The harp seal (Phoca groenlandica Erxleben) in Denmark, southern Scandinavia, during the Holocene

The harp seal ( Phoca groenlandica ) is a low-arctic species that is currently a rare visitor to Danish waters. However, bone remains from archaeological and geological deposits in Denmark and the Baltic Sea testify to a regular presence of harp seals in this region during the mid-Holocene. The paradox of the presence of a low-arctic seal species in southern Scandinavia during the mid-Holocene thermal maximum has been widely discussed. In order to improve the Holocene chronology for the presence of harp seal in Denmark, 24 bone remains of the species were radiocarbon dated. The oldest date is around 4100 cal. yr BC, indicating that the harp seal arrived several millennia after fully marine conditions were established in Danish waters. The majority of the dated specimens fall within two age groups, one centred around 3900 cal. yr BC (11 dates), the other around 2700 cal. yr BC (7 dates). It is argued that these two groups may reflect periods with suitable living conditions for the harp seal in Danish waters and that this is connected with an enhanced inflow of high-salinity North Sea water and higher biological productivity. Six dates show a scattered distribution between c . 1400 cal. yr BC and c . AD 1000, suggesting sporadic visits of the harp seal to Danish waters during the late Holocene.     

Post‐Glacial immigration of the harbour porpoise (Phocoena phocoena) into the Baltic Sea*

At the end of the Pleistocene, environmental conditions in the Baltic Basin were affected by the melting glaciers and the resultant freshwater bodies. In contrast to various seal species, there is no subfossil evidence of the harbour porpoise (Phocoena phocoena) from the early Holocene stages of the Baltic Basin. This article is an attempt to clarify the colonization of the harbour porpoise into the Baltic Sea and to reveal the ecological background of this process. All published Holocene subfossil records from the porpoise in the Baltic region were sought and supplemented with those from museums and zoological collections; 148 records document the porpoise's occurrence. The earliest records of the harbour porpoise date from the time between 9600 and 7000 cal. yr BP and originate from the early and middle Mesolithic coastal settlements of the Maglemose and Kongemose culture during the early Littorina stage. Around 7500–5700 cal. yr BP, the porpoise is recorded frequently at many localities from late Mesolithic (Ertebølle culture) and Neolithic in the coastal areas of the western Baltic Sea, as well as for the first time in the Gulfs of Bothnia and Finland. Since 4000 cal. yr BP, P. phocoena has only been recorded in the western Baltic. We suggest that immigration and dispersion of P. phocoena into the Baltic Sea was connected with the Littorina transgression beginning around 9000 cal. yr BP. The continuous influx of seawater and the associated ecological changes led to a new, very species‐rich, fish community and adequate living conditions for the harbour porpoise.     

The geology of the southeastern Baltic Sea: a review

The Baltic Sea, particularly its southeastern part, is discussed in the paper. Investigations of regional character as well as specialized studies in the area are reviewed. General historical works are mentioned briefly. Previous surveys since the 1950s are presented by the subject studied. The compilation of geological structure of the SE Baltic Sea bottom and adjacent land of Balticum (Baltic States: Estonia, Latvia, Lithuania) is based on considerable amounts of summarized materials. The crystalline basement, sedimentary cover and Quaternary deposits are characterized in the comprehensive survey of geological structure. From a stratigraphical point of view, geological sequence of the platformal cover is comparatively complete: deposits of all geological systems (from the Archean to Cenozoic) are present in the Baltic Syneclise. Considering geotectonical cycles, the sedimentary cover of the syneclise is subdivided into four structural complexes. The thickness and distribution of Quaternary deposits are closely related to the recent bottom relief of the Baltic Sea that in turn is inherited from the Pre-Quaternary surface. Buried palaeo-valleys are characteristic of the Pre-Quaternary surface in the Baltic region and the Baltic Sea bottom. The Quaternary is characterized by layers of various geneses and by sharp changes of their thicknesses.     

