贡嘎山海螺沟降雪中多环芳烃的短周期分布特征及来源分析

2013年1月在贡嘎山海螺沟3个不同采样点共收集了多个雪样,利用GC-MS分析了雪样中16种优控多环芳烃的含量,探讨了多环芳烃的短周期分布特征与来源,估算了采样点与排放源的直线距离。结果显示,海螺沟各采样点雪样中多环芳烃的总含量在163.7 ng/L~281.4 ng/L之间,其中菲的含量最高。雪样中2~4环多环芳烃占多环芳烃总量的百分比为92.0%~93.7%,表明污染来自较远距离传输,但主要排放源离海螺沟的直线距离不超过357 km。将雪层与气象资料的降雪期对应,结果表明从2012年11月到2013年1月这个短周期内,海螺沟雪样受多环芳烃污染的程度没有太大变化。对海螺沟雪样中的多环芳烃进行了来源分析,结果表明海螺沟雪样中的多环芳烃主要来自煤燃烧,不排除少部分木材燃烧,这一源解析结果与海螺沟及其周边地区主要以煤炭作为燃料的能源特征相吻合。     

贡嘎山海螺沟冰川沉积特征与冰下过程研究

贡嘎山海螺沟冰川是典型的海洋性冰川,粒度分析表明:冰下融出碛的细粒组分中粉砂占优势,压碎组分与磨碎组分界线在0.5 mm附近,说明其经历充分的研磨细化.与西藏枪勇冰川和天山乌鲁木齐河源冰川的矿物组成和化学成分对比,海螺沟冰川沉积物的经历的化学风化作用更强,即海洋性冰川冰下化学作用比大陆性冰川活跃.显微层理构造、正粒序层理和沉积透镜体反映海洋性冰川底部存在周期性沉积机制和明显的流水作用,显微滞碛是较常见的冰下融出碛类型.沉积物中显微褶皱和断层等反映海洋性冰川强烈滑动、剪切变形过程机制.     

贡嘎山海螺沟冰川径流水文规律的同位素示踪研究

应用同位素地球化学的基本原理和示踪技术, 对贡嘎山海螺沟冰川河源区和干流的不同区段, 不同时域径流的组成特点及其水文动态变化规律进行分析研究.结果表明: 贡嘎山海螺沟冰川河源区水的组成, 不同季节、不同时段(早、晚)有明显的变化. 夏季晚上的水大约有82.4%是来自冰川区的水, 17.6%为非冰川区的径流; 早晨中的水来自冰川区的占74.6%, 非冰川区径流占25.4%. 冰川消融水的最大可占总水量的6.9%～7.8%左右. 在冬季时段, 冰舌末端排泄水(BCH-1)和冰川水文站(HLG-6)径流的同位素组成均低于底部冰川冰(BCB-2: -16.639‰), 显示出严重同位素不平衡的特点, 反映了冬季底部冰川消融水在源区水(BCH-1)中的贡献已达很低的程度, 而代之以冰川上部占主导优势的雨雪水. 这意味着在冬季当地冰川的退缩速度与夏季相比有明显减慢的趋势. 示踪表明, 在冰川水文站附近区域内存在水的渗漏, 夏季可能延伸到倒中桥(HLG-13采样点上方)一带, 下渗水通过地下通道, 到杉树坪(HLG-2采样点)邻近的区域回补到河道内.     

Stable isotopic information for hydrological investigation in Hailuogou watershed on the eastern slope of Mount Gongga, China

Hydrological systems have been seriously affected by changes of glaciations and snow covers in Mount Gongga, Sichuan, China, but the relevance of ice-snow melt for alpine river basin hydrology is so far not well known. To better understand hydrological features of the Hailuogou River, changes of δ¹⁸O and δ²H were investigated by analyzing 117 water samples collected from May 2008 to November 2009. Our results show that the stream water contains a relatively intermediate magnitude of isotopic variations, with δ¹⁸O ranging from ?18.09 to ?13.08 ‰ and δ²H from ?126.5 to ?88.8 ‰. The average values are both higher than those of ice-snow meltwater, but lower than those of meteoric water. These data also show a gradually increasing trend from upstream to downstream, and these changes might document the fingerprint of ice-snow melt in the headwater region and indicate the increasing recharge of heavy isotope-enriched waters with flow distance. The similarity in slopes of δ²H and δ¹⁸O relationship for meteoric waters and stream waters suggests that the isotopic signature of precipitation is well preserved in stream flow, and during the rainfall and stream flow the evaporation is only minor. Based on δ¹⁸O model, the results suggested that the fraction of ice-snow meltwater input over the total stream flow ranged from 84.50 to 86.52 % in the headwater region, but the fraction of ice-snow meltwater input from upper basin downward was significantly decreased. The study demonstrates that ice-snow meltwater is a substantially important water source in alpine regions on the edge of Tibetan Plateau.     

