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1.
Summary The electric conductivity of basaltic rocks of the final volcanic phase of the Alpine-Carpathian orogenesis was studied in the temperature interval of 200–1000°C. The results obtained are compared with the chemical and modal composition of the rocks and with the content of trace elements (Cr, Co, Ni, V). The statistical treatment of a set of 11 rocks types indicated that the electric conductivity is mostly affected by the modal composition of the rock in the temperature interval of 200–600°C, whereas the effect of trace elements can be seen distinctly in the interval of 600–1000°C.  相似文献   

2.
The variability of sedimentary thermal conductivities with increasing temperature are explored for their impact on estimates of present-day heat flux and subsurface temperature gradient. For sand thicknesses less than about 10–20 km, or shale thicknesses less than about 40–80 km, the subsurface temperature is closely linearly proportional to the thermal resistance integral obtained in the absence of the temperature dependence of thermal conductivity. Estimates of heat flux should be increased (decreased) by about 5% for sands and decreased by about 1% for shales. For salt, because of the much shorter temperature range over which its thermal conductivity decreases, effects produced by the temperature dependence are more noticeable: heat flux should be increased by around 13%, salt thicknesses in excess of 5 km will yield major (around 30–100°C) changes in their temperature regimes solely as a consequence of the temperature-dependent thermal conductivity, and the linear increase of temperature with increasing thermal resistance is not an adequate approximation but has to be replaced with a more exact exponential increase.The impact of the variations, particularly in the case of salt, for geologic processes is briefly considered.  相似文献   

3.
高温高压下地幔岩和苦橄质榴辉岩的电导率实验   总被引:1,自引:1,他引:0       下载免费PDF全文
为了探讨地幔岩模型和苦橄质榴辉岩模型在上地幔存在的合理性,建立上地幔的电性结构,本文利用YJ-3000t紧装式六面顶压机和Solartron IS-1260阻抗/增益-相位分析仪,在1.0~4.0GPa、700~1150℃的条件下,采用交流阻抗谱法(频率范围10-1~106 Hz)分别测量了地幔岩和苦橄质榴辉岩的电导率.实验结果表明:随着温度的升高,地幔岩和苦橄质榴辉岩的电导率大幅增加;随着压力的增大,地幔岩的电导率略有增加,活化体积ΔV为-4.73cm3·mol-1,而苦橄质榴辉岩的电导率几乎没有变化,活化体积ΔV为-0.11cm3·mol-1;在电性方面,用苦橄质榴辉岩来表示深部的物质较为合理,地幔岩解释浅部可能更恰当,但浅部物质的分布不均匀,电导率随深度的变化主要受控于温度的影响,其次才是成分.  相似文献   

4.
The lower crust is generally considered to be an aseismic, weak zone where fluid distribution might be governed by textural equilibrium geometries. Saline fluids below the transition from brittle to ductile rheology have been advanced as a joint explanation for deep crustal conductivity and seismic reflectivity, the depth of onset of both phenomena being apparently bounded by isotherms in the 300–450 °C temperature range. Some petrologists, meanwhile, contest that the deep crust should be devoid of extensive fluid networks. This review exposes some geophysical exceptions to the statistical norm suggested by global geophysical data compilations and presents counter-arguments that the lower crust in places may be both dry and strong, that fluids if at all present at such depths may not necessarily be connected and that fluid mobility in the lower crust may be more limited and heterogeneous than commonly assumed.Laboratory data on crustal rocks implies that the transition from brittle to ductile rheology actually occurs over a much broader range of temperatures than 300–450 °C, and the apparent association of deep crustal conductive horizons with a temperature field of 300–450 °C may be interpretable in terms of formation temperatures of graphite, rather than fluids and brittle-ductile transition rheology.High vP/vS ratios from a 6 km thick, seismically layered zone below the Weardale granite, NE England can be explained by underplated mafic material. They are unlikely to be explained by fluids in an area where deep crustal conductance has been shown to be relatively low, unless conventional assumptions regarding deep crustal fluid distribution are inadequate or false.Perusal of the literature reveals that lower crustal seismicity is less seldom than generally appreciated. Interpretation of earthquakes nucleating at lower crustal depths is ambiguous, but in some tectonic regimes may indicate preservation of brittle rheology to the Moho and a lower crust that is predominantly mafic and dry.A better understanding of lower crustal deformation mechanisms and history may provide better insight into deep crustal conductivity mechanisms. Recent rock mechanical experiments suggest that permeability (and thus fluid connectivity) may be decreased by ductile shearing, whereas ductile shearing may aid graphitisation at lower crustal temperatures. If the lower crust in some regions is strong, this may explain the apparent preservation of both extant- and palaeostress orientations in interpretations involving electrical anisotropy.  相似文献   

