铜陵矿集区舒家店矿区正长花岗岩的年代学和地球化学特征及其指示意义

舒家店岩体位于长江中下游成矿带中部的铜陵断隆区,与繁昌断凹区(盆地)临近,主要的岩浆岩岩石类型有辉石闪长岩、石英闪长斑岩和花岗闪长岩等。正长花岗岩为舒家店岩体深部新发现的岩石类型,其矿物组合与岩体内其他类型岩石明显不同,其形成的背景存在争议。本文通过对岩体中正长花岗岩的锆石LA-ICP MS精确定年、Hf同位素和地球化学组成分析,研究舒家店岩体正长花岗岩的年代学、岩浆源区等问题。研究显示舒家店岩体为"异源同体"的复式岩体,岩体中的正长花岗岩的侵入时间为126.5±1.6Ma~129.8±2.4Ma,明显晚于早期的辉石闪长岩和石英闪长斑岩(138.2±4.6Ma~143.7±1.7Ma),也明显晚于舒家店斑岩型铜矿床的形成时代。全岩元素地球化学和锆石Hf同位素组成指示舒家店岩体中正长花岗岩为叠加到早期辉石闪长岩及石英闪长斑岩之上的后期岩浆活动的产物,可能与繁昌盆地内花岗岩有相同的源区,为新元古代新生地壳(类似新元古花岗岩)部分熔融的产物,其岩浆源区处于高温低压的环境,相较于辉石闪长岩和石英闪长斑岩起源更浅,指示长江中下游成矿带在145~123Ma地壳处于不断减薄的过程。     

安徽省铜陵矿集区狮子山岩浆流体系统地球化学测试数据集

铜陵矿集区是中国最著名的铜、金、铁产地之一,该矿集区内成矿与岩浆作用关系密切。狮子山岩浆流体系统分布最为广泛,是铜陵矿集区岩浆活动与成矿作用的主体,为众多地质学家所重视。狮子山岩浆流体系统地球化学测试数据集包括系统内具有代表性的34件岩石样品主微量元素数据、32件流体包裹体显微测温数据; 5件石英包裹体稀土、微量元素数据; 28件样品C-H-O同位素数据及27件样品的硫同位素测试数据。全部测试均在国家知名测试数据实验室进行,数据质量可靠。该数据集可以反映狮子山岩浆子系统的岩浆活动特征、成矿流体特征、成矿物质来源,为揭示矿床成因、成矿流体来源及演化等科学问题提供数据支撑。     

铜官山矿田深部构造的三维计算模拟及其找矿意义

计算模拟已成为研究矿田深部三维构造重要可行手段,对深部找矿具有重要意义。基于铜官山矿田地质背景及所获勘查数据特征,我们采用知识驱动下多级约束和多源数据融合建模方法模拟矿田范围内–2000 m以上主要地质界面。以逆冲推覆导致断展–断弯褶皱理论模式解释大地测深的电阻率数据,推断地质界面位置,在Micromine-GOCAD耦合平台上在多级约束下融合多源的界面位置数据,以离散光滑插值算法和Delaunay三角网剖分法重构主要地质界面,在计算机虚拟空间再现矿田三维构造格架。结果显示:铜官山岩体和天鹅抱蛋岩体三维形态变化复杂,总体上向西倾,向深部岩体规模快速变小。位于铜官山岩体东接触带的铜官山铜矿田深部无找矿潜力,原因是接触带产状变陡,并且是岩体直接与上泥盆统砂岩接触;矿田深部主要构造为走向NE并沿倾向弯曲的逆冲推覆断层;铜官山背斜东翼含矿的中–上石炭统层位向深部倒转后又在–1200 m至–1500 m深度返转成向东南缓倾的正常层位,其底部与逆冲推覆断层重合,是深部找矿的有利靶区。     