Past occurrences of hypoxia in the Baltic Sea and the role of climate variability,environmental change and human impact

The hypoxic zone in the Baltic Sea has increased in area about four times since 1960 and widespread oxygen deficiency has severely reduced macro benthic communities below the halocline in the Baltic Proper and the Gulf of Finland, which in turn has affected food chain dynamics, fish habitats and fisheries in the entire Baltic Sea. The cause of increased hypoxia is believed to be enhanced eutrophication through increased anthropogenic input of nutrients, such as nitrogen and phosphorus. However, the spatial variability of hypoxia on long time-scales is poorly known: and so are the driving mechanisms. We review the occurrence of hypoxia in modern time (last c. 50 years), modern historical time (AD 1950–1800) and during the more distant past (the last c. 10 000 years) and explore the role of climate variability, environmental change and human impact. We present a compilation of proxy records of hypoxia (laminated sediments) based on long sediment cores from the Baltic Sea. The cumulated results show that the deeper depressions of the Baltic Sea have experienced intermittent hypoxia during most of the Holocene and that regular laminations started to form c. 8500–7800 cal. yr BP ago, in association with the formation of a permanent halocline at the transition between the Early Littorina Sea and the Littorina Sea s. str. Laminated sediments were deposited during three main periods (i.e. between c. 8000–4000, 2000–800 cal. yr BP and subsequent to AD 1800) which overlap the Holocene Thermal Maximum (c. 9000–5000 cal. yr BP), the Medieval Warm Period (c. AD 750–1200) and the modern historical period (AD 1800 to present) and coincide with intervals of high surface salinity (at least during the Littorina s. str.) and high total organic carbon content. This study implies that there may be a correlation between climate variability in the past and the state of the marine environment, where milder and dryer periods with less freshwater run-off correspond to increased salinities and higher accumulation of organic carbon resulting in amplified hypoxia and enlarged distribution of laminated sediments. We suggest that hydrology changes in the drainage area on long time-scales have, as well as the inflow of saltier North Sea waters, controlled the deep oxic conditions in the Baltic Sea and that such changes have followed the general Holocene climate development in Northwest Europe. Increased hypoxia during the Medieval Warm Period also correlates with large-scale changes in land use that occurred in much of the Baltic Sea watershed during the early-medieval expansion. We suggest that hypoxia during this period in the Baltic Sea was not only caused by climate, but increased human impact was most likely an additional trigger. Large areas of the Baltic Sea have experienced intermittent hypoxic from at least AD 1900 with laminated sediments present in the Gotland Basin in the Baltic Proper since then and up to present time. This period coincides with the industrial revolution in Northwestern Europe which started around AD 1850, when population grew, cutting of drainage ditches intensified, and agricultural and forest industry expanded extensively.     

The Pre-Windermere Interstadial (Late Devensian) raised marine strata of eastern Scotland and their macrofauna: a review

Late Devensian raised marine deposits predating the Windermere Interstadial (c. 13–11 ka BP) are found between the Moray Firth and Berwick. The widely distributed, sparsely fossiliferous Errol Clay Formation of the firths of Forth and Tay was laid down in a high-arctic environment immediately following the retreat of the Late Devensian (Dimlington Stadial) ice. In the Tay Estuary, sedimentation took place under distal glaciomarine to marine conditions at a time when there was a fully marine connection between the Scottish east coast and the then high-arctic Norwegian Sea. On the south shore of the Moray Firth, the similar, but undated Spynie Clay Formation seems to have been laid down in a wholly glaciomarine environment. Part of the macrofauna attributed to the St. Fergus Silt Formation of the NE Scottish coast may have been either misidentified, or is not in situ. The preservation of the fauna and of delicate sedimentary structures indicate that the arctic clays as a whole were laid down rapidly. It is suggested that tidal currents were minimal, and that waves were dampened by sea ice for much of the year. Bones of the ringed seal, Phoca hispida, have been recorded from 12 sites in eastern Scotland. About 40 macrofaunal taxa are present in the Errol Clay Formation, a number similar to that recorded in the Danish Younger Yoldia Clay, which is of comparable age. The faunal nomenclature is updated, and three species (Cylichna occulta, Retusa obtusa and Lyonsia arenosa) are added to the macrofaunal list for the Errol Clay Formation. Reports of in situ boreal molluscs and of one possibly North American species in the otherwise high-arctic assemblage are not supported by specimens in extant collections. Differential decay of the fauna below the zone of weathering in the Errol Clay Formation may have resulted from early diagenesis. Deposition of the Late Devensian, pre-Windermere Interstadial marine sediments as a whole was probably diachronous, beginning after 15–14 ka BP on the outer coast, but was confined to a short interval (c. 13.5–13 ka BP) at the type site in the Tay Estuary. In the Forth Estuary, the high-arctic marine fauna adjacent to the retreating ice-front may have survived the rapid climatic amelioration (c. 13 ka BP) at the beginning of the Windermere Interstadial (marked by the Main Perth Shoreline) for perhaps a few decades.     

