Residence of REE, Y, Th and U in Granites and Crustal Protoliths; Implications for the Chemistry of Crustal Melts

A systematic study with laser ablation—ICP-MS, scanningelectron microscopy and electron microprobe revealed that 70–95wt% of REE (except Eu), Y, Th and U in granite rocks and crustalprotoliths reside within REEYThU-rich accessories whose nature,composition and associations change with the rock aluminosity.The accessory assemblage of peraluminous granites, migmatitesand high-grade rocks is composed of monazite, xenotime (in low-Cavarieties), apatite, zircon, Thorthosilicate, uraninite andbetafite-pyrochlore. Metaluminous granites have allanite, sphene,apatite, zircon, monazite and Thorthosilicaie. Peralkaline graniteshave aeschinite, fergusonite, samarskite, bastnaesite, fluocerite,allanite, sphene, zircon, monazite, xenotime and Th-orthosilicate.Granulite-grade garnets are enriched in Nd and Sm by no lessthan one order of magnitude with respect to amphibolite-gradegarnets. Granulitegrade feldspars are also enriched in LREEwith respect to amphibolite-grade feldspars. Accessories causenon-Henrian behaviour of REE, Y, Th and U during melt—solidpartitioning. Because elevated fractions of monazite, xenotimeand zircon in common migmatites are included within major minerals,their behaviour during anatexis is controlled by that of theirhost. Settling curves calculated for a convecting magma showthat accessories are too small to settle appreciably, beingseparated from the melt as inclusions within larger minerals.Biotite has the greatest tendency to include accessories, therebyindirectly controlling the geochemistry of REE, Y, Th and U.We conclude that REE, Y, Th and U are unsuitable for petrogeneticalmodelling of granitoids through equilibrium-based trace-elementfractionation equations. KEY WORDS: accessory minerals; geochemical modelling; granitoids; REE, Y, Th, U     

Granulite-Facies Metamorphism and Crustal Magmatism in the Ashuanipi Complex, Quebec--Labrador, Canada

The high-grade Archean Ashuanipi complex contains an older sequenceof granulite-facies migmatitic paragneiss and tonalite cut byabundant orthopyroxene-bearing, enclave-laden granitoid bodies(diatexite) of strongly peraluminous (garnet-bearing) and mildlyperaluminous (garnet—absent) granodioritic composition,inferred to be magmatic in origin. Temperature estimates forgarnet–orthopyroxene–biotite–plagioclase–quartzassemblages in both metamorphic and igneous rock types are mainlyin the range 700– 835 ?C, but apparent pressures are higher(0?6–0?65 GPa) in a wide belt of paragneiss and associatedtonalite than in the enclosing diatexites (0?35–0?55 GPa),possibly owing to fluid-enhanced retrograde re-equilibrationwithin the crystallizing igneous assemblages. Paragneiss has bulk compositions typical of Archean greywacke(58–68 wt. % SiO₂), including high Cr (110–250 ppm),Ni (20–100 ppm), and LREE [(70–100) ?chondrites].Garnet-bearing diatexites have compositions virtually identicalto paragneiss whereas garnet-absent diatexites are characterizedby marked HREE depletion. High degrees of fusion of a sourcesuch as paragneiss, with entrainment of crystalline phases suchas garnet and orthopyroxene, are required to explain the compositionof garnet-bearing diatexites, whereas lower amounts of melting,leaving residual garnet, may account for the origin of the garnet-absentvarieties. CO2 may have been a melt component in diatexite, based on severalobservations: (l)the high degrees of fusion implied in the genesisof diatexite require either extreme temperatures (> 1000?C)for which there is no mineralogical evidence, or some fluxingagent other than H₂O (cf. Peterson & Newton, 1990); (2)some xenoliths have orthopyroxene-rich (dehydration) margins,implying relatively anhydrous melt conditions; and (3) orthopyroxeneis unaltered, suggesting that low aH₂O conditions persistedduring crystallization. U–Pb zircon geochronology constrains the time for heatingand magma production to <18 Ma (2700 Ma for detrital zirconin paragneiss; 2682 Ma for crystallization of igneous zirconin diatexite). Combined with the evidence for high crustal temperaturesand possible CO₂ involvement, the rapid heating implies thatunderplated basaltic magmas played a key role as heat and fluidsources driving high-grade metamorphism and granitoid melt production.     

Thermobarometry, Geochronology and the Interpretation of P-T-t Data in the Britt Domain, Ontario Grenville Orogen, Canada

