The behavior of ore elements in oxidized heterophase chloride and carbonate–chloride–sulfate fluids of porphyry Cu–Mo(Au) deposits (from experimental data)

The spatial coexistence and synchronous formation of magmatogene porphyry Cu–Mo mineralization and epithermal gold mineralization are due to the genetic relationship between their formation processes. This relationship might be due to the generation of metal-bearing fluids of different geochemical compositions by the porphyry ore-magmatic system, which then participate in the formation of magmatogene porphyry Cu–Mo(Au) and associated epithermal gold deposits. Synthesis of fluid inclusions in quartz was performed for experimental study of the behavior of Cu, Mo, W, Sn, Au, As, Sb, Te, Ag, and Bi in heterophase fluids similar in composition and aggregate state to natural ore-forming fluids of porphyry Cu–Mo(Au) deposits. We have established that at 700 °C, a pressure decrease from 117 to 106 MPa leads to a significant enrichment of the gas phase of heterophase chloride fluid with Au, As, Sb, and Bi. The heterophase state of carbonate–chloride–sulfate fluids is observed at 600 °C and 100–90 MPa. It characterizes the highly concentrated liquid carbonate–sulfide phase–liquid chloride phase–low-density gas phase equilibrium. A decrease in the pressure of heterophase carbonate–chloride–sulfate fluid leads to a noticeable enrichment of its chloride phase with Cu, Mo, Fe, W, Ag, Sn, Sb, and Zn relative to the carbonate–sulfate phase. The processes of redistribution of ore elements between the phases of heterophase fluids can be considered a model of generation of metal-bearing chloride fluids, which occurs in nature during the formation of porphyry Cu–Mo(Au) deposits, as well as a model of generation of gas fluids supplying Au, Te, As, and other ore elements to the place of formation of epithermal Au–Cu and Au–Ag mineralization.© 2015, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.     

福建紫金山矿田罗卜岭斑岩型铜钼矿地球化学立体探测示范

罗卜岭矿床是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床, 矿区位于紫金山矿田的东北部; 铜钼矿体主要产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中, 矿石矿物组合为黄铜矿+辉钼矿; 少量过渡类型矿体产于高级泥化带中, 矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区的原生晕地球化学三维模型显示, 微量元素具有一定的分带特征, 低温元素Au与高温元素组合W、Sn、Bi分布于矿体上方, 中低温元素Pb、Zn、Ag分布于Cu、Mo元素之间; 元素直观垂向分带序列大致为: (As、Sb、Hg)-(W、Bi、Sn)-Ga-Au、Ba-Cu、Ag-Pb、Zn-Mn-Mo; 前缘晕的元素与氧化物组合为As、Sb、Au、Ga、Al2O3, 矿体近矿晕元素组合为Ag、Pb、Zn, 缺失尾晕元素组合; Cu、Mo可直接作为找矿指示元素, Au、Ag、Pb、Zn、As、Sb、Ga、Ba、Mn可作为间接指示元素, 矿床深部K2O正异常与Al2O3负异常可作为斑岩型铜钼矿的重要找矿标志, 这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。     

Stream sediment geochemical exploration for gold in Central Eastern Desert,Egypt: Application of the concentration-number fractal model,factor analysis,and geochemical mineralization probability index

Geochemical exploration by stream sediment sampling using bulk leach extractable gold (BLEG) technique and applying concentration-number (C-N) fractal model, factor analysis (FA), and geochemical mineralization probability index (GMPI) resulted in the recognition of new Au occurrences around the Sukari gold mine in the central Eastern Desert of Egypt. The geochemical data of 128 stream sediment samples collected from the study area was used for delineating the geochemical anomalies and characterizing the dispersion trains of ore and associated elements (Au, Ag, As, Sb, Cu, Pb, Zn, Mo). Statistical analysis of the geochemical data applying the C-N fractal modeling enabled us to identify significant anomaly and background populations of the investigated elements and to construct reliable geochemical anomaly maps. Factor analysis using centered log-ratios (CLR), to address the problem of closed compositional data, revealed significant element associations for mineralization (Au, As, Mo, Zn, Ba), country rock compositions (Rb, Li, Be, Sn, Bi for granite, and Co, Cr, Ni for mafic rocks), and element mobility (e.g. Sb, Zr, and Ag). Weak and moderate Au anomalies that cannot be detected by factor score maps can be delineated clearly by using the C-N fractal method and GMPI distribution map. Our study revealed that Ag, As, and Sb are the main pathfinder elements for gold mineralization in arid to semiarid regions exemplified by the Sukari gold district. Silver can be used as a “direct” pathfinder, whereas As and Sb are “indirect” pathfinders for Au in such regions. The spatial distribution of Au and Ag anomalies indicate that gold mineralization in the Sukari district is structurally controlled. However, the spatial distribution of Cu, Pb, Zn, and Mo is controlled by mineralogical and lithological factors and is not related to any significant base metal deposits.     

