Using variations in the stable carbon isotope composition of macrophyte remains to quantify nutrient dynamics in lakes

The apparent isotope enrichment factor ε_macrophyte of submerged plants (ε_{macrophyte–DIC} = δ¹³C_macrophyte − δ¹³C_DIC) is indicative of dissolved inorganic carbon (DIC) supply in neutral to alkaline waters and is related to variations in aquatic productivity (Papadimitriou et al. in Limnol Oceanogr 50:1084–1095, 2005). This paper aims to evaluate the usage of ε_macrophyte inferred from isotopic analyses of submerged plant fossils in addition to analyses of lake carbonate as a palaeolimnological proxy for former HCO₃ ⁻ concentrations. Stable carbon isotopic analysis of modern Potamogeton pectinatus leaves and its host water DIC from the Tibetan Plateau and Central Yakutia (Russia) yielded values between −23.3 and +0.4‰ and between +14.0 and +6.5‰, respectively. Values of ε _{Potamogeton–DIC} (range −15.4 to +1.1‰) from these lakes are significantly correlated with host water HCO₃ ⁻ concentration (range 78–2,200 mg/l) (r = −0.86; P < 0.001), thus allowing for the development of a transfer function. Palaeo-ε _{Potamogeton–ostracods} values from Luanhaizi Lake on the NE Tibetan Plateau, as inferred from the stable carbon isotope measurement of fossil Potamogeton pectinatus seeds (range −24 to +2.8‰) and ostracods (range −7.8 to +7.5%) range between −14.8 and 1.6‰. Phases of assumed disequilibrium between δ¹³C_DIC and δ¹³C_ostracods known to occur in charophyte swards (as indicated by the deposition of charophyte fossils) were excluded from the analysis of palaeo-ε. The application of the ε _{Potamogeton–DIC}-HCO₃ ⁻ transfer function yielded a median palaeo-HCO₃ ⁻ -concentration of 290 mg/l. Variations in the dissolved organic carbon supply compare well with aquatic plant productivity changes and lake level variability as inferred from a multiproxy study of the same record including analyses of plant macrofossils, ostracods, carbonate and organic content.     

Paleotemperature reconstruction in tropical Africa using fossil Chironomidae (Insecta: Diptera)

Fossil assemblages of chironomid larvae (non-biting midges) preserved in lake sediments are well-established paleothermometers in north-temperate and boreal regions, but their potential for temperature reconstruction in tropical regions has never before been assessed. In this study, we surveyed sub-fossil chironomid assemblages in the surface sediments of 65 lakes and permanent pools in southwestern Uganda (including the Rwenzori Mountains) and central and southern Kenya (including Mount Kenya) to document the modern distribution of African chironomid communities along the regional temperature gradient covered by lakes situated between 489 and 4,575 m above sea level (a.s.l). We then combined these faunal data with linked Surface-Water Temperature (SWTemp: range 2.1–28.1°C) and Mean Annual Air Temperature (MATemp: range 1.1–24.9°C) data to develop inference models for quantitative paleotemperature reconstruction. Here we compare and discuss the performance of models based on different numerical techniques [weighted-averaging (WA), weighted-averaging partial-least-squares (WA-PLS) and a weighted modern analogue technique (WMAT)], and on subsets of lakes with varying gradient lengths of temperature and other environmental variables. All inference models calibrated against MATemp have a high coefficient of determination ( r_\textjack² r_{\text{jack}}^{2}  = 0.81–0.97), low maximum bias (0.84–2.59°C), and low root-mean-squared error of prediction (RMSEP = 0.61–1.50°C). The statistical power of SWTemp models is generally weaker ( r_\textjack² r_{\text{jack}}^{2}  = 0.77–0.95; maximum bias 1.55–3.73°C; RMSEP = 1.39–1.98°C), likely because the surface-water temperature data are spot measurements failing to catch significant daily and seasonal variation. Models based on calibration over the full temperature gradient suffer slightly from the limited number of study sites at intermediate elevation (2,000–3,000 m), and from the presence of morphologically indistinguishable but ecologically distinct taxa. Calibration confined to high-elevation sites (>3,000 m) has poorer error statistics, but is less susceptible to biogeographical and taxonomic complexities. Our results compare favourably with chironomid-based temperature inferences in temperate regions, indicating that chironomid-based temperature reconstruction in tropical Africa can be achieved.     