5.
We examine the nonlinear inverse problem of electromagnetic induction to recover electrical conductivity. As this is an ill-posed problem based on inaccurate data, there is a critical need to find the reliable features of the models of electrical conductivity. We present a method for obtaining bounds on Earth’s average conductivity that all conductivity profiles must obey. Our method is based completely on optimization theory for an all-at-once approach to inverting frequency-domain electromagnetic data. The forward modeling equations are constraints in an optimization problem solving for the electric fields and the conductivity simultaneously. There is no regularization required to solve the problem. The computational framework easily allows additional inequality constraints to be imposed, allowing us to further narrow the bounds. We draw conclusions from a global geomagnetic depth sounding data set and compare with laboratory results, inferring temperature and water content through published Boltzmann-Arrhenius conductivity models. If the upper mantle is assumed to be volatile free we find it has an average temperature of 1409-1539 ° C. For the top 1000 km of the lower mantle, we find an average temperature of 1849-2008 ° C. These are in agreement with generally accepted mantle temperatures. Our conclusions about water content of the transition zone disagree with previous research. With our bounds on conductivity, we calculate a transition zone consisting entirely of Wadsleyite has <0.27  wt.% water and as we add in a fraction of Ringwoodite, the upper bound on water content decreases proportionally. This water content is less than the 0.4 wt.% water required for melt or pooling at the 410 km seismic discontinuity.  相似文献   

6.
The results of seismic measurements along the deep seismic sounding profile VII and terrestrial heat flow measurements used for construction of heat generation models for the crust in the Paleozoic Platform region, the Sudetic Mountains (Variscan Internides) and the European Precambrian Platform show considerable differences in mantle heat flow and temperatures. At the base of the crust variations from 440–510°C in the models of Precambrian Platform to 700–820°C for the Paleozoic Platform and the Variscan Internides (Sudets) are found. These differences are associated with considerable mantle heat flow variations.The calculated models show mantle heat flow of about 8.4–12.6 mW m–2 for the Precambrian Platform and 31 mW m–2 to 40.2 mW m–2 for Paleozoic orogenic areas. The heat flow contribution originating from crustal radioactivity is almost the same for the different tectonic units (from 33.5 mW m–2 to 37.6 mW m–2). Considerable physical differences in the lower crust and upper mantle between the Precambrian Platform and the adjacent areas, produced by lateral temperature variations, could be expected. On the basis of carbon ratio data it can be concluded that the Carboniferous paleogeothermal gradient was much lower in the Precambrian Platform area than in the Paleozoic Platform region.  相似文献   

7.
The cooling of a magmatic intrusion is simulated by a simple model of a non-homogeneous earth, with thermal properties depending on temperature, in which heat transfer is assumed to take place by conduction only. The mathematical problem consists in solving a non-linear partial differential equation with continuity conditions on temperature and heat flux imposed at the contacts between different rocks. This has been done numerically by a finite difference method. The model is then adopted as “reality” against which a number of commonly used approximations are tested. It is found that the effect of latent heat liberation can be reasonably taken into account by attributing an effective initial temperature to the magma (errors within 20°C for t > 105 years, when the temperature of the magma is still as high as 600°C); the effective specific heat approximation does not work as well. The dependence of thermal conductivity and specific heat on temperature may be eliminated by maintaining the errors within 30°C for t < 5 × 105 years. The assumption that magma and country rocks have the same thermal properties allows an estimate of the temperature field in the host rocks with errors of 50°C at most. The assumption that all rocks have the same constant conductivity yields results that are far from “reality” (errors of 100–200°C even at shallow depth).  相似文献   