Subfossil littoral Cladocera as indicators of brackish-water Littorina transgression of the Baltic Basin in a small lake in Finland

The study aimed to investigate the value of freshwater littoral Cladocera (chydorids, Ophryoxus gracilis and Sida crystallina ) in stratigraphical studies of shore displacement of the Baltic Sea. Diatoms and Cladocera were analysed from a sediment core from Lake Ruokolampi (S Finland, 60°34'N, 27°26'E), where a brackish-water Baltic transgression (Littorina Sea) is clearly expressed by changes in lithology. The diatom flora indicates a development of the waterbody from an Ancylus Lake bay to a small lake that was subject to a brackish Littorina transgression followed by another small-lake stage. There was a rich chydorid fauna in the Ancylus Lake bay and the following small lake. Littoral Cladoceran diversity fell sharply at the onset of the brackish transgression; however, three species ( Alona rectangula, Alona affinis and Chydorus sphaericus s.l. ) appear to have been tolerant of the saline conditions. Concentrations of all species rose rapidly after the transgression. Littoral Cladocera appear to react to the inflow of brackish water as sensitively as the diatoms and may provide a valuable additional method for pinpointing Baltic Sea transgression and isolation events, especially in cases where the diatom and biostratigraphical evidence is not as clear as in the Ruokolampi sequence.     

The Baltic-Kattegat-Skagerrak estuarine system

Measurements of alkalinities and calcium concentrations in the Baltic Sea indicate that there has been a slight increase in both these parameters over the last century. These increases may have been caused by the leaching of limestone by acid rain. About ten percent of the nutrients are exported from the Baltic to the Kattegat; however, very little, if any, alkalinity is stored in the Baltic since river input and system output are approximately equal. Since the precipitation and evaporation are almost equal in the Baltic Sea, corrections are not needed for river inputs.     

Paleoenvironmental and Human Behavioral Implications of the Boegoeberg 1 Late Pleistocene Hyena Den, Northern Cape Province, South Africa

Boegoeberg 1 (BOG1) is located on the Atlantic coast of South Africa, 850 km north of Cape Town. The site is a shallow rock shelter in the side of a sand-choked gully that was emptied by diamond miners. Abundant coprolites, chewed bones, and partially digested bones implicate hyenas as the bone accumulators. The location of the site, quantity of bones, and composition of the fauna imply it was a brown hyena nursery den. The abundance of Cape fur seal bones shows that the hyenas had ready access to the coast. Radiocarbon dates place the site before 37,000 ¹⁴C yr ago, while the large average size of the black-backed jackals and the presence of extralimital ungulates imply cool, moist conditions, probably during the early part of the last glaciation (isotope stage 4 or stage 3 before 37,000 ¹⁴C yr ago) or perhaps during one of the cooler phases (isotope substages 5d or 5b) within the last interglaciation. Comparisons of the BOG1 seal bones to those from regional Middle Stone Age (MSA) and Later Stone Age (LSA) archeological sites suggest (1) that hyena and human seal accumulations can be distinguished by a tendency for vertebrae to be much more common in a hyena accumulation and (2) that hyena and LSA accumulations can be distinguished by a tendency for hyena-accumulated seals to represent a much wider range of individual seal ages. Differences in the way hyenas and people dismember, transport, and consume seal carcasses probably explain the contrast in skeletal part representation, while differences in season of occupation explain the contrast in seal age representation. Like modern brown hyenas, the BOG1 hyenas probably occupied the coast year-round, while the LSA people focused their coastal visits on the August–October interval when nine-to-eleven-month-old seals were abundant. The MSA sample from Klasies River Mouth Cave 1 resembles BOG1 in seal age composition, suggesting that unlike LSA people, MSA people obtained seals more or less throughout the year.     

