Gemstone Mineralization in the Palghat-Cauvery Shear Zone System (Karur-Kangayam Belt), Southern India

We summarize here the occurrence of a number of semiprecious stones within a major gemstone belt in the Palghat-Cauvery shear zone system close to the northern margin of the Madurai Granulite Block, southern India. The gem mineralization in this belt includes different varieties of corundum (star ruby, sapphire), cordierite (iolite), feldspar (moonstones and sunstone of various hues), beryl (emerald, aquamarine), chrysoberyl (alexandrite), kornerupine, topaz, spinel, crystal quartz and amethyst, among others. Gem mineralisation has not been directly dated, but is associated with pegmatites that crosscut rocks metamorphosed in late Neoproterozoic/Early Cambrian times. Similar aged gem mineralization occurs south of the Achankovil Shear Zone in southern India, as well as in Sri Lanka and Madagascar and strengthen the view of a broad late Neoproterozoic-early Cambrian gemstone province in central Gondwana. The ruby mineralization within this belt can be correlated with similar occurrences in eastern Madagascar, supporting a correlation between the Malagasy Betsimisaraka suture zone and the Palghat-Cauvery shear zone system in southern India.     

Cordierite-bearing granulites from Ihosy,southern Madagascar:Petrology,geochronology and regional correlation of suture zones in Madagascar and India

Madagascar,a major fragment of Gondwana,is mainly composed of Precambrian basenent rocks formed by Mesoarchean to Neoproterozoic tectono-thernial events and recording a Pan-African metamorphic overprint.The Ranotsara Shear Zone in southern Madagascar has been correlated with shear zones in southern India and eastern Africa in the reconstruction of the Gondwana supercontinent.Here we present detailed petrology,mineral chemistry,metamorphic P-T constraints using phase equilibrium modelling and zircon U-Pb geochronological data on high-grade metamorphic rocks from Ihosy within the Ranotsara Shear Zone.Garnet-cordierite gneiss from Ihosy experienced two stages of metamorphism.The peak mineral assemblage is interpreted as garnet+sillimanite+cordierite+quartz+plagioclase+Kfeldspar+magnetite+spinel+ilmenite,which is overprinted by a retrograde mineral assemblage of biotite+garnet+cordierite+quartz+plagioclase+K-feldspar+magnetite+spinel+ilmenite.Phase equilibria nodelling in the system Na_2 O-CaO-K_2 O-FeO-MgO-Al_2 O_3-SiO_2-H_2 O-TiO_2-Fe_2 O_3(NCKFMASHTO) indicates peak metamorphic conditions of 850-960 C and 6.9-77 kbar,and retrograde P-Tconditions of 740 C and 4.8 kbar,that define a clockwise P-T path.Near-concordant ages of detrital zircon grains in the garnet-cordierite gneiss dominantly exhibit ages between 2030 Ma and 1784 Ma,indicating dominantly Paleoproterozoic sources.The lower intercept age of 514±33 Ma probably indicates the timing of high-grade metamorphism,which coincides with the assembly of the Gondwana supercontinent.The comparable rock types,zircon ages and metamorphic P-T paths between the Ranotsara Shear Zone and the Achankovil Suture Zone in southern India support an interpretation that the Ranotsara Shear Zone is a continuation of the Achankovil Suture Zone.     

Late Neoproterozoic-Cambrian Felsic Magmatism Along Transcrustal Shear Zones in Southern India: U-Pb Electron Microprobe Ages and Implications for the Amalgamation of the Gondwana Supercontinent

