五台地区高凡群形成时代新证据:锆石SHRIMP U-Pb定年

五台地区高凡群对于华北克拉通早前寒武纪变质地层层序建立具有重要意义。本文对高凡群磨河组开展了地球化学和锆石年代学研究。变质沉积岩稀土总量为(132.78~231.84)×10^-6(样品W1927的稀土总量为1016.55×10^-6),轻重稀土分离弱((La/Yb)_N=4.5~12.5),具明显负铕异常(δEu=0.37~0.62),稀土模式与太古宙后泥砂质碎屑沉积岩十分类似。一个白云石英片岩样品(D004)的变质原岩中存在大量2.7 Ga、2.54~2.5 Ga、2.3 Ga和2.18 Ga碎屑锆石,最年轻锆石可能来自同时代火山岩。一个含黄铁矿白云片岩样品(W1927)的最年轻锆石年龄为2194 Ma,被认为代表了岩石形成时代。结合前人研究,可把高凡群形成时代限定在<2176 Ma和2350 Ma之间,碎屑物质主要来自恒山、五台、阜平、云中山、吕梁地区新太古代—古元古代变质基底或更远的地区。     

河西走廊晚泥盆世地层中冥古宙碎屑锆石的发现

河西走廊地区晚泥盆统中宁组地层中,利用LA-ICP-MS法测年获得了3.9Ga和4.0Ga两颗碎屑锆石,其Th/U依次为1.01和0.58,均为岩浆锆石。两颗锆石稀土元素呈轻稀土(LREE)亏损、重稀土(HREE)富集,均具有Ce正异常,其中4.0Ga锆石具有Eu负异常,3.9Ga锆石无Eu负异常。利用锆石中⁴⁹Ti的含量计算原岩岩浆温度分别为792±36℃(3.9Ga)和967±45℃(4.0Ga)。3.9Ga锆石获得原位Hf同位素结果,¹⁷⁶Hf/¹⁷⁷Hf_i=0.280169,ε_Hf(t)=-3.6,t_DM=4139Ma, t_DM^C=4319Ma。这两颗>3.9Ga碎屑锆石为西北地区首次发现,其微量元素特征说明在冥古宙时地球上可能存在地壳;结合前人古生物和古地磁研究结果,说明河西走廊在晚泥盆世时同澳大利亚西北部可能具有亲缘性。     

华北克拉通南缘豫西下汤地区2.3 Ga岩浆作用和1.94 Ga变质作用

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成。岩石呈包体形式存在于中元古代花岗岩中。片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30Ga;岩石高SiO2和K2O,低ΣFeO、MgO和CaO,具稀土总量较高(ΣREE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu*=0.76)的稀土模式;εNd(t)(t=2.30Ga)=-0.75;tDM(Nd)=2.66Ga。黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25Ga;岩石低SiO2和MgO,高Al2O3和P2O5,具稀土总量高(ΣREE=373.4×10-6)、轻重稀土分离不强[(La/Yb)n=9.4]及较强负铕异常(Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25Ga)=-1.21;tDM(Nd)=2.75Ga。片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94Ga变质锆石年龄。片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30Ga)=-6.71～0.38,tDM1(Hf)=2627～2910Ma,tDM2(CC)(Hf)=2823～3255Ma。黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25Ga)=-19.58～-1.73,tDM1(Hf)=2664～3360Ma,tDM2(CC)(Hf)=2968～4011Ma。结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在一规模较大的约2.3Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的>2.7Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史。     