阿舍勒铜锌矿床地球化学特征

阿舍勒铜锌矿床原生晕和次生晕均受矿体、中泥盆统阿舍勒组第二岩性段地层、近ＳＮ向一断裂控制。阿舍勒铜锌矿床的成矿、成晕作用是多期次的，其成矿、成晕直接（矿体）指示元素为Ｃｕ，Ｐｂ，Ｚｎ，Ａｕ，Ａｇ，Ｂａ等。前晕指示元素为Ａｓ，Ｓｂ，Ｈｇ等；尾晕指示元素为Ｓｎ，Ｍｏ等。利用这些异常元素的地球化学特征，不仅可确定该矿床的矿化类型和矿体剥蚀深度（或埋深），而且也可确定与该矿床相似的成矿靶区（即异常区），并对成矿靶区进行预测评价。     

青海北祁连冷龙岭地区水系沉积物元素地球化学特征及异常圈定

青海冷龙岭地区位于北祁连成矿段的东段,是形成与海相火山岩有关的块状硫化物矿床及岩浆热液型矿床的有利地区,具有良好的找矿潜力。在1∶5万水系沉积物测量成果的基础上,对青海冷龙岭地区Au、Cu、Pb、Zn等17种元素的地球化学特征进行了初步分析,发现本区Ag、Pb、Zn、W、Sn、Bi、Mo、Ba、Cd等元素丰度明显高于青海省及祁连地区水系沉积物的平均丰度值;元素分布特征显示下奥陶统阴沟群除Hg、La、Ce相对贫化外,各元素都呈现不同程度的浓集,加里东期侵入岩中Ag、Cu、Pb、Zn、W、Au、Sn、Bi等元素富集程度较高,海西期正长岩内Ba、La、Ce等元素富集程度较为显著;R型聚类分析和因子分析显示区内的主要成矿元素组合为Cu Pb Ag Mo Ba La Ce,Au具有独立成矿的潜力。结合元素地球化学参数及富集离散特征,认为本区Au、Ag、Cu、Pb、Zn、Mo、La、Ce等元素具有一定的找矿潜力。本次工作共圈定8个综合异常。根据研究区成矿地质背景、异常特征及查证成果,与该区域内浪力克铜矿床和青分岭金矿床的地质地球化学特征对比研究后,优选出干沙河和三道路圈—倒阳河2个成矿远景区。     

广西高龙金矿鸡公岩矿段地质特征和构造地球化学找矿

对矿区地表至960m中段共计6个中段平面系统采集构造地球化学样品,共采集地层和构造蚀变岩样品184件,测试了Au、Ag、As、Sb、Cu、Pb、Zn、Sn、Mo、Mn、Co、Ni、Cr、V、Ti 15种微量元素的含量,编制了各元素地球化学纵剖面图和单个矿脉元素含量曲线图,综合地球化学图件分析法和格里戈良分带指数法确定了元素的纵向、横向和轴向分带序列,建立了原生晕地球化学三维分带模式。综合地质地球化学资料分析得到:硅化砂泥岩、构造蚀变岩中Au、As、Sb、Ag元素含量高,是地壳的数倍到数百倍,变异系数大,表明这些元素卷入了成矿作用,硅化泥岩是主要的富矿围岩,而矿体大部分赋存于由于成矿热液多期次强烈活动而形成的石英岩和构造角砾岩中。矿区原生晕轴向分带序列为:As、Pb、Mo、Sn、Cu、Au、Ag、Mn、Zn、Sb。与矿体北西向侧伏规律一致,矿区地球化学异常体亦具向北西侧伏的趋势。根据元素地球化学纵剖面图中主成矿元素异常高值带向下延伸未封闭,矿体向下未尖灭、特征前缘晕元素Sb和成矿晕元素Zn出现在矿尾晕等特征说明,矿体向下仍有一定的延伸,已知矿体北西侧深部是下一步找矿勘探的重点区域。     