We report U-Pb electron microprobe ages for zircon and monazite from two granitic plutons from southern India, the Vattamalai granite within the Palghat-Cauvery Shear Zone system and the Pathanapuram granite within the Achankovil Shear Zone. A zircon grain from the Vattamalai granite has a core age of 693±132 Ma and is surrounded by a thick overgrowth with an age of 504±104 Ma. Monazites from the Vattamalai granite show a small range of ages between 500-520 Ma. PbO vs. ThO₂* plots of the monazites define a precise isochron age of 517±6.7 Ma (MSWD = 0.25). The oldest zircons in the Pathanapuram pluton are in the range 961-1149 Ma, with younger overgrowths at ~540-560 Ma. Monazite cores from the granite lie in the range of 526-574 Ma, whereas rims and bright overgrowths range from 506-539 Ma. These monazites define two linear arrays in PbO vs. ThO₂* plots with cores yielding an isochron age of 550±25 Ma (MSWD = 0.58) and the rims defining an age of 515±15 Ma (MSWD = 0.68).The age data from the granite plutons indicate multiple thermal imprints in southern India with the latest orogeny during the Late Neoproterozoic-Cambrian (Pan-African). The older zircon cores up to 1149 Ma from the Pathanapuram pluton suggest inherited components of late Mesoproterozoic age, caught up within the granite magma. However, the dominant 570-520 Ma ages obtained from both zircons and monazites closely compare with similar ages for magmatism and metamorphism from throughout the East African Orogen. Late Neoproterozoic-Cambrian felsic magmatism occurred along both the Palghat-Cauvery Shear System and the Achankovil Shear Zone, indicating that these shears were active at this time and may have served as pathways for the emplacement of magmas generated at depth. The magmatism represents part of the various collisional-extensional episodes that marked the final amalgamation of the Gondwana supercontinent.     

Dunite, Glimmerite and Spinellite in Achankovil Shear Zone, South India: Implications for Highly Potassic CO2-rich Melt Influx Along an Intra-continental Shear Zone

In the Kakkaponnu area within the Achankovil Shear Zone (ACSZ), southern India, an undeformed ultramafic body occurs within intensely deformed granulite facies metamorphic rocks of Pan-African age. The Kakkaponnu ultramafic body is composed of spinel-dunite, phlogopite-dunite, glimmerite, graphite-spinel-glimmerite, and phlogopite-graphite-spinellite. The spinel-dunite is a fine- to medium-grained rock composed mainly of olivine and aluminous spinel and is characterized by relatively high MgO (50.39–50.90 wt.%), (Mg/ (Mg+Fe) = 0.95), Al₂O₃ (7.8–8.98 wt.%), and low Ni (10–14 ppm). The phlogopite-dunite comprises serpentinized olivine, phlogopite and subordinate amounts of dolomite and is high in MgO (36.5 wt.%), Mg# [(Mg/(Mg+Fe) = 0.97], and K₂O (%%5.5 wt.%). Olivine in the spinel-dunite is marked by unusually high MgO (Mg# = 0.96) and extremely low NiO (<0.14 wt.%). Spinels in all rock variants are highly aluminous with low Cr# [Cr/(Al+Cr)] ratio (<0.01). Magnesian ilmenite [Mg# = 59], rutile, zirconolite and baddeleyite are main accessory phases. No significant compositional variation is noted between large grains and small inclusions for all minerals. Abundant graphite, magnesite, melt and ubiquitous CO₂ fluid inclusions are identified in the olivine and spinel grains. The data imply that the Kakkaponnu ultramafic body was formed by progressive crystallization of highly potassic CO₂-rich melts injected into lower crustal levels. K-Ar ages of 470.5±9.3 and 464.5±9.2 Ma are obtained for phlogopite separates from glimmerite and phlogopite-dunite respectively. These ages are comparable to the phlogopite K-Ar ages reported from lithospheric shear zones in southern Madagascar, which was once conjugated to the Southern Peninsular India prior to the Gondwana breakup. This implies widespread highly potassic CO₂-rich fluid/melt influx along shear zones in this part of East Gondwana continent.     

Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Sapphire within zircon-rich gem deposits,Bo Loei,Ratanakiri Province,Cambodia: trace elements,inclusions, U–Pb dating and genesis

Subordinate sapphire accompanies prevalent zircon megacrysts in the Bo Loei basaltic gem field, Ratanakiri Province, Cambodia. These deposits are important for heat-treated gem zircon. Dark blue sapphire, with rare blue-green, orange-brown and yellow stones, up to a few cm in size, include hexagonal-shaped and growth-zoned crystals. Analyses of the sapphires (electron microprobe and laser ablation-inductively coupled plasma-mass spectrometry) showed Fe as the main chromophore (0.6–2.7 wt%), with minor Ti (<0.7 wt%). Sapphire cores show enrichment in Fe relative to rims and some include exotic heavy elements (Nb up to 56, Ta up to 144, Sn up to 5 ppm). The sapphires show high Ga values (271–724 ppm) and Ga/Mg ratios (4.8–77.0) suggesting magmatic associations. Two sapphires with syngenetic inclusions (zircon, Nb-rich rutile) gave U–Pb (Th-disequilibrium corrected) ages at ca 0.93 ± 0.1 Ma. The Bo Loei sapphires show higher Fe and Ga than other magmatic sapphire suites elsewhere in Cambodia (Pailin), Laos (Ban Huai Sai, Ban Sam Sai), South Vietnam (Dak Nong, Dak Lac) and SE Thailand (Chanthaburi-Trat). This suggests potential for geographic typing of sapphire suites between these different fields.     

Tectonic framework of the Precambrian of Madagascar and its Gondwana connections: a review and reappraisal

The Precambrian of Madagascar is divided into two sectors by the north-west trending sinistral Ranotsara shear zone, which continues in the Mozambique belt, probably as the Surma shear zone, and in Southern India as the Achankovil shear zone. South of Ranotsara six north-south trending tectonic belts are recognized that consist largely of granulite and high amphibolite facies paragneisses, phlogopite diopsidites, concordant granites and granulites. North of Ranotsara the central-northern segment is traversed by a north-trending axial 100–150 km wide dextral shear zone of probable Pan-African age, which was metamorphosed under granulite and high amphibolite facies conditions and which has reworked older basement. This shear zone continues across southern India as the Palghat-Cauvery shear zone. Major stratiform basic -ultrabasic complexes occur in the axial zone and in the basement to the west. Well preserved low grade continental margin-type sediments (quartzites, mica schists and stromatolitic marbles) of Kibaran age are present in western Madagascar. Two partly greenschist grade sedimentary groups lie unconformably on high grade basement in north-east Madagascar. Isotopic age data suggest the presence in Madagascar of Archaean, Early and Mid-Proterozoic crustal material that was extensively reworked in Pan-African times.     

Southern Granulite Terrain, South of the Palghat-Cauvery Shear Zone: Implications for India-Madagascar Connection

The present paper correlates the southern Madgascar terrain, south of the Ranotsara shear with the granulite terrain of southern India, occurring south of the Palghat-Cauvery (P-C) shear zone. Both the terrains have witnessed high temperature to ultra high temperature granulite metamorphism at 550 Ma and are traversed by shear zones and deep crustal faults. The 550 Ma old granulite terrains of Madagascar and southern India have similar lithologies, in particular, sapphirine bearing pelitic assemblages. Graphite deposits and gem occurrences are common to both these terrains. The 550 Ma old southern granulite terrain of southern India comprises of different blocks, the Madurai and the Kerala Khondalite belt, but all the blocks have similar lithologies with pelite—calc silicate rocks inter-banded with two pyroxene granulite bodies. These lithologies occur amidst an essentially charnockitic terrain. The protolith ages of the southern granulite terrain, south of the P-C shear zone ranges between 2400–2100 Ma. The terrain as a whole has witnessed the 550 Ma old granulite event. The granulite metamorphism took place under temperatures of 800–1000°C and at pressures of 9.5 to 5 Kbar.The source of heat for the high temperature granulite event of the southern Madagascar terrain has been linked to advective heat transfer along mantle deep faults. The source for the high temperature granulite metamorphism for the southern granulite terrain may be attributed to high temperature carbonatite and alkaline intrusives in an extensional setting which followed an initial crustal thickening.Many workers have linked Madagascar to southern India by connecting the Ranotsara shear either to the P-C shear zone or to the Achankovil shear zone, further south. The important factor is the lithologies of the Madagascar terrain, south of Ranotsara shear zone and the 550 Ma. old southern Indian granulite terrain are similar in many aspects. It will be more appropriate to link the Ranotsara shear to the curvilinear lineament bounding the Anaimalai-Kodaikanal ranges and which merges with the southern margin of the P-C shear zone.However, north of the Ranotsara shear/fault, the northern Madagascar terrain comprises of a dominant Itremo sequence (< 1850 Ma) and 780 Ma old calc-alkaline intrusives. The latter have similarities with that of Aravallis and the Sirohi, Malani sequences occurring further north east. The Rajasthan terrain has witnessed igneous intrusive activity at 1000–800 Ma. If we can broaden the area of investigations and include the above areas, the Madagascar-India connection can be better understood.     

