Geochemistry and petrogenesis of the kilimanjaro volcanic rocks of the Amboseli area,Kenya

The paper summarizes the geochemical and petrogenetic aspects of an investigation of late Tertiary to Recent volcanic rocks in the Amboseli area of southern Kenya. A study of chemical variations in the Amboseli and Kilimanjaro lavas distinguishes a mildly alkaline series (alkali olivine basalts, trachybasalts/trachyandesites, trachytes, rhomb porphyries and phonolites) from a strongly alkaline series embracing subordinate nephelinitic, phonolitic and tephritic lavas. The two series probably evolved independently from a source in the mantle. A comparison of Kilimanjaro with other East African volcanoes shows that the focus of strongly alkaline volcanicity moved from eastern Uganda and western Kenya to northern Tanzania at the end of Miocene times. The Pliocene to Recent centres near the Kenya-Tanzania border show evidence of decreasing alkalinity from a western zone of nephelinite-phonolite volcanoes to an eastern region in which central volcanoes are characterized by the association of strongly and mildly alkaline suites.     

河北沽源—多伦地区中生代含铀火山岩地球化学

沽源和多伦地区是燕辽多金属成矿带的重要组成部分，中生界主要发育上侏罗统白旗组、张家口组，下白垩统大北沟组和花吉营组。张家口组火山岩分布广、厚度大，是铀（钼）矿床的主要含矿主岩。中生代火山岩属于钙碱性系列，化学成分富硅、偏碱，δ值1.17-7.60。稀土元素特征反映火山岩有壳幔混合和壳源改造两种成因。火山岩形成于弱造山环境，其年龄与库拉—太平洋板块向亚洲板块俯冲的时间吻合。张家口组酸性火山岩具有我国相山产铀火山杂岩富硅、富钾，铕极亏损的地球化学特征。     

Geochemistry of upper cretaceous volcanic rocks from the pontic chain,northern turkey

Preliminary data on major elements, Cs, Ba, Rb, Pb, Sr, REE, Y, Th, U, Zr, Ht, Sn, Nb, W, Mo, Cr, V, Sc, Ni, Co and Cu contents for eight samples coming from the Upper Cretaceous volcanic belt of the Pontic Chain (Northern Turkey) are reported. SiO, versus K₂O relationship shows that the analyzed samples belong to the calc-alkaline and shoshonite series. The calc-alkaline rocks appear to represent two distinct magma types one close in composition to typical island are calc-alkaline magmas and one with high incompatible elements concentration and tractionated heavy REE patterns which suggest a genesis by partial melting at high pressure with a garnet bearing residue. Shoshonitic rocks show Na₂O/K₂O close to one, high incompatible elements concentration, and TiO₂%. Al₂O₃%, Ni and Co contents, Ni/Co and V/Ni ratios and REE patterns similar to typical island are andesites which suggest for these rocks similar genetical processes as the island are calc-alkaline magmas.     

Geochemistry of ophiolite cherts from the Qinling orogenic belt and implications for their tectonic settings

Since the 1980s, one of the important progresses in the study of the Qinling orogenic belt is marked by findings of numerous ophiolite zones[1—4]. On the basis of the former orogenic models of the Paleozoic colli-sional orogeny[1,5,6] and the Mesozoic collision[7—9], another orogenic evolution model from the Paleozoic subduction-collision along the Shangdan suture to the Mesozoic final collision orogeny along the Mianle suture[3,10], including the relicts of the Jining orogeny, has been pr…     

Petrology of the volcanic rocks of saba,West Indies

Saba is composed of basic and intermediate members of the calc alkaline series with a broad resemblance to volcanic rocks on other islands of the northern Lesser Antilles. The most abundant rock-type is hornblende andesite with relatively high potassium and associated elements. Notable petrographic features are the persistence of magnesian olivine into relatively siliceous whole-rock composition and the prevalence of hornblende even in the more basic rocks. Quartz xenocrysts also occur in the basalts Clinopyroxene phenocrysts are of an gite composition but groundmass grains are sometimes in the range subcalcic augite to magnesian pigeonite. Disequilibrium features in the petrography, together with anomalies in the chemical trends may be due to incorporation of xenocrysts or perhaps in extreme instances to the hybridisation of contrasting magmas.     

