermal waters range from 3.8 to 6.7 R_A, and approach those for crater fumarole gas (6.1–7.1 R_A), indicating widespread addition of magmatic volatiles. An economic S deposit (El Vinagre) is being mined in the Rio Vinagre fault zone at 3600 m elevation. Sulfur isotopic data are consistent with a magmatic origin for S species in thermal waters and gases, and for the S ore deposit. Isotopic equilibration between S species may have occurred at 220±40°C, which overlaps possible equilibration temperatures (170±40°C) determined by a variety of other geothermometers for neutral thermal waters. Apparent CH₄–CO₂ equilibration temperatures for gases from thermal springs (400±50°C) and crater fumaroles (520±60°C) reflect higher temperatures deeper in the system. Hot magmatic gas ascending through the Rio Vinagre fault zone is though to have precipitated S and generated thermal waters by interaction with descending meteoric waters.     

Geological and seismological evidence of increased explosivity during the 1986 eruptions of Pavlof volcano,Alaska

We present results of study of the best-documented eruptions of Pavlof volcano in historic time. The 1986 eruptions were mostly Strombolian in character; a strong initial phase may have been Vulcanian. The 1986 activity erupted at least 8×10⁶ m³ of feldspar-phyric basaltic andesite lava (SiO₂=53–54%), and a comparable volume of wind-borne tephra. During the course of the eruption, 5300 explosion earthquakes occurred, the largest of which was equivalent to an M _L =2.5 earthquake. Volcanic tremor was recorded for 2600 hours, and the strongest tremor was recorded out to a distance of 160 km and had an amplitude of at least 54 cm² reduced displacement. The 1986 eruptions modified the structure of the vent area for the first time in over two decades. A possible pyroclastic flow was observed on 19 June 1986, the first time such a phenomenon has been observed at the volcano. Overall, the 1986 eruptions were the strongest and longest duration eruptions in historic time, and changed a temporal pattern of activity that had persisted from 1973–1984.     

Seismic experiments on Showa-Shinzan lava dome using firework shots

Seismic experiments were conducted on Showa-Shinzan, a parasitic lava dome of volcano Usu, Hokkaido, which was formed during 1943–1945 activity. Since we found that firework shots fired on the ground can effectively produce seismic waves, we placed many seismometers on and around the dome during the summer festivals in 1984 and 1985. The internal structure had been previously studied using a prospecting technique employing dynamite blasts in 1954. The measured interval velocity across the dome in 1984 ranges 1.8–2.2 km/s drastically low compared to the results (3.0–4.0 km/s) in 1954; in addition, the velocity is 0.3–0.5 km/s higher than that in the surrounding area. The variation of the observed first arrival amplitudes can be explained by geometrical spreading in the high velocity lava dome. These observations show a marked change in the internal physical state of the dome corresponding to a drop in the measured highest temperature at fumaroles on the dome from 800°C in 1947 to 310°C in 1986.     

New terrestrial heat flow values from Hungary

Summary Temperature and conductivity measurements show, that in the Southern part of Transdanubia (the part of Hungary which lies Westwards from Danube) the heat flow is about 2–2.4·10^–6 cal/cm² sec. Eastward from the Danube, in the Hungarian Plain estimates are even higher, and vary between 2.3·10^–6 and 2.8·10^–6 cgs. The gradient of temperature is everywhere quite high, 5.0 resp. 5.8·10^–4 deg. C/cm on the average. Thus, at a depth of 1000 m, the virgin rock temperature is about 60–70 deg. C, at 2000 m about 110–130 deg. C.     