鲁西七星台地区新太古代基性岩浆作用:变质辉长岩的时代和组成

通过研究鲁西七星台地区新太古代变质辉长岩及相关岩石的锆石SHRIMP U-Pb年龄和地球化学组成.它们侵入新太古代表壳岩和TTG岩体.根据12个样品SHRIMP U-Pb锆石定年,可把形成时代划分为3期:2 662~>2 711 Ma、2 608~2 618 Ma和2 508~2 526 Ma.其他样品（进行地球化学分析）的形成时代是根据岩石空间分布、野外特征及与定年样品所代表岩石的关系来确定的.>2.65 Ga变质辉长岩既有来自于富集地幔源区也有来自亏损地幔源区.~2.6 Ga变质辉长岩具平坦型稀土模式,大离子亲石元素富集,Nb、Ta、P亏损,来自亏损地幔源区,可能遭受陆壳物质影响,~2.6 Ga变质辉石岩显示中稀土富集,与单斜辉石堆晶作用有关.~2.5 Ga变质辉长岩存在平坦型-轻微亏损轻稀土和轻稀土富集型两种类型稀土模式.与~2.5 Ga变质辉长岩相比,~2.5 Ga变质辉长闪长岩稀土含量更高,轻重稀土分异程度更高,大离子亲石元素更为富集,Nb、Ta亏损更为明显,是~2.5 Ga辉长质岩浆进一步结晶分异产物.结合前人研究,可得出如下结论.（1）七星台地区存在>2.65 Ga、~2.6 Ga和~2.5 Ga 3期变质辉长岩,其中~2.6 Ga变质辉长岩规模最大;（2）不同时代变质辉长岩地球化学组成特征不同,反映了源区组成和形成过程的复杂性;（3）鲁西地区在新太古代早期（>2.7~2.6 Ga）存在长期连续的基性岩浆作用,可能与地幔岩浆板底垫托有关;（4）在七星台地区首次发现~2.5 Ga辉长岩-辉长闪长岩,为鲁西地区A带广泛存在的~2.5 Ga深熔作用提供了热源来自地幔的直接证据.      

扬子陆块西南缘3.8 Ga碎屑锆石及其地质意义

古老锆石和岩石的发现,是探索地球早期地质演化的关键.为进一步揭示扬子陆块基底物质组成和早期地壳形成演化,采用LA-ICP-MS锆石微区U-Pb测年,对扬子陆块西南缘禄丰地区东川群变质砂岩进行了年代学研究,发现3 822±21 Ma的古老碎屑锆石.这是目前在扬子陆块获得的第2颗>3.8 Ga的古老锆石,也是目前在该地区发现的最老锆石.变质砂岩碎屑物质主要包括4个峰值年龄（~2 320 Ma、~2 162 Ma、~2 036 Ma和~1 915 Ma）,2颗最年轻的锆石年龄基本限定了东川群早期最大沉积时限,与区域上火山岩时代相吻合.另外还包含少量中-晚太古代（2.6~2.9 Ga）和始太古代（3.7~3.8 Ga）的碎屑物质.Hf同位素组成显示这些碎屑锆石具有不同成因,其中2 674~3 822 Ma的碎屑锆石总体具有正的ε_Hf（t）值和2.9~3.9 Ga的两阶段模式年龄,暗示扬子陆块在冥古宙-古太古代时期就有一定规模的新生陆壳分布.古元古代（1.9~2.4 Ga）的岩浆活动除有少量古元古代（2.3~2.4 Ga）新生地壳组分熔融外,大多为太古宙（2.5~3.7 Ga）古老地壳部分熔融.中元古代更多表现为古老地壳的熔融和物质再循环.研究结果为深化扬子陆块早前寒武纪地质演化认识提供了新资料.      