新疆哈密红石铜矿区300m中段原生晕地球化学特征及成矿预测

新疆哈密红石铜矿位于东天山大南湖-头苏泉岛弧带北段的卡拉塔格地区,为浅成低温热液脉型铜矿床。在矿床深部300m中段开展1:100原生晕地球化学剖面测量,选择Ag、Cu、Mo、Zn、As、Sb、Hg、Au、Pb、W、Ba、Bi、Sn等13种元素进行测试分析,查明与矿有关的地球化学特征,预测成矿有利地段。研究通过R型因子分析,识别Sb-Hg-As-Au前缘晕指示元素组合、Ag-Cu-Mo-Zn近矿晕指示元素组合、Ba-Bi尾晕指示元素组合,以及Se-Zn-Pb等元素共同代表岩浆期后中高温热液活动阶段,显示出该矿床具有多期、多阶段成矿的特征;依据C.B.格里戈良分带指数原理,建立（Sb×Hg）D/（Ba×Bi）D矿体定量预测指标,并结合矿化-蚀变特征,圈定1处成矿有利重点地段和1处成矿有利一般地段,分别为300m中段25线~19线成矿热液角砾岩筒的深部或周边,以及300m中段13线~7线1、6、9号脉矿（化）带的深部和周边;验证孔ZKY2101揭露了角砾岩筒深部的矿化情况,取得良好效果。     

河南省罗山县山店地区地球化学方法找铜钼矿实践

大别山北麓山店地区发现的斑岩型铜钼矿床均为隐伏矿床,在地质勘探过程中采用土壤地球化学测量方法,查明地球化学晕指示元素为金、银、铜、铜、锌、钨、锡、钼、砷、锑、铋,结合地球化学异常选定勘查靶区;综合研究元素组合的前缘晕、近矿晕和尾晕及各元素的叠合情况,判断是否为矿致异常及矿体赋存部位。实践证明,运用地球化学方法预测隐伏铜钼矿床是一种经济有效的找矿方法,采用地球化学资料和地质资料相结合,可有效地判断地质体的含矿性,确定有利的成矿部位。     

新疆富蕴县希勒库都克钼铜矿床地球化学特征

通过对希勒库都克钼铜矿床的矿床地质、矿区地层、岩浆岩微量元素含量特征进行研究,认为下石炭统南明水组上亚组地层富集成矿元素,为矿区的主要含矿层位,该地层中强蚀变砂岩、凝灰质粉砂岩的成矿元素含量较高,为矿区的主要赋矿围岩。岩浆岩中成矿元素及主要伴生元素的含量特征显示,海西中晚期侵入的花岗闪长岩、花岗闪长斑岩和闪长斑岩（玢岩）与成矿作用密切,可能直接或间接提供了成矿物质来源。矿床在水平和垂直方向上均具有良好的分带特征,水平上由矿床中心向外呈现Mo、Cu（Au）、→V、Ti、Co、Cr、Ni、Mn、As、Sb、Hg、W、Sn、Bi→Ag、Zn、B、F的分带特征,垂向上自上而下呈现F、B、As（Cr、Ni）→Au、Cu、W（Mo、V、Co、Bi）→Mn（Au、V、Bi、Mo）的分带特征,对指导找矿具有一定意义。     