Postglacial occurrence of the beaver (Castor fiber L.) in Finland

Subfossil finds of the beaver in Finland, both stray finds and bones among refuse at cultural sites, are reviewed. The beaver may have arrived in the Preboreal period together with other elements of the taiga fauna; the earliest finds, however, are from the Late Ancylus or Early Litorina phase of the Baltic. The animal's arrival and occurrence in this country since the end of the last glaciation are tentatively discussed.     

Marine conditions in central Sweden during the early Preboreal as inferred from a stable oxygen isotope gradient

The marine benthic fauna and the δ¹⁸O_c of foraminifers and ostracods from six sites situated on a west–east transect through central Sweden have been analysed in order to estimate the palaeosalinity and palaeocirculation in this shallow‐marine environment. The measurements have been undertaken on material from the early Preboreal, when the Baltic Basin was in contact with the North Sea through straits in central Sweden. The δ¹⁸O_c values have a more negative value towards the east, indicating decreasing salinity. This was the result of limited possibilities for marine water to penetrate into the Baltic Basin and the mixing with freshwater from the melting Fennoscandian ice‐sheet. Four water masses existed in the area: a surface layer of freshwater, marine water from the North Sea, brackish–marine intermediate water on the Swedish west coast and brackish Yoldia Sea water in the Baltic Basin. The chronology is based on radiocarbon dates of marine fossils and, at one site, on the occurrence of the Vedde Ash (10 400–10 300 ¹⁴C yr BP). This is the first record from marine settings in Sweden. Copyright © 2001 John Wiley & Sons, Ltd.     

Toward a standard stratigraphical classification practice for the Baltic Sea sediments: the CUAL approach

The Late Pleistocene and Holocene glacial and postglacial sediments of the Baltic Sea basin are conventionally classified into units according to the so‐called Baltic Sea stages: Baltic Ice Lake, Yoldia Sea, Ancylus Lake and Litorina Sea. The Baltic Sea stages have been identified in offshore sediment cores by fundamentally different criteria, precluding detailed comparisons of the sediment units amongst different sea areas and studies. Here, long sediment cores and reflection seismic and pinger sub‐bottom profiles were studied from an offshore area in the Gulf of Finland, northern Baltic Sea. The strata are divided on the basis of sedimentological criteria into three allostratigraphical formations with subordinate allostratigraphical members and lithostratigraphical formations, following the combined allostratigraphical and lithostratigraphical (CUAL) approach. Sedimentological features are recommended as the primary stratigraphical classification criteria because they do not require the palaeoenvironmental inferences of salinity and water level that are inherent in the conventional classification practice. The presented stratigraphical division is proposed as a flexible template for future stratigraphical work on the Baltic Sea basin, whereby lower‐rank allounits and lithounits can be included and removed locally, while the alloformations will remain at the highest hierarchical level and guarantee regional correlatability. The stratigraphical division is compatible with international guidelines, facilitating communication to the wider scientific community and comparison with other similar basins.     

