Clouds on Titan during the Cassini prime mission: A complete analysis of the VIMS data

We use data from the VIMS instrument on board the Cassini spacecraft to construct high sensitivity and high spatial-resolution maps of the locations of tropospheric clouds on Titan in the late northern winter season during which the Cassini prime mission took place. These observations show that, in this season, clouds on Titan are strongly hemispherically asymmetric. Mid-latitude clouds, in particular, occur only in the southern hemisphere and have not ever been observed in the north. Such an asymmetry is in general agreement with circulation models where sub-solar surface heating controls the locations of clouds and appears in conflict with models where perennial polar hazes prevent significant summertime polar heating from affecting the circulation. The southern mid-latitude clouds appear to be distributed uniformly in longitude, in contrast to some previous observations. Southern high-latitude clouds exhibit a significant concentration, however, between about 180° and 270°E longitude. A spatially and temporally uniform cloud always appears northward of ∼50°N latitude. This cloud appears unchanged over the course of the observations, consistent with the interpretation that it is caused by continuous ethane condensation as air subsides and radiatively cools through the tropopause. The location of this cloud likely provides a direct tracer of elements of north polar atmospheric circulation, potentially allowing continuous monitoring of circulation changes as Titan passes through equinox into north polar spring and summer. We show that a similar analysis of this dataset by Rodriguez et al. (2009) contains substantial errors and should not be used.     

Dissipation of Titan's north polar cloud at northern spring equinox

Saturn's Moon Titan has a thick atmosphere with a meteorological cycle. We report on the evolution of the giant cloud system covering its north pole using observations acquired by the Visual and Infrared Mapping Spectrometer onboard the Cassini spacecraft. A radiative transfer model in spherical geometry shows that the clouds are found at an altitude between 30 and 65 km. We also show that the polar cloud system vanished progressively as Titan approached equinox in August 2009, revealing at optical wavelengths the underlying sea known as Kraken Mare. This decrease of activity suggests that the north-polar downwelling has begun to shut off. Such a scenario is compared with the Titan global circulation model of Rannou et al. (2006), which predicts a decrease of cloud coverage in northern latitudes at the same period of time.     

Convective cloud heights as a diagnostic for methane environment on Titan

The appearance of convective clouds in Titan’s troposphere has been documented from ground-based observation for more than a decade. Cloud tops have been reported between 14 and 25 km. Higher resolution Cassini data have shown smaller portions of the cloud system can reach up to 42 km. We use the Titan Regional Atmospheric Modeling System (TRAMS) to explore environments which allow convective clouds to reach the tropopause. In general, cloud tops remain below 30 km, but for environments where the surface humidity of methane is greater than 50%, a small portion at the center of the cloud rises briefly to higher altitudes; for ?65% humidity, the cloud top reaches nearly to the tropopause (∼40 km). A number of other parameters also have noticeable affects on cloud top such as nucleation critical saturation, haze abundance, and collisional growth of cloud particles.     

Dissipation of Titan's south polar clouds

Nearly all adaptive optics images of Titan taken between December 2001 and November 2004 showed tropospheric clouds located within 30° of the south pole. We report here on a dissipation of Titan's south polar clouds observed in twenty-nine Keck and Gemini images taken between December 2004 and April 2005. The near complete lack of south polar cloud activity during this time, and subsequent resurgence months later at generally higher latitudes, may be the beginning of seasonal change in Titan's weather. The ∼5 month decrease in cloud activity may also have been caused by methane rainout from a large cloud event in October 2004. Understanding the seasonal evolution of Titan's clouds, and of any precipitation associated with them, is essential for interpreting the geological observations of fluid flow features observed over a wide range of Titan latitudes with the Cassini/Huygens spacecraft.     

