新疆塔尔巴哈台-萨吾尔地区多重分形地球化学异常提取及成矿预测

塔尔巴哈台-萨吾尔地区位于中国新疆西北部,目前已发现若干处铜、金矿床,具有很好的成矿潜力。成矿定量预测方法常被用于综合成矿标志信息,进行成矿远景区的定量预测和评价。本文首先结合多重分形理论-奇异性指数模型进行地球化学异常提取,之后通过对区域成矿条件进行综合分析,基于地球化学异常以及构造、岩浆岩、地层与矿化的相关关系构建了塔尔巴哈台-萨吾尔地区铜-金成矿预测模型;研究进一步基于新近的找矿成果,以已知矿床和新近发现的矿化点信息作为依据,利用证据权重方法对研究区铜-金矿化的远景区进行了定量预测。预测结果显示出塔尔巴哈台-萨吾尔地区具有良好的找矿前景,区内存在多个新的成矿远景区,可作为新的找矿勘探的目标,开展进一步找矿勘查工作。     

广西平南县新坪金矿成矿规律及找矿预测

新坪金矿地处广西大瑶山成矿带的东部,是桂东南地区一个较为典型的构造破碎蚀变岩型金矿。调查发现：矿区内金矿体(金矿化)主要赋存于寒武系黄洞口组中,部分金矿体(金矿化)赋存于花岗斑岩与寒武系硅化砂岩接触破碎带以及花岗斑岩体内,近EW向、NE向的次生断裂和裂隙是主要的容矿构造,而金矿化强度与硅化、黄铁矿化、绢云母化关系密切。根据新坪金矿的矿床地质特征、成矿规律和化探异常进行综合分析,圈定了矿区内2个成矿远景区及6个找矿靶区。     

湘东南水口地区水系沉积物地球化学特征及找矿预测

利用1∶5万水口幅水系沉积物测量成果,分析研究湘东南水口地区水系沉积物地球化学特征。利用DGSInfo软件对元素分布、单元素异常、元素相关性、异常元素组合等特征进行分析研究,认为W、Sn、Bi、Cu、Ag为区内的主要成矿元素,共圈出15处地球化学综合异常。结合综合异常所处的成矿地质条件进行综合分析,划分为下湾毒砂金锑找矿远景区、联坑—渣村钨钼铜铅锌多金属找矿远景区、曾子坳—鹰咀岩—田心钨锡铜多金属找矿远景区。通过对远景区内的综合异常查证,在下湾AS1综合异常区、联坑AS3综合异常区、曾子坳AS6综合异常区均找到了与异常相关的矿化信息。结果表明,水系沉积物地球化学测量在该区具有较好的找矿效果,为研究区下一步的找矿工作指明了方向。     

西藏革吉县尕尔穷铜金矿区岩石地球化学勘查异常特征及找矿方向

尕尔穷矿区具有三种类型矿化:产于斑岩型中的铜钼(金)矿化、产于矽卡岩中的铜金矿化和产于构造破碎带中的铜金矿化,三种矿化类型同属斑岩成矿系统。岩石地球化学测量结果表明,矿区存在R-1、R-2和R-3等三个主要异常,三个异常区的元素分布特征大体相似,R-1由异常浓集中心向外具有Cu-Mo-Se-Te-(Bi)-Pb-Zn-As-Sb-Tl的元素分带现象,这种元素组合及分带具有高温→中低温成矿演化的特点,特征与斑岩成矿系统很相似,具有寻找斑岩型矿床的潜力;R-2异常区Te、Se、Sb、Pb、Zn等外围元素在此范围内较弱的异常和Cu、Mo的强异常表明此异常区遭受剥蚀程度较大;R-3异常区是与石英闪长岩和花岗闪长岩有关的斑岩型矿化、矽卡岩矿化和构造破碎带中的矿化,其中以矽卡岩型和构造破碎带中的矿化的找矿前景最好,深部斑岩型矿化也具有一定的找矿潜力。     

宁夏贺兰山北段1∶5万化探数据的含量-面积分形异常特征及找矿预测

以宁夏贺兰山北段金铜矿产资源预测为研究对象,采用R型因子分析研究元素组合规律,应用含量-面积分形法研究地球化学异常并确定其异常下限,圈定元素组合异常和综合异常,并结合区域成矿地质背景和研究区地质-地球化学特征,划分出5处找矿远景区:哈尔木腾、柳葫芦沟-大麦里沟、树龙沟-麦子井金找矿远景区;梁根-牛头沟-其勒格金铜找矿远景区;达拉布盖钴镍找矿远景区。异常查证结果显示,梁根-牛头沟目前已控制3条工业矿体,为有利的金铜找矿靶区,其勒格已发现5处金矿化体,成矿地质条件良好,为下一步重点找矿地段。     