A numerical approach to the design parameters of permanent stoppings (seals and bulkheads) in Turkish underground coal mines

Observing permanent seals with different physical and mechanical characteristics under various conditions in the field is almost impossible. In conjunction with the development of high-speed computer algorithms, numerical simulation has become one of the major means to study the dynamics of such problems. Therefore, this study covers only the numerical approach to analyze the stability of underground seals. In this regard, the purpose of this study is to provide an insight to the design of underground seals by numerically analyzing their behaviors under different static and dynamic explosion overpressures using a geo-technical commercial software FLAC3D. For this purpose, a series of numerical models were constructed for a typical seal in an underground gallery with different properties such as seal thickness, seal dimensions, gallery geometry, and strength of the seal material to investigate the stability of seals exposed to various static and dynamic explosion overpressures. A total of 896 numerical analyses (512 static and 384 dynamic) were performed and evaluated. Regarding the gallery geometry, it was found that seals constructed in trapeze-shaped galleries are more stable than those constructed in horseshoe-shaped galleries having the same dimensions. Moreover, the results showed that the seal stability increases with the increasing seal thickness rather than the strength of the seal material. The statistical analyses suggest that there is a very strong exponential relationship between the seal thickness and the maximum displacement measured at the midpoints of the outer surfaces of the seals. The coefficients of determination values obtained are in the range of 0.92–0.93 and 0.92–0.95 for static and dynamic analyses, respectively. We proposed formulas which use the longer dimension of the seal (W _max ), maximum allowable displacement on the seal (D _max ), explosion overpressure applied onto the seal (P _exp ), and compressive strength of the seal material (σ _c and σ _cd for static and dynamic conditions, respectively) to predict the minimum required seal thickness (T _s ) for static and dynamic conditions. The proposed formulas enable calculating the necessary seal thickness easily if the explosion overpressure (or hydrostatic pressure) is known or approximated.     

An illustrated key and (palaeo)ecological primer for Postglacial to Recent Ostracoda (Crustacea) of the Baltic Sea

Frenzel, P., Keyser, D. & Viehberg, F.A. 2010: An illustrated key and (pala6e6o)ecological primer for Postglacial to Recent Ostracoda (Crustacea) of the Baltic Sea. Boreas, Vol. 39, pp. 567–575. 10.1111/j.1502‐3885.2009.00135.x. ISSN 0300‐9483 This synopsis of Baltic Sea brackish water Ostracoda gives an overview of all known Recent species for the first time. It also includes Holocene taxa now extinct in the area. There are 131 species, two of which are recorded only from Yoldia stage (Preboreal) sediments. The illustrated key is based exclusively on valve morphology, providing a taxonomical base for geoscience and biological studies using ostracods from the Baltic Sea area. A list of ecological tolerances and preferences as well as the latitudinal distribution of all species is intended as a reference for palaeoenvironmental analyses. Salinity, temperature and oxygen tolerance values as well as preferences for latitudinal distribution, water depth and energy, habitat and substrate are given. The data are based on quantitative sampling in the southern, central and western Baltic Sea and on information gained from literature.     

History of the reindeer (Rangifer tarandus) in the eastern Baltic region and its implications for the origin and immigration routes of the recent northern European wild reindeer populations

A total of 45 subfossil reindeer (Rangifer tarandus) antlers and bones - artefacts excluded - have been found over the years in the Baltic countries of Estonia, Latvia and Lithuania. The relatively high number of specimens suggests a stable residence of the species in the eastern Baltic region. For the first time, 12 of these finds were radiocarbon-dated. The ages of the samples range between 12 085 and 9970 ¹⁴C yr BP (14 180-11 280 cal. yr BP), and cover the Lateglacial and early Holocene, a time period during which climatic conditions shifted from periglacial to temperate. The dates suggest a rapid colonization of the area during the deglaciation period and a local extinction around the Pleistocene-Holocene boundary. The results of the study do not support the theory that the recent wild reindeer populations of northern Europe had their origin in the Late Weichselian reindeer populations of the eastern Baltic region.     