Changes of the Hailuogou Glacier, Mt. Gongga,China, against the Background of Global Warming in the Last Several Decades

Great change, associated with global warming, has occurred at the Hailuogou (海螺沟)has retreated 1 822 m in the past 106 years, with an annual mean retreat of 17.2 m, and the front elevation has risen by 300 m since 1823. Comparison of glacier variations and temperature fluctuations in China and the Northern Hemisphere, over the last 100 years, indicates that glacier retreat stages occurred during the warm phase, and vice versa. Mass balance records during 1959/60--2003/04 have shown that the glacier has suffered a constant mass loss of snow and ice. The accumulated mass balance, -10.83 m water equivalent, indicates an annual mean value of -0.24 m water equivalent. The correlation between the mass balance and temperature is significant, which also indicates that climate warming is the crucial cause of glacier loss.Local hydrological and climatic data demonstrate that runoff from the glacier has been increasing both seasonally and annually.The correlation analysis and trend analysis indicate that ice and snow melted water is the main cause of an increase in the runoff. As the climate has become warmer, changes in the glacier surface morphology have obviously occurred. These include a decrease in glacier thickness, enlargement of glacial caves, and reduction of the size of clefts on the glacier surface. The ablation period has lengthened and the ablation area has expanded. A variety of factors thus provide evidence that the Hailuogou glacier has suffered a rapid loss of snow and ice as a result of climatic warming.     

Features of climate change and their effects on glacier snow melting in Xinjiang,China

The features of climate change and their effects on glacier snow melting in the past 50 years (1961–2010) in Xinjiang were studied. Regional climate data for 49 meteorological stations in the Tianshan Mountains and the northern and southern areas of Xinjiang were collected with the aid of techniques such as climatological statistical diagnosis, regional climate models, remote sensing, and geographic information system. The annual average temperature displayed a rising trend across the Tianshan mountainous area and both areas of Xinjiang. The trend was particularly apparent in winter and autumn with the rate of increase in the annual average minimum temperature being significantly higher than that of the maximum temperature. Rainfall also tended to increase in all three areas over the 50-year period, with the magnitude of change being highest in the mountainous area followed by northern Xinjiang and then southern Xinjiang. As a result of the rising temperatures, there was a negative material balance among the region's glaciers, of which the year 1982/1983 was the key year for the development of Tianshan mountain glacier snow. After this date, glacial ablation intensified with an annual change increase in average temperature of 1 °C, leading to a glacier material balance change of about 300 mm. To establish rainfall and temperature sequences for three regional climate change scenarios in the 2011–2050 period, we adopted the delta method using actual measurements during the 1961–2000 period against corrected data from rainfall and temperature simulations. All three scenarios indicated that temperatures will continue to increase, that the increase in rainfall may decrease in mountainous regions but will increase in the basin, and that the speed of glacial ablation in Xinjiang will continue to accelerate.     

青藏高原东南部贡嘎山海螺沟冰川冰下沉积物形成与变形

冰岩界面的冰川动力学是冰川系统的重要组成部分, 海螺沟冰川地处温暖湿润的海洋环境, 冰川运动速度较快, 冰川底部接近压融点, 是研究冰下过程的较理想地点. 在海螺沟冰川大型磨光面上浅显侵蚀坑内发现了碎屑物质. 对碎屑物质理化特征研究表明: 粒度特征、地球化学与石英砂SEM 分析表明沉积在冰岩界面上的物质来自于冰川底部的底碛层, 而不是冰上环境的产物. 偏光显微镜下观察到的冰下沉积物呈现出一系列塑性变形(微旋转、褶皱)和脆性变形(线性结构、支撑结构、断层)微观结构和构造. 两种变形结构的存在是碎屑物质在形成过程中其含水量波动情况的反映. 冰下碎屑物质是冰下融出、滞碛作用的共同产物. 在整个冰下碎屑物质形成与变形过程中, 由于冰下水系季节性变化带来的冰岩界面上冰川融水含量的波动起了决定性作用.     

贡嘎山海螺沟冰川消融区表面消融特征及其近期变化

冰川消融过程与水热条件、气象要素、冰面局地和周边地形以及冰川表面状况等密切相关.利用海螺沟冰舌段GPS测量的结果,对冰舌段的冰川近期变化包括规模变化和厚度减薄进行了新的评估.结果表明:自1989年以来冰舌段冰川厚度减薄约26%,远显著于20世纪60年代以来冰川面积的减少比例4.05%.基于对海螺沟冰川消融区冰舌段详细消...     

