The Cretaceous-Tertiary boundary in a sector of the south limb of the Miranda-Treviño synclinal: the first appearance of chelonia and archosauria in the Basque country

This paper presents a study of the Cretaceous-Tertiary boundary in the Miranda-Treviño Synclinorium (Basque-Cantabric basin) where two main sequences have been recognised; the lower is regressive and theupper one has a marked transgressive trend. They are separated by a low angled un-conformity which is indicative of the Maastrichtian-Danian boundary.The lower sequence (S1) indicates a clear transition between the shoreface and backshore sub-environments. Bone accumulations are located in the sandy sediments of the upper foreshore and backshore, associated with ferrugenous hardgrounds and gypsum efflorescences.The upper sequence (S2) indicates the beginning of a marine transgression. It is composed a dominantly carbonate-rich sediments and the fauna suggests a deposition in environmental conditions ranging from stenohaline, to littoral, and to a coastal lagoon and inner carbonaterich platform.In the lower sequence (Maastrichtian Unit S₁ U₃), the following herpetofauna have been identified; an eusuchian alligator, and two dinosaurs (an ornithopod and a sauropod). Several plates of chelonia have been identified as? Adocus sp.     

Paleoenvironmental reconstruction of quaternary sedimentation in eastern Sri Lanka: An ichnological study

Quaternary sediment deposits are well exposed along the eastern coastal margin of Sri Lanka. Systematic trace fossil studies along with sediment characteristics have been carried out for the first time to interpret the paleoenvironment that prevailed during Quaternary sedimentation in eastern Sri Lanka. The trace fossils Thalassinoides, Skolithos and Polykladichnus have been recognized about 5m above the present mean sea level. Features of the major trace fossil, Thalassinoides, indicate that it was formed by Thalassinidean shrimp Calianassa. Isolated, vertical to steeply inclined, cylindrical to sub cylindrical tubes with thin internal wall lining and inner wall striations of Skolithos and Polykladichnus show that they were formed by polychaetes. The typical characteristic of Polykladichnus isY-shaped branching with slight enlargement at junctions. Morphology and association of burrows as well as mineralogy, grain size and roundness of sediments indicate that the environment prevailed was marine soft grounds of the intertidal zone. Presence of preserved fine-scale features of burrows indicate that the bioturbated sandy tidal flat was suddenly exposed to the tropical environment due to sea level regression in Quaternary periods. Due to the microbial activities of wall linings, burrows were preserved and it was supported by other microbial activities that produced secondary iron bearing minerals that suffered subsequent oxidation. The bio-origination of red sediments of eastern coastal area of the present study can be used to interpret the debatable origin of the red beds found in northwestern and southeastern coastal areas of the island.     

A short note on the geo-archeological significance of the ancient Theodosius harbour (İstanbul, Turkey)

The sedimentary sequence discovered at archaeological excavations in ancient Theodosius Harbour at İstanbul contains the records of sea level, environmental changes and the cultural history of the region. The cobbles at the base of the sequence include archaeological remnants of Neolithic culture that settled in the area between 8.4 and 7.3 ¹⁴C ka BP, and are located at 6 m below the present sea level. The sediments representing a coastal environment indicate that the area was used as a harbour from AD 4th to at least the 11th century and were filled by the sediments derived from Lykos Stream after 11th century.     