Seasonal change on Saturn from Cassini/CIRS observations, 2004-2009

Five years of thermal infrared spectra from the Cassini Composite Infrared Spectrometer (CIRS) are analyzed to determine the response of Saturn’s atmosphere to seasonal changes in insolation. Hemispheric mapping sequences at 15.0 cm⁻¹ spectral resolution are used to retrieve the variation in the zonal mean temperatures in the stratosphere (0.5-5.0 mbar) and upper troposphere (75-800 mbar) between October 2004 (shortly after the summer solstice in the southern hemisphere) and July 2009 (shortly before the autumnal equinox).Saturn’s northern mid-latitudes show signs of dramatic warming in the stratosphere (by 6-10 K) as they emerge from ring-shadow into springtime conditions, whereas southern mid-latitudes show evidence for cooling (4-6 K). The 40-K asymmetry in stratospheric temperatures between northern and southern hemispheres (at 1 mbar) slowly decreased during the timespan of the observations. Tropospheric temperatures also show temporal variations but with a smaller range, consistent with the increasing radiative time constant of the atmospheric response with increasing pressure. The tropospheric response to the insolation changes shows the largest magnitude at the locations of the broad retrograde jets. Saturn’s warm south-polar stratospheric hood has cooled over the course of the mission, but remains present.Stratospheric temperatures are compared to a radiative climate model which accounts for the spatial distribution of the stratospheric coolants. The model successfully predicts the magnitude and morphology of the observed changes at most latitudes. However, the model fails at locations where strong dynamical perturbations dominate the temporal changes in the thermal field, such as the hot polar vortices and the equatorial semi-annual oscillation (Orton, G., and 27 colleagues [2008]. Nature 453, 196-198). Furthermore, observed temperatures in Saturn’s ring-shadowed regions are larger than predicted by all radiative-climate models to date due to the incomplete characterization of the dynamical response to the shadow. Finally, far-infrared CIRS spectra are used to demonstrate variability of the para-hydrogen distribution over the 5-year span of the dataset, which may be related to observed changes in Saturn’s tropospheric haze in the spring hemisphere.     

Cassini SAR, radiometry, scatterometry and altimetry observations of Titan’s dune fields

Large expanses of linear dunes cover Titan’s equatorial regions. As the Cassini mission continues, more dune fields are becoming unveiled and examined by the microwave radar in all its modes of operation (SAR, radiometry, scatterometry, altimetry) and with an increasing variety of observational geometries. In this paper, we report on Cassini’s radar instrument observations of the dune fields mapped through May 2009 and present our key findings in terms of Titan’s geology and climate. We estimate that dune fields cover ∼12.5% of Titan’s surface, which corresponds to an area of ∼10 million km², roughly the area of the United States. If dune sand-sized particles are mainly composed of solid organics as suggested by VIMS observations (Cassini Visual and Infrared Mapping Spectrometer) and atmospheric modeling and supported by radiometry data, dune fields are the largest known organic reservoir on Titan. Dune regions are, with the exception of the polar lakes and seas, the least reflective and most emissive features on this moon. Interestingly, we also find a latitudinal dependence in the dune field microwave properties: up to a latitude of ∼11°, dune fields tend to become less emissive and brighter as one moves northward. Above ∼11° this trend is reversed. The microwave signatures of the dune regions are thought to be primarily controlled by the interdune proportion (relative to that of the dune), roughness and degree of sand cover. In agreement with radiometry and scatterometry observations, SAR images suggest that the fraction of interdunes increases northward up to a latitude of ∼14°. In general, scattering from the subsurface (volume scattering and surface scattering from buried interfaces) makes interdunal regions brighter than the dunes. The observed latitudinal trend may therefore also be partially caused by a gradual thinning of the interdunal sand cover or surrounding sand sheets to the north, thus allowing wave penetration in the underlying substrate. Altimetry measurements over dunes have highlighted a region located in the Fensal dune field (∼5° latitude) where the icy bedrock of Titan is likely exposed within smooth interdune areas. The hemispherical assymetry of dune field properties may point to a general reduction in the availability of sediments and/or an increase in the ground humidity toward the north, which could be related to Titan’s asymmetric seasonal polar insolation. Alternatively, it may indicate that either the wind pattern or the topography is less favorable for dune formation in Titan’s northern tropics.     