Mantle heat flow and geotherms for major tectonic units in central Europe

The results of seismic measurements along the deep seismic sounding profile VII and terrestrial heat flow measurements used for construction of heat generation models for the crust in the Paleozoic Platform region, the Sudetic Mountains (Variscan Internides) and the European Precambrian Platform show considerable differences in mantle heat flow and temperatures. At the base of the crust variations from 440–510°C in the models of Precambrian Platform to 700–820°C for the Paleozoic Platform and the Variscan Internides (Sudets) are found. These differences are associated with considerable mantle heat flow variations.The calculated models show mantle heat flow of about 8.4–12.6 mW m^–2 for the Precambrian Platform and 31 mW m^–2 to 40.2 mW m^–2 for Paleozoic orogenic areas. The heat flow contribution originating from crustal radioactivity is almost the same for the different tectonic units (from 33.5 mW m^–2 to 37.6 mW m^–2). Considerable physical differences in the lower crust and upper mantle between the Precambrian Platform and the adjacent areas, produced by lateral temperature variations, could be expected. On the basis of carbon ratio data it can be concluded that the Carboniferous paleogeothermal gradient was much lower in the Precambrian Platform area than in the Paleozoic Platform region.     

Effect of displacement rate on the real area of contact and temperatures generated during frictional sliding of Tennessee sandstone

Summary The real area of contact has been determined, and measurements of the maximum and average surface temperatures generated during frictional sliding along precut surfaces in Tennessee sand-stone have been made, through the use of thermodyes. Triaxial tests have been made at 50 MPa confining pressure and constant displacement rates of 10^–2 to 10^–6 cm/sec, and displacements up to 0.4 om. At 0.2 cm of stable sliding, the maximum temperature decreases with decreasing nominal displacement rate from between 1150° to 1175°C at 10^–2 cm/sec to between 75° to 115°C at 10^–3 cm/sec. The average temperature of the surface is between 75 and 115°C at 10^–2 cm/sec, but shows no rise from room temperature at 10^–3 cm/sec. At 0.4 cm displacement, and in the stick-slip mode, as the nominal displacement rate decreases from 10^–3 to 10^–6 cm/sec, the maximum temperature decreases from between 1120° to 1150°C to between 1040° to 1065°C. The average surface temperature is 115° to 135°C at displacement rates from 2.6×10^–3 to 10^–4 cm/sec.With a decrease in the displacement rate from 10^–2 to 10^–6 cm/sec, the real area of contact increases from about 5 to 14 percent of the apparent area; the avergge area of asperity contact increases from 2.5 to 7.5×10^–4 cm². Although fracture is the dominate mechanism during stick-up thermal softening and creep may also contribute to the unstable sliding process.     

Anatomy of 1986 Augustine volcano eruptions as recorded by multispectral image processing of digital AVHRR weather satellite data

Eighteen digital AVHRR (advanced very high resolution radiometer) data sets from NOAA-6 and NOAA-9 polar-orbiting satellites recorded between 27 March and 7 April 1986 depict the eruptive activity of Augustine volcano, located 280 km SW of Anchorage, Alaska. The synoptic view (resolution of either 1.1 or 4.4 km), frequent coverage (often twice a day), and multispectral coverage (five bands: 0.58–0.68; 0.72–1.1; 3.55–3.93; 10.5–11.3; and 11.5–12.5 m) makes the AVHRR broadly applicable to analyzing explosive eruption clouds. The small scale of the Augustine activity (column heights of 2–13 km and eruption rates of 2x10⁶–8x10⁷ metric tonnes/day) facilitated intensive multispectral study because the plumes generally covered areas within the 550x550 km area of one easily manipulated image field. Hourly ground weather data and twice-daily radiosonde measurements from stations surrounding the volcano plus numerous volcanological observations were made throughout the eruption, providing important ground truth with which to calibrate the satellite data. The total erupted volume is estimated to be at least 0.102 km³. The pattern of changing eruption rates determined by satellite observations generally correlate with more detailed estimates of explosion magnitudes. Multispectral processing techniques were used to distinguish eruption clouds from meteorological clouds. Variable weather during the Augustine eruption offered an opportunity to test various trial algorithms. A ratio between thermal IR channels four and five, served to delineate the ashbearing eruption plumes from ordinary clouds. Future work is needed to determine whether the successful multispectral discrimination is caused by wavelength-dependent variable emission of silicate ash or reflects a spectral role of sulfuric acid aerosol in the plume.     