安徽铜陵岩浆岩中辉长质岩石包体的发现及其地质意义

在安徽铜陵白芒山、老庙基和小铜官山岩体中发现了3个辉长质岩石包体。报道了这些辉长质岩石包体及其寄主岩的岩相学观察以及矿物电子探针和全岩岩石化学、微量元素、稀土元素和锶钕同位素分析资料,总结了辉长质岩石包体的特征,讨论了它们的地质意义。该区辉长质岩石包体主要有两类。一类具“斑状”结构,“斑晶”主要是斜长石和角闪石。“基质”具微粒半自形一自形等粒状结构,主要矿物成分为斜长石和角闪石;另有少量黑云母,有时还有少量辉石。另一类具辉长结构,主要由辉石、斜长石、角闪石和黑云母组成。本区辉长质岩石包体低铝高镁和富碱,其Cr,Co和Ni的含量明显偏高,重稀土元素,特别是钇相对富集,(^87Sr／^86Sr)．为0．7063到0．7069,εNd(t)为-4．9～-8．8,与大陆裂谷碱性玄武岩的特征一致,表明本区此时属于拉张环境。研究还表明,铜陵地区不具“斑状”结构的辉长质岩石包体是由底侵的碱性玄武岩浆在约26km深处的深位岩浆房中直接冷凝结晶形成的。本区具“斑状”结构的辉长质岩石包体中的“斑晶”由闪长质岩浆在8～13km深处的中位岩浆房中发生结晶分异作用形成,而“基质”是在“斑晶”形成以后,由深位岩浆房中的中基性演化岩浆上侵到中位岩浆房,并围绕早期“斑晶”矿物结晶而形成。     

安徽铜陵冬瓜山矿床中磁黄铁矿矿石结构特征及其成因意义

安徽铜陵冬瓜山矿床是长江中下游地区具有代表性的大型层状硫化物矿床,磁黄铁矿为矿床中的主要硫化物矿物.该矿床主要由层状硫化物矿体组成,伴有矽卡岩型和斑岩型矿体.在层状矿体上部,磁黄铁矿主要为块状构造,而层状矿体下部,磁黄铁矿多为层纹状、条带状构造,具有显著的沉积结构构造特征.野外地质观察及室内矿相学研究表明,层状矿体中磁黄铁矿矿石遭受了强烈的变质作用及热液交代作用.进变质过程中形成的结构主要为胶黄铁矿转变为黄铁矿以及进一步变质转变为磁黄铁矿、磁铁矿时形成的交代残留结构.退变质过程则以磁黄铁矿的退火、黄铁矿变斑晶的生长和单纯六方磁黄铁矿的形成为特征.岩浆热液对单纯六方磁黄铁矿的交代作用形成了单斜和六方磁黄铁矿的交生结构.这些结构特征表明层状矿体中的磁黄铁矿并不是岩浆热液成因,而主要为石炭纪同生沉积胶黄铁矿、黄铁矿在燕山期岩浆侵入所引起的热变质作用下脱硫所形成,并在热变质作用之后又受到岩浆热液的叠加交代.磁黄铁矿的结构特征显示冬瓜山矿床的形成经历了同生沉积、热变质、热液交代等多个阶段,支持其为同生沉积-叠加改造型矿床.     

Numerical Simulation of Fluid Migration during Ore Formation of Carboniferous Exhalation-Sedimentary Massive Sulfide Deposits in the Tongling District, Anhui Province

Numerical simulation of fluid migration during the ore-forming process of the Carboniferous exhalationsedimentary (Sedex) massive sulfide deposits in the Tongling district shows that fluid and thermal activities in lying-wall rocks were limited to a small area around the main draining passage, which led to weak mineralization and alteration in the lying-wall rock. Temperature and fluid fields indicate that mineralization and alteration in the lying-wall rock of the Sedex-type deposits are usually weaker than those of volcano-hosted massive sulfide deposits. Fluid migration involves the following processes: seawater penetrating and leaching the lying-wall rocks, then mixing with ascending hydrothermal fluids in the main draining passage, and finally jetting into seafloor. Although fluid activity-influenced area is rather small,the content of metals leached out from the lying-wall rocks is high enough to form large-scale ore deposits. Tensional contemporaneous faults accompanied with strong heat flows controlled the formation and distribution of Sedex deposits.The tensional tectonic regime on the northern margin of the Yangtze block during the Hercynian provided Sedex deposits with a prerequisite geodynamic condition.     