新疆汉水泉地区水系沉积物测量地球化学特征及找矿方向

对汉水泉地区水系沉积物地球化学特征进行分析,结合工作区成矿地质条件共圈出8个综合异常。对Y1综合异常进行查证,发现3条铜矿化蚀变带,其内发育数条铜矿化体,表明水系沉积物地球化学测量在该区具有较好的找矿效果。在综合异常分析和查证的基础上,结合区域成矿地质条件、区内矿产地质特征,圈定出3处找矿远景区,即868高地铜金找矿远景区、咸水泉西部铜金找矿远景区和咸水泉石膏找矿远景区,为该区下一步找矿工作指明了方向。     

西秦岭温泉—中川一带金属矿床的成矿规律及找矿预测

西秦岭温泉—中川一带实施的1:5万矿产地质调查项目,共圈定1:5万局部高磁异常33处,1:5万地球化学综合异常11处,发现矿点2处,矿化点5处,矿种有金、钼、铁、铜、铷等。通过分析研究区成矿地质条件、1:5万地球物理和地球化学综合异常特征、矿(化)点特征及分布规律等,阐明了该区成矿时空分布规律和矿产共生组合规律,划分成矿远景区9处,提交找矿靶区6处。对其中2处找矿靶区进行槽探验证的结果为: 关子镇幅玉杨观找矿靶区圈定了4条含铷矿化伟晶岩脉和多处铁矿化破碎蚀变带,具有形成伟晶岩型铷矿的潜力; 礼县幅李坝金矿床南侧百叶沟—河西沟找矿靶区圈定了14条蚀变破碎带,在矿化蚀变带内圈定了11条金矿(化)体,具有形成构造蚀变岩(微细粒浸染状)型金矿床的潜力。     

河南桐柏马道地区水系沉积物地球化学特征及找矿方向

通过河南桐柏马道地区1∶5万水系沉积物测量和元素地球化学特征分析研究认为,Au、Ag、Cu、Pb、Zn、Cr、Ni、Fe 8种元素为区内主要成矿元素,共圈出单元素异常831个、综合异常27个,地球化学异常严格受地层、大河断裂带及其次级断裂、岩浆岩等因素联合控制。结合综合异常特征以及成矿地质条件,圈定了围山城金银多金属矿找矿远景区、刘山岩铜锌多金属矿找矿远景区、月儿湾金银多金属矿找矿远景区、老和尚帽银多金属矿找矿远景区4处。通过对远景区综合异常查证,在围山城5-甲1-1和11-甲1-1、刘山岩14-甲3-1、月儿湾2-甲3-1、老和尚帽24-甲2-2综合异常区发现与异常相关的矿化信息,为下一步地质找矿工作指明了方向     

西秦岭温泉—中川一带金属矿床的成矿规律及找矿预测

西秦岭温泉—中川一带实施的1∶5万矿产地质调查项目,共圈定1∶5万局部高磁异常33处,1∶5万地球化学综合异常11处,发现矿点2处,矿化点5处,矿种有金、钼、铁、铜、铷等。通过分析研究区成矿地质条件、1∶5万地球物理和地球化学综合异常特征、矿(化)点特征及分布规律等,阐明了该区成矿时空分布规律和矿产共生组合规律,划分成矿远景区9处,提交找矿靶区6处。对其中2处找矿靶区进行槽探验证的结果为:关子镇幅玉杨观找矿靶区圈定了4条含铷矿化伟晶岩脉和多处铁矿化破碎蚀变带,具有形成伟晶岩型铷矿的潜力;礼县幅李坝金矿床南侧百叶沟—河西沟找矿靶区圈定了14条蚀变破碎带,在矿化蚀变带内圈定了11条金矿(化)体,具有形成构造蚀变岩(微细粒浸染状)型金矿床的潜力。     

乌干达优势矿产成矿地质特征及远景区划分

作者在野外考察和资料整理分析的基础上,根据乌干达区域地质构造发展演化、矿产资源类型、矿点(矿化点)分布以及典型矿床特征,圈定了4个金有利成矿远景区:Busia金矿区,Mubende金矿区,Buhweju-Mashonga金矿区和Karamoja金矿区。通过对乌干达优势矿产资源的整体评估,划分了6个具有良好成矿潜力的多金属成矿远景区:基伦贝(Kilembe)铜-钴成矿区,布惠朱(Buhweju)金成矿区,穆本德-班尤诺(Mubende-Bunyoro)金、钨、锡等多金属成矿区,基索罗-恩通加莫(Kisoro-Ntungamo)金、锡、绿柱石等多金属成矿区,布希亚(Busia)金成矿区,卡亚穆伽(Karamoja)金、铜等多金属成矿区,并对各成矿远景区进行了简要阐述。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

Roles of xenomelts,xenoliths, xenocrysts,xenovolatiles, residues,and skarns in the genesis,transport, and localization of magmatic Fe-Ni-Cu-PGE sulfides and chromite

Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

Petrographic, mineralogy, and geochemistry of coals of Pabedana, Kerman Province, Central Iran

This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.