中国最老岩石和锆石

在中国大陆的许多地区都已发现大于3.4Ga的锆石和岩石.鞍山是全球仅有几个存在≥3.8Ga岩石的地区之一.它们以不大的规模存在于白家坟、东山、深沟寺杂岩中,由糜棱岩化奥长花岗岩、条带状奥长花岗岩和变质石英闪长岩组成.近年来,在鞍山地区还发现了许多3.7～3.6Ga岩石和锆石.锆石Hf同位素组成表明鞍山地区在3.8～3.6Ga期间存在周期性的地幔添加和陆壳形成.除鞍山外,在中国许多地区的不同类型岩石中也获得了≥3.4Ga锆石,虽然它们大多数都是碎屑和残余成因.(1)华北克拉通冀东铬云母石英岩中3.85～3.55Ga碎屑锆石:(2)华北克拉通信阳中生代火山岩长英质麻粒岩中3.66Ga岩浆锆石;(3)华南克拉通宜昌地区杨子地块新元古代砂岩中3.80Ga碎屑锆石(一颗);(4)华南克拉通华夏地块新元古代一古生代变质沉积岩中3.76～3.6Ga碎屑锆石;(5)西北地区塔里木地块阿克塔什塔格地区古元古代片麻状花岗岩中3.6Ga残余锆石;(6)西秦岭奥陶纪变质火山岩中4.08Ga捕掳锆石(一颗);(7)西藏普兰地区奥陶纪石英岩中4.1Ga碎屑锆石(一颗,有3.61Ga增生边).一些古老锆石有高达4.1～4.0Ga的Hf同位素模式年龄.在中国,>3.4Ga地壳物质的比例以往被低估了,发现冥古宙和始太古代物质的可能性仍然存在,它们将对中国早期陆壳演化提供新的制约.     

北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的岩石成因及其构造意义

文中研究了北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的年代学、地球化学和Sr-Nd同位素组成。毛藏寺岩体主要岩石类型为花岗闪长岩。锆石U Pb定年获得花岗闪长岩岩浆结晶年龄为（424±4） Ma。花岗闪长岩具有高的Mg#（约55）,K2O/Na2O=0.77~0.91,A/CNK=0.92~0.94,表明岩石属准铝质。在微量元素组成上,花岗闪长岩富集LILE、亏损HFSE,轻重稀土分异明显［(La/Yb)N=16.9~19.5］,具有弱的Eu负异常（Eu/Eu*=0.75~0.83）;花岗闪长岩具有ISr=0.706 3~0.706 5,εNd(t) =-1.5~-1.1,TDM=1.10~1.16 Ga。这些地球化学特征和Sr Nd同位素组成表明,花岗闪长岩岩浆源区为基性下地壳变玄武质岩石,但在成岩过程中有少量幔源物质的加入。黄羊河岩体主要由钾长花岗岩组成,其岩浆结晶年龄为（402±4） Ma。岩石富碱（K2O+Na2O=6.91‰~7.66%）,K2O/Na2O>1,A/CNK=0.97~1.05。钾长花岗岩富集LILE及HFSE,轻重稀土元素分馏中等［(La/Yb)N =10.6~17.8］,并具有明显的负Eu异常（Eu/Eu*=0.43~0.68）,表明钾长花岗岩具有铝质A型花岗岩的地球化学特征。钾长花岗岩具有ISr=0.710 3~0.711 3,εNd(t)=-6.7~-6.0,TDM=1.46~1.55 Ga,反映岩浆主要来自地壳中长英质物质的部分熔融。冷龙岭地区花岗岩类的岩石成因及其岩浆演化揭示了北祁连山造山带从加里东早期的挤压构造体制向加里东晚期的伸展构造体制的演化。这些花岗岩类形成于碰撞后构造背景,岩浆的产生可能与俯冲的北祁连洋板片的断离作用有密切联系。     

鲁西莲花山地区新太古代晚期二长花岗岩中的表壳岩包体——SHRIMP锆石U-Pb定年和地球化学特征

为了确定鲁西莲花山地区新太古代晚期二长花岗岩中的表壳岩包体的形成时代，并探讨与相邻雁翎关地区的雁翎关岩组中的新太古代早期变质火山岩系的关系。本文对表壳岩包体及相关岩石进行了锆石年代学和地球化学研究。表壳岩包体主要由变质超基性岩和斜长角闪岩组成，另含少量（黑云）角闪变粒岩和黑云变粒岩。SHRIMP锆石U-Pb定年结果显示：角闪变粒岩的岩浆锆石年龄为2 757 Ma；侵入斜长角闪岩的奥长花岗岩脉的年龄为2 593 Ma；从变质超基性岩分选出很少锆石，它们普遍遭受强烈变质重结晶，²⁰⁷Pb/²⁰⁶Pb年龄为2 657~2 397 Ma。变质超基性岩具轻稀土亏损型或平坦型稀土模式，斜长角闪岩具平坦型稀土模式，角闪变粒岩具轻稀土略富集稀土模式，虽然大离子亲石元素相对富集，但都无明显Nb、Ta亏损。表壳岩包体的岩石组合、地球化学组成特征和形成时代可与相邻雁翎关地区的雁翎关岩组中的新太古代早期变质火山岩系对比，形成于大洋环境。新太古代早期表壳岩的原有分布范围应比现在所见到的更为广泛。     