安徽铜陵凤凰山夕卡岩型铜矿床中辉钼矿Re-Os同位素年龄及其地质意义

铜陵矿集区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的有色金属基地之一,凤凰山矿床是铜陵矿集区的重要组成部分,为一个典型的夕卡岩型铜矿床。本文利用Re-Os同位素定年方法对凤凰山铜矿床进行了成矿时代测定,获得了辉钼矿的Re-Os同位素模式年龄范围为139.1±2.4～142.0±2.2Ma,等时线年龄为141.1±1.4Ma,与矿区内石英二长闪长岩和花岗闪长岩SHRIMP锆石U-Pb年龄(144.2±2.3Ma)相吻合,也与铜陵地区其他矿田的成矿时代基本一致,可能为岩石圈减薄事件的成矿响应。     

Prediction of hidden ore bodies by synthesis of geological, geophysical and geochemical information based on dynamic model in Fenghuangshan ore field, Tongling district, China

Although the Tongling district is one of the most important Cu districts in China, exploration strategies need to be urgently updated to achieve a more predictive method for discovering hidden ore bodies. This paper presents a case study showing how new exploration strategies were developed and successfully used to discover a hidden ore body in the Fenghuangshan ore field of the Tongling district. All previously discovered ore bodies in the Fenghuangshan ore field were Cu skarn deposits located where dilational fault zones cut the contact zone of the Xingwuli granitoid complex. The features of the ores and the related magmatic rocks and hydrothermal alteration suggest that porphyry copper deposits are also likely to be present in the ore field. After assessing spatial controls on ore formation, ore-related indicators numerical simulating the coupled thermal–hydrological–mechanical processes during syn-deformation cooling of the Xingwuli Intrusion were used to choose a target area to the south of the Fenfhuangshan mine. In this target area, we have carried out an exploration program involving mapping, rock chip sampling for Cu in the fractured and altered rocks, and pesu-random triple frequency induced polarization (IP) and the controlled source audio-frequency magnetotellurics (CSAMT) surveys. Synthesis of the data obtained in this program identified a target that was subsequently drilled. This test hole demonstrated the presence of high grade Cu ores typical of both skarn and porphyry copper deposits.     

安徽南陵姚家岭铜铅锌矿床的发现及意义

姚家岭铜铅锌矿床是长江中下游金属成矿带铜陵矿集区近年来普查新发现的大型矿产地.矿床类型是与燕山晚期隐爆斑岩体侵入活动相关的浅成热液充填交代-斑岩型矿床。姚家岭铜铅锌矿床的发现,反映了该区成矿的多样性和复杂性,突破了本区矽卡岩型和层控叠加改造型两个传统的成矿模式。对铜陵矿集区乃至长江中下游地区的深部找矿工作具有十分重要的指导意义。     

矽卡岩矿床的汇流扩容空间控矿机制及其对深部找矿的意义:以铜陵—安庆地区为例

本文以铜陵-安庆地区凤凰山铜矿和安庆铜矿为例,通过野外地质分析和计算模拟实验探讨了浅成岩体冷却过程中接触带上汇流扩容空间对矽卡岩矿体的控制.在风凰山矿田和安庆矿田,围绕新屋里岩体和月山岩体的接触带上矿体的分布极不均匀,形成大规模矽卡岩矿体的位置既与接触带本身的特征有关,也与构造变形有关.矿体的边界特征以及与矿体密切相关的角砾岩的特征表明水压致裂在赋矿扩容空间的形成过程中可能起重要的作用.矿体的围岩蚀变特征以及流体包裹体地球化学特征显示来自岩体和囤岩的流体的混合以及高压流体的减压沸腾可能是矿石沉淀的主要机制.新屋里岩体和月山岩体的同构造冷却过程力学变形-传热-流体流动耦合动力学计算模拟结果显示:所有矿体都位于汇流扩容空间内,且主矿体位于最大最强的汇流扩容带内,这表明力-热-流耦合作用形成的汇流扩客空间不仅控制了矿体的位置,也控制了矿体的规模.在铜陵-安庆地区开展深部找矿勘查,应该将重点放在大规模高强度的汇流扩容区,特别是还没有发现大规模矿体的汇流扩容区,凤凰山和安庆铜矿深部找矿已取得的成果证明了汇流扩容空间控矿模式对这一地区深部找矿勘查具有重要意义.     

