Instantaneous global ozone balance including observed nitrogen dioxide

The catalytic destruction of stratospheric ozone by the oxides of nitrogen is believed to be an important part of the global ozone balance. The lack of sufficient measurements of NO _x concentrations has impeded efforts to quantify this process. Recent measurements of stratospheric nitrogen dioxide from ground-based stations as well as aircraft and balloons have provided a first approximation to a global distribution of NO₂ vertical columns at sunset. These observed vertical columns have been translated into time-dependent vertical NO₂ profiles by means of a one-dimensional atmospheric photochemical model. Using recent observations of air temperature and ozone along with this information, the independent instantaneous (one second) rates of ozone production from oxygen photolysis P(O₃), of ozone destruction from pure oxygen species (Chapman reactions) L(O _x ), and of ozone destruction by nitrogen oxides L(NO _x ) were estimated over the three-dimensional atmosphere. These quantities are displayed as zonal average contour maps, summed over various latitude zones, summed over various altitude bands, and integrated globally between 15 and 45 km. Although the global summation between 15 and 45 km by no means tells the complete story, these numbers are of some interest, and the relative values are: P(O₃), 100; L(O _x ), 15; L(NO _x ), 45±15. It is to be emphasized that this relative NO _x contribution to the integrated ozone balance is not a measure of the sensitivity of ozone to possible perturbations of stratospheric NO _x ; recent model results must be examined for current estimates of this sensitivity.     

The present-day and future impact of NOx emissions from subsonic aircraft on the atmosphere in relation to the impact of NOx surface sources

The effect of present-day and future NO_x emissions from aircraft on the NO_x and ozone concentrations in the atmosphere and the corresponding radiative forcing were studied using a three-dimensional chemistry transport model (CTM) and a radiative model. The effects of the aircraft emissions were compared with the effects of the three most important anthropogenic NO_x surface sources: road traffic, electricity generation and industrial combustion. From the model results, NO_x emissions from aircraft are seen to cause an increase in the NO_x and ozone concentrations in the upper troposphere and lower stratosphere, and a positive radiative forcing. For the reference year 1990, the aircraft emissions result in an increase in the NO_x concentration at 250 hPa of about 20 ppt in January and 50 ppt in July over the eastern USA, the North Atlantic Flight Corridor and Western Europe, corresponding to a relative increase of about 50%. The maximum increase in the ozone concentrations due to the aircraft emissions is about 3-4 ppb in July over the northern mid-latitudes, corresponding to a relative increase of about 3-4%. The aircraft-induced ozone changes cause a global average radiative forcing of 0.025 W/m² in July. According to the ANCAT projection for the year 2015, the aircraft NO_x emissions in that year will be 90% higher than in the year 1990. As a consequence of this, the calculated NO_x perturbation by aircraft emissions increases by about 90% between 1990 and 2015, and the ozone perturbation by about 50-70%. The global average radiative forcing due to the aircraft-induced ozone changes increases by about 50% between 1990 and 2015. In the year 2015, the effects of the aircraft emissions on the ozone burden and radiative forcing are clearly larger than the individual effects of the NO_x surface sources. Taking chemical conversion in the aircraft plume into account in the CTM explicitly, by means of modified aircraft NO_x emissions, a significant reduction of the aircraft-induced NO_x and ozone perturbations is realised. The NO_x perturbation decreases by about 40% and the ozone perturbation by about 30% in July over Western Europe, the eastern USA and the North Atlantic Flight Corridor.     

Part Load Performance and Emission Improvement of Direct Injection Diesel Engine through Porous Medium Combustion Technique

Diesel engines are being extensively used in the transport sector owing to their excellent fuel efficiency, low emissions of carbon dioxide, unburned hydrocarbons and carbon monoxide. However, high emissions of nitrogen oxides (NO_x) and particulate matter (PM) place diesel engines on the down side. It is extremely complex to reduce both emissions at the same time, because of the trade‐off between NO_x and PM emissions. Even though the implementation of high pressure injection and common rail system could reduce both NO_x and PM emissions together, the cost involved would be high and unaffordable for many engine producers and consumers. In this research work, a new combustion technique termed, porous medium combustion, has been proven to be a proficient technique in reducing both NO_x and PM emissions from the direct injection diesel engines. However, the NO_x and PM emissions were found to be higher than the conventional engine at low range of part loads.     