Ultrahigh-temperature metamorphism in the Achankovil Zone: Implications for the correlation of crustal blocks in southern India

The Achankovil Zone of southern India, a NW–SE trending lineament of 8–10 km in width and > 100 km length, is a kinematically debated crustal feature, considered to mark the boundary between the Madurai Granulite Block in the north and the Trivandrum Granulite Block in the south. Both these crustal blocks show evidence for ultrahigh-temperature metamorphism during the Pan-African orogeny, although the exhumation styles are markedly different. The Achankovil Zone is characterized by discontinuous strands of cordierite-bearing gneiss with an assemblage of cordierite + garnet + quartz + plagioclase + spinel + ilmenite + magnetite ± orthopyroxene ± biotite ± K-feldspar ± sillimanite. The lithology preserves several peak and post-peak metamorphic assemblages including: (1) orthopyroxene + garnet, (2) perthite and/or anti-perthite, (3) cordierite ± orthopyroxene corona around garnet, and (4) cordierite + quartz symplectite after garnet. We estimate the peak metamorphic conditions of these rocks using orthopyroxene-bearing geothermobarometers and feldspar solvus which yield 8.5–9.5 kbar and 940–1040 °C, the highest P–T conditions so far recorded from the Achankovil Zone. The retrograde conditions were obtained from cordierite-bearing geothermobarometers at 3.5–4.5 kbar and 720 ± 60 °C. From orthopyroxene chemistry, we record a multistage exhumation history for these rocks, which is closely comparable with those reported in recent studies from the Madurai Granulite Block, but different from those documented from the Trivandrum Granulite Block. An evaluation of the petrologic and geochronologic data, together with the nature of exhumation paths leads us to propose that the Achankovil Zone is probably the southern flank of the Madurai Granulite Block, and not a unit of the Trivandrum Granulite Block as presently believed. Post-tectonic alkali granites that form an array of “suturing plutons” along the margin of the Madurai Granulite Block and within the Achankovil Zone, but are absent in the Trivandrum Granulite Block, suggest that the boundary between the Madurai Granulite Block and the Trivandrum Granulite Block might lie along the Tenmalai shear zone at the southern extremity of the Achankovil Zone.     

Peninsular India in Gondwana: The tectonothermal evolution of the Southern Granulite Terrain and its Gondwanan counterparts