甘肃北山金、铜矿床红沙的植物地球化学特征及其找矿意义

北山地区植被属戈壁荒漠植被类型，主要植物群落为红沙，红沙中多数元素特别是成矿元素及其伴生元素的含量和变化系数矿区大于背景区，元素含量背景区呈对数正态分布，矿区呈偏对数正态或多峰分布，红沙中的元素组合分类背景区为Au,Cu,Pb,Zn,As,Sb,Mo,V,Mn和Ag,Sn,Sr,Ba及Ti,Cr,Co,Ni,金矿区为Au,Ag,As,Sb,Mo,Mn,Sr和Cu,Pb,Zn,Sn,Ba及Co,Ni,Ti,V,Cr,铜矿区为Cu,Pb,Zn,Mo,Au,Ag,Ba和As,Sb,Sn,Mn及Ti,V,Cr,Co,Ni,Sr，矿区红沙中浓集系数较大的元素多数在矿区岩石中的浓集系统亦较大，金，铜矿床红沙和岩石中的特征元素分别都有Au,Ag,Ag,Sb,Mo,(Mn)和Cu,Pb,(Ba,Ti,Cr)。在金，铜矿床（体上方分别发育有良好的Au和Cu的生物地球化学异常和元素组合及分带，根据红沙的地球化学特征能，判断金或铜矿种类型，并能对掩埋，隐伏金，铜矿床（体）进行定位预测。     

Material composition and geochemical characteristics of ores of the Malinovskoe gold-ore deposit (Primorskii Krai,Russia)

The mineral composition and geochemical characteristics of the ores of the Malinovskoe gold-ore deposit are studied by the data from mining works (ditches, cleanings, and boreholes). It is found that the ore–magma system of the deposit was formed in several stages of mineralization characterized by two phases of magmatism differing in age. In terms of the set of features (the geological–structural position of the deposit, as well as the material composition and geochemical characteristics of the ores), the deposit is attributed to the gold–tourmaline type of mineralization associated spatially and genetically with the “raremetal” granitoid magmatism. This type has not previously been found in Primorskii Krai. The studies of the material composition and geochemical characteristics of the ores allow us to ascertain the correlations between the elements along with the reasons of their origination. By analogy with other gold-ore formations of the Russian Far East, the mineralogical and geochemical model of the deposit is developed (Be–Sn–Cr–Ba–Au–Cu–Mo–Pb–V–Ti–Co–W–Ag–Bi–Ni–Mn–Sr–Zn–Sb–As modeling element series of vertical zoning), which enables us to estimate the levels of the erosion section of the ore bodies and to evaluate their prospects. It is found that the most productive associations in the deposit are the gold–bismuth geochemical association (Au–Ag–Bi–Cu–As–Co) and, to a lesser degree, the gold–tungsten association (W–Au–Ag–Cu–Bi–As).     

Types,features, and prospecting potential for Mesozoic metal ore deposits in Zhejiang Province,southeast China

The geotectonic units of Zhejiang Province include the Yangtze Plate in the northwest juxtaposed against the South China fold system in the southeast along the Jiangshan–Shaoxing fault. The South China fold system is further divided into the Chencai–Suichang uplift belt and the Wenzhou–Linhai geotectogene belt, whose boundary is the Yuyao–Lishui fault. The corresponding metallogenic belts are the Mo–Au(–Pb–Zn–Cu) metallogenic belt in northwest Zhejiang, the Chencai–Suichang Au–Ag–Pb–Zn–Mo metallogenic belt, and the coastal Ag–Pb–Zn–Mo–Au metallogenic belt. The main Mesozoic metal ore deposits include epithermal Au–Ag(Ag), hydrothermal vein-type Ag–Pb–Zn(Cu), and porphyry–skarn-type Mo and vein-type Mo deposits. These ore bodies are related to the Mesozoic volcanic-intrusive structure: the epithermal Au–Ag(Ag) deposits are represented by the Zhilingtou Au–Ag deposit and Houan Ag deposit and their veins are controlled by volcanic structure; the hydrothermal vein-type Ag–Pb–Zn deposits are represented by the Dalingkou Ag–Pb–Zn deposit and also controlled by volcanic structure; and the porphyry–skarn-type Mo deposits are represented by the Tongcun Mo deposit and the vein-type Mo deposits are represented by the Shipingchuan Mo deposit, all of which are related to granite porphyries. These metal ore deposits have close spatio-temporal relationships with each other; both the epithermal Au–Ag(Ag) deposits and the hydrothermal vein-type Ag–Pb–Zn deposits exhibit vertical zonations of the metallic elements and form a Mo–Pb–Zn–Au–Ag metallogenetic system. These Jurassic–Cretaceous deposits may be products of tectonic-volcanic-intrusive magmatic activities during the westward subduction of the Pacific Plate. Favourable metallogenetic conditions and breakthroughs in the recent prospecting show that there is great resource potential for porphyry-type deposits (Mo, Cu) in Zhejiang Province.     