Impact of different energies of precipitating particles on NOx generation in the middle and upper atmosphere during geomagnetic storms

Energetic particle precipitation couples the solar wind to the Earth's atmosphere and indirectly to Earth's climate. Ionisation and dissociation increases, due to particle precipitation, create odd nitrogen (NO_x) and odd hydrogen (HO_X) in the upper atmosphere, which can affect ozone chemistry. The long-lived NO_x can be transported downwards into the stratosphere, particularly during the polar winter. Thus, the impact of NO_x is determined by both the initial ionisation production, which is a function of the particle flux and energy spectrum, as well as transport rates. In this paper, we use the Sodankylä Ion and Neurtal Chemistry (SIC) model to simulate the production of NO_x from examples of the most representative particle flux and energy spectra available today of solar proton events (SPE), auroral energy electrons, and relativistic electron precipitation (REP). Large SPEs are found to produce higher initial NO_x concentrations than long-lived REP events, which themselves produce higher initial NO_x levels than auroral electron precipitation. Only REP microburst events were found to be insignificant in terms of generating NO_x. We show that the Global Ozone Monitoring by Occultation of Stars (GOMOS) observations from the Arctic winter 2003–2004 are consistent with NO_x generation by a combination of SPE, auroral altitude precipitation, and long-lived REP events.     

On the NOx production by laboratory electrical discharges and lightning

Different approaches are used in estimating the global production of NO_x by lightning flashes, including field measurements carried out during thunderstorm conditions, theoretical studies combining the physics and chemistry of the electrical discharges, and measurements of NO_x yield in laboratory sparks with subsequent extrapolation to lightning. In the latter procedure, laboratory data are extrapolated to lightning using the energy as the scaling quantity. Further, in these studies only the return strokes are considered assuming that contributions from other processes such as leaders, continuing currents, M components, and K processes are negligible. In this paper, we argue that the use of energy as the scaling quantity and omission of all lightning processes other than return strokes are not justified. First, a theory which can be used to evaluate the NO_x production by electrical discharges, if the current flowing in the discharge is known, is presented. The results obtained from theory are compared with the available experimental data and a reasonable agreement is found. Numerical experiments suggest that the NO_x production efficiency of electrical discharges depends not only on the energy dissipated in the discharge, but also on the shape of current waveform. Thus, the current signature, can influence extrapolation of laboratory data to lightning flashes. Second, an estimation of the NO_x yield per lightning flash is made by treating the lightning flash as a composite event consisting of several discharge processes. We show that the NO_x production takes place mainly in slow discharge processes such as leaders, M components, and continuing currents, with return strokes contributing only a small fraction of the total NO_x. The results also show that cloud flashes are as efficient as ground flashes in NO_x generation. In estimating the global NO_x production by lightning flashes the most influencing parameter is the length of the lightning discharge channel inside the cloud. For the total length of channels inside the cloud of a typical ground flash of about 45 km, we estimate that the global annual production of NO_x is about 4 Tg(N).     

Effects of elevated pCO2 on reproductive properties of the benthic copepod Tigriopus japonicus and gastropod Babylonia japonica

We investigated the effects of elevated pCO₂ in seawater both on the acute mortality and the reproductive properties of the benthic copepod Tigriopus japonicus and gastropod Babylonia japonica with the purpose of accumulating basic data for assessing potential environmental impacts of sub-sea geological storage of anthropogenic CO₂ in Japan. Acute tests showed that nauplii of T. japonicus have a high tolerance to elevated pCO₂ environments. Full life cycle tests on T. japonicus indicated NOEC = 5800 μatm and LOEC = 37,000 μatm. Adult B. japonica showed remarkable resistance to elevated pCO₂ in the acute tests. Embryonic development of B. japonica showed a NOEC = 1500 μatm and LOEC = 5400 μatm. T. japonicus showed high resistance to elevated pCO₂ throughout the life cycle and B. japonica are rather sensitive during the veliger stage when they started to form their shells.     