A primordial origin for the atmospheric methane of Saturn’s moon Titan

The origin of Titan’s atmospheric methane is a key issue for understanding the origin of the saturnian satellite system. It has been proposed that serpentinization reactions in Titan’s interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan’s planetesimals before its formation. Here, we point out that serpentinization reactions in Titan’s interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan’s water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan’s interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/H ratio is its direct capture in the satellite’s planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan’s interior can be up to ∼1300 times the current mass of atmospheric methane.     

Far-infrared opacity sources in Titan’s troposphere reconsidered

We use Cassini far-infrared limb and nadir spectra, together with recent Huygens results, to shed new light on the controversial far-infrared opacity sources in Titan’s troposphere. Although a global cloud of large CH₄ ice particles around an altitude of 30 km, together with an increase in tropospheric haze opacity with respect to the stratosphere, can fit nadir and limb spectra well, this cloud does not seem consistent with shortwave measurements of Titan. Instead, the N₂-CH₄ collision-induced absorption coefficients are probably underestimated by at least 50% for low temperatures.     

A large cloud outburst at Titan's south pole

Images of Titan acquired over five nights in October 2004 using the adaptive optics system at the Keck Observatory show dramatic increases in tropospheric cloud activity at the south pole compared with all other images of Titan clouds to date. During this time, Titan's south polar clouds brightened to more than 18 times their typical values. The Cassini Ta flyby of Titan occurred as this storm was rapidly dissipating. We find that the brightness of this cloud outburst is consistent with the dramatic transient brightening of Titan observed in atmospheric windows on two nights in 1995 by Griffith et al. [Griffith, C.A., Owen, T., Miller, G.A., Geballe, T., 1998. Nature 395 (6702) 575-578] if we scale the brightness of the cloud by projecting it onto the equator. While apparently infrequent, the fact that large cloud events have been observed in different seasons of Titan's year indicates that these large storms might be a year-round phenomenon on Titan. We propose possible mechanisms to explain these occasional short-term increases in Titan's cloud activity.     

Temporal variations of Titan’s middle-atmospheric temperatures from 2004 to 2009 observed by Cassini/CIRS

We use five and one-half years of limb- and nadir-viewing temperature mapping observations by the Composite Infrared Radiometer-Spectrometer (CIRS) on the Cassini Saturn orbiter, taken between July 2004 and December 2009 (L_S from 293° to 4°; northern mid-winter to just after northern spring equinox), to monitor temperature changes in the upper stratosphere and lower mesosphere of Titan. The largest changes are in the northern (winter) polar stratopause, which has declined in temperature by over 20 K between 2005 and 2009. Throughout the rest of the mid to upper stratosphere and lower mesosphere, temperature changes are less than 5 K. In the southern hemisphere, temperatures in the middle stratosphere near 1 mbar increased by 1-2 K from 2004 through early 2007, then declined by 2-4 K throughout 2008 and 2009, with the changes being larger at more polar latitudes. Middle stratospheric temperatures at mid-northern latitudes show a small 1-2 K increase from 2005 through 2009. At north polar latitudes within the polar vortex, temperatures in the middle stratosphere show a ∼4 K increase during 2007, followed by a comparable decrease in temperatures in 2008 and into early 2009. The observed temperature changes in the north polar region are consistent with a weakening of the subsidence within the descending branch of the middle atmosphere meridional circulation.     

