Biomediation of calcrete at the gold anomaly of the Barns prospect,Gawler Craton,South Australia

Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH₄⁺ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH₄⁺ were detected compared to a control that contained below 0.05 mg/l NH₄⁺. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO₂ environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.     

Oceanographic controls on shallow‐water temperate carbonate sedimentation: Spencer Gulf,South Australia

Spencer Gulf is a large (ca 22 000 km²), shallow (<60 m water depth) embayment with active heterozoan carbonate sedimentation. Gulf waters are metahaline (salinities 39 to 47‰) and warm‐temperate (ca 12 to ?28°C) with inverse estuarine circulation. The integrated approach of facies analysis paired with high‐resolution, monthly oceanographic data sets is used to pinpoint controls on sedimentation patterns with more confidence than heretofore possible for temperate systems. Biofragments – mainly bivalves, benthic foraminifera, bryozoans, coralline algae and echinoids – accumulate in five benthic environments: luxuriant seagrass meadows, patchy seagrass sand flats, rhodolith pavements, open gravel/sand plains and muddy seafloors. The biotic diversity of Spencer Gulf is remarkably high, considering the elevated seawater salinities. Echinoids and coralline algae (traditionally considered stenohaline organisms) are ubiquitous. Euphotic zone depth is interpreted as the primary control on environmental distribution, whereas seawater salinity, temperature, hydrodynamics and nutrient availability are viewed as secondary controls. Luxuriant seagrass meadows with carbonate muddy sands dominate brightly lit seafloors where waters have relatively low nutrient concentrations (ca 0 to 1 mg Chl‐a m^?3). Low‐diversity bivalve‐dominated deposits occur in meadows with highest seawater salinities and temperatures (43 to 47‰, up to 28°C). Patchy seagrass sand flats cover less‐illuminated seafloors. Open gravel/sand plains contain coarse bivalve–bryozoan sediments, interpreted as subphotic deposits, in waters with near normal marine salinities and moderate trophic resources (0·5 to 1·6 mg Chl‐a m^?3) to support diverse suspension feeders. Rhodolith pavements (coralline algal gravels) form where seagrass growth is arrested, either because of decreased water clarity due to elevated nutrients and associated phytoplankton growth (0·6 to 2 mg Chl‐a m^?3), or bottom waters that are too energetic for seagrasses (currents up to 2 m sec^?1). Muddy seafloors occur in low‐energy areas below the euphotic zone. The relationships between oceanographic influences and depositional patterns outlined in Spencer Gulf are valuable for environmental interpretations of other recent and ancient (particularly Neogene) high‐salinity and temperate carbonate systems worldwide.     

Geoheritage at the small scale: tidal-zone bubble-sand structures as diagnostic paleo-environmental indicators,and their geoheritage significance

In identifying sites of geoheritage significance, commonly there has been an emphasis on the larger-scale features. However, the story of geology and the significant features that are critical to unravel geological processes and geological history are commonly small in scale. This contribution focuses on bubble sand and bubble-sand structures as features that are small-scale but nonetheless important to geology, and hence are of geoheritage significance. Bubble sand and bubble-sand structures are ubiquitous on modern beaches and tidal flats, occurring in the uppermost tidal zone of sandy beaches, as a distinct layer in a shoaling beach-to-dune stratigraphy, and are a diagnostic indicator of upper-tidal conditions where a rising tide and a concomitantly rising water-table interacts with the upper swash-zone wave processes. On sandy tidal flats, bubble sand and bubble-sand structures may occur in the mid- to upper-tidal zones; here they are also diagnostic indicators of tidal conditions, forming during a rising tide where a rising water-table forces air upwards to be trapped in moist sand. If found in ancient sequences, bubble-sand structures are a powerful environmental indicator of tidal conditions and, for beach sequences, an indicator of the high-tide level and sea level. Bubble-sand structures have been found in a number of ancient sequences throughout the geological record as far back as the Neoproterozoic, e.g. within beach-to-dune stratigraphy in Pleistocene limestones of the Perth Basin and in southeastern USA, and in tidal-flat sands of the Mesozoic Broome Sandstone of the Canning Basin. The bubble-sand structure is a significant geological tool for use in paleo-environmental and paleo-oceanographic reconstructions, and determination of the position of a paleo-water-table. Given the rarity of their preservation, these occurrences of bubble-sand structures are of geoheritage significance in their own right and, depending on age of sequence and how common they are in the region, they may be nationally significant or globally significant.     