安徽铜陵矿集区南部新生代岩浆活动——来自科学深钻TK01的证据

本文主要是对铜陵矿集区南部丁桥科学深钻中的碱性辉长岩进行了LA-MC-ICPMS锆石U-Pb定年,年龄为63.54±0.53 Ma,表明碱性辉长岩是新生代岩浆侵入活动的产物。全岩主、微量研究结果表明TK01中的碱性辉长岩富钾(K_2O平均为1.75%)、富碱(K_2O+Na_2O平均为3.90%)、富钛(TiO_2平均为1.58%),富集大离子不相容元素和轻稀土元素,亏损重稀土元素,属于过铝质岩石。SiO_2-K_2O图解中,样品点落在含钾较高的钾玄岩和钙碱性区域中,岩浆演化过程中有矿物的分离结晶作用。碱性辉长岩的锆石εHf(t)值介于-4.7~-11.5。推测TK01中的碱性辉长岩主要来源于富集地幔,稍有陆壳物质的混染,岩浆形成于大陆板内拉张的构造背景。     

地球化学块体与大型矿集区的关系——以东天山为例

通过在东天山15万km2的战略性深穿透地球化学调查共圈出大于1000km2以上的地球化学块体18处,其中铜-铅-锌-银地球化学块体5处,铜地球化学块体3处,铜-镍地球化学块体1处,金的地球化学块体4处,铀的地球化学块体3处,铂-钯地球化学块体1处,钨地球化学块体1处。有6处地球化学块体与已知矿集区相对应,新圈定的地球化学块体12处,其中有3处发现了新的矿床。根据这些块体与矿集区的对比得出如下结论:所有的已知矿集区都位于地球化学块体的范围之内,地球化学块体为矿集区的形成提供了丰富的物质基础;有矿集区的存在一定有地球化学块体的存在,但反过来有地球化学块体的存在不一定有矿集区的存在,地球化学块体是客观存在的,而矿集区是已经发现了一系列矿床并勘探到一定程度才能称作矿集区,因此,地球化学块体内可能会存在潜在的矿集区,这为利用地球化学块体预测新的矿集区提供了依据。     

复杂形态岩体接触带成矿耦合动力学三维数值模拟:以安庆铜矿为例

安庆铜矿是长江中下游成矿带中重要的矽卡岩矿床,其矿体绝大部分产在形态复杂的岩体接触带上,对于这种矿体定位特点,本文采用数值模拟的方法探讨了其动力学机制和主要的控矿因素。首先以AutoCAD和GO-CAD为平台构建安庆铜矿岩体及围岩的三维实体模型,并通过C++编程实现到模拟软件的模型格式转换,然后以FLAC3D为平台进行安庆铜矿热液成矿过程的力-热-流耦合数值模拟。结果显示,受控于拉张应力场,岩体大部分位置表现为正的体应变;月山岩体东枝南接触带是扩容最为明显的区域,部分岩石单元的大扩容角对扩容区出现有一定的贡献,岩石物理性质的差异及接触带的复杂形态则是其主要原因;岩石扩容部位成为流体汇集的有利场所,汇流部位与明显扩容区及主矿体产出位置相一致,推断矿体的定位是力-热-流共同作用的结果;运算结果亦指示现有矿体深部存在新的有利找矿靶区。     