Low enthalpy geothermal energy resources in Denmark

The deep oil exploration drillings in Denmark have shown that especially the Danish Embayment contains low enthalpy geothermal resources associated with warm aquifers. The most promising reservoirs have been found in highly permeable Upper Triassic sand and sandstone beds, which cover at least 5000 km² at depths of 2000–3000 m and at temperatures of 60–100°C. The porosity of the main reservoir is of 15–25%, and the permeability is presumed to be approximately 1 darcy (10^–12 m²) or higher. A layer thickness of 30–60 m has been observed on a number of localities. Also the Middle Jurassic and the Lower Triassic contain reservoirs of interest. A major geothermal exploration work is planned with seismic investigations, drillings to depths of 2000–4000 m and probably establishment of pilot district heating plants.     

Die Eiskeimbildung bei Temperaturen unter −30° C

Zusammenfassung An künstlich erzeugten unterkühlten Nebeln wurde die Eiskeimbildung his –85°C untersucht. Bei tiefen Temperaturen treten so hohe Eisteilchendichten auf, daß sie erst an fotografischen Aufnahmen der Eiswolken bei geeigneter Vergrösserung bestimmt werden konnten. Die von anderer Seite bei –40°C behauptete und mit homogener Keimbildung gedeutete Vervielfachung der Eisteilchenzahl konnte nicht festgestellt werden. Meistens steigt die Teilchendichte spätestens bei –30°C stark an, bleibt dann aber zwischen –40°C und –65°C praktisch konstant bei im Mittel 174 Eisteilchen pro cm³. Dieser Uebergang, der an der vollständigen Vereisung der Tröpfchenwolke direkt zu erkennen ist, findet je nach Wetterlage zwischen –40 und –50°C statt und muß somit noch durch Gefrierkerne hervorgerufen sein.Erst bei Annäherung an –70°C bilden sich in Uebereinstimmung mit früheren Ergebnissen des Verf. ausserordentlich dichte und beständige Nebel aus feinsten Eisteilchen mit. Anzeichen von homogener Bildung.

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Summary The formation of ice germs down to –85°C was investigated with artificial supercooled nebula. At low temperatures the densities of ice particles are so high that they could only be determined by photographs of the ice clouds with suitable enlargements. The multiplication of the number of ice particles which, according to assertions from another side, should take place at –40°C and which was interpreted by homogeneous formation of germs, could not be ascertained. In most cases the density of particles increases considerably at –30° at the latest, and then remains practically constant between –40 and –65°C with an average of 174 ice particles per cm³. This transition which can directly be observed at the complete icing of the cloud of droplets, takes place — according to the weather conditions —between –40 and –50°C and must, therefore, also be caused by freezing nuclei.Extremely dense and constant nebula consisting of the finest ice particles with signs of homogeneous formation are only formed with an approximation to –70°C, which is in good agreement with earlier results of the author.

     

A reconnaissance geochemical study of La Primavera geothermal area, Jalisco, Mexico

The Sierra La Primavera, a late Pleistocene rhyolitic caldera complex in Jalisco, México, contains fumaroles and large-discharge 65°C hot springs that are associated with faults related to caldera collapse and to later magma insurgence. The nearly-neutral, sodium bicarbonate, hot springs occur at low elevations at the margins of the complex, whereas the water-rich fumaroles are high and central.The Comisión Federal de Electricidad de México (CFE) has recently drilled two deep holes at the center of the Sierra (PR-1 and Pr-2) and one deep hole at the western margin. Temperatures as high as 285°C were encountered at 1160 m in PR-1, which produced fluids with 820 to 865 mg/kg chloride after flashing to one atmosphere. Nearby, PR-2 encountered temperatures to 307°C at 2000 m and yielded fluids with chloride contents fluctuating between 1100 and 1560 mg/kg after flashing. Neither of the high-temperature wells produced steam in commercial quantities. The well at the western margin of the Sierra produced fluids similar to those from the hot springs. The temperature reached a maximum of 100°C near the surface and decreased to 80°C at 2000 m.Various geothermometers (quartz conductive, Na/K, Na-K-Ca, δ¹⁸O(SO₄-H₂O) and D/H (steam-water) all yield temperatures of 170 ± 20°C when applied to the hot spring waters, suggesting that these spring waters flow from a large shallow reservoir at this temperature. Because the hot springs are much less saline than the fluids recovered in PR-1 and PR-2, the mixed fluid in the shallow reservoir can contain no more than 10–20% deep fluid. This requires that most of the heat is transferred by steam. There is probably a thin vapor-dominated zone in the central part of the Sierra, through which steam and gases are transferred to the overlying shallow reservoir. Fluids from this reservoir cool from 170°C to 65°C by conduction during the 5–7 km of lateral flow to the hot springs.     