Water ice clouds in the Martian atmosphere: Two Martian years of SPICAM nadir UV measurements

The SPICAM instrument onboard Mars Express has successfully performed two Martian years (MY 27 and MY28) of observations. Water ice cloud optical depths spatial and temporal distribution was retrieved from nadir measurements in the wavelength range 300–320 nm. During the northern spring the cloud hazes complex distribution was monitored. The clouds in the southern hemisphere formed a zonal belt in the latitude range 30–60°S. The edge of the retreating north polar hood merged with the northern tropical clouds in the range 250–350°E. The development of the aphelion cloud belt (ACB) started with the weak hazes formation (cloud optical thickness 0.1–0.3) in the equatorial region. At the end of the northern spring, the ACB cloud optical thickness reached already values of 0.3–1. The ACB decay in the end of the northern summer was accompanied with a presence of clouds in the north mid-latitudes. The expanded north polar hood merged with the north mid-latitude clouds in the eastern hemisphere. The interannual comparison indicates a decrease in cloud activity immediately after a strong dust storm in southern summer of MY28. The strong dust storms of the MY28 may also be a reason of the observed north polar hood edge shifting northward by 5°.     

Organic sedimentary deposits in Titan’s dry lakebeds: Probable evaporite

We report the discovery of organic sedimentary deposits at the bottom of dry lakebeds near Titan’s north pole in observations from the Cassini Visual and Infrared Mapping Spectrometer (VIMS). We show evidence that the deposits are evaporitic, making Titan just the third known planetary body with evaporitic processes after Earth and Mars, and is the first that uses a solvent other than water.     

Titan's highly dynamic magnetic environment: A systematic survey of Cassini magnetometer observations from flybys TA-T62

We analyze the variability of the ambient magnetic field near Titan during Cassini encounters TA-T62 (October 2004-October 2009). Cassini magnetometer (MAG) data show that the moon's magnetic environment is strongly affected by its proximity to Saturn's warped and highly dynamic magnetodisk. In the nightside sector of Saturn's magnetosphere, the magnetic field near Titan is controlled by intense vertical flapping motions of the magnetodisk current sheet, alternately exposing the moon to radially stretched lobe-type fields and to more dipolar, but highly distorted current sheet fields. In southern summer, when most of the Cassini encounters took place, the magnetodisk current sheet was on average located above Titan's orbital plane. However, around equinox in August 2009, the distortions of Titan's magnetic environment due to the rapidly moving current sheet reached a maximum, thus suggesting that the equilibrium position of the sheet at that time was significantly closer to the moon's orbital plane. In the dayside magnetosphere, the formation of the magnetodisk lobes is partially suppressed due to the proximity of the magnetopause. Therefore, during most encounters that took place near noon, Titan was embedded in highly distorted current sheet fields. Within the framework of this study, we not only provide a systematic classification of all Titan flybys between October 2004 and October 2009 as lobe-type or current sheet scenarios, but we also calculate the magnetospheric background field near Titan's orbit whenever possible. Our results show that so far, there is not a single Cassini flyby that matches the frequently applied picture of Titan's plasma interaction from the pre-Cassini era (background field homogeneous, stationary and perpendicular to the moon's orbital plane). The time scales upon which the ambient magnetospheric field close to Titan undergoes significant changes range between only a few minutes and up to several hours. The implications for the development of numerical models for Titan's local plasma interaction are discussed as well.     

Titan trace gaseous composition from CIRS at the end of the Cassini-Huygens prime mission

This paper reports on the results from an extensive study of all nadir-looking spectra acquired by Cassini/CIRS during the 44 flybys performed in the course of the nominal mission (2004-2008). With respect to the previous study (Coustenis, A., and 24 colleagues [2007]. Icarus 189, 35-62, on flybys TB-T10) we present here a significantly richer dataset with, in particular, more data at high northern and southern latitudes so that the abundances inferred here at these regions are more reliable. Our enhanced high-resolution dataset allows us to infer more precisely the chemical composition of Titan all over the disk. We also include improved spectroscopic data for some molecules and updated temperature profiles. The latitudinal distributions of all of the gaseous species are inferred. We furthermore test vertical distributions essentially for acetylene (C₂H₂) from CIRS limb-inferred data and from current General Circulation Models for Titan and compare our results on all the gaseous abundances with predictions from 1-D photochemical-radiative models to check the reliability of the chemical reactions and pathways.     