Textural evidence, thermobarometry, and geochronology were usedto constrain the pressure-temperature-time (P—T—t)history of the southern portion of the Britt domain in the CentralGneiss Belt, Ontario Grenville Province. Typical metapeliticassemblages are quartz+plagioclase+ biotite + garnet + kyanite alkali feldspar sillimanite rutile ilmenite staurolite gahnite muscovite. Metatonalitic assemblages have quartz+ plagioclase + garnet biotite + hornblende + rutile + ilmenite.Metagabbroic rocks contain plagioclase + garnet + clinopyroxene+ biotite + ilmenite hornblende rutile quartz. Notabletextural features include overgrowths of sillimanite on kyaniteand of spinel on staurolite. The spinel overgrowths can be modeledby the breakdown of staurolite via the reaction Fe-staurolite= hercynite +kyanite + quartz + H₂O. The decomposition of stauroliteto her-cynite has a steep dP/dT slope and constrains the lateprograde path of a staurolite metapelite. Garnet—Al₂SiO₅—plagioclase—quartz(GASP) barometry applied to metapelitic garnets that preservecalcium zoning reveals a pressure decrease from 11 to 6 kbat an assumed temperature of 700 C. Garnet—plagioclase—ilmenite—rutile—quartzand garnet—clinopyroxene—plagioclase—quartzbarometry is in good agreement with pressures obtained withthe GASP barometer. Geochronologic data from garnet, allanite,and monazite in metapelitic rocks give ages that fall into twogroups, 1–4 Ga and 1.1 Ga, suggesting the presence ofat least two metamorphic events in the area. It is most reasonableto assign the 1.4 Ga age to the high-pressure data and the 1.1Ga age to the lower-pressure data. Collectively the P—T—tdata indicate a complex and protracted history rather than asingle cycle of burial and uplift for this part of the GrenvilleProvince.     

Petrology and Petrogenesis of the Monchique Alkaline Complex, Southern Portugal

Monchique is a sizeable subvolcanic ?laccolith, unusual amongalkaline complexes in invading sediments and lacking apparentconnection with either rifting or orogeny; it may however relateto the opening of the North Atlantic(age = 76 m.y.). The intrusionis predominantly miaskitic syenite, varying irregularly fromfoyaite to pulaskite with fine-grained nepheline-poor marginsbut showing no rhythmic or cryptic layering. Minor rock-typesinclude early masses of olivine-free kaersutite—theralites(berondrites) and essexites, bodies of igneous breccias, maligniteand agpaite, veins of foyaite—pegmatite and shonkinite,and dykes of lamprophyres and peralkaline tinguaite. Coevaldykes outside the main intrusion include quartz—trachytes,normal (olivine-bearing) basanites and amphibole—picrites. The whole suite may have derived from a basanitic parent undermoderately oxidizing conditions. Geochemistry is apparentlycontinuous along the trend Berondrite—Essexite—Foyaite(Malignite)—Pulaskite—Quartz trachyte. As far asFoyaite this parallels the normal oceanic basanite—phonolitetrend with major and trace elements and minerals (except olivine)behaving as in normal fractionation; the absence of nepheline—monzonites,creating a Daly Gap, may merely reflect high fractionation efficiency.The apparent evolution across the thermal barrier in Ne—Ks—Qtz,with a reversal in some major element trends, however, can beexplained neither by fractionation nor country-rock assimilation.The enigmatic pulaskites cannot be related directly to the foyaitesbut might have formed from the same parent under lower pressureconditions; they themselves fractionated to the peralkalinetinguaites. The quartz—trachytes probably originated wherefoyaite magmas lost alkalis to the siliceous country-rocks,became oversaturated, and then fractionated feldspars. Liquidimmiscibility might explain some anomalous monzonitic rocksbut otherwise contributed little to the evolution of the complex.     

An EMP and TEM--AEM Study of Margarite, Muscovite and Paragonite in Polymetamorphic Metabauxites of Naxos Cyclades, Greece) and the Implications of Fine-scale Mica Interlayering and Multiple Mica Generations

Coexisting white micas and plagioclase were studied by electronmicroprobe (EMP), and transmission and analytical electron microscopy(TEM—AEM) in greenschist- to amphibolite-grade metabauxitesfrom Naxos. The TEM—AEM studies indicate that sub-micronscale (0.01–1.0 µm thick) semicoherent intergrowthsof margarite, paragonite and muscovite are common up to loweramphibolite conditions. If unrecognized, such small-scale micainterlayering can easily lead to incorrect interpretation ofEMP data. Muscovite and paragonite in M₂ greenschist-grade Naxosrocks are mainly relics of an earlier high-pressure metamorphism(M₁). Owing to the medium-pressure M₂ event, margante occursin middle greenschist-grade metabauxites and gradually is replacedby plagioclase + corundum in amphibolite-grade metabauxites.The margarite displays minor ^IVAl_{3 VI}(Fe³⁺, Al) Si_-3 ^VI-_-1 andconsiderable (Na, K) SiCa_-1Al_-1 substitution, resulting in upto 44 mol% paragonite and 6 mol % muscovite in solution. Thecompositional variation of muscovite is mainly described by^VI(Fe²⁺, Mg) Si ^VI Al_-1^VI Al_-1 and _VI(Fe₃₊Al^-1) exchanges, thelatter becoming dominant at amphibolite grade, Muscovite issignificantly richer in Fe than margarite or paragonite. Ca—Na—Kpartitioning data indicate that margarite commonly has a significantlyhigher Na/(Na+ K+Ca) value than coexisting muscovite or plagioclase.Exceptions are found in several greenschist-grade rocks, inwhich M₁-formed mussovite may have failed to equilibrate withM₂ margarite. The sluggishness of K-rich micas to recrystallizeand adjust composidonally to changing P-T conditions is alsoreflected in the results of mus-covite-paragonite solvus thermometry.Chemical data for Ca—Na micas from this study and literaturedata indicate that naturally coexisting margarite—paragonitepairs display considerably less mutual solubility than suggestedby experimental work. The variable and irregular Na partitioningbetween margarite and muscovite as observed in many metamorphicrocks could largely be related to opposing effects of pressureon Na solubility in margarite and paragonite and/or non-equilibriumbetween micas. KEY WORDS: Ca—Na—K mica; margarite; metabauxite; Naxos; sub-micron-scale mica interlayering     