Peninsular India forms a keystone in Gondwana, linking the East African and Malagasy orogens with Ediacaran–Cambrian orogenic belts in Sri Lanka and the Lützow Holm Bay region of Antarctica with similar aged belts in Mozambique, Malawi and Zambia. Ediacaran–Cambrian metamorphism and deformation in the Southern Granulite Terrane (SGT) reflect the past tectonic setting of this region as the leading vertex of Neoproterozoic India as it collided with Azania, the Congo–Tanzania–Bangweulu Block and Kalahari on one side and the Australia/Mawson continent on the other. The high-grade terranes of southern India are made up of four main tectonic units; from north to south these are a) the Salem Block, b) the Madurai Block, c) the Trivandrum Block, and d) the Nagercoil Block. The Salem Block is essentially the metamorphosed Dharwar craton and is bound to the south by the Palghat-Cauvery shear system — here interpreted as a terrane boundary and the Mozambique Ocean suture. The Madurai Block is interpreted as a continuation of the Antananarivo Block (and overlying Palaeoproterozoic sedimentary sequence — the Itremo Group) of Madagascar and a part of the Neoproterozoic microcontinent Azania. The boundary between this and the Trivandrum Block is the Achankovil Zone, that here is not interpreted as a terrane boundary, but may represent an Ediacaran rift zone reactivated in latest Ediacaran–Cambrian times.     

Geochemical and oxygen isotope signatures of mantle corundum megacrysts from the Mbuji-Mayi kimberlite,Democratic Republic of Congo,and the Changle alkali basalt,China

Oxygen isotope signatures of ruby and sapphire megacrysts, combined with trace-element analysis, from the Mbuji-Mayi kimberlite, Democratic Republic of Congo, and the Changle alkali basalt, China, provide clues to specify their origin in the deep Earth. At Mbuji-Mayi, pink sapphires have δ¹⁸O values in the range 4.3 to 5.4‰ (N = 10) with a mean of 4.9 ± 0.4‰, and rubies from 5.5 to 5.6‰ (N = 3). The Ga/Mg ratio of pink sapphires is between 1.9 and 3.9, and in rubies, between 0.6 and 2.6. The blue or yellow sapphires from Changle have δ¹⁸O values from 4.6 to 5.2 ‰, with a mean of 4.9 ± 0.2‰ (N = 9). The Ga/Mg ratio is between 5.7 and 11.3. The homogenous isotopic composition of ruby suggests a derivation from upper mantle xenoliths (garnet lherzolite, pyroxenite) or metagabbros and/or lower crustal garnet clinopyroxenite eclogite-type xenoliths included in kimberlites. Data from the pink sapphires from Mbuji-Mayi suggest a mantle origin, but different probable protoliths: either subducted oceanic protolith transformed into eclogite with δ¹⁸O values buffered to the mantle value, or clinopyroxenite protoliths in peridotite. The Changle sapphires have a mantle O-isotope signature. They probably formed in syenitic magmas produced by low degree partial melting of a spinel lherzolite source. The kimberlite and the alkali basalt acted as gem conveyors from the upper mantle up to the surface.     

刚玉宝石矿物

文章简介丁刚玉族宝石矿物的化学成分、物理性质及产状;描述了红宝石、蓝宝石、粉蓝宝石、黄蓝宝石、绿蓝宝石、无色蓝宝石和星光宝石的特征、真伪鉴别方法及市场行情。     

The application of single zircon evaporation and model Nd ages to the interpretation of polymetamorphic terrains: an example from the Proterozoic mobile belt of south India