THE ATMOSPHERES OF SATURN AND TITAN IN THE NEAR-INFRARED: FIRST RESULTS OF CASSINI/VIMS

The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH₄ fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet’s sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn’s troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO₂, and CH₃D on Titan’s nightside limb, (2) the mapping of CH₄ fluorescence over the dayside bright limb, extending to ∼ ∼750 km altitude, (3) wind measurements of ∼ ∼0.5 ms⁻¹, favoring prograde, from the movement of a persistent (multiple months) south polar cloud near 88° S latitude, and (4) the imaging of two transient mid-southern-latitude cloud features.     

Photometric properties of Titan''s surface from Cassini VIMS: Relevance to titan''s hemispherical albedo dichotomy and surface stability

The Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini Saturn Orbiter returned spectral imaging data as the spacecraft undertook six close encounters with Titan beginning 7 July, 2004. Three of these flybys each produced overlapping coverage of two distinct regions of Titan's surface. Twenty-four points were selected on approximately opposite hemispheres to serve as photometric controls. Six points were selected in each of four reflectance classes. On one hemisphere each control point was observed at three distinct phase angles. From the derived phase coefficients, preliminary normal reflectances were derived for each reflectance class. The normal reflectance of Titan's surface units at 2.0178 μm ranged from 0.079 to 0.185 for the most absorbing to the most reflective units assuming no contribution from absorbing haze. When a modest haze contribution of τ=0.1 is considered these numbers increase to 0.089–0.215. We find that the lowest three reflectance classes have comparable normal reflectance on either hemisphere. However, for the highest brightness class the normal reflectance is higher on the hemisphere encompassing longitude 14–65° compared to the same high brightness class for the hemisphere encompassing 122–156° longitude. We conclude that an albedo dichotomy observed in continental sized units on Titan is due not only to one unit having more areal coverage of reflective material than the other but the material on the brighter unit is intrinsically more reflective than the most reflective material on the other unit. This suggests that surface renewal processes are more widespread on Titan's more reflective units than on its less reflective units.

We note that one of our photometric control points has increased in reflectance by 12% relative to the surrounding terrain from July of 2004 to April and May of 2005. Possible causes of this effect include atmospheric processes such as ground fog or orographic clouds; the suggestion of active volcanism cannot be ruled out.

Several interesting circular features which resembled impact craters were identified on Titan's surface at the time of the initial Titan flyby in July of 2004. We traced photometric profiles through two of these candidate craters and attempted to fit these profiles to the photometric properties expected from model depressions. We find that the best-fit attempt to model these features as craters requires that they be unrealistically deep, approximately 70 km deep. We conclude that despite their appearance, these circular features are not craters, however, the possibility that they are palimpsests cannot be ruled out.

We used two methods to test for the presence of vast expanses of liquids on Titan's surface that had been suggested to resemble oceans. Specular reflection of sunlight would be indicative of widespread liquids on the surface; we found no evidence of this. A large liquid body should also show uniformity in photometric profile; we found the profiles to be highly variable. The lack of specular reflection and the high photometric variability in the profiles across candidate oceans is inconsistent with the presence of vast expanses of flat-lying liquids on Titan's surface. While liquid accumulation may be present as small, sub-pixel-sized bodies, or in areas of the surface which still remain to be observed by VIMS, the presence of large ocean-sized accumulations of liquids can be ruled out.

The Cassini orbital tour offers the opportunity for VIMS to image the same parts of Titan's surface repeatedly at many different illumination and observation geometries. This creates the possibility of understanding the properties of Titan's atmosphere and haze by iteratively adapting models to create a best fit to the surface reflectance properties.     

