福建省闽清县池园地区早、中株罗世地新发现

福建中部闽清园－上莲一带晚侏罗世南园组火山岩地层之下覆盖着一套沉积－火山岩,原划归晚侏罗世长林组,通过对该地区1∶500000区调,依岩性组合特征、同位素地质年龄值、古生物化石及接触关系等资料,重新厘定划分为梨山组、藩坑组、漳平组。早侏罗世藩坑组的发现为福建中部火山岩基底地质构造研究、火山岩区找矿提供新的线索。     

福建永定山口早侏罗世火山喷发-沉积型钼矿床地质特征

通过对福建永定山口钼矿床地质特征的初步总结,认为永定山口钼矿床主要产于早侏罗世藩坑组中段,矿体受地层岩性控制,呈层状、似层状分布,成矿作用与火山喷发-沉积关系密切,属早侏罗世火山喷发-沉积型钼矿床。     

浙东南英安质火山岩早侏罗世锆石SHRIMP年龄的首获及其地质意义

浙江中生代晚期火山岩极为发育,而有无中生代早期火山岩,则向无定论。本文在确认浙东南松阳毛弄煤矿一带煤系沉积下部火山岩属中生界毛弄组的基础上,测得其SHRIMP锆石U-Pb年龄为180±4Ma,首次证明浙江存在早一中侏罗世火山岩,同时表明浙东南尚没有确切的中侏罗世晚期至晚侏罗世火山岩活动记录,而且也缺失晚侏罗世和大部分中侏罗世地层。     

福建省中生代双峰式火山岩的特征及成因

福建省中生代双峰式火山岩分别发育于早侏罗世藩坑组、早白垩世石帽山群,二者在剖面上均表现为流纹质火山岩直接覆盖在玄武岩之上。两个时期的双峰式火山岩均发育于断陷带上的火山构造洼地（盆地）内,形成于活动大陆边缘板内拉张环境。玄武岩是上地幔经１０％～２０％部分熔融形成;流纹质岩浆来源于下地壳经１５％～２３％部分熔融,并有较多地幔物质参与。     

福建省中生代双峰式火山岩的特征及成因

福建省中生代双峰式火山岩分别发育于早侏罗世藩坑组,早白垩世石帽山群,二者在剖面上均表现为流纹质火山岩直接覆盖在玄武岩之上。两个时期的双峰式火山岩均发育于断陷带上的火山构造洼地（盆地）内,形成于活动大陆边缘板内拉张环境,玄武岩是上地幔经１０％￣２０％部分熔融形成;流纹质岩浆来源于下地壳经１５％￣２３％部分熔融,并有较多地幔物质参与。     

福建晚三叠世－中侏罗世地层划分

福建晚三叠世－中侏罗世地层以陆相盆地沉积为主，仅闽西南局部有海陆交互相沉积。地层分区大致以政和－大埔断裂为界，分为闽西地层小区和闽东地层小区。根据各盆地地层序列及岩石组合特征，岩石地层单位可划分为陆相沉积的大坑村组、文宾山组、焦坑组、梨山组及漳平组和以海陆交互相沉积的象牙群，包括下村组和藩坑组。其中大坑村组相当于年代地层单位的上三叠统卡尼－诺利阶，文宾山组、焦坑组相当于诺利阶上部－瑞替克阶，梨山组相当于下侏罗统赫塘－托尔阶，漳平组相当于中侏罗统巴柔－卡洛阶中下部，下村组相当于下侏罗统赫塘－辛涅缪尔阶，藩坑组相当于辛涅缪尔－托尔阶。此外，文中还论述了各门类生物群的组合特征及其分布范围。     

福建晚三叠世—中侏罗世地层划分

福建晚三叠世－中侏罗世地层以陆相盆地沉积为主，仅闽西南局部有海陆交互相沉积。地层分区大致以政和一大埔断裂为界，分为闽西地层小区和闽东地层小区。根据各盆地地层序列及岩石组合特性，岩石地层单位可划分为陆相沉积的大坑村组，文宾山组、焦坑组、梨山组及漳平组和以海陆交互相沉积的象牙群，包括下材组和藩坑组。其中大坑杆组相当于年仝层单位的上三叠统卡尼一诺利阶，文宾山组、焦坑组相当于诺利阶上部一瑞替克价，梨山组相     

永定五湖早侏罗世火山喷发盆地基本特征

五湖早侏罗世火山喷发盆地位于永安县东18km。构成该盆地的火山地层属藩坑组。岩石组合为玄武岩(安山岩)-流纹岩组合,属双峰式火山岩组合。火山岩相划分为爆发相、溢流相、火山通道相、潜火山相及喷发沉积相五种基本类型,并建立了相序和相组合。火山构造圈定有白叶湖崃破火山、天子山东及大雪山东层状火山,本文重点剖析了白叶湖(山东)破火山,并阐述该火山喷发盆地的发展历史。     

闽东北晚侏罗世南园组火山岩地球化学特征及构造意义

通过福建1∶5万漳湾镇、溪南镇幅区域地质调查,对闽东北福安和霞浦晚侏罗世南园组火山岩组合、地球化学特征、岩浆起源及构造环境进行了分析.结果 表明,研究区南园组火山岩共分为中性-中酸性、酸性及中性-中酸性3个岩性段,分别对应南园组第一段、第二段和第三段.南园组中性火山岩具有高铝、低镁铁特征,酸性火山岩具有高硅、高铝、低镁...     

福建华安地区晚侏罗世南园组火山岩成因及其构造环境探讨

通过对华安地区晚侏罗世火山岩岩石组合、岩石地球化学特征的研究,认为晚侏罗世南园组火山岩岩浆主要来源于地壳部分熔融,并有少量地幔物质加入,属于壳幔混源型岩浆;火山岩形成可能与古太平洋板块相对欧亚大陆的俯冲消减有关,属陆缘弧火山岩。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。