Petrology of the volcanic rocks of martinique,West Indies

Volcanological differences between the old and the recent lavas from Martinique, Lesser Antilles, are presented, showing that two volcanic series exist in this island:

Dash

a high-alumina basalt series generally mafic, line-grained, partly pillowed, with clinopyroxene-rich lavas which show iron enrichment tendancies en an A.F.M. plot;

a calc-alkaline (slightly potassic) series much more siliceous as a group, porphyric, predominantly sub-aerially erupted with orthopyroxene-rich lavas which show no iron enrichment.

The high-alumina basalt series is considered as having originated from a differentiation trend by fractionation of olivine, clinopyroxene and plagioclase. Lavas range from olivine basalt to tridymite-rich dacite. The calc-alkaline series probably derives from the contamination of the first suite but the occurence of hornblende-rich cumulates indicates the process of fractionation takes place too. Lavas range from orthopyroxene andesite and hornblende andesite to quartz-hornblende dacite and quartz-biotite dacite.     

Geochemistry of calc-alkaline volcanic rocks from southeastern Iran (kouh-e-shahsavaran)

The Upper Tertiary to Quaternary volcanic complex of Kouh-e-Shahsavaran in southeastern Iran is composed of calc-alkaline rocks of island are type (high-alumina basalts, basic andesites, andesites and dacites) even though it was emplaced on the continental basement. The volcanic rocks of the complex are genetically related and were probably derived by low-pressure fractional crystallization of high-Al basalts. The anomalously high content of Sr in some rocks probably reflects an accumulation of plagioclase. The trace element data are consistent with the origin of the parental magma by partial melting of an “enriched” upper mantle peridotite.     

Geochemistry of mafic cainozoic volcanic rocks from Sardinia (western mediterranean)

The Cainozoic volcanism of Sardinia (Italy) can be divided into two main cycles with different magmatic and geodynamic significance. The early cycle — Oligo-Miocenic in age (29-13 My ago) — shows the calc-alkaline character typical of converging plate areas. The later activity, ranging from Lower Pliocene (about 5 My ago) to recent Pleistocene, produced mostly basic lavas extruded onto a continental plate («within plate basalts»). It was related to a period of tensional tectonics which had affected the western Mediterranean area prior to, and during, the volcanic activity. Intermediate and acid volcanic products were associated with the mafic rocks of the latest magmatic episodes. The main groups of rocks — the basic ones, already classified from their petrographic features and geological setting — can be characterized very well when a statistical elaboration of their chemical analyses is used. In fact, from chemical data it is possible to distinguish the Oligo-Miocene volcanic products from those of Plio-Pleistocene age. Moreover, within this latter group basanites, alkalic and subalkalic basaltic rocks can clearly be distinguished. Samples that had not clearly been defined on the basis of their petrographic characteristics (anonymous samples) have been attributed to one or the other of the main groups by means of discriminant functions. Chemical variations in the Plio-Pleistocenic rocks are due to fractionation episodes at shallow depths superimposed on primary magmatic variations. A model of partial fusion of the mantle accounts for many but not all the observed original chemical variations. Different physical melting conditions, the effects of minor mineral phases in the mantle and, probably, crustal contamination were also effective in creating the observed chemical variations.     

Geochemistry and petrogenesis of rift-related volcanic rocks from South Kivu (Zaire)

Two volcanic zones (Bukavu and Kamituga) south of Lake Kivu (southeastern Zaire) are part of the western branch of the Eastern African rift. They were formed during three volcanic cycles, one pre-rift (70-7 Ma old) and the other two syn-rift (7.8-1.9 Ma old and 14,000 y.-sub-Recent, respectively), and evolved from quartz tholeiites of the pre-rift period to alkali basalts of the rift stage. The basaltic rocks, which strongly predominate, are compositionally similar to other rift-related basalts and also to oceanic-island rocks. Most of the basalts have undergone only limited fractional crystallization (5–10%) dominated by olivine and clinopyroxene. The distinct variations of incompatible elements even in rocks of very similar major-element composition imply that the basaltic rocks were derived from a heterogeneous source by variable degrees of melting. The inferred source composition closely resembles that of metasomatized peridotite xenoliths from alkali basalts.     