The technique of single zircon dating from the thermal evaporation of ²⁰⁷Pb/²⁰⁶Pb (Kober 1986, 1987) provides a means of dating successive periods of growth and nucleation of zircons in polymetamorphic assemblages. In contrast Nd model ages may provide a measure of the period of crustal residency for the sample or its protolith. These two techniques have been combined to elucidate the tectonic history of the Proterozoic mobile belt of southern India, exposed south of the Palghat-Cauvery Shear Zone that marks the southern boundary of the Archaean craton of Karnataka. The two main tectonic units of this mobile belt comprise the Madurai and Trivandrum Blocks, both of which are characterised by massive charnockite uplands and low-lying polymetamorphic metasedimentary belts that have undergone a complex tectonic history throughout the Proterozoic. Evidence for early Palaeoproterozoic magmatism is restricted to the Madurai Block where single zircon evaporation ages from a metagranite (2436 ± 4 Ma) are similar to model Nd ages from a range of lithologies suggesting crustal growth at that time. The Trivandrum Block, to the south of the Achankovil shear zone, is comprised of the Kerala Khondalite Belt, the Nagercoil charnockites and the Achankovil metasediments. Single zircon evaporation ages, together with conventional zircon and garnet chronometry, suggest that all three units underwent upper-amphibolite facies metamorphism at ∼1800 Ma, an event unrecorded in the metagranite from the Madurai Block. This implies that the Madurai and Trivandrum blocks represent distinct terrains throughout the Palaeoproterozoic. Model Nd ages from the Achankovil metasediments are much younger (1500–1200 Ma) than those from the adjacent Kerala Khondalite Belt and Madurai Blocks (3000–2100 Ma), but there is no evidence for zircon growth in these metasediments during the Mesoproterozoic. Hence the comparatively young model Nd ages of the metasediments are indicative of a mixed provenance rather than a discrete period of crustal growth. Zircon overgrowths from the Madurai Block (547 ± 17 Ma) and Achankovil metasediments (530 ± 21 Ma) suggest that all tectonic units of the Proterozoic mobile belt of South India shared the same metamorphic history from the early Palaeozoic. This event has been recognised in the basement lithologies of Sri Lanka and East Antarctica, confirming that the constituent terrains of East Gondwana had assembled by this time. Received: 10 October 1995 / Accepted: 27 October 1997     

Mineral inclusions in sapphire from the basalt-related deposit in Bo Phloi,Kanchanaburi, western Thailand: indication of their genesis

The Bo Phloi gem field in Kanchanaburi Province, Western Thailand, is closely associated with Cenozoic basalts. Blue and yellow sapphire, black spinel, and minor zircon have been mined for over three decades. The mineral inclusions observed in sapphire samples are alkali feldspar, nepheline, hercynitic spinel, zircon, manganiferous ilmenite, silica-rich enstatite, almandine–pyrope garnet, monazite, calcite, sapphirine, biotite–phlogopite mica, and staurolite. Based on their geochemical affinity, these mineral inclusions can be categorized into two main groups: felsic alkaline and contact-metamorphic, which appear to have originated from different processes. These inclusions provide new evidence for proposing a bimodal genetic model. Felsic alkaline origin is evidenced by the occurrence of a felsic alkaline inclusion suite and the REE geochemistry of sapphire-associated zircon, which indicates that most of the sapphires crystallized from a high-alkali felsic melt (probably, in the lower crust). Contact-metamorphic origin is evidenced by the presence of a contact-metamorphic inclusion suite, suggesting that some of these sapphires might also have originated from metasomatized crustal rocks and a contaminated melt along the contact zone of a basaltic intrusion (probably, in the upper mantle or lower crust).     

Integrated geophysical studies to elicit the subsurface structures associated with Uranium mineralization around South Purulia Shear Zone,India: A review

South Purulia Shear Zone in India is an important zone that hosts uranium mineralization. Since detailed geophysical studies have not been carried out in this region, an integrated geophysical study using self-potential, resistivity, very low frequency electromagnetic and radiometric methods was performed to identify the subsurface structures that could host the hydrothermally altered uranium deposits in the area. The study reveals the wide and large magnitude of negative self-potential anomaly across the South Purulia Shear Zone. The peak negative self-potential anomalies are correlated with the low gravity and low resistivity anomalies measured along various profiles. The low self-potential, gravity and low resistivity anomaly zones are also correlated with conducting zones inferred from very low frequency electromagnetic measurements. Interpretation of self-potential data reveals multiple thick sheet-type vertical and/or inclined structures which might be associated with uranium mineralization. Schlumberger resistivity sounding data reveals an increasing trend of apparent resistivity with current electrode separations/depth. Apparent conductance measured simultaneously with resistivity measurement reveals an increase in current flow of current as depth increases. This exhibits the presence of thin conducting layers at these depths, which is not reflected in resistivity sounding data due to suppression problem. Also this conducting layer is consistent in various soundings and is connected from Raghunathpur to the South Purulia Shear Zone. Correlation of very low frequency and self-potential data shows that the structures are comparable and a radiometric profile also advocate that the conducting structure is associated with radioactive minerals. These structures are likely to be mineralized zones as hydro-uranium anomaly has also been reported from various locations in the area. Moreover, drilling results at a specific mine near the study area also confirms the presence of uranium mineralization. The hydrothermal activity associated with uranium mineralization seems to be still active in the area. Such combined geophysical studies are essential to understand this highly complex shear zone for the economic exploitation of its natural resources.     