贡嘎山海螺沟冰川冰舌地段的泥石流

海螺沟冰川冰舌地段1976年以来发生过两次大的冰雪雨水泥石流。1989年7月8日和26日观景台西沟的泥石流通过1.7km长的冰面后,在冰川末端前形成一个5.5×10~4m~3的扇形地;1976年8月长草坝3号冰川下部冰碛体边坡的两处滑坡泥石流在开阔地上扩散堆积后,达1317.8m~3/s的泥石流和洪水下到冰川上。今后每年雨季还有可能发生更大规模的泥石流,值得人们警惕。     

贡嘎山亚高山演替林林冠截留特征与模拟

通过对贡嘎山亚高山峨眉冷杉与冬瓜杨演替林连续两年林下降水与树干径流的实验观测,分析研究了演替林林下降水、树干径流、林冠截留的变化特征,并验证了Gash(1995)模型模拟该区林冠截留的适用性.结果显示,2008年和2009年贡嘎山亚高山演替林林下降水分别占降水量的76.4%和77.0%,树干径流量较小,可以忽略不计,林...     

基于遥感和GPS的贡嘎山地区1966—2008年现代冰川变化研究

以对气候变化最为敏感的季风温冰川——贡嘎山冰川为研究对象,利用2002年的ETM+遥感影像和第一次冰川编目数据,提取两期冰川边界并叠加到一起,分析冰川变化趋势.结果表明:从1966年到2002年,贡嘎山冰川总体处于退缩状态,冰川总面积减少6.36%,年均减小0.447 km2,西坡冰川由41条减少到39条,面积减小7.89 km2,减小率为7.97%;东坡冰川由33条增加到36条,但冰川面积减少7.20 km2,减小率为4.71%.2008年5月GPS野外实地测量结果显示,1966—2008年的42 a,海螺沟冰川退缩约943 m,燕子沟冰川退缩494 m,小贡巴冰川退缩210 m,而大贡巴冰川长度基本保持不变,但冰储量在减少.在全球气候变暖的大背景下,温度升高可能是导致贡嘎山地区现代冰川退缩的主要原因.     

Source apportionment and distribution of atmospheric mercury in urban Beijing,China

The concentration of gaseous elemental mercury (GEM) in the atmosphere of urban Beijing was measured from October 2003 to September 2004 to investigate the origins and spatial-temporal variations of atmospheric Hg. The mean value of Hg concentration is 17.1 ng·m-3 (n=653). The atmospheric Hg data showed spatial-temporal variations throughout the duration of our observation. The maximum GEM concentration (53.7 ng·m-3) was observed at Gucheng in the western area of urban Beijing. The GEM concentrations increased from the north to the south of the studied area, and were higher in winter than in summer. The highest and lowest monthly averages of GEM concentrations were measured to be 23.3 and 4.1 ng·m-3 in January and July, respectively. In addition, GEM concentrations are higher in the daytime than at night in Autumn and from 14 March to 15 April, but daily GEM variation showed an inverse pattern from 22 April to 22 May. In winter, two peak values of GEM concentrations occurred at 13:30 and 21:30. Daily variation of GEM concentrations in summer was the lowest in the four seasons. Mercury from coal combustion was estimated to be the main source of anthropogenic emissions in Beijing from October 2003 to September 2004. Additionally, Hg emission from natural gas burning was estimated to be another dominant source of atmospheric Hg in Beijing.     

Application of multivariate spatial analysis in scale-based distribution and source study of PAHs in the topsoil: an example from Tianjin,China

Polycyclic aromatic hydrocarbons (PAHs) in soil originate from various sources under different spatial scales. Coregionalization analysis is more revealing than univariate geostatistical analysis. Scale-dependent spatial features of variables reflect different sources of spatial variability. In this study, 188 topsoil samples in the Tianjin area were collected. The contents of 16 PAHs and soil background properties were determined for all samples. A multivariate geostatistical approach was used for multi-scale spatial analysis for PAH compounds. Results show that coal combustion was the major source for the spatial distribution patterns of PAHs in the topsoil of the studied area. It worked mainly at the short-range scale (5–10 km). Significant spatial variation patterns were identified. In contrast, no significant spatial distribution trends at the nugget (0–5 km) or long-range scales (10–50 km) were seen. Long-range transport and site contamination of PAHs might not be key contributors in forming the distribution pattern of PAHs in the topsoil of Tianjin area.     