Benthic nutrient remineralization in a coastal lagoon ecosystem

In situ measurements of the exchange of ammonia, nitrate plus nitrite, phosphate, and dissolved organic phosphorus between sediments and the overlying water column were made in a shallow coastal lagoon on the ocean coast of Rhode Island, U.S.A. The release of ammonia from mud sediments in the dark (20–440 μmol per m² per h) averaged ten times higher than from a sandy tidal flat (0–60 μmol per m² per h), and while mud sediments also released nitrate and phosphate, sandy sediments took up these nutrients. Fluxes of nutrients from mud sediments, but not from sandy areas, markedly increased with temperature. Ammonia release rates for mud sediments in the light (0–350 μmol per m² per h) were lower than those in the dark and it is estimated that some 25% of the ammonia released to the water column on an annual basis may be intercepted by the benthic microfloral community. Estimates of the annual net exchange of nutrients across the sediment-water interface, weighted by sediment type for the lagoon as a whole, showed a release of 450 mmol per m² of ammonia, 5 mmol per m² of phosphate, 5 mmol per m² of dissolved organic phosphorus, and an uptake of 80 mmol per m² of nitrate. Although rates of ammonia and nitrate exchange were comparable to those described for the deeper heterotrophic bottom communities of nearby Narragansett Bay, rates of benthic phosphate release were significantly lower. On an annual basis the Bay benthos released approximately 20 times more inorganic phosphate per unit area than did the lagoon benthos. As a result., the N/P ratio for the flux from the sediments was 74∶1 in the lagoon, compared with 16∶1 in “average” marine plankton and 8∶1 for the benthic flux from Narragansett Bay. The lack of remineralized phosphate in the lagoon, is reflected in water, column phosphate concentrations (always <1 μm) and water column N/P ratios (annual N/P=27) and suggests that the lagoon may show phosphate limitation rather than the nitrogen limitation commonly associated with marine systems.     

Isotopic compositions of tropical East African flora and their potential as source indicators of organic matter in coastal marine sediments

The C and N stable isotope compositions of some flora of East Africa from coastal Tanzania and Amboseli National Park (Kenya) are used to assess if they can be used as a terrestrial end member during the estimation of terrestrial fraction in coastal marine sediments. The results of C isotope composition of various tree leaves, which average −29.3 ± 1.4%, indicate that these tropical higher land plant species follow a Calvin-Benson or non-Kranz (C₃) type of metabolism. The results for grass species, which average −13.2 ± 2.4%, indicate that most of them follow a Hatch-Slack or Kranz (C₄) type of metabolism. However, some of the succulent plants from the Amboseli National Park have δ¹³C values that average −14.7%, an indication that they follow a CAM (Crassulacean Acid Metabolism) type of metabolism. The N isotope values are relatively higher than expected for the terrestrial organic material. The average δ¹⁵N values for both tree and grass samples are higher than 5% and fall within the range normally considered to be marine. The high enrichment in ¹⁵N may be related to the environmental conditions in which plants thrive. Plants growing in sandy, dry and overgrazed environments are expected to be enriched in ¹⁵N owing to full utilisation of all available N species, regardless of their isotopic compositions. Other processes which may cause an enrichment in ¹⁵N include adsorption by various types of clay minerals, supply of ¹⁵N-enriched nitrate through sea-spray, and local denitrification, especially in swampy and lake margins where the input of organic matter may be higher than the rate of decomposition.The stable isotopic composition of organic C and N for surficial organic matter for the coastal marine sediments averages −17.0 ± 0.9% and 5.4 ± 1.1%, respectively. These values indicate a substantial contribution of C₄ plants and sea grasses. However, contribution of C₄ relative to that of sea grasses can not be evaluated owing to the fact that there is no significant difference in the isotopic compositions between the two groups.In the savannah environment, where a contribution from the C₄ types of plants might be substantial, the δ¹³C value for a terrestrial end member needs to be established prior to evaluation of the terrestrially derived organic matter in the marine environment. Owing to a significant contribution of sea grasses to the total organic matter preserved in coastal marine sediments, the stable isotopes of organic C seem to have a limited applicability as source indicators in the East African coastal waters. Furthermore, the results indicate that N stable isotopes seem to have a limited applicability as source indicators in coastal waters of East Africa. However, more work needs to be conducted to determine the terrestrial and sea grass end member values for the coastal areas.     

Environmental magnetic and geochemical characteristics of Chennai coastal sediments,Bay of Bengal,India