华北克拉通太古宙构造热事件时代及演化

华北克拉通存在3.8 Ga以上的形成演化历史,存在4.0~4.1 Ga锆石年龄记录.本文对华北克拉通太古宙变质基底构造热事件进行了综述,重点是事件时限.最古老变质锆石年龄记录为3.71~3.75 Ga和4.0 Ga,为北秦岭造山带西段古生代变质火山-沉积岩中的碎屑或外来锆石.古太古代（~3.3 Ga）构造热事件在鞍山地区广泛存在,导致条带状奥长花岗岩形成.新太古代早期-中太古代晚期变质锆石年龄可进一步划分为两期:2.65~2.85 Ga和~2.6 Ga.2.65~2.85 Ga变质锆石年龄记录存在于胶东、鲁西、鲁山地区.由于后期构造热事件影响,在很多情况下难以确定变质锆石的准确年龄,但>2.65 Ga构造热事件在华北克拉通无疑存在.与2.65~2.85 Ga构造热事件相比,~2.6 Ga构造热事件更为发育,除在鲁西地区广泛存在外,在胶东、鲁山等地也存在.可把2.6 Ga作为华北克拉通新太古代早期和晚期的年龄界线.华北克拉通最重要的太古宙构造热事件出现在新太古代晚期（2.49~2.53 Ga）.所有太古宙岩石分布区,都遭受了这一构造热事件影响.总体上,与华北克拉通南部地区相比,华北克拉通北部地区普遍记录了更高级别变质作用,可能与地壳剥蚀深度不同有关.华北克拉通太古宙变质作用强度和范围随时间演化不断增大,在新太古代晚期达到高潮.与太古宙大陆壳厚度和规模随时间演化不断增大的演化趋势一致.一些地区存在古元古代最早期（2.40~2.47 Ga）甚至更年轻的变质锆石年龄记录,并不意味着构造热事件的真实存在,而是古元古代晚期构造热事件强烈叠加改造的缘故.      

Trace-element composition of hydrothermal zircon and the alteration of Hadean zircon from the Jack Hills,Australia