Pressure-Temperature Path Recorded in the Yangkou Garnet Peridotite, in Su-Lu Ultrahigh-pressure Metamorphic Belt, Eastern China

Chemical variations along with changes in microstructure ofthe principal constituent minerals make it possible to identifyat least four equilibrium stages in the evolution of the Yangkougarnet peridotite in the Su-Lu ultrahigh-pressure metamorphicbelt, eastern China: Stage I—a primary garnet lherzolitestage represented by coarse-grained (a few millimeters size)porphyroclastic aluminous pyroxenes + chromian spinel ±garnet; Stage II—an ultrahigh-pressure (UHP) stage definedby fine-grained matrix phases (0·1–0·3 mmsize) of garnet + extremely low-Al orthopyroxene + high-Na clinopyroxene+ chromite; Stage III—a medium-pressure stage definedby fine-grained mineral aggregates (<0·1–0·2mm size) mainly composed of aluminous spinel + high-Al orthopyroxenein the matrix; Stage IV—an amphibolite- to greenschist-faciesstage defined by poikiloblastic amphibole. Orthopyroxene–clinopyroxenethermometry and an empirical spinel barometer give temperaturesof around 800–830°C and pressures of 1·2–2·9GPa for porphyroclasts of Stage I. Garnet–orthopyroxene,garnet–clinopyroxene and empirical spinel geothermobarometersgive relatively uniform P–T conditions for the matrixgarnet–orthopyroxene–clinopyroxene–chromiteassemblage of Stage II (     

Dissolution of Quartz, Albite, and Orthoclase in H2O-Saturated Haplogranitic Melt at 800{degrees}C and 200 MPa: Diffusive Transport Properties of Granitic Melts at Crustal Anatectic Conditions

We have conducted experiments on dissolution of quartz, albite,orthoclase, and corundum into H₂O-saturated haplogranite meltat 800°C and 200 MPa over a duration of 120–1488 hwith the aim of ascertaining the diffusive transport propertiesof granitic melts at crustal anatectic temperatures. Cylindersof anhydrous starting glass and a single mineral phase (quartzor feldspar) were juxtaposed along flat and polished surfacesinside gold or platinum capsules with 10 wt % added H₂O. Concentrationprofiles in glass (quenched melt) perpendicular to the mineral–glassinterfaces and comparison with relevant phase diagrams suggestthat melts at the interface are saturated in the dissolvingphases after 384 h, and with longer durations the concentrationprofiles are controlled only by diffusion of components in themelt. The evolution of the concentration profiles with timeindicates that uncoupled diffusion in the melt takes place alongthe following four linearly independent directions in oxidecomposition space: SiO₂, Na₂O, and K₂O axes (Si-, Na-, and K-eigenvectors,respectively), and a direction between the Al₂O₃, Na₂O, andK₂O axes (Al-eigenvector), such that the Al/Na molar ratio isequal to that of the bulk melt and the Al/(Na + K) molar ratiois equal to the equilibrium ASI (= mol. Al₂O₃/[Na₂O + K₂O])of the melt. Experiments in which a glass cylinder was sandwichedbetween two mineral cylinders—quartz and albite, quartzand K-feldspar, or albite and corundum—tested the validityof the inferred directions of uncoupled diffusion and exploredlong-range chemical communication in the melt via chemical potentialgradients. The application of available solutions to the diffusionequations for the experimental quartz and feldspar dissolutiondata provides diffusivities along the directions of the Si-eigenvectorand Al-eigenvector of (2·0–2·8) x 10^–15m²/s and (0·6–2·4) x 10^–14 m²/s, respectively.Minimum diffusivities of alkalis [(3–9) x 10^–11m²/s] are orders of magnitude greater than the tetrahedral componentsof the melt. The information provided here determines the rateat which crustal anatexis can occur when sufficient heat issupplied and diffusion is the only mass transport (mixing) processin the melt. The calculated diffusivities imply that a quartzo-feldspathicsource rock with initial grain size of 2–3 mm undergoinghydrostatic, H₂O-saturated melting at 800°C (infinite heatsupply) could produce 20–30 vol. % of homogeneous meltin less than 1–10 years. Slower diffusion in H₂O-undersaturatedmelts will increase this time frame. KEY WORDS: chemical diffusion; haplogranite; mineral dissolution experiments; crustal anatexis     

