Proterozoic anorogenic magmatic rocks and their constraints on mineralizations in the Bayan Obo deposit region,Inner Mongolia

The Proterozoic anorogenic magmatic rocks are well developed in the Bayan Obo deposit region. They are composed of trachyte, magnesioarfvedesonite-feldspatite, potash-rhyolite, dacite, rhyolite, quartz porphyry and trachy basalt. A lot of high-K diabase veins (dykes) are also found. These anorogenic magmatic rocks are derived from the mantle. They have lower?^Nd(t) (4.52-5.88) with T ^Nd _DM = 1.54-1.92 Ga. Their Nd isotopic compositions and T ^Nd _DM are consistent with those of ores, implying that the ore-forming materials were derived from these anorogenic magmatic rocks. The zircon U-Pb ages of the rocks are 1.8 Ga. Research results indicate that the Bayan Obo Group was replaced by the hydrothermal solution related to the anorogenic magmatic rocks, resulting in the formation of the deposit.     

Fractionation trends of basalt magmas in lava flows

Chemical compositions of schlieren in basalt flows are compared with those of the host rocks for tracing the fractionation trends of basalt magmas under extrusive conditions. In the Warner high-alumina basalt of California and in the tholeiite of Hawaii and Japan, total iron increases markedly from the host rock to the schlieren whileSiO ₂ is nearly constant. In the high-alumina basalt of Huzi Volcano and in the tholeiite near Catania, Italy, total iron is nearly constant during fractionation whileSiO ₂ increases. In basalts of the hypersthenic rock series or calc-alkali rock series from California, total iron is also nearly constant whileSiO ₂ increases. The difference in fractionation trend in these flows is attributable to the difference of the state of oxidation of iron in the original magmas. Oxygen partial pressure of the magmas would not be maintained constant during the fractionation of extrusive bodies.     

The noble gas isotope geochemical composition of chert at the bottom of Cambrian in Tarim Basin,China

In the Tarim Basin, black shale series at the bottom of Cambrian is one of the important marine facies hydrocarbon source rocks. This research focuses on the analysis of the isotope of noble gas of 11 cherts. The R/R _a ratio of chert in the Keping area is 0.032–0.319, and ⁴⁰Ar/³⁶Ar is 338–430. In Quruqtagh the R/R _a ratio is 0.44–10.21, and ⁴⁰Ar/³⁶Ar is 360–765. The R/R _a ratio of chert increases with ⁴⁰Ar/³⁶Ar from the west to the east accordingly. They have evolved from the crust source area to the mantle source area in a direct proportion. Surplus argon ⁴⁰Ar_E in chert is in direct proportion to the R/R _a ratio, indicating that it has the same origin of excess argon as in fluid and mantle source helium. Comparison of the R/R _a ratios between the west and the east shows that the chert in the eastern part formed from the activity system of the bottom hydrothermal venting driven by the mantle source, where the material and energy of crust and mantle had a strong interaction in exchange; whereas in the western part, chert deposited from the floating of hydrothermal plume undersea bottom, which is far away from the centre of activities of the hydrothermal fluid of ocean bottom. In addition, from noble gas isotope composition of chert, it is suggested that the ocean anoxia incident happened at the black shale of the Cambrian bottom probably because of the large-scaled ocean volcanoes and the following hydrothermal activities.     

Crustal Structure Along Sunda-Banda Arc Transition Zone from Teleseismic Receiver Functions

We analyzed receiver function of teleseismic events recorded at twelve Indonesian-GEOFON (IA-GE) broadband stations using nonlinear Neighbourhood Algorithm (NA) inversion and H-k stacking methods to estimate crustal thickness, V _p /V _s ratios and S-wave velocity structure along Sunda-Banda arc transition zone. We observed crustal thickness of 34–37 km in Timor Island, which is consistent with the previous works. The thick crust (> 30 km) is also found beneath Sumba and Flores Islands, which might be related to the arc-continent collision causing the thickened crust. In Timor and Sumba Islands, we observed high V _p /V _s ratio (> 1.84) with low velocity zone that might be associated with the presence of mafic and ultramafic materials and fluid filled fracture zone. The high V _p /V _s ratio observed at Sumbawa and Flores volcanic Islands might be an indication of partial melt related to the upwelling of hot asthenosphere material through the subducted slab.     