Hypsometry of Titan

Cassini RADAR topography data are used to evaluate Titan’s hypsometric profile, and to make comparisons with other planetary bodies. Titan’s hypsogram is unimodal and strikingly narrow compared with the terrestrial planets. To investigate topographic extremes, a novel variant on the classic hypsogram is introduced, with a logarithmic abscissa to highlight mountainous terrain. In such a plot, the top of the terrestrial hypsogram is quite distinct from those of Mars and Venus due to the ‘glacial buzz-saw’ that clips terrestrial topography above the snowline. In contrast to the positive skew seen in other hypsograms, with a long tail of positive relief due to mountains, there is an indication (weak, given the limited data for Titan so far) that the Titan hypsogram appears slightly negatively skewed, suggesting a significant population of unfilled depressions. Limited data permit only a simplistic comparison of Titan topography with other icy satellites but we find that the standard deviation of terrain height (albeit at different scales) is similar to those of Ganymede and Europa.     

Dynamics of Saturn's magnetodisk near Titan's orbit: Comparison of Cassini magnetometer observations from real and virtual Titan flybys

We analyze the variability of the ambient magnetospheric field along Titan's orbit at 20.3 Saturn radii. However, while our preceding study (Simon et al., 2010) focused on Cassini magnetometer observations from the 62 Titan flybys (TA-T62) between October 2004 and October 2009, the present work discusses magnetic field data that were collected near Titan's orbit when the moon was far away. In analogy to the observations during TA-T62, the magnetospheric fields detected during these 79 “virtual” Titan flybys are strongly affected by the presence of Saturn's bowl-shaped and highly dynamic magnetodisk current sheet. We therefore provide a systematic classification of the magnetic field observations as magnetodisk current sheet or lobe-type scenarios. Among the 141 (62 real+79 virtual) crossings of Titan's orbit between July 2004 and December 2009, only 17 encounters (9 real+8 virtual) took place within quiet, magnetodisk lobe-type fields. During another 50 encounters (21 real+29 virtual), rapid transitions between current sheet and lobe fields were observed around the moon's orbital plane. Most of the encounters (54=22 real+32 virtual) occurred when Titan's orbit was embedded in highly distorted current sheet fields, thereby invalidating the frequently applied idealized picture of Titan interacting with a homogeneous and stationary magnetospheric background field. The locations of real and virtual Titan flybys are correlated to each other. Each of the 62 real Titan flybys possesses at least one virtual counterpart that occurred shortly before or after the real encounter and at nearly the same orbital position. A systematic comparison between Cassini magnetometer observations from the real Titan flybys and their virtual companions suggests that there is no clear evidence of Titan exerting a significant level of control on the vertical oscillatory motion of the magnetodisk near its orbit.     

Observations of a stationary mid-latitude cloud system on Titan

We report the observation of a cloud system on Titan that remained localized near 40°S latitude and 60°W longitude for at least 34 h. Ground-based observations obtained with the SINFONI imaging spectrograph at the Very Large Telescope over four consecutive nights recorded the lifetime and altitude of the unresolved cloud system. Concomitant measurements made by Cassini/VIMS over 3 h resolved changes in the altitude and opacity of individual regions within the system during this time. Clouds are measured from 13 to 37 km altitude with optical depths per pixel ranging from τ=0.13 to 7. Short timescale rise times are consistent with previous measurements of the evolution of mid-latitude clouds; however the long timescale localization of the cloud structure is unexplained. We speculate about the role of mesoscale circulation in relation to cloud formation.     

The photochemical products of benzene in Titan’s upper atmosphere

The Cassini spacecraft detected benzene high in Titan’s atmosphere as well as the presence of large mass positive and negative ions. Previous work has suggested that these large mass ions could be composed of fused-ring polycyclic aromatic hydrocarbon compounds. These fused-ring PAHs, such as naphthalene and anthracene, are usually the result of high temperature processes that may not occur in Titan’s thin, cold, upper thermosphere. Here we suggest that a different class of aromatic compounds, polyphenyls, may be a better explanation of the data. Polyphenyls can grow to be large polymeric structures and could condense to form the aerosols seen in Titan’s cloud and hazes. They have similar properties to fused-ring PAHs (for example, electron affinity, ionization potential) and could be the negative ion species seen in the CAPS instrument data from the Cassini spacecraft.