Synthesis and Stability Relations of Mg--Al Pumpellyite, Ca4Al5MgSi6O21(OH)7

Hydrothermal synthesis and investigations of stability relationsof Mg—Al pumpellyite were conducted using high-pressurecold-seal apparatus over the temperature range 250–600°C and 2–8 kb P_fluid. Mg—Al pumpellyite Ca₄Al₅MgSi₆O₂₁(OH)₇was synthesized from partially crystalline gel mixtures of stoichiometriccomposition at 275–410 °C, 6–9 kb P_fluid, andruns of 7–90 days. Pure monomineralic synthetic Mg—Alpumpellyite has refractive index n_ß = 1.624 (2) andcell dimensions = 8.825 (8) Á, b = 5.875 (5) Á,c = 19.10 (1) Á, and ß = 97.39 (7)°. The high temperature assemblage of the equivalent bulk compositionconsists of clinozoisite, hydrogrossular/grossular, aluminousseptechlorite/chlorite, quartz, and H₂O. Hydrogrossular wassynthesized in the presence of quartz at 8 kb from 400–500°C, and hydrogrossular + quartz are unstable with respectto grossular + H₂O at 400 °C and 8 kb P_fluid. At 8 kb P_fluid,aluminous septechlorite forms at temperatures below 500 °Cwhereas aluminous 14 Á chlorite crystallizes at 500–600°C. The equilibrium relations of Mg—Al pumpellyite were determinedusing subequal mixtures of synthetic Mg—Al pumpellyiteand its high temperature assemblage. The reaction 9 Mg—Alpumpellyite = 9 clinozoisite + 6 grossular + 2 chlorite + 4quartz + 19 H₂O occurs at temperatures of 390 °C at 8 kb,368 °C at 5 kb, and near 325 °C at 2 kb P_fluid. Thereversal data yield an approximate value of –3141 joules/mole°K for the standard entropy of formation for the syntheticMg—Al pumpellyite. The Schreinemakers' relations for pumpellyite, prehnite, clinozoisite,tremolite, grossular, and amesite in the presence of excessquartz and fluid were constructed in the pseudo-ternary systemCaO–Al₂O₃–MgO(SiO₂–H₂O). The results, togetherwith reconnaissance experiments on the reaction 4 Mg—Alpumpellyite + 2 quartz = 8 prehnite + aluminous septechlorite+ 2 H₂O, locate the invariant point [TR] at approximately 5.7kb P_fluid and 375 °C. The results of the present study arenot compatible with previous experimental data on the invariantpoint [GR]. The P–T oriented phase relations are used to interpretsome natural parageneses developed in low-grade metabasalticrocks recrystallized under conditions of low _co2. The high-temperaturestability relations of Mg—Al pumpellyite are useful todenote the onset of greenschist facies metamorphism in rocksof basaltic composition.     

(Ruby--Sapphire)--Chromian Mica--Tourmaline Rocks from Westland, New Zealand

Boulders of the assemblage ruby—sapphire corundum, chromianmuscovite, margarite, tourmaline (chromian chlorite, Zn—Mnchromite and Mn—Ti magnetite) occur in glacial moraineand rivers of north Westland, South Island of New Zealand. Thelocation, Cr-rich composition of the boulders and the presenceof rare serpentinite rinds indicate that they are derived fromultramafic rocks (Pounamu Ultramafics) that occur within AlpineSchist of the Southern Alps. The largest sample is progressivelyzoned outwards from a corundum—margarite core, throughan intermediate zone of Cr-muscovite, to an outer zone of Cr-chloritethat is in contact with serpentinite. Most finds consist oferosion-resistant corundum-rich cores. In the corundum, Cr₂O₃content ranges from 0.5 to 13%, with red coloration becomingmore intense with increasing Cr. In addition to the dominantCr³⁺ Al³⁺ substitution, those of (Fe, V)³⁺ Cr³⁺ and (Ti⁴⁺+Fe²⁺) 2Cr³⁺ result in spectacular colour zoning from colourlessto deep ruby red-carmine and pale blue to dark blue—violet.Corundum has grown by replacement of the micaceous matrix thatconsists of chromian muscovite (0.10–4.10% Cr₂O₃) andchromian margarite (0.46–1.20% Cr₂O₃). Both micas containa significant paragonite component (up to 21.5% in muscoviteand up to 40.8% in margarite). Late phase muscovite is Ba richwith up to 4.77% BaO, and margarite has up to 0.66% SrO. Tourmalineoccurs as veins, vein outgrowths and larger poikilitic crystalsthat replace the mica matrix. Chromium content ranges between0.82 and 3.6% Cr₂O₃. High bulk rock Al (up to 78% Al₂O₃), K,Ca, Cr and Na, and low Si (14.5–23.1% SiO₂), suggest thatthe corundum—Cr-silicate rocks are the products of extrememetasomatic alteration of quartzofeldspathic schist enclavesin serpentinite. Isocon analysis indicates that conversion ofthe schist to the micaceous matrix of the corundum rocks involvesconservation of Ca, Al, K, volatiles and Sr, a mass loss of59% and a volume reduction of 69% consequent on removal of 70–80%Si and all other elements (most >80%), with enrichment ofbetween 900 and 1800% Cr. The formation of corundum from themica matrix involved a further mass—volume reduction anddecrements in Si, Ca, K, volatiles and Sr from reaction sites.Concentric mineral zonation in single rock samples and zoning—replacementin minerals, e.g. Cr in corundum and chromite, Ti, Fe²⁺ in corundum,Ba in muscovite, Sr in margarite, and Mn and Zn in chromiteand magnetite, imply element redistribution during metasomatism.Experimental reaction between quartzofeldspathic schist andserpentinite at 450C and 2 kbar produced reaction sequencescontaining newly formed Ca-plagioclase—phlogopitic micachloriteand muscovite—chlorite that in terms of composition areanalogous with the observed (corundum—margarite)—muscovite—chloritezonation. The temperature of metamorphism of garnet zone rocks(45020C) that contain the corundum—Cr-silicate rocksis well below that of the breakdown of muscovite and margariteto form corundum and indicates the importance of fluid composition,particularly the cation—hydrogen variables a_Ca²⁺/H⁺, aK⁺/H₊and a_S1O2. Introduction of boron into the schist (from serpentinite),and boron released from the breakdown of original tourmalinein the schist, resulted in tourmaline veining and reaction ofthe mica matrix to form tourmaline that invoved both a massand volume increase and addition of Fe, Mg together with B. KEY WORDS: corundum—Cr-silicate rocks; metasomatism; New Zealand; Southern Alps ^*Corresponding author.     