Geochemistry of basaltic and gabbroic rocks from the West Mariana basin and the Mariana trench

This paper describes the chemistry of 33 basaltic rocks dredged from the West Mariana basin and from the Mariana trench during the R/V “Dmitry Mendeleev” 1976 cruise in the western Pacific.The shipboard investigations were carried out by an international working group of 66 earth scientists under the IGCP Project “Ophiolites” and sponsored by the U.S.S.R. Academy of Sciences, Moscow. The purpose of the expedition was to investigate the structure and composition of the oceanic crust of marginal basins, remnant island arcs and deep-sea trenches. Tholeiitic basalts and gabbros as well as ultramafic rocks in various stages of alteration were dredged from the central part of the West Mariana basin demonstrating the presence of oceanic crust.The Pacific slope of the Mariana trench yielded altered basaltic rocks of tholeiitic and alkalic (? trachybasaltic to shoshonitic) composition. The lower part of the island arc slope contains typical tholeiitic basalts, dolerites and gabbros as well as ultramafics associated with flysch-type sediments. This is strong evidence for the formation of an “ophiolite-schuppenzone”, probably due to subduction of Pacific oceanic crust.Associated with these rocks are amygdaloidal, highly magnesian lavas (similar to boninites), which have not been recognized previously in oceanic ridge basalts.These rocks (together with the dolerites) are interpreted as parts of the Mariana island arc and are thought to be the first stage of island arc development (an immature island arc).     

The composition and differentiation of the volcanic rocks of Carriacou,grenadines, West Indies

Tertiary volcanic rocks of Carriacou occupy two-thirds of the island. The volcanics include volcaniclastics, lava flows and dome lavas and range in composition from basalts to andesites. Carriacou basalts fall into two petrographic types (a) clinopyroxene-plagioclase-phyric basalts and (b) olivine microphyric basalts; the latter having higher MgO and lower Al₂O₃ than the clinopyroxene basalts. Both types are unusually rich in mafic minerals compared with Lesser Antilles basalts in general, although similar types have been reported from the nearby island of Grenada. The potash to silica ratios are relatively high and confirm the similarity between Carriacou and Grenada basalts and the differences between these basalts and basalts from other islands of the Lesser Antilles. The basaltic andesites and andesites from Carriacou correspond closely in mineralogical and chemical composition with typical andesites found elsewhere in the Lesser Antilles. The geochemistry of the volcanics shows that the olivine microphyric basalts display tholeiitic affinities whereas the clinopyroxeneplagioclase-phyric basalt, basaltic andesites and andesites are calcalkaline. The compositional gradation in both the geochemistry and mineralogy of these volcanics suggests that fractional crystallization played an important role in the derivation of the various magma.     

SHRIMP dating of volcanic rocks from Ningwu area and its geological implications

Preciselydatingofvolcanicrocksisfundamentaltotheunderstandingofthegeologicalevolutionofabasin.However,involcanicrocks,particularlyinthecaseofintermediate-maficrocks,thezirconpopulationsarecomplicatedbecauseofthecommonoccurrenceofinheritance(orcores)and/or…     

Geochemistry of the ophiolite and oceanic island basalt in the Kangxian-Pipasi-Nanping tectonic melange zone, South Qinling and their tectonic significance

Detailed studies indicate that Kangxian-Pipasi-Nanping tectonic zone is a complicated melange zone which includes many tectonic slabs of different origins. Ophiolite (MORB-type basalt), oceanic island tholeiite and alkaline basalt have been identified. Moreover, this tectonic melange zone is eastward connected with the Mianlue suture zone. The deformation characteristics, consisting components and volcanic rock geochemical features for the Kangxian-Pipasi-Nanping tectonic melange zone are much similar to those of the Mianlue suture zone and Deerni ophiolite. Therefore, the Kangxian-Pipasi-Nanping tectonic melange zone should be the westward extension part of the Mianlue suture zone. It indicates that the Mianlue suture zone had extended to the Nanping area.     

Geochemistry and geochronology of Late Triassic volcanic rocks in the Chiang Khong region, northern Thailand