Time-dependent modeling of the Baltic entrance area. 2. Water and salt exchange of the Baltic Sea

A time-dependent model for stratification and circulation within the Baltic entrance area (Gustafsson 2000) is tested against observed salinities for the period 1961–1993. Although the Baltic Sea is one of the largest estuarine systems on earth, this model could be applicable to smaller estuarine systems and embayments with tidal exchange. The seasonal cycle of freshwater flux across the sill area does not follow the seasonal cycle of freshwater supply to the Baltic Sea. The seasonal variation of the flux is a combined effect of the seasonal variation in freshwater supply, in Baltic mean sea level, and in dispersion of salt across the sills. The seasonal variation in dispersion of salt is due to the seasonal cycle of sea level variability. The model is used to predict the inflow of high saline water to the Baltic Sea. The resulting inflow time-series is consistent with variations in the deep-water salinity and temperature in the deeper parts of the Baltic Sea. A comparison with previous estimates of the magnitude of major Baltic inflows shows that the model is able to reproduce the characteristics fairly well although the magnitude of the flows of water and salt appears lower than other estimates. It is shown that a climatic change that increases the wind mixing does not significantly change the major inflows. Both increased amplitudes of sea level variations in the Kattegat and decreased freshwater supply to the Baltic Sea substantially increase the magnitude of the inflows. It is shown that deep-water renewal in the Baltic Sea is obstructed during years with high freshwater supply even if the sea level forcing is favorable to a major inflow.     

Mineral magnetic properties of Late Weichselian-Holocene sediments from the northwestern Baltic Proper

Mineral magnetic measurements were carried out on twelve sediment cores from the northwestern part of the Baltic Proper. The purpose was to use magnetic properties to correlate sediment sequences and to investigate changes in depositional conditions (e.g. rate of sedimentation and redox conditions). A general lithostratigraphy consisting of five units was established based mainly on mineral magnetic properties. Sediment has been deposited from the time of the Baltic Ice Lake (before 10 300 ¹⁴C years BP) to the present, i.e. since the Late Weichselian deglaciation. Five of the cores were also investigated by means of biostratigraphical methods and three by ¹⁴C dates. Based on the general stratigraphy and hiatuses, variations in sedimentation rate were identified. The occurrence of authigenically formed ferrimagnetic greigite (Fe₃S₄), mainly in sediments deposited during the brackish Yoldia Sea and Litorina Sea stages, is implied. These sequences are characterized by low S-ratios and high SIRM/z ratios. Glacial clay, deposited in freshwater during the Baltic Ice Lake stage and the early freshwater phase of the Yoldia Sea stage, seems to be unaffected by diagenetic processes. Gyttja clay, deposited in the Litorina Sea, has significantly lower susceptibility and SIRM than in the underlying clay. Dissolution of magnetic iron oxides (e.g. magnetite and hematite) in an anoxic environment was suggested as an explanation.     

Near-shore Baltic Ice Lake deposits in Fakse Bugt, southeast Denmark

Shallow seismic, sedimentological and macrofossil data and AMS radiocarbon dates on terrestrial plant remains from submarine deposits in Fakse Bugt in the southwestern part of the Baltic Sea are presented. The sediments were deposited near the shore of the Baltic Ice Lake, mostly in barrier-lagoon environments, during two highstand episodes dated to around 12.5–12.2 ¹⁴C ka BP and 10.6–10.3 ka BP. Coastal sediments from the highstands indicate maximum water levels of 13–15 m and 13 m below present sea level, respectively. During the first episode Salix polaris was widespread in the land area, and during the second episode Dryas octopetala and Betula nana were the most common woody plants. During the lowstand episode Betula pubescens woods dominated. The flora and fauna of the Baltic Ice Lake were rather diverse, reflecting the long and increasing distance to the margin of the Fennoscandian Ice Sheet. Calcium-carbonate-rich, mesotrophic water characterized the Baltic Ice Lake in Fakse Bugt.     