Mineralogic and Oxygen Isotopic Studies of Open System Magmatie Processes in the South Kawishiwi Intrusion, Spruce Road Area, Duluth Complex, Minnesota

The South Kawishiwi intrusion, located along the western marginof the Duluth Complex, Minnesota, is one of several compositeintrusions that are found in the Complex. The Duluth Complexis the principal exposed plutonic portion of the 1.1 Ga MidcontineniRift system. In the Spruce Road area the South Kawishiwi intrusionis divided into seven distinct units that are part of the broaderSouth Kawishiwi Troctolite Series defined by Severson (Tech.Rep. NRRI/TR-91/13a, Natural Resources Research Institute, Universityof Minnesota, Duluth, 1994). Units may be characterized as follows:Unit I—basal accumulation of heterogeneous gabbro, troctolite,and norite; Unit II—norite with abundant inverted pigeonite;Unit III—troctolite and olivine gabbro with local oxide-richlayers; Unit IV—mlatroctolite, troctolite, olivine gabbro;Unit VI—increased plagioclase abundance in troctolitesand leucocratic troctolites; Unit VI—strongly alteredtroctolite; Unit VII—similar to Unit V, troctolite andleucocratic troctolite. Country rocks in the Spruce Road areaare granodiorite to quartz monzonite of the Archean Giants RangeBatholith. Sutfide mineralization, consisting of 1–5 vol.% of disseminated pyrrhotitt, cubanite, chalcopyrite and pentlandite,occurs in Units I, II, III, and VI. Oxygen isotopic analysesindicate that Unit II has experienced extensive crustal contamination.¹⁸O values of Unit II range from 6.9 to 7.1% and are ¹⁸O enrichedcompared with values of 5.1–6.8% found in other units.Silica contamination is indicated based not only on ¹⁸O values,but also by the predominance of orthopyroxene in the unit. Possiblehigh-¹⁸O contaminant rocks include the Giants Range Batholithand pelitic rocks of the Lower Proterozoic Virginia Formationor Biwabik Iron Formation. Mass balance computations suggestthat units in the Spruce Road area may be related through varyingdegrees of fractionation of a high-Al, olivine tholeiite magma.Modeling of trace element concentrations and variations in mineralchemistry suggest that discontinuities within the major unitsdeveloped by in situ boundary-layer equilibrium crystallizationof solidification zones 20–50 m in thickness, followedby recharge of fresh magma. Upward enrichment of incompatibleelements, olivine Fa content, and plagioclase Ab content maybe effectively explained by this process. ¹⁸O values of uncontaminatedrock types are strongly correlative with modal mineralogy, andcan also be modeled by boundary-layer fractionation, A parentalmagma ¹⁸ O value of 6.3% is calculated for Unit VII based onolivine and plagioclase values, and is similar to that of severalother large, layered mafic intrusives. KEY WORDS: Duluth Complex; South Kawishiwi Intrusion; high-Al olivine tholeiite; open system crystallization; oxygen isotopes ^* Present address: Korea Basic Science Center, Isotope Research Group, Yeocun Dong 224–1, Yusung Ku, Yusung P.O. Box 41, Taejean 305–333, Korea     

Dunite--Harzburgite--Chromitite Complexes as Refractory Residue in the Sangun--Yamaguchi Zone, Western Japan

Dunite, harzburgite and chromitite of alpine-type ultramaficcomplexes emplaced in the Paleozoic sediments in the Sangun—Yamaguchizone, western Japan, are massive and almost lacking in layeredstructure. Constituent minerals are more or less deformed andequilibrated at a relatively low temperature, about 700 °Cor lower. Chromian spinels in ultramafic rocks from dunite—harzburgite—chromititecomplexes in the Sangun—Yamaguchi zone are characterizedby the uniformity of the Cr/Cr + Al ratio, around 0.5, regardlessof locality and rock type, which is in contrast to the widevariation of the ratio of chromian spinel from the ordinaryalpine-type dunite—harzburgite complex. Mg/Mg + Fe" ratioof chromian spinel, on the other hand, is variable in parallelto the volume per cent of chromian spinel in ultramafic rocks.Olivine in ultramafic rocks is uniform in chemical composition,from Fo₈₈ to Fo₉₂, except for that in chromitite, of which itis Fo₉₅ to Fo₉₇. Primary chemical compositions (especially the Mg/Mg + Fe" ratio)of the constituent minerals have been modified to some extentby element redistribution at low temperature (700 °C orlower), the degree of modification depending on the volume ratioof the minerals. For example, the Mg/Mg + Fe" ratio of chromianspinel in peridotitic rocks has been lowered substantially,and inversely, that of olivine in chromitite has been raised.Primary Mg/Mg + Fe" ratios of olivine and chromian spinel canbe estimated, assuming a certain value of high temperature,e.g. 1200 °C, and the partition coefficient between olivineand chromian spinel at that temperature. As a result, the Mg/Mg+ Fe" ratio of olivine (0.88 to 0.92), and that of chromianspinel (0.78 to 0.80) were uniform, irrespective of rock typeand locality, at the high-temperature stage. Dunite—harzburgite—chromitite complexes in the Sangun—Yamaguchizone were accumulated as refractory residue after the relativelylarge-scaled partial fusion of some primordial peridotites,which resulted in the chemical uniformity of the residual minerals.They may have initially constituted the lowest part of an ophioliticsuite as ultramafic tectonite and been emplaced as dismemberedportions after the disruption of the parent body.     