Hydrogeochemistry of Groundwater and Its Suitability for Drinking and Agricultural Use in Nahavand,Western Iran

Groundwater is the major source of drinking water in Nahavand city. However, the groundwater quality at the agricultural areas has been deteriorating in recent years. Ground water quality monitoring is a tool which provides important information for water management and sustainable development of the water resources in Nahavand. Hydrochemical investigations were carried out in an agricultural area in Nahavand, western Iran, to assess chemical composition of groundwater. In this study, 64 representative groundwater samples were collected from different irrigation wells and analyzed for pH, electrical conductivity, major ions, and nitrate. The results of the chemical analysis of the groundwater showed that concentrations of ions vary widely and the most prevalent water type is Ca–Mg–HCO₃, followed by other water types: Ca–HCO₃, Ca–Na–HCO₃, and Na–Cl, which is in relation with their interactions with the geological formations of the basin, dissolution of feldspars and chloride and bicarbonate minerals, and anthropogenic activities. Thirty-seven percent of the water samples showed nitrate (NO₃ ⁻) concentrations above the human affected value (13 mg L⁻¹). The phosphorous (P) concentration in groundwater was between 0.11 and 0.90 mg L⁻¹, with an average value of 0.30 mg L⁻¹, with all of the samples over 0.05 mg L⁻¹. The most dominant class C2-S1 (76.5%) was found in the studied area, indicating that sodicity is very low and salinity is medium, and that these waters are suitable for irrigation in almost all soils. Agronomic practices, such as cultivation, cropping, and irrigation water management may decrease the average NO₃ ⁻ concentration in water draining from the soil zone.     

Uranium and Thorium Isotope Distribution in an Offshore Bottom Sediment Core of the Selenga Delta, Lake Baikal, Siberia

Distribution of uranium and thorium isotopes in a short sediment core obtained offshore of the Selenga Delta in Lake Baikal, Siberia, was investigated to establish their sedimentary behaviors and to look for a linkage to paleoenvironmental changes. The sediments were composed of dominantly fine detrital materials (70–85%) and a relatively high sedimentation rate (ca. 0.03 cm y⁻¹). The depth profile of ²³⁸U content in bulk sediment samples showed a large variation of 70–123 Bq kg⁻¹, while ²³²Th profile showed a relatively narrow range from 36 to 56 Bq kg⁻¹. The observed ²³⁴U/²³⁸U activity ratios revealed a marked disequilibrium ranging from 1.53 to 1.84 with a mean value of 1.71 ± 0.07, demonstrating the presence of 50–80% authigenic ²³⁸U in the bulk sediments. The distribution of this authigenic ²³⁸U did not display any clear correlation with variations in sediment composition (organic, carbonate, Bio-SiO₂ and mineral contents) including grain size median. The profile of terrigenous ²³⁸U showed a relatively similar pattern to that of ²³²Th. Results of sequential leaching indicate that ²³⁸U in Fe–Mn oxyhydroxides fractions were responsible for the distribution of authigenic ²³⁸U rather than in Bio-SiO₂ fraction. The distribution of authigenic ²³⁸U in the bottom sediments may be explained by the fluctuation of U adsorption capacity on particles including organic matter and Fe–Mn oxyhydroxides before they entered the lake. This study highlights the potential use of authigenic and terrigenous U (Th) signatures in sediments to trace the behavior of U (Th) and to reconstruct environmental (e.g., hydrological) changes in the lake catchment area.     