Hydrothermal zircon can be used to date fluid-infiltration events and water/rock interaction. At the Boggy Plain zoned pluton (BPZP), eastern Australia, hydrothermal zircon occurs with hydrothermal scheelite, molybdenite, thorite and rutile in incipiently altered aplite and monzogranite. The hydrothermal zircon is texturally distinct from magmatic zircon in the same rocks, occurring as murky-brown translucent 20–50 μm-thick mantles on magmatic cores and less commonly as individual crystals. The hydrothermal mantles are internally textureless in back-scatter electron and cathodoluminescence images whereas magmatic zircon is oscillatory zoned. The age of the hydrothermal zircon is indistinguishable from magmatic zircon, indicating precipitation from a fluid evolved from the magma during the final stages of crystallization. Despite indistinguishable U-Pb isotopic compositions, the trace-element compositions of the hydrothermal and magmatic zircon are distinct. Hydrothermal zircon is enriched in all measured trace-elements relative to magmatic zircon in the same rock, including V, Ti, Nb, Hf, Sc, Mn, U, Y, Th and the rare-earth elements (REE). Chondrite-normalized REE abundances form two distinct pattern groupings: type-1 (magmatic) patterns increase steeply from La to Lu and have Ce and Eu anomalies—these are patterns typical for unaltered magmatic zircon in continental crust rock types; type-2 (hydrothermal) patterns generally have higher abundances of the REE, flatter light-REE patterns [(Sm/La)_N = 1.5–4.4 vs. 22–110 for magmatic zircon] and smaller Ce anomalies (Ce/Ce* = 1.8–3.5 vs. 32–49 for magmatic zircon). Type-2 patterns have also been described for hydrothermally-altered zircon from the Gabel Hamradom granite, Egypt, and a granitic dyke from the Acasta Gneiss Complex, Canada.Hadean (∼4.5–4.0 Ga) zircon from the Jack Hills, Western Australia, have variable normalized REE patterns. In particular, the oldest piece of Earth—zircon crystal W74/2-36 (dated at 4.4 Ga)—contains both type-1 and type-2 patterns on a 50 μm scale, a phenomenon not yet reported for unaltered magmatic zircon. In the context of documented magmatic and hydrothermal zircon compositions from constrained samples from the BPZP and the literature, the type-2 patterns in crystal W74/2-36 and other Jack Hills Hadean (JHH) zircon are interpreted as hydrothermally-altered magmatic compositions. An alteration scenario, constrained by isotope and trace-element data, as well as α-decay event calculations, involving fluid/zircon cation and oxygen isotope exchange within partially metamict zones and minor dissolution/reprecipitation, may have occurred episodically for some JHH zircon and at ∼4.27 Ga for zircon W74/2-36. Type-2 compositions in JHH zircon are interpreted to represent localized exchange with a light-REE-bearing, high δ¹⁸O (∼6–10‰ or higher) fluid. Thus, a complex explanation involving “permanent” liquid water oceans, large-scale water/rock interaction and plate tectonics in the very early Archean is not necessary as the zircon textures and compositions are simply explained by exchange between partially metamict zircon and a low volume ephemeral fluid.     

浙西南玉岩花岗片麻岩锆石U-Pb年代学——华夏地块古老基底物质的探讨

通过对浙西南遂昌县玉岩古元古代花岗片麻岩锆石LA-ICP-MS U-Pb年代学研究,以探讨和揭示华夏地区基底的物质组成。玉岩花岗片麻岩锆石可分为两类:第一类锆石年龄相对年轻,其~(207)Pb/~(206)Pb年龄介于597~1917 Ma之间,结合稀土元素特征,表明为变质成因锆石,在锆石谐和图上,15个年轻锆石点整体上构成了一条不一致线,其上交点年龄为1904±19Ma,代表了片麻岩形成的变质时间,表明华夏地区存在古老的古元古代晚期岩浆岩-变质岩基底,下交点年龄为262±47Ma,可能记录了华夏地块晚二叠世―早三叠世构造-变质作用的响应。第二类锆石年龄相对较老,锆石~(207)Pb/~(206)Pb年龄介于2087~2523Ma之间,锆石发育核幔结构并有明显的振荡环带,较老的锆石年龄表明华夏地区可能存在太古宙末至2.5Ga的古老基底物质。     

冀东地区始太古代早期—冥古宙锆石发现

内容提要:最古老大陆地壳的形成、组成和演化是阐释地球壳幔物质分异、构造演化的逻辑起点.由于长期地质作用改造,地球上保存的古老陆壳物质十分稀少,寻找和研究都极具挑战性.在冀东卢龙喇叭山地区,早期研究发现含有大量3.4～3.8 Ga碎屑锆石的铬云母石英岩,岩石特征和碎屑锆石年龄分布与迁安黄柏峪地区的铬云母石英岩十分类似.本...     