Resolving Sediment Subduction and Crustal Contamination in the Lesser Antilles Island Arc: a Combined He-O-Sr Isotope Approach

We report an extensive helium isotope survey of basaltic toandesitic lavas from the Lesser Antilles island arc—anarc system with well-documented evidence of crustal contamination.Given the sensitivity of helium isotopes as a tracer of theeffects of crustal additions, our aim is to evaluate the relationshipof ³He/⁴He ratios to other indices of contamination processessuch as oxygen and strontium isotopes. To this end, we havecarried out 53 ³He/⁴He analyses on separated minerals (olivinesand pyroxenes) from throughout the arc, which we compare withwhole-rock strontium and phenocryst oxygen isotope measurements.We show that the three isotopic tracers show coherent patternsthroughout the Lesser Antilles, indicating a regional controlon crustal contamination. The southern section of the arc (Grenadato Martinique) shows clear evidence for major crustal contaminationin all three isotopic systems with results for our samples inthe range ³He/⁴He_(olivine) 3·6–7·6R_A,     

The Formation of Chrysoberyl in Metamorphosed Pegmatites

Mineral assemblages in pegmatite samples from Kolsva, Swedenand Marikov, Czechoslovakia show that chrysoberyl is alwaysaccompanied by quartz, and is a breakdown product of primarypegmatitic beryl. Textures and the mineral-forming process forthe Kolsva pegmatite are explained by the reactions beryl +K-feldspar + H+ = chrysoberyl + quartz + SiO_{2, aq} + K⁺ + H₂Oor alternatively beryl —K—feldspar + H₂O = chrysoberyl+ quartz + melt. Mineral assemblages from mica-rich parts ofthe pegmatite include sillimanite—K—feldspar, muscovite—K—feldspar—sillimanite,and annite—magnetite—spinel—sillimanite—garnet.Details about the composition and the textural relationshipsof these minerals are given; they indicate a post-pegmatiticmetamorphic event at P—T conditions near to the anatecticregime. The samples from Marikov show textures, which are explainedby the reactions beryl + albite + H⁺ = chrysoberyl + quartz+ Na⁺ + H₂O or alternatively beryl + albite + H₂O = chrysoberyl+ quartz + melt. Breakdown of muscovite produces sillimaniteaccording to the reactions beryl + albite + muscovite + H⁺ =chrysoberyl + quartz + sillimanite + Na⁺ + K⁺ + H₂O or alternativelyberyl + albite + muscovite + H₂O = chrysoberyl + quartz + sillimanite+ melt. Similar reaction textures and mineral assemblages were foundin other chrysoberyl-bearing pegmatites (Maroankora, Madagascar;Helsinki, Finland; Haddam, Greenfield, Greenwood, U.S.A.). Hydrothermal experiments located the reaction beryl + alkalifeldspar + H₂O = chrysoberyl + phenakite + melt at P—Tconditions between the K—feldspar—quartz—H₂Osolidus and the K—feldspar—albite—quartz-H₂Osolidus. It is concluded that the formation of Al-rich minerals likechrysoberyl and sillimanite in pegmatites is due to a post-pegmatiticevent at high P—T conditions. The question as to whichof the alternative set of reactions is more likely, the ionicequilibria or the anatectic chrysoberyl formation, must be leftopen. The previous hypothesis of a desilification of a pegmatitewhich intruded into SiO₂-poor country rocks, or of the assimilationof Al₂O₃-rich country rocks, cannot explain the mineral assemblagesof the two pegmatites.     

Palaeozoic Intraplate Crustal Anatexis in the Mount Painter Province, South Australia: Timing, Thermal Budgets and the Role of Crustal Heat Production

The effect of radiogenic heat production within the crust onthermal processes such as crustal anatexis is generally disregardedas bulk geochemical models suggest that crustal heat generationrates are too low to effect significant heating. However, theMount Painter Province in northern South Australia is characterizedby a total crustal contribution to surface heat flow of morethan twice the global average. The province is composed dominantlyof Proterozoic granites and granite gneisses with an area averageheat production of 16·1 µW/m³; individual lithologieshave heat production >60 µW/m³. These Proterozoic rocksare intruded by the British Empire Granite, a younger intrusivewhose origin has remained enigmatic. Isotope geochemistry suggestscrustal sources for the melt and it has a crystallization ageof 440–450 Ma, which places the setting >750 km inboardof the nearest active plate boundary zone at this time. Phaseequilibria calculations suggest that temperatures of at least720–750°C are required to produce the granite butthe intensity of crustal thickening during Palaeozoic deformation(12%) cannot account for these conditions. Here we describea model for the generation of the British Empire Granite inwhich the primary thermal perturbation for mid-crustal anatexiswas provided by the burial of the high heat-producing MountPainter basement rocks beneath the known thickness of Neoproterozoiccover sediments. The high heat-producing rocks at Mount Painterimply that the natural range and variability of crustal heatproduction is much greater than previously believed, with importantconsequences for our understanding of temperature-dependentcrustal processes including the exploitation of geothermal energyresources. KEY WORDS: geothermal energy; low-pressure anatexis; thermal conductivity; thermal regime     