In this study, environmental magnetic, heavy metal and statistical analyses were conducted on 21 surface sediments collected from Chennai coast, India, to examine the feasibility of heavy metal pollution using magnetic susceptibility. The Chennai coastal sediment samples are dominated by ferrimagnetic minerals corresponding to magnetite-like minerals. The percentage of frequency dependent magnetic susceptibility reflects the presence of super-paramagnetic/single domain magnetic minerals in Chennai harbour, Cooum and Adayar rivers sediments. High pollution load index in sample E1, E2, CH7, C11, C12 and A16 is mainly due to anthropogenic activities such as, harbour activities, Cooum and Adayar rivers input and industrial effluent. Factor analysis shows that the magnetic concentration dependent parameters (χ, χ _ARM and SIRM) covary with the heavy metal concentrations, suggesting that the input of magnetic minerals and heavy metals in Chennai coastal sediments are derived from the same anthropogenic sources. Strong correlation obtained between pollution load index (PLI) and concentration dependent parameters (χ, χ _ARM and SIRM) for the polluted samples with magnetic susceptibility excess of 50×10^− 8 m³kg^− 1. Significant correlations between heavy metals and magnetic susceptibility point out the potential of magnetic screening/monitoring for simple and rapid proxy indicator of heavy metal pollution in marine sediments.     

Evidence for the zircon origin of cadmium anomalies in bottom sediments from the littoral zone of the northern part of Lake Ladoga

The minor-element composition of bottom sediments from the littoral zone of the northern part of Lake Ladoga was studied. Close relationships between the anomalous Cd concentrations in lake sediments and Quaternary glacial formations on the territory of Karelia were shown. A negative correlation of Cd with other heavy metals and a positive correlation with Zr were observed. Most likely, Cd is an impurity in zircons from sandy and sandy loam sedimentary formations on the northern coastal area of Lake Ladoga.     

The influence of tortuosity on molecular diffusion in freshwater sediments of high porosity

In sediments, diffusive transport of ions and molecules is basically influenced by two sediment characteristics: tortuosity and porosity. For the first time, the formation factor F, which combines the effect of tortuosity and porosity on diffusion, was quantified in freshwater sediments at submillimeter resolution. Sediment cores were treated with KCl and F was determined using a resistivity sensor and K⁺ selective electrodes.F was determined in sediments from different water depths of the eutrophic Lake Zug (Switzerland): In sandy sediments from a shallow site (12 m depth), F increased by approximately 50% within a few millimeters below the sediment surface. In clayey and silty sediments from the oxic (<80 m depth) and seasonally anoxic (80-120 m depth) zones of the lake, the initial increase in F was only 20%. In the permanent anoxic zone (>160 m depth), F increased by only 10% just below the sediment surface. Values of F were correlated with the porosity at each depth. We found close correlations of F = 1.02 · φ^−1.81 for clay-silt sediments, and F = 1.04 · φ^−1.21 for sandy sediments. The exponents are considerably smaller in Lake Zug than found for marine sediments, thus, diffusive transport seems to be less affected by tortuosity in this freshwater system.     

Rapid erosion of the coast of Sagar island, West Bengal - India

The coastal zone of the Sagar island has been studied. The island has been subjected to erosion by natural processes and to a little extent by anthropogenic activities over a long period. Major landforms identified in the coastal area of the Sagar island are the mud flats/salt marshes, sandy beaches/dunes and mangroves. The foreshore sediments are characterized by silty, slightly sandy mud, slightly silty sand and silty sand. Samples 500 m inland from high waterline are silty slightly sandy mud, and by clayey slightly sandy mud. The extent of coastline changes are made by comparing the topographic maps of 1967 and satellite imageries of 1996, 1998 and 1999. Between 1967 and 1999 about 29.8 km² of the island has been eroded and the accreted area is only 6.03 km². Between 1996 and 1998 the area underwent erosion of 13.64 km² while accretion was 0.48 km². From 1998 to 1999, 3.26 km² additional area was eroded with meager accretion. Erosion from 1997 to 1999 was estimated at 0.74 km² /year; however, from 1996 to 1999, the erosion rate was calculated as 5.47 km²/year. The areas severely affected by erosion are the northeastern, southwestern and southeastern faces of the island. As a consequence of coastal erosion, the mud flats/salt marshes, sandy beaches/dunes and mangroves have been eroded considerably. Deposition is experienced mainly on the western and southern part of the island. The island is built primarily by silt and clay, which can more easily be eroded by the waves, tides and cyclonic activities than a sandy coast. Historic sea level rises accompanied by land subsidence lead to differing rates of erosion at several pockets, thus periodically establishing new erosion planes.     