蒙古国那仁陶勒盖金矿床原生晕特征及深部预测

为预测和评价那仁陶勒盖金矿的成矿潜力,运用多元统计方法,结合地球化学各参数信息,对那仁陶勒盖金矿原生晕进行系统研究.结果显示:那仁陶勒盖金矿赋矿花岗闪长岩中Au、Ag、Bi等元素浓集克拉克值明显偏高,与那仁陶勒盖金成矿作用关系密切;矿石中Au与Sb、Cu、Pb、Ag、Hg、Zn、As、Bi等关系最为密切;矿体原生晕轴向分带序列出现尾晕元素W、Sn等与前缘晕元素As叠加的现象,同时(As+Sb)/(Bi+Mo)、100Sb/(Bi·Mo)等分带性指数出现转折,指示深部存在盲矿体.依据上述矿体原生晕特征,建立矿体叠加晕预测模型,预测盲矿体赋存位置在海拔710m以下的岩体与地层接触带附近.     

辽宁五龙金矿163矿脉深部钻孔地球化学特征及找矿意义

五龙金矿是辽东地区大型岩浆热液型金矿床,163矿脉是矿区内目前发现的最大含矿构造。为进一步探测深部找矿潜力,近几年矿山对163矿脉进行了大量的探采工程,其中在-762 m坑道实施了600 m钻孔。本文在详细编录该钻孔的基础上,对全孔样品进行成矿元素测试工作,利用SPSS软件对所得测试数据进行元素相关性、聚类、因子分析。相关性分析显示,具有显著正相关的元素主要为Bi、W、Cu、Ag、Au和As、Sb、Sn、Zn两组;Mo元素与Sn、Ag、Cu、Bi、W、Sb地素具有显著正相关性,而Pb元素与Cu、Mo、Au、W元素呈显著负相关性,Hg元素与其它元素相关性不明显。聚类分析结果表明,R型聚类在类的距离为5的水平上,这些元素明显可分为3组：Hg、Cu、Pb、Zn、Sn、Mo、As、W;Ag、Au、Sb、Bi。因子分析结果表明,提取3个因子可以反映出12个元素变量64.42%的地球化学信息,F1的主要载荷因子组成为Sn、Ag、As、Zn、Sb, F2的主要载荷因子组成为Au、W、Bi、-Pb, F3的主要载荷因子组成为Hg。根据成矿元素随深度变化特征,结合前人构造叠加晕研究成果,推测该钻孔深部还...     

五台山—恒山绿岩带Au-Ag-Cu成矿作用地球化学特征

五台山—恒山绿岩带Ａｕ、Ａｇ、Ｃｕ矿床可分为二大类型：（１）再生型金银铜矿，产在包括岩浆岩在内的各类岩石断裂构造中，与岩浆期后热液有关；（２）变生型金银铜矿，产于各类变质岩中，具有层控特征（即绿岩型金矿）。在地球化学特征上，再生型矿床与变生型矿床相比，矿体及围岩中Ｍｏ、Ａｇ、Ｐｂ、Ｚｎ、Ｃｄ等成矿及伴生元素明显富集；Ｋ２Ｏ、Ｒｂ、Ｓｒ、Ｂａ、Ｔｈ、Ｕ也明显富集，是后期岩浆热液作用的结果；Ｈｇ、Ｆ的明显富集则与后期构造活动有关；Ｚｎ／Ｃｄ比值较低，说明受到后期岩浆侵入影响；Ｔｈ／Ｕ比值低，可能指示富钙的酸性岩环境。再生型Ａｕ矿化的元素组合为Ｃｄ、Ａｓ、Ｎｉ、Ａｇ、Ｓｂ、Ａｕ、Ｈｇ（Ｂｉ），再生型Ａｇ矿化的元素组合为Ａｓ、Ｓｂ、Ａｇ、Ｃｄ、Ｃｕ、Ｎｉ（Ｍｏ、Ｐｂ、Ｚｎ、Ｂｉ），变生型Ａｕ矿化的元素组合较简单，只为Ａｕ、Ｈｇ、Ａｓ或Ａｕ、Ｃｕ。上述地球化学特征不仅可以有效地区分矿化类型，而且可以作为地球化学找矿和评价的指标     