The Chiang Khong segment of the Chiang Khong–Lampang–Tak Volcanic Belt is composed of three broadly meridional sub‐belts of mafic to felsic volcanic, volcaniclastic, and associated intrusive rocks. Associated sedimentary rocks are largely non‐marine red beds and conglomerates. Three representative Chiang Khong lavas have Late Triassic (223–220 Ma) laser ablation inductively coupled mass‐spectroscopy U–Pb zircon ages. Felsic‐dominated sequences in the Chiang Khong Western and Central Sub‐belts are high‐K calc–alkaline rocks that range from basaltic to dominant felsic lavas with rare mafic dykes. The Western Sub‐belt lavas have slightly lower high field strength element contents at all fractionation levels than equivalent rocks from the Central Sub‐belt. In contrast, the Eastern Sub‐belt is dominated by mafic lavas and dykes with compositions transitional between E‐mid‐oceanic ridge basalt and back‐arc basin basalts. The Eastern Sub‐belt rocks have higher FeO* and TiO₂ and less light rare earth element enrichment than basalts in the high‐K sequences. Basaltic and doleritic dykes in the Western and Central sub‐belts match the composition of the Eastern Sub‐belt lavas and dykes. A recent geochemical study of the Chiang Khong rocks concluded that they were erupted in a continental margin volcanic arc setting. However, based on the dominance of felsic lavas and the mainly non‐marine associated sediments, we propose an alternative origin, in a post‐collisional extensional setting. A major late Middle to early Late Triassic collisional orogenic event is well documented in northern Thailand and Yunnan. We believe that the paucity of radiometric dates for arc‐like lavas in the Chiang Khong–Lampang–Tak Volcanic Belt that precede this orogenic event, coupled with the geochemistry of the Chiang Khong rocks, and strong compositional analogies with other post‐collisional magmatic suites, are features that are more typical of volcanic belts formed in a rapidly evolving post‐collisional, basin‐and range‐type extensional setting.     

The geochemistry and petrogenesis of the volcanic rocks of Carriacou,Grenadine Islands,West Indies

Carriacou is small volcanic island located near the southern end of the Lesser Antillean chain. Field relationships, petrography and geochemistry of the Tertiary lavas, outcropping in the southern half of the island, are used to identify the rocks present and to determine their petrogenesis and assess their significance within the island arc.Six main volcanic units are present. From oldest to youngest, these are the clinopyroxene-phyric basalt (CPB) sequence, the amphibole-phyric andesite (APA) sequence, the clinopyroxene-megaphyric basalt (CMB) sequence, the olivine-microphyric basalt (OMB) sequence, the clinopyroxene phyric andesite (CPA) sequence, and the amphibole-megaphyric andesite (AMA) sequence. Volcaniclastic deposits are associated with the APA, CMB, and AMA sequences. The APA sequence is calcalkaline, whereas the other five sequences are tholeiitic.Sr isotope and rare earth element (REE) data suggest that these volcanic rocks were derived from partial melts of garnet-peridotite generated deep within the mantle. The OMB lavas have the highest temperature assemblages of intratelluric minerals and the least evolved chemical characteristics, and are considered to be closest in composition to a parental melt. Phenocryst assemblages and chemical variation suggest that the andesite sequences have been derived from the mafic melts by low pressure fractional crystallization of approximately 20% clinopyroxene and 20% olivine, plus smaller amounts of plagioclase and amphibole. The high concentrations of incompatible and compatible elements and the high⁸⁷Sr/⁸⁶Sr ratios may indicate that subduction is slower in the southern part of the arc, and fluids released during slab dehydration rich in Incompatible trace elements, in Radiogenic strontium, and in Silica (IRS), have modified the parental melts.     

Ar-Ar geochronology of Late Mesozoic volcanic rocks from the Yanji area, NE China and tectonic implications

Ar-Ar dating results of late Mesozoic-Cenozoic volcanic rocks from the Yanji area, NE China provide a new volcano-sedimentary stratigraphic framework. The previously defined “Triassic-Jurassic” volcanic rocks (including those from Sanxianling, Tuntianying, Tianqiaoling and Jingouling Fms.) were erupted during 118―106 Ma, corresponding to Early Cretaceous. The new eruption age span is slightly younger than the main stage (130―120 Ma) of the extensive magmatism in the eastern Central Asian Orogenic Belt and its adjacent regions. Subduction-related adakites occurring in the previously defined Quanshuicun Fm. were extruded at ca. 55 Ma. Based on these new Ar-Ar ages, the late Mesozoic to Palaeocene volcano-sedimentary sequences is rebuilt as: Tuopangou Fm., Sanxianling/Tuntianying Fm. (118―115 Ma), Malugou/Tianqiaoling Fm. (K1), Huoshanyan/Jingouling Fm. (108―106 Ma), Changcai Fm. (K2), Quanshuicun Fm. (~55 Ma) and Dalazi Fm. Our results suggest that subduction of the Pa- laeo-Pacific Ocean beneath the East Asian continental margin occurred during 106 to 55 Ma, consistent with the paleomagnetic observations and magmatic records which indicated that the Izanagi-Farallon ridge subduction beneath the southwestern Japan took place during 95―65 Ma.     