基于GPR图像的福建海坛岛北部海岸冲积扇沉积构造及其成因的初步研究

福建海坛岛北部海岸发育一座覆盖淡灰黄色风成砂层、相对高度达30 m的大沙山,外貌很像风成大沙丘,但同时又具有冲积扇形态。其成因和沉积环境有待考证,而探明大沙山内部沉积构造是判别其成因的主要途径之一。在野外考察的基础上,运用探地雷达（GPR）对大沙山内部沉积构造进行探测,获得约20 m深度范围内的沉积构造图像数据。结果表明:大沙山中上部发育由棱角状砾石或粗砂细砂组成的沉积旋回和沟槽沉积构造,显示出冲积扇上部的沉积构造组合特点;中下部层面中交替呈现弧形沉积构造,大沙山南侧发育有向南倾斜28°～30°的前积层理。结合大沙山西侧冲沟剖面沉积构造、大沙山表面的棱角状砾石特征以及现代风沙地貌分布规律,初步认为大沙山是山前多期沟谷洪流携带的碎屑物沉积形成的冲积扇残余堆积体,沉积间隙受海岸带风沙活动影响。     

A geochemical study of long-chain n-aldehydes in Washington coastal sediments

A series of n-aldehydes, C₂₀ to C₃₂, with strong even-to-odd carbon preference was identified in the mixture of solvent extractable lipids isolated from various Washington coastal sediments. A limited survey of the lipid composition of surface waxes of foliage and cuticular waxes of pollen from several major plant species indigenous to the Pacific Northwest revealed that similar series of n-aldehydes are intrinsic to regional vegetation. Debris from such plants, discharged at the mouth of the Columbia River, represents a “preformed” source of the n-aldehyde series accumulating in sediments from the Washington coastal region. Although the evidence suggests n-aldehydes are largely introduced erosionally to this region as a chemical component of land-derived debris and are not formed in situ in the coastal sediments, further study is warranted to establish the postdepositional stability of this series of compounds relative to other lipids of higher plantwax origin. Despite but few literature reports of the occurrence of these geochemicals, long-chain n-aldehydes are very likely common in many sediments from environments that receive an input of detrital organic matter from higher plants.     

Heavy metal distribution in surface sediments of the Tirumalairajan river estuary and the surrounding coastal area, east coast of India

Surface sediments collected at the Tirumalairajan river estuary and their surrounding coastal areas were analyzed for the bulk metal concentration. The sediments were collected from post- and premonsoon seasons. Dominances of heavy metals are in the following order: Fe > Mn > Zn > Pb > Cu in both seasons from estuary and coastal area. The results reveal that Fe, Mn, Cu, Pb, and Zn demonstrated an increased pattern from the estuary when compared to the coastal area. The heavy metal pattern of the sediments of the Tirumalairajan river estuary and its surrounding coastal area offered strong evidence that the coastal area was a major source of heavy metals to the estuarine region. For various metals, the contamination factor and geoaccumulation index (I _geo) have been calculated to assess the degree of pollution in sediments. The contamination factor and geoaccumulation index show that Zn, Pb, and Cu unpolluted to moderately pollute the sediments in estuarine part. This study shows the major sources of metal contamination in catchment and anthropogenic ones, such as agriculture runoff, discharge of industrial wastewater, and municipal sewage through the estuary and adjoining coastal area.     

Coastal progradation in response to the recent sea level rise: a case study of El Grine coast, Gulf of Gabes (Southeastern Tunisia)

Over the last 30 years El Grine coast recorded significant morphological changes leading to the shoreline progradation. Diachronic coastal evolution, through a set of satellite images data, supported by sedimentologic analysis of five sand cores have been applied to elucidate tidal flat reaction following the recent sea level rise. We found that an emerging sandy barrier and salt marsh domain were shaped by the local hydro-sedimentary processes. The marine sediments, mobilised by wave and tide currents, have been the sole sedimentary source. Recent sandy accumulations, occurred around 1987, have been able to balance a recent sea level rise. While during a mid-Holocene period, El Grine coast was governed by net erosion tendency inducing cliff recession.     