四川、甘肃地区VS30经验估计研究

目前我国建筑工程抗震设计规范中对于工程场地条件的判断依据主要是地表以下20m深度范围内土层的等效剪切波速,简称VS20。相比之下,国外应用较广的是地表以下30m深度范围内的等效剪切波速,简称VS30。这种差别导致国内科研工作者在应用国外的地震工程、工程抗震模型时经常遇到对场地条件描述不准确的困难。为了解决这个问题,本文根据147个四川、甘肃地区国家强震动台站20m左右深度的钻孔剪切波速数据,利用延拓方法、场地分类统计方法以及基于地形特征的VS30估计方法研究各台站VS30与VS20的经验关系,对比发现基于速度梯度延拓的结果最为可取。参考国际上通用的Geomatrix Classification场地分类标准,最终得到四川、甘肃地区各类场地的平均VS30,此结果可以为缺乏钻孔数据的工程场地的VS30估计提供参考。     

Effects of copper and the sea lice treatment Slice on nutrient release from marine sediments

Copper-based antifoulant paints and the sea lice treatment Slice^® are widely used, and often detectable in the sediments beneath farms where they are administered. Ten-day, whole sediment mesocosm experiments were conducted to examine how increasing sediment concentrations of copper or Slice^® influenced final water column concentrations of ammonium-nitrogen (NH₄-N), nitrate + nitrite-nitrogen (NO_X-N) and phosphate-phosphorus (PO₄-P) in the presence of the non-target, benthic organisms Corophium volutator and Hediste diversicolor. Nominal sediment concentrations of copper and Slice^® had significant effects on the resulting concentrations of almost all nutrients examined. The overall trends in nutrient concentrations at the end of the 10-day incubations were highly similar between the trials with either copper or Slice^®, irrespective of the invertebrate species present. This suggests that nutrient exchange from the experimental sediments was primarily influenced by the direct effect of copper/Slice^® dose on the sediment microbial community, rather than the indirect effect of reduced bioturbation/irrigation due to increased macrofaunal mortality.     

Reduction in Exhaust Gas Temperature of Biodiesel Fueled Engine by Exhaust Gas Recirculation

Biodiesel is a renewable alternative fuel that can be used as substitute for mineral diesel. The use of biodiesel in diesel engines reduces all of the exhaust emissions expect NO_x. The higher temperature in the combustion chamber increases the NO_x emissions. The recirculation of a small percentage of cooled exhaust gases into the combustion chamber through the intake manifold reduces the in‐cylinder temperature. Moreover, the cooling of exhaust gases before mixing with fresh air introduced to the engine does not affect its volumetric efficiency but it absorbs the heat of combustion. This leads to a reduction in NO_x emissions and improves the engine brake thermal efficiency. This paper describes the investigation of the performance and emission characteristics of a biodiesel‐fueled, naturally aspirated, single cylinder diesel engine with cooled exhaust gas recirculation.     

Investigating Correlations and Variations of Air Pollutant Concentrations under Conditions of Rapid Industrialization – Kocaeli (1987–2009)