Anomalies of Thermomagnetic Characteristics of Lower Cretaceous Red-Beds in the Tadjik Depression (Southern Tien-Shan)

The paper features data on thermomagnetic characteristics of the red-bed sediments of the Lower Cretaceous of the Tadjik depression which turned out to be somewhat anomalous. The thermomagnetic characteristics of monolithic samples are stable under long-term heating (2–3 hours) at high temperature (600°–700°C). At the same time, the thermomagnetic characteristics of the powders, obtained from heated monolithic samples, display instability under even lesser temperatures. During heating at 600°–700°C, part of the hematite, dispersed in the rock, turns into stable maghemite. Disintegration of the monoliths changes the properties of the secondary maghemite - it becomes unstable to heating and at temperatures of 550°-600°C irreversibly changes into hematite.     

A fracture mechanics study of subcritical tensile cracking of quartz in wet environments

Load relaxation and cross-head displacement rate-change experiments have been used to establish log₁₀ stress intensity factor (K) versus log₁₀ crack velocity (v) diagrams for double torsion specimens, of synthetic quartz cracked on thea plane in liquid water and moist air.For crack propagation normal toz and normal tor at 20°C,K _Ic (the critical stress intensity factor) was found to be 0.852±0.045 MN·m^–3/2 and 1.002±0.048 MN·m^–3/2, respectively.Subcritical crack growth at velocities from 10^–3 m·s^–1 to 10^–9 m·s^–1 at temperatures from 20°C to 80°C is believed to be facilitated by chemical reaction between the siloxane bonds of the quartz and the water or water vapour of the environment (stress corrosion). The slopes, of isotherms in theK-v diagrams are dependent upon crystallographic orientation. The isotherms have a slope of 12±0.6 for cracking normal tor and 19.9±1.7 for cracking normal toz. The activation enthalpy for crack propagation in the former orientation in liquid water at temperatures from 20°C to 80°C is 52.5±3.8 kJ·mole^–1.A discussion is presented of the characteristics of theK-v diagrams for quartz.     

Crustal thermal models for South Siberia

Summary The results of geothermal research carried out in South Siberia (West-Siberian and Siberian Platforms, Altai-Sayan folded area and the Baikalian arched uplift zone) were employed to calculate the Earth's crustal temperatures. It is shown that temperature is a function of the heat flow value. The maps of the surface heat flow and the temperatures at the Moho discontinuity are presented and characteristic temperature-depth profiles were compiled for specific tectonic areas. The West-Siberian and Siberian Platforms, as well as the Altai-Sayan folded region are characterized by rather low heat flow, 42–50mW m ^–2 (1.0–1.2 µcal/cm ² s), and low temperatures at the Moho boundary.400–500 °C. The thermal conditions in the area of Lake Baikal are extreme, the heat flow reaches here100–142 mW m ^–2 (2.4–3.4 µcal/cm ² s), and the temperature at the crust's bottom may exceed1000 °C. The Moho-surface according to our calculations is nonisothermal.     