青藏高原北羌塘三叠纪花岗岩中发现新元古代的基底信息:来自锆石SIMS U-Pb年龄和Hf-O同位素的约束

羌塘地块基底研究工作是青藏高原地学领域的难点。羌塘地区是否具有前寒武纪基底一直以来存在着很大的争议,现有的年代学资料虽有报道,但至今仍缺乏统一的认识。本文对北羌塘中部双湖地区花岗岩进行了SIMS锆石U-Pb年代学、全岩主微量元素、Sr-Nd同位素和锆石Hf-O同位素地球化学研究。双湖花岗岩形成于晚三叠世(~217 Ma),并捕获~828 Ma的锆石。双湖花岗岩具有高的SiO₂、K₂O和低的MgO含量(SiO2=64.00%~69.54%,K2O=4.09%~5.17%,MgO=1.44%~3.34%),具有轻稀土元素富集的配分模式,以及富集的全岩εNd(t)值(-9.6)和锆石原位εHf(t)值(-10.8~-8.1),岩浆锆石的δ¹⁸O值为6.98‰~8.30‰。岩相学和地球化学特征表明双湖花岗岩主要来源于中下地壳的部分熔融。综合区域内时空演化格架以及大量相关地质事实,认为双湖晚三叠世花岗岩形成于后碰撞伸展构造背景。捕获锆石的阴极发光显示较明显的振荡环带,表明来自于酸性岩浆岩;其具有高的不均一的O同位素(δ¹⁸O=8.20‰~10.23‰),Hf模式年龄为1.7~1.9 Ga,表明其源岩是来自古元古代地壳物质重熔形成的S型花岗岩,代表了北羌塘地块的基底。综合区域地质、岩石地球化学特征及其捕获锆石信息,本文认为双湖花岗岩为北羌塘地块可能具有扬子型晋宁期基底提供了重要信息。     

Evidence for an Early Archean component in the Middle to Late Archean gneisses of the Wind River Range,west-central Wyoming: conventional and ion microprobe U-Pb data

Gneissic rocks that are basement to the Late Archean granites comprising much of the Wind River Range, west-central Wyoming, have been dated by the zircon U-Pb method using both conventional and ion microprobe techniques. A foliated hornblende granite gneiss member from the southern border of the Bridger batholith is 2670±13 Ma. Zircons from a granulite just north of the Bridger batholith are equant and faceted, a typical morphology for zircon grown under high grade metamorphic conditions. This granulite, which may be related to a second phase of migmatization in the area, is 2698±8 Ma. South of the Bridger batholith, zircons from a granulite (charnockite), which is related to an earlier phase of migmatization in the Range, yield a discordia with intercept ages of about 2.3 and 3.3 Ga. However, ion microprobe analyses of single zircon grains indicate that this rock contains several populations of zircon, ranging in age from 2.67 to about 3.8 Ga. Based on zircon morphology and regional geologic relationships, we interpret the data as indicating an age of ≃3.2 Ga for the first granulite metamorphism and migmatization. Older, possibly xenocrystic zircons give ages of ≃3.35, 3.65 and ≃3.8 Ga. Younger zircons grew at 2.7 and 2.85 Ga in response to events, including the second granulite metamorphism at 2.7 Ga, that culminated in the intrusion of the Bridger batholith and migmatization at 2.67 Ga. These data support the field and petrographic evidence for two granulite events and provide some temporal constraints for the formation of continental crust in the Early and Middle Archean in the Wyoming Province.     

辽东半岛隆昌地区~2 113 Ma变辉长岩地球化学与Hf同位素研究:对胶辽吉造山带构造演化的制约

辉长岩的成岩时代、成因等研究对限定胶辽吉造山带构造背景等关键问题具有重要意义.对其开展详细的岩石地球化学分析、全岩Nd同位素和锆石U-Pb测年及原位Hf同位素分析,结果显示样品受蚀变影响不大,TiO₂含量较低（< 1.31%）,FeOT（11.91%~14.25%）、MgO（6.88%~7.62%）含量不高,K₂O含量中等偏高（0.85%~1.23%）,属钙碱性-高钾钙碱性岩浆系列,岩石轻重稀土分馏不明显,富集Rb、Ba、K等大离子亲石元素,亏损高场强元素P、Hf等,岩石相对富集Nd同位素,ε_Nd（t）值介于-1.6~2.6,（176Hf/177Hf）_i比值变化于0.281 497~0.281 612之间,ε_Hf（t）值变化于2.2~6.3之间,模式年龄t_DM1（Hf）值介于2.25~2.33 Ga.多种特征元素地球化学图解显示辉长岩具有E-MORB特征,与裂谷构造环境中产出的MORB和OIB不同.研究认为胶辽吉造山带在~2.1 Ga已存在洋壳俯冲,并可能已存在古岛弧,造山带演化过程中存在弧陆碰撞.      