Evolution of the Mount Woods Inlier, northern Gawler Craton, Southern Australia: an integrated structural and aeromagnetic analysis

Structural mapping integrated with interpretation and forward modelling of aeromagnetic data form complimentary and powerful tools for regional structural analysis because both techniques focus on architecture and overprinting relationships. This approach is used to constrain the geometry and evolution of the sparsely exposed Mount Woods Inlier in the northern Gawler Craton. The Mount Woods Inlier records a history of poly-phase deformation, high-temperature metamorphism, and syn- and post-orogenic magmatism between ca. 1736 and 1584 Ma. The earliest deformation involved isoclinal folding, and the development of bedding parallel and axial planar gneissic foliation (S₁). This was accompanied by high-temperature, upper amphibolite to granulite facies metamorphism at ca. 1736 Ma. During subsequent north–south shortening (D₂), open to isoclinal south–southeast-oriented F₂ folds developed as the Palaeoproterozoic successions of the inlier were thrust over the Archaean nuclei of the Gawler Craton. The syn-D₂ Engenina Adamellite was emplaced at ca. 1692 Ma. The post-D₂ history involved shear zone development and localised folding, exhumation of metamorphic rocks, and deposition of clastic sediments prior to the emplacement of the ca. 1584 Ma Granite Balta Suite. The Mount Woods Inlier is interpreted as the northern continuation of the Kimban Orogen.     

An Upper Cretaceous paleo-aquifer system in the Eromanga Basin of the central Gawler Craton,South Australia: evidence from apatite fission track thermochronology

An apatite fission track (AFT) study of crystalline basement in the central Gawler Craton reveals apparent ages in the range of ca 430–58 Ma. The majority of samples underwent protracted monotonic cooling related to regional Paleozoic exhumation, consistent with long-term crustal stability as expected for cratonic interiors. However, multiple samples show evidence of Late Cretaceous–early Paleogene reheating, indicating a more dynamic low-temperature history. Inverse time–temperature modelling of AFT data indicates varying degrees of thermal overprinting between ～60 and 110°C, with substantially overprinted and negligibly overprinted samples in close proximity (<1 km). Time–temperature histories for samples that experienced thermal overprinting reveal localised Late Cretaceous–early Paleogene (ca 100–50 Ma) heating that is significantly younger than the Paleozoic–early Mesozoic exhumation recorded regionally. The highly localised nature and non-systematic patterns of overprinting combined with the lack of major Mesozoic or Cenozoic fault structures are not consistent with a regional thermal event associated with substantial reburial and later exhumation. Rather, localised reheating was most likely caused by heated groundwater from the once-overlying Mesozoic Eromanga Basin aquifer system, whose modern discharge margin (～400 km north of the study area) is marked by thermal mound springs that produce fluids with temperatures up to 100°C. Only basement rocks in close proximity to fluid pathways in the overlying aquifer would have recorded reheating, resulting in the observed sporadic distribution of partially overprinted samples. Thermal history modelling indicates rejuvenated apatite grains cooled to near-surface temperatures in the latest Cretaceous–Paleogene. This was likely in response to local removal of the overlying Eromanga Basin aquifer unit due to a relatively minor degree of exhumation (≤1 km) recorded regionally, which consequently disrupted the anomalous heating mechanism. These results show that the flow of heated groundwater is a feasible reheating mechanism for low-temperature thermochronometers, resulting in cooling patterns that may become decoupled from exhumation in cratonic interiors.     