Homologous temperature of olivine: Implications for creep of the upper mantle and fabric transitions in olivine

The homologues temperature of a crystalline material is defined as T/T_m, where T is temperature and T_m is the melting(solidus) temperature in Kelvin. It has been widely used to compare the creep strength of crystalline materials. The melting temperature of olivine system,(Mg,Fe)_2SiO_4, decreases with increasing iron content and water content, and increases with confining pressure. At high pressure, phase transition will lead to a sharp change in the melting curve of olivine. After calibrating previous melting experiments on fayalite(Fe_2SiO_4), the triple point of fayalite-Fe_2SiO_4 spinel-liquid is determined to be at 6.4 GPa and 1793 K. Using the generalized means, the solidus and liquidus of dry olivine are described as a function of iron content and pressure up to 6.4 GPa. The change of T/T_m of olivine with depth allows us to compare the strength of the upper mantle with different thermal states and olivine composition. The transition from semi-brittle to ductile deformation in the upper mantle occurs at a depth where T/T_m of olivine equals 0.5. The lithospheric mantle beneath cratons shows much smaller T/T_m of olivine than orogens and extensional basins until the lithosphere-asthenosphere boundary where T/T_m 0.66, suggesting a stronger lithosphere beneath cratons. In addition, T/T_m is used to analyze deformation experiments on olivine. The results indicate that the effect of water on fabric transitions in olivine is closely related with pressure. The hydrogen-weakening effect and its relationship with T/T_m of olivine need further investigation. Below 6.4 GPa(200 km), T/T_m of olivine controls the transition of dislocation glide from [100] slip to [001] slip. Under the strain rate of 10~(-12)–10~(-15) s~(-1) and low stress in the upper mantle, the [100](010) slip system(A-type fabric) becomes dominant when T/T_m 0.55–0.60. When T/T_m 0.55–0.60, [001] slip is easier and low T/T_m favors the operation of [001](100) slip system(C-type fabric). This is consistent with the widely observed A-type olivine fabric in naturally deformed peridotites, and the C-type olivine fabric in peridotites that experienced deep subduction in ultrahigh-pressure metamorphic terranes. However, the B-type fabric will develop under high stress and relatively low T/T_m. Therefore, the homologues temperature of olivine established a bridge to extrapolate deformation experiments to rheology of the upper mantle. Seismic anisotropy of the upper mantle beneath cratons should be simulated using a four-layer model with the relic A-type fabric in the upper lithospheric mantle, the B-type fabric in the middle layer, the newly formed A- or B-type fabric near the lithosphere-asthenosphere boundary, and the asthenosphere dominated by diffusion creep below the Lehmann discontinuity. Knowledge about transition mechanisms of olivine fabrics is critical for tracing the water distribution and mantle flow from seismic anisotropy.     

Solubilities of metallic sulfides and quartz in hydrothermal sulfide solutions

Thermal waters contain small amounts of dissolved sulfides which in places precipitate at or near the earth’s surface. Knowledge of the physical chemistry of hydrothermal solutions is needed at elevated temperatures and pressures. Therefore, solubilities of the epithermal minerals cinnabar, stibnite, quartz, and orpiment in aqueousNa ₂ S solutions was determined from 25–250° C, 1–2000 bars, and at severalNa ₂ S concentrations. All the minerals are appreciably soluble inNa ₂ S solutions. Pressure increase decreases solubilities of metallic sulfides but slightly increases quartz solubility. Temperature increase causes increased solubility at temperatures above 150° C, but at lower temperatures, cinnabar, orpiment and quartz show solubility decreases with increasing temperatures. Quartz and cinnabar are mutually soluble, but in the presence of stibnite only a small amount of cinnabar dissolves. The second ionization constant ofH ₂ S as calculated from the solubility data ranges from 10^?16,21 at 0°C to 10^?12,59 at 250°C. TheK ₂ ofH ₂ S is lower according to this study than any reported before, and the variation with temperature is several orders of magnitude greater than had been predicted.     