Coastal and ancient harbour geoarchaeology

What roles have human impacts and natural processes had in shaping the evolution of Mediterranean coastlines during the Holocene? Where, when and how did societies transform the coastal zone? At what scales and rhythms did these changes take place? What can ancient harbour sediments tell us about human‐environment interactions? During the past 20 years, geoarchaeological research in the Mediterranean has attempted to understand the interplay between culture and nature, and more particularly how environments and processes have played a role in Holocene human occupation of the coastal zone. This approach has drawn on the multidisciplinary study of sediments, as archives of information, to attempt to differentiate between anthropogenic and natural factors, the latter, we argue, having played an increasingly secondary role with time. Three important spatial scales of analysis have emerged, local, regional and Mediterranean, all of which are outlined here.     

Mobility of heavy metals in harbour sediments: an environmental aspect for the reuse of contaminated dredged sediments

Different methods to determine the source strength of two harbour sediment fractions were applied and are discussed with a focus on As, Cd, Cr, Co, Cu, Mo, Ni, Pb, and Zn. Four different batch experiments were performed with both the sandy and the silty fractions of harbour sediments sampled at the disposal site for dredged material in Bremen Seehausen, north Germany. In addition to the batch experiments a modified centrifugation tube was used in order to obtain pore water from the unsaturated silty fraction. Column experiments were run with the sandy fraction of the material under saturated and unsaturated conditions, irrigated with artificial acid rain water. The results show that the legal threshold value applying to Mo and Pb is not exceeded in any of the methods applied to the sandy or the silty fractions. As for the sandy fraction, Cr and Co were also below this limit. Cd, Ni, Cu and Zn exceeded the threshold values in some of the batch experiments applied to both fractions, depending on the pH value and the elution agent used in the experiment. All results obtained from saturated column leaching were below the respective threshold values; however, it should be noted that the pH was between 7 and 8 throughout the entire experiment. This pH also applied to the unsaturated column, with the exception of the first flush. This first sample had a pH value of 3.8, which was due to sulphide oxidation at the beginning of the experiment and led to strong leaching of all the elements under study. As a consequence, arsenic, Cu and Ni values exceeded their respective threshold values.     

Taraxerol and Rhizophora pollen as proxies for tracking past mangrove ecosystems

Angola Basin and Cape Basin (southeast Atlantic) surface sediments and sediment cores show that maxima in the abundance of taraxerol (relative to other land-derived lipids) covary with maxima in the relative abundance of pollen from the mangrove tree genus Rhizophora and that in the surface sediments offshore maxima in the relative abundance of taraxerol occur at latitudes with abundant coastal mangrove forests. Together with the observation that Rhizophora mangle and Rhizophora racemosa leaves are extraordinarily rich in taraxerol, this strongly indicates that taraxerol can be used as a lipid biomarker for mangrove input to the SE Atlantic. The proxy-environment relations for taraxerol and Rhizophora pollen down-core show that increased taraxerol and Rhizophora pollen abundances occur during transgressions and periods with a humid climate. These environmental changes modify the coastal erosion and sedimentation patterns, enhancing the extent of the mangrove ecosystem and/or the transport of mangrove organic matter offshore. Analyses of mid-Pleistocene sediments show that interruption of the pattern of taraxerol maxima during precession minima occurs almost only during periods of low obliquity. This demonstrates the complex environmental response of the interaction between precession-related humidity cycles and obliquity-related sea-level changes on mangrove input.     

Methane flux from mangrove sediments along the Southwestern coast of Puerto Rico

Although the sediments of coastal marine mangrove forests have been considered a minor source of atmospheric methane, these estimates have been based on sparse data from similar areas. We have gathered evidence that shows that external nutrient and freshwater loading in mangrove sediments may have a significant effect on methane flux. Experiments were performed to examine methane fluxes from anaerobic sediments in a mangrove forest subjected to secondary sewage effluents on the southwestern coast of Puerto Rico. Emission rates were measured in situ using a static chamber technique, and subsequent laboratory analysis of samples was by gas chromatography using a flame ionization detector. Results indicate that methane flux rates were lowest at the landward fringe nearest to the effluent discharge, higher in the seaward fringe occupied by red mangroves, and highest in the transition zone between black and red mangrove communities, with average values of 4 mg CH₄ m^?2 d^?1, 42 mg CH₄ m^?2 d^?1, and 82 mg CH₄ m^?2 d^?1, respectively. Overall mean values show these sediments may emit as much as 40 times more methane than unimpacted pristine areas. Pneumatophores ofAviciennia germinans have been found to serve as conduits to the atmosphere for this gas. Fluctuating water level overlying the mangrove sediment is an important environmental factor controlling seasonal and interannual CH₄ flux variations. Environmental controls such as freshwater inputs and increased nutrient loading influence in situ methane emissions from these environments.     