Unravelling the tectonothermal evolution of reworked Archean granulite facies metapelites using in situ geochronology: an example from the Gawler Craton,Australia

The use of in situ geochronological techniques allows for direct age constraints to be placed on fabric development and the metamorphic evolution of polydeformed and reworked terranes. The Shoal Point region of the southern Gawler Craton consists of a series of reworked granulite facies metapelitic and metaigneous units which belong to the Late Archean Sleaford Complex. Structural evidence indicates three phases of fabric development with D₁ retained within boudins, D₂ consisting of a series of upright open to isoclinal folds producing an axial planar fabric and D₃ composed of a highly planar vertical high‐strain fabric which overprints the D₂ fabric. Th–U–total Pb EPMA monazite and garnet Sm–Nd geochronology constrain the D₁ event to the c. 2450 Ma Sleaford Orogeny, whereas the D₂ and D₃ events are constrained to the 1730–1690 Ma Kimban Orogeny. P–T pseudosections constrain the metamorphic conditions for the Sleafordian Orogeny to between 4.5 and 6 kbar and between 750 and 780 °C. Subsequent Kimban‐aged reworking reached peak metamorphic conditions of 8–9 kbar at 820–850 °C during the D₂ event, followed by high‐temperature decompression to metamorphic conditions <6 kbar and 790–850 °C associated with the development of the D₃ high‐strain fabric. The P–T–t evolution of the Shoal Point rocks reflects the transpressional exhumation of lower crustal rocks during the Kimban Orogeny and the development of a regional ‘flower structure’.     

Sedimentological interpretation of an Ediacaran delta: Bonney Sandstone,South Australia

The type section of the late Ediacaran (ca 565 Ma) Bonney Sandstone in South Australia provides an opportunity to interpret a succession of Precambrian clastic sediments using physical sedimentary structures, lithologies and stacking patterns. Facies models, sequence stratigraphic analysis, and process-based architectural classification of depositional elements were used to interpret depositional environments for a series of disconformity-bounded intervals. This study is the first detailed published work on the Bonney Sandstone, and provides additional context for other Wilpena Group sediments, including the overlying Rawnsley Quartzite and its early metazoan fossils. Results show that the ～300 m-thick section studied here shows a progressive change from shallow marine to fluvially dominated sediments, having been deposited in storm-dominated shelf and lower shoreface environments, lower in the section, and consisting primarily of stacked channel sands, in a proximal deltaic environment near the top. Based on the degree of influence of wave, tidal or fluvial depositional processes, shallow marine sediments can be classified into beach, mouth bar, delta lobe and channel depositional elements, which can be used to assist in predicting sandbody geometries when only limited information is available. Sediments are contained within a hierarchical series of regressive, coarsening-upward sequences, which are in turn part of a larger basin-scale sequence that likely reflects normal regression and filling of accommodation throughout a highstand systems tract. Paleogeographic reconstructions suggest the area was part of a fluvially dominated clastic shoreline; this is consistent with previous reconstructions that indicate the area was on the western edge of the basin adjacent to the landward Gawler Craton. This research fills in a knowledge gap in the depositional history of a prominent unit in the Adelaide Rift Complex and is a case study in the interpretation of ancient deposits that are limited in extent or lacking diagnostic features.     

Sediment transfer in an extremely low-gradient,low-relief and highly buffered system: Darwin Harbour catchment,northern Australia

Abstract

Sediment yields from and sediment transfer within catchments of very low relief and gradient, which make up about 50% of Earth’s surface, are poorly documented and their internal sediment dynamics are poorly known. Sediment sources, their proportionate contributions to valley floors and sediment yield, and storage are estimated using fallout radionuclides ²¹⁰Pb_(ex) and ¹³⁷Cs in the catchments that drain into Darwin Harbour, northern Australia, an example of this understudied catchment type that appears to be globally at the extreme end of this category of catchments. Unchannelled grassy valley floors (dambos, or seasonal wetlands) trap ～90% of the sediment delivered from hillslopes by sheet and rill erosion. Further down valley, small channels transport ～10% of the sediment that escapes from the dambos, and the remaining sediment comes from erosion of the channels. In this case, the fractional sediment storage is very high as a result of the existence of dambos, a landform that depends for its existence on low gradients.     