Experimental study on the shear behavior of the interface between cushion materials and the concrete raft

Cushion is a layer of granular materials between the raft and the ground. The shear behavior of the interface between the cushion and the raft may influence the seismic performance of the superstructure. In order to quantify such influences, horizontal shear tests on the interfaces between different cushion materials and concrete raft under monotonic and cyclic loading were carried out. The vertical pressure P_v, material type and cushion thickness h_c were taken as variables. Conclusions include: 1) under monotonic loading, P_v is the most significant factor; the shear resistance P_(hmax) increases as P_v increases, but the normalized factor of resistance μ_n has an opposite tendency; 2) for the materials used in this study, μ_n varies from 0.40 to 0.70, the interface friction angle δ_s varies from 20° to 35°, while u_(max) varies from 3 mm to 15 mm; 3) under cyclic loading, the interface behavior can be abstracted as a "three-segment" back-bone curve, the main parameters include μ_n, the displacement u_1 and stiffness K_1 of the elastic stage, the displacement u_2 and stiffness K_2 of the plastic stage; 4) by observation and statistical analysis, the significance of different factors, together with values of K_1, K_2 and μ_n have been obtained.     

Sampling uncertainties and source <Emphasis Type="Italic">b</Emphasis> likelihood for the Gutenberg-Richter <Emphasis Type="Italic">b</Emphasis> value from the Aki-Utsu method

The Aki-Utsu method of Gutenberg-Richter (G-R) b value estimation is often misapplied so that estimations not using the G-R histogram are often meaningless because they are not based on adequate samples. We propose a method to estimate the likelihood Pr(b?b _m , N, M ₁, M ₂) that an observed b _m estimate, based on a sample of N magnitudes within an [M ₁????≤?ΔM/2,?M ₂?+?ΔM/2) range, where ΔM?=?0.1 is the usual rounding applied to magnitudes, is due to a “true” source b value, b, and use these likelihoods to estimate source b ranges corresponding to various confidence levels. As an example of application of the method, we estimate the b values before and after the occurrence of a 7.4-magnitude earthquake in the Mexican subduction zone, and find a difference of 0.82 between them with 100% confidence that the b values are different.     

Behavior of Parameters of Enhancements in the Nighttime Electron Concentration in the Ionospheric <Emphasis Type="Italic">F</Emphasis>2 Layer

We have analyzed the behavior of the F2 layer parameters during nighttime periods of enhanced electron concentration by the results of vertical sounding of the ionosphere carried out with five-minute periodicity in Almaty (76°55′ E, 43°15′ N) in 2001–2012. The results are obtained within the frameworks of the unified concept of different types of ionospheric plasma disturbances manifested as variations in the height and half-thickness of the layer accompanied by an increase and decrease of N _m F2 at the moments of maximum compression and expansion of the layer. A good correlation is found between height h _Am , which corresponds to the maximum increase, and layer peak height h _m F, while h _Am is always less than h _m F. The difference between h _Am and h _m F linearly increases with increasing h _m F. Whereas the difference is ~38 km for h _m F = 280 km, it is ~54 km for h _m F = 380 km. Additionally, the correlation is good between the increase in the electron concentration in the layer maximum ΔN _m and the maximum enhancement at the fixed height ΔN; the electron concentration enhancement in the layer maximum is about two to three times lower than its maximum enhancement at the fixed height.     

Precursor times of abnormal <Emphasis Type="Italic">b</Emphasis>-values prior to mainshocks

Seismic observations exhibit the presence of abnormal b-values prior to numerous earthquakes. The time interval from the appearance of abnormal b-values to the occurrence of mainshock is called the precursor time. There are two kinds of precursor times in use: the first one denoted by T is the time interval from the moment when the b-value starts to increase from the normal one to the abnormal one to the occurrence time of the forthcoming mainshock, and the second one denoted by T _p is the time interval from the moment when the abnormal b-value reaches the peak one to the occurrence time of the forthcoming mainshock. Let T* be the waiting time from the moment when the abnormal b-value returned to the normal one to the occurrence time of the forthcoming mainshock. The precursor time, T (usually in days), has been found to be related to the magnitude, M, of the mainshock expected in a linear form as log(T)?=?q?+?rM where q and r are the coefficient and slope, respectively. In this study, the values of T, T _p , and T* of 45 earthquakes with 3?≤?M?≤?9 occurred in various tectonic regions are compiled from or measured from the temporal variations in b-values given in numerous source materials. The relationships of T and T _p , respectively, versus M are inferred from compiled data. The difference between the values of T and T _p decreases with increasing M. In addition, the plots of T*/T versus M, T* versus T, and T* versus T-T* will be made and related equations between two quantities will be inferred from given data.     