华南晚奥陶世次火山岩的发现:早古生代与俯冲有关的英安岩?

华南早古生代花岗岩广泛分布,但同时代的(次)火山岩却很罕见.本次研究采用LA-ICPMS锆石U-Pb定年方法,结合微区原位Hf同位素分析,对南岭广东韶关地区的河口、上洞英安岩进行了系统研究.结果表明英安岩形成于448.7±1.7 Ma,为晚奥陶世岩浆活动产物.岩石为斑状结构,常见石英碎斑或港湾状石英斑晶,基质为隐晶质,具有典型浅成岩石特征.地球化学资料表明,这些岩石属于高钾钙碱性英安岩.英安岩微量元素显示了轻稀土富集、高场强元素(Ta、Nb)亏损和极低的Cr、Ni含量等明显火山弧岩浆特征.同位素数据显示河口、上洞英安岩全岩I_Sr=0.709 0~0.714 0,ε_Nd(t)=-8.9~-9.3,锆石ε_Hf(t)变化范围为-8.06~-3.80,与华南加里东期主要花岗岩类同位素特征一致,具有壳源属性.二阶段Hf模式年龄范围为1.67~1.93 Ga,与Nd模式年龄结果1.91~1.94 Ga相近;表明河口、上洞英安岩来源于古元古代结晶基底地壳物质.河口、上洞奥陶纪英安岩的发现,进一步证明该区早古生代存在俯冲岩浆活动,为研究华南早古生代地质事件提供了新的证据.      

张家口地区桑干杂岩中花岗片麻岩的锆石U-Pb年龄与Hf同位素特征及其对华北克拉通早期演化的制约

冀西北崇礼地区的桑干变质杂岩位于赤城-崇礼断裂以南,怀安杂岩东北侧,主要为一套遭受强烈变质,普遍达到角闪-麻粒岩相的中高级变质岩系。锆石U-Pb定年结果显示,花岗闪长质片麻岩的原岩形成年龄为2.54～2.50Ga;富钾的二长花岗质岩浆侵位时代为～2.44Ga;二者都在2.37～2.30Ga经历了一次重要的变质事件。花岗闪长质片麻岩相对较低的εNd(t)值(-1.06),锆石εHf(t)值(平均值为-1.6)以及较老的Hf模式年龄表明其原岩的形成源区含有更古老地壳物质,反映了该区或周围地区可能存在3.0～2.9Ga的基底。二长花岗质片麻岩的地球化学特征(如高SiO2、K、低Mg#等)以及相对较高的εNd(t)值(-0.39～+0.92)和锆石εHf(t)值(+0.11～+1.85)表明其源区含有大量的新生地壳物质,可能为早期TTG质岩石部分熔融的产物。结合前人对华北克拉通中部构造带的研究资料,我们认为～2.44Ga左右富钾质的岩浆活动可能反映了中部构造带局部发生的碰撞后构造背景,而2.37～2.30Ga该地区可能包括整个中部构造带经历了一次变质热事件,与区域广泛的伸展作用相关。     

Stages and conditions of metamorphism of mafic granulites in the Early Precambrian complex of the Angara–Kan terrane (southwestern Siberian Craton)