Hydrochemical Characteristics and Sodification of Groundwater in the Shirin Sou, Hamedan, Western Iran

Salinity and sodicity of groundwater are the principal water quality concerns in irrigated areas of arid and semi-arid regions. The hydrochemical characteristics and sodicity of groundwater in the Shirin Sou area, western Iran were investigated in this study by chemical analyses of groundwater samples from 49 wells. Chemical analysis of the groundwater showed that the mean concentration of the cations was in the order: Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, while that for anions was SO₃ ²⁻ > Cl⁻ > HCO₃ ⁻ > NO₃ ⁻. The most prevalent water type is Na–SO₄ followed by water types Na–Cl and Ca–SO₄. The chemical evolution of groundwater is primarily controlled by water–rock interactions: mainly weathering of aluminosilicates, dissolution of sulfate minerals, and cation exchange reactions. Sulfate dissolution and pyrite weathering may both contribute to the SO₄ ²⁻ load of the groundwater. High Na⁺ concentrations in groundwater participate in ion-exchange processes, resulting in the displacement of base cations into solution and raised concentrations in groundwater. The principal component analysis (PCA) performed on groundwater identified three principal components controlling variability of groundwater chemistry. Electrical conductivity, Ca²⁺, Mg²⁺, Na⁺, SO₄ ²⁻, and Cl⁻ content were associated in the same component (PC1) (salinity), most likely linked to anthropogenic activities.     

Quantitative summer-temperature reconstructions for the last 2000 years based on pollen-stratigraphical data from northern Fennoscandia

Quantitative reconstructions of mean July temperatures (T _jul) based on new and previously published pollen-stratigraphical data covering the last 2000 years from 11 lakes in northern Fennoscandia and the Kola Peninsula are presented. T _jul values are based on a previously published pollen-climate transfer function for the region with a root-mean-square error of prediction (RMSEP) of 0.99°C. The most obvious trend in the inferred temperatures from all sites is the general decrease in T _jul during the last 2000 years. Pollen-inferred T _jul values on average 0.18 ± 0.56°C (n = 91) higher than present (where “present” refers to the last three decades based on pollen-inferred T _jul in core-top samples) are indicated between 0 and 1100 AD (2000–850 cal year BP), and temperatures −0.2 ± 0.47°C (n = 78) below present are inferred between 1100 and 1900 AD (850–50 cal year BP). No consistent temperature peak is observed during the ‘Medieval Warm Period’, ca. 900–1200 AD (1100–750 cal year BP), but the cooler period between 1100 and 1900 AD (850–50 cal year BP) corresponds in general with the ‘Little Ice Age’ (LIA). Consistently with independent stable isotopic data, the composite pollen-based record suggests that the coldest periods of the LIA date to 1500–1600 AD (450–350 cal year BP) and 1800–1850 AD (150–100 cal year BP). An abrupt warming occurred at about 1900 AD and the twentieth century is the warmest century since about 1000 AD (950 cal year BP).

A model for inferring dissolved organic carbon (DOC) in lakewater from visible-near-infrared spectroscopy (VNIRS) measures in lake sediment

We developed an inference model to infer dissolved organic carbon (DOC) in lakewater from lake sediments using visible-near-infrared spectroscopy (VNIRS). The inference model used surface sediment samples collected from 160 Arctic Canada lakes, covering broad latitudinal (60–83°N), longitudinal (71–138°W) and environmental gradients, with a DOC range of 0.6–39.6 mg L⁻¹. The model was applied to Holocene lake sediment cores from Sweden and Canada and our inferences are compared to results from previous multiproxy paleolimnological investigations at these two sites. The inferred Swedish and Canadian DOC profiles are compared, respectively, to inferences from a Swedish-based VNIRS-total organic carbon (TOC) model and a Canadian-based diatom-inferred (Di-DOC) model from the same sediment records. The 5-component Partial Least Squares (PLS) model yields a cross-validated (CV) R_CV² R_{CV}^{2}  = 0.61 and a root mean squared error of prediction (RMSEP _CV ) = 4.4 mg L⁻¹ (11% of DOC gradient). The trends inferred for the two lakes were remarkably similar to the VNIRS-TOC and the Di-DOC inferred profiles and consistent with the other paleolimnological proxies, although absolute values differed. Differences in the calibration set gradients and lack of analogous VNIRS signatures in the modern datasets may explain this discrepancy. Our results corroborate previous geographically independent studies on the potential of using VNIRS to reconstruct past trends in lakewater DOC concentrations rapidly.     