A way of estimating the characteristic slip displacement

During the ruptures of an earthquake,the strain energy.△E,.will be transferred into,at least,three parts,i.e..the seismic radiation energy(E_s),fracture energy(E_g),and frictional energy(E_f),that is,△E = E_s + E_g + E_f.Friction,which is represented by a velocity- and state-dependent friction law by some researchers,controls the three parts.One of the main parameters of the law is the characteristic slip displacement.D_c.It is significant and necessary to evaluate the reliable value of D_c from observed and inverted seismic data.Since D_c controls the radiation efficiency.η_R = E_s/(E_s+ E_g),the value of η_r is a good constraint of estimating D_c.Integrating observed data and inverted results of source parameters from recorded seismograms.the values of E_s and E_g of an earthquake can be measured,thus leading to the value of η_R.The constraint used to estimate the reliable value of D_c will be described in this work.An example of estimates of D_c.based on the observed and inverted values of source parameters of the September 20,1999 M_S 7.6 Chi-Chi(Ji-Ji).Taiwan region,earthquake will be presented.     

Activation of seismicity in Central and South Asia after the Makran earthquakes: Possible acceleration of preparation of large seismic events in the Tien Shan region

Two zones of seismicity (ten events with M _w = 7.0–7.7) stretching from Makran and the Eastern Himalaya to the Central and EasternTien Shan, respectively, formed over 11 years after the great Makran earthquake of 1945 (M _w = 8.1). Two large earthquakes (M _w = 7.7) hit theMakran area in 2013. In addition, two zones of seismicity (M ≥ 5.0) occurred 1–2 years after theMakran earthquake in September 24, 2013, stretching in the north-northeastern and north-northwestern directions. Two large Nepal earthquakes struck the southern extremity of the “eastern” zone (April 25, 2015, M _w = 7.8 and May 12, 2015, M _w = 7.3), and the Pamir earthquake (December 7, 2015, M _w = 7.2) occurred near Sarez Lake eastw of the “western” zone. The available data indicate an increase in subhorizontal stresses in the region under study, which should accelerate the possible preparation of a series of large earthquakes, primarily in the area of the Central Tien Shan, between 70° and 79° E, where no large earthquakes (M _w ≥ 7.0) have occurred since 1992.     

Properties of solar activity and ionosphere for solar cycle 25

Based on the known forecast of solar cycle 25 amplitude (Rz _max ≈ 50), the first assessments of the shape and amplitude of this cycle in the index of solar activity F10.7 (the magnitude of solar radio flux at the 10.7 cm wavelength) are given. It has been found that (F10.7)_max ≈ 115, which means that it is the lowest solar cycle ever encountered in the history of regular ionospheric measurements. For this reason, many ionospheric parameters for cycle 25, including the F2-layer peak height and critical frequency (hmF2 and foF2), will be extremely low. For example, at middle latitudes, typical foF2 values will not exceed 8–10 MHz, which makes ionospheric heating ineffective in the area of upper hybrid resonance at frequencies higher than 10 MHz. The density of the atmosphere will also be extremely low, which significantly extends the lifetime of low-orbit satellites. The probability of F-spread will be increased, especially during night hours.     

Mechanism of formation of <Emphasis Type="Italic">Q</Emphasis>-disturbances in the <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript> region of the equatorial ionosphere

Using model simulations, the morphological picture (revealed earlier) of the disturbances in the F ₂ region of the equatorial ionosphere under quiet geomagnetic conditions (Q-disturbances) is interpreted. It is shown that the observed variations in the velocity of the vertical E × B plasma drift, related to the zonal E _y component of the electric field, are responsible for the formation of Q-disturbances. The plasma recombination at altitudes of the lower part of the F ₂ region and the dependence of the rate of this process on heliogeophysical conditions compose the mechanism of Q-disturbance formation at night. The daytime positive Q-disturbances are caused exclusively by a decrease in the upward E × B drift, and this type of disturbances could be related to the known phenomenon of counter electrojet. Possible causes of formation of the daytime negative Q-disturbances are discussed.     