8.
为了建立具有普遍适用性的上地幔电性结构,本文利用Kawai-1000t压机和Solartron IS-1260阻抗/增益-相位分析仪,在4.0~14.0 GPa、873~1673 K的条件下,采用交流阻抗谱法(频率范围10-1~106Hz)测量了不含水的地幔岩电导率.实验结果显示,岩石的电导率随温度升高而大幅度的增大;在较大的温度范围内岩石的导电机制发生了变化,中低温时为小极化子导电,此时激活焓为0.94 eV (±0.13) eV,激活体积为0.11(±0.92) cm3·mol-1,高温时为和镁空穴相关的离子导电,此时激活焓为1.6~3.17 eV,激活体积为6.75(±7.43) cm3·mol-1;本次测量的电导率比低压下岩石的电导率要高,比矿物的电导率也要高.用本次的实验结果回归计算得到Fennoscandian地区的上地幔的一维电导率剖面,发现200 km以上本次实验计算的结果和大地电磁测深的电导率剖面吻合的比较好,在200 km以下本次实验得到的要比野外测量的电导率稍稍高一点,可能是因为实验过程中没有完全避免水的影响.本次的实验结果比用有效均匀介质方法计算得到的pyrolite矿物模型的电导率要高出两个数量级,这样的结果显示只用一种矿物的电导率或是几种矿物理论计算的结果有一定的不合理性.  相似文献   

9.
Measurements on thermal conductivity and diffusivity as functions of temperature (up to 1150 K) and pressure (up to 1000 MPa) are presented for Archaean and Proterozoic mafic high-grade rocks metamorphosed in middle and lower crustal pressures, and situated in eastern Finland, central Fennoscandian Shield. Decrease of 12–20% in conductivity and 40–55% in diffusivity was recorded between room temperature and 1150 K, which can be considered as typical of phonon conductivity. Radiative heat transfer effects were not detected in these samples. Pressure dependencies of the samples are weak if compared to crystalline rocks in general, but relatively typical for mafic rocks.The temperature and pressure dependencies of thermal transport properties (data from literature and the present study) were applied in an uncertainty analysis of lithospheric conductive thermal modellings with random (Monte Carlo) simulations using a 4-layer model representative of shield lithosphere. Model parameters were varied according to predetermined probability functions and standard deviations were calculated for lithospheric temperature and heat flow density after 1500 independent simulations. The results suggest that the variations (uncertainties) in calculated temperature and heat flow density values due to variations in the temperature and pressure dependencies of conductivity are minor in comparison to the effects produced by typical variations in the room temperature value of conductivity, heat production rate or lower boundary condition values.  相似文献   

10.
Summary The temperature-depth distribution was calculated to a depth of 70 km along the 520 km long Taratashskiy refraction profile crossing the Ural Mts., approximately along latitude 56°N. The steady-state model was solved numerically using the finite-difference method, the vertical distribution of heat production was derived from the observed seismic velocities. It was shown that at the Moho boundary, the mantle heat flow varied between 10 and 25 mWm–2, and the Moho temperature amounted to 300–550°C for the two versions studied.  相似文献   

11.
The electrical properties of rocks and minerals are controlled by thermodynamic parameters like pressure and temperature and by the chemistry of the medium in which the charge carriers move. Four different charge transport processes can be distinguished. Electrolytic conduction in fluid saturated porous rocks depends on petrophysical properties, such as porosity, permeability and connectivity of the pore system, and on chemical parameters of the pore fluid like ion species, its concentration in the pore fluid and temperature. Additionally, electrochemical interactions between water dipoles or ions and the negatively charged mineral surface must be considered. In special geological settings electronic conduction can increase rock conductivities by several orders of magnitude if the highly conducting phases (graphite or ores) form an interconnected network. Electronic and electrolytic conduction depend moderately on pressure and temperature changes, while semiconduction in mineral phases forming the Earth’s mantle strongly depends on temperature and responds less significantly to pressure changes. Olivine exhibits thermally induced semiconduction under upper mantle conditions; if pressure and temperature exceed ~ 14 GPa and 1400 °C, the phase transition olivine into spinel will further enhance the conductivity due to structural changes from orthorhombic into cubic symmetry. The thermodynamic parameters (temperature, pressure) and oxygen fugacity control the formation, number and mobility of charge carriers. The conductivity temperature relation follows an Arrhenius behaviour, while oxygen fugacity controls the oxidation state of iron and thus the number of electrons acting as additional charge carriers. In volcanic areas rock conductivities may be enhanced by the formation of partial melts under the restriction that the molten phase is interconnected. These four charge transport mechanisms must be considered for the interpretation of geophysical field and borehole data. Laboratory data provide a reproducible and reliable database of electrical properties of homogenous mineral phases and heterogenous rock samples. The outcome of geoelectric models can thus be enhanced significantly. This review focuses on a compilation of fairly new advances in experimental laboratory work together with their explanation.  相似文献   