Gem corundum deposits of Madagascar: A review

Madagascar is one of the most important gem-producing countries in the world, including ruby and sapphires. Gem corundum deposits formed at different stages in the geological evolution of the island and in contrasting environments. Four main settings are identified: (1) Gem corundum formed in the Precambrian basement within the Neoproterozoic terranes of southern Madagascar, and in the volcano-sedimentary series of Beforona, north of Antananarivo. In the south, high-temperature (700 to 800 °C) and low-pressure (4 to 5 kbar) granulites contain deposits formed during the Pan-African orogenesis between 565 and 490 Ma. They accompany mafic and ultramafic complexes (ruby deposits of the Vohibory group), skarns at the contact between Anosyan granites and the Proterozoic Tranomaro group (sapphire deposits of the Tranomaro–Andranondambo district), and shear-zone corridors cross-cutting feldspathic gneisses, cordieritites and clinopyroxenites in the Tranomaro, Vohimena and Androyan metamorphic series (biotite schist deposits of Sahambano and Zazafotsy, cordieritites of Iankaroka and Ambatomena). The circulation of fluids, especially along discontinuities, allowed in-situ alkaline metasomatism, forming corundum host rocks related to desilicified granites, biotitites, “sakenites” and “corundumites”. (2) Gem corundum also occurs in the Triassic detrital formations of the Isalo group, as giant palaeoplacers in the Ilakaka–Sakaraha area. Here, sapphires and rubies may come from the metamorphic granulitic terranes of southern Madagascar. (3) Gem corundum deposits occur within the Neogene-Quaternary alkali basalts from Ankaratra (Antsirabe–Antanifotsy area) and in the Ambohitra Province (Nosy Be, Ambato and Ambondromifehy districts). Primary deposits are rare, except at Soamiakatra where ruby in gabbroic and clinopyroxenite xenoliths within alkali-basalts probably derive from mantle garnet peridotites. The blue-green-yellow sapphires typical of basaltic fields are always recovered in palaeoplacer (in karst formed upon Jurassic limestones from the Montagne d'Ambre, Antsiranana Province) and alluvial and soil placers (Ankaratra volcanic massif). (4) Deposits occur within Quaternary eluvial, colluvial and alluvial concentrations, such as high-quality rubies from the Andilamena and Vatomandry deposits.     

Gem‐bearing basaltic volcanism,Barrington, New South Wales: Cenozoic evolution,based on basalt K–Ar ages and zircon fission track and U–Pb isotope dating