Effects of temporally correlated infiltration on water flow in an unsaturated–saturated system

Effects of temporally correlated infiltration on water flow in an unsaturated–saturated system were investigated. Both white noise and exponentially correlated infiltration processes were considered. The moment equations of the pressure head (ψ) were solved numerically to obtain the variance and autocorrelation functions of ψ at 14 observation points. Monte Carlo simulations were conducted to verify the numerical results and to estimate the power spectrum of ψ (S _ψψ ). It was found that as the water flows through the system, the variance of the ψ (\( \sigma_{\psi }^{2} \)) were damped by the system: the deeper in the system, the smaller the \( \sigma_{\psi }^{2} \), and the larger the correlation timescale of the infiltration process (λ _I ), the larger the \( \sigma_{\psi }^{2} \). The unsaturated–saturated system gradually filters out the short-term fluctuations of ψ and the damping effect is most significant in the upper part of the system. The fluctuations of ψ is non-stationary at early time and becomes stationary as time progresses: the larger the value of λ _I , the longer the non-stationary period. The correlation timescale of the ψ (λ _ψ ) increases with depth and approaches a constant value at depth: the larger the value of λ _I , the larger the value of λ _ψ . The results of the estimated S _ψψ is consistent with those of the variance and autocorrelation function.     

Limits of transversely isotropic elastic parameters for the existence of classical Rayleigh waves

Solutions of P-SV equations of motion in a homogeneous transversely isotropic elastic layer contain a factor exp(±ν _j z), where z is the vertical coordinate and j?=?1, 2. For computing Rayleigh wave dispersion in a multi-layered half space, ν _j is computed at each layer. For a given phase velocity (c), ν _j becomes complex depending on the transversely isotropic parameters. When ν _j is complex, classical Rayleigh waves do not exist and generalised Rayleigh waves propagate along a path inclined to the interface. We use transversely isotropic parameters as α _H , β _V , ξ, ? and η and find their limits beyond which ν _j becomes complex. It is seen that ν _j depends on ? and η, but does not depend on ξ. The complex ν _j occurs when ? is small and η is large. For a given c/β _V , the region of complex ν _j in a ? -η plane increases with the increase of α _H /β _V . Further, for a given α _H /β _V , the complex region of ν _j increases significantly with the decrease of c/β _V . This study is useful to compute dispersion parameters of Rayleigh waves in a layered medium.     

Effect of zonal E × B plasma drift on electron density in the low-latitude ionospheric <Emphasis Type="Italic">F</Emphasis> region at a solar activity maximum near vernal equinox

The variations in the density of the ionospheric F2 layer maximum (NmF2) under the action of the zonal plasma drift perpendicularly to the magnetic (B) and electric (E) fields in the direction geomagnetic west-geomagnetic east have been studied using the three-dimensional nonstationary theoretical model of electron and ion densities (N _e and N _i ) and temperatures (T _e and T _i ) in the low-latitude and midlatitude ionospheric F region and plasmasphere. The method of numerical calculations of N _e , N _i , T _e , and T _i , including the advantages of the Lagrangian and Eulerian methods, is used in the model. A dipole approximation of the geomagnetic field (B), taking into account the non-coincidence of the geographic and geomagnetic poles and differences between the positions of the Earth’s and geomagnetic dipole centers, is accepted in the calculations. The calculated NmF2 and altitudes of the F2 layer maximum (hmF2) have been compared with these quantities measured at 16 low-latitude ionospheric sounding stations during the geomagnetically quiet period October 11–12, 1958. This comparison made it possible to correct the input model parameters: the NRLMSISE-00 model [O], the meridional component of the neutral wind velocity according to the HWW90 model, and the meridional component of the equatorial plasma drift due to the electric field specified by the empirical model. It has been indicated that the effect of the zonal E × B plasma drift on NmF2 can be neglected under daytime conditions and changes in NmF2 and hmF2 under the action of this drift are insignificant under nighttime conditions north of 25° and south of ?26° geomagnetic latitude. The effect of the zonal E × B plasma drift on NmF2 and hmF2 is most substantial in the nightside ionosphere approximately from ?20° to 20° geomagnetic latitude, and the neglect of this drift results in an up to 2.4-fold underestimation of NmF2. The found dependence of the effect of the zonal E × B plasma drift on NmF2 and hmF2 on geomagnetic latitude is related to the longitudinal asymmetry of B, asymmetry of the neutral wind about the geomagnetic equator, and changes in the meridional E × B plasma drift at a change in geomagnetic longitude.     