We present results of study of mineral assemblages and PT-conditions of metamorphism of mafic garnet–two-pyroxene and two-pyroxene granulites in the Early Precambrian metamorphic complex of the Angara–Kan terrane as well as the U–Pb age and trace-element and Lu–Hf isotope compositions of zircon from these rocks and the zircon/garnet REE distribution coefficients. The temperatures of metamorphism of two-pyroxene granulites are estimated as 800–870 to ~ 900 °C. Mafic garnet–two-pyroxene granulites contain garnet coronas formed at 750–860 °C and 8–9.5 kbar. The formation of the garnet coronas proceeded probably at the retrograde stage during cooling and was controlled by the rock composition. The age (1.92–1.94 Ga) of zircon cores, which retain the REE pattern typical of magmatic zircon, can be taken as the minimum age of protolith for the mafic granulites. The metamorphic zircon generation in the mafic granulites is represented by multifaceted or soccerball crystals and rims depleted in Y, MREE, and HREE compared to the cores. The age of metamorphic zircon in the garnet–two-pyroxene (~ 1.77 Ga) and two-pyroxene granulites (~ 1.85 and 1.78 Ga) indicates two episodes of high-temperature metamorphism. The presence of one generation (1.77 Ga) of metamorphic zircon in the garnet–two-pyroxene granulites and, on the contrary, the predominance of 1.85 Ga zircon in the two-pyroxene granulites with single garnet grains suggest that the formation of the garnet coronas proceeded at the second stage of metamorphism. The agreement between the zircon/garnet HREE distribution coefficients and the experimentally determined values at 800 °C suggests the simultaneous formation of ~ 1.77 Ga metamorphic zircon and garnet. Zircon formation by dissolution/reprecipitation or recrystallization in a closed system without exchange with the rock matrix is confirmed by the close ranges of ¹⁷⁶Hf/¹⁷⁷Hf values for the core and rims. The positive ε_Hf values (up to + 6.2) for the zircon cores suggest that the protolith of mafic granulites are derived from depleted-mantle source. The first stage of metamorphism of the mafic granulites and paragneisses of the Kan complex (1.85–1.89 Ga) ended with the formation of collisional granitoids (1.84 Ga). The second stage (~ 1.77 Ga) corresponds to the intrusion of the second phase of subalkalic leucogranites of the Taraka pluton and charnockites (1.73–1.75 Ga).     

辽宁鞍山地区东山杂岩带3.3~3.1 Ga期间的岩浆作用——锆石SHRIMP U-Pb定年

报道了鞍山地区东山杂岩带奥长花岗岩和二长花岗岩的锆石SHRIMP U-Pb年龄。中粗粒奥长花岗岩中岩浆锆石的年龄为3329 Ma ± 22 Ma (MSWD=9.6),存在年龄为3687~3784 Ma的残余锆石。细粒奥长花岗岩和二长花岗岩中岩浆锆石的年龄分别为3141 Ma ± 8 Ma (MSWD=1.5)和3142 Ma ± 5 Ma (MSWD=0.35)。研究表明,约~3.3 Ga和3.1 Ga是鞍山地区2个重要的地壳演化阶段。     

LA-ICP-MS U-Pb Zircon Dating for Felsic Granulite, Huangtuling Area, North Dabieshan: Constraints on Timing of Its Protolith and Granulite-Facies Metamorphism, and Thermal Events in Its Provenance

Information about the protolith of the Huangtuling granulite in North Dabieshan has been unavailable. The complex evolution history of the rock and its host basement must be further discussed. LA-ICP-MS U-Pb dating was conducted on three textural domains in zircon from a high-temperature, high-pressure felsic granulite in the Huangtuling area, North Dabieshan, Central China. The metamorphic growth-derived detrital zircon domain yields a 207Pb/206Pb age in the range of (2 493±54) -(2 500±180) Ma. The magmatic genesis-derived detrital zircon domain gives a 207Pb/206Pb age ranging from 2 628 Ma to 2 690 Ma, with an oldest 206Pb/238U age of (2 790±150) Ma. The metamorphic overgrowth or metamorphic recrystallization zircon domain yields a dicsordia with an upper intercept age of (2 044.7±29.3) Ma. Compositions of the mineral assemblage, major element geochemistry, and especially the complex interior texture of the zircon suggest that the prololith of the felsic granulite is of sedimentary origin. Results show that the protolith material of the granulite came from a provenance with a complex thermal history, i.e. ～2.8 Ga magmatism and ～2.5 Ga metamorphism, and was deposited in a basin not earlier than 2.5 Ga. The high-temperature and high-pressure granulite-facies metamorphic age was precisely constrained at (2.04±0.03) Ga, which indicates the granulite in Huangtuling area should be a relict of a Paleoproterozoic UHT (ultrahigh temperature) metamorphosed slab.