Impacts of Coal-Fired Power Plants on Trace Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lake Sediments in Central Alberta, Canada

Trace metals and polycyclic aromatic hydrocarbons (PAH) were analyzed in sediment cores from three central Alberta lakes to determine the contributions of local coal-fired power plants to contaminant loadings. In Wabamun Lake, with four power plants built since 1950 within a 35-km radius, sediment concentrations of mercury, copper, lead, arsenic and selenium have increased by 1.2- to 4-fold. Trace metal enrichments were less pronounced in Lac Ste. Anne and Pigeon Lake, situated 20 km north and 70 km south of Wabamun Lake, respectively. Total Hg flux to Wabamun Lake sediments (21–32μg m⁻² yr⁻¹) has increased 6-fold since 1950, compared to 2- and 1.5-fold increases in Lac Ste. Anne and Pigeon Lake, respectively, since circa 1900. Total PAH flux to surface sediments was 730–1100μg m⁻² yr⁻¹ in Wabamun Lake, 290–420μg m⁻² yr⁻¹ in Lac Ste. Anne, and 140–240μg m⁻² yr⁻¹ in Pigeon Lake. Without adoption of pollution-abatement technology that compensates for increases in generating capacity, continued expansion of coal-burning industry in Alberta will result in increased contaminant deposition, primarily from local sources.     

Observed dryness and wetness variability in Shanghai during 1873–2005

Dryness and wetness variations on different time scales in Shanghai were analyzed using the Standardized Precipitation Index (SPI) based on monthly precipitation data for 1873–2005. The SPI on scales of 3, 6, 12 and 24 months has been calculated. The SPI on 3, 6, 12 and 24 months present 4 wet periods prevailed during 1873–1885, 1904–1923, 1938–1960 and 1983–2005, and 3 dry episodes during 1886–1903, 1924–1937 and 1961–1982. Significant periods of higher wavelet power in the SPI-24 months occurred on the time scales of 2–7-year band in around 1880–1890, 1910–1950 and 1970–1990, and at 8–15-year band in 1920–1960 and 1965–2000 respectively. Periodicities in the SOI and ENSO indices are similar to those in SPI-24 months with little difference, namely, in the SPI-24 months, there are significant periods at the 2–7- and 8–15-year bands during 1930–1940. The periodicity components in individual SPI-24 months, SOI and ENSO indices are more complicated, showing the wetness and dryness variability in Shanghai is controlled by more than one physical factors. The research results indicate that the Shanghai area has experienced dryness and wetness variability on different time scales during the past 133 years. Foundation: Frontier Project of Nanjing Institute of Geography and Limnology, CAS, No.CXNIGLAS200814; National Forestry Science and Technique Foundation during the 11th Five-Year Plan Period, No.2006BAD03A1601; Project of Huaihe River Basin, No.HRM200708; National Climate Center, China Meteorological Administration, No.CCSF2007-35 Author: Zhang Zengxin (1977–), Ph.D, specialized in climatic changes.     

Insights from a Simple Hotelling Model of the World Oil Market

This paper uses annual data on world oil price and consumption from 1965 to 2006 to calibrate a Hotelling model of optimal nonrenewable resource extraction. Numerical solutions are generated for various specifications of the elasticity of demand for both isoelastic demand and linear demand under each of two possible market structures: perfect competition and monopoly. Prior to the 1973 oil crisis, the model that best fits actual data is one of perfect competition with linear demand and a demand elasticity of −0.4. For the periods 1973–1981 and 1981–1990, the model that best fits actual data is one of monopoly with linear demand and demand elasticities of −0.8 and −0.7, respectively, suggesting that the market was strongly influenced by OPEC during this time. Under the model that best fits the most recent period (perfect competition with linear demand and demand elasticity −0.5), the real oil price (in 1982–1984 U.S.$) should fall in the range $60.87–$66.31/barrel over the years 2010–2030.

Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

High Potential Regions for Enhanced Geothermal Systems in Canada

Previous estimates of geothermal energy potential in Canada give an indication of available heat to be ‘farmed’ at depth. This article examines in more detail depth–temperature relationships near large population centers in western Canada, as well as remote communities in northern Canada, in order to provide a first order assessment of Enhanced Geothermal Systems (EGS) potential for electrical generation. Quantities of EGS thermal power output and electrical generation are dependent on output temperature and flow rate. We relate these potential power rates as a whole to drilling and installation cost for the doublet systems and triplet system. Results show areas with significant EGS potential in northern Alberta, northeastern British Columbia, and southern Northwest Territories related to high heat flow and thermal blanketing of thick sedimentary cover. Estimated installation costs in 2008 dollars are under 2 mln$/MW_e. We also estimate significant reductions in CO₂ emissions by conversion to geothermal electric production.     

Issues in Energy Economics Led by Emerging Linkages between the Natural Gas and Power Sectors

Fuel prices in 2006 continued at record levels, with uranium continuing upward unabated and coal, SO₂ emission allowances, and natural gas all softening. This softening did not continue for natural gas, however, whose prices rose, fell and rose again, first following weather influences and, by the second quarter of 2007, continuing at high levels without any support from fundamentals. This article reviews these trends and describes the remarkable increases in fuel expenses for power generation. By the end of 2005, natural gas claimed 55% of annual power sector fuel expenses, even though it was used for only 19% of electric generation. Although natural gas is enormously important to the power sector, the sector also is an important driver of the natural gas market—growing to over 28% of the market even as total use has declined. The article proceeds to discuss globalization, natural gas price risk, and technology developments. Forces of globalization are poised to affect the energy markets in new ways—new in not being only about oil. Of particular interest in the growth of intermodal traffic and its a little-understood impacts on rail traffic patterns and transportation costs, and expected rapidly expanding LNG imports toward the end of the decade. Two aspects of natural gas price risk are discussed: how understanding the use of gas in the power sector helps define price ceilings and floors for natural gas, and how the recent increase in the natural gas production after years of record drilling could alter the supply–demand balance for the better. The article cautions, however, that escalation in natural gas finding and development costs is countering the more positive developments that emerged during 2006. Regarding technology, the exploitation of unconventional natural gas was one highlight. So too was the queuing up of coal-fired power plants for the post-2010 period, a phenomenon that has come under great pressure with many consequences including increased pressures in the natural gas market. The most significant illustration of these forces was the early 2007 suspension of development plans by a large power company, well before the Supreme Court’s ruling on CO₂ as a tailpipe pollutant and President Bush’s call for global goals on CO₂ emissions.

Mineral magnetism and other characteristics of sediments from an alpine lake (3,410 m a.s.l.) in central China and implications for late Holocene climate and environment

The Qinling Mountain Range (33°–34°30′N, 107°–111°E; 3,767 m a.s.l.) lies south of the Chinese Loess Plateau and functions as the boundary between ‘north’ and ‘south’ China. Taibai Mountain (33°41′–34°10′N, 107°19′–107°58′E; 3,767 m a.s.l.) is the central massif and highest part of the range and is the highest mountain in eastern and central China, east of 105°E. It is also one of two mountains higher than the modern climatic timberline and the only one where high alpine lakes (>2,500 m a.s.l.) exist in eastern and central China. Sediments were recovered from Foye Chi (33°57′N, 107°44′E; 3,410 m a.s.l.), a small lake on the southern slope of the mountain, and measured for magnetic properties. Chronological control was achieved with AMS ¹⁴C dating. Combined with analyses of particle-size, TOC, C/N, δ¹³C_org and pollen in these sediments, and magnetic properties of catchment soils, the mineral-magnetic data reveal late Holocene palaeoenvironmental changes on the high-altitude southern slope of Taibai Mountain. Climate gradually ameliorated about 2,300 cal yr BP and warm and wet conditions occurred afterwards, culminating from 1,700 to 1,510 cal yr BP. The climate began to deteriorate at 1,510 cal yr BP, but was still warmer and wetter than present until ~663 cal yr BP. Cool, arid conditions peaked and were cooler and drier than the present at 663–290 cal yr BP, coincident with the Little Ice Age. Climate became warmer and more humid again after 290 cal yr BP. Data from these less anthropologically-disturbed alpine-lake sediments provide a record of late Holocene palaeoenvironmental change that supplements information from historical documents and literature for eastern and central China.     