Prestack migration velocity analysis based on simplified two-parameter moveout equation

Stacking velocity V _C2, vertical velocity ratio γ ₀, effective velocity ratio γ _eff, and anisotropic parameter χ _eff are correlated in the PS-converted-wave (PS-wave) anisotropic prestack Kirchhoff time migration (PKTM) velocity model and are thus difficult to independently determine. We extended the simplified two-parameter (stacking velocity V _C2 and anisotropic parameter k _eff) moveout equation from stacking velocity analysis to PKTM velocity model updating and formed a new four-parameter (stacking velocity V _C2, vertical velocity ratio γ ₀, effective velocity ratio γ _eff, and anisotropic parameter k _eff) PS-wave anisotropic PKTM velocity model updating and process flow based on the simplified two-parameter moveout equation. In the proposed method, first, the PS-wave two-parameter stacking velocity is analyzed to obtain the anisotropic PKTM initial velocity and anisotropic parameters; then, the velocity and anisotropic parameters are corrected by analyzing the residual moveout on common imaging point gathers after prestack time migration. The vertical velocity ratio γ ₀ of the prestack time migration velocity model is obtained with an appropriate method utilizing the P- and PS-wave stacked sections after level calibration. The initial effective velocity ratio γ _eff is calculated using the Thomsen (1999) equation in combination with the P-wave velocity analysis; ultimately, the final velocity model of the effective velocity ratio γ _eff is obtained by percentage scanning migration. This method simplifies the PS-wave parameter estimation in high-quality imaging, reduces the uncertainty of multiparameter estimations, and obtains good imaging results in practice.     

Differential physiological responses of the coastal cyanobacterium <Emphasis Type="Italic">Synechococcus</Emphasis> sp. PCC7002 to elevated <Emphasis Type="Italic">p</Emphasis>CO<Subscript>2</Subscript> at lag,exponential, and stationary growth phases

We studied the effects of expected end-of-the-century pCO₂ (1000 ppm) on the photosynthetic performance of a coastal marine cyanobacterium Synechococcus sp. PCC7002 during the lag, exponential, and stationary growth phases. Elevated pCO₂ significantly stimulated growth, and enhanced the maximum cell density during the stationary phase. Under ambient pCO₂ conditions, the lag phase lasted for 6 days, while elevated pCO₂ shortened the lag phase to two days and extended the exponential phase by four days. The elevated pCO₂ increased photosynthesis levels during the lag and exponential phases, but reduced them during the stationary phase. Moreover, the elevated pCO₂ reduced the saturated growth light (Ik) and increased the light utilization efficiency (α) during the exponential and stationary phases, and elevated the phycobilisome:chlorophyll a (Chl a) ratio. Furthermore, the elevated pCO₂ reduced the particulate organic carbon (POC):Chl a and particulate organic nitrogen (PON):Chl a ratios during the lag and stationary phases, but enhanced them during the exponential phase. Overall, Synechococcus showed differential physiological responses to elevated pCO₂ during different growth phases, thus providing insight into previous studies that focused on only the exponential phase, which may have biased the results relative to the effects of elevated pCO₂ in ecology or aquaculture.     

Correlation between foam-bubble size and drag coefficient in hurricane conditions

A recently proposed model of foam impact on the air–sea drag coefficient C _d has been employed for the estimation of the effective foam-bubble radius R _b variation with wind speed U₁₀ in hurricane conditions. The model relates C _d (U₁₀) with the effective roughness length Z _eff (U₁₀) represented as a sum of aerodynamic roughness lengths of the foam-free and foam-covered sea surfaces Z _w (U₁₀) and Z _f (U₁₀) weighted with the foam coverage coefficient α _f (U₁₀). This relation is treated for known phenomenological distributions C _d (U₁₀), Z _w (U₁₀), and α _f (U₁₀) at strong wind speeds as an inverse problem for the effective roughness parameter of foam-covered sea surface Z _f (U₁₀). The present study is aimed at the estimation of the effective roughness of the sea surface assuming that the measurement data for the effective drag coefficient are known. The effective foam-bubble size is found as a function of the wind speed.