Quantifying rates of coastal progradation from sediment volume using GPR and OSL: the Holocene fill of Guichen Bay, south-east South Australia

Guichen Bay on the south‐east coast of South Australia faces west towards the prevailing westerly winds of the Southern Ocean. The bay is backed by a 4 km wide Holocene beach‐ridge plain with more than 100 beach ridges. The morphology of the Guichen Bay strandplain complex shows changes in the width, length, height and orientation of beach ridges. A combination of geomorphological interpretation, shallow geophysics and existing geochronology is used to interpret the Holocene fill of Guichen Bay. Six sets of beach ridges are identified from the interpretation of orthorectified aerial photographs. The ridge sets are distinguished on the basis of beach‐ridge orientation and continuity. A 2·25 km ground‐penetrating radar (GPR) profile across the beach ridges reveals the sedimentary structures and stratigraphic units. The beach ridges visible in the surface topography are a succession of stabilized foredunes that overlie progradational foreshore and upper shoreface sediments. The beach progrades show multiple truncation surfaces interpreted as storm events. The GPR profile shows that there are many more erosion surfaces in the subsurface than beach ridges on the surface. The width and dip of preserved beach progrades imaged by GPR shows that the shoreface has steepened from around 2·9° to around 7·5°. The changes in beach slope are attributed to increasing wave energy associated with beach progradation into deeper water as Guichen Bay was infilled. At the same time, the thickness of the preserved beach progrades increases slightly as the beach prograded into deeper water. Using the surface area of the ridge sets measured from the orthophotography, and the average thickness of upper shoreface, foreshore and coastal dune sands interpreted from the GPR profile, the volume of Holocene sediments within three of the six sets of beach‐ridge accretion has been calculated. Combining optically stimulated luminescence (OSL) ages and volume calculations, rates of sediment accumulation for Ridge Sets 3, 4 and 5 have been estimated. Linear rates of beach‐ridge progradation appear to decrease in the mid‐Holocene. However, the rates of sediment accumulation calculated from beach volumes have remained remarkably consistent through the mid‐ to late Holocene. This suggests that sediment supply to the beach has been constant and that the decrease in the rate of progradation is due to increasing accommodation space as the beach progrades into deeper water. Changes in beach‐ridge morphology and orientation reflect environmental factors such as changes in wave climate and wind regime.     

Discussion: Palaeomagnetism,radiometric age and geochemistry of an adamellite at Yetholme,N.S.W.

Volcanic rocks, mainly of intermediate composition, occupy several basins within the rift zone along which the Yangtze River flows in its lower reaches. Potassium‐argon (K‐Ar) age measurements on minerals and whole rock samples from lavas and syenitic intrusives in the Lujiang‐Tzungyang volcanic basin range from 131 to 123 m.y., and biotites from two lavas in the Nanjing‐Wuhu basin have measured ages of 127 and 130 m.y. Incremental heating experiments by the ⁴⁰Ar/³⁹Ar method on biotite from two volcanic rocks, one from each basin, yield simple age spectra with plateau ages of 129 to 130 m.y. These data provide evidence that the two biotites have remained undisturbed since crystallisation. The combined results show that volcanism was contemporaneous within the two basins in the Early Cretaceous. Vol‐canism in the Yangtze Volcanic Zone is thought to be related to adjustments within the Eurasian plate as a consequence of collision between the earlier Pacific (Kula) plate and the Eurasian plate.     

Field scale remediation of mine wastes at an abandoned gold mine,Australia II: Effects on plant growth and groundwater