A spatio-chemical survey of hydrogeothermal springs in Lake Elementaita, Kenya

The hydrochemistry of three areas of geothermal activity in the Lake Elementaita basin were surveyed. The results indicated warm temperatures between 30–40°C, high alkalinity (1,200 mg CaCO₃/l) and specific conductance (4,300–8,100 μS/cm). pH was above 9 with a high concentration of carbonates, chlorides and sulphates. Apart from playing a significant role in the lake chemistry, lacustrine springs provide a significant source of water supply, particularly during the dry season. However, there is a serious lack of scientific information on the hydrogeology and hydrochemistry of the thermal springs.     

Occurrence and environmental significance of long-chain alkenones in Tibetan Zabuye Salt Lake, S.W. China

Long-chain alkenones, a group of sensitive organic molecular indicators of water temperature, have been rather extensively studied in marine environments. However they have never been systematically examined in lacustrine environments, despite reports of their occurrence in lake sediments. Here, we report on a recent study of long-chain alkenones in a sedimentary core from a high altitude (≈5400 m) salt lake, Zabuye Salt Lake (ZSL), Tibet. This is a critical location for global climate studies, especially of the atmospheric circulation of the North Hemisphere. C₃₇−C₃₉ methyl and/or ethyl alkenones, usually dominated by components with tetra- and tri-double bounds, are commonly the major components of the polar fraction of the extracted organic matter from most sections. Down-core (vertical) variation of alkenone indices, the measure of molecular unsaturation, is compared primarily with other environmental signals, including lithology, elemental and mineral compositions, and stable carbon isotopes of hydrocarbon biomarkers of this core. Down-core profiles of alkenone climatic indices (U ₃₇ ^k and U ₃₈ ^k ) suggest ZSL had two warm periods, one during ≈20–30 ka (≈Jabula Interglacial Optimum) and another at 8–5 ka (Middle Holocene Optimum), and a severe cold period from ≈18–11 ka (Last Glacial Maximum). The proposed warmer intervals are generally characterized by higher contents of carbonate, organic carbon, alkenones and heavier δ¹³C values ofn-alkanes.     

Sediment geochemistry of Lake Daihai,north-central China: implications for catchment weathering and climate change during the Holocene

A 12.87-m-long sediment core was retrieved from closed-basin Lake Daihai in the monsoon–arid transition zone of north-central China. Oxides of major elements and their ratios normalized to Al in the AMS-¹⁴C-dated core were employed to evaluate chemical weathering intensity (CWI) in the lake drainage basin, which reflects hydrothermal conditions in the study area. Lower CWI periods occurred prior to 14.5 ka BP, and during the intervals ca. 11.7–10.3, 3.5–3.2, 2.6–1.7 ka BP, and 1.2–0 ka BP, indicating relatively low temperatures and moisture availability. Greater CWI during the intervening periods ca. 14.5–11.7, 10.3–9.0, 3.2–2.6, and 1.7–1.2 ka BP, with the maximum CWI at ca. 6.7–3.5 ka BP, imply ameliorated hydrothermal conditions in the lake basin, i.e. higher temperatures and precipitation. Exceptionally low CWI, associated with high CaO/MgO ratio during ca. 9.0–6.7 ka BP, suggests higher evaporation rates in the area under warmer temperature. Overall, CWI displays in-phase variations with changes in organic matter (TOC, TN), carbonate (CaCO₃) and pollen assemblages, all of which are related to variations in monsoon effective precipitation. High CWI indicates strong monsoon-induced precipitation, whereas low CWI reflects a weak precipitation regime. The optimum hydrothermal status, recorded by the strongest CWI and maximum monsoon effective precipitation during ca. 6.7–3.5 ka BP defines the Holocene climate optimum (HCO) in the Lake Daihai region. These results indicate that the HCO prevails after the early Holocene in the monsoon–arid transition zone of north-central China. Temperature and precipitation variations during most of the Holocene, inferred from the lake sediments, are due largely to insolation forcing. Dry but warm conditions ca. 9.0–6.7 ka BP, however, probably reflect the complex interactions between insolation and geography (e.g. altitude and local topography).     