Copper-Polymetal Metallogenic Series and Prospecting Perspective of Eastern Section of Gangdise

Geological, geophysical, geochemical and remote sensing comprehensive studies show that big ore-prospecting potentiality is contained in the eastern section of the Gangdise Mountains, Tibet.There are various mineralization types with dominant types of porphyry and exhalation. According to their relations with tectonic evolution, they are divided into four kinds of metallogenic series as follows:magnmtic type (Cr, Pt, Cu, Ni) and exhalation type (Cu, Pb, Zn, Ag) ore deposit series related to Neo-Tethys oceanic crust subduction action (125-96 Ma); epithermai type (Au, Ag, Pb, Zn, Sb), altered fractured rock type (Cu, Mo) and skarn rock type (Cu) ore deposit series related to arc-continental collision; porphyry type (Cu, Mo), cryptoexplosion breccia type (Cu, Au, Pb, Zn), shear zone type (Au, Ag, Sb) and skarn rock type (Cu, Fe) ore deposit series with relation to post-orogenic extensional strike-slip. From subductive complex to the north, zoning appears to be crystallization differentiation type (segregation type)-shear zone type (altered rock type)-skarn rock type, epithermai type-porphyry type-porphyry type and exhalation type-exhalation type-hydrothermai filling-replacement type.The ore deposit is characterized by multi-places from the same source, parity and multi-stage, hypabyssal rock from the deep source and poly genetic compound as a whole.     

滇西北烂泥塘斑岩铜矿床原生晕异常结构研究

烂泥塘矿床是云南香格里拉地区典型的斑岩型铜矿床,主矿体产于在地表以下300～500米,地表矿化带仅见脉状铜矿体和铜矿化体.为研究云南香格里拉烂泥塘斑岩铜矿床的原生晕异常结构,本文以异常结构模式理论和方法为基础,对矿床地表和坑道岩矿石样品开展了元素组合、异常特征和水平分带规律研究.结果表明,烂泥塘铜矿床地球化学系统的结构...     

内蒙古五岔沟地区物化探异常特征及找矿前景

以1∶10000物化探异常查证成果为基础,依据内蒙古大兴安岭南段成矿带的多金属矿成矿规律,详细分析了五岔沟地区的物化探异常特征,总结出了两种典型的物化探异常类型,一种以Pb、Zn、Ag为主要成矿元素,元素组合为Cu、Pb、Zn、Ag、Bi、Sn、Au、As、Sb、Hg,一般以低阻高极化为特征;另一种以Mo为主要成矿元素...     

浙江临安西天目地区找矿潜力分析

浙江临安西天目地区地处早古生代扬子被动陆缘和晚中生代西太平洋活动陆缘构造叠加区域.该区发育碳酸盐岩建造,有大量的脉岩出露,环形、放射状断裂构造发育,具有面型蚀变及铜、铅、锌、金等多个矿（化）点;重磁等物探信息显示,该区深部发育EW向深断裂和隐伏岩体;化探扫面揭示,区内钨、钼、铋、铜、铅、锌、金、银、砷等元素背景高;自然重砂调查反映,白钨矿、铅族、钼族等重砂矿物组合具有异常显示.综合成矿地质条件及物、化、重砂异常等信息,认为该区具有寻找斑岩型、夕卡岩型、低温热液型钨、钼、铜、铅锌、金银等多位一体矿床的潜力.     

北山地区北东向构造对金钨锡钼(稀土)矿床控制作用初探

地处甘、新、内蒙交界部位的北山地区是我国重要的内生金属矿产集中区之一,金、钨、锡、钼等与花岗岩有关的金属矿床具有良好的成矿地质条件和找矿潜力。本文通过对北山地区地球物理、地球化学和矿床成矿地质背景的系统分析,讨论了北东向基底断裂构造对与花岗岩有关的金、钨、锡、钼等矿床形成的重要控制作用。指出了该区今后开展地质找矿工作的方向。