In this study, it was aimed to characterize temporal variations of air pollutants for determining contribution to pollution episodes and to obtain correlations between these pollutants. With this aim we used data analysis for measured sulfur dioxide (SO₂), particulate matter (PM, black fume and PM10), nitrogen oxides (NO_x), ozone (O₃), carbon monoxide (CO), methane (CH₄), and non‐methane hydrocarbons (NMHC) recorded in Kocaeli, one of the most industrilizated cities of Turkey. Pollutant concentrations were the results of continuous and semi‐automatic measurements. Semi‐automatic measurements of SO₂ and PM (black fume) were enclosing period from 1987 to 2008 whereas continuous monitoring of all pollutants included years of 2007–2009. In the first stage of the study daily, monthly, annual, and seasonal variations of pollution were researched. Annual average concentrations were compared with limits set by Air Quality Protection Regulation (AQPR), Air Quality Evaluation and Management Regulation (AQEMR), World Health Organization (WHO), European Union (EU), and National Ambient Air Quality Standards (USEPA). In the following stage relationships between pollutants such as NO₂–O₃, NO_x–CO, NO_x–NMHC, and NO_x–SO₂ were investigated and correlation coefficients were determined as 0.87, 0.56, 0.51, and 0.69, respectively. R² values of regression models developed from these correlations were 0.78, 0.56, 0.34, and 0.72, respectively. Vehicle density of the traffic was evaluated with NO_x–O₃ emissions and decrease was seen in NO_x emissions due to decreasing vehicle density at weekends whereas O₃ concentrations increased. These correlations enable prediction of the parameters that cannot be measured which is important for providing improvement in early warning systems.     

四川芦山7.0级地震前中小地震P轴方位角CV值的变化

通过对2003年1月1日—2013年4月1日芦山地震前震源区中小地震震源机制解的分析,发现不同阶段的震源机制解在一定程度上反映了强震孕育过程中构造应力场随时间的变化。震源区中小地震的P轴方位角C_V值在芦山M7.0地震发生前有一个上升-下降-上升的过程,只是相比于汶川8.0级地震前C_V值的下降-上升过程经历了更长的时间,这表明四川芦山M7.0地震的孕育经历了长时间的应力积累,与许多研究结果相一致。2007年1月1日—2014年4月1日C_V值空间分布的非均匀性特征在龙门山断裂带南段有显著的增强与减弱过程,对于发震地点可能有一定的指示意义。     

Simulating the global transport of nitrogen oxides emissions from aircraft

With the atmosphere general circulation model ECHAM the passive transport of NO_x emitted from global subsonic air traffic and the NO_x concentration change due to these emissions are investigated. The source of NO_x is prescribed according to an aircraft emission data base. The sink of NO_x is parameterized as an exponential decay process with globally constant lifetime. Simulations in perpetual January and July modes are performed. Both the resulting mean and the standard deviation of the NO_x mass mixing ratio are analysed. In January horizontal dispersion is more pronounced and vertical mixing is smaller than in July. In both cases the resulting quasi-stationary fields of the mass mixing ratio display a pronounced zonal asymmetry. The variability accounts up to 30% of the mean field.     

2009年7月24日西藏尼玛西南MS5.6地震研究

主要研究2009年7月24日西藏尼玛西南MS5.6地震的基本参数、地震序列特征、震源参数、发震构造等;利用震中附近600km范围内台站测定参数研究地震的震源机制解,与哈佛大学给出的震源机制解较一致,且与通过现场考察的发震断层走向具有一致性。研究认为本次地震发生在冈底斯山—拉萨块体内部,断裂为NNW向,主要受张应力作用产生左旋走滑正断层活动。此外还分析了震前地震学条带异常特征,结束表明,震前1年出现NW向条带非常显著,研究结论为该地区今后地震预测提供科学依据。     

New insights into the spatial variability of the surface water carbon dioxide in varying sea ice conditions in the Arctic Ocean