Mineralogy and Petrology of the Gunflint Iron Formation, Minnesota-Ontario: Correlation of Compositional and Assemblage Variations at Low to Moderate Grade

Near the Ontario—Minnesota boundary, the middle Precambriansedimentary Gunflint Iron Formation has been contact metamorphosedby the Duluth Complex to the pyroxene hornfels facies. Threemetamorphic zones have been recognized based on mineralogicalchanges observed within the aureole; a fourth zone correspondsto essentially unmetamorphosed iron formation. Each zone maybe recognized by the dominant iron silicate present: zone 1—greenalitezone (unmetamorphosed), zone 2—minnesotaite zone (slightlymetamorphosed), zone 3—grunerite zone (moderately metamorphosed),zone4—ferrohypersthene zone (highly metamorphosed). Granule bearing cherty rocks of zone 2 are characterized bythe reduction of hematite to magnetite and reaction of greenaliteand siderite to minnesotaite ± magnetite. Relict texturesare well preserved in zone 2 and retrograde reactions are minimal.Grunerite first appears in banded slaty rocks of zone 3. ‘Slaty’grunerite formed principally by reaction between carbonate andstilpnomelane, while in cherty rocks grunerite formed by reactionbetween greenalite and silica. Original bulk chemical differencesbetween cherty and slaty iron formation is reflected by amphibolechemistry as shown by the higher Al content and lower Fe/Fe+ Mg ratio of slaty grunerite, and by the greater ahundanceof Na, Al-bearing amphiboles such as ferrotschermakite in slatyrocks. Hedenbergite and fayalite appear in the upper part ofzone 3; both formed by silication of carbonates and both arepartially retrograded to amphibole. Prograde grunerite-cummingtoniteis partially replaced by minnesotaite in cherty rocks of zones3 and 4. In zone 4, greenalite and siderite-bearing assemblagesreacted to ferrohypersthene, fayalite (±quartz), pigeoniteand grunerite-cummingtonite. Retrogradation is widespread andresulted mainly in the formation of grunerite. Primary textureswere destroyed in slaty rocks but are still recognizable incherty rocks. Preservation of sedimentary textures within the contact aureoleis a characteristic feature of cherty rocks. In zone l theserocks typically consist of the following textural-mineralogicalassociation: granules (greenalite, quartz, hematite), cement(quartz, siderite, ankerite, calcite) and mottles (various carbonates).Retention of these textural elements, combined with compositionaldata for assemblages in the low to moderate grade rocks, enablesidentification of numerous metamorphic reactions. In the absenceof relict phases or relict textures sedimentary assemblagescan sometimes be inferred from abundances of minor elementssuch as Al and Mn. In some slaty rocks the presence of carbonaceous or graphiticmaterial has preserved perfectly premetamorphic structures suchas siderite spherules and ankerite rhombs, enabling the recognitionof several amphibole-forming reactions. Chemographic analysis of simplified subsystems for cherty rocksof zone 1, zone 2, and the lower part of zone 3, are consistentwith observed assemblages and reactions.     

Using Quantitative Textural Analysis to Understand the Emplacement of Shallow-Level Rhyolitic Laccoliths--a Case Study from the Halle Volcanic Complex, Germany

In qualitatively homogeneous magmatic bodies, quantitative texturalanalysis—such as crystal size distribution, modal abundance,and spatial distribution pattern analyses—allows theirinternal heterogeneity to be measured and interpreted. In thisstudy, these methods are applied to samples from a 300 m drillcore through one of the porphyritic rhyolitic laccoliths (Petersbergunit) of the     

Caledonian Magma Genesis and Crustal Recycling

The isotopic compositions of Sr, Nd, Pb and O together withabundance data for Rb, Sr, Sm, Nd, U and Pb are reported forsamples from the component parts of the c. 400 Ma old EtiveComplex, temporally and spatially related Lorne and Glencoelavas, and the Dalradian country rocks into which the Complexhas been emplaced. These and published data available for otherCaledonian granites are used to evaluate the petrogenesis ofthe Etive Complex in particular, and the role of crustal recyclingin the generation and evolution of the Caledonian granites ingeneral. Nd-isotope compositions of Etive samples at 400 Ma range from – 9.9 to – 4.7 compared with–8.4 < – 3.2 for the associated volcanics investigated here, and an estimatedvalue for depleted mantle 400 Ma ago at approximately ? 7. Dalradiancountry rocks have – 23.4 < – 7.5 and two partially digested metasedimentaryxenoliths within the granite have values of –9. 3 and -4.0. Initial ⁸⁷Sr/ ⁸⁶Sr ratios forthe Etive Complex range from 0–7043 to 0–7079, whereasDalradian metasediment in the immediate vicinity of the granitehas an initial ratio of 0–726. Oxygen isotopes in theComplex have 7. 6 per mil <¹⁸O < 10.0 per mil, all inexcess of typical values of mantle oxygen and reflect a crustalcomponent. An upper limit of 25 per cent Dalradian assimilationis set by the Nd-Sr isotopic variations with the granites andxenoliths. The Etive complex parent magma prior to Dalradian xenolith assimilationis estimated to have values between – 10 and – 5. In order to satisfy the Srand Pb isotope composition, additional components from a deepersource within the lithosphere (lower crust or continental lithosphericmantle) with relatively unradiogenic Sr, Nd and Pb are required. The crustal residence ages of the Etive Complex average about1.5 Ga, similar to those of many other late and post-tectonicCaledonian granites. The generation of the Etive Complex andCaledonian granites in general has been dominated by recyclingof the continental lithosphere, rather than the addition ofnew material from asthenospheric sources.     