12.
An attempt is made to obtain a combined geophysical model along two regional profiles: Black Sea— White Sea and Russian Platform—French Central Massif. The process of the model construction had the following stages: 1. The relation between seismic velocity (Vp, km/s) and density (σ, g/cm3) in crustal rocks was determined from seismic profiles and observed gravity fields employing the trial and error method. 2. Relations between heat production HP (μW/m3), velocity and density were established from heat flow data and crustal models of old platforms where the mantle heat flow HFM is supposed to be constant. The HFM value was also determined to 11 ± 5 mW/m2. 3. A petrological model of the old platform crust is proposed from the velocity-density models and the observed heat flow. It includes 10–12 km of acid rocks, 15–20 km of basic/metamorphic rocks and 7–10 km of basic ones. 4. Calculation of the crustal gravity effects; its substraction from the observed field gave the mantle gravity anomalies. Extensively negative anomalies have been found in the southern part of Eastern Europe (50–70 mgal) and in Western Europe (up to 200 mgal). They correlate with high heat flow and lower velocity in the uppermost mantle. 5. A polymorphic advection mechanism for deep tectonic processes was proposed as a thermal model of the upper mantle. Deep matter in active regions is assumed to be transported (advected) upwards under the crust and in its place the relatively cold material of the uppermost mantle descends. The resulting temperature distribution depends on the type of endogeneous regime, on the age and size of geostructure. Polymorphic transitions were also taken into account.  相似文献   

13.
Continental shield regions are normally characterized by low-to-moderate mantle heat flow. Archaean Dharwar craton of the Indian continental shield also follows the similar global pattern. However, some recent studies have inferred significantly higher mantle heat flow for the Proterozoic northern block of Southern Granulite Terrain (SGT) in the immediate vicinity of the Dharwar craton by assuming that the radiogenic elements depleted exposed granulites constitute the 45-km-thick crust. In this study, we use four-layered model of the crustal structure revealed by integrated geophysical studies along a geo-transect in this region to estimate the mantle heat flow. The results indicate that: (i) the mantle heat flow of the northern block of SGT is 17 ± 2 mW/m2, supporting the global pattern, and (ii) the lateral variability of 10–12 mW/m2 in the surface heat flow within the block is of crustal origin. In terms of temperature, the Moho beneath the eastern Salem–Namakkal region appears to be at 80–100 °C higher temperature than that beneath the western Avinashi region.  相似文献   

14.
本文利用藏北地区三口天然气水合物钻孔测温数据,在分析样品热导率测试结果基础上,计算了藏北地区的热流值.对于样品热导率值,首先根据样品孔隙度对实验室测试结果进行了饱水校正,计算热流时采用的是对应井段的岩石热导率饱水校正值的厚度加权平均值.地温梯度以三口钻孔48 h的测温数据为基础,回归三口井的地温梯度,计算时去除了浅部受地表温度和冻土带对温度影响的数值.A钻孔地温梯度分为200~438 m和438~882 m两段回归,分段热流的加权平均值作为钻孔热流值,计算结果为42.7 mW·m-2; B钻孔和C钻孔回归地温梯度时未分段,热流计算结果分别为58.3 mW·m-2、70 mW·m-2.综合分析认为,岩石圈断裂、地幔上涌、碰撞造山过程中的剪切生热等因素可能造成了班公湖—怒江缝合带以南热流值较高,而北部羌塘地块热流值相对较低.  相似文献   

15.
We use telluric and magnetic data of the diurnal variation recorded in Europe, Australia and North America to study the magnetotelluric tensor in the 6h–24h period range. We use associate directions and we eliminate the effects of deviation of telluric currents. We thus obtain for each observatory reliable phases and apparent resistivity values representative of the neighbouring stratified substratum. It appears that the values obtained in the four European observatories (Saint-Maur, France; Ebro, Spain; Toledo, Spain; Nagycenk, Hungary) give similar results and that these results are different from those obtained either in Tucson (USA) or in Watheroo (Australia).Using Bostick transform we interpret these phase and apparent resistivity values in terms of conductivity of the upper mantle. We discuss then the conductivity heterogeneities in terms of change either in temperature, or partial melting or percentage of fluids of the upper mantle: at depths of about 300 km, the upper mantle appears to be 100 °C hotter under Australia than under Europe; the probable presence of fluids at depths about 100 km in the southwestern North America upper mantle appears to be responsible for the high observed conductivities. All these conductivity values are coherent with tomography results from Woodhouse and Dziewonsky: high (low) conductivities are cohernet with low (high)seismic wave velocities.  相似文献   

16.
Electromagnetic measurements have demonstrated that the lower continental crust has remarkable electrical anomalies of high conductivity and electrical anisotropy on a global scale (probably with some local exceptions), but their origin is a long-standing and controversial problem. Typical electrical properties of the lower continental crust include: (1) the electrical conductivity is usually 10−4 to 10−1 S/m; (2) the overlying shallow crust and underlying upper mantle are in most cases less conductive; (3) the electrical conductivity is statistically much higher in Phanerozoic than in Precambrian areas; (4) horizontal anisotropy has been resolved in many areas; and (5) in some regions there appear to be correlations between high electrical conductivity and other physical properties such as seismic reflections. The explanation based on conduction by interconnected, highly conductive phases such as fluids, melts, or graphite films in grain boundary zones has various problems in accounting for geophysically resolved electrical conductivity and other chemical and physical properties of the lower crust. The lower continental crust is dominated by mafic granulites (in particular beneath stable regions), with nominally anhydrous clinopyroxene, orthopyroxene, and plagioclase as the main assemblages, and the prevailing temperatures are mostly 700–1,000°C as estimated from xenolith data, surface heat flow, and seismic imaging. Pyroxenes have significantly higher Fe content in the lower crust than in the upper mantle (peridotites), and plagioclase has higher Na content in the lower crust than in the shallow crust (granites). Minerals in the lower continental crust generally contain trace amounts of water as H-related point defects, from less than 100 to more than 1,000 ppm H2O (by weight), with concentrations usually higher than those in the upper mantle. Observations of xenolith granulites captured by volcano-related eruptions indicate that the lower continental crust is characterized by alternating pyroxene-rich and plagioclase-rich layers. Experimental studies on typical lower crustal minerals have shown that their electrical conductivity can be significantly enhanced by the higher contents of Fe (for pyroxenes), Na (for plagioclase), and water (for all minerals) at thermodynamic conditions corresponding to the lower continental crust, e.g., to levels comparable to those measured by geophysical field surveys. Preferred orientation of hydrous plagioclase, e.g., due to ductile flow in the deep crust, and alternating mineral fabrics of pyroxene-rich and plagioclase-rich layers can lead to substantial anisotropy of electrical conductivity. Electrical conductivity properties in many regions of the lower continental crust, especially beneath stable areas, can mostly be accounted for by solid-state conduction due to the major constituents; other special, additional conduction mechanisms due to grain boundary phases are not strictly necessary.  相似文献   

17.
Summary Temperature and conductivity measurements show, that in the Southern part of Transdanubia (the part of Hungary which lies Westwards from Danube) the heat flow is about 2–2.4·10–6 cal/cm2 sec. Eastward from the Danube, in the Hungarian Plain estimates are even higher, and vary between 2.3·10–6 and 2.8·10–6 cgs. The gradient of temperature is everywhere quite high, 5.0 resp. 5.8·10–4 deg. C/cm on the average. Thus, at a depth of 1000 m, the virgin rock temperature is about 60–70 deg. C, at 2000 m about 110–130 deg. C.  相似文献   

18.
19.
Laboratory Electrical Conductivity Measurement of Mantle Minerals   总被引:4,自引:1,他引:3  
Electrical conductivity structures of the Earth’s mantle estimated from the magnetotelluric and geomagnetic deep sounding methods generally show increase of conductivity from 10−4–10−2 to 100 S/m with increasing depth to the top of the lower mantle. Although conductivity does not vary significantly in the lower mantle, the possible existence of a highly conductive layer has been proposed at the base of the lower mantle from geophysical modeling. The electrical properties of mantle rocks are controlled by thermodynamic parameters such as pressure, temperature and chemistry of the main constituent minerals. Laboratory electrical conductivity measurements of mantle minerals have been conducted under high pressure and high temperature conditions using solid medium high-pressure apparatus. To distinguish several charge transport mechanisms in mantle minerals, it is necessary to measure the electrical conductivity in a wider temperature range. Although the correspondence of data has not been yet established between each laboratory, an outline tendency of electrical conductivity of the mantle minerals is almost the same. Most of mineral phases forming the Earth’s mantle exhibit semiconductive behavior. Dominant conduction mechanism is small polaron conduction (electron hole hopping between ferrous and ferric iron), if these minerals contain iron. The phase transition olivine to high-pressure phases enhances the conductivity due to structural changes. As a result, electrical conductivity increases in order of olivine, wadsleyite and ringwoodite along the adiabat geotherm. The phase transition to post-spinel at the 660 km discontinuity further can enhance the conductivity. In the lower mantle, the conductivity once might decrease in the middle of the lower mantle due to the iron spin transition and then abruptly increase at the condition of the D″ layer. The impurities in the mantle minerals strongly control the formation, number and mobility of charge carriers. Hydrogen in nominally anhydrous minerals such as olivine and high-pressure polymorphs can enhance the conductivity by the proton conduction. However, proton conduction has lower activation enthalpy compared with small polaron conduction, a contribution of proton conduction becomes smaller at high temperatures, corresponding to the mantle condition. Rather high iron content in mantle minerals largely enhances the conductivity of the mantle. This review focuses on a compilation of fairly new advances in experimental laboratory work together with their explanation.  相似文献   

20.
A technique has been developed to determine attenuation in rocks at high temperature using a gas-media, high-pressure apparatus. A pulse transmission technique and a spectral ratio method are used to study compressional seismic properties of rocks. Seismic waves are transmitted to and from the sample through buffer rods of mullite. The effect of seismic wave reflections within the sample assembly are cancelled out by taking ratios of the spectra measured at different temperatures. In order to obtain good signal-to-noise ratio for resolving the attenuation at high pressure and temperature, special care is taken in the sample assembly and the ultrasonic coupling between the sample, buffer rods and transducers. A very tight connection of the sample-buffer rod-transducer is essential for obtaining high frequency signals (>300 kHz) at high temperature. A small mass is attached to each outside end of the transducer to drive low frequency signals (<250 kHz) into the sample. Before attenuation measurements, the sample and the buffer rods are tightly compacted in a platinum tube at high pressure and room temperature to ensure pressure seal of the sample assembly. The frequency range of measurement covers 50 to 450 kHz for the sample. Attenuation is very small in the buffer rod compared to the sample for the entire temperature range of the study. Because of the small attenuation, a wide frequency band of 50 kHz to 3.2 MHz can be covered for investigating the attenuation in the buffer rod. The technique has been used to measure attenuation at high confining pressure, and temperatures including sub- and hyper-solidus of upper mantle rocks. Therefore, effects of partial melting on attenuation can be studied.The method is applied to the attenuation measurement in a peridotite as a function of temperature to 1225°C at 200 MPa confining pressure. At high temperature, signal amplitude decays more rapidly at high frequency than at low frequency, from which attenuation (andQ) can be determined using a spectral ratio method. No frequency dependence ofQ is resolved for both the sample and the buffer rod over the entire temperature and frequency ranges of the measurement. The results show thatQ decreases rapidly with increasing temperature even in the temperature range below the solidus of peridotites. Such temperature sensitivity ofQ is probably more useful to probe thermal structure in the upper mantle than that of conductivity at temperatures below the solidus. The results in this study are compared with available seismic velocity, electrical conductivity and solidus data for peridotites, suggesting that there is no discontinuous change in both mechanical and electrical properties of peridotites at the solidus temperature. Even at hypersolidus temperatures, it appears that velocity drops and conductivity increases continuously (not abruptly) with increasing melt fraction. This implies that mechanical and electrical properties of the upper mantle will gradually change at the boundary where the geotherm crosses the solidus.  相似文献   

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