Elemental distribution of coastal sea and stream sediments in the island-arc region of Japan and mass transfer processes from terrestrial to marine environments

A total of 49 elements have been identified in 338 coastal sea sediment samples collected from an area situated off the Ise-Tokai region of Japan for a nationwide marine geochemical mapping project. The spatial distribution patterns of the elemental concentrations in coastal seas along with the existing geochemical maps in terrestrial areas were used to define the natural geochemical background variation, mass transport, and contamination processes. The elemental concentrations of coastal sea sediments are determined primarily by particle size and regional differences. Most elemental concentrations increase with a decrease in particle size. Some elements such as Ca, Mn, and Yb are found to exist in large quantities in coarse particles containing calcareous shells, Fe–Mn oxides, and felsic volcanic sediments. Regional differences reflect the mass transfer process from terrestrial areas to coastal seas and the influence of the local marine geology. An analysis of variance (ANOVA) reveals that for many elements, the particle size effect is predominant over regional difference. The mean chemical compositions of coastal sea sediments are similar to those of stream sediments in adjacent terrestrial areas and in the upper crust of Japan. This observation supports the fact that coastal sea sediments have certainly originated from terrestrial materials. However, the spatial distributions of elemental concentrations are not always continuous between the land and coastal seas. The scale of mass movement observed in marine geochemical maps occurs at a distance of 20 km from the river mouth. A detailed examination of the spatial distribution patterns of K (K₂O) and Cr concentrations suggests that terrestrial materials supplied through rivers are deposited near the shore initially, and then gravity-driven processes shift the sediments deeper into the basin. Contamination with heavy metals such as Zn, Cd and Pb was observed in coastal bays surrounded by urban and industrial areas. It is noteworthy that the areas with the highest concentration of these elements usually do not occur near the shore (not near the contamination source) but at the center of the bay. Unexpected low concentrations of Zn, Cd and Pb near shore may either be due to a decreased anthropogenic load in the most recent sediments or to dilution by unpolluted flood sediments.     

Sedimentological and geomorphological effects of the Sumatra–Andaman Tsunami in the area of Khao Lak,southern Thailand

The Sumatra–Andaman Tsunami left distinctive sedimentological and geomorphological signatures in the area of Khao Lak. Fine-grained sediments, predominantly layers of cohesive, carbonate-rich, fine-sandy silt with thicknesses of 1–10 cm, erosionally overlying pre-tsunami sandy soils and sediments, represent the most common tsunami deposits in the study area. Petrographically, they differ significantly from other coastal sediments and affiliated soils. Due to their grain size and corresponding clay mineral content, muddy shelf sediments (sub-wave base) are indicated as a main source. The present results suggest that indications of shelf influence, although varying regionally, might contribute to the identification of fine-grained tsunami sediments and their differentiation from storm sediments. However, the observed differences of tsunami sediments to soils and other coastal sediments, especially with respect to carbonate mineralogy, might disappear in short geological time under conditions of intensive weathering and bioturbation. At Cape Pakarang, hundreds of boulders with up to 24 tons were deposited on the foreshore and upper shoreface. Applying Nott’s (Earth Planet Sci Lett 210:269–276, 2003) formulas, minimum flow velocities of 3.9 m/s are required to transport the largest boulders. The devastating tsunami effect of both, onshore flow and backflow, is documented by damaged human constructions. Geomorphological effects include intensive widening of estuary mouths and the development of erosional channels. Now, estuary mouths are reduced, and erosional channels cut off from the sea due to the formation of a post-tsunami beach ridge.