Direct application of compound-specific radiocarbon analysis of leaf waxes to establish lacustrine sediment chronology

This study demonstrates use of compound-specific radiocarbon analysis (CSRA) for dating Holocene lacustrine sediments from carbonate-hosted Ordy Pond, O‘ahu, Hawai‘i. Long-chain odd-numbered normal alkanes (n-alkanes), biomarkers characteristic of terrestrial higher plants, were ubiquitous in Ordy Pond sediments. The δ¹³C of individual n-alkanes ranged from −29.9 to −25.5‰, within the expected range for n-alkanes synthesized by land plants using the C₃ or C₄ carbon fixation pathway. The ¹⁴C ages of n-alkanes determined by CSRA showed remarkably good agreement with ¹⁴C dates of rare plant macrofossils obtained from nearby sedimentary horizons. In general, CSRA of n-alkanes successfully refined the age-control of the sediments. The sum of n-alkanes in each sample produced 70–170 μg of carbon (C), however, greater age errors were confirmed for samples containing less than 80 μg of C. The ¹⁴C age of n-alkanes from one particular sedimentary horizon was 4,155 years older than the value expected from the refined age-control, resulting in an apparent and arguable age discrepancy. Several lines of evidence suggest that this particular sample was contaminated by introduction of ¹⁴C-free C during preparative capillary gas chromatography. This study simultaneously highlighted the promising potential of CSRA for paleo-applications and the risks of contamination associated with micro-scale ¹⁴C measurement of individual organic compounds.     

内蒙古锡林河流域羊草草原植物生长旺季呼吸的影响因素分析和区分

Based on the static opaque chamber method,the respiration rates of soil microbial respiration,soil respiration,and ecosystem respiration were measured through continuous in-situ experiments during rapid growth season in semiarid Leymus chinensis steppe in the Xilin River Basin of Inner Mongolia,China. Soil temperature and moisture were the main factor affecting respiration rates. Soil temperature can explain most CO2 efflux variations (R2=0.376-0.655) excluding data of low soil water conditions. Soil moisture can also effectively explain most of the variations of soil and ecosystem respiration (R2=0.314-0.583),but it can not explain much of the variation of microbial respiration (R2=0.063). Low soil water content (≤5%) inhibited CO2 efflux though the soil temperature was high. Rewetting the soil after a long drought resulted in substantial increases in CO2 flux at high temperature. Bi-variable models based on soil temperature at 5 cm depth and soil moisture at 0-10 cm depth can explain about 70% of the variations of CO2 effluxes. The contribution of soil respiration to ecosystem respiration averaged 59.4%,ranging from 47.3% to 72.4%; the contribution of root respiration to soil respiration averaged 20.5%,ranging from 11.7% to 51.7%. The contribution of soil to ecosystem respiration was a little overestimated and root to soil respiration little underestimated because of the increased soil water content that occurred as a result of plant removal.     

Sample preparation methods and replicability in macroscopic charcoal analysis

We explored the use of hydrogen peroxide (H₂O₂) of different strengths (1, 3, 6, and 9%) in the preparation of lake-sediment samples for macroscopic charcoal determination. In previous work we found that soaking sediment samples in 3% H₂O₂ for 24 h disaggregates samples and removes or bleaches some non-charred organic material, making it easier to distinguish macroscopic charcoal particles from dark, non-charred organic matter. To determine whether this procedure alters charcoal particle abundances and size distributions, we tested the procedure on wood and grass samples containing a known number of laboratory-produced charcoal particles from different size classes (250–500, 500–1,000, and 1,000–2,000 μm). For both sample types, we found that post-treatment numbers were not statistically different from pre-treatment numbers. However, application of hydrogen peroxide solutions of 3, 6, and 9% to fossil charcoal assemblages in a sediment core from northwestern Costa Rica reduced charcoal concentrations markedly, by bleaching or removing particles that were not fully charred. We also tested the replicability of charcoal counts by conducting enumerations on multiple samples from the same stratigraphic depths in a core. Horizontally adjacent samples from the same core may vary in charcoal concentration. This finding has implications for establishing sample volume in macroscopic charcoal analysis.