This second paper reports the results of plant growth, plant mortality, plant leaf tissue metal and salt concentrations and leachate quality monitoring from lysimeters in four large field trial treatments established on sulfidic waste rock/soil that was used for haul road construction at a closed gold mine in Australia. The TerraB™, lime and clay treatments allowed good tree growth of four Eucalypt species, compared to the control. There was no statistical difference in tree growth between the TerraB™, lime or clay treatments over the 2 years of monitoring in this paper. However, the growth of one tree species was poor in the TerraB™ treatment. Leaf tissue metal and major ion data are also presented. Leachate pH in the control became increasingly acidic (pH 4.57–3.95). The addition of Ca(OH)₂ and biosolids led to an initial increase in leachate pH, compared to the control; however, this has decreased over the duration of the study (pH 5.37–4.89) and may affect the sustainable growth of plants in the future. In the TerraB™ and biosolids treatment leachate pH increased to 6.92 after the first rainfall event and continued to increase over the duration of the study to pH 7.4 after 24 months. After 24 months average heavy metal leachate concentrations (mg/L) in the lysimeters for Al, Cd, Cu, Mn and Zn were, control: 32.55, 5.67, 12.71, 39.29, 121.80, TerraB™: 0.07, 0.02, 0.07, 0.57, 0.23, and lime: 2.19, 1.19, 2.33, 3.6, 28.4. No leachate was available for collection from the clay treatment indicating that this technique was functioning in terms of minimizing the infiltration of water into the mine soil.     

Transport and sediment–water partitioning of trace metals in acid mine drainage: an example from the abandoned Kwangyang Au–Ag mine area, South Korea

Transport and sediment–water partitioning of trace metals (Cr, Co, Fe, Pb, Cu, Ni, Zn, Cd) in acid mine drainage were studied in two creeks in the Kwangyang Au–Ag mine area, southern part of Korea. Chemical analysis of stream waters and the weak acid (0.1 N HCl) extraction, strong acid (HF–HNO₃–HClO₄) extraction, and sequential extraction of stream sediments were performed. Heavy metal pollution of sediments was higher in Chonam-ri creek than in Sagok-ri creek, because there is a larger source of base metal sulfides in the ores and waste dump upstream of Chonam-ri creek. The sediment–water distribution coefficients (K _d) for metals in both creeks were dependent on the water pH and decreased in the order Pb ≈ Al > Cu > Mn > Zn > Co > Ni ≈ Cd. K _d values for Al, Cu and Zn were very sensitive to changes in pH. The results of sequential extraction indicated that among non-residual fractions, Fe–Mn oxides are most important for retaining trace metals in the sediments. Therefore, the precipitation of Fe(–Mn) oxides due to pH increase in downstream sites plays an important role in regulating the concentrations of dissolved trace metals in both creeks. For Al, Co, Cu, Mn, Pb and Zn, the metal concentrations determined by 0.1 N HCl extraction (Korean Standard Method for Soil Pollution) were almost identical to the cumulative concentrations determined for the first three weakly-bound fractions (exchangeable + bound to carbonates + bound to Fe–Mn oxides) in the sequential extraction procedure. This suggests that 0.1 N HCl extraction can be effectively used to assess the environmentally available and/or bioavailable forms of trace metals in natural stream sediments.     

A Lateglacial archaeological site in the far north‐west of Europe at Rubha Port an t‐Seilich,Isle of Islay,western Scotland: Ahrensburgian‐style artefacts,absolute dating and geoarchaeology

The exact pattern, process and timing of the human re‐colonization of northern Europe after the end of the last Ice Age remain controversial. Recent research has provided increasingly early dates for at least pioneer explorations of latitudes above 54°N in many regions, yet the far north‐west of the European landmass, Scotland, has remained an unexplained exception to this pattern. Although the recently described Hamburgian artefacts from Howburn and an assemblage belonging to the arch‐backed point complex from Kilmelfort Cave have established at least a sporadic human presence during earlier stages of the Lateglacial Interstadial, we currently lack evidence for Younger Dryas/Greenland Stadial 1 (GS‐1) activity other than rare stray finds that have been claimed to be of Ahrensburgian affiliation but are difficult to interpret in isolation. We here report the discovery of chipped stone artefacts with technological and typological characteristics similar to those of the continental Ahrensburgian at a locality in western Scotland. A preliminary analysis of associated tephra, pollen and phytoliths, along with microstratigraphic analysis, suggest the artefacts represent one or more episodes of human activity that fall within the second half of GS‐1 and the Preboreal period. © 2015 The Authors. Journal of Quaternary Science published by John Wiley & Sons, Ltd.