In the summer of 2005, continuous surface water measurements of fugacity of CO₂ (fCO₂^sw), salinity and temperature were performed onboard the IB Oden along the Northwest Passage from Cape Farwell (South Greenland) to the Chukchi Sea. The aim was to investigate the importance of sea ice and river runoff on the spatial variability of fCO₂ and the sea–air CO₂ fluxes in the Arctic Ocean. Additional data was obtained from measurements of total alkalinity (A_T) by discrete surface water and water column sampling in the Canadian Arctic Archipelago (CAA), on the Mackenzie shelf, and in the Bering Strait. The linear relationship between A_T and salinity was used to evaluate and calculate the relative fractions of sea ice melt water and river runoff along the cruise track. High-frequency fCO₂^sw data showed rapid changes, due to variable sea ice conditions, freshwater addition, physical upwelling and biological processes. The fCO₂^sw varied between 102 and 678 μatm. Under the sea ice in the CAA and the northern Chukchi Sea, fCO₂^sw were largely CO₂ undersaturated of approximately 100 μatm lower than the atmospheric level. This suggested CO₂ uptake by biological production and limited sea–air CO₂ gas exchange due to the ice cover. In open areas, such as the relatively fresh water of the Mackenzie shelf and the Bering Strait, the fCO₂^sw values were close to the atmospheric CO₂ level. Upwelling of saline and relatively warm water at the Cape Bathurst caused a dramatic fCO₂^sw increase of about 100 μatm relative to the values in the CAA. At the southern part of the Chukchi Peninsula we found the highest fCO₂^sw values and the water was CO₂ supersaturated, likely due to upwelling. In the study area, the calculated sea–air CO₂ flux varied between an oceanic CO₂ sink of 140 mmol m⁻² d⁻¹ and an oceanic source of 18 mmol m⁻² d⁻¹. However, in the CAA and the northern Chukchi Sea, the sea ice cover prevented gas exchange, and the CO₂ fluxes were probably negligible at this time of the year. Assuming that the water was exposed to the atmosphere by total melting and gas exchange would be the only process, the CO₂ undersaturated water in the ice-covered areas will not have the time to reach the atmospheric CO₂ value, before the formation of new sea ice. This study highlights the value of using high-frequency measurements to gain increased insight into the variable and complex conditions, encountered on the shelves in the Arctic Ocean.     

A stochastic model for daily subsurface CO2 concentration and related soil respiration

Near-surface soil CO₂ gas-phase concentration (C) and concomitant incident rainfall (P_i) and through-fall (P_t) depths were collected at different locations in a temperate pine forest every 30 min during the 2005 and 2006 growing seasons (and then averaged to the daily timescale). At the daily scale, C temporal variations were well described by a sequence of monotonically decreasing functions interrupted by large positive jumps induced by rainfall events. A stochastic model was developed to link rainfall statistics responsible for these jumps to near-surface C dynamics. The model accounted for the effect of daily rainfall variability, both in terms of timing and amount of water, and permitted an analytical derivation of the C probability density function (pdf) using the parameters of the rainfall pdf. Given the observed positive correlation between daily C and soil CO₂ fluxes to the atmosphere (F_s), the effects of various rainfall regimes on the statistics of F_s can be deduced from the behavior of C under different climatic conditions. The predictions from this analytical model are consistent with flux measurements reported in manipulative experiments that varied rainfall amount and frequency.     

Morphological changes in branchial mitochondria-rich cells of the teleost Paralichthys olivaceus as a potential indicator of CO2 impacts

We studied the morphological and biochemical changes of mitochondria-rich cells (MRCs) of a demersal teleost, Paralichthys olivaceus, during exposure to 0.98, 2.97 and 4.95 kPa pCO₂. The apical opening area of MRCs increased 2.2 and 4.1 times by 24 h exposure to 2.97 and 4.95 kPa pCO₂, respectively, while the cross-sectional area or density of MRCs did not change. Gill Na⁺/K⁺-ATPase activity more than doubled at 72 h and then returned to the pre-exposure level at 168 h in 0.98 kPa pCO₂, while it increased 1.7 times at 24 h at 4.95 kPa. These results indicate that the apical opening area of MRCs and the gill Na⁺/K⁺-ATPase activity may be used as an indicator of acute (up to 72 h), but not chronic, impacts of high (>1 kPa) seawater CO₂ conditions in P. olivacues. Limitations of those parameters as indices of CO₂ impacts are discussed.     