Barrington shield volcano was active for 55 million years, based on basalt K–Ar and zircon fission track dating. Activity in the northeast, at 59 Ma, preceded more substantial activity between 55 and 51 Ma and more limited activity on western and southern flanks after 45 Ma. Eruptions brought up megacrystic gemstones (ruby, sapphire and zircon) throughout the volcanism, particularly during quieter eruptive periods. Zircon fission track dating (thermal reset ages) indicates gem‐bearing eruptions at 57, 43, 38, 28 and 4–5 Ma, while U–Pb isotope SHRIMP dating suggests two main periods of zircon crystallisation between 60 and 50 Ma and 46–45 Ma. Zircons show growth and sector twinning typical of magmatic crystallisation and include low‐U, moderate‐U and high‐U types. The 46 Ma high‐U zircons exhibit trace and rare‐earth element patterns that approach those of zircon inclusions in sapphires and may mark a sapphire formation time at Barrington. Two Barrington basaltic episodes include primary lavas with trace‐element signatures suggesting amphibole/apatite‐enriched lithospheric mantle sources. Other basalts less‐enriched in Th, Sr, P and light rare‐earth elements have trace‐element ratios that overlap those of HIMU‐related South Tasman basalts. Zircon and sapphire formation is attributed to crystallisation from minor felsic melts derived by incipient melting of amphibole‐enriched mantle during lesser thermal activity. Ruby from Barrington volcano is a metamorphic type, and a metamorphic/metasomatic origin associated with basement ultramafic bodies is favoured. Migratory plate/plume paths constructed through Barrington basaltic episodes intersect approximately 80% of dated Palaeogene basaltic activity (65–30 Ma) along the Tasman margin (27–37°S) supporting a migratory plume‐linked origin. Neogene Barrington activity dwindled to sporadic gem‐bearing eruptions, the last possibly marking a minor plume trace. The present subdued thermal profile in northeastern New South Wales mantle suggests future Barrington activity will be minimal.     

刚玉的铍扩散处理实验研究

铍扩散处理是一种较新的刚玉处理方法,目前在国内还未见相关的实验研究报道。运用类质同象替代原理与扩散原理,以焰熔法合成无色刚玉和山东天然蓝宝石为实验对象,在一定的温度环境下,加入适量的BeO或金属Be粉末及其它添加剂,进行了铍扩散处理实验。实验结果显示,样品的颜色色调及浓度有明显的改善,表明铍扩散处理可以使样品的颜色变为粉红色、黄色和橙红色,也可以使山东天然蓝宝石样品的颜色变浅。     

福建明溪蓝宝石的红外光谱研究

福建省明溪的蓝宝石颜色以蓝绿色和黄绿色为主。颜色不均匀,蓝色宝石中常见黄色的色带或色块。二色性明显。在紫外—可见吸收光谱中,明溪蓝宝石的吸收带出现在３７７、３８８、４５１、５１０、５７０、和８１０ｎｍ处。其中黄色主要是由４５１ｎｍ吸收引起的,蓝色与５７０ｎｍ和８１０ｎｍ吸收带有关。蓝宝石具有较高的ＦｅＯ和较低的ＴｉＯ２。ＦｅＯ的平均含量为１－３４％,ＴｉＯ２的含量为０－０７％。电子探针分析没有发现ＦｅＯ和ＴｉＯ２含量与颜色之间有明显的相关性［１］。一些学者曾发现,不同颜色蓝宝石的红外光谱特征有所…     

Late Cretaceous India–Madagascar fit and timing of break-up related magmatism

A U–Pb zircon age of 91.2 ± 0.2 Myr from western India (St. Mary islands) confidently links India with the Late Cretaceous magmatic province in Madagascar (≈ 84–92 Ma), and the U–Pb age is within analytical error of the U–Pb age of the Analalava gabbro pluton (91.6 ± 0.3 Myr) in northeastern Madagascar. Palaeomagnetic data from India and Madagascar allow us to postulate a new India–Madagascar fit (Euler latitude = 14.24°, longitude = 38.8° and rotation angle = –69.2°). This fit is applicable to the Late Cretaceous, directly prior to and during the early phase of Madagascar–India separation. In our Late Cretaceous reconstruction, south-west India runs roughly subparallel with the first known break-up related magnetic anomaly (A34); it maintains a close connection between Mada-gascar and India, but places India slightly rotated compared to the eastern margin of Madagascar and more northerly compared with some reconstructions. St. Mary magmatism is linked to the initial break-up between India and Madagascar, and magmatism probably resulted from rift-related extensional processes initially induced by the Marion hotspot underlying southern Madagascar during the Late Cretaceous.