Characteristics of aerosol dust in fresh snow in the Asian dust and non-dust periods at Urumqi glacier no. 1 of eastern Tian Shan,China

Windblown mineral aerosol dust derived from the crustal surface is an important atmospheric component affecting the earth’s radiation budget. Deposition of atmospheric dust was measured in the fresh snow on glacier no. 1 at the headwater of the Urumqi River in eastern Tian Shan, central Asia. An analysis of seasonal variation of concentrations of dust particles in the snow suggests that the number concentration of dust particle is significantly high from April to June, which may be caused by Asian dust storms in the spring. The comparison of mass-size distribution of dust particles from April to August shows an obvious seasonal change trend. The distribution of particles changes from single model (3–21 μm) in the non-dust period before dust events in April, to bi-model (3–21 and 20–80 μm) during the Asian dust period, and to single model (3–21 μm) after July in the non-dust period again. The Ca²⁺ concentration in the fresh snow is also very high from April to June, while NH₄ ⁺ and SO₄ ²⁻, as water-soluble constituents, have concentration changes that are different from each other. Backward trajectory was also employed to examine the transport process of air mass in this region.     

Seasonal variations of major ions in fresh snow at Baishui Glacier No. 1, Yulong Mountain, China

This study presented a study of seasonal variations of major ion concentrations in fresh snow on Baishui Glacier No. 1, the largest glacier on Yulong Mountain, China. Fresh snow samples at Baishui Glacier No. 1 were collected from November 2008 to October 2009 for chemical data analysis. The results showed that the neutralizing effect of terrestrial source aerosols raised the pH value of fresh snow. The conductivity of fresh snow was much higher in dry season than that in rainy season. It was evident that the concentration of inorganic ions was generally higher in the dry season than that in rainy season, and the highest values occurred in the pre-monsoon period (April–May). The ions of fresh snow mainly came from terrestrial under the influence of west wind circulation and the Plateau monsoon in dry seasons, and had much complex sources in rainy season under the control of southeast and southwest monsoons. Both wind speed and precipitation had potential effects on ion concentration and composition of fresh snow as well. Moreover, principal component analysis showed that fresh snow ions were mainly from local lithology in dry season and from oceans in rainy season.     

Source Apportionment of PAHs Using Two Mathematical Models for Mangrove Sediments in Shantou Coastal Zone,China

Thirty-five surface sediment samples collected from three mangroves in Shantou coastal zone, China in 2007 were analyzed for a suite of polycyclic aromatic hydrocarbons (PAHs). Two mathematical models were used to determine the profiles and relative contributions of PAH sources to the mangroves. The two models are principal component analyses (PCA) with multiple linear regression analysis (MLR) and positive matrix factorization (PMF). Both models identified five factors and gave excellent correlation coefficients between predicted and measured levels of 16 PAH compounds, but the results had some differences. The PAH contribution rate attributed to vehicular emission sources identified by PCA-MLR was 37.20%, but the rate identified by PMF was only 12.37%. The main sources identified by PCA-MLR were combination of biomass/coal combustion and vehicular emissions, whereas the main source identified by PMF was only biomass/coal combustion. The PMF analysis was the preferred model for the paper data set.     

贡嘎山暗针叶林区森林蒸散发特征与模拟

通过对贡嘎山森林区的蒸发实验观测,利用修正的Penman-Monteith公式对地面和冷杉林蒸散进行模拟,并与水面实际观测资料进行对比。结果显示:控制该区蒸散的主导因子是太阳有效辐射、大气温度以及植被类型;对裸地、灌草、森林模拟的年内变化过程与水面蒸发的实际观测值趋势一致,分别在4月和9月出现两个明显的蒸发高峰。原始Penman公式可以用于裸露地面和短草地面的蒸发计算,然而对森林蒸散发应采用Penman-Monteith公式模拟,其模拟结果显示,在非生长季节森林蒸散发低于非森林地面,而在森林生长季节的蒸散发比非林地要高,其变化差异在±25%之间。因此修正的Penman-Monteith公式是森林地区水量平衡计算的有效工具。     

2008—2018年中国冰川变化分析

调查冰川资源的分布与变化,对区域乃至全球的自然环境与经济社会发展都具有十分重要的意义.基于315景Landsat 8 OLI遥感影像,结合中国第二次冰川编目数据与Google Earth软件,通过人工目视解译等方法调查了2018年中国冰川的分布与变化.结果表明:中国现存冰川53238条,总面积为(47174.21±19...     

Source,migration, distribution,toxicological effects and remediation technologies of arsenic in groundwater in China

Groundwater with high arsenic(As) content seriously threatens human life and health. Drinking high-As groundwater for a long time will lead to various pathological changes such as skin cancer, liver cancer,and kidney cancer. High-As groundwater has become one of the most serious environmental geological problems in China and even internationally. This paper aims to systematically summarize the sources,migration, distribution, toxicological effects, and treatment techniques of As in natural groun...