安徽铜陵矿集区斑岩型铜钼金矿床地质特征及成矿背景

铜陵矿集区以发育大型和为数众多的矽卡岩型矿床而闻名于世,而近年来作为该区找矿的重要成果和突破则是斑岩型矿床和矿化的陆续发现。本文以铜陵矿集区3个代表性斑岩型矿床为研究对象,在详细的野外地质调查和室内显微观察研究的基础上,开展了较为系统的矿床地质和地球化学研究,阐述了斑岩型矿床的地质特征,确定了含矿侵入岩体的地质和地球化学特征,分析了矿床蚀变特征和流体包裹体特征,探讨了成岩成矿的大地构造背景,并与世界典型斑岩型矿床进行了对比。研究表明,铜陵矿集区斑岩型铜钼金矿床通常发育于含矿岩体的围岩或盖层为砂岩、砂页岩或硅质岩的条件下,含矿岩体为富碱低镁高钾准铝质钙碱性系列中浅成侵入岩体,具有与埃达克岩一致的地球化学特征;与世界典型斑岩型矿床含矿岩体对比,岩体侵位较深,有些矿区多期多相特征不明显;含矿岩体发育钾硅酸盐化、黄铁绢英岩化、青磐岩化等热液蚀变且有一定的分带性,但各矿床蚀变特征略有不同;矿床矿石矿物中富气相、富液相和含子晶多相包裹体共生,流体包裹体均一温度和盐度演化特征显示具有岩浆作用控制的高温热液型矿床特征。结合区域构造演化,作者确定铜陵矿集区斑岩型矿床属大陆环境斑岩型矿床,成矿作用发生于陆内造山作用由挤压向拉张转化的动力学背景之下,斑岩型矿床与矽卡岩型矿床及热液脉状矿床共同构成受统一的岩浆热液系统控制的矿床系列。     

Shear Alteration, Mass Transfer and Gold Mineralization: An Example from Jiaodong Ore Deposit Concentrating Area, Shandong, China

Since Ramsay and Graham (1970 ) system atically deliv-ered study results of ductile shear zone,the study on shearzone has been put forward rapidly and has obtained greatachievements.After the“gold- bearing shear zone” type ofmetallogenic model proposed by Bonnemaison(1986 ) ,lots ofstudies showed that large gold- bearing shear zone system,which underwent multi- stage and multi- level tectonic- m inerl-ization evolution,is a complex deformational metam orphic ge-ological body with different d…     

Petrogenesis and metallogenic implications of Late Mesozoic intrusive rocks in the Tongling region,eastern China: a case study and perspective review

ABSTRACT

Large-scale Cu–Au mineralization is associated with Late Mesozoic intrusive rocks in the Tongling region of eastern China, which mainly comprise pyroxene monzodiorite, quartz monzodiorite, and granodiorite. To constrain the petrogenesis of the intrusive rocks and Cu–Au mineralization, detailed analyses of the geochronology, apatite in situ geochemistry, whole-rock geochemistry, and zircon Hf isotopic compositions were performed. Magmatic zircons from pyroxene monzodiorites, quartz monzodiorites, and granodiorites yield U–Pb ages of 136–149 Ma, 136–146 Ma, and 138–152 Ma, respectively, indicating that their formation ages are contemporaneous. Quartz monzodiorites and granodiorites (SiO₂ = 57.9–69.5 wt.%) are highly potassic calc-alkaline rocks with adakitic affinity and have low MgO and Y contents, low zircon ε_Hf(t) values (?11.7 to ?39.0), high apatite Cl contents (>0.2 wt.%), and log fO₂ values (?23.2 to ?8.23), indicating that they may have formed when metasomatized mantle-derived magmas mixed with slab-derived magmas before undergoing crustal assimilation and fractional crystallization. Pyroxene monzodiorites (SiO₂ = 48.4–53.0 wt.%) are shoshonitic and record high MgO, P₂O₅, and Y contents, high zircon ε_Hf(t) values (1.55 to ?7.87), high oxygen fugacity, low Nb and Ta contents, and low apatite Cl contents (mainly <0.2 wt.%), suggesting that they were primarily derived from a metasomatized lithospheric mantle-derived magma that experienced the assimilation of lower crustal materials. The results indicate that the intrusive rocks and associated large-scale Cu–Au mineralization of the Tongling region resulted from the partial melting of the subducted oceanic slab in an oxidizing environment.     