2012年新疆新源、和静交界MS6.6地震前后震源机制解一致性参数变化特征

基于新疆地震台网中心自2009年1月—2013年5月的波形数据,利用CAP方法和P波初动方法计算2012年6月30日新疆新源、和静交界M_S6.6地震周围(81°~89° E,42°~45° N)共418次中小地震震源机制解,反演其一致性参数Var的空间分布特征。结果表明:震中附近一致性参数Var在震前呈低值,震后恢复正常;震前最大主应力P轴方位角与主震基本一致,震后恢复到历史平均水平。     

The atmospheric effects of October 2003 solar proton event simulated with the chemistry–climate model SOCOL using complete and parameterized ion chemistry

October 2003 solar proton events (SPE) is rather well covered by the observations; therefore its studies represent a good way for model validation and intercomparison. Here we apply chemistry–climate model (CCM) SOCOL with complete (SOCOLⁱ) and parameterized ion chemistry to evaluate the accuracy of a commonly used ion chemistry parameterization scheme. We performed ensemble experiments with and without SPE to characterize the effect of the October 2003 SPE on the NO_x, HO_x, ClO_x and O₃ in the middle atmosphere. Preliminary comparison of the simulated effects against MIPAS observations revealed rather good general agreement for most of the species. Comparison of the results obtained with complete and parameterized ion chemistry representation showed that the model with parameterized ion chemistry underestimates the effect of SPE on chemical composition of the middle atmosphere by up to 40% for NO_x and N₂O, up to 70% for HO_x and ClO_x and up to 600% for HNO₃. The parameterization is more accurate for ozone, however the model with parameterized ion chemistry underestimates ozone depletion by up to 15% during the SPE in the mesosphere and by 10% 2 weeks later in the stratosphere, which can be important for the long-term effects of SPE on the ozone layer.     

Chemical composition and photochemical reactivity of exhaust from aircraft turbine engines

Assessment of the environmental impact of aircraft emissions is required by planners and policy makers. Seveal areas of concern are: 1. exposure of airport workers and urban residents to toxic chemicals emitted when the engines operate at low power (idle and taxi) on the ground; 2. contributions to urban photochemical air pollution of aircraft volatile organic and nitrogen oxides emissions from operations around airports; and 3. emissions of nitrogen oxides and particles during high-altitude operation. The environmental impact of chemicals emitted from jet aircraft turbine engines has not been firmly established due to lack of data regarding emission rates and identities of the compounds emitted. This paper describes an experimental study of two different aircraft turbine engines designed to determine detailed organic emissions, as well as emissions of inorganic gases. Emissions were measured at several engine power settings. Measurements were made of detailed organic composition from C₁ through C₁₇, CO, CO₂, NO, NO _x , and polycyclic aromatic hydrocarbons. Measurements were made using a multi-port sampling pro be positioned directly behind the engine in the exhaust exit plane. The emission measurements have been used to determine the organic distribution by carbon number and the distribution by compound class at each engine power level. The sum of the organic species was compared with an independent measurement of total organic carbon to assess the carbon mass balance. A portion of the exhaust was captured and irradiated in outdoor smog chambers to assess the photochemical reactivity of the emissions with respect to ozone formation. The reactivity of emissions from the two engines was apportioned by chemical compound class.     

The effect of the HO2+NO reaction rate constant on one-dimensional model calculations of stratospheric ozone perturbations

With the aid of a one-dimensional steady-state, stratospheric model we have calculated ozone changes coused by atmosphric injections of NO_x, N₂O and chlorofluoromethanes. Adopting the fast rate constant, for the reaction HO₂+NO»OH+NO₂ measured by Howard and Evenson, we calculate much smaller perturbations of the ozone layer by NO_x and N₂O additions than previously estimated, but about two times larger ozone reductions as a result of continued emissions of chlorofluoromethanes, CF₂Cl₂ and CFCl₃.The model results are sensitive to adopted values for the rate coefficients for the reactions HO₂+O₃»OH+2O₂ and OH+HO₂»H₂O+O₂ and the eddy diffusion profile near the tropopause. More accurate assessments of ozone perturbations require the development of photochemical models that incorporate meteorological processes in more than one dimension.