Geochemistry of some volcanic rocks from south-eastern sicily: Rare earth and other trace element distribution

Some trace element data for volcanic rocks found at different levels, from Tertiary to Holocene, in south-eastern Sicily (Iblean Plateau and Mt. Etna) are presented and discussed in the present paper in order to better the information about the origin and relationships of the various rock types. Four groups of volcanic rocks have been recognized on the basis of their major element chemistry: 1) low-K tholeiites, 2) associated alkali basalts to nephelinites of the Iblean Plateau (Upper Pliocene to Lower Pleistocene), 3) the basal subalkaline lavas of Mt. Etna, and 4) the alkalic suite rocks that make up the bulk of the volcano. The distribution of Rb, Sr, Ni, Cr, Co, Cu, REE, Th and Sc suggests:

1. an origin of the Iblean magmas by a different degree of partial melting of a Rb-poor and possibly slightly hetereogeneous mantle;
2. quite distinct source compositions for the Etnean magmas, relative to those of the Iblean area, on the basis of their Rb and Sr contents;
3. an origin of the alkalic rocks of Mt. Etna from independently generated magma(s) rather than by crystal fractionation of the Etnean subalkaline magmas or of a magma having the geochemical features of the Iblean alkali basalts; evidence for this is given by the distribution features of the incompatible elements showing an origin for these rocks from compositionally different parent magmas and/or an evolution under widely variable environmental conditions;
4. the primary character for the chemical differences observed in some of the Etnean subalkaline rocks that can be accounted for by different physico-chemical conditions at their source rather than by crystal fractionation processes.

     

Geochemistry of Cenezoic volcanic rocks, Baja California, Mexico: Implications for the petrogenesis of post-subduction magmas

Late Cenozoic volcanism in Baja California records the effects of cessation of subduction at a previously convergent, plate margin. Prior to 12.5 m.y., when subduction along the margin of Baja ceased, the predominant volcanic activity had a calc-alkaline signature, ranging in composition from basalt to rhyolite. Acidic pyroclastic activity was common, and possibly represented the westermost, distal edge of the Sierra Madre Occidental province. After 12.5 m.y., however, the style and composition of the magmatic products changed dramatically. The dominant rock type within the Jaraguay and San Borja volcanic fields is a magnesian andesite, with up to 8% MgO at 57% SiO₂, low Fe/Mg ratios, and high Na/K ratios. These rocks have unusual trace-element characteristics, with high abundances of Sr (up to 3000 ppm), low contents of Rb; K/Rb ratios are very high (usually over 1000, and up to 2500), and Rb/Sr ratios are low (less than 0.01). Furthermore, La_n/Yb_n ratios are high, consistent with derivation from a mantle source with fractionated REE patterns. ⁸⁷Sr/⁸⁶Sr ratios are less than 0.7048, and usually less than 0.7040, whereas the pre-12.5 m.y. lavas have ⁸⁷Sr/⁸⁶Sr ratios between 0.7038 and 0.7063. We have previously termed these rocks bajaites, in order to distinguish them from other magnesian andesites. Bajaites also occur in southernmost Chile and the Aleutian Islands, areas which also have histories of attempted or successful ridge subduction.It is proposed that the bajaite series is produced during the unusual physico-chemical conditions operating during the subduction of young oceanic lithosphere, or subduction of a spreading centre. During normal subduction, the oceanic crust dehydrates, releasing volatiles (water, Rb and other large-ion lithophile elements) into the overlying wedge. Subduction of younger crust will result in a progressive decrease, and eventual cessation of the transfer of volatiles when subduction stops. Thermal rebound of the mantle may cause the slab to melt, perhaps under eclogitestable conditions. The resulting melt will be heavy-REE-depleted, perhaps dacitic, but will otherwise inherit MORB-like Rb/Sr and K/Rb ratios. The ascending melt will react with the mantle to form the source of the bajaitic rocks. Furthermore, any amphibole in the mantle, stabilised during the higher PH₂O conditions of earlier subduction, will break down and contribute a high-K/Rb ratio component.The implications of this study are that firstly, the subducted slab does not contribute a highly fractionated REE component in most modern arcs (i.e. the slab does not melt); secondly, Rb has a very short residence time in the mantle, and its abundance in arc rocks is a direct reflection of the input from the dehydrating slab; and thirdly, bajaitelike rocks may provide recognition of attempted or successful ridge subduction in the geologic past.