中国金矿资源特征及勘查方向概述

基于金矿成矿地球动力学环境以及矿床基本地质特征等,将中国金矿床类型归纳为11 类,其中以构造破碎带蚀变岩型、中深成侵入岩体内及其外接触带型、卡林-似卡林型、浅变质碎屑岩中热液型、陆相火山岩型等为主要找矿类型;成矿年代以中生代、新生代为主。在中国Ⅲ级成矿区带划分基础上,总结研究大地构造单元、地质演化、成矿地质条件、空间分布特征、金矿类型、区域成矿要素、资源量等,初步厘定42 个金矿集区,其空间呈集中分布特征。根据金矿勘查单位面积的钻探数量,初步将中国金矿集区划分为高、中、低工作程度区,高程度区主要分布在中东部地区;除砂金矿外,中国88.12%的岩金（伴生金） 矿探矿深度在500 m 以上,说明探矿钻探验证偏少、偏浅。文章还探讨了中国金矿集区资源找矿潜力,提出了勘查找矿方向和建议,指出中东部老矿山深部、外围和西部金矿集区特别是位于新疆、青海、西藏等地区的,是未来找矿潜力重点区域,未查明资源储量巨大。     

Numerical Modeling of the Coupled Mechanical and Hydrological Processes during Deformation and Mineralization in the Mount Isa Block, Australia

Mount Isa is a major Australian and world Pb‐Zn‐Ag mineral province. The wide varieties of mineralization in the province are believed to be closely related to the geodynamic processes of Isan Orogeny, which occurred between ca 1500 and 1620 Ma. In order to understand the geodynamic processes associated with the Isan Orogeny and the giant mineralization systems in the Mount Isa district, a series of numerical models has been constructed to simulate coupled mechanical–hydrological processes, using Fast Lagrangian Analysis of Continua (FLAC), a finite difference computer code. The numerical modeling results have demonstrated that the most probable far‐field stress orientation during the Isan Orogeny is the asymmetrical E–W shortening, which led to greater easternward tectonic movement at the west boundary of the district in comparison with westward movement at the east boundary. During the initial and early stage of the Isan Orogeny, the mechanical and hydrological conditions in the Leichardt Fault Trough of the West Fold Belt are much more favorable for fluid accumulation and mineralization than in the East Fold Belt. The Mount Isan fault zone developed as a high dilation shear zone where the fluids were focused. As the asymmetrical shortening progressed, shortening deformation and shear strain localization became intensified in the eastern part of the orogenic district. The eastern region therefore became a more favorable locality for hydrothermal mineralization. This structural development feature seems to explain why mineralization in the East Fold Belt is generally later than in the West Fold Belt. Fluid production from the Williams–Naraku granites could result in fluid over‐pressuring, and this probably contributed to the extensive brecciation and related mineralization in the East Fold Belt.     

Meta分析在深部找矿预测中的应用——以铜陵铜山铜矿为例

为了深入研究找矿技术方法的优选和集成,引入了"有效性"的概念来衡量某种探测技术方法的找矿预测效果.Meta分析是一种起源于医学领域,对具备特定条件的、同类研究主题的大量研究结果进行综合后统计的超常规综合统计方法.文中对引入Meta分析的思路和可行性充分分析论证后,以铜山铜矿为例,首次应用Meta分析方法对CSAMT,TEM,EH4三种物探方法所获得的二维反演剖面进行了三种方法找矿预测的有效性定量对比研究.结果表明,在铜山铜矿前山南测区,CSAMT法与EH4法的找矿预测有效性比TEM法明显要高;而CSAMT法和EH4法的找矿预测有效性没有明显差异.     

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。