Environmental co-operation in the Baltic Sea region: A Lithuanian perspective

International co-operation is vital if the ecological crisis in the Baltic Sea is to be reversed. Organisations such as the Baltic Co-operation Council and HELCOM and agreements such as the Helsinki Convention, the Baltic Sea Declaration, and the Gdansk Convention, already exist to facilitate co-operation. Successful implementation of these conventions requires commitment at the national level. Lithuania's commitment is hampered by internal economic, and political problems which must be surmounted if the country is to reduce its impact on the Baltic Sea.Part of the following article is published in Baltic Studies in Australia II: AABS; Melbourne, 1993 — the proceedings from the 7th bi-annual Conference of the Association for the Advancement of Baltic Studies (Australasian Section) held in Melbourne, September, 1993.     

Late Holocene Baltic Sea outflow changes reconstructed using C37:4 content from marine cores

The Baltic Sea is an intra‐continental brackish water body. Low saline surface water, the so‐called Baltic outflow current, exits the Baltic Sea through the Kattegat into the Skagerrak. Ingressions of saline oxygen‐rich bottom water enter the Baltic Sea basins via the narrow and shallow Kattegat and are of great importance for the ecological and ventilation state of the Baltic Sea. Over recent decades, progress has been made in studying Holocene changes in saline water inflow. However, reconstructions of past variations in Baltic Sea outflow changes are sparse and hampered because of the lack of suitable proxies. Here, we used the relative proportion of tetra‐unsaturated C₃₇ ketones (C_37:4 %) in long‐chain alkenones produced by coccolithophorids as a proxy for outflowing Baltic Sea water in the Skagerrak. To evaluate the applicability of the proxy, we compared the biomarker results with grain‐size records from the Kattegat and Mecklenburg Bay in addition to previously published salinity reconstructions from the Kattegat over the last 5000 years. All Skagerrak records showed an increase in C_37:4 % that is accompanied by enhanced bottom water currents in the Kattegat and western Baltic Sea over the past 3500 cal. a BP, indicating an increase in Baltic Sea outflow. This probably reflects higher precipitation in the Baltic Sea catchment area owing to a re‐organization of North Atlantic atmospheric circulation with an increased influence of wintertime Westerlies over the Baltic catchment from the mid‐ to the late Holocene.     

Nd isotope signature of Holocene Baltic Mn/Fe precipitates as monitor of climate change during the Little Ice Age

Neodymium (Nd) isotope profiles were analyzed on two Baltic Mn/Fe precipitates (99/2 and TL1) from shallow water (20 m) of the Mecklenburg Bay. The age range of these Mn/Fe precipitates determined by ²²⁶Ra_ex/Ba dating reaches from recent growth back to ∼4300 and 1000 yr BP, respectively. Over this time range, the Nd isotope composition varies from ε_Nd (0) = −13.1 to −17.5 in the selected Baltic precipitates indicating substantial changes in the Nd isotope composition of the Baltic Sea. The lowest ε_Nd values were recorded during the time interval of the Little Ice Age (LIA, AD ∼1350 to 1850). These minimum values indicate either an increase of the input of less radiogenic Nd from Scandinavian Archean-Proterozoic sources (ε_Nd about −22) to the Baltic Sea or a decrease of the input of more radiogenic Nd from continental European sources (ε_Nd about −12) and/or North Sea water (ε_Nd about −10). Variations of both, erosive continental input and North Sea inflow may indicate a direct response of the Nd isotope signal in the Baltic Sea to climate changes during the LIA and be related to cyclic shifts in the atmospheric circulation triggered by the North Atlantic Oscillation (NAO). Another aspect that possibly influenced the input of trace elements and Nd isotopes into the Baltic Sea is the population development in the circum Baltic area during the LIA. The lowest ε_Nd values also correspond to the medieval demographic crises that led to a significant decrease of agricultural activity and farmland. The reduction of soil erosion and enhanced regrowth of natural vegetation may have changed the amount and proportions of dissolved and suspended particulate matter transported into the Baltic Sea by rivers which in turn may have resulted in a change of the Nd isotope composition of Baltic Sea water.