Fumarole distribution,morphology, and encrustation mineralogy associated with the 1986 eruptive deposits of mount St. Augustine,Alaska

Numerous rootless fumaroles were developed on pyroclastic flows and a lava flow generated during the March 1986 eruptive cycle of Mount St. Augustine. Gases issued from fumarole vents with four different shapes: fissure, phreatic explosion crater, single/multiple ovoid opening, and diffuse, multiple opening. Fumarole distribution and morphology were controlled by preeruption drainage and topography, as well as by the thickness, compaction, and settling of the flow deposits. Fumarole temperatures measured in June and July 1986 ranged from 75°–394°C. Varying amounts of colorful and often roughly zoned encrustations are associated with all fumarole vent shapes. Only six types of crystalline phases were detected by X-ray diffraction, with gypsum the most abundant mineral, followed by anhydrite, sulfur, tridymite, halite, and soda alum. Scanning electron microscopy and energy dispersive X-ray analysis revealed a number of amorphous phases, mainly halogen-rich, as well as other minor crystalline phases. The mineral assemblages in the encrustations suggest formation conditions for these deposits within a general range of 25°–250°C in an oxidizing environment. Many of the amorphous phases are metastable and upon cooling of the fumarole lose nonstructural water and crystallize to more stable forms. The high halogen contents of the fumarole condensates and the mineralogy, chemistry, and morphology of the encrustations support leaching of the andesitic ash and lava flow by condensed acid vapors as the primary source for the chemical components contained in the encrustations. Comparison of traceelement (Sr, Ba, V, Co, Ni, and Cr) contents in unaltered and altered ash suggests that trace-element distribution follows a pattern of isomorphic substitution in the encrustation phases.     

Assessment of a shallow magmatic system: the 1888–90 eruption,Vulcano Island,Italy

The magmatic system feeding the last eruption of the volcano La Fossa, Vulcano Island, Italy was studied. The petrogenetic mechanisms controlling the differentiation of erupted rocks were investigated through petrography, mineral chemistry, major, trace and rare earth element and Sr, Nd and Pb isotopic geochemistry. In addition, melt inclusion and fluid inclusion data were collected on both juvenile material and xenolithic partially melted metamorphic clasts to quantify the P-T conditions of the magma chamber feeding the eruption. A regular and continuous chemical zoning has been highlighted: rhyolites are the first erupted products, followed by trachytes and latites, whereas rhyolitic compositions were also found in the upper part of the sequence. The chemical and isotopic composition of the rhyolites indicates that they originated by fractional crystallization from latitic magmas plus the assimilation of crustal material; the trachytes represent hybrid magmas resulting from the mixing of latites and rhyolites, contaminated in the shallow magmatic system. The erupted products, primarily compositionally zoned from latites to rhyolites, are heterogeneous due to syn-eruptive mingling. The occurrence of magmacrust interaction processes, evidenced by isotopic variations (⁸⁷Sr/⁸⁶Sr=0.70474±3 to 0.70511±3; ¹⁴³Nd/¹⁴⁴Nd=0.512550±6 to 0.512614±8; ²⁰⁶Pb/²⁰⁴Pb=19.318–19.489; ²⁰⁷Pb/²⁰⁴Pb=15.642–15.782; ²⁰⁸Pb/²⁰⁴Pb=39.175–39.613), is confirmed by the presence of partially melted metamorphic xenoliths, with ⁸⁷Sr/⁸⁶Sr=0.71633±6 to 0.72505±2 and ¹⁴³Nd/¹⁴⁴Nd=0.51229±7, in rhyolites and trachytes. AFC calculations indicate a few percentage contribution of crustal material to the differentiating magmas. Thermometric measurements on melt inclusions indicate that the crystallization temperatures of the latites and trachytes were in the range of 1050–1100° C, whereas the temperature of the rhyolites appears to have been around 1000°C at the time of the eruption. Compositional data on melt inclusions reveal that the magmas involved in the eruption contained about 1–1.5 wt.% dissolved H₂O in pre-eruptive conditions. Secondary fluid inclusions found in metamorphic xenoliths give low equilibration pressure data (30–60 MPa), giving the location of the higher portions of the chamber at around 1500–2000 m of depth.