The Lower Zone of the Eastern Bushveld Complex in the Olifants River Trough

The Lower Zone of the Eastern Bushveld Complex in the OlifantsRiver Trough reaches 1584 m in thickness and is divisible intoBasal subzone, Lower Bronzitite, Harzburgite subzone, and UpperBronzitite. The Lower Zone is directly and conformably overlainby the Critical Zone; there is no break between the two. The principal cumulus minerals in the Lower Zone are bronziteand olivine. Chromite is an accessory cumulus mineral in peridotites,especially in the Harzburgite subzone, and cumulus plagioclaseoccurs in two thin units in the Basal subzone. Elsewhere plagioclase,with or without chromian augite, is postcumulus in origin. Electron microprobe analyses show that the range in En and Focontents of bronzite and olivine, respectively, is only a fewper cent over the entire rock sequence. Highest values of bothare found in the Harzburgite subzone. From modal and mineralanalyses the bulk composition of the Lower Zone (wt. per cent)is calculated as SiO₂—53.94, TiO₂—0.08, Cr₂O₃—0.55,V₂O₃—0.01, Al₂O₃—2.64, NiO—0.09, FeO (totalFe as FeO)—9.62, MnO—0.20, MgO—31.72, CaO—1.48,K₂O—0.1, Na₂O—0.13. This composition is unlike thatof any magma type, indicating that the Lower Zone is indeeda pile of crystal cumulates. From the data for the Lower Zone, together with available datafor the Critical, Main, and Upper Zones, the average MgO contentof the Eastern Bushveld Complex is calculated as about 13 percent, the Cr content as in excess of 1000 ppm. Even if the Complexformed from a single body of magma, the magma cannot have beentholeiitic, but rather olivine tholeiitic or picritic. An hypothesis of evolution of the Lower Zone is presented. Shiftsin total pressure are inferred to have been a major factor inproducing the succession of rock types and in producing theextraordinarily persistent chromitites of the overlying CriticalZone. It is suggested that the extraordinary richness in chromiteof the Bushveld is related to its formation not from tholeiiticmagma, but from more Mg-rich, chromium-rich magma drawn froma deeper level of the mantle than that which has yielded thetholeiitic basalts.     

Igneous nepheline-bearing rocks of the Haliburton-Bancroft province of Ontario

Assemblages of magmatic origin—hypersolvus nepheline syenites,theralites, and theralitic canadites—developed in a beltof nepheline rocks extending through Monmouth and Glamorgantownships of Haliburton County, Ontario, are described and theirsignificance in the problems of origin of the Haliburton–Bancroftalkali province briefly disocussed.     

The Origin and Significance of Garnet Phenocrysts and Garnet-Bearing Xenoliths in Miocene Calc-alkaline Volcanics from Northland, New Zealand

Xenoliths, considered to be of igneous origin and consistingof hornblendegarnetplagioclase clinopyroxene, occur in associationwith high-pressure phenocrysts in early Miocene high-silicaandesites and dacites, Northland, New Zealand. Microstructuresof these xenoliths range from coarse, even-grained sub-ophitictypes to others with coarse glomerocrysts set in a finer-grainedmesostasis. The xenoliths are commonly flow-banded and are arguedto represent direct crystallization products and crystal aggregationsfrom the calc-alkaline host or related magmas at depth. Manygarnets within these high-pressure aggregates and also discretegarnet phenocrysts are rimmed by medium—coarse-grained,interlocking hornblendeplagioclase, representing partial adjustmentto an assemblage stable at shallower levels. The garnets aretypically pyrope—almandine with 17–28 mol.% grossularand show normal, reverse and oscillatory zoning; the associatedamphibole is pargasite trending to hornblende in phenocrystrims and reaction rims. Metamorphic xenoliths with plagioclase-hornblende-quartzassemblages are also found in the rocks and are characterizedby fine-grained granoblastic mosaic microstructures with well-developedfoliation defined by preferred orientation of elongate grainsand a mineral layering. These metamorphic xenoliths are interpretedas fragments of lower-crustal country rocks accidentally incorporatedinto rising andesitic magma. Application of established experimental high-pressure phasediagrams for andesites indicates crystallization of these assemblagesat depths corresponding to 10–20-kb pressure, and appropriategeothermometers indicates the following temperatures for equilibrationof assemblages at a nominal pressure of 12 kb: garnet-augite980C; garnet-augite-hornblende 920–1020 C. Geobarometryon a single garnet—orthopyroxene-bearing xenolith indicatesa pressure of 10–12 kb for a likely temperature rangeof 950–1000C. Thus the xenoliths point to the generationof host andesite-dacite magmas at suberustal depths of 35–45km, from fractional crystallization of more mafic mantlederivedmagmas, and demonstrate that relatively silicic calc-alkalinemagmas may evolve in the mantle. The rarity of evidence forsuch a process may be linked with the obduction-related tectonicevents operative in Northland just before the magmatic